Abstract: ABSTRACT AN OXIDIZING COMPOSITION FOR DYEING AND/OR LIGHTENING OF KERATIN FIBRES,METHODS, AND USE THEREOF 5 The present disclosure provides an oxidizing composition comprising at least one oxidizing agent, at least one fatty alcohol, at least one oxyalkylenated fatty alcohol, at least one oxyalkylenated fatty amide, and water, wherein the total amount of the oxyalkylenated fatty amide(s) is greater than 1.5% by weight, relative to the total weight of the composition, and the composition has a pH of less or equal to 5. The 10 composition achieves improved cosmetic properties and colour delivery. The present disclosure also provides a method for the application of the composition and uses thereof.
FORM 2
THE PATENTS ACT, 1970 (39 of 1970) & THE PATENTS RULES, 2003
COMPLETE SPECIFICATION (See section 10, rule 13)
1. Title of the invention: AN OXIDIZING COMPOSITION FOR DYEING AND/OR
LIGHTENING OF KERATIN FIBRES, METHODS, AND USE THEREOF
2. Applicant(s)
NAME NATIONALITY ADDRESS
L'OREAL French 14, rue Royale 75008 PARIS, France
3. Preamble to the description
COMPLETE SPECIFICATION
The following specification particularly describes the invention and the manner in which it
is to be performed.
FIELDOFINVENTION
[0001] The present disclosure relates, in general, to cosmetic products, and
more particularly, to compositions for the dyeing and/or lightening of keratin fibres. The present disclosure further relates to methods and kits for dyeing and/or lightening of keratin fibres.
BACKGROUNDOFINVENTION
[0002] Oxidizing compositions are used in cosmetics for the purposes of
dyeing, bleaching, and permanently reshaping keratin fibres, such as the hair.
[0003] When used for the purposes of dyeing keratin fibres, oxidizing
compositions are commonly used for oxidative dyeing and direct dyeing. In oxidative dyeing, oxidizing compositions are mixed with oxidation dyes (bases and couplers), which are intrinsically colourless, to generate coloured and colouring compounds via a process of oxidative condensation. In direct dyeing methods, oxidizing compositions are used with direct dyes, which are coloured and colouring substances, to obtain colouring with a lightening effect on the hair.
[0004] Oxidizing compositions may also be used for bleaching keratin
fibres, such as hair. In bleaching reactions, oxidizing compositions can be used alone and applied to keratin fibres to bleach the hair. They may also be used in combination with compositions comprising peroxygenated salts such as persulfates when the oxidizing composition is based on hydrogen peroxide.
[0005] Permanently reshaping keratin fibres, involves the opening of the -
S-S disulfide bonds of keratin (cystine) using a composition containing a suitable reducing agent (reduction step). After rinsing the treated fibres, the disulfide bonds are reconstituted, which requires that the fibres are placed under tension beforehand (curlers and others), and then applying an oxidizing composition (oxidation step, also known as the fixing step) to finally give the hair the desired shape. This technique thus makes it possible, without preference, either to make the hair wavy or to relax or uncurl it. The new shape given to the hair by a chemical treatment
such as that above is eminently long-lasting and especially withstands the action of washing with water or shampoos, as opposed to the simple standard techniques of temporary reshaping, such as hair setting.
[0006] Oxidizing compositions conventionally used in the dyeing
(oxidation dyeing or direct dyeing), bleaching or permanent reshaping of keratin fibres suffer from poor cosmetic performance qualities. In particular, in respect of dyeing, currently used oxidizing compositions lack good dyeing and lightening effects, demonstrate poor colour uptake, and chromaticity. Thus, there is a requirement for oxidizing compositions which lead to good dyeing or lightening properties, especially in terms of power, chromaticity and selectivity with good working qualities and providing good cosmetic properties.
SUMMARYOFTHEINVENTION
[0007] In an aspect of the present disclosure, there is provided an oxidizing
composition comprising at least one oxidizing agent, at least one fatty alcohol, at least one oxyalkylenated fatty alcohol, at least one oxyalkylenated fatty amide, and water, wherein the total amount of the oxyalkylenated fatty amide(s) is greater than 1.5% by weight, relative to the total weight of the composition, and the composition has a pH of less or equal to 5.
[0008] In an aspect of the present disclosure, there is provided a kit for
dyeing and/or lightening keratin fibres comprising (a) an oxidizing composition comprising at least one oxidizing agent, at least one fatty alcohol, at least one oxyalkylenated fatty alcohol, at least one oxyalkylenated fatty amide, and water, wherein the total amount of the oxyalkylenated fatty amide(s) is greater than 1.5% by weight, relative to the total weight of the composition, and the composition has a pH of less or equal to 5, and (b) a dyeing and/or lightening composition comprising one or more direct dyes and/or one or more oxidation dyes and/or one or more alkaline agents.
[0009] In another aspect of the present disclosure, there is provided a
method for treating keratin fibers, comprising application to the keratin fibers an oxidizing composition comprising at least one oxidizing agent, at least one fatty
alcohol, at least one oxyalkylenated fatty alcohol, at least one oxyalkylenated fatty amide, and water, wherein the total amount of the oxyalkylenated fatty amide(s) is greater than 1.5% by weight, relative to the total weight of the composition, and the composition has a pH of less or equal to 5.
[0010] In another aspect of the present disclosure, there is provided a
method for dyeing and/or lightening keratin fibers comprising mixing an oxidizing
composition comprising at least one oxidizing agent, at least one fatty alcohol, at
least one oxyalkylenated fatty alcohol, at least one oxyalkylenated fatty amide, and
water, wherein the total amount of the oxyalkylenated fatty amide(s) is greater than
1.5% by weight, relative to the total weight of the composition, and the composition
has a pH of less or equal to 5, with a dyeing and/or lightening composition
comprising one or more direct dyes and/or one or more oxidation dyes and/or one
or more alkaline agents to obtain a mixture; and applying the mixture on said fibres.
[0011] In a further aspect of the present disclosure, there is provided a use
of an oxidizing composition comprising at least one oxidizing agent, at least one fatty alcohol, at least one oxyalkylenated fatty alcohol, at least one oxyalkylenated fatty amide, and water, wherein the total amount of the oxyalkylenated fatty amide(s) is greater than 1.5% by weight, relative to the total weight of the composition, and the composition has a pH of less or equal to 5, for treating keratin fibers, preferably for dyeing and/or lightening keratin fibers.
[0012] These and other features, aspects, and advantages of the present
subject matter will be better understood with reference to the following description and appended claims. This summary is provided to introduce a selection of concepts in a simplified form. This summary is not intended to identify key features or essential features of the claimed subject matter, nor is it intended to be used to limit the scope of the claimed subject matter.
DESCRIPTIONOFTHEINVENTION
[0013] Those skilled in the art will be aware that the present disclosure is
subject to variations and modifications other than those specifically described. It is to be understood that the present disclosure includes all such variations and
modifications. The disclosure also includes all such steps, features, compositions,
and compounds referred to or indicated in this specification, individually or
collectively, and any and all combinations of any or more of such steps or features.
Definitions
[0014] For convenience, before further description of the present
disclosure, certain terms employed in the specification, and examples are delineated
here. These definitions should be read in the light of the remainder of the disclosure
and understood as by a person of skill in the art. The terms used herein have the
meanings recognized and known to those of skill in the art, however, for
convenience and completeness, particular terms and their meanings are set forth
below.
[0015] The articles “a”, “an” and “the” are used to refer to one or to more
than one (i.e., to at least one) of the grammatical object of the article.
