DESC:FORM 2
THE PATENTS ACT 1970
(39 of 1970)
&
The Patents Rules, 2003
COMPLETE SPECIFICATION
(See section 10 and rule 13)
1. TITLE OF THE INVENTION: “A ternary insecticidal composition for insects, pests and mites”
2. APPLICANT:
(a) Name : RAJDHANI PETROCHEMICALS PRIVATE LIMITED
(b) Nationality : INDIAN
(c) Address : 6, LALITA COMPLEX, RASALA ROAD, NAVRANGPURA, AHMEDABAD-380009 Gujarat, India
PROVISIONAL
The following specification describes the invention. ? COMPLETE
The following specification particularly describes the invention and the manner in which it is to be performed.

FIELD OF INVENTION
The present invention relates to a ternary insecticidal composition for insects, pests and mites. More specifically, the present invention relates to a ternary insecticidal composition comprising 3-[benzoyl(methyl)amino] -N- [2-bromo-4-(1,1,1,2,3,3,3-heptafluoropropan-2-yl)-6-(trifluoromethyl)phenyl] -2- fluorobenzamide, 4-chloro-5-ethyl -2- methyl-N-[[4-(4-methylphenoxy)phenyl]methyl] pyrazole-3-carboxamide, and at least one compound selected from the group of insecticide; and a process of preparing said composition. The present invention further relates to a ternary insecticidal composition that provides an effective and synergistic control to broad spectrum of insect pests and mites with one shot application. Further, the ternary insecticidal composition of present invention increases yield and vigor of the plant by providing residual control and increment in tolerance against insect pests and mites.

BACKGROUND OF THE INVENTION
In recent years, the problem of pest resistance in agricultural production is a global problem and has always been a key topic of concern for agricultural science and technology workers. Further, with the continuation of the use of chemical insecticides to control pests year after year, and the increase in the use of insecticides as well as the unscientific use of insecticides and other factors, the resistance of pests is becoming more and more serious, and the types of resistant pests are increasing.
At the same time, the high-intensity use of insecticides has led to a series of problems such as excessive insecticides residues in agricultural products, pollution of the environment, and increased costs for farmers to use drugs, which is not conducive to the sustainable development of agriculture.
The long-term use of single chemical insecticides will form a directional choice for insects, pests and mites which will increase the resistance of insects, pests and mites. Moreover, due to long-term use of chemical insecticides, insects, pests and mites have become more resistant to insecticides.
W0 2023/229820 Al relates to pesticidal bait composition which contains pesticides, corn grit having transgenic Bacillus thuringensis, grounded corn cob and a binder. The said patent application is focued on a composition in which pesticides has been mentioned from which (a) at least one pesticide in combination of (b) corn grit or mixture and (c) a binder has been utilized to control the pests in agriculture.
CN108056102A relates to an insecticidal composition containing 3-[benzoyl(methyl)amino]-N-[2-bromo-4-(1,1,1,2,3,3,3-heptafluoropropan-2-yl)-6-(trifluoromethyl)phenyl]-2-fluorobenzamide and 4-chloro-5-ethyl-2-methyl-N-[[4-(4-methylphenoxy)phenyl]methyl]pyrazole-3-carboxamide. The said patent application is concerned with the binary composition showing its effect on rice/rice leaf roller, cabbage/bamboo moth, and eggplant/puma.
WO 2022/208504 A1 relates to the combination of active compounds comprising novaluron and at least one further active compound and to method of controlling pests applying the said combinations. The said patent application is concerned with the binary composition in particular, a pesticidal mixture containing a compound of formula I i.e. novaluron and at least one compound II selected from A.1 to A.26.
The active ingredients known from the prior arts have certain disadvantages such as insufficient control efficacy, restriction of its use due to the appearance of drug-resistant insects, pests and mites phytotoxicity and contamination to plants, or toxicity to human beings, fishes and the like.
From the above shown prior arts it is also pertinent to note that none of them shows the ternary combination of the components and its effective and synergistic approach to control insects, pests and mites as shown by the present invention.
The insecticides currently in use are not that effective; and due to their prolonged indiscriminate and non-judicious use, some pests have developed resistance to such commonly used insecticides. Their use is thereby becoming increasingly difficult.
However, insecticides with different action mechanisms can be mixed reasonably according to a certain proportion, which can improve the efficacy, reduce the dosage, fewer residues, reduce environmental pollution, and effectively reduce the drug resistance of crops against insect pests and mites.
Therefore, there is an urgent need to develop new methods and formulations for controlling these harmful pests. The present inventors have surprisingly developed an effective insecticidal combination which ameliorates the aforesaid shortcomings of the prior art comprising high-efficiency, low-toxicity and environmentally-friendly insecticides which has become a mainstream direction in the field of insecticides research.

OBJECT OF THE INVENTION
The principal object of the present invention is to provide a ternary insecticidal composition for insects, pests and mites.
Another object of the present invention is to provide a ternary insecticidal composition comprising bioactive amounts of3-[benzoyl(methyl)amino]-N-[2-bromo-4-(1,1,1,2,3,3,3-heptafluoropropan-2-yl)-6-(trifluoromethyl)phenyl]-2-fluorobenzamide, 4-chloro-5-ethyl-2-methyl-N-[[4-(4 methylphenoxy)phenyl]methyl]pyrazole-3-carboxamide, at least one insecticide and agrochemically acceptable excipients; and method of preparation thereof.
Further object of the present invention is to provide ternary insecticidal composition demonstrating effective and synergistic control.
Yet another object of the present invention is to provide ternary insecticidal composition providing delay in development of resistance and effective control of hard to kill and resistant insect-pests and mites.
Still another object of the present invention is to provide ternary insecticidal composition which increases yield of treated plants.
Further object of the present invention is to provide ternary insecticidal composition having residual control by providing longer duration of control with immediate crop protection.
Another object of the present invention is to provide a method of preparing a stable and non-phytotoxic formulation which improves overall health, yield and vigor of the treated plant.
Further object of the present invention is to provide ternary insecticidal composition which increases plant vigor, is tolerant against insect-pests and mites and is environmentally safe.

SUMMARY OF THE INVENTION
The present invention provides aternary insecticidal composition for insects, pests and mites. Further, the ternary insecticidal composition comprises bioactive amounts of component (A) 3-[benzoyl(methyl)amino]-N-[2-bromo-4-(1,1,1,2,3,3,3-heptafluoropropan-2-yl)-6-(trifluoromethyl)phenyl] -2-fluorobenzamide; component (B) 4-chloro-5-ethyl-2-methyl-N-[[4-(4-methylphenoxy) phenyl] methyl]pyrazole-3-carboxamide; component (C) at least one compound selected from the group of insecticides; and agrochemically acceptable excipients.

The formulation for aternary insecticidal composition is selected from Capsule suspension (CS), Dispersible concentrate (DC), Emulsifiable concentrate (EC), Emulsion, water in oil (EO), Emulsion, oil in water (EW), Jambo balls or bags (bags in water soluble pouch), Micro-emulsion (ME), Oil dispersion (OD), Oil miscible flowable concentrate (oil miscible suspension (OF), Oil miscible liquid (OL), Suspension concentrate (SC), Suspo-emulsion (SE), Soluble concentrate (SL), Wettable granule/Water dispersible granule (WG/WDG), Water soluble granule (SG), Water soluble powder (SP), Wettable powder (WP), A mixed formulation of CS and SC (ZC), A mixed formulation of CS and SE (ZE), a mixed formulation of CS and EW (ZW), Granule (GR) / Soil Applied Granules (SAG), Controlled release granules (CR).

The process for preparing the present ternary insecticidal composition can be modified accordingly by any person skilled in the art based on the knowledge of the manufacturing the formulation. However, all such variation and modification is still covered by the scope of present invention.
The present invention is formulated to control broad spectrum control of harmful insect pests (caterpillars, sucking pests) and mites with one shot application. Further, the ternary insecticidal composition provides effective and synergistic control i.e. grams of active ingredients required are less to achieve desired level of control.
Moreover, the ternary insecticidal composition increases delay in development of resistance and effective control of hard to kill and resistant insect-pests and mites. Furthermore it also increases the yield of the treated plants by increasing plant vigor and tolerant against insects, pests and mites.

DETAILED DESCRIPTION OF THE INVENTION
Before explaining the present invention in detail, it is to be understood that the invention is not limited in its application to the details of the parts illustrated. The invention is capable of other embodiments, as described above and of being practiced or carried out in a variety of ways. It is to be understood that the phraseology and terminology employed herein is for the purpose of description and not to limitation. The invention may have various embodiments and they may be performed as described in the following pages of the complete specification.
The terms and words used in the following description are not limited to the bibliographical meanings, but, are merely used by the inventors to enable a clear and consistent understanding of the invention. Accordingly, it should be apparent to those skilled in the art that the following description of exemplary embodiments of the present invention are provided for illustration purpose only and not for the purpose of limiting the scope of the invention.
It is to be understood that the singular forms "a," "an," and "the" include plural reference unless the context clearly dictates otherwise.
Features that are described and/or illustrated with respect to one embodiment may be used in the same way or in a similar way in one or more other embodiments and/or in combination with or instead of the features of the other embodiments.
It should be emphasized that the term "comprises/comprising" when used in this specification is taken to specify the presence of stated features, steps or components but does not preclude the presence or addition of one or more other features, steps, components or groups thereof.
The term 'plants' as used herein, refers to all physical parts of a plant, including seeds, seedlings, saplings, roots, tubers, stems, stalks, foliage and fruits. The term "plant" is to be understood as including wild type plants and plants, which have been modified by either conventional breeding, or mutagenesis or genetic engineering, or by a combination thereof.
The term "crop" refers to both, growing and harvested crops.
The term "insects" as used herein, includes all organisms in the class "Insecta."
The term "animal pest" includes arthropods, gastropods, and nematodes. Preferred animal pests according to the invention are arthropods, preferably insects and arachnids, in particular insects. Insects, which are of particular relevance for crops, are typically referred to as crop insect pests.
The term "insecticidal" as used herein, refers to the ability of an insecticide to increase mortality or inhibit growth rate of insects.
To "control" or "controlling" pests means to inhibit, through a toxic effect, the ability of pests to survive, grow, feed, and/or reproduce, or to limit pest related damage or loss in crop plants. To "control" pests may or may not mean killing the pests, although it preferably means killing the pests.
The term "health of a plant" or "plant health" is defined as a condition of the plant and/or its products. As a result of the improved health, yield, plant vigor, quality and tolerance to abiotic or biotic stress are increased.
"Yield" is to be understood as any plant product of economic value that is produced by the plant such as grains, fruits in the proper sense, vegetables, nuts, grains, seeds, wood (e.g. in the case of silviculture plants) or even flowers (e.g. in the case of gardening plants, ornamentals).
"Increased yield" of a plant, in particular of an agricultural, silvicultural and/or horticultural plant means that the yield of a product of the respective plant is increased by a measurable amount over the yield of the same product of the plant produced under the same conditions, but without the application of the composition according to the invention.
The present invention provides a ternary insecticidal composition comprising
1. Component A –3-[benzoyl(methyl)amino]-N-[2-bromo-4- (1,1,1,2,3,3,3-heptafluoropropan-2-yl) -6-(trifluoromethyl) phenyl]-2-fluorobenzamide,

