FORM 2
THE PATENTS ACT, 1970
(39 of 1970)
&
THE PATENTS RULES, 2003
COMPLETE SPECIFICATION (See section 10, rule 13)
1. Title of the invention: A PRODUCT FOR DYEING OF KERATIN FIBRES, AND
METHODS THEREOF
2. Applicant(s)
NAME NATIONALITY ADDRESS
L'OREAL French 14 rue royale 75008 PARIS, France
3. Preamble to the description
COMPLETE SPECIFICATION
The following specification particularly describes the invention and the manner in which it
is to be performed.

FIELDOFINVENTION
[0001] The present disclosure relates, in general, to personal care products,
and more particularly, to products and compositions for the dyeing of keratin fibres. The present disclosure further relates to a method for the dyeing of keratin fibres.
BACKGROUNDOFINVENTION
[0002] The use of colorants and developers in dyeing or coloring of hair is
a well-known practice. Efforts towards achieving long lasting effect, uniform color delivery, and improved color effect have resulted in the development and use of various oxidizing dyes, oxidizing agents, etc in hair dyeing products. Typically, in dyeing of hair, the melanin pigment in keratin fibres is decolorized to bleach the hair followed by coloring using a colorant or dye, for eg. oxidative dye. Oxidizing compositions having colorants and developers including oxidizing dye and oxidation agents, respectively, are generally required to be mixed in a bowl which may then be applied to hair. This is often inconvenient for users as it requires prior preparation, especially the provision of bowls, brushes, etc., and is not desirable. Further, such products having varied rheologies often pose issues in achieving optimum spreadability and uniform color delivery on the hair. While it is desirable to achieve creamy and uniform consistency, the use of thickeners or rheology modifiers pose an issue in respect of stability in oxidizing compositions. Such issues of stability may be attributed to the high reactivity of such thickeners with the oxidizing agents.
[0003] Further, the colorant and developers are generally required to remain
on the hair for a pause time of about 30 to 60 minutes, for color development. It is highly desirable to reduce this pause time to achieve faster coloration of hair, especially without compromising color uptake by the keratin fibres. Generally known compositions having oxidizing agents are required to have a pause time of about 60 minutes making hair dyeing a time taking process. Therefore, there is a

need for products that achieve improved cosmetic properties such as uniform color delivery, even color tone, efficient coloration, good conditioning effect, and creamy consistency while having a good consumer feel and improving consumer convenience.
SUMMARYOFTHEINVENTION
[0004] In an aspect of the present disclosure, there is provided a product for
dyeing of keratin fibres, comprising a first composition and a second composition, wherein said first composition comprises at least one oxidative dye, at least one alkaline agent, at least one non-ionic surfactant, and at least one fatty acid; and said second composition comprises at least one oxidizing agent, and at least one non-ionic ether of polyoxyalkylenated fatty alcohol.
[0005] In an aspect of the present disclosure, there is provided a method for
dyeing of keratin fibre, comprising providing a first composition and a second
composition, wherein said first composition comprises at least one oxidative dye,
at least one alkaline agent, at least one non-ionic surfactant, and at least one fatty
acid; and said second composition comprises at least one oxidizing agent, and at
least one non-ionic ether of polyoxyalkylenated fatty alcohol; mixing the first
composition and second composition, applying the mixture on said fibre; and
allowing the mixture to stand for a pause time in the range of 5 to 15 minutes.
[0006] In another aspect of the present disclosure, there is provided a
method for dyeing of keratin fibre, comprising providing a product including a first composition and second composition, wherein said first composition comprises at least one oxidative dye, at least one alkaline agent, at least one non-ionic surfactant, and at least one fatty acid; and said second composition comprises at least one oxidizing agent, and at least one non-ionic ether of polyoxyalkylenated fatty alcohol; and applying the product on said fibre.
[0007] In another aspect of the present disclosure, there is provided a ready-
to-use composition obtained by mixing a first composition and a second composition, wherein said first composition comprises at least one oxidative dye, the total amount of oxidative dye in the first composition is ranging from 0.0002%

to 20% by weight, relative to the first composition, at least one alkaline agent, at least one non-ionic surfactant, the total amount of non-ionic surfactant in the first composition is ranging from 0.1 to 20% by weight, relative to the first composition, and at least one fatty acid; and said second composition comprises: at least one oxidizing agent, and at least one non-ionic ether of polyoxyalkylenated fatty alcohol.
[0008] These and other features, aspects, and advantages of the present
subject matter will be better understood with reference to the following description and appended claims. This summary is provided to introduce a selection of concepts in a simplified form. This summary is not intended to identify key features or essential features of the claimed subject matter, nor is it intended to be used to limit the scope of the claimed subject matter.
DESCRIPTIONOFTHEINVENTION
[0009] Those skilled in the art will be aware that the present disclosure is
subject to variations and modifications other than those specifically described. It is to be understood that the present disclosure includes all such variations and modifications. The disclosure also includes all such steps, features, compositions, and compounds referred to or indicated in this specification, individually or collectively, and any and all combinations of any or more of such steps or features. Definitions
[0010] For convenience, before further description of the present
disclosure, certain terms employed in the specification, and examples are delineated here. These definitions should be read in the light of the remainder of the disclosure and understood as by a person of skill in the art. The terms used herein have the meanings recognized and known to those of skill in the art, however, for convenience and completeness, particular terms and their meanings are set forth below.
[0011] The articles “a”, “an” and “the” are used to refer to one or to more
than one (i.e., to at least one) of the grammatical object of the article.

[0012] The terms “comprise” and “comprising” are used in the inclusive,
open sense, meaning that additional elements may be included. It is not intended to
be construed as “consists of only”.
[0013] The term "at least one" is used to mean one or more and thus includes
individual components as well as mixtures/combinations.
[0014] Throughout this specification, unless the context requires otherwise
the word “comprise”, and variations such as “comprises” and “comprising”, will be
understood to imply the inclusion of a stated element or step or group of element or
steps but not the exclusion of any other element or step or group of element or steps.
[0015] The term “including” is used to mean “including but not limited to”.
“Including” and “including but not limited to” are used interchangeably.
[0016] The term “INCI” is an abbreviation of International Nomenclature
of Cosmetic Ingredients, which is a system of names provided by the International
Nomenclature Committee of the Personal Care Products Council to describe
personal care ingredients.
[0017] The term “pause time”, as used herein, refers to the time period a
hair dyeing product remains on hair. It particularly refers to the duration of time for
which the hair dyeing product remains on the hair for coloration or color
development.
[0018] The term “alkanolamine”, as used herein, refers to an organic amine
comprising a primary, secondary, or tertiary amine function, and one or more linear
or branched C1-C8 alkyl groups bearing one or more hydroxyl radicals.
[0019] The term “alkoxylated surfactant”, as used herein, refers to
surfactants having oxyalkyl or oxyalkylene units, for example oxyethylene units,
oxypropylene units, or combination thereof, and include monooxyalkylated and/or
polyoxyalkylated surfactants.
[0020] The term “C8-C30 fatty alcohol”, as used herein, refers fatty alcohols
which are linear or branched, acyclic or cyclic, substituted, or unsubstituted,
saturated or unsaturated alcohols containing 8 to 30 carbon atoms.
[0021] The term “C8-C30 amides”, as used herein, refers to amides which
are linear or branched, acyclic or cyclic, substituted, or unsubstituted, saturated, or

unsaturated amides containing from 8 to 30 carbon atoms. The C8-C30 acids, in various embodiments herein, refers to acids, for eg: fatty acid, which are linear or branched, acyclic or cyclic, substituted, or unsubstituted, saturated, or unsaturated acids containing 8 to 30 carbon atoms.
[0022] The term "associative polymers", as used herein, refers to water-
soluble polymers that are capable, in an aqueous medium, of reversibly combining with each other or with other molecules. Their chemical structure comprises at least one hydrophilic region and at least one hydrophobic region characterized by at least one C8-C30 fatty chain.
[0023] The term “amphoteric polymers”, as used herein, refers to any
polymer comprising cationic groups and/or groups that can be ionized to cationic
groups, and anionic groups and/or groups that can be ionized to anionic groups.
[0024] The term “liquid”, as used herein, refers to liquid state, especially of
fatty compounds, at ambient temperature (25°C) and at atmospheric pressure (760 mmHg or 1.013 × 105 Pa), and include for eg: oils.
[0025] All percentages, parts and ratios are based upon the total weight of
the compositions of the present disclosure unless otherwise indicated. Ratios, concentrations, amounts, and other numerical data may be presented herein in a range format. It is to be understood that such range format is used merely for convenience and brevity and should be interpreted flexibly to include not only the numerical values explicitly recited as the limits of the range, but also to include all the individual numerical values or sub-ranges encompassed within that range as if each numerical value and sub-range is explicitly recited. For example, a percentage range of about 15 % to 20 % should be interpreted to include not only the explicitly recited limits of about 15 % to about 20 %, but also to include sub-ranges, such as 16 % to 18 %, 17 % to 19%, and so forth, as well as individual amounts, including fractional amounts, within the specified ranges, such as 15.8 %, and 17.25 %, for example.
[0026] Unless defined otherwise, all technical and scientific terms used
herein have the same meaning as commonly understood by one of ordinary skill in the art to which this disclosure belongs. Although any methods and materials

similar or equivalent to those described herein can be used in the practice or testing of the disclosure, the preferred methods and materials are now described. All publications mentioned herein are incorporated herein by reference.
[0027] The present disclosure is not to be limited in scope by the specific
embodiments described herein, which are intended for the purposes of exemplification only. Functionally equivalent products, compositions, and methods are clearly within the scope of the disclosure, as described herein.
[0028] Embodiments herein provide a product for dyeing of keratin fibres.
The product, according to embodiments herein, achieves improved cosmetic properties in dyeing of the fibres. It facilitates achieving uniform color delivery, smoothening of keratin fibres, and long-lasting effect while having a shorter pause time. It further provides improved consumer convenience and faster dyeing solutions while achieving efficient color delivery along with a good conditioning effect. In various embodiments herein, the product includes a first composition and a second composition which can be received and applied by hand on keratin fibres. Further, the first composition and second composition, according to embodiments herein, have rheological properties that are suited to provide uniform delivery of the product on the fibres and achieve a creamy consistency. The embodiments herein provide a consumer convenient method of dyeing keratin fibres which also enables improved and even coverage through application by hand and does not require the use of brushes, bowls, etc, for application. Accordingly, the embodiments herein provide a method for dyeing keratin fibres. The embodiments herein, further, include a method for preparation of the product and compositions.
Product
[0029] Embodiments herein provide a product for dyeing of keratin fibres.
The product, according to embodiments herein, comprises a first composition and a second composition. The combination of the first composition and second composition, as disclosed herein, achieves improved tinctorial and cosmetic properties, such as uniform color delivery, long lasting effect, improved color effect, such as intensity, selectivity, chromaticity, etc. while having a shorter pause