[0016] The terms “comprise” and “comprising” are used in the inclusive,
open sense, meaning that additional elements may be included. It is not intended to
be construed as “consists of only”.
[0017] The term "at least one" is used to mean one or more and thus includes
individual components as well as mixtures/combinations.
[0018] Throughout this specification, unless the context requires otherwise
the word “comprise”, and variations such as “comprises” and “comprising”, will be
understood to imply the inclusion of a stated element or step or group of element or
steps but not the exclusion of any other element or step or group of element or steps.
[0019] The term “including” is used to mean “including but not limited to”.
“Including” and “including but not limited to” are used interchangeably.
[0020] The term “oxidizing composition” and “composition” are used
interchangeably.
[0021] The term “INCI” is an abbreviation of International Nomenclature
of Cosmetic Ingredients, which is a system of names provided by the International
Nomenclature Committee of the Personal Care Products Council to describe
personal care ingredients.
[0022] All percentages, parts and ratios are based upon the total weight of
the compositions of the present disclosure unless otherwise indicated. Ratios, concentrations, amounts, and other numerical data may be presented herein in a range format. It is to be understood that such range format is used merely for convenience and brevity and should be interpreted flexibly to include not only the numerical values explicitly recited as the limits of the range, but also to include all the individual numerical values or sub-ranges encompassed within that range as if each numerical value and sub-range is explicitly recited. For example, a percentage range of about 0.5 % to 40 % should be interpreted to include not only the explicitly recited limits of about 2% to about 20%, but also to include sub-ranges, such as 16% to 18%, 17% to 19%, and so forth, as well as individual amounts, including fractional amounts, within the specified ranges, such as 5.8%, and 15.25%, for example.
[0023] Unless defined otherwise, all technical and scientific terms used
herein have the same meaning as commonly understood by one of ordinary skill in the art to which this disclosure belongs. Although any methods and materials similar or equivalent to those described herein can be used in the practice or testing of the disclosure, the preferred methods and materials are now described. All publications mentioned herein are incorporated herein by reference.
[0024] The present disclosure is not to be limited in scope by the specific
embodiments described herein, which are intended for the purposes of exemplification only. Functionally equivalent products, compositions, and methods are clearly within the scope of the disclosure, as described herein.
[0025] Embodiments herein provide an oxidizing composition comprising
at least one oxidizing agent, at least one fatty alcohol, at least one oxyalkylenated fatty alcohol, at least one oxyalkylenated fatty amide, and water, wherein the total amount of the oxyalkylenated fatty amide(s) is greater than 1.5% by weight, relative to the total weight of the composition, and the composition has a pH of less or equal to 5. The oxidizing composition demonstrates superior performance qualities, particularly in terms of dyeing and lightening effects, colour uptake and intensity, and chromaticity, and also provides a good shine, smoothness, and nourishment to
hair. In addition, the composition is also superior in terms of its working qualities including ease of mixing, ease of application on keratin fibres, such as hair, non-drippy texture and consistency that is preferred by customers, and ease of rinsing. Embodiments herein also provide a method for dyeing and/or lightening keratin fibers comprising mixing the oxidizing composition of the present invention, with a dyeing and/or lightening composition comprising one or more direct dyes and/or one or more oxidation dyes and/or one or more alkaline agents to obtain a mixture; and applying the mixture on said fibres. In addition, embodiments herein also include a kit comprising the composition according to the present invention and a dyeing and/or lightening composition comprising one or more direct dyes and/or one or more oxidation dyes and/or one or more alkaline agents; and the use of the composition, according to the present invention, for dyeing and/or lightening keratin fibres.
Composition
[0026] Embodiments herein provide an oxidizing composition
(“composition”), according to the present invention, comprising at least one oxidizing agent, at least one fatty alcohol, at least one oxyalkylenated fatty alcohol, at least one oxyalkylenated fatty amide, and water, wherein the total amount of the oxyalkylenated fatty amide(s) is greater than 1.5% by weight, relative to the total weight of the composition, and the composition has a pH of less or equal to 5. The composition, according to the present invention, is used for dyeing and/or lightening keratin fibres, such as hair.
[0027] The oxidizing composition (“composition”), according to
embodiments herein, demonstrates good performance qualities and working qualities. Superior colour uptake and chromaticity, particularly in terms of the intensity of the colour obtained, selective dyeing and uniform colour application are among the performance benefits of the composition. Moreover, the composition has good working qualities including a non-drippy texture, ease of mixing and application, and ease of rinsing without an oily feel to hair.
[0028] Overall, the combination of at least one oxidizing agent, at least one
fatty alcohol, at least one oxyalkylenated fatty alcohol, at least one oxyalkylenated fatty amide, and water, wherein the total amount of the oxyalkylenated fatty amide(s) is greater than 1.5% by weight, relative to the total weight of the composition, and the composition has a pH of less or equal to 5, in the composition according to the present invention, function synergistically to contribute to the superior performance for dyeing and/or lightening keratin fibres, such as hair.
Oxidizing agent
[0029] The oxidizing composition, according to the present invention,
comprises one or more oxidizing agents.
[0030] For the purposes of the present invention, the term "oxidizing agent"
means an oxidizing agent other than atmospheric oxygen. The term “oxidizing agent” also refers to “chemical oxidizing agent”.
[0031] The oxidizing agents, in some embodiments, are selected from
hydrogen peroxide, urea peroxide, alkali metal bromates or ferricyanides, peroxygenated salts, for instance, persulfates, perborates, peracids, and precursors thereof, and percarbonates of alkali metals or of alkaline-earth metals such as sodium, potassium, or magnesium.
[0032] One or more redox enzymes such as laccases, peroxidases, and 2-
electron oxidoreductases (such as uricase), optionally in the presence of the respective donor or cofactor thereof, may also be used as oxidizing agents.
[0033] Preferably, the oxidizing agent(s), according to embodiments herein,
is(are) selected from hydrogen peroxide, urea peroxide, alkali metal bromates or ferricyanides, peroxygenated salts, alkali metal percarbonates, alkaline-earth metal percarbonates, or combinations thereof.
[0034] More preferably, the oxidizing agent(s), according to embodiments
herein, is hydrogen peroxide.
[0035] The oxidizing agent(s), according to embodiments herein, is(are) in
a total amount ranging from 0.5% to 40% by weight, preferably from 1% to 30% by weight, more preferably from 2% to 20% by weight, and better from 4% to 15% by weight relative to the total weight of the composition.
[0036] Preferably, the oxidizing agent(s), according to embodiments herein,
is(are) selected from hydrogen peroxide, urea peroxide, alkali metal bromates or ferricyanides, peroxygenated salts, alkali metal percarbonates, alkaline-earth metal percarbonates, or combinations thereof, and is(are) in a total amount ranging from 0.5% to 40% by weight, preferably from 1% to 30% by weight, more preferably from 2% to 20% by weight, better from 4% to 15% by weight, relative to the total weight of the composition.
[0037] Preferably, the oxidizing agent(s), according to embodiments herein,
is hydrogen peroxide, and is in a total amount ranging from 0.5% to 40% by weight, preferably from 1% to 30% by weight, more preferably from 2% to 20% by weight, and better from 4% to 15% by weight, relative to the total weight of the composition.
Fatty alcohols
[0038] The oxidizing composition, according to the present invention,
comprises one or more fatty alcohols.
[0039] The term “fatty alcohol” includes a long-chain aliphatic alcohol
comprising from 6 to 40 carbon atoms and comprising at least one hydroxyl group
(OH).