2. Component B – 4-chloro-5-ethyl-2-methyl-N-[[4-(4-methylphenoxy) phenyl] methyl]pyrazole-3-carboxamide

3. Component C – at least one compound selected from group of insecticides with the following mass percentage of the composition:

Sr. No. Ingredient Concentration range (w/w %)
1. Component A 1 to 20
2. Component B 5 to 30
3. Component C 1 to 50

Component A is Broflanilide having chemical name as 3-[benzoyl(methyl)amino]-N-[2-bromo-4-(1,1,1,2,3,3,3-heptafluoropropan-2-yl)-6-(trifluoromethyl)phenyl]-2-fluorobenzamide is a polycyclic, bisamide based organo halogen insecticide.

3-[benzoyl(methyl)amino] -N- [2-bromo -4- (1,1,1,2,3,3,3-heptafluoropropan-2-yl) -6- (trifluoromethyl)phenyl]-2-fluorobenzamide is mainly focused for controlling vegetable, rice, soyabean, cotton, corn and non-crop non-crop lepidoptera. Coleoptera pests and health pests such as termites, mosquitoes and cockroaches. The agent has a high larvicidal activity against spodopteralitura and is suitable for controlling human, animal and is environmental safety.
Component B is tolfenpyrad having chemical name as 4-chloro-5-ethyl-2-methyl-N-[[4-(4-methylphenoxy) phenyl]methyl] pyrazole-3-carboxamide.

It is used to control or suppress wide range of insect pests and diseases including Lepidoptera, Coleoptera, Diptera, Hemiptera, Orthoptera, and Thysanoptera insects, downy mildew and powdery mildew. It is effective in controlling all developmental stages of most target pests. Further, tolfenpyrad is a MET 1 inhibitor, which inhibits cell respiration when it comes in contact with the target pests.
Insecticide(s) for Component C is selected from the class of carbamates (AChE-acetylcholine esterase inhibitors),

from the class of organophosphates (AChE-acetylcholine esterase inhibitors),

from the class of phenylpyrazoles-fiproles (GABA-gated chloride channel blockers),

from the class of pyrethroids (sodium channel modulators),

from the class of nicotinic insecticides (nicotinic acteylcholine receptor (nAChR) competitive modulators),

from the class of nereistoxin analogues (nicotinic acetylcholine receptor (nAChR) channel blockers),from the class of spinosyns (nicotinic acteylcholine receptor (nAChR) allosteric modulators-Site I),

from the class of juvenile hormone mimics,from the class of non-specific multi-site inhibitors,

from the class of chordotonal organs modulators,

from the class of mite growth inhibitors affecting CHS1, from the class of benzoylureas (inhibitors of the chitin biosynthesis affecting CHS1), from the class of buprofezin (inhibitors of the chitin biosynthesis type 1),from the class of cyromazine (moulting disruptors for dipteran),

from the class of microbial disruptors of insect midgut membrane, from the class of uncouplers of oxidative phosphorylation, from the class of diacylhydrazines (ecdyson receptor agonists),from the class of octopamin receptor agonists,

from the class of inhibitors of mitochondrial ATP synthase,from the class of METI (mitochondrial complex I) inhibitors,from the class of METI (mitochondrial complex II) inhibitors,from the class of METI (mitochondrial complex III) inhibitors,from the class of voltage-dependent sodium channel blockers,

from the class of inhibitors of the lipid synthesis, inhibitors of acetyl CoA carboxylase,from the class of baculoviruses,from the class of calcium activated potassium channel (KCa2) modulators andCompounds of unknown or uncertain mode of action.

Insecticides is selected from the group consisting of
C1 diafenthiuron: 1-tert-butyl-3-(2,6-diisopropyl-4-phenoxyphenyl)thiourea,

C2 Profenofos: 4-bromo-2-chloro-1-[ethoxy(propylsulfanyl)phosphoryl]oxybenzene,

C3 lambda cyhalothrin: [(R)-cyano-(3-phenoxyphenyl)methyl] (1S,3S) -3- [(Z) -2- chloro- 3,3,3- trifluoroprop -1- enyl]-2,2 dimethylcyclopropane-1-carboxylate,

C4 fenpyroximate: tert-butyl4- [[(E-(1,3-dimethyl-5-phenoxypyrazol-4 yl) methylideneamino] oxymethyl] benzoate,

C5 methoxyfenozide: N’-tert-butyl-N’-(3,5-dimethylbenzoyl)-3-methoxy-2-methylbenzohydrazide,

C6 hexythiazox: (4S,5S)-5-(4-chlorophenyl)-N-cyclohexyl-4-methyl-2 oxo-1,3-thiazolidine-3-carboxamide,

C7 etoxazole: 4-(4-tert-butyl-2-ethoxyphenyl)-2-(2,6-difluorophenyl)-4,5-dihydro-1,3-oxazole,

C8 chlorfenapyr: 4-bromo-2-(4-chlorophenyl)-1-(ethoxymethyl)-5-(trifluoromethyl)--pyrrole-3-carbonitrile,

C9 cyenopyrafen: [(E)-2-(4-tert-butylphenyl)-2-cyano-1-(2,4,5-trimethylpyrazol-3-yl)ethenyl] 2,2-dimethylpropanoate,

C10 phenthoate: ethyl 2-dimethoxyphosphinothioylsulfanyl-2-phenylacetate,

C11 phosalone: 6-chloro-3-(diethoxyphosphinothioylsulfanylmethyl) -1,3-benzoxazol-2-one,

C12 quinalphos: diethoxy-quinoxalin-2-yloxy-sulfanylidene-?5-phosphane,

C13 emamectin benzoate: benzoic acid;(1'R,2R,3S,4’S,6S,8’R,10’E,12’S,13’S,14’E,16’E,20’R,21’R,24’S) -2-)[(2S)-butan-2-yl]-21',24'-dihydroxy-12'-[(2R,4S,5S,6S)-4-methoxy -5-[(2S,4S,5S,6S)-4-methoxy-6-methyl-5-(methylamino)oxan-2-yl]oxy -6-methyloxan-2-yl] oxy-3,11',13',22'-tetramethylspiro[2,3-dihydropyran-6,6'-3,7,19-trioxatetracyclo[15.6.1.14,8.020,24] pentacosa-10,14,16,22-tetraene]-2'-one,

C14 indoxacarb: methyl (4aS)-7-chloro-2-[methoxycarbonyl-[4-(trifluoromethoxy) phenyl]carbamoyl]-3,5-dihydroindeno[1,2 e][1,3,4]oxadiazine-4a-carboxylate,

C15 novaluron: N-[[3-chloro-4-[1,1,2-trifluoro-2-(trifluoromethoxy)ethoxy]phenyl]carbamoyl]-2,6-difluorobenzamide,

C16 spirotetramat: [3-(2,5-dimethylphenyl)-8-methoxy-2-oxo-1-azaspiro[4.5]dec-3-en-4-yl] ethyl carbonate,

C17 spiromesifen: [2-oxo-3-(2,4,6-trimethylphenyl)-1-oxaspiro[4.4]non-3-en-4-yl] 3,3-dimethylbutanoate,

C18 pyriproxyfen: 2-[1-(4-phenoxyphenoxy)propan-2-yloxy]pyridine,

C19 acetamiprid: N-[(6-chloropyridin-3-yl)methyl]-N’-cyano-N-methylethanimidamide,

C20 clothianidin: 1-[(2-chloro-1,3-thiazol-5-yl)methyl]-3-methyl-2-nitroguanidine,
C21 thiamethoxam: (NE)-N-[3-[(2-chloro-1,3-thiazol-5-yl)methyl]-5-methyl-1,3,5-oxadiazinan-4-ylidene]nitramide,

C22 dinotefuran: 1-methyl-2-nitro-3-(oxolan-3-ylmethyl)guanidine,

C23 spinosad: mixture of 50–95% (2R,3aS,5aR,5bS,9S,13S,14R,16aS,16bR) -2- [(6-deoxy-2,3,4-tri-O-methyl-a-L-mannopyranosyl)oxy] -13- {[4-(dimethylamino)-2,3,4,6-tetradeoxy-ß-D-erythropyranosyl]oxy} -9- ethyl 2,3,3a,5a,5b,6,7,9,10,11,12,13,14,15,16a,16b-hexadecahydro-14-methyl-1H-as-indaceno[3,2-d]oxacyclododecine-7,15-dione and 50–5% (2S,3aR,5aS,5bS,9S,13S,14R,16aS,16bS) -2- [(6-deoxy-2,3,4-tri-O-methyl-a-L-mannopyranosyl)oxy] -13- {[4-(dimethylamino)-2,3,4,6-tetradeoxy-ß-D-erythropyranosyl]oxy} -9- ethyl 2,3,3a,5a,5b,6,7,9,10,11,12,13,14,15,16a,16b- hexadecahydro -4,14-dimethyl- 1H-as-indaceno[3,2-d] oxacyclododecine-7,15-dione,