time. The pause time generally varies between 30 to 60 mins. Embodiments herein achieve a shorter or reduced pause time of less than 10 mins, in the range of 5 to 10 min. Therefore, the embodiments herein, achieve improved tinctorial and cosmetic properties such as uniform color delivery, long lasting, improved color, etc. in about 5 to 10 mins.
[0030] The first composition and second composition, according to
embodiments herein, have rheological properties that facilitate improved tinctorial and cosmetic properties such as uniform color delivery, even color tone, efficient color delivery, good conditioning effect, and creamy consistency having good consumer feel. The product, and the compositions, are capable of being received and applied on keratin fibres by hand of a user. Thus, it achieves the application of the product without the need for brushes, spatula, bowls, etc, thereby contributing to consumer convenience.
[0031] In an embodiment, the product comprises a first composition and a
second composition, wherein the first composition comprises at least one oxidative dye, at least one alkaline agent, at least one non-ionic surfactant, and at least one fatty acid; and the second composition comprises at least one oxidizing agent, and at least one non-ionic ether of polyoxyalkylenated fatty alcohol.
[0032] In another embodiment, the product comprises a first composition
and a second composition, wherein the first composition comprises at least one oxidative dye, at least one alkaline agent, at least one non-ionic surfactant, at least one fatty acid, and at least one fatty compound other than fatty acids; and the second composition comprises at least one oxidizing agent, and at least one non-ionic ether of polyoxyalkylenated fatty alcohol.
[0033] In an embodiment, the product comprises a first composition and a
second composition, wherein the first composition comprises at least one oxidative dye, at least one alkaline agent, at least one non-ionic surfactant, at least one fatty acid, and at least one polymer selected from the group consisting of non-ionic associative polymer and amphoteric polymer; and the second composition

comprises at least one oxidizing agent, and at least one non-ionic ether of polyoxyalkylenated fatty alcohol.
[0034] In an embodiment, the product comprises a first composition and a
second composition, wherein the first composition comprises at least one oxidative dye, at least one alkaline agent, at least one non-ionic surfactant, at least one fatty acid, at least one fatty compound other than fatty acids, and at least one polymer selected from the group consisting of non-ionic associative polymer and amphoteric polymer; and wherein the second composition comprises at least one oxidizing agent, and at least one non-ionic ether of polyoxyalkylenated fatty alcohol.
[0035] In another embodiment, the product comprises a first composition
and a second composition, wherein the first composition comprises at least one oxidative dye, the total amount of oxidative dye(s) in the first composition ranging from 0.0002% to 20% by weight of the first composition; at least one alkaline agent, at least one non-ionic surfactant, the total amount of non-ionic surfactant in the first composition ranging from 0.1 to 20% by weight of the first composition; at least one fatty acid; and the second composition comprises at least one oxidizing agent; and at least one non-ionic ether of polyoxyalkylenated fatty alcohol.
First composition
[0036] Embodiments herein include a first composition comprising at least
one oxidative dye, at least one alkaline agent, at least one non-ionic surfactant, at least one fatty acid. The first composition, according to embodiments herein, may further, optionally include other additives such as at least one fatty compound, vitamins, fragrances, adjuvants, dispersants, polymers, film-forming agents, ceramides, preserving agents, opacifiers, antioxidants, penetrants, sequestrants, solvents, etc.
Oxidative dye
[0037] Embodiments of the first composition include at least one oxidative
dye. The oxidative dye, according to embodiments herein, include at least one oxidation base and at least one oxidation coupler. Oxidation bases are generally

colorless or weakly colored compounds which when mixed with oxidizing compounds give rise to colored compounds or dye. Further, the color shades obtained with such oxidation bases can be varied by combining them with oxidation couplers or color modifiers. The first composition, according to embodiments herein, may include one or more oxidation bases and couplers.
[0038] The oxidation bases, according to embodiments herein, may be
selected from para-phenylenediamines, bis(phenyl)alkylenediamines, para-aminophenols, ortho-aminophenols, heterocyclic bases, or the addition salts thereof, or combinations thereof.
[0039] The para-phenylenediamines that may be used include, for example,
para-phenylenediamine, para-tolylenediamine, 2-chloro-para-phenylenediamine,
2,3-dimethyl-para-phenylenediamine, 2,6-dimethyl-para-phenylenediamine, 2,6-
diethyl-para-phenylenediamine, 2,5-dimethyl-para-phenylenediamine, N,N-
dimethyl-para-phenylenediamine, N,N-diethyl-para-phenylenediamine, N,N-
dipropyl-para-phenylenediamine, 4-amino-N,N-diethyl-3-methylaniline, N,N-
bis(p-hydroxyethyl)-para-phenylenediamine, 4-N,N-bis(p-hydroxyethyl)amino-2-
methylaniline, 4-N,N-bis(p-hydroxyethyl)amino-2-chloroaniline, 2-p-
hydroxyethyl-para-phenylenediamine, 2-y-hydroxypropyl-para-phenylenediamine,
2-methoxymethyl-para-phenylenediamine, 2-fluoro-para-phenylenediamine, 2-
isopropyl-para-phenylenediamine, N-(p-hydroxypropyl)-para-phenylenediamine,
2-hydroxymethyl-para-phenylenediamine, N,N-dimethyl-3-methyl-para-
phenylenediamine, N,N-(ethyl-p-hydroxyethyl)-para- phenylenediamine, N-(p,y-
dihydroxypropyl)-para-phenylenediamine, N-(4'-aminophenyl)-para-
phenylenediamine, N-phenyl-para-phenylenediamine, 2-p-hydroxyethyloxy-para-phenylenediamine, 2-p-acetylaminoethyloxy-para-phenylenediamine, N-(p-methoxyethyl)-para-phenylenediamine, 4-aminophenylpyrrolidine, 2-thienyl-para-phenylenediamine, 2-p-hydroxyethylamino-5-aminotoluene, 3-hydroxy-1-(4'-aminophenyl)pyrrolidine, and/or the addition salts thereof with an acid.
[0040] The para-phenylenediamines, that may be used in embodiments
herein, may preferably be selected from para-phenylenediamine, para-

tolylenediamine, 2-isopropyl-para-phenylenediamine, 2-p-hydroxyethyl-para-phenylenediamine, 2-p-hydroxyethyloxy-para-phenylenediamine, 2,6-dimethyl-para-phenylenediamine, 2,6-diethyl-para-phenylenediamine, 2,3-dimethyl-para-phenylenediamine, N,N-bis(p-hydroxyethyl)-para-phenylenediamine, 2-chloro-para-phenylenediamine, 2-p-acetylaminoethyloxy-para-phenylenediamine, or, preferably, the addition salts thereof with an acid, or mixtures thereof.
[0041] The bis(phenyl)alkylenediamines that may be used include, for
example, N,N'-bis(p-hydroxyethyl)-N,N'-bis(4'-aminophenyl)-1,3-
diaminopropanol, N,N'-bis-(p-hydroxyethyl)-N,N'-bis(4'-
aminophenyl)ethylenediamine, N,N'-bis(4-aminophenyl)tetramethylenediamine,
N,N'-bis(p-hydroxyethyl)-N,N'-bis(4-aminophenyl)tetramethylenediamine, N,N'-
bis(4-methylaminophenyl)tetramethylenediamine, N,N'-bis(ethyl)-N,N'-bis(4'-
amino-3'-methylphenyl)ethylenediamine, 1,8-bis(2,5-diaminophenoxy)-3,6-
dioxaoctane, and/or the addition salts thereof.
[0042] The para-aminophenols that may be used include, for example, para-
aminophenol, 4-amino-3-methylphenol, 4-amino-3-fluorophenol, 4-amino-3-chlorophenol, 4-amino-3-hydroxymethylphenol, 4-amino-2-methylphenol, 4-amino-2-hydroxymethylphenol, 4-amino-2-methoxymethylphenol, 4-amino-2-aminomethylphenol, 4-amino-2-(p-hydroxyethylaminomethyl)phenol and 4-amino-2-fluorophenol, and/or the addition salts thereof with an acid. In an example, the addition salt is salt of sulphurous acid or sodium metabisulphite salt. Accordingly, in an embodiment, the oxidation base is a combination of para-aminophenol and sodium metabisulphite.
[0043] The ortho-aminophenols that may be used include, for example, 2-
aminophenol, 2-amino-5-methylphenol, 2-amino-6-methylphenol and 5-acetamido-2-aminophenol, and/or the addition salts thereof.
[0044] Various heterocyclic bases are known and may be used in
embodiments herein. Examples of such heterocyclic bases include pyridine derivatives, pyrimidine derivatives and pyrazole derivatives.