[0040] In an embodiment, the fatty alcohols may be saturated or
unsaturated, and linear or branched, and include 6 to 40 carbon atoms, preferably 8
to 30 carbon atoms.
[0041] Preferably, the fatty alcohols, according to embodiments herein, are
selected from C14 to C22 fatty alcohols.
[0042] The fatty alcohols, according to the present invention, are non-
oxyalkylenated and non-glycerolated.
[0043] The fatty alcohols, according to the present invention, are neither
poly(oxyalkylenated), nor poly(glycerolated) and are different from oxyalkylenated fatty alcohols.
[0044] Preferably, the fatty alcohols, in some embodiments, are selected
from compounds having the structure R-OH with R denoting a linear or branched, saturated or unsaturated alkyl group optionally substituted with one or more hydroxyl groups, comprising from 8 to 30 carbon atoms.
[0045] More preferably, the fatty alcohols, in some embodiments, are
selected from fatty alcohols comprising 6 to 40, more preferably from 8 to 30, better from 12 to 24, or even better from 14 to 22 carbon atoms.
[0046] The fatty alcohols may be selected from solid fatty alcohols, liquid
fatty alcohols, or combinations thereof.
[0047] For the purposes of the present invention, the term "solid fatty
alcohol" includes a fatty alcohol with a melting point of greater than 25°C, preferably greater than or equal to 28°C, more preferentially greater than or equal to 30°C at atmospheric pressure (1.013×105 Pa).
[0048] In some embodiments, the solid fatty alcohols may be selected from
compounds having the structure R-OH with R denoting a saturated linear alkyl group, optionally substituted with one or more hydroxyl groups, comprising from 6 to 40 carbon atoms, preferably from 8 to 30, more preferably from 12 to 24 atoms, and better still from 14 to 22 carbon atoms.
[0049] In various embodiments, the solid fatty alcohols that may be used,
alone or as a mixture, are selected from lauryl alcohol (or 1-dodecanol); myristyl alcohol (or 1-tetradecanol); cetyl alcohol (or 1-hexadecanol); stearyl alcohol (or 1-octadecanol); arachidyl alcohol (or 1-eicosanol); behenyl alcohol (or 1-docosanol); lignoceryl alcohol (or 1-tetracosanol); ceryl alcohol (or 1-hexacosanol); montanyl alcohol (or 1-octacosanol); and myricyl alcohol (or 1-triacontanol).
[0050] The solid fatty alcohols, in a further embodiment, are selected from
cetyl alcohol, stearyl alcohol, behenyl alcohol, myristyl alcohol, arachidyl alcohol,
or combinations thereof, such as, cetylstearyl alcohol or cetearyl alcohol. More preferably, the solid fatty alcohols, may be selected from cetyl alcohol, stearyl alcohol, and/or mixtures such as cetearyl alcohol.
[0051] The liquid fatty alcohols that may be used, according to the present
invention, are preferably selected from compounds having the structure R-OH with R denoting a saturated or unsaturated, linear or branched, preferably unsaturated and/or branched, alkyl group optionally substituted with one or more hydroxyl groups, comprising from 6 to 40, preferably from 8 to 30, more preferably from 12 to 24, and better still from 14 to 22 carbon atoms.
[0052] For the purposes of the present invention, the term "liquid fatty
alcohol" includes a fatty alcohol with a melting point of less than or equal to 25°C,
preferably less than or equal to 20°C at atmospheric pressure (1.013×105 Pa).
[0053] The liquid fatty alcohols, may be used alone or as a combination,
and are selected from oleyl alcohol, linoleyl alcohol, linolenyl alcohol, isocetyl alcohol, isostearyl alcohol, 2-octyl-1-dodecanol, 2-butyloctanol, 2-hexyl-1-decanol, 2-decyl-1-tetradecanol, 2-tetradecyl-1-cetanol, or combinations thereof, and more preferably is oleyl alcohol.
[0054] Preferably, the fatty alcohol(s), according to embodiments herein,
is(are) selected from at least one solid fatty alcohol, at least one liquid fatty alcohol,
or combinations thereof, preferably from at least one solid fatty alcohol comprising
6 to 40 carbon atoms, and more preferably comprising 8 to 30 carbon atoms.
[0055] More preferably, the fatty alcohol(s), according to embodiments
herein, is(are) selected from cetyl alcohol, stearyl alcohol, behenyl alcohol, myristyl
alcohol, arachidyl alcohol, lignoceryl alcohol, ceryl alcohol, montanyl alcohol,
myricyl alcohol, or combinations thereof, and preferably is cetearyl alcohol.
[0056] The fatty alcohol(s), according to embodiments herein, is(are) in a
total amount ranging from 0.5% to 40% by weight, preferably from 1% to 30% by weight, more preferably from 5% to 20% by weight, and better still from 7% to 15% by weight, relative to the total weight of the composition.
[0057] Preferably, the fatty alcohol(s), according to embodiments herein,
is(are) selected from at least one solid fatty alcohol, at least one liquid fatty alcohol,
or combinations thereof, preferably from at least one solid fatty alcohol comprising 6 to 40 carbon atoms, and more preferably comprising 8 to 30 carbon atoms, and is(are) in a total amount ranging from 0.5% to 40% by weight, preferably from 1% to 30% by weight, more preferably from 5% to 20% by weight, and better still from 7% to 15% by weight, relative to the total weight of the composition.
[0058] Preferably, the fatty alcohol(s), according to embodiments herein,
is(are) selected from cetyl alcohol, stearyl alcohol, behenyl alcohol, myristyl alcohol, arachidyl alcohol, lignoceryl alcohol, ceryl alcohol, montanyl alcohol, myricyl alcohol, or combinations thereof, more preferably is cetearyl alcohol, and is(are) in a total amount ranging from 0.5% to 40% by weight, preferably from 1% to 30% by weight, more preferably from 5% to 20% by weight, and better still from 7% to 15% by weight, relative to the total weight of the composition.
Oxyalkylenated fatty alcohol
[0059] The oxidizing composition, according to the present invention,
comprises one or more oxyalkylenated fatty alcohols.
[0060] The oxyalkylenated fatty alcohols, according to the present
invention, may comprise from 1 to 50 oxyalkylenated groups. The oxyalkylenated groups may be chosen from oxyethylenated (OE) or oxypropylenated (OP) groups, preferably OE groups.
[0061] In some embodiments, the oxyalkylenated fatty alcohols may be
saturated or unsaturated, and linear or branched, and comprise from 8 to 30 carbon atoms. Preferably, in some embodiments, the oxyalkylenated fatty alcohols have the structure Ra-(Ra’O)pH with Ra denoting a linear alkyl group which is optionally substituted with one or more hydroxyl groups, comprising from 8 to 30, better still from 10 to 28, or even from 12 to 24 atoms, even better still from 14 to 22 carbon atoms, Ra’ represents a divalent alkylene radical comprising from 1 to 6 carbon atoms, preferably from 1 to 4 carbon atoms, preferentially 2 to 3 carbon atoms, more preferably 2 carbon atoms, p represents a number ranging from 1 to 50,
preferably from 2 to 40, preferentially from 10 to 35, better still from 15 to 30. More preferably, Ra’ is a -CH2CH2- radical.
[0062] The oxyalkylenated, preferably oxyethylenated, fatty alcohols
according to the invention may be selected from oxyethylenated cetyl alcohol,
oxyethylenated oleyl alcohol, oxyethylenated oleocetyl alcohol, oxyethylenated
behenyl alcohol, oxyethylenated cetearyl alcohol, oxyethylenated stearyl alcohol,
and combinations thereof, and more preferably from oxyethylenated stearyl
alcohol, oxyethylenated cetyl alcohol and oxyethylenated cetearyl alcohol.