C24 spinetoram: (2R,5R,9R,10S,14R,15S,19S)-15-[(2R,5S,6R)-5-(dimethylamino)-6-methyloxan-2-yl]oxy -7- [(2R,3R,4R,5S,6S)-4-ethoxy-3,5-dimethoxy-6-methyloxan-2-yl]oxy-19-ethyl -14- methyl-20 oxatetracyclo[10.10.0.02,10.05,9] docos-11-ene-13,21-dione,

C25 bifenthrin: (2-methyl-3-phenylphenyl)methyl (1R,3R)-3-[(Z)-2-chloro-3,3,3-trifluoroprop-1-enyl] -2,2- dimethylcyclopropane-1 carboxylate,

C26 fenpropathrin: [cyano-(3-phenoxyphenyl)methyl] 2,2,3,3-tetramethylcyclopropane-1-carboxylate,

C27 deltamethrin: [(S)-cyano-(3-phenoxyphenyl)methyl] (1R,3R)-3-(2,2-dibromoethenyl)-2,2-dimethylcyclopropane-1-carboxylate,

C28 beta cyfluthrin: [(R)-cyano-(4-fluoro-3-phenoxyphenyl)methyl] (1S)-3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropane-1-carboxylate,

C29 triflumezopyrim: 4-oxo-1-(pyrimidin-5-ylmethyl)-3-[3-(trifluoromethyl)phenyl]pyrido[1,2-a]pyrimidin-1-ium-2-olate,

C30 flupyrimin: N-[1-[(6-chloropyridin-3-yl)methyl]pyridin-2-ylidene]-2,2,2-trifluoroacetamide,

C31 cartap hydrochloride: S-[3-carbamoylsulfanyl-2-(dimethylamino)propyl] carbamothioate;hydrochloride,

C32 thiocyclam hydrogen oxalate: N,N-dimethyltrithian-5-amine;oxalic acid,

C33 spirodiclofen: [3-(2,4-dichlorophenyl)-2-oxo-1-oxaspiro[4.5]dec-3-en-4-yl] 2,2-dimethylbutanoate,

C34 spiropidion: [3-(4-chloro-2,6-dimethylphenyl)-8-methoxy-1-methyl-2-oxo-1,8-diazaspiro[4.5]dec-3-en-4-yl] ethyl carbonate,

C35 spidoxamat: 2-(4-chloro-2,6-dimethylphenyl)-1-hydroxy-9,12-dioxa-4-azadispiro[4.2.48.25]tetradec-1-en-3-one,

C36 azadirachtin: dimethyl (1S,4S,5R,6S,7S,8R,11S,12R,14S,15R)-12-acetyloxy-4,7-dihydroxy-6-[(1S,2S,6S,8S,9R,11S)-2-hydroxy-11-methyl-5,7,10-trioxatetracyclo[6.3.1.02,6.09,11]dodec-3-en-9-yl]-6-methyl-14-[(E)-2-methylbut-2-enoyl]oxy-3,9dioxatetracyclo[6.6.1.01,5.011,15]pentadecane-4,11-dicarboxylate,

C37 clofentazine: 3,6-bis(2-chlorophenyl)-1,2,4,5-tetrazine,
C38 cyflumetofen: 2-methoxyethyl 2-(4-tert-butylphenyl)-2-cyano-3-oxo-3-[2-(trifluoromethyl) phenyl]propanoate,

C39 bifenazate: propan-2-yl N-(2-methoxy-5-phenylanilino) carbamate,

C40 flometoquin: [2-ethyl-3,7-dimethyl-6-[4-(trifluoromethoxy)phenoxy]quinolin-4-yl] methyl carbonate, and

C41 tebufenoazide: N-tert-butyl-N'-(4-ethylbenzoyl)-3,5-dimethylbenzohydrazide.

Further, the ternary insecticidal composition provides broad spectrum synergistic control i.e. grams of active ingredients required are less to achieve the desired level of control of insects-pests (caterpillars, sucking pets) and mites with one shot application. Moreover, it provides residual control i.e. longer duration of control with immediate crop protection and showcases the delay in development of resistance and effective control of hard to kill and resistant insect-pests and mites.

Furthermore, the ternary insecticidal composition increases yield of treated plants (cereals, pulses, oilseeds, fiber crop, sugar crops, leafy vegetables, tuber crops, fruit crops, flowers, ornamentals, etc). The ternary insecticidal composition increases yield due to greater number of tillers, more branches and sub branches, flowers and fruits as well as increases plant vigor and tolerance against insect-pests and mites damage.

The present invention optionally comprises agrochemically acceptable excipients and hence, those skilled in the art will appreciate that it is possible to utilize additional agrochemically acceptable excipients without departing from the scope of the present invention. The agrochemically acceptable excipient can be in the range from 0.1% to 99% of the total weight of the composition.
The amount of a composition according to the invention to be applied, will depend on various factors, such as the subject of the treatment, such as, for example plants, soil or seeds; the type of treatment, such as, for example spraying, dusting or seed dressing; the purpose of the treatment, such as, for example prophylactic or therapeutic disease control; or the application time. This amount of the combinations of the present invention to be applied can be readily deduced by a skilled agronomist.

The combination of the present invention is formulated in a manner which suits the specific application. The formulation is selected from Capsule suspension (CS), Dispersible concentrate (DC), Emulsifiable concentrate (EC), Emulsion, water in oil (EO), Emulsion, oil in water (EW), Jambo balls or bags (bags in water soluble pouch), Micro-emulsion (ME), Oil dispersion (OD), Oil miscible flowable concentrate (oil miscible suspension (OF), Oil miscible liquid (OL), Suspension concentrate (SC), Suspo-emulsion (SE), Soluble concentrate (SL), Wettable granule/Water dispersible granule (WG/WDG), Water soluble granule (SG), Water soluble powder (SP), Wettable powder (WP), A mixed formulation of CS and SC (ZC), A mixed formulation of CS and SE (ZE), a mixed formulation of CS and EW (ZW), Granule (GR) / Soil Applied Granules (SAG), Controlled release granules (CR).

More particularly, the composition is selected from Oil dispersion (OD), Suspo Emulsion (SE), Suspension Concentrate (SC), Water Dispersible Granule/ Wettable Granule (WG/WDG) and a mixed formulation of capsule suspension CS and SC (ZC).

The inactive excipients used in various formulations are as follows:

A. List of inactive excipients used in the ZC formulation [mixed formulation of CS+SC]:
The mixed formulation (ZC) of the present invention comprises agrochemically acceptable excipients including, but not limited to, wall forming material(s) 1, wall forming material(s) 2, dispersing agent(s), wetting agent(s), wetting-spreading-penetrating agent(s), solvent(s), thickner(s), suspending agent(s), antifoaming agent(s), antifreezing agent(s), preservative(s) and buffering agent(s).

The wall forming material 1 of ZC is selected from, but not limited to, tetramethylene diisocyanate, pentamethylene diisocyanate, hexamethylene di-isocyanate, toluene di-isocyanate, 4,4’-diphenylmethane diisocyanate (MDI), polymethylene polyphenylene isocyanate, 2,4,4’-diphenyl ether tri-isocyanate, 3,3’-dimethyl-4,4’-diphenyl diisocyanate, 3,3’-dimethoxy-4,4’-diphenyl diisocyanate, 1,5-naphthylene diisocyanate, 4,4’4"-triphenylmethane tri-isocyanate, toluene diisocyanate or polymethylene polyphenylisocyanate, polyurethane comprising of polyfunctional iso cyanate and a polyamine in polarized form or mixture thereof.

The wall forming material 2 of ZC is selected from, but not limited to, diethylene triamine, ammonia, hexamine, ethylenediamine, propylene-1,3-diamine, tetramethylenediamine, pentamethylenediamine, 1,6-hexamethylenediamine, diethylenetriamine, triethylenetetramine, tetra ethylene pentamine, pentaethylenehexamine, 4,9-dioxadodecane-1, 12-diamine, 1,3- phenylenediamine, 2,4- and 2,6-toluenediamine and 4,4’-diaminodiphenylmethane, 1,3-phenylenediamine, 2,4- and 2,6-toluenediamine, 4,4'-diaminodiphenylmethane, 1,5-diaminonaphthalene, 1,3,5-triaminobenzene, 2,4,6-triaminotoluene, 1,3,6-triaminonaphthalene, 2,4,4'-triaminodiphenyl ether, 3,4,5-triamino-1,2,4-triazole, 1,4,5,8-tetraminoanthraquinone or mixture thereof.

The dispersing agent of ZC is selected from, but not limited to, acrylic graft copolymer, sodium naphthalene sulphonate formaldehyde condensate, ethoxylated lignosulfonic acid salts, lignosulfonic acid salts, oxidized lignins, lignin salts, salts of styrenemaleic anhydride copolymers, polyvinyl alcohol, salts of partial esters of styrene-maleic anhydride copolymers, partial salts of polyacrylic acid and partial salts of polyacrylic acid terpolymers. The surfactant is lignosulfonate of calcium or sodium or mixtures thereof or a modified kraft lignin with a high sulfonic acid group, dibutylnaphthalenesulfonic acid, fatty acids, alkyl and alkylarylsulfonates, alkyl sulfates, lauryl ether sulfates and fatty alcohol sulfates, and salts of sulfated hexa, hepta and octadecanols and of fatty alcohol glycol ethers, condensates of sulfonated naphthalene and its derivatives with formaldehyde, condensates of naphthalene or of the naphthalenesulfonic acids with phenol and formaldehyde, polyoxyethylene octylphenol ether, ethoxylated isooctyl, octyl or nonylphenol, alkyl phenyl polyglycol ethers, tributyl phenyl polyglycol ethers, alkyl aryl polyether alcohols, is tridecyl alcohol, fatty alcohol/ethylene oxide condensates, ethoxylated castor oil, polyoxyethylene alkyl ethers or polyoxypropylene alkyl ethers, lauryl alcohol polyglycol ether acetate, sorbitol esters, lignin-sulphite waste liquors, and proteins, denatured proteins, polysaccharides, ammonium salts of sulfonates, sulfates, phosphates or carboxylates, alkylarylsulfonates, diphenyl sulfonates, alpha-olefin sulfonates, sulfonates of fatty acids and oils, sulfonates of ethoxylated alkylphenols, sulfonates of condensed naphthalene, sulfonates of dodecyl and tridecyl benzenes, sulfonates of naphthalene and alkylnaphthalenes, sulfosuccinates or sulfosuccinates, alkoxylates, N-alkylated fatty acid amides, amine oxides, esters or sugar-based surfactants, alkylphenols, amines (e.g. tallow amine), amides, aryl phenols, fatty acids or fatty acid esters which have been alkoxylated. Ethylene oxide and/or propylene oxide may be employed for the alkoxylation, preferably ethylene oxide, polyethylene oxide and polypropylene oxide, polyacids or polybases or mixture thereof.