[0045] Further, the pyridine derivatives, in various embodiments herein,
may be selected from the compounds as described, for example, in patents GB 1 026 978 and/or GB 1 153 196, including 2,5-diaminopyridine, 2-(4-methoxyphenyl)amino-3-aminopyridine, 3,4-diaminopyridine, and/or the addition salts thereof.
[0046] The pyridine derivatives that may be used, in some embodiments
herein, include 3-aminopyrazolo[1,5-a]pyridine oxidation bases or addition salts
thereof described, for example, in patent application FR 2 801 308. Examples of
such bases include pyrazolo[1,5-a]pyrid-3-ylamine, 2-acetylaminopyrazolo[1,5-
a]pyrid-3-ylamine, 2-morpholin-4-ylpyrazolo[1,5-a]pyrid-3-ylamine, 3-
aminopyrazolo[1,5-a]pyridine-2-carboxylic acid, 2-methoxypyrazolo[1,5-a]pyrid-
3-ylamine, (3-aminopyrazolo[1,5-a]pyrid-7-yl)methanol, 2-(3-aminopyrazolo[1,5-
a]pyrid-5-yl)ethanol, 2-(3-aminopyrazolo[1,5-a]pyrid-7-yl)ethanol, (3-
aminopyrazolo[1,5-a]pyrid-2-yl)methanol, 3,6-diaminopyrazolo[1,5-a]pyridine,
3,4-diaminopyrazolo[1,5-a]pyridine, pyrazolo[1,5-a]pyridine-3,7-diamine, 7-
morpholin-4-ylpyrazolo[1,5-a]pyrid-3-ylamine, pyrazolo[1,5-a]pyridine-3,5-
diamine, 5-morpholin-4-ylpyrazolo[1,5-a]pyrid-3-ylamine, 2-[(3-
aminopyrazolo[1,5-a]pyrid-5-yl)(2-hydroxyethyl)amino]ethanol, 2-[(3-
aminopyrazolo[1,5-a]pyrid-7-yl)(2-hydroxyethyl)amino]ethanol, 3-
aminopyrazolo[1,5-a]pyridin-5-ol, 3-aminopyrazolo[1,5-a]pyridin-4-ol, 3-
aminopyrazolo[1,5-a]pyridin-6-ol and 3-aminopyrazolo[1,5-a]pyridin-7-ol, and/or
the addition salts thereof.
[0047] Embodiments herein may further include pyrimidine derivatives
selected from the compounds described, for example, in the patents DE 2359399; JP 88-169571; JP 05-63124; EP 0770375 or patent application WO 96/15765, including 2,4,5,6-tetraaminopyrimidine, 4-hydroxy-2,5,6-triaminopyrimidine, 2-hydroxy-4,5,6-triaminopyrimidine, 2,4-dihydroxy-5,6-diaminopyrimidine, 2,5,6-triaminopyrimidine and their addition salts and their tautomeric forms, when a tautomeric equilibrium exists.

[0048] The pyrazole derivatives that may be used, in various embodiments
herein, may be selected from, for example, the compounds described in the patents
DE 3843892, DE 4133957 or patent applications WO 94/08969, WO 94/08970,
FR-A-2 733 749 or DE 195 43 988, including for example 4,5-diamino-1-methyl-
pyrazole, 4,5-diamino-1-(p-hydroxyethyl)pyrazole, 3,4-diaminopyrazole, 4,5-
diamino-1-(4'-chlorobenzyl)pyrazole, 4,5-diamino-1,3-dimethylpyrazole, 4,5-
diamino-3-methyl-1-phenylpyrazole, 4,5-diamino-1-methyl-3-phenylpyrazole, 4-
amino-1,3-dimethyl-5-hydrazinopyrazole, 1-benzyl-4,5-diamino-3-methyl-
pyrazole, 4,5-diamino-3-tert-butyl-1-methylpyrazole, 4,5-diamino-1-tert-butyl-3-
methylpyrazole, 4,5-diamino-1-(p-hydroxyethyl)-3-methylpyrazole, 4,5-diamino-
1-ethyl-3-methylpyrazole, 4,5-diamino-1-ethyl-3-(4'-methoxyphenyl)pyrazole,
4,5-diamino-1-ethyl-3-hydroxymethylpyrazole, 4,5-diamino-3-hydroxymethyl-1-
methylpyrazole, 4,5-diamino-3-hydroxymethyl-1-isopropylpyrazole, 4,5-diamino-
3-methyl-1-isopropylpyrazole, 4-amino-5-(2'-aminoethyl)amino-1,3-
dimethylpyrazole, 3,4,5-triaminopyrazole, 1-methyl-3,4,5-triaminopyrazole, 3,5-
diamino-1-methyl-4-methylaminopyrazole, 3,5-diamino-4-(p-hydroxyethyl)-
amino-1-methylpyrazole, and their addition salts. 4,5-diamino-1-(p-methoxyethyl)-pyrazole may also be used.
[0049] The pyrazole derivatives that may also be used, in various
embodiments herein, include diamino-N,N-dihydropyrazolopyrazolones and
especially those described in patent application FR-A-2 886 136, including 2,3-
diamino-6,7-dihydro- 1H, 5H-pyrazolo[1,2-a]pyrazol-1 -one, 2-amino-3 -
ethylamino-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazol-1-one, 2-amino-3-
isopropylamino-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazol-1-one, 2-amino-3-
(pyrrolidin-1-yl)-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazol-1-one, 4,5-diamino-
1,2-dimethyl-1,2-dihydropyrazol-3-one, 4,5-diamino-1,2-diethyl-1,2-
dihydropyrazol-3-one, 4,5-diamino-1,2-di-(2-hydroxyethyl)-1,2-dihydropyrazol-3-
one, 2-amino-3-(2-hydroxyethyl)amino-6,7-dihydro-1H,5H-pyrazolo[1,2-
a]pyrazol-1-one, 2-amino-3-dimethylamino-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazol-1-one, 2,3-diamino-5,6,7,8-tetrahydro-1H,6H-pyridazino[1,2-a]pyrazol-

1 -one, 4-amino-1,2-diethyl-5-(pyrrolidin-1 -yl)-1,2-dihydropyrazol-3 -one, 4-amino-5-(3-dimethylaminopyrrolidin-1-yl)-1,2-diethyl-1,2-dihydropyrazol-3-one, 2,3-diamino-6-hydroxy-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazol-1-one, 2,3-diamino-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazol-1-one and/or, preferably, a salt thereof, or mixture thereof.
[0050] In some embodiments, the heterocyclic base is one or more selected
from 4,5-diamino-1-(p-hydroxyethyl)pyrazole, 2,3-diamino-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazol-1-one, and/or a salt thereof.
[0051] In an embodiment, the oxidation bases comprises a combination of
at least one p-aminophenol, or salt thereof, selected from para-aminophenol, 4-
amino-3-methylphenol, 4-amino-3-fluorophenol, 4-amino-3-chlorophenol, 4-
amino-3-hydroxymethylphenol, 4-amino-2-methylphenol, 4-amino-2-
hydroxymethylphenol, 4-amino-2-methoxymethylphenol, 4-amino-2-
aminomethylphenol, 4-amino-2-(p-hydroxyethylaminomethyl)phenol and 4-
amino-2-fluorophenol, wherein the salt is an addition salts with an acid; and at least
one p-phenylenediamine, or salt thereof, selected from para-phenylenediamine,
para-tolylenediamine, 2-isopropyl-para-phenylenediamine, 2-p-hydroxyethyl-
para-phenylenediamine, 2-p-hydroxyethyloxy-para-phenylenediamine, 2,6-
dimethyl-para-phenylenediamine, 2,6-diethyl-para-phenylenediamine, 2,3-
dimethyl-para-phenylenediamine, N,N-bis(p-hydroxyethyl)-para-
phenylenediamine, 2-chloro-para-phenylenediamine, 2-p-acetylaminoethyloxy-para-phenylenediamine, wherein the salt is, preferably, an addition salts with an acid.
[0052] In an embodiment, the oxidation base is selected from para-
aminophenol, p-aminophenol, and sodium metabisulfite, p-phenylenediamine, or mixtures thereof.
[0053] Further, the embodiments herein include oxidation couplers.
Various couplers are generally known and may be used in embodiments herein. The couplers, according to embodiments herein, include meta-phenylenediamines,

meta-aminophenols, meta-diphenols, naphthalene-based couplers, heterocyclic couplers and/or the addition salts thereof.
[0054] Examples of couplers include 1,3-dihydroxybenzene, 1,3-
dihydroxy-2-methylbenzene, 4-chloro-1,3-dihydroxybenzene, 2,4-diamino-1-(ß-
hydroxyethyloxy)benzene, 2-amino-4-(ß-hydroxyethylamino)-1 -methoxybenzene,
1,3-diaminobenzene, 2,4-diaminophenoxyethanol, 1,3-bis(2,4-diaminophenoxy)-
propane, 3-ureidoaniline, 3-ureido-1-dimethylaminobenzene sesamol, 1-ß-
hydroxyethylamino-3,4-methylenedioxybenzene, a-naphthol, 2-methyl-1-
naphthol, 6-hydroxyindole, 4-hydroxyindole, 4-hydroxy-N-methylindole, 2-
amino-3-hydroxypyridine, 6-hydroxybenzomorpholine, 3,5-diamino-2,6-
dimethoxypyridine, 1-N-(ß-hydroxyethyl)amino-3,4-methylenedioxybenzene, 2,6-bis(ß-hydroxyethylamino)toluene, 6-hydroxyindoline, 2,6-dihydroxy-4-methyl-pyridine, 1-H-3-methylpyrazol-5-one, 1-phenyl-3-methylpyrazol-5-one, 2,6-dimethylpyrazolo-[1,5-b]-1,2,4-triazole, 2,6-dimethyl-[3,2-c]-1,2,4-triazole and 6-methylpyrazolo[1,5-a]-benzimidazole and/or the addition salts thereof with an acid, or mixtures thereof.
[0055] In an embodiment, the coupler is selected from 1,3-dihydroxy-
benzene, m-aminophenol, 2,4-diaminophenoxyethanol and/or salts thereof, or mixtures thereof.
[0056] In some embodiments, the addition salts of the oxidation bases
and/or couplers are especially chosen from the addition salts with an acid such as the hydrochlorides, hydrobromides, sulfates, citrates, succinates, tartrates, lactates, tosylates, benzenesulfonates, phosphates, and acetates.
[0057] The oxidation base(s), according to various embodiments herein,
each may, generally, be present in an amount ranging from 0.0001% to 10% by weight, relative to the total weight of the first composition. In an embodiment, the total amount of oxidation base is an amount ranging from 0.0001% to 10% by weight, relative to the total weight of the first composition. In another embodiment, the first composition comprises the oxidation base in an amount ranging from 0.005% to 5% by weight, relative to the total weight of the composition. In a

preferable embodiment, the amount of oxidation bases ranges from 0.005% to 5% by weight, relative to the total weight of the composition.
[0058] The coupler(s), according to embodiments herein, each may,
generally, be present in an amount ranging from 0.0001% to 10% by weight, relative to the total weight of the first composition. In an embodiment, the total amount of oxidation coupler is an amount ranging from 0.0001% to 10% by weight, relative to the total weight of the first composition. In a preferable embodiment, the composition comprises the oxidation coupler in an amount ranging from 0.005% to 5% by weight, relative to the total weight of the first composition.
[0059] The composition, in some embodiments, may further include one or
more direct dyes, preferably selected from cationic or nonionic, synthetic or natural direct dyes.
[0060] Examples of suitable direct dyes include nitrobenzene dyes; azo
direct dyes; azomethine direct dyes; methine direct dyes; azacarbocyanin direct dyes, such as tetraazacarbocyanins (tetraazapentamethines); quinone, particularly anthraquinone, naphthoquinone or benzoquinone direct dyes; azine direct dyes; xanthene direct dyes; triarylmethane direct dyes; indoamine direct dyes; indigoid direct dyes; phthalocyanine direct dyes; porphyrin direct dyes; natural direct dyes; or mixtures thereof. In some embodiments, the direct dyes are selected from azo; methine; carbonyl; azine; nitro (hetero)aryl; tri(hetero)arylmethane; porphyrin; phthalocyanine; natural direct dyes; and/or mixtures thereof.
[0061] The direct dye(s), according to embodiments herein, may be present
in an amount ranging from 0.0001% to 10% by weight, relative to the total weight of the first composition. In an embodiment, the total amount of direct dye is an amount ranging from 0.005% to 5% by weight, relative to the total weight of the composition. In a preferable embodiment, the composition comprises the direct dye in an amount ranging from 0.005% to 5% by weight, relative to the total weight of the composition.