[0063] As compounds of oxyalkylenated fatty alcohol type, mention may
especially be made of the following products on the market:
- Dehydol LS 2 DEO N (BASF) [lauryl alcohol 2 OE];
- GENAPOL LA 120 L O MB (CLARIANT) [lauryl alcohol 12 OE];
- Empilan KA 2.5/90FL (INNOSPEC ACTIVE CHEMICALS) [decyl alcohol 3 OE];
- Empilan KA 5/90FL (INNOSPEC ACTIVE CHEMICALS) [decyl alcohol 5 OE];
- Brij C20(CRODA) [cetyl alcohol 20 OE];
- Emulgin O5 (BASF) [oleocetyl alcohol 5 OE];
- Emulgin O30 (BASF) [oleocetyl alcohol 30 OE];
- Brij S2 (CRODA) [stearyl alcohol 2 OE];
- Brij S10 (CRODA) [stearyl alcohol 10 OE];
- Brij S20 (CRODA) [stearyl alcohol 20 OE];
- Brij S100 (CRODA) [stearyl alcohol 100 OE];
- Eumulgin B1 (BASF) [cetylstearyl alcohol 12 OE];
- Eumulgin L (BASF) [cetyl alcohol 9 OE and 2OP];
- Eumulgin B 25 (BASF) [cetylstearyl alcohol 25 OE];
- Tegosoft APM (EVONIK Goldschmidt) [myristyl alcohol 3 OP].
[0064] Preferably, according to embodiments herein, the oxyalkylenated
fatty alcohol(s) comprise(s) at least 10 oxyalkylenated groups, preferably from 10
to 50 groups, more preferably from 10 to 35 groups, and better still from 15 to 30
groups.
[0065] More preferably, the oxyalkylenated fatty alcohol(s), according to
embodiments herein, is(are) selected from oxyethylenated fatty alcohols, preferably
having a number of oxyethylene groups ranging from 10 to 50 groups, more
preferably from 10 to 35 groups, and better still from 15 to 30 groups.
[0066] Preferably, the oxyalkylenated fatty alcohol(s), according to
embodiments herein, is(are) selected from oxyethylenated fatty alcohols, preferably
from oxyethylenated (OE) stearyl alcohol, oxyethylenated cetyl alcohol,
oxyethylenated cetylstearyl alcohol, or combinations thereof, more preferably from
stearyl alcohol 20 OE, cetylstearyl alcohol 25 OE, or combinations thereof.
[0067] In some embodiments, the composition comprises at least two
different oxyalkylenated fatty alcohols, preferably at least two different oxyethylenated fatty alcohols. These oxyalkylenated, preferably oxyethylenated, fatty alcohols may be selected from the list above, preferably stearyl alcohol 20 OE and cetylstearyl alcohol 25 OE.
[0068] The oxyalkylenated fatty alcohol(s), according to embodiments
herein, is(are) in a total amount ranging from 0.1% to 5% by weight, preferably
from 0.2% to 4% by weight, more preferably from 0.3% to 3% by weight, and better
still from 0.5% to 2% by weight, relative to the total weight of the composition.
[0069] Preferably, the oxyalkylenated fatty alcohol(s), according to
embodiments herein, is(are) selected from oxyethylenated fatty alcohols, preferably having a number of oxyethylene groups ranging from 10 to 50 groups, more preferably from 10 to 35 groups, and better still from 15 to 30 groups, and is(are) in a total amount ranging from 0.1% to 5% by weight, preferably from 0.2% to 4% by weight, more preferably from 0.3% to 3% by weight, and better still from 0.5% to 2% by weight, relative to the total weight of the composition.
[0070] Preferably, the oxyalkylenated fatty alcohol(s), according to
embodiments herein, is(are) selected from oxyethylenated fatty alcohols, preferably from oxyethylenated (OE) stearyl alcohol, oxyethylenated cetyl alcohol, oxyethylenated cetylstearyl alcohol, or combinations thereof, more preferably from stearyl alcohol 20 OE, and cetylstearyl alcohol 25 OE, and is(are) in a total amount ranging from 0.1% to 5% by weight, preferably from 0.2% to 4% by weight, more
preferably from 0.3% to 3% by weight, and better still from 0.5% to 2% by weight, relative to the total weight of the composition.
[0071] Preferably, the weight ratio between fatty alcohol(s) and
oxyalkylenated fatty alcohol(s) is greater or equal to 2, preferably to 3, more
preferably to 4. More preferably, the weight ratio between fatty alcohol(s) and
oxyalkylenated fatty alcohol(s) ranges from 4 to 20, preferably from 6 to 15.
[0072] Preferably, the weight ratio between fatty alcohol(s) and
oxyethylenated fatty alcohol(s) is greater or equal to 2, preferably to 3, more preferably to 4. More preferably, the weight ratio between fatty alcohol(s) and oxyethylenated fatty alcohol(s) ranges from 4 to 20, preferably from 6 to 15.
Oxyalkylenated fatty amide
[0073] The oxidizing composition, according to the present invention,
comprises one or more oxyalkylenated fatty amides in a content greater than 1.5% by weight, relative to the total weight of the composition.
[0074] The oxyalkylenated fatty amide(s) is(are) selected from a compound
of formula (I) below:
wherein,
R1 is selected from linear or branched C1 to C30 alkyl or C2 to C30 alkenyl groups optionally substituted with oxygen atoms, nitrogen atoms, hydroxyl groups, ether groups, or oxyalkylene groups;
R2 is selected from hydrogen, (R’-O)mH radical, linear, or branched, saturated or unsaturated, C1 to C22 alkyl groups optionally substituted with oxygen atoms, nitrogen atoms, hydroxyl groups, ether groups, or oxyalkylene groups, wherein R’ denotes an optionally substituted C1-C12 alkyl radical; and
R3 is selected from hydrogen, (Alk-O)nH radical, linear or branched, saturated or unsaturated, C1 to C22 alkyl groups optionally substituted with oxygen atoms, nitrogen atoms, hydroxyl groups, ether groups, or oxyalkylene groups,
wherein Alk denotes a divalent alkylene radical comprising from 1 to 12 carbon atoms;
n, m denote, independently of one another, a number ranging from 1 to 50;
provided at least one of R1, R2, and R3 has at least one oxyalkylene group optionally substituted with linear or branched C1 to C30 alkyl or C2 to C30 alkenyl groups.
[0075] Preferably, according to embodiments herein, the oxyalkylenated
fatty amide(s) is(are) selected from a compound of formula (I’) below:
R1-CO-N(R2)-(Alk-O)nH (I’)
wherein,
R1 is selected from an optionally substituted C8-C30, preferably C10-C24, and better still C12-C22 alkyl or alkenyl radical;
R2 is selected from hydrogen or (R’-O)mH radical, and preferably is hydrogen;
R’ denotes an optionally substituted C1-C10, preferably C1-C8, and better still C1-C6 alkyl radical;
Alk denotes a divalent alkylene radical comprising from 1 to 8 carbon atoms, preferably 2 or 3 carbon atoms,
n, m denote, independently of one another, a number ranging from 1 to 50, preferably from 1 to 20, better still from 1 to 10.
[0076] In some embodiments, the oxyalkylenated fatty amide(s) is (are)
selected from compounds of formula (I’) wherein R2 denotes hydrogen; R1 denotes C12-C22 alkyl or alkenyl radical; Alk denotes a divalent alkylene radical comprising 2 or 3 carbon atoms; and n denotes a number ranging from 1 to 50, preferably from 1 to 20, more preferably from 1 to 10, and better still from 2 to 5.