The wetting agent of ZC is selected from, but not limited to, ethylene oxide/propylene oxide block copolymer, polyarylphenyl ether phosphate, ethoxylated fatty alcohol, sodium dioctyl sulfosuccinate, sodium lauryl sulphate, sodium dodecyl benzene sulfonate, alkyl diphenyl sulfonates, sodium isopropyl naphthalene sulfonate, alkyl naphthalene sulfonate, octyl phenol ethoxylate, alkyl phenol ethoxylate or mixture thereof.

The wetting-spreading-penetrating agent of ZC is selected from, but not limited to, organosilicone surfactants, trisiloxane ethoxylate, polydimethylsiloxane, polyoxyethylene methyl polysiloxane, polyoxyalkylene methyl polysiloxane, polyether polymethyl siloxane copolymer, heptamethyl trisiloxane, polyalkyleneoxide modified heptamethyl trisiloxane, polyether modified polysiloxane, 10 mole ethylene oxide adduct of octylphenol, may or may not be in modified form, may be liquid or powder form or mixture thereof.

The solvent of ZC is selected from, but not limited to, hydrocarbon solvent such a an aliphatic, cyclic and aromatic hydrocarbons (for example toluene, xylene, paraffin, tetrahydronaphthalene, alkylated naphthalene or their derivatives, mineral oil fractions of medium to high boiling point (such as kerosene, diesel oil, coal tar oils)); a vegetable oil such as corn oil, rapeseed oil; a fatty acid ester such as C1-C10-alkylester of a C10-C22-fatty acid; or, methyl or ethyl esters of vegetable oils such as rapeseed oil methyl ester or corn oil methyl ester, acetophenone, 2-heptanon, 3-heptanone, 2-hexanone, 5-methyl-2-hexanone, 5-methyl-3-heptanone, 3-methyl-2-hexanone, 4-methyl-2-hexanone, 2-methyl-3-hexanone, 4-methyl-3-hexanone, 5-methyl-3-hexanone, 3-ethyl-2-pentanone, 3,3-dimethyl-2-pentanone, 3,4-dimethyl-2-pentanone, 4,4-dimethyl-2-pentanone, 2,2-dimethyl-3-pentanone, 2,4-dimethyl-3-pentanone, 2-octanone, 2,5-dimethyl-3-hexanone, 2,2-dimethyl-3-hexanone, 3,3-dimethyl-2-hexanone, 3,4-dimethyl-2-hexanone, 4,4-dimethyl-3-hexanone, 3-ethyl-4-methyl-2-pentanone, 2-methyl-3-heptanone, 2-methyl-4-heptanone, 3-methyl-2-heptanone, 3-methyl-4-heptanone, 5-methyl-3-heptanone, 6-methyl-2-heptanone, 6-methyl-3-heptanone, 3-octanone, 4-octanone, 2,2,4-trimethyl-3-pentanone, 3-ethyl-3-methyl-2-pentanone, 5-methyl-2-heptanone, isoprene or mixture thereof.

The thickener of ZC is selected from, but not limited to, xanthan gum, carboxy methyl cellulose, attapulgite clay, bentonite clay or mixture thereof.

The suspending agent of ZC is selected from, but not limited to, aluminium magnesium silicate, bentonite clay, silica, attapulgite clay or mixture thereof.

The antifoaming agent of ZC is selected from, but not limited to, silicone oil, silicone compound, C10~C20 saturated fat acid compounds or C8~C10 aliphatic alcohols compound, silicone antifoam emulsion, dimethyl siloxane, polydimethyl siloxane, vegetable oil based antifoam, tallow based fatty acids, polyalkyleneoxide modified polydimethylsiloxane or mixture thereof.

The antifreezing agent of ZC is selected from, but not limited to, ethylene glycol, propane diols, glycerine or the urea, glycol (monoethylene glycol, diethylene glycol, polypropylene glycol, polyethylene glycol), glycerine, urea, magnesium sulphate heptahydrate, sodium chloride or mixture thereof.

The preservative of ZC is selected from, but not limited to, 1,2-benzisothiazolin-3(2H)-one, sodium salt, sodium benzoate, 2-bromo-2-nitropropane-1,3-diol, formaldehyde, sodium o-phenyl phenate, 5-chloro-2-methyl-4-isothiazolin-3-one, 2-methyl-4-isothiazolin-3-one or mixture thereof.

The buffering agent of ZC is selected from, but not limited to, sodium hydroxide, potassium hydroxide, acetic acid, sulphuric acid, hydrochloric acid, ortho phosphoric acid, ammonium hydroxide or mixture thereof.

The emulsifier of ZC is selected from, but not limited to, alkylbenzene sulfonate calcium salts, tristyrylphenol polyethoxyester phosphate or mixture thereof.

Manufacturing process for mixed formulation ZC:

Step 1: The aqueous phase - Charged water is added to a stainless steel vessel equipped with a high speed stirrer. The wetting agent(s), dispersing agent(s) 1 and dispersing agent(s) 2 is/are added into the vessel under agitation followed by the addition of 50% quantity of antifoam to avoid foam generation in this vessel.

Step 2: The organic phase - Charged heavy aromatic hydrocarbons solvent is added into second stainless-steel reactor followed by the addition of melted active ingredient into the reactor slowly. Afterwards, the wall forming material(s) 1 is/are charged to the reactor while mixing it. At last, the contents of the reactor are cooled down to room temperature.

Step 3: The high shear disperser of aqueous phase is initiated and the ‘organic solution’ is charged into the ‘aqueous phase solution’ under gravity at a specific rate to achieve the required particle size followed by shearing for 30 min. Initiate the reactor to heat around 50 °C by stirring the formulation under slow rpm for 3-4 hours for the completion of polymerization reaction

Step 4: The wall forming material(s) 2 is/are added so that the residual wall forming material(s) 1 can be consumed. Stir the same for 1 hour at the same temperature. Upon requirement, half quantity of the antifoam can be added to remove foam generation caused due to CO2 during the reaction.

Step 5: Upon the completion of wall polymerization reaction, the agitator’s speed is increased. The remaining half quantity of the antifoam(s) is/are added to the formulation. The mixture is allowed to de-gas for approximately 30 minutes to remove CO2 from the solution under slight vacuum. The linear polysaccharide(s), preservative(s) and at last freezing agent(s) is/are added and mixed for few minutes. At last, buffering agent(s) is/are added for pH adjustment and mixed well.

Step 6: The final product is sent for the approval of QC.

Step 7: Upon the approval, the material is packed in its required pack sizes.

B. List of inactive excipient used in the Oil dispersion (OD) formulation:

The Oil Dispersion formulation (OD) of the present invention comprises agrochemically acceptable excipients including, but not limited to, wetting agent(s), wetting-spreading-penetrating agent(s), emulsifying agent(s), dispersing agent(s), stabilizer(s), antifoaming agent(s), antifreezing agent(s), solvent(s), preservative(s) and co solvent(s).

The emulsifier of OD is selected from, but not limited to, polyoxyethylene sorbitol hexaoleate, ethoxylated sorbitan ester, castor oil ethoxylates, alcohol ethoxylates, fatty acid ethoxylates, sorbitan ester ethoxylates, sulphosuccinate, calcium salts of dodecylbenzene sulphonate, alkylammonium salts of alkylbenzene sulphonate, alkylsulphosuccinate salts, ethylene oxide-propylene oxide block copolymers, ethoxylated alkylamines, ethoxylated alkyl phenols and polyoxyethylene sorbitan monolaurate or mixture thereof.

The wetting agent of OD is selected from, but not limited to, ethylene oxide/propylene oxide block copolymer, polyarylphenyl ether phosphate, ethoxylated fatty alcohol, sodium dioctyl sulfosuccinate, sodium lauryl sulfate, sodium dodecyl benzene sulfonate, alkyldiphenyl sulfonates, sodium isopropyl naphthalene sulfonate, alkylnaphthalene sulfonate or mixture thereof.

The wetting-spreading-penetrating agent of OD is selected from, but not limited to, organosilicone surfactants, trisiloxane ethoxylate, polydimethylsiloxane, polyoxyethylene methyl polysiloxane, polyoxyalkylene methyl polysiloxane, polyether polymethyl siloxane copolymer, heptamethyl trisiloxane, polyalkyleneoxide modified heptamethyl trisiloxane, polyether modified polysiloxane, may or may not be in modified form, may be liquid or powder form or mixture thereof.