[0062] The oxidation bases and couplers may be in suitable amounts such
that the total amount of oxidative dye is in the range of 0.0002% to 20% by weight, relative to the total weight of the first composition. In an embodiment, the total amount of oxidative dye in the first composition ranges from 0.0002% to 20% by weight, relative to the total weight of the first composition.
Alkaline agent
[0063] Embodiments of the first composition include at least one alkaline
agent. The alkaline agent, according to embodiments herein, may be selected from mineral, organic or hybrid alkaline agents, or mixtures thereof.
[0064] The mineral alkaline agents, in embodiments herein, may preferably
be selected from aqueous ammonia, alkali metal carbonates, alkali metal bicarbonates, or mixtures thereof. Example of suitable alkaline agents include mineral sodium carbonates, potassium carbonates, sodium bicarbonates, potassium bicarbonates, sodium hydroxide and potassium hydroxide.
[0065] The organic alkaline agents, in embodiments herein, may preferably
be selected from organic amines with a pKb at 25°C of less than 12, preferably less than 10, and more preferably less than 6. It should be noted that it is the pKb corresponding to the function of highest basicity.
[0066] The hybrid alkaline agents, in embodiments herein, may include the
salts of the organic amines with acids such as carbonic acid or hydrochloric acid.
[0067] In an embodiment, the alkaline agent is an organic alkaline agent
preferably selected from alkanolamines, oxyethylenated and/or oxypropylenated ethylenediamines, amino acids, compounds of formula (I), or mixtures thereof.
[0068] The compounds of formula (I) are represented below:


wherein, W is a C1-C6 alkylene residue optionally substituted with a hydroxyl group or a C1-C6 alkyl radical; Rx, Ry, Rz and Rt, may be identical or different, represent a hydrogen atom or a C1-C6 alkyl, C1-C6 hydroxyalkyl or C1-C6 aminoalkyl radical. Examples of such amines include 1,3-diaminopropane, 1,3-diamino-2-propanol, spermine and spermidine.
[0069] In various embodiments, alkanolamine is selected from
monoalkanolamines, dialkanolamines, trialkanolamines, or mixtures thereof, comprising one to three identical or different C1-C4 hydroxyalkyl radicals, particularly.
[0070] Examples of suitable alkanolamines include monoethanolamine,
diethanolamine, triethanolamine, monoisopropanolamine, diisopropanolamine, N-
dimethylaminoethanolamine, 2-amino-2-methyl-1-propanol, triisopropanolamine,
2-amino-2-methyl-1,3-propanediol, 3-amino-1,2-propanediol, 3-dimethylamino-
1,2-propanediol and tris(hydroxymethylamino)methane. In an embodiment, the
alkaline agent is selected from monoethanolamine, diethanolamine,
triethanolamine, or mixtures thereof.
[0071] The amino acids that may be used, in various embodiments herein,
may be of natural or synthetic origin, in their L, D or racemic form, or mixtures thereof, and comprise at least one acid function selected more particularly from carboxylic acid, sulfonic acid, phosphonic acid or phosphoric acid functions. The amino acids may be in neutral or ionic form.
[0072] Examples of suitable amino acids include aspartic acid, glutamic
acid, alanine, arginine, ornithine, citrulline, asparagine, carnitine, cysteine, glutamine, glycine, histidine, lysine, isoleucine, leucine, methionine, N-phenylalanine, proline, serine, taurine, threonine, tryptophan, tyrosine and valine.
[0073] The amino acids, in some embodiments, may further include basic
amino acids comprising an additional amine function optionally included in a ring or in a ureido function.

[0074] Such basic amino acids are preferably selected from those of
formula (II) below:

wherein, R denotes a group selected from (a), (b), (c), (d) and (e):

[0075] Examples of the amino acids corresponding to formula (II) are
histidine, lysine, arginine, ornithine and citrulline.
[0076] Further, the organic amine, in some embodiments, may be selected
from organic amines of heterocyclic type. Examples of suitable heterocyclic type amines include histidine, pyridine, piperidine, imidazole, triazole, tetrazole and benzimidazole. The organic amine may also be selected from amino acid dipeptides. Examples of suitable amino acid dipeptides include carnosine, anserine and baleine.
[0077] The organic amine, in various embodiments herein, may also be
selected from compounds comprising a guanidine function. Examples of suitable
organic amines include arginine, creatine, creatinine, 1,1-dimethylguanidine, 1,1-
diethylguanidine, glycocyamine, metformin, agmatine, N-amidinoalanine, 3-
guanidinopropionic acid, 4-guanidinobutyric acid and 2-
([amino(imino)methyl]amino)ethane-1-sulfonic acid.
[0078] In some embodiments, the hybrid alkaline agent is selected from
guanidine carbonate, monoethanolamine hydrochloride, or mixtures thereof.

[0079] In an embodiment, the first composition comprises an alkaline agent
selected from at least one alkanolamines, preferably monoethanolamine, aqueous ammonia, or mixtures thereof, most preferably monoethanolamine.
[0080] The alkaline agent(s), according to embodiments herein, may be
present in an amount ranging from 0.01% to 30% by weight relative to the weight of the first composition. In an embodiment, the total amount of alkaline agent is an amount ranging from 0.01% to 30% by weight, relative to the weight of the composition. In an embodiment, the first composition comprises the alkaline agent in an amount ranging from 0.1% to 20% by weight, and preferably from 1% to 10% by weight, relative to the weight of the first composition.
Non-ionic surfactants
[0081] Embodiments of the first composition include at least one non-ionic
surfactant. The non-ionic surfactants, according to embodiments herein, may be selected from alkoxylated including monooxyalkylated and/or polyoxyalkylated, nonionic surfactants; monoglycerolated and/or polyglycerolated nonionic surfactants, or combination thereof. Accordingly, in an embodiment, the non-ionic surfactant is selected from alkoxylated C8-C30 alcohols, alkoxylated fatty acid C8-C30 esters of sorbitan, or combinations thereof.
[0082] In an embodiment, the composition comprises ethoxylated non-ionic
surfactants. The alkoxylated C8-C30 fatty alcohol, in various embodiments herein, include fatty alcohols which are linear or branched, saturated or unsaturated alcohols containing from 8 to 30 carbon atoms.
[0083] Examples of suitable fatty alcohols for use in embodiments herein
include cetyl alcohol, stearyl alcohol and a mixture thereof (cetylstearyl alcohol),
lauryl alcohol, octyldodecanol, 2-butyloctanol, 2-hexyldecanol, 2-
undecylpentadecanol, oleyl alcohol, behenyl alcohol, linolenyl alcohol, ricinoleyl alcohol, undecylenyl alcohol, linoleyl alcohol, and/or mixtures thereof.
[0084] In some embodiments, the non-ionic surfactants include alkoxylated
(C8-C24)alkylphenols; saturated or unsaturated, linear, or branched, alkoxylated C8-

C30 alcohols; saturated or unsaturated, linear or branched, alkoxylated C8-C30 amides; esters of saturated or unsaturated, linear or branched, C8-C30 acids and of polyethylene glycols; condensates of ethylene oxide and/or of propylene oxide, or mixtures thereof.
[0085] The esters of fatty acids and/or of fatty alcohols, in various
embodiments herein, include esters of saturated or unsaturated, linear C1-C26 or branched C3-C26 aliphatic monoacids or polyacids and of saturated or unsaturated, linear C1-C26 or branched C3-C26 aliphatic monoalcohols or polyalcohols, the total carbon number of the esters being greater than or equal to 6 and more advantageously greater than or equal to 10.
[0086] In various embodiments herein, the non-ionic surfactant include
alkoxylated C8-C30 alcohols comprising a number of moles of alkylene oxide, for example ethylene oxide and/or propylene oxide. In a preferable embodiment, the non-ionic surfactant is alkoxylated, preferably ethoxylated, C8-C30 alcohol comprising from 1 to 100 mol, preferably from 1 to 50 mol, more preferably 2 to 30 mol, of alkylene oxide, preferably ethylene oxide.
[0087] In an embodiment, the non-ionic surfactant is selected from
ethoxylated C8-C30 alcohols comprising from 1 to 100 mol of ethylene oxide; and polyoxyethylenated esters of linear or branched, saturated or unsaturated C8-C30 acids and/or of sorbitol, comprising from 1 to 100 mol of ethylene oxide.
[0088] Embodiments herein include monoglycerolated or polyglycerolated
nonionic surfactants. In some embodiments, the monoglycerolated or
polyglycerolated nonionic surfactants include monoglycerolated or
polyglycerolated C8-C30 alcohols.
[0089] In particular, the monoglycerolated or polyglycerolated C8-C30
alcohols include those of the formula (III):
RO-[CH2-CH(CH2OH)-O]m-H Formula (III)