[0077] More preferably, the oxyalkylenated fatty amide(s) according to the
invention is (are) chosen from the oxyethylenated fatty amides of formula (II) below:
R1-CO-N(R2)-(CH2CH2O)nH (II) wherein:
R1 denotes an optionally substituted C8-C30, preferably C10-C30 and better still C12-C22 alkyl or alkenyl radical,
R2 denotes a hydrogen atom or a (CH2CH2O)mH radical, and preferably a hydrogen atom,
n, m denote, independently of one another, a number ranging from 1 to 50, preferably from 1 to 20, better still from 1 to 10.
[0078] In some embodiments, the oxyalkylenated fatty amide(s) is (are)
selected from the oxyalkylenated fatty amides of formula (II) wherein R2 represents a hydrogen atom, R1 denotes a C12-C22 alkyl or alkenyl radical and n denotes a number ranging from 2 to 5.
[0079] Among the compounds of formula (II), oxyethylenated rapeseed
acid amides are preferred, such as the compound having the INCI name PEG-4
rapeseedamide, sold in particular under the name Amidet ®N by the company Kao.
[0080] Preferably, the oxidizing composition, according to the present
invention, comprises one or more oxyethylenated fatty amides in a content greater than 1.5% by weight, relative to the total weight of the composition.
[0081] The oxyalkylenated fatty amide(s), according to embodiments
herein, is(are) in a total amount ranging from 1.6% to 20% by weight, preferably
from 1.6% to 10% by weight, more preferably from 1.6% to 5% by weight, and
better from 1.7% to 3% by weight, relative to the total weight of the composition.
[0082] Preferably, the oxyalkylenated fatty amide(s), according to
embodiments herein is(are) selected from a compound of formula (I), and is(are) in a total amount ranging from 1.6% to 20% by weight, preferably from 1.6% to 10% by weight, more preferably from 1.6% to 5% by weight, and better from 1.7% to 3% by weight, relative to the total weight of the composition.
[0083] Preferably, the oxyalkylenated fatty amide(s), according to
embodiments herein is(are) selected from a compound of formula (I’), and is(are) in a total amount ranging from 1.6% to 20% by weight, preferably from 1.6% to 10% by weight, more preferably from 1.6% to 5% by weight, and better from 1.7% to 3% by weight, relative to the total weight of the composition.
pH
[0084] The pH of the oxidizing composition, according to the present
invention, is generally between 1 and 5, preferably between 1 and 4, more
preferably between 1.5 and 3.5.
[0085] In some embodiments, the pH of the composition of the present
invention may be adjusted and/or stabilized by means of basifying agents and/or
acidifying agents that are well known to those skilled in the art.
[0086] Basifying agents that may be used, in some embodiments, include
aqueous ammonia, alkali metal carbonates or bicarbonates, organic amines with a
pKb at 25°C of less than 12, in particular less than 10 and even more advantageously
less than 6; among the salts of the amines mentioned previously with acids such as
carbonic acid or hydrochloric acid, it should be noted that it is the pKb
corresponding to the function of highest basicity.
[0087] Preferably, the amines are selected from alkanolamines, in particular
comprising a primary, secondary, or tertiary amine function, and one or more linear
or branched C1-C8 alkyl groups bearing one or more hydroxyl radicals; from
oxyethylenated and/or oxypropylenated ethylenediamines, and from amino acids
and compounds having the following formula (III):
wherein, W is a C1-C6 alkylene residue optionally substituted with a hydroxyl group or a C1-C6 alkyl radical; Rx, Ry, Rz and Rt, which may be identical
or different, represent a hydrogen atom or a C1-C6 alkyl, C1-C6 hydroxyalkyl or C1-C6 aminoalkyl radical.
[0088] In some embodiments, acidifying agents that may especially be
mentioned include hydrochloric acid, (ortho)phosphoric acid, sulfuric acid, boric acid, and also carboxylic acids, for instance, acetic acid, lactic acid or citric acid, or sulfonic acids.
Additives
[0089] The composition, according to the present invention, comprises one
or more additives.
[0090] The additives, according to the present invention, that may be used
are selected from fatty substances other than fatty alcohols and oxyalkylenated fatty alcohols, solvents, stabilizers and sequestrants.
[0091] The composition, according to embodiments herein, comprises
water, which generally represents from 10% to 95% by weight, preferably from 20% to 95% by weight and preferably from 50% to 95% by weight, relative to the total weight of the composition.
[0092] In some embodiments, the composition may contain cosmetically
acceptable organic solvents, more particularly including alcohols such as ethyl alcohol, isopropyl alcohol, benzyl alcohol and phenylethyl alcohol, or polyols or polyol ethers, for instance, ethylene glycol monomethyl, monoethyl or monobutyl ether, propylene glycol or ethers thereof, for instance, propylene glycol monomethyl ether, butylene glycol, dipropylene glycol, and also diethylene glycol alkyl ethers, for instance, diethylene glycol monoethyl ether or monobutyl ether, glycerin.
[0093] The organic solvents may then represent from 0.1% to 20% by
weight and preferably from 0.2% to 10% by weight relative to the total weight of the composition according to the invention.
[0094] Of course, those skilled in the art will take care to choose the
optional additional compound(s) so that the advantageous properties intrinsically associated with the composition according to the present invention are not, or not substantially, detrimentally affected by the envisioned addition(s).
[0095] The additive(s), according to embodiments herein, is(are) in a total
amount ranging from 0.01% and 20% by, relative to the total weight of the composition.
[0096] The oxidizing composition of the invention is preferably free of
oxidative dyes.
Method
[0097] The oxidizing composition of the present invention may be
manufactured using known methods that are generally used in the cosmetics or dermatological field. Typically, the method for preparation of the composition comprises blending at least one oxidizing agent, at least one fatty alcohol, at least one oxyalkylenated fatty alcohol, at least one oxyalkylenated fatty amide, and water, wherein the total amount of the oxyalkylenated fatty amide(s) is greater than 1.5% by weight, relative to the total weight of the composition, with a suitable organic solvent, and optionally one or more additives to obtain the composition, such that the composition has a pH of less or equal to 5.
[0098] Embodiments herein further include a method for treating keratin
fibres, preferably human keratin fibres such as the hair, comprising the application to the keratin fibres of the composition as described herein.
[0099] In some embodiments, the method according to the present
invention comprises a method for bleaching keratin fibres. In this method, the oxidizing composition according to the present invention is applied to the keratin fibres, optionally with a preliminary step of mixing with at least one other composition, said other composition possibly comprising one or more peroxygenated salts, preferably chosen from persulfates.
[0100] In a further embodiment, the method according to the invention
comprises a method of dyeing and/or lightening keratin fibres. The method comprises the application of the oxidizing composition as described herein, simultaneously, or sequentially, with a dye composition comprising one or more oxidation dyes and/or one or more direct dyes and/or alkaline agents.
[0101] Preferably the dyeing and/or lightening composition comprises one
or more alkaline agents and one or more oxidation dyes.
[0102] The alkaline agent(s) that may be used is(are) selected from at least
one mineral, organic, or hybrid alkaline agent or combinations thereof.
[0103] The mineral alkaline agents are selected from ammonium hydroxide,
alkali metal carbonates or bicarbonates such as sodium (hydrogen)carbonate and potassium (hydrogen)carbonate, alkali metal or alkaline-earth metal silicates or metasilicates such as sodium metasilicate, or combinations thereof.