The dispersing agent of OD is selected from, but not limited to, salts of polyolefin condenstaes, styrene acrylic polymer, alkyl sulfonates, alkyl benzene sulfonates, alkyl aryl sulfonates, alkylphenolalkoxylates, tristyrylphenol ethoxylates, natural or synthetic fatty ethoxylate alcohols, natural or synthetic fatty acid alkoxylates, natural or synthetic fatty alcohols alkoxylates, alkoxylated alcohols (such as n-butyl alcohol poly glycol ether), block copolymers (such as ethylene oxide-propylene oxide block copolymers and ethylene oxide-butylene oxide block copolymers), fatty acid-polyalkylene glycol condensates, polyamine-fatty acid condensates, polyester condensates, salts of polyolefin condensates, sodium ligno sulfonate, sodium ploycarboxylate, EO/PO based copolymer, phenol sulfonate, sodium methyl oleoyl taurate, styrene acrylic acid copolymer, propyleneoxide-ethyleneoxide-copolymer, polyethylene glycol 2,4,6-tristyrylphenyl ether, tristyrylphenol-polyglycolether-phosphate, tristyrylphenole with 16 moles EO, tristyrylphenol-polyglycolether-phosphate, oleyl-polyglycolether with ethylene oxide, tallow fattyamine polyethylene oxide, nonylphenol polyglycolether with 9-10 moles ethylene oxide or mixture thereof.

The stabilizer of OD is selected from, but not limited to, hectorite clay, aluminium magnesium silicate, bentonite clay, silica, attapulgite clay or mixture thereof.

The antifoaming agent of OD is selected from, but not limited to, silicone oil, silicone compound, C10~C20 saturated fat acid compounds or C8~C10 aliphatic alcohols compound, silicone antifoam emulsion, dimethylsiloxane, polydimethyl siloxane, vegetable oil based antifoam, tallow based fatty acids and polyalkyleneoxide modified polydimethylsiloxane or mixture thereof.
The anti-freezing agent of OD is selected from, but not limited to, ethylene glycol, propane diols, glycerine or the urea, glycol, monoethylene glycol, diethylene glycol, polypropylene glycol, polyethylene glycol, glycerine, urea, magnesium sulfate heptahydrate and sodium chloride or mixture thereof.

The preservative of OD is selected from, but not limited to, 1,2-benzisothiazolin-3(2H)-one, sodium salt, sodium benzoate, 2-bromo-2-nitropropane-1,3-diol, formaldehyde, sodium o-phenylphenate, 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin-3-one or mixture thereof.

The solvent of OD is selected from, but not limited to, vegetable oil (plant, seed or tree) or its alkylated or ethoxylated or esterified. The alkylated vegetable oil may be methylated vegetable oil or ethylated vegetable oil. The vegetable oils include olive oil, kapok oil, castor oil, papaya oil, camellia oil, sesame oil, corn oil, rice bran oil, cotton seed oil, soybean oil, groundnut oil, rapeseed-mustard oil, linseed oil, tung oil, sunflower oil, safflower oil, coconut oil. The alkyl ester of vegetable oils includes methyl ester, ethyl ester, propyl ester or butyl ester of vegetable oils. Some of the examples are methylated seed oil, polyalkyleneoxide modified polydimethylsiloxane alkylphenol ethoxylate, rapeseed oil methyl ester, rapeseed oil ethyl ester, rapeseed oil propyl esters, rapeseed oil butyl esters, soybean oil methyl ester, soybean oil ethyl ester, soybean oil propyl ester, soybean oil butyl ester, castor oil methyl ester, castor oil ethyl ester, castor oil propyl ester, castor oil butyl ester, cotton seed oil methyl ester, cotton seed oil ethyl ester, cotton seed oil butyl ester, cotton seed oil propyl ester, tall oil fatty acids esters-tallow methyl ester, tallow ethyl ester, tallow propyl ester, bio-diesel, mineral oil (aromatic solvents, isoparaffin, base solvent), fatty acid amides (for example C1-C3 amines, alkylamines or alkanolamines with C6–C18 carboxylic acids), fatty acids, alkyl esters of fatty acids, methyl and ethyl oleate, methyl, ethyl soyate, alkyl benzenes, alkylnaphthalenes, polyalkylene glycol ethers, fatty acid diesters, fatty alkylamides and diamides, dialkylene carbonates, ketones and alcohols. The above oil based carrier/diluting agents may be used as solo or mixture of two or more if desired.

The Co solvent of OD is selected from, but not limited to, cyclohexanone, acetophenone, NMP, dimethyl sulfoxide, benzyl alcohol, butanol, N-octanol, N-propanol, 2-ethyl hexanol, tetrahydro furfuryl alcohol, isophorone, fatty acid dimethyl amide, 2-hexylethyl lactate, propylene carbonate or mixture thereof.

The Rheology modifier of OD is selected from, but not limited to, bentonite clay.

Manufacturing process for Oil dispersion (OD) formulation:

Part A-Preparation of the liquid premix (OD)
Step 1: The vegetable oil or solvent or both are charged into a vessel with an anchor stirrer.
Step 2: The emulsifier(s) and dispersing agent(s) are added under stirring condition until all the ingredients get completely dissolved.

Part B-Preparation of the slurry (OD)

Step 1: The liquid premix is charged into a second vessel which is equipped with a cooling and heating device of a high shear stirrer.
Step 2: The active ingredients are added and homogenized thoroughly. The mixture is pre-milled and a particle size distribution is achieved by the final milling, practised along with a bead mill as required by the specification.

Part C-Preparation of the Thickener gel (OD)

Step 1: The vegetable/plant/seed oil or solvent is charged to the vessel which is equipped with a high shear stirrer.
Step 2: The thickener(s) is/are gradually added throughout by mixing and maintaining high-shear. The stirring is continued until thoroughly mixed.
Step 3: The thickener activating agent(s) is/are added under stirring condition. Further, the gel is allowed to get swell whilst maintaining the mixing.

Part D-Preparation of the final formulation (OD)

Step 1: The thickener gel is added and the mixture is dispersed by using a high shear stirrer.
Step 2: The recommended wetting and spreading agent(s) or adjuvant(s) (silicone or non-silicone based) are finally added to this formulation and dispersed by using high shear stirrer.
Step 3: The finished formulation is checked with specification.
Step 4: The material is packed in its required package sizes when approved.

C. Lists of inactive excipients used in Suspension Concentrate (SC) formulation:

The Suspension Concentrate formulation (SC) of the present invention comprises agrochemically acceptable excipients including, but not limited to, wetting agent(s), wetting-spreading-penetrating agent(s), dispersing agent(s), suspending agent(s), antifoaming agent(s), antifreezing agent(s), preservative(s), thickener(s) and humectants(s).

The wetting agent of SC is selected from, but not limited to, ethylene oxide/propylene oxide (EO/PO) block copolymer, poly aryl phenyl ether phosphate, polyalkoxylated butyl ether, ethoxylated fatty alcohol, sodium dioctyl sulfosuccinate, sodium lauryl sulfate, sodium dodecyl benzene sulfonate, alkyl diphenyl sulfonates, sodium isopropyl naphthalene sulfonate, alkyl naphthalene sulfonate. Ethoxylated alcohol includes natural fatty alcohol (lauryl alcohol ethoxylate, lauryl alcohol alkoxylate), synthetic alcohol ethoxylate (tridecyl alcohol ethoxylate, 2-ethyl hexanol, 2-propylheptanol, isodecyl alcohol) or mixture thereof.

The wetting-spreading-penetrating agent of SC is selected from, but not limited to, methylated seed oil, polyalkyleneoxide modified trisiloxane, trisiloxane ethoxylate, heptamethyl trisiloxane, modified form includes polyalkyleneoxide modified heptamethyl trisiloxane, polyether modified polysiloxane, polyalkyleneoxide modified trisiloxane, polyalkyleneoxide modified polydimethylsiloxane, may be liquid or powder form or mixture thereof.

The dispersing agent of SC is selected from, but not limited to, ethylene propylene oxide block copolymer, sodium naphthalene sulphonate formaldehyde condensates, naphthalenesulfonic acid, sodium salt condensate with formaldehyde, alkylated naphthalene sulfonate, sodium salt, sodium salt of naphthalene sulfonate condensate, sodium ligno sulfonate, sodium polycarboxylate, EO/PO based copolymer, phenol sulfonate, sodium methyl oleoyl taurate, styrene acrylic acid copolymer, propylene oxide-ethylene oxide-copolymer, polyethylene glycol 2,4,6-tristyrylphenyl ether, tristyrylphenol-polyglycol ether-phosphate, tristyrylphenole with 16 moles EO, tristyrylphenol-polyglycol ether-phosphate, oleyl-polyglycol ether with ethylene oxide, tallow fatty amine polyethylene oxide, nonylphenol polyglycol ether with 9-10 moles ethylene oxide or mixture thereof.

The suspending agent of SC is selected from, but not limited to, aluminum magnesium silicate, bentonite clay, silica and attapulgite clay or mixture thereof.

The antifoaming agent of SC is selected from, but not limited to, silicone antifoam emulsion, dimethyl siloxane, polydimethyl siloxane, vegetable oil based antifoam and tallow based fatty acids or mixture thereof.

The anti-freezing agent of SC is selected from, but not limited to, ethylene glycol, propane diols, glycerin or the urea, glycol (monoethylene glycol, diethylene glycol, polypropylene glycol, polyethylene glycol), glycerin, urea, magnesium sulfate heptahydrate, sodium chloride or mixture thereof.

The preservative of SC is selected from, but not limited to, 1,2-benzisothiazolin-3(2H)-one, sodium salt, sodium benzoate, 2-bromo-2-nitropropane-1,3-diol, formaldehyde, sodium o-phenyl phenate, 5-chloro-2-methyl-4-isothiazolin-3-one, 2-methyl-4-isothiazolin-3-one or mixture thereof.

The thickener of SC is selected from, but not limited to, xanthan gum, PVK, carboxymethyl celluloses, polyvinyl alcohols, gelatin, sodium carboxymethylcellulose, hydroxyethyl cellulose, sodium polyacrylate, modified starch, acacia gum or mixture thereof.

The humectant of SC is selected from, but not limited to, urea, humic acid, glycerol, lactose or mixture thereof.

Manufacturing process for Suspension Concentrate (SC) formulation:

Step 1: Gel preparation: A required quantity of water is charged to a vessel which is equipped with a high shear stirrer whilst the agitation is initiated. A required amount of preservative(s) is/are added and mixed to form a homogenous mixture. A required amount of thickener(s) is/are added and mixed vigorously to achieve wetness.