wherein, R represents a linear or branched C8-C40 and preferably C8-C30 alkyl or alkenyl radical, and m represents a number ranging from 1 to 30 and preferably from 1 to 10.
[0090] Examples of suitable non-ionic surfactants include lauryl alcohol
having 4 mol of glycerol (INCI name: Polyglyceryl-4 Lauryl Ether), lauryl alcohol having 1.5 mol of glycerol, oleyl alcohol having 4 mol of glycerol (INCI name: Polyglyceryl-4 Oleyl Ether), oleyl alcohol having 2 mol of glycerol (INCI name: Polyglyceryl-2 Oleyl Ether), cetearyl alcohol having 2 mol of glycerol, cetearyl alcohol having 6 mol of glycerol, oleocetyl alcohol having 6 mol of glycerol, and octadecanol having 6 mol of glycerol.
[0091] The alcohol may represent a mixture of alcohols in the same way
that the value of m represents a statistical value, which means that, in a commercial product, several species of polyglycerolated fatty alcohols may coexist in the form of a mixture.
[0092] In an embodiment, the monoglycerolated or polyglycerolated
alcohols, is preferably C8/C10 alcohol containing 1 mol of glycerol, the C10/C12 alcohol containing 1 mol of glycerol and the C12 alcohol containing 1.5 mol of glycerol.
[0093] The non-ionic surfactant(s), according to embodiments herein, may
be present in an amount ranging from 0.1 to 20% by weight, relative to the total weight of the first composition. In an embodiment, the first composition comprises total non-ionic surfactants in an amount ranging from 0.1 to 20% by weight, preferably 0.5% to 15% by weight, relative to the total weight of the first composition. In a preferable embodiment, the amount of non-ionic surfactant ranges from 1% to 10% by weight, relative to the total weight of the composition.
[0094] Preferably, the first composition comprises total non-ionic
surfactants selected from ethoxylated C8-C30 alcohols comprising from 1 to 100 mol of ethylene oxide in an amount ranging from 0.1 to 20% by weight, preferably 0.5% to 15% by weight, relative to the total weight of the first composition. In a

preferable embodiment, the amount of non-ionic surfactant ranges from 1% to 10% by weight, relative to the total weight of the first composition
Fatty acid
[0095] Embodiments of the first composition include at least one fatty acid,
and/or salts thereof. The fatty acids, according to embodiments herein, comprises a saturated or unsaturated, linear or branched alkyl chain having at least 8 carbon atoms, preferably from 10 to 24 carbon atoms and preferably 12 to 20 carbon atoms, more preferably 12 to 18 carbon atoms.
[0096] The fatty acids may be chosen from solid acids, liquid fatty acids
and mixtures thereof.
[0097] For the purposes of the present invention, the term "solid fatty acid"
means a fatty acid having a melting point above 25°C, preferably above or equal to 28°C, more preferentially above or equal to 30°C at atmospheric pressure
(1.013×105 Pa).
[0098] The solid fatty acids that can be used in the present invention are
notably selected from myristic acid, cetylic acid (or palmitic acid), arachidic acid, stearic acid, lauric acid, behenic acid, 12-hydroxystearic acid, or mixtures thereof.
[0099] Particularly preferably, the solid fatty acid(s) are selected from
lauric acid, myristic acid, palmitic acid (also referred to as cetylic acid), stearic acid, or mixtures thereof.
[0100] For the purposes of the present invention, the term "liquid fatty acid"
means a fatty acid having a melting point below or equal to 25°C, preferably below or equal to 20°C at atmospheric pressure (1.013×105 Pa).
[0101] The liquid fatty acid(s), according to the invention, may be selected
from oleic acid, linoleic acid, arachidonic acid, isostearic acid, isostearic acid, isopalmitic acid, or mixtures thereof.
[0102] Preferably, the fatty acid(s) is/are chosen from myristic acid,
palmitic acid, stearic acid, or mixtures thereof.

[0103] The fatty acid(s), according to embodiments herein, may be present
in an amount ranging from 0.05% to 15 % by weight, preferably 0.1& to 10 % by weight, more preferably 0.1% to 5 % by weight and even more preferably 0.1% to 3% by weight, relative to the total weight of the first composition. In an embodiment, the total amount of fatty acid(s), is an amount ranging from 0.05% to 15% by weight, relative to the total weight of the first composition.
[0104] In an embodiment, the fatty acid(s) is in an amount of at least 0.15%
by weight, preferably at least 0.2% by weight, relative to the total weight of the first composition.
[0105] In a preferable embodiment, the first composition comprises at least
0.2% by weight of fatty acid(s), relative to the total weight of the first composition.
Polymers
[0106] Embodiments of the first composition includes at least one polymer
selected from a group consisting of non-ionic associative polymers and amphoteric
polymer. Embodiments herein include non-ionic associative polymers. The
associative polymers, according to embodiments herein, include non-ionic type
polymers. The non-ionic associative polymer, in various embodiments herein, may
be selected from celluloses; or cellulose derivatives. The cellulose derivatives
include modified hydroxyethylcelluloses, modified
hydroxypropylmethylcelluloses, or combinations thereof.
[0107] The modified hydroxyethylcelluloses, in some embodiments herein,
include hydroxyethylcelluloses modified with groups comprising at least one fatty chain, such as linear or branched alkyl, linear or branched arylalkyl or linear or branched alkylaryl groups, or mixtures thereof, and in which the linear or branched alkyl groups are preferably C8-C22, for example, such as products sold under the reference Natrosol Plus Grade 330 CS® (C16 alkyl) by the company Aqualon, Polysurf 67 CS (cetylhydroxyethylcellulose) by the company Ashland, or Bermocoll EHM 100® by the company Berol Nobel.

[0108] The modified hydroxyethylcelluloses, in other embodiments,
include hydroxyethylcelluloses modified with alkylphenyl polyalkylene glycol ether groups, for example such as products sold under the reference Amercell Polymer HM-1500® (polyethylene glycol (15) nonylphenyl ether) by the company Amerchol.
[0109] The modified hydroxypropylmethylcelluloses, according to
embodiments herein, include hydroxypropylmethylcelluloses modified with groups with linear or branched C8-C22 alkyl groups, for example, such as products sold under the reference Sangelose 60L (INCI name: hydroxypropyl methylcellulose stearoxy ether) by the company Daido Chemical.
[0110] The associative polymer(s), according to embodiments herein, may
be present in an amount ranging from 0.005% to 5% by weight. In an embodiment, the total amount of associative polymer is an amount ranging from 0.005% to 5% by weight, relative to the total weight of the composition. In a preferable embodiment, the first composition comprises associative polymer in a total amount ranging from 0.01% to 2% by weight, relative to the total weight of the first composition.
[0111] Embodiments herein may further include amphoteric polymers. The
amphoteric polymers, according to embodiments herein, include copolymers based on acrylic acid and quaternary ammonium salt. In a preferable embodiment, the amphoteric polymer is a copolymer of (meth)acrylic acid, and dialkyldiallylammonium salt such as dimethyldiallyl ammonium chloride (DMDAAC), diethyldiallyl ammonium chloride (DEDAAC), or mixtures thereof.
[0112] In an embodiment, the amphoteric polymer is a copolymer of
(meth)acrylic acid and dimethyldiallylammonium chloride. Examples of suitable amphoteric polymers includes polyquaternium-22 sold under the reference Merquat 280, by Nalco.
[0113] The amphoteric polymers(s), according to embodiments herein, may
be present in an amount ranging from 0.01% and 5% by weight, relative to the

composition. In an embodiment, the total amount of amphoteric polymers is an amount ranging from 0.01% and 5% by weight, relative to the composition. In a preferable embodiment, the first composition comprises 0.05% to 3% by weight, more preferably 0.1% to 2% by weight, relative to the first composition.
Fatty compounds
[0114] Embodiments of the first composition may further include at least
one fatty compound other than fatty acid(s). The fatty compounds, according to embodiments herein, include liquid fatty compounds, solid fatty compounds, and their mixtures. In an embodiment, the first composition comprises a fatty compound which is other than fatty acids.
[0115] The fatty compounds, according to embodiments herein, may be
selected from oil of plant origin, oil having hydrocarbons comprising more than 16 carbon atoms, or combinations thereof
[0116] In other embodiment, the fatty compounds may further include C6-
C16 hydrocarbons, hydrocarbons containing more than 16 carbon atoms, non-silicone oils of animal origin, triglycerides of plant or synthetic origin, fluoro oils, fatty alcohols, esters of fatty acids and/or of fatty alcohols other than triglycerides, non-silicone waxes other than solid fatty alcohols and solid synthetic esters, and silicones, and mixtures thereof.
[0117] The linear or branched hydrocarbons of inorganic or synthetic origin
containing more than 16 carbon atoms, for use in various embodiments herein, may preferably be selected from liquid paraffins or liquid petroleum jelly, petroleum jelly, polydecenes, hydrogenated polyisobutene such as Parleam®, or mixtures thereof.
[0118] The oil of plant origin, for use in various embodiments herein, may
be selected from liquid non-silicone wax(es); triglycerides of plant; or mixtures thereof.
[0119] The liquid non-silicone wax(es) refers to non-silicone wax(es) other
than solid fatty alcohols and solid synthetic esters. The liquid non-silicone wax(es),

according to embodiments herein, may be selected from carnauba wax, candelilla wax, esparto wax, paraffin wax, ozokerite, plant waxes, such as olive tree wax, rice wax, hydrogenated jojoba wax or absolute flower waxes, for example blackcurrant blossom essential wax sold by Bertin (France).
[0120] The triglycerides of plant, for use in various embodiments herein,
are preferably chosen from liquid fatty acid triglycerides comprising from 8 to 30 carbon atoms, for instance, heptanoic or octanoic acid triglycerides, or alternatively, more particularly from those present in plant oils, for instance, sunflower oil, corn oil, soybean oil, marrow oil, grapeseed oil, sesame seed oil, hazelnut oil, apricot oil, macadamia oil, arara oil, castor oil, avocado oil, jojoba oil, shea butter oil or synthetic caprylic/capric acid triglycerides, for example, those sold by Stéarineries Dubois or those sold under the reference Miglyol® 810, 812 and 818 by the company Dynamit Nobel, and mixtures thereof.
[0121] In some embodiments, the fatty compound comprises at least one
liquid fatty compound and at least one fatty alcohol, wherein fatty alcohol is solid at room temperature and at atmospheric pressure, preferably selected from cetyl alcohol (1-hexadecanol), stearyl alcohol (1-octadecanol), or mixture thereof for example cetylstearyl alcohol.
[0122] Preferably, the first composition comprises at least one solid fatty
compound, more preferably selected from fatty alcohols.
[0123] Preferably, the first composition comprises at least one liquid fatty
compound, more preferably selected from oils having hydrocarbons comprising more than 16 carbon atoms, triglycerides of plant, or mixtures thereof.
[0124] Preferably, the first composition comprises at least one fatty
compound, more preferably selected from oils having hydrocarbons comprising more than 16 carbon atoms, triglycerides of plant, fatty alcohols, or mixtures thereof.
[0125] The fatty compound(s) different from fatty acids, according to
embodiments herein, may be present in a total amount of at least 1%, preferably at