[0104] The organic alkaline agents are selected from alkanolamines, amino
acids, organic amines other than alkanolamines, oxyethylenated and/or oxypropylenated ethylenediamines, 1,3-diaminopropane, spermine, spermidine, or combinations thereof.
[0105] The term “alkanolamine” means an organic amine comprising a
primary, secondary, or tertiary amine function, and one or more linear or branched C1-C8 alkyl groups bearing one or more hydroxyl radicals.
[0106] In some embodiments, organic amines selected from alkanolamines
such as, monoalkanolamines, dialkanolamines or trialkanolamines comprising one to three identical or different C1-C10 hydroxyalkyl radicals are in particular suitable for performing the present invention.
[0107] In particular, in some embodiments, the alkanolamine(s) are selected
from monoethanolamine (MEA), diethanolamine, triethanolamine,
monoisopropanolamine, diisopropanolamine, N,N-dimethylethanolamine, 2-
amino-2-methyl-1-propanol, triisopropanolamine, 2-amino-2-methyl-1,3-
propanediol, 3-amino-1,2-propanediol, 3-dimethylamino-1,2-propanediol,
tris(hydroxymethyl)aminomethane, or combinations thereof.
[0108] Preferably, the alkaline agent(s) according to embodiments herein,
is(are) selected from alkanolamines and ammonium hydroxide. More preferably,
the alkaline agent is selected from alkanolamines, better is, monoethanolamine.
[0109] The oxidation dyes used in this dyeing and/or lightening process
may comprise:
- one or more standard oxidation dye precursors selected from oxidation bases such as phenylenediamines, bis(phenyl)alkylenediamines, para aminophenols, ortho-aminophenols and heterocyclic bases, and the addition salts thereof, optionally combined with one or more common couplers, for instance meta-phenylenediamines, meta-aminophenols, meta-diphenols, naphthalene-based couplers and heterocyclic couplers, and also the addition salts thereof, and/or
- one or more direct dyes selected from synthetic or natural, cationic, anionic, or nonionic direct dyes.
[0110] In some embodiments, suitable direct dyes that may be used are
selected from nitrobenzene dyes, azo direct dyes, azomethine direct dyes, methine
direct dyes, azacarbocyanines, for instance, tetraazacarbocyanines
(tetraazapentamethines), quinone and in particular anthraquinone, naphthoquinone or benzoquinone direct dyes, azine direct dyes, xanthene direct dyes, triarylmethane direct dyes, indoamine direct dyes, indigoid direct dyes, phthalocyanine direct dyes, porphyrin direct dyes and natural direct dyes, alone or as mixtures. In particular, mention may be made of direct dyes from among: azo, methine, carbonyl, azine, nitro (hetero)aryl, tri(hetero)arylmethane, porphyrin, phthalocyanine and natural direct dyes, alone or as mixtures.
[0111] The dyeing and/or lightening composition usually comprises dyes
(oxidation dyes and/or direct dyes) in a total amount ranging from 0.0001% to 10% by weight, and preferably from 0.005% to 5% by weight, relative to the weight of the dye composition.
[0112] The dyeing and/or lightening composition usually comprises
alkaline agent(s) in a total amount ranging from 1% to 30% by weight, and preferably from 2% to 20% by weight, relative to the weight of the dye composition.
[0113] In some embodiments, the dyeing and/or lightening composition
may also comprise other ingredients such as fatty substances, adjuvants such as, in
a non-limiting manner, nonionic, cationic, anionic, or amphoteric surfactants,
anionic, nonionic, or amphoteric polymers, or combinations thereof, antioxidants,
penetrants, sequestrants, fragrances, dispersants, film-forming agents, ceramides,
preserving agents, opacifiers.
[0114] The adjuvants may each be present in an amount ranging from
0.01% and 20% by weight, relative to the weight of the dye composition. The dye
composition may also comprise water and/or one or more organic solvents such as
those described hereinabove.
[0115] In some embodiment, the organic solvents, when present, are in an
amount ranging from 1% and 40% by weight, and preferably between 5% and 30%
by weight, relative to the total weight of the dye composition. The dye composition
is preferably aqueous.
[0116] The pH of the dyeing and/or lightening composition generally
ranges from 6 to 12, preferentially from 8.5 to 11. It may be adjusted by the addition
of acidifying agents and/or basifying agents such as those such as those described
hereinabove.
[0117] In some embodiments, the dyeing and/or lightening of keratin fibres,
according to the invention, is performed by applying to the keratin fibres the
composition according to the invention in the presence of the abovementioned
dyeing and/or lightening composition. These two compositions may be applied one
after the other, without intermediate rinsing, or alternatively and preferably mixed
just before application to the keratin fibres.
[0118] The method, according to the present invention, may be repeated
several times so as to obtain the desired colouring.
[0119] In a further embodiment, the method according to the present
invention comprises a process for permanently reshaping keratin fibres. According
to this embodiment, the method generally comprises a first step of applying a
reducing composition comprising one or more reducing agents, followed by a step
of applying the oxidizing composition according to the present invention.
[0120] In some embodiments, the method comprises a step of placing the
keratin fibres under tension (for example with rollers) and/or a step of heat treatment of the keratin fibres.
[0121] The method according to the present invention, in some
embodiments, comprises optionally mixing beforehand the composition(s) (including the oxidizing composition, and/or the bleaching composition, and/or the dyeing and/or lightening composition, and/or reducing composition) beforehand, and applying the mixture to wet or dry keratin fibres.
[0122] The mixture is usually left in place on the fibres for a time generally
ranging from 1 minute to 1 hour and preferably from 5 minutes to 45 minutes.
[0123] The temperature during the method(s) according to the present
invention is conventionally between 20 and 80°C, preferably between 20 and 60°C.
[0124] On the conclusion of the treatment and method(s), the keratin fibres
are advantageously rinsed with water. They may optionally be washed with a shampoo, followed by rinsing with water, before being dried or left to dry.
Kit
[0125] Embodiments provided herein also include a kit comprising an
oxidizing composition (A) as described in the embodiments hereinabove comprising at least one oxidizing agent, at least one fatty alcohol, at least one oxyalkylenated fatty alcohol, at least one oxyalkylenated fatty amide, and water, wherein the total amount of the oxyalkylenated fatty amide(s) is greater than 1.5% by weight relative to the total weight of the composition, and the composition has a pH of less or equal to 5, and a dyeing and/or lightening composition (B) comprising one or more direct dyes and/or one or more oxidation dyes and/or one or more alkaline agents as described hereinabove.
[0126] The compositions (A) and (B) are intended to be mixed together at
the time of use which is then applied to keratin fibres for dyeing and/or lightening of keratin fibres.
Use
[0127] Embodiments herein include use of the oxidizing composition
according to the present invention.
[0128] The composition, according to embodiments herein, may be used for
dyeing and/or lightening keratin fibres, particularly hair. The composition may be used for the purpose of colour change, colour lightening/bleaching of hair, and/or coverage of greying hair.
[0129] The composition may be used on natural hair and/or artificial hair,
including hair extensions.
[0130] The composition may be used at different temperatures, including
conventionally at room temperature (between 25oC to 30oC) and 80°C and preferably between room temperature and 60°C.
[0131] Although the subject matter has been described in considerable
detail with reference to certain examples and implementations thereof, it is understood that other implementations are possible and included within the scope of the present invention.