Step 2: A required quantity of water is charged to a vessel which is equipped with a bulk agitator and a high shear homogenizer; initiated the agitation. Further, a required amount of an anti freezing agent(s) is/are added and mixed to achieve uniformity. Moreover, the antifoaming agent(s) is/are added whilst ensuring that it is well dispersed. The wetting and dispersing agent(s) is/are added and mixed to achieve uniformity whilst ensuring that the dispersing agent(s) is/are fully dispersed.

Step 3: The active ingredients are added and the agitation of the vessel contents are continued until all the components get dissolved. The pre-mix is milled through a colloid mill and subsequently through a dyno mill to meet the specified particle size.

Step 4: The remaining antifoaming agent(s) is/are added to this SC mill base to a vessel which is equipped with the bulk agitator and mixed to achieve uniformity. The required amount of 2% aqueous pre-gel and suspending agent(s) is/are added and the agitation is continued until the formulation is homogeneous and has reached the target viscosity.

Step 5: The final product is submitted for QC’s approval.

Step 6: The material is packed in its required package sizes when received approval.

D. Lists of inactive excipient used in Suspo Emulsion (SE) formulation:

The Suspo Emulsion formulation (SE) of the present invention comprises agrochemically acceptable excipients including, but not limited to, solvent(s), emulsifier(s), stabilizer(s), antifreezing agent(s), antifoaming agent(s), suspending agent(s), wetting agent(s), wetting-spreading-penetrating agent(s), preservative(s), thickener(s), dispersing agent(s), buffering agent(s) and humectants(s).
The solvent of SE is selected from, but not limited to, includes water, water soluble alcohols and dihydroxy alcohol ethers. Water soluble alcohol or lower alcohol (1-4 carbon atoms) includes-methanol, ethanol, n-propanol, isopropanol, n-butanol, tert-butanol. Macromolecular alcohol includes polyethylene glycol, sorbitol, glucitol, dihydroxy alcohol ethers includes dihydroxy alcohol alkyl ether or dihydroxy alcohol aryl ethers. The examples of dihydroxy alcohol alkyl ether include ethylene glycol methyl ether, diethylene glycol methyl ether, propylene glycol methyl ether, di-propylene glycol methyl ether, ethylene glycol ethyl ether, diethylene glycol ethyl ether, propylene glycol ethyl ether, di-propylene glycol ethyl ether. The examples of dihydroxy alcohol aryl ethers include ethylene glycol phenyl ether, 5 diethylene glycol phenyl ether, propylene glycol phenyl ether, di-propylene glycol phenyl ether, and the like. Any of the mentioned solvent can be used either alone or in combinations thereof.

Hyrdocarbons includes n-pentane, hexane(s), cyclohexane, methylcyclohexane, heptane, isooctane, benzene, toluene, xylene(s), isophorone and ester solvents such as methyloleate, dimethylamide and morpholineamide derivatives of C6-C16 fatty acids, and mono-alkylene carbonates such as ethylene carbonate, propylene carbonate and butylene carbonates, dimethylsulfoxide (DMSO), 2-ethylhexanol and n-butanol, n-alkylpyrrolidones, fatty acid dimethyl esters, fatty acid esters, dibasic esters, aromatic hydrocarbons and/or aliphatic hydrocarbons, one or more dimethylamides, such as C8-dimethylamide, C10-dimethylamide, C12-dimethylamide, ethylene glycol, propylene glycol, polyalkylene glycols, aromatic hydrocarbons, methylpyrrolidinone (NMP); dimethylformamide (DMF); dimethylisosorbide (DMI); isophorone; acetophenone; 1,3-dimethyl-2-imidazolidonone; lactate esters; dimethyl and diethylcarbonates; alcohols including methanol; ethanol; iso-propanol; n-propanol; n-butanol; iso-butanol; and tert-butanol; methyl L-lactate, 2-ethylhexyl L-lactate, ethyl L-lactate, n-butyl L-lactate, octyl phenol ethoxylates or mixture thereof.

The Emulsifier of SE is selected from, but not limited to, polyarylphenyl anionic ether sulfate, ammonium salt, emulsifiers containing salts of dodecylbenzene sulphonate, for example Ca-salts or amine salts, and sulphonates of other C11-C16 alkylbenzenes, alkylether sulphates, alkylphenoletherphosphates and ester phosphates; non-ionic surfactants such as alkoxylated alcohols, alkylphenols, ethoxylated fatty acids, ethoxylated vegetable oils, e.g. ethoxylated castor oil, fatty acid esters, e.g. of sorbitol, and their ethoxylated derivatives, ethoxylated amines, and condensates of glycerol; and catanionic emulsifiers such as a cationic amine, optionally in combination with an alkylsulphonate or ether sulphonate or ether phosphate, alkoxylated alcohols; alkoxylated alkylphenols; ethoxylated fatty acids; ethoxylated vegetable oils; ethoxylated tristyrylphenol (tristyrlphenol with 16 moles EO), tristyrylphenol-polyglycolether-phosphate, fatty acid esters of sorbitol and ethoxylated derivatives thereof; ethoxylated amines and condensates of glycerol; sulfonated alkylbenzenes in the range C11-C16 and salts thereof; alkylether sulphates, alkyletherphosphates, alkylphenoletherphosphates; or combinations thereof; salts of phosphate esters of ethoxylated tristyrylphenol; salts of sulphated ethers of ethoxylated tristyrylphenol or a catanionic system, wherein a cationic amine is present in combination with an alkylsulphonate, an alkylethersulphonate, an ether sulphate, or an ether phosphate such as an alkyletherphosphate, nonylphenol polyethoxy ethanols, castor oil polyglycol ethers, polyadducts of ethylene oxide and polypropylene, tributyl phenoxy polyethoxy ethanol, octyl phenoxy polyethoxy ethanol or mixture thereof.

The Stabilizer of SE is selected from, but not limited to, butylated hydroxytoluene (BHT), epoxidized soybean oil (ESBO) and epichlorhydrin or mixture thereof.

The Anti-freezing agent of SE is selected from, but not limited to, ethylene glycol, propane diols, glycerine or the urea, glycol (monoethylene glycol, diethylene glycol, polypropylene glycol, polyethylene glycol), glycerine, urea, magnesium sulfate heptahydrate, sodium chloride or mixture thereof.

The Antifoaming agent of SE is selected from, but not limited to, silicone oil, silicone compound, C10~C20 saturated fat acid compounds or C8~C10 aliphatic alcohols compound, silicone antifoam emulsion, dimethylsiloxane, polydimethyl siloxane, vegetable oil based antifoam, tallow based fatty acids, polyalkyleneoxide modified polydimethylsiloxane or mixture thereof.

The Suspending agent of SE is selected from, but not limited to, aluminum magnesium silicate, bentonite clay, silica silicone dioxide, attapulgite clay or mixture thereof.

The Wetting agent of SE is selected from, but not limited to, ethylene oxide/propylene oxide block copolymer, polyarylphenyl ether phosphate, ethoxylated fatty alcohol, sodium dioctyl sulfosuccinate, sodium lauryl sulphate, sodium dodecyl benzene sulfonate, alkyl diphenyl sulfonates, sodium isopropyl naphthalene sulfonate, alkyl naphthalene sulfonate, octyl phenol ethoxylate, alkyl phenol ethoxylate or mixture thereof.

The Wetting-spreading-penetrating agent of SE is selected from, but not limited to, organosilicone surfactants includes trisiloxane ethoxylate, polydimethylsiloxane, polyoxyethylene methyl polysiloxane, polyoxyalkylene methyl polysiloxane, polyether polymethyl siloxane copolymer, heptamethyl trisiloxane, polyalkyleneoxide modified heptamethyl trisiloxane, heptamethyl trisiloxane ethoxylate, polyether modified polysiloxane, 10 mole ethylene oxide adduct of octylphenol, may or may not be in modified form, may be liquid or powder form or mixture thereof.

The Preservative of SE is selected from, but not limited to, propionic acid and its sodium salt, sorbic acid and its sodium or potassium salt, benzoic acid and its sodium salt, p-hydroxy benzoic acid sodium salt; methyl p-hydroxy benzoate; and biocide such as sodium benzoate, 1,2-benzisothiazoline-3(2H)-one, 2-methyl-4-isothiazolin-3-one, 5-chloro-2- methyl-4-isothiazolin-3-one, potassium sorbate, para hydroxy benzoates or mixture thereof.

The Thickeners of SE is selected from, but not limited to, thickening, gelling, and anti-settling agents generally fall into two categories, namely water-insoluble particulates and water-soluble polymers. It is possible to produce suspension concentrate formulations using clays and silicas. Examples of these types of materials, include, but are limited to, montmorillonite, e.g. bentonite; magnesium aluminum silicate; and attapulgite. Water-soluble polysaccharides have been used as thickening-gelling agents for many years. The types of polysaccharides most commonly used are natural extracts of seeds and 15 seaweeds are synthetic derivatives of cellulose or mixtures thereof. Examples of these types of materials include, but are not limited to, guar gum; locust bean gum; carrageenam; xanthan gum; alginates; methyl cellulose; sodium carboxymethyl cellulose (SCMC); hydroxyethyl cellulose (HEC) or mixtures thereof. Other types of anti-settling agents are based on modified starches, polyacrylates, polyvinyl 20 alcohol and polyethylene oxide or mixture thereof.