least 5%, more preferably at least 10% by weight relative to the total weight of the first composition. In an embodiment, the first composition comprises the fatty compound(s) different from fatty acids in a total amount ranging from 1 to 30%, preferably from 5% to 25 % by weight, preferably 10% to 20% by weight, relative to the weight of the first composition.
Second composition
[0126] Embodiments herein include a second composition comprising at
least one oxidizing agent and at least one nonionic ether of a polyoxyalkylenated fatty alcohol. The second composition, according to embodiments herein, may further, optionally include other additives such as non-ionic surfactants different from nonionic ether of a polyoxyalkylenated fatty alcohols, vitamins, fragrances, adjuvants, dispersants, film-forming agents, ceramides, preserving agents, opacifiers, antioxidants, penetrants, sequestrants, solvents, etc.
Oxidizing agent
[0127] Embodiments of the second composition include at least one
oxidizing agent. The oxidizing agents, according to embodiments herein, may be selected from, for example, hydrogen peroxide, urea peroxide, alkali metal bromates or ferricyanides, peroxygenated salts, such as persulfates, perborates, peracids and/or precursors thereof, and percarbonates of alkali metals or alkaline-earth metals. In a preferable embodiment, the oxidizing agent is hydrogen peroxide.
[0128] The oxidizing agent(s), according to embodiments herein, may be
present in an amount ranging from 0.1% to 40% by weight, relative to the weight of the second composition. In a preferable embodiment, the composition comprises the oxidizing agent in an amount ranging from 0.5% to 20% by weight, more preferably 1% to 15% by weight, relative to the weight of the second composition.
Nonionic ether of a polyoxyalkylenated fatty alcohol
[0129] Embodiments of the second composition include at least one
nonionic ether of a polyoxyalkylenated fatty alcohol. The nonionic ether of a polyoxyalkylenated fatty alcohol, according to the embodiments herein, comprises

at least one nonionic ether of a polyoxyalkylenated fatty alcohol include those of formula (IV):
R-(O-Alk)n-OR’ Formula (IV),
and/or optical isomers and/or geometrical isomers thereof,
wherein, R denotes a linear or branched, saturated or unsaturated C10-C30 hydrocarbon-based radical; R’ denotes a linear or branched, saturated or unsaturated C10-C30 hydrocarbon-based radical, which may be substituted with a hydroxyl radical, the hydroxyl preferably being p to the ether function; n is an integer between 1 and 100 inclusive; and Alk represents a linear or branched, preferably linear, (C1-C6)alkylene group such as ethylene or propylene, preferably ethylene.
[0130] In one particular embodiment, the radical Alk of formula (i)
represents a group -CH2-CH2-.
[0131] More particularly, the nonionic ether of formula (IV) is such that R
and R, independently of each other, denote a linear or branched, preferably linear, saturated or unsaturated, preferably saturated, C12-C20 and preferably C14-C18 hydrocarbon-based radical; R possibly being substituted with at least one hydroxyl radical and n denotes an integer greater than or equal to 20, for example ranging from 20 to 100 and preferably 40 to 80. Preferably, the R and R denote an alkyl radical.
[0132] In preferable embodiments, the nonionic ether of formula (IV) is
such that: R denotes a C16-C18 alkyl radical, which is preferably linear, and R denotes a C14 alkyl radical, which is preferably linear, substituted with an OH group, and n is equal to 60.
[0133] In a preferable embodiment, the nonionic ether of a
polyoxyalkylenated fatty alcohol is of formula (V):


wherein, R is a cetyl or stearyl group with n = 60.
[0134] Such nonionic ethers of a polyoxyalkylenated fatty alcohol are
known, for example, in the CTFA dictionary under the name Ceteareth 60 myristyl glycol or Hydrogenated talloweth 60 myristyl glycol. Examples include commercial available Ceteareth 60 myristyl glycol, such as those sold under the reference Elfacos GT 282 S by Akzo.
[0135] In an embodiment, the nonionic ether(s) of a polyoxyalkylenated
fatty alcohol is(are) in a total amount ranging from 0.001 to 5% by weight, preferably from 0.01 to 1% by weight, more preferably from 0.02 to 0.5% by weight relative to the weight of the second composition.
Non-ionic surfactants
[0136] Embodiments of the second composition herein may also include at
least one non-ionic surfactant different from nonionic ether of a polyoxyalkylenated fatty alcohols. The non-ionic surfactants, according to embodiments herein, include the non-ionic surfactants described previously herein.
[0137] Accordingly, in an embodiment, the second composition comprises
saturated or unsaturated, linear or branched, acyclic or cyclic, substituted or unsubstituted, nonionic surfactant selected from alkoxylated C8-C30 alcohols, alkoxylated fatty acid C8-C30 esters of sorbitan, or combinations thereof, wherein said alkoxylated C8-C30 alcohol is ethoxylated C8-C30 alcohol comprising from 1 to 100 mol of ethylene oxide, preferably 1 to 50 mol of ethylene oxide, more preferably 2 to 30 mol of ethylene oxide, wherein said C8-C30 alcohol is selected from lauryl alcohol, oleyl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol, cetearyl alcohol, or mixtures thereof.

[0138] Preferably, the second composition comprises at least one non-ionic
surfactant different from nonionic ether of a polyoxyalkylenated fatty alcohols, more preferably chosen from alkoxylated C8-C30 alcohols.
[0139] In an embodiment, the second composition comprises total non-
ionic surfactants different from nonionic ether of a polyoxyalkylenated fatty alcohols in an amount ranging from 0.1 to 20% by weight, preferably 0.5% to 15% by weight, relative to the total weight of the second composition. In a preferable embodiment, the amount of non-ionic surfactant ranges from 1% to 10% by weight, relative to the total weight of the second composition.
Fatty compounds
[0140] Embodiments of the second composition may further include at least
one fatty compound other than fatty acid(s). The second composition, according to embodiments herein, may include at least one fatty compound selected from those described previously herein.
[0141] In an embodiment, the second composition comprises fatty
compounds selected from oil of plant origin, oil having hydrocarbons comprising more than 16 carbon atoms, or combinations thereof.
[0142] In some embodiments, the fatty compound comprises at least one
liquid fatty compound and at least one fatty alcohol, wherein fatty alcohol is solid at room temperature and at atmospheric pressure, preferably selected from cetyl alcohol (1-hexadecanol), stearyl alcohol (1-octadecanol), or mixture thereof for example cetylstearyl alcohol.
[0143] Preferably, the second composition comprises at least one solid fatty
compound, more preferably selected from fatty alcohols.
[0144] Preferably, the second composition comprises at least one liquid
fatty compound, more preferably selected from oils having hydrocarbons comprising more than 16 carbon atoms, triglycerides of plant, or mixtures thereof.
[0145] Preferably, the second composition comprises at least one fatty
compound, more preferably selected from oils having hydrocarbons comprising

more than 16 carbon atoms, triglycerides of plant, fatty alcohols, or mixtures thereof.
[0146] In an embodiment, the second composition comprises the fatty
compound(s) different from fatty acids in a total amount ranging from 0.5 to 30%, preferably from 0.5% to 25 % by weight, preferably 0.5% to 20% by weight, relative to the weight of the second composition.
Additives
[0147] Embodiment of the first and second composition may each include
one or more additives. Various additives are generally known conventionally for use in hair dyeing composition. Embodiments of the composition herein may include all such suitable additives. The additives, according to embodiments herein, include conditioning agents, vitamins, fragrances, adjuvants, dispersants, film-forming agents, ceramides, preserving agents, opacifiers, antioxidants, penetrants, sequestrants, solvents, etc. The term fragrances, vitamins, conditioning agents, etc, as used herein, refer to their generally accepted meaning and include compounds or substances that are generally used in personal care and cosmetic compositions.
[0148] Each of the additives, in various embodiments herein, may be
present in an amount ranging from 0.01% and 20% by weight, relative to the weight of the composition.
[0149] Embodiments of each of the first and second compositions herein,
independently, further include one or more solvents. The solvents, according to embodiments herein, include water and/or one or more organic solvents. Examples of organic solvents that may be suitable include linear or branched and, preferably, saturated monoalcohols or diols, comprising 2 to 10 carbon atoms, such as ethanol, isopropanol, hexylene glycol (2-methyl-2,4-pentanediol), neopentyl glycol and 3-methyl-1,5-pentanediol, butylene glycol, dipropylene glycol and propylene glycol; aromatic alcohols such as benzyl alcohol or phenylethyl alcohol; polyols containing more than two hydroxyl functions, such as glycerol; polyol ethers, for instance ethylene glycol monomethyl, monoethyl or monobutyl ether, propylene glycol or

ethers thereof, for instance propylene glycol monomethyl ether; and also diethylene glycol alkyl ethers, especially C1-C4 alkyl ethers, for instance, diethylene glycol monoethyl ether or monobutyl ether, or mixtures thereof.
[0150] In an embodiment, each of said first and second compositions
comprise water. In a preferable embodiment, the each of the first composition and second composition comprises water in an amount in ranging from 30% to 99% by weight, more preferably 40% to 95% by weight, even more preferably 50% to 90% by weight, relative to the total weight of each of the first composition and second composition.
[0151] In another embodiment, each of the first and second compositions
comprise organic solvents in an amount ranging from 0.1% and 40% by weight, preferably 1% and 30% by weight, relative to the total weight of each of the first and second composition.
[0152] The first compositions and the second composition are intended to
be mixed together to obtain the product disclosed herein. The product may then be applied to keratin fibres for dyeing of keratin fibres.
[0153] The product according to embodiments herein may be in the form of
a kit, wherein the first composition and second composition are present in separate sachets or containers. Alternatively, the product may be in the form of a multi-compartment device comprising the first and second composition in separate compartments such that the two compositions may be dispensed simultaneously.
[0154] Accordingly, embodiments herein include a kit and a multi-
compartment device for dyeing of hair. In an embodiment, the kit includes the product comprising the first composition and second composition. In another embodiment, the multi-compartment device includes the product comprising the first composition and second composition.
[0155] It is understood that various forms, sizes, and designs of such multi-
compartment device would be apparent to a person skilled in the art, especially in