Examples
[0132] The disclosure will now be illustrated with working examples,
which is intended to illustrate the working of disclosure and not intended to take restrictively to imply any limitations on the scope of the present disclosure. Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood to one of ordinary skill in the art to which this disclosure belongs. Although methods and materials similar or equivalent to those described herein can be used in the practice of the disclosed methods and compositions, the exemplary methods, devices, and materials are described herein. It is to be understood that this disclosure is not limited to particular methods, and experimental conditions described, as such methods and conditions may apply.
Example 1
Oxidizing Composition
[0133] In an example, the oxidizing composition according to the invention
(inv.) (Composition A) was formulated using oxidizing agent viz. 6 wt% hydrogen peroxide, fatty alcohol viz. 8 wt% cetearyl alcohol, oxyalkylenated fatty alcohol viz. 0.2 wt% steareth-20, and 0.57 wt% ceteareth-25, oxyalkylenated fatty amide viz. 1.84 wt% PEG-4 rapeseedamide, sequestrant viz. 0.06 wt% tetrasodium etidronate, and stabilizers viz.0.04 wt% tetrasodium pyrophosphate, and 0.035 wt% sodium salicylate, organic solvent viz 0.5 wt% glycerin, water qs 100, and phosphoric acid pH ≤ 5.
[0134] Table 1 depicts the oxidizing composition A, according to the
present invention, and comparative (comp.) compositions C1 and C2.
[0135] Comparative compositions C1 and C2 were prepared in the same
manner as the composition A, except that the amount of PEG-4 rapeseedamide was 1.38 wt%, and 0.92 wt% in compositions C1 and C2, respectively.
Table 1
No.
1
2
3
4
5
6
7
8
9 10 11 Ingredient (INCI) Amount (wt%)
A (inv.) C1 (comp.) C2 (comp.)
Hydrogen peroxide 6 6 6
Cetearyl alcohol 8 8 8
Steareth-20 0.2 0.2 0.2
Tetrasodium etidronate 0.06 0.06 0.06
Glycerin 0.5 0.5 0.5
Sodium salicylate 0.035 0.035 0.035
PEG-4 rapeseedamide 1.84 1.38 0.92
Ceteareth-25 0.57 0.57 0.57
Tetrasodium pyrophosphate 0.04 0.04 0.04
Water qs 100 qs 100 qs 100
Phosphoric acid qs pH = 2.2 qs pH = 2.2 qs pH = 2.2
[0136] The dye composition B, according to embodiments herein, was
prepared according to the ingredients provided in Table 2 below.
Table 2
No. Ingredient (INCI) Amount (wt%)
1 Glyceryl stearate SE 0.4
2 Ethanolamine 7.9
3 Coco-glucoside 1.0
4 2-Amino-3-hydroxypyridine 0.07
5 Sucrose stearate 0.3
6 Hydroxybenzomorpholine 0.72
7 Glyceryl caprylate 1.4
8 Tetrasodium glutamate diacetate 0.5
9 N,N-bis(2-hydroxyethyl)-p-phenylenediamine sulfate 0.25
10 Myristic acid 0.02
11 Palmitic acid 0.26
12 Stearic acid 0.32
13 Propylene glycol 5
14 m-Aminophenol 0.27
15 Glycol distearate 2
16 2,4-diaminophenoxyethanol HCl 0.03
17 Fatty alcohol (Cetearyl alcohol) 23
18 Hydroxypropyl guar hydroxypropyltrimonium chloride 0.5
19 Polyglyceryl-4 caprate 0.6
20 Helianthus annuus (sunflower) seed oil 6
21 Hydroxyethyl-3,4-methylenedioxyaniline HCl 0.33
22 Toluene-2,5-diamine 0.95
23 Water qs 100
24 Sequestrant, reducing agent qs
Example 2: Evaluation of dyeing and/or lightening effect
[0137] Protocol: The oxidizing compositions A, C1, and C2 were each
mixed with the dye composition B, each mixture in a weight ratio of 1:1.
[0138] Each of the mixtures was applied to locks of natural 90% white hair,
in a proportion of 5 g of mixture per 1 g of hair.
[0139] After a leave-on time of 35 minutes on a hot plate at 27°C, the hair
was rinsed, washed with a standard shampoo, and dried.
[0140] Results: The colouration of the hair was evaluated with a
spectrocolorimeter Minolta CM3600d, illuminant D65, angle 10°, SCI values for
the L*, a*, b* colorimetric measurements.
[0141] In this L*, a*, b* system, L* represents the intensity of the colour,
a* indicates the green/red colour axis and b* indicates the blue/yellow colour axis.
The lower the value of L, the darker or more intense the colour.
[0142] The variation in colouring between the locks of natural white hair
which is untreated (control) and after treatment or coloration are defined by ΔE,
corresponding to the colour uptake on keratin fibres, according to the following
equation:
[0143] In this equation, L*, a* and b* represent the values measured after
dyeing the natural hair comprising 90% of white hairs and L0*, a0* and b0* represent the values measured for the untreated natural hair comprising 90% of white hairs.
[0144] The greater the value of AE, the greater the difference in colour
between the control locks and the dyed locks and the greater colour uptake is.
[0145] Table 3 provides the results of the application of the oxidizing
compositions on hair:
Table 3
ΔE
A + B (invention) 40.18
C1 + B (comparative) 38.10
C2 + B (comparative) 38.13
[0146] The results from Table 3 demonstrated that the inventive
composition A, that comprised the oxyalkylenated fatty amide in an amount that is greater than 1.5 wt% relative to the total weight of the composition, clearly showed a significantly better colour uptake with a difference of AE > 2 in comparison to the
comparative compositions C1 and C2 which comprised the oxyalkylenated fatty amide in an amount that is less than 1.5% by weight.
[0147] Therefore, the composition according to the present invention shows
good colour uptake, chromaticity, and colour visibility with long-lasting colour. In addition, the oxidizing composition according to the present invention had a non-drippy and thicker texture that was easy to apply on hair and was also easy to rinse out as it did not leave an oily residue.
[0148] Moreover, the oxidizing composition according to the present
invention also imparted a good shine and smoothness to hair.
ADVANTAGES OF THE PRESENT DISCLOSURE
[0149] The oxidizing composition of the present disclosure demonstrates
good performance in terms of dyeing and/or lightening of hair and also shows good working qualities. The composition provides good bleaching efficiency, good colour uptake, and chromaticity, with long-lasting colour. In terms of its working qualities, the composition has a non-drippy texture, is easy to apply to the hair in a uniform manner, and is easy to rinse out, with mistake-proof application and therefore, is less time-consuming to apply. The composition also does not weigh down hair with an oily residue and instead provides a shine, smoothness and softness to hair.
I/We Claim
1. An oxidizing composition comprising:
at least one oxidizing agent;
at least one fatty alcohol;
at least one oxyalkylenated fatty alcohol;
at least one oxyalkylenated fatty amide; and
water;
wherein the total amount of the oxyalkylenated fatty amide(s) is greater than 1.5%
by weight, relative to the total weight of the composition, and the composition has
a pH of less than or equal to 5.
2. The composition as claimed in claim 1, wherein the oxidizing agent(s) is(are) selected from hydrogen peroxide, urea peroxide, alkali metal bromates or ferricyanides, peroxygenated salts, alkali metal percarbonates, alkaline-earth metal percarbonates, or combinations thereof, preferably is hydrogen peroxide.
3. The composition as claimed in any one of the preceding claims, wherein the oxidizing agent(s) is(are) in a total amount ranging from 0.5% to 40% by weight, preferably from 1% to 30% by weight, more preferably from 2% to 20% by weight, and better from 4% to 15% by weight, relative to the total weight of the composition.