The Dispersing agent of SE is selected from, but not limited to, can be a conventionally available for example polyesters, polyamides, poly- carbonates, polyurea and polyurethanes, acrylic polymers, acrylic graft copolymer, butyl polyalkylene oxide block copolymer, styrene copolymers, butadiene copolymers, polysaccharides such as starch and cellulose derivatives, vinylalcohol, vinylacetate and vinylpyrrolidone polymers and copolymers, polyethers, epoxy, phenolic and melamine resins, polyolefins and define copolymers and mixtures thereof. Examples of preferred polymers are acrylate polymers such as poly(methacrylate), poly(ethyl methacrylate), poly(methylmethacrylate), acrylate copoylmers and styrene-acrylic copolymers as defined herein below, poly(styrene-co maleic anhydride), cellulosic polymers such as ethyl cellulose, cellulose acetate, cellulose acetatebutyrate, acetylated mono, di, and triglycerides, poly(vinylpyrrolidone), vinyl acetate polymers and copolymers, poly(alkylene glycol), styrene butadiene copolymers, poly(orthoesters), alkyd resins, and mixtures of two or more of these. Polymers that are biodegradable are also useful in the present invention. As used herein, a polymer is biodegradable if is not water soluble, but is degraded over a period of several weeks when placed in an application environment. Examples of biodegradable polymers that are useful in the present invention include biodegradable polyesters, starch, polylactic acid starch blends, polylactic acid, poly(lactic acid-glycolic acid) copolymers, polydioxanone, cellulose esters, ethyl cellulose, cellulose acetate butyrate, starch esters, starch esteraliphatic polyester blends, modified corn starch, polycaprolactone, poly(namylmethacrylate), wood rosin, polyanhydrides, polyvinylalcohol, polyhydroxybutyratevalerate, biodegradable aliphatic polyesters, and polyhydroxybutyrate or mixtures thereof. The examples of dispersing agents are alkylated naphthalene sulfonate, sodium salt, sodium salt of naphthalene sulfonate condensate, sodium salt of alkyl naphthalene sulfonate, sodium ligno sulfonate, sodium ploycarboxylate, EO/PO block copolymer, phenol sulfonate, sodium methyl oleoyl taurate, styrene acrylic acid copolymer, propyleneoxide-ethyleneoxide-copolymer, polyethylene glycol 2,4,6-tristyrylphenyl ether, tristyrylphenol-polyglycolether-phosphate, tristyrylphenole with 16 moles EO, tristyrylphenol-polyglycolether-phosphate, oleyl-polyglycolether with ethylene oxide, tallow fattyamine polyethylene oxide, nonylphenol polyglycolether with 9-10 moles ethylene oxide or mixture thereof.

The Buffering agent of SE is selected from, but not limited to, as used herein is selected from group consisting of citric acid, calcium hydroxyapatite, potassium dihydrogen phosphate, sodium hydroxide, carbonated apatite, calcium carbonate, sodium bicarbonate, tricalcium phosphate, calcium phosphates, carbonated calcium phosphates, amine monomers, lactate dehydrogenase and magnesium hydroxide or mixture thereof.

The Humectant of SE is selected from, but not limited to, urea, humic acid, glycerol and lactose or mixture thereof.

Manufacturing process for Suspo Emulsion (SE) formulation:

Step 1: Gel preparation: A required quantity of water is charged to a vessel which is equipped with a high shear stirrer whilst the agitation is initiated. The required amount of preservative(s) is/are added and mixed to achieve homogeneity. Further, a required amount of thickener(s) is/are added and mixed vigorously to achieve full wetness.

Step 2: Oil phase: The solvent(s) is/are charged into the vessel and then the active is slowly added and if required, it is heated for 50° C so that the active ingredients can be dissolved in the solvent and followed by addition of emulsifier(s).

Step 3: The agitation is initiated when a required quantity of water is charged to a vessel which is equipped with a bulk agitator and a high shear homogenizer. A required amount of anti freezing agent(s) is/are added and mixed to achieve a uniform mixture. The antifoaming agent(s) is/are added and ensured that it is well dispersed. The wetting and dispersing agent(s) is/are added and mixed to achieve uniform mixture and ensured that the dispersing agent is fully dispersed.

Step 4: The active ingredients are added in the vessel and agitated till entire components get dissolved. The pre-mix is milled through a colloid mill and subsequently through a dyno mill to achieve a specified particle size.

Step 5: The remaining antifoaming agent(s) is/are added in the mill base to a vessel which is equipped with bulk agitator and mixed to achieve uniformity.

Step 6: An addition of an oil phase in an aqueous phase is performed and stirred for 30 minutes by using homogenizer.

Step 7: A required amount of aqueous pre-gel and suspending agent(s) are added. A homogenous mixture and a target viscosity are achieved by continuous agitation.

Step 8: The final product is submitted for QC’s approval.

Step 9: The material is packed in its required package sizes when approved.

E. Lists of inactive excipient used in WG (Wettable Granule)/WDG (Water Dispersible Granule) formulation:

The wettable granule/ water dispersible granule formulation (WG/WDG) of the present invention comprises agrochemically acceptable excipients including, but not limited to, dispersing agent(s), wetting agent(s), antifoaming agent(s), carrier(s), disintegrating agent(s) and humectants(s).

The Dispersing agent of WG/WDG is selected from, but not limited to, modified sodium lignosulphonate, modified polyacrylate copolymer, alkylnaphthalene sulfonate sodium salt, sodium polycarboxylate, naphthalene sulfonic acid, sodium salt condensates with formaldehyde, polyalcoxylated alkylphenol, naphthalene sulfonic acid formaldehyde condensate, methyl naphthalene-formaldehyde-condensate sodium salt, naphthalene condensates, lignosulfonates, polyacrylates and phosphate esters, calcium lignosulfonate, lignin sulfonate sodium salt or mixture thereof.

The Wetting agent of WG/WDG is selected from, but not limited to, sodium isopropyl naphthalene sulfonate, sodium N-methyl-N-oleoyl taurate, alkylated naphthalene sulfonate, sodium salt, mixture of isomers of dibutyl naphthalene sulphonic acid sodium salt, sodium di-isopropyl naphthalene sulphonate, sodium lauryl sulfate, dioctyl sulfate, alkyl naphthalene sulfonates, phosphate esters, sulphosuccinates and non-ionic such as tridecyl alcohol ethoxylate, alkyl or alkaryl sulfonates such as alkylbenzene sulfonates, alpha olefin sulfonate and alkyl naphthalene sulfonates, ethoxylated or non-ethoxylated alkyl or alkaryl carboxylates, alkyl or alkaryl phosphate esters, alkyl polysaccharide, di or mono alkyl sulfosuccinate derivatives, alpha olefin sulfonates, alkyl naphthalene sulfonates, dialkyl sulphosuccinates, butyl, dibutyl, isopropyl and di-isopropyl naphthalene sulfonate salts, C12 alkyl benzene sulfonate or C10-C16 alkyl benzene sulfonate, organosilicons surfactants includes trisiloxane ethoxylate, polydimethylsiloxane, polyoxyethylene methyl polysiloxane, polyoxyalkylene methyl polysiloxane, polyether polymethyl siloxane copolymer, trisiloxane heptamethyl, polyalkyleneoxide modified heptamethyl trisiloxane, polyether modified polysiloxane, may or may not be in modified form, may be liquid or powder form or mixture thereof.

The Antifoaming agent of WG/WDG is selected from, but not limited to, polydimethylsiloxane.

The Carrier of WG/WDG is selected from, but not limited to, china clay, silica, lactose anhydrous, ammonium sulfate, sodium sulfate anhydrous, corn starch, urea, EDTA, urea formaldehyde resin, diatomaceous earth, kaolin, bentonite, kieselguhr, fuller's earth, attapulgite clay, bole, loess, talc, chalk, dolomite, limestone, lime, calcium carbonate, powdered magnesia, magnesium oxide, magnesium sulphate, sodium chloride, gypsum, calcium sulphate, pyrophyllite, silicates and silica gels; fertilizers such as, ammonium sulphate, ammonium phosphate, ammonium nitrate; natural products of vegetable origin such as, for example, grain meals and flours, bark meals, wood meals, nutshell meals and cellulosic powders; and synthetic polymeric materials such as, ground or powdered plastics and resins, bentonites, zeolites, titanium dioxide, iron oxides and hydroxides, aluminium oxides and hydroxides, or organic materials such as bagasse, charcoal, or synthetic organic polymers or mixture thereof.

The Disintegrating agent of WG/WDG is selected from, but not limited to, citric acid, succinic acid or sodium bicarbonate or mixture thereof.

The Humectant of WG/WDG is selected from, but not limited to, urea, humic acid, glycerol, lactose or mixture thereof.

Manufacturing process for Wettable granule/ Water Dispersible Granule (WG/ WDG):

Step 1: An exact weight of active ingredients is considered and a required quantity of binder(s) and surfactant(s) is/are added in the blender and mixed to achieve a complete homogenization.

Step 2: The homogenized mixture is milled to achieve required wet sieve and post blended to attain homogeneity.

Step 3: The above described homogenous material is passed through an extruder for granulation.

Step 4: The granules are transferred through fluid bed dryer to remove excess moisture.
Step 5: The granules are transferred to vibro shifter.

Step 6: The final material is collected from the vibro shifter into drum.

Step 7: The sample is sent to QC for an approval.

Step 8: The material is transferred into the different size of drums when received an approval from QC.

EXAMPLES

The present invention has been described with reference to specific embodiment which is merely illustrative and not intended to limit the scope of the invention as defined in the present complete specification.

Biological Examples:

The synergistic pesticide action of the inventive mixtures can be demonstrated by the experiments below. A synergistic effect exists wherever the action of a combination (ready-mix) or tank mix of active ingredient is greater than the sum of the action of each of the components alone. Therefore, a synergistically effective amount or an effective amount of a synergistic composition or combination is an amount that exhibits greater pesticide activity than the sum of the pesticide activities of the individual components.

In the field of agriculture, it is often understood that the term “synergy” is as defined by Colby S.R. in an article entitled “ Calculation of the synergistic and antagonistic responses of herbicide combinations” published in the journal Weeds, 1967, 15, p.20-22, incorporated herein by reference in its entirety. The action expected for a given combination of two or three active components can be calculated as follows:

The objective of the present invention is to study the synergism and benefits of present compositions.