light of the present disclosure. Embodiments herein are intended to cover all such kits and devices within its scope.
[0156] Each of first and second composition may be in the form of gel,
cream, etc, preferably having a creamy consistency. Preferably, the weight ratio of the first composition and the second composition to form the product, for application, may range from 0.3:1 to 2:1, preferably 0.5:1 to 1.5:1, and more preferably 1:1.
[0157] Each of the first composition and the second composition, according
to embodiments herein have viscosities suited to achieve creamy consistency. The viscosity of each of the compositions may be in the range of 500 to 1500 mPa.s preferably 600 to 1200 mPa.s. In an embodiment, the viscosity of the first composition is in the range of 500 to 1500 mPa.s, preferably 600 to 1200 mPa.s. In an embodiment, the viscosity of the second composition is in the range of 500 to 1500 mPa.s preferably 600 to 1200 mPa.s.
[0158] The first and second composition are intended to be mixed before
application on keratin fibres. In an embodiment, the viscosity of the mixture of the first and second composition is in the range of 550 to 1500 mPa.s, preferably 550 to 1200 mPa.s.
[0159] The viscosity of the compositions can be measured by means of a
rheometer Pro Rheo R180 Rotational Viscometer, with a spindle M3 and shear rate of 1 s-1, at 25°C and atmospheric pressure, measurement at 30s.
[0160] Each of the first composition and the second composition, according
to embodiments herein, may be formulated in the form of an emulsion. In an embodiment, each of the first and second composition is in the form of an oil-in-water emulsion. In general, oil-in-water emulsions are emulsions in which oil is the dispersed phase that is distributed into an aqueous continuous phase.
Method
[0161] Each of the first and second composition, according to embodiments
herein, may be manufactured using known methods that are generally used in the

cosmetics or dermatological field. Typically, the method for preparation of the first composition comprises blending the oxidative dye, the alkaline agent, the non-ionic surfactant, and the fatty acid, thereof, with a suitable solvent, and optionally the additive, to obtain the first composition. The method for preparation of the second composition comprises blending oxidizing agent and non-ionic ether of polyoxyalkylenated fatty alcohol into a mixture with a suitable solvent, and, optionally, comprising the additive to obtain the second composition.
[0162] Embodiments herein further include a method for dyeing of keratin
fibre. In an embodiment, the method comprises applying the product on said fibre. In another embodiment, the method comprises providing the first composition and second composition of the product; mixing the first composition and second composition; applying the mixture on the fibre and allowing the mixture to stand for a pause time in the range of 5 to 15 minutes. In a preferable embodiment, the first composition and the second composition are provided in a ratio ranging from 0.3:1 to 2:1, preferably 0.5:1 to 1.5:1, and more preferably 1:1.
[0163] Although the subject matter has been described in considerable
detail with reference to certain examples and implementations thereof, it is understood that other implementations are possible and included within the scope of the present invention.
Examples
[0164] The disclosure will now be illustrated with working examples,
which is intended to illustrate the working of disclosure and not intended to take restrictively to imply any limitations on the scope of the present disclosure. Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood to one of ordinary skill in the art to which this disclosure belongs. Although methods and materials similar or equivalent to those described herein can be used in the practice of the disclosed methods and compositions, the exemplary methods, devices, and materials are described herein. It is to be understood that this disclosure is not limited to particular methods, and experimental conditions described, as such methods and conditions may apply.

Example 1: First composition (Composition 1)
[0165] In an example, the first composition (also referred to herein as
Composition 1) was formulated using surfactants viz. 0.72 wt% of laureth-12, 1.44 wt% of laureth-4, 0.72 wt% of oleth-20 and 0.10 wt%, of Polysorbate 21; amphoteric polymer viz. 0.20 wt% of polyquaternium-22; non-ionic associative polymer viz. 0.05 wt% of cetyl hydroxyethylcellulose; fatty compounds viz. 8.16 wt% of cetearyl alcohol, 0.06 wt% of olea europaea (olive) fruit oil and 2.88 wt% of mineral oil, oxidative dyes viz. 0.22 wt% of 2,4-diaminophenoxyethanol HCL, 1.48 wt% of resorcinol, 0.51 wt% of m-aminophenol, 2 wt% of p-phenylenediamine and 0.08 wt% of p-aminophenol and 0.50 wt% of sodium metabisulfite; 4.7 wt% of ethanolamine; 0.2 wt% of EDTA, 0.25 wt% of ascorbic acid, 0.75 wt% of fragrance, water (up to 100 wt%), 0.13 wt% of stearic acid, 0.007 wt% of myristic acid and 0.10 wt% of palmitic acid.
[0166] Table 1 depicts the first composition, according to embodiments
herein.
Table 1

No.
1
2
3
4
5
6
7
8
9 10 11 12 13 14 Ingredient (INCI) Amount (wt%)

Laureth-12 0.72

Stearic acid 0.13

Laureth-4 1.44

Cetearyl alcohol 8.16

Oleth-20 0.72

Polysorbate 21 0.10

Polyquaternium-22 0.20

Cetyl hydroxyethylcellulose 0.05

Olea europaea (olive) fruit oil 0.06

Mineral oil 2.88

2,4-diaminophenoxyethanol HCL 0.22

Resorcinol 1.48

m-Aminophenol 0.51

p-Phenylenediamine 2

15 16 17 18 19 20 21 22 23 p-Aminophenol 0.08

Sodium metabisulfite 0.5

Ethanolamine 4.7

EDTA 0.2

Ascorbic acid 0.25

Fragrance 0.75

Water qs 100

Myristic acid 0.007

Palmitic acid 0.10
Example 2: Second composition (Composition 2)
[0167] In an example, the second composition (also referred to herein as
Composition 2) was formulated using 0.06 wt% of tetrasodium etidronate, 0.03 wt % of sodium salicylate, 6 wt% of hydrogen peroxide, 0.04 wt% of tetrasodium pyrophosphate, 4.4 wt% of cetearyl alcohol, 0.45 wt% of beheneth-10 (polyethylene glycol ether of behenyl alcohol) docosanol, 1.53 wt% of ceteareth-33, 0.8 wt% of mineral oil, 0.03 wt% of ceteareth-60 myristyl glycol, and water up to 100 wt%.
[0168] Table 2 depicts an example of the second composition, according to
embodiments herein.
Table 2

No. Ingredient (INCI) Amount (wt%)
1 Tetrasodium etidronate 0.06
2 Sodium salicylate 0.03
3 Hydrogen peroxide 6
4 Tetrasodium pyrophosphate 0.04
5 Cetearyl alcohol 4.4
6 Beheneth-10 0.45

7 Ceteareth-33 1.53
8 Water qs 100
9 Mineral oil 0.8
10 Ceteareth-60 myristyl glycol 0.03
Example 3: Evaluation of viscosity
[0169] The viscosity of Composition 1 and Composition 2 was evaluated in
comparison with a commercially available composition (also referred to herein as Composition 3, depicted in Table 3), using Viscometer model used – pro Rheo Model - R 180 with spindle M3 at 25°C. Viscosities were measured of individual compositions, i.e. Composition 1, Composition 2, and Composition 3. Further, viscosities of the mixtures of the compositions after mixing the Composition 1 with Composition 2 or Composition 3, in a 1:1 ratio, i.e. mixture of Composition 1 and Composition 2 (also referred to herein as Mixture 1); and mixture of Composition 1 and Composition 3 (also referred to herein as Mixture 2), were also measured.
[0170] Composition 3 include 0.06 wt% of tetrasodium etidronate, 0.03
wt% of sodium salicylate, 6 wt % of hydrogen peroxide, 0.04 wt% of tetrasodium pyrophosphate, 2.28 wt% of cetearyl alcohol, 0.85 wt% of trideceth-2 carboxamide MEA, 0.5 wt% of glycerin, 0.57 wt% of ceteareth-25, and water up to 100 wt%.
Table 3

No. Ingredient (INCI) Amount (wt%)
1 Tetrasodium etidronate 0.06
2 Sodium salicylate 0.03
3 Hydrogen peroxide 6.0
4 Tetrasodium pyrophosphate 0.04
5 Cetearyl alcohol 2.28
6 Trideceth-2 carboxamide MEA 0.85
7 Glycerin 0.5
8 Ceteareth-25 0.57

9 Water qs 100
[0171] Results: The results of the viscosity test are depicted in Table 4. The
viscosity of Composition 2 was observed to be lesser as compared to Composition 3. The difference in viscosities of Composition 3 and 2 was found to facilitate improved cosmetic properties and consumer convenience of the product, according to embodiment herein. It was found that dispensing of the Composition 1 and Composition 3 became uneven due to the difference in viscosities thereby affecting the cosmetic properties and consumer convenience. This difference, and the improved properties, may be attributed to the carefully selected combination of ingredients in the Composition 2 within specific ranges of amounts. For example, Composition 2 include ceteareth-33, mineral oil, ceteareth-60 myristyl glycol which is not present in in the Composition 3.
[0172] Further, on comparison of the viscosities of the combined
compositions, i.e Mixtures 1 and 2, it was observed that the Mixture 1 had creamy consistency as compared to that of Mixture 2, thereby contributing to improved user feel, and improved and uniform spreadability of the mixture/product on keratin fibres. It further led to difference in color delivery as the product was intended to be applied by hands, i.e. without the requirement for brush and bowl. The creamy consistency enabled the composition to be taken by hand for mixing and applying on keratin fibres.
Table 4

Description Viscosity

mPa.s
Composition 1 1020
Composition 2 855
Composition 3 270
Mixture 1 (Composition 1 + Composition 2) 770
Mixture 2 (Composition 1 + Composition 3) 510