4. The composition as claimed in any one of the preceding claims, wherein the fatty alcohol(s) is(are) selected from at least one solid fatty alcohol, at least one liquid fatty alcohol, or combinations thereof, preferably from at least one solid fatty alcohol comprising 6 to 40 carbon atoms, and more preferably comprising 8 to 30 carbon atoms.
5. The composition as claimed in any one of the preceding claims, wherein the fatty alcohol(s) is(are) selected from cetyl alcohol, stearyl alcohol, behenyl alcohol,
myristyl alcohol, arachidyl alcohol, lignoceryl alcohol, ceryl alcohol, montanyl alcohol, myricyl alcohol, or combinations thereof, and preferably selected from cetyl alcohol, stearyl alcohol, or combinations thereof such as cetearyl alcohol, and more preferably is cetearyl alcohol.
6. The composition as claimed in any one of the preceding claims, wherein the fatty alcohol(s) is(are) in a total amount ranging from 0.5% to 40% by weight, preferably from 1% to 30% by weight, more preferably from 5% to 20% by weight, and better still from 7% to 15% by weight, relative to the total weight of the composition.
7. The composition as claimed in any one of the preceding claims, wherein the oxyalkylenated fatty alcohol(s) comprise(s) at least 10 oxyalkylenated groups, preferably from 10 to 50 groups, more preferably from 10 to 35 groups, and better still from 15 to 30 groups.
8. The composition as claimed in one of the preceding claims, wherein the oxyalkylenated fatty alcohol(s) is(are) selected from oxyethylenated fatty alcohols, preferably having a number of oxyethylene groups ranging from 10 to 50 groups, more preferably from 10 to 35 groups, and better still from 15 to 30 groups.
9. The composition as claimed in any one of the preceding claims, wherein the oxyalkylenated fatty alcohol(s) is(are) selected from oxyethylenated fatty alcohols, preferably from oxyethylenated (OE) stearyl alcohol, oxyethylenated cetyl alcohol, oxyethylenated cetylstearyl alcohol, or combinations thereof, and more preferably from stearyl alcohol 20 OE, cetylstearyl alcohol 25 OE, or combinations thereof.
10. The composition as claimed in one of the preceding claims, wherein the composition comprises at least two different oxyalkylenated fatty alcohols, preferably at least two different oxyethylenated fatty alcohols.
11. The composition as claimed in any one of the preceding claims, wherein the oxyalkylenated fatty alcohol(s) is(are) in a total amount ranging from 0.1% to 5% by weight, preferably from 0.2% to 4% by weight, more preferably from 0.3% to 3% by weight, and better still from 0.5% to 2% by weight, relative to the total weight of the composition.
12. The composition as claimed in any one of the preceding claims, wherein the oxyalkylenated fatty amide(s) is(are) selected from a compound of formula (I) below:
wherein,
R1 is selected from linear or branched C1 to C30 alkyl or C2 to C30 alkenyl groups optionally substituted with oxygen atoms, nitrogen atoms, hydroxyl groups, ether groups, or oxyalkylene groups;
R2 is selected from hydrogen, (R’-O)mH radical, linear, or branched, saturated or unsaturated, C1 to C22 alkyl groups optionally substituted with oxygen atoms, nitrogen atoms, hydroxyl groups, ether groups, or oxyalkylene groups,
wherein R’ denotes an optionally substituted C1-C12 alkyl radical; and R3 is selected from hydrogen, (Alk-O)nH radical, linear or branched, saturated or unsaturated, C1 to C22 alkyl groups optionally substituted with oxygen atoms, nitrogen atoms, hydroxyl groups, ether groups, or oxyalkylene groups,
wherein Alk denotes a divalent alkylene radical comprising from 1 to 12 carbon atoms;
n, m denote, independently of one another, a number ranging from 1 to 50;
provided at least one of R1, R2, and R3 has at least one oxyalkylene group optionally substituted with linear or branched C1 to C30 alkyl or C2 to C30 alkenyl groups.
13. The composition as claimed in any one of the preceding claims, wherein the
oxyalkylenated fatty amide(s) is(are) selected from a compound of formula (I’)
below:
R1-CO-N(R2)-(Alk-O)nH (I’) wherein,
R1 is selected from an optionally substituted C8-C30, preferably C10-C24, and better still C12-C22 alkyl or alkenyl radical;
R2 is selected from hydrogen or (R’-O)mH radical, and preferably is hydrogen;
R’ denotes an optionally substituted C1-C10, preferably C1-C8, and better still C1-C6 alkyl radical;
Alk denotes a divalent alkylene radical comprising from 1 to 8 carbon atoms, preferably 2 or 3 carbon atoms,
n, m denote, independently of one another, a number ranging from 1 to 50, preferably from 1 to 20, better still from 1 to 10.
14. The composition as claimed in claim 13, wherein the oxyalkylenated fatty amide(s) is (are) selected from compounds of formula (I’) wherein R2 denotes hydrogen; R1 denotes C12-C22 alkyl or alkenyl radical; Alk denotes a divalent alkylene radical comprising 2 or 3 carbon atoms; and n denotes a number ranging from 1 to 50, preferably from 1 to 20, more preferably from 1 to 10, and better still from 2 to 5.
15. The composition as claimed in any one of the preceding claims, wherein the oxyalkylenated fatty amide(s) is(are) in a total amount ranging from 1.6% to 20% by weight, preferably from 1.6% to 10% by weight, and more preferably from 1.6% to 5% by weight, better still from 1.7% to 3% by weight, relative to the total weight of the composition.
16. The composition as claimed in any one of the preceding claims is free of
oxidation dye(s).
17. A kit for dyeing and/or lightening keratin fibres comprising:
(a) an oxidizing composition as claimed in any one of the preceding claims; and
(b) a dyeing and/or lightening composition comprising one or more direct dyes
and/or one or more oxidation dyes and/or one or more alkaline agents.
18. A method for treating keratin fibers, comprising application to the keratin fibers the oxidizing composition as claimed in any one of the preceding claims 1 to 16.
19. A method for dyeing and/or lightening keratin fibers comprising
mixing the oxidizing composition as claimed in any one of the preceding claims 1 to 16, with a dyeing and/or lightening composition comprising one or more direct dyes and/or one or more oxidation dyes and/or one or more alkaline agents to obtain a mixture; and applying the mixture on said fibres.
20. Use of the oxidizing composition as claimed in any one of the preceding
claims 1 to 16, for treating keratin fibers, preferably for dyeing and/or
lightening keratin fibers.
| # | Name | Date |
|---|---|---|
| 1 | 202321085963-STATEMENT OF UNDERTAKING (FORM 3) [15-12-2023(online)].pdf | 2023-12-15 |
| 2 | 202321085963-POWER OF AUTHORITY [15-12-2023(online)].pdf | 2023-12-15 |
| 3 | 202321085963-FORM 1 [15-12-2023(online)].pdf | 2023-12-15 |
| 4 | 202321085963-DECLARATION OF INVENTORSHIP (FORM 5) [15-12-2023(online)].pdf | 2023-12-15 |
| 5 | 202321085963-COMPLETE SPECIFICATION [15-12-2023(online)].pdf | 2023-12-15 |
| 6 | 202321085963-Proof of Right [30-01-2024(online)].pdf | 2024-01-30 |
| 7 | 202321085963-Proof of Right [30-01-2024(online)]-1.pdf | 2024-01-30 |
| 8 | 202321085963-FORM 3 [23-05-2024(online)].pdf | 2024-05-23 |
| 9 | 202321085963-FORM 18 [19-07-2024(online)].pdf | 2024-07-19 |