[0173] The coloration achieved by Mixture 1 and Mixture 2 (referred to in
Example 3) was evaluated using L*, a*, b* system. The evaluation of the coloration can be done visually or read on a spectrocolorimeter (such as Minolta CM3600d, illuminant D65, angle 10°, SCI values) for the L*, a*, b* colorimetric measurements. In this L*, a*, b* system, L* represents the intensity of the color, a* indicates the green/red color axis and b* indicates the blue/yellow color axis. The lower the value of L, the darker or more intense the color. The higher the value of a*, the redder the shade; the higher the value of b*, the yellower the shade. The variation in coloring between the colored locks of natural white hair which is untreated (control) and after treatment or coloration are defined by AE*, corresponding to the colour uptake on keratin fibres, according to the following equation:

[0174] In this equation, L*, a* and b* represent the values measured after
dyeing the natural hair comprising 90% of white hairs and L0*, a0* and b0* represent the values measured for the untreated natural hair comprising 90% of white hairs.
[0175] The greater the value of AE, the greater the difference in color
between the control locks and the dyed locks and greater is the colour uptake.
[0176] Results: The results of the coloration test are depicted in Table 5. A
clear difference on swatches with the 2 mixtures, Mixture 1 and Mixture 2 was observed. It was found that the Mixture 1, having AE of 43.99, had improved colour uptake on keratin fibres as compared to Mixture 2, having AE of 40.39 The higher color uptake was further achieved by the Mixture 1, i.e. the product according to embodiments herein, in reduced pause time. Moreover, the intensity of the color was better with mixture 1 (L* significantly smaller for mixture 1).
Table 5

No
1
2 Colorant L* a* b* AE

Blank Swatch 59.41 0.49 12.17

Mixture 1 (Composition 1 + Composition 2) 16.88 0.75 0.92 43.99

3 Mixture 2 (Composition 1 + Composition 3) 20.22 1.23 2.41 40,39
ADVANTAGES OF THE PRESENT DISCLOSURE
[0177] The product of the present disclosure achieves improved cosmetic
properties in dyeing of keratin fibres. It facilitates in achieving uniform color delivery, smoothening of keratin fibres, and long-lasting effect while having a shorter pause time. It further provides improved consumer convenience and faster dyeing solutions while achieving efficient color delivery along with good conditioning effect. The product, as disclosed herein, can be received into the hands or palm of a user; and applied by hand on keratin fibres. Further, the product as disclosed herein, have rheological properties that are suited to provide uniform delivery of the product on the fibres.
[0178] Improved consumer feel and convenience is also attributed to the
creamy consistency of the compositions or product as it does not require the use of brushes, bowls, etc, for mixing or application. The embodiments herein provide a consumer convenient method of dyeing keratin fibres which also enables improved and even coverage through application by hand.

I/We Claim:
1. A product for dyeing of keratin fibres, comprising a first composition and a
second composition,
wherein said first composition comprises:
at least one oxidative dye;
at least one alkaline agent;
at least one non-ionic surfactant; and
at least one fatty acid; and wherein said second composition comprises:
at least one oxidizing agent; and
at least one non-ionic ether of polyoxyalkylenated fatty
alcohol.
2. The product as claimed in claim 1, wherein the total amount of oxidative dye in the first composition is ranging from 0.0002% to 20% by weight, relative to the first composition.
3. The product as claimed in claim 1, wherein the oxidative dye comprises at least one oxidation base and at least one oxidation coupler, the total amount of each of which is ranging from 0.0001% to 10% by weight, relative to the first composition.
4. The product as claimed in any of previous claims, wherein
the oxidation base is selected from para-phenylenediamines, bis(phenyl)alkylenediamines, para-aminophenols, ortho-aminophenols, heterocyclic bases, or their addition salts; and
the oxidation coupler is selected from meta-phenylenediamines,
meta-aminophenol, meta-diphenols, naphthalene-based couplers,
heterocyclic couplers, or their addition salts.
5. The product as claimed in any of previous claims, wherein the alkaline agent
is in an amount ranging from 0.01% to 30% by weight, relative to the first
composition.

6. The product as claimed in any of previous claims, wherein the alkaline agent is alkanolamine selected from monoalkanolamines, dialkanolamines, trialkanolamines, or combinations thereof, preferably monoethanolamine.
7. The product as claimed in any of previous claims, wherein the first composition comprises at least one fatty compound other than fatty acids.
8. The product as claimed in claim 7, wherein the fatty compound is in an amount ranging from 1% to 30% by weight, preferably from 5% to 25% by weight, more preferably from 10% to 20% by weight, relative to the first composition.
9. The product as claimed in claims 7 to 8, wherein the fatty compound is selected from at least one oil of plant origin, oil having hydrocarbons comprising more than 16 carbon atoms, fatty alcohols, or combinations thereof.
10. The product as claimed in any of previous claims, wherein the non-ionic surfactant is selected from alkoxylated C8-C30 alcohols, alkoxylated fatty acid C8-C30 esters of sorbitan, or combinations thereof.
11. The product as claimed in claim 10, wherein the alkoxylated C8-C30 alcohol is ethoxylated C8-C30 alcohol comprising from 1 to 100 mol of ethylene oxide, preferably 1 to 50 mol of ethylene oxide, more preferably 2 to 30 mol of ethylene oxide.
12. The product as claimed in claims 10 or 11, wherein the C8-C30 alcohol is selected from lauryl alcohol, oleyl alcohol, cetyl alcohol, stearyl alcohol, cetearyl alcohol, or combinations thereof.
13. The product as claimed in any of previous claims, wherein the non-ionic surfactant in the first composition is in an amount ranging from 0.1% to 20% by weight, preferably 0.5% to 15% by weight, more preferably from 1% to 10% by weight, relative to the first composition.
14. The product as claimed in any of previous claims, wherein the fatty acid comprises C10 to C24 fatty acid, or salts thereof, preferably the C10 to C24 fatty acid is selected from C12-C18 fatty acids, or salts thereof, more

preferably selected from lauric acid, myristic acid, stearic acid, oleic acid, palmitic acid, or combinations thereof.
15. The product as claimed in any of previous claims, wherein the fatty acid is in an amount ranging from 0.05% to 15 % by weight, preferably 0.1% to 10 % by weight, more preferably 0.2% to 5 % by weight, even more preferably 0.2 to 3 % by weight, relative to the first composition.
16. The product as claimed in any of previous claims, wherein the first composition comprises at least one non-ionic associative polymer.
17. The product as claimed in claim 16, wherein the non-ionic associative polymer is selected from non-ionic cellulose derivatives; and the total amount of non-ionic associative polymer ranging from 0.005% to 5% by weight, preferably 0.01% to 2% by weight, relative to the first composition.
18. The product as claimed in any of previous claims, wherein the first composition comprises at least one amphoteric polymer.
19. The product as claimed in claim 18, wherein the amphoteric polymer is a copolymer of (alkyl)acrylic acid and dialkyl diallyl ammonium salt, preferably a copolymer of (meth)acrylic acid and dimethyl diallyl ammonium chloride; and the total amount of amphoteric polymer ranging from 0.01% to 5% by weight, preferably 0.05% to 3% by weight, more preferably from 0.1% to 2% by weight, relative to the first composition.
20. The product as claimed in any of previous claims, wherein the oxidizing
agent is in an amount ranging from 0.1% to 40% by weight, preferably 0.5%
to 20% by weight, more preferably 1% to 15% by weight, relative to the
second composition.
21. The product as claimed in any of previous claims, wherein the non-ionic
ether of polyoxyalkylenated fatty alcohol is in an amount ranging from
0.001% to 5% by weight, preferably from 0.01% to 1% by weight, more
preferably from 0.02% to 0.5% by weight, relative to the weight of the
second composition.

22. The product as claimed in any of previous claims, wherein the non-ionic
ether of polyoxyalkylenated fatty alcohol is selected from those of formula
(IV):
R-(O-Alk)n-OR’ Formula (IV),
and/or optical isomers and/or geometrical isomers thereof,
wherein, R denotes a linear or branched, saturated or unsaturated C10-C30 hydrocarbon-based radical; R’ denotes a linear or branched, saturated or unsaturated C10-C30 hydrocarbon-based radical, which may be substituted with a hydroxyl radical, the hydroxyl preferably being p to the ether function; n is an integer between 1 and 100 inclusive; and Alk represents a linear or branched, preferably linear, (C1-C6)alkylene group such as ethylene or propylene, preferably ethylene.
23. The product as claimed in any of previous claims, wherein the first composition and second composition, independently comprises at least one solvent, preferably water, in an amount ranging from 30% to 99% by weight, more preferably 40% to 95% by weight, even more preferably 50% to 90% by weight, relative to the total weight of each of said first composition and second composition.
24. The product as claimed in any of previous claims, wherein the second composition comprises at least one non-ionic surfactant different from nonionic ether of a polyoxyalkylenated fatty alcohols, preferably in an amount ranging from 0.1% to 20% by weight, preferably 0.5% to 15% by weight, relative to the second composition.
25. The product as claimed in claim 24, wherein the non-ionic surfactant is selected from alkoxylated C8-C30 alcohols, alkoxylated fatty acid C8-C30 esters of sorbitan, or combinations thereof; said alkoxylated C8-C30 alcohol is ethoxylated C8-C30 alcohol comprising from 1 to 100 mol of ethylene oxide, preferably 1 to 50 mol of ethylene oxide, more preferably 2 to 30 mol of ethylene oxide; and

said C8-C30 alcohol is selected from lauryl alcohol, oleyl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol, cetearyl alcohol, or combinations thereof.
26. The product as claimed in any of previous claims, wherein viscosity of the first composition and second composition, independently, is ranging from 500 to 1500 mPa.s, preferably 600 to 1200 mPa.s.
27. A method for dyeing of keratin fibre, comprising applying the product claimed in claims 1 to 26, on said fibre.
28. A method for dyeing of keratin fibre, comprising
providing the first composition and the second composition of the product as claimed in claims 1 to 26;
mixing the first composition and the second composition to obtain a mixture;
applying the mixture on said fibre; and allowing the mixture to stand for a pause time in the range of 5 to 15 minutes. .
29. The method as claimed in claim 28, wherein the first composition and second composition are provided in a weight ratio range of 0.3:1 to 2:1, preferably 0.5:1 to 1.5:1, and more preferably 1:1.
30. The method as claimed in claim 28, wherein viscosity of said mixture is ranging from 550 to 1500 mPa.s, preferably 600 to 1200 mPa.s.