Example 1: Bio efficacy against insect-pests infesting chilli crop
Crop : Chilli
Location : Umreth, Gujarat
Number of Treatments : 24
Plot size : 50 sq.m. (m2)
Crop stage : 80 days after transplanting.
Method of application : foliar spray with battery operated backpack sprayer.
Water volume : 485 liter per hectare

Observation Methods:
Thrips (mixed infestation of Scirtothrips dorsalis and Thrips parvispinus): The numbers of live thrips were counted by shaking the twigs on black piece of paper. The observations were recorded from 3 twigs per plant and 10 plants per plot on 7 and 14 DAA (days after application). Calculate thrips control (%) as observed and apply Colby’s formula to calculate synergism.

Mite (Polyphagotarsonemus latus): The numbers of motile stages of mite were counted per unit area using 10X pocket microscope. The observations were recorded from 5 spots on randomly selected leaves (young growing leaves) per plant. 10 plants per plot were observed. Calculate mite control (%) as per the given formula.

Fruit borer (Helicoverpa armigera) larvae: The numbers of live larvae per plant were counted. The observations from 10 plants per plot were recorded. The larval control (%) was calculated by using given formula.

Healthy Fruit count: The numbers of healthy marketable fruits per plant were counted. The observations from 10 plants per plot were recorded and the increase (%) in healthy marketable fruits over UTC (untreated check) was calculated.

Composition of Component A 3% + Component B 15% + Component C4 2.5% OD [T4 of Ex. 1]
Chemical composition Function content (% w/w)
Component A Component A 3.00
Component B Component B 15.00
Component C4 Component C 2.50
Polyoxyethylene sorbitol hexaoleate Oil Emulsifier 10.00
Salts of polyolefin condensates Non-Aqueous dispersant 2.50
Ethoxylated sorbitan ester Co-Emulsifier 8.50
Bentonite clay Rheology modifier 1.50
Styrene acrylic polymer Aqueous dispersant 1.50
Methylated seed oil solvent 55.50
Total 100.00
active ingredient on 100% purity basis

Storage Stability: Component A 3%+ Component B 15%+Component C4 2.5% OD [T4 of Ex. 1]

Laboratory storage stability for 14 days
Parameters Specifications Initial At 54±2 0C At 0±2 0C
Component A 2.85 to 3.30 3.30 3.19 3.3
Component B 14.25 to 15.75 15.25 15.12 15.25
Component C4 2.375 to 2.75 0 2.65 2.53 2.65
Component A suspensibility (%) 80 98.90 98.10 98.80
Component B suspensibility (%) 80 99.00 98.50 98.90
Component C4 suspensibility (%) 80 98.80 98.10 98.80
pH range (1% aq. Suspension) 5.5 to 8.0 6.90 7.05 6.90
Pourability (%) 95 98.20 98.10 98.20
Specific gravity 1.00-1.10 1.03 1.03 1.03
Viscosity at spindle no.62,20 rpm 350-800 cps 510 520 510
Particle size (micron) D50<3, D90<10 2.1,8.0 2.1,8.2 2.1,8.1
Persistent foam ml (after 1 minute) max. 60 nil nil nil

Room temperature storage stability up to 12 months OD [T4 of Ex. 1]
Parameters Specifications Initial 1 month 6 month 12 month
Component A 2.85 to 3.30 3.30 3.30 3.28 3.27
Component B 14.25 to 15.75 15.25 15.25 15.24 15.22
Component C4 2.375 to 2.75 0 2.65 2.65 2.64 2.62
Component A suspensibility (%) 80 98.90 98.90 98.80 98.80
Component B suspensibility (%) 80 99.00 98.90 98.90 98.80
Component C4 suspensibility (%) 80 98.80 98.80 98.70 98.70
pH range (1% aq. Suspension) 5.5 to 8.0 6.90 6.90 6.90 6.95
Pourability (%) 95 98.20 98.20 98.20 98.20
Specific gravity 1.00-1.10 1.03 1.03 1.03 1.03
Viscosity at spindle no. 62, 20 rpm 350-800 cps 510 510 510 515
Particle size (micron) D50<3, D90<10 2.1,8.0 2.1,8.1 2.1,8.1 2.1,8.1
Persistent foam in ml (after 1 minute) max. 60 nil nil nil nil
The composition of Component A 3% + Component B 15% + Component C4 2.5% OD meets the all inhouse specifications for storage stability studies in laboratory (at 54 ± 2 °C and at 0 ± 2 °C for 14 days) and room temperature (for 12 months).

Manufacturing Process for 100 kg batch of Component A 3%+ Component B 15%+ Component C4 2.5% OD [T4 of Ex. 1]
Step 1: Preparation of 15% Bentonite clay solution: The bentonite clay (15 kg) was added into methylated seed oil (85 kg) and homogenized it till it gets completely dissolved. The said solution must be kept for 12 to 18 hours prior to use.
Step 2: OD Premix: The methylated seed oil (45.5 kg) was charged into a designated vessel for OD production.

Step 3: The polyoxyethylene sorbitol hexaoleate (10 kg), styrene acrylic polymer (1.5 kg), ethoxylated sorbitan ester (8.5 kg), salts of polyolefin condensates (2.5 kg) and polydimethyl siloxane (0.15 kg) were added and homogenized the contents for 45 to 60 minutes using high shear homogenizer.
Step 4: The Component A technical (3 kg), Component B technical (15 kg) and Component C4 technical (2.5 kg) were added into the premix and homogenized for 30 to 45 minutes.
Step 5: The remaining silicon antifoam (0.15 kg) and 15% bentonite clay solution (10 kg) were added after milling to avoid foaming.
Step 6: The final formulation was sent to QC for quality check.

Table 1: Treatment details:
Treatment Number Treatment compositions gram actives per hectare
T1 Component A 3%+ Component B 15%+ Component C6 2.5% SE 22.5+112.5+18.75
T2 Component A 3%+ Component B 15%+ Component C7 3% SC 22.5+112.5+22.5
T3 Component A 3%+ Component B 15%+ Component C8 7.5% SC 22.5+112.5+56.25
T4 Component A 3%+ Component B 15%+ Component C4 2.5% OD 22.5+112.5+18.75
T5 Component A 3%+ Component B 15%+ Component C9 9% SC 22.5+112.5+67.5
T6 Component A 3%+ Component C6 2.5% SE 22.5+18.75
T7 Component A 3%+ Component C7 3% SC 22.5+22.5
T8 Component A 3%+ Component C8 7.5% SC 22.5+56.25
T9 Component A 3%+ Component C4 2.5% OD 22.5+18.75
T10 Component A 3%+ Component C9 9% SC 22.5+67.5
T11 Component B 15%+ Component C6 2.5% SE 112.5+18.75
T12 Component B 15%+ Component C7 3% SC 112.5+22.5
T13 Component B 15%+ Component C8 7.5% SC 112.5+56.25
T14 Component B 15%+ Component C4 2.5% OD 112.5+18.75
T15 Component B 15%+ Component C9 9% SC 112.5+67.5
T16 Component A 3%+ Component B 15% SC 22.5+112.5
T17 Component A 30% SC 22.5
T18 Component B 15% EC 112.5
T19 Component C6 5% EC 18.75
T20 Component C7 10% SC 22.5
T21 Component C8 10% SC 56.25
T22 Component C4 5% SC 18.75
T23 Component C9 30% SC 67.5
T24 Untreated Check (UTC) -

T1 to T5 are present compositions and T6 to T16 are known formulations. Abbreviation: SE suspo emulsion, SC suspension concentrate, OD oil dispersion, EC emulsifiable concentrate.

Table 2a: Thrips control in chilli crop:
Treatment Number Thrips control (%)
at 7 DAA at 14 DAA
control observed control expected Colby's ratio Synergism (Y/N) control observed control expected Colby's ratio Synergism (Y/N)
T1 100.0 96.5 1.04 Y 98.4 91.1 1.10 Y
T2 100.0 96.3 1.04 Y 97.6 90.9 1.07 Y
T3 100.0 96.8 1.03 Y 99.2 91.9 1.05 Y
T4 100.0 96.7 1.03 Y 99.0 91.3 1.09 Y
T5 100.0 96.6 1.04 Y 98.8 91.2 1.08 Y
T6 89.2 88.1 1.01 Y 74.8 79.0 0.92 N
T7 88.4 87.6 1.01 Y 73.2 78.3 0.94 N
T8 90.4 89.2 1.01 Y 74.8 80.7 0.05 N
T9 89.2 88.8 1.00 Y 71.2 79.5 0.07 N
T10 89.8 88.4 1.02 Y 72.4 79.0 0.03 N
T11 87.4 86.0 1.02 Y 67.8 74.9 1.13 N
T12 86.0 85.4 1.01 Y 66.8 74.2 1.14 N
T13 88.0 87.3 1.01 Y 68.4 77.0 1.10 N
T14 87.2 86.9 1.00 Y 67.0 75.5 1.13 N
T15 87.0 86.4 1.01 Y 66.2 75.0 1.12 N
T16 93.2 92.5 1.01 Y 74.4 85.1 0.84 N
T17 74.8 64.6
T18 70.4 57.8
T19 52.8 40.6
T20 50.6 38.8
T21 57.2 45.6
T22 55.6 42.0
T23 54.0 40.8
T24 0.0 0.0

Abbreviation: DAA - days after application, Y - yes, N - no.

All the present compositions (T1 to T5) show synergism in terms of thrips control and provide residual on 7th and 14th days, whereas known formulations (T6 to T16) show synergism on 7th day only and do not provide residual control. All the present compositions (T1 to T5) show strong synergism as compared to known formulations (T6 to T16). As the Colby’s ratio increases the strength of synergism also increases.

Table 2b: Control of Fruit borer larvae, yellow mites, and chilli fruit yield

Treatment Number Fruit borer larval control (%) at 7 DAA Yellow mite control (%) at 7 DAA Number of healthy fruits per plant Increase (%) in fruits over UTC

T1 100.0 99.8 101.5 112.3
T2 100.0 97.6 102.8 115.1
T3 100.0 96.4 102.2 113.8
T4 100.0 100.0 103.9 117.4
T5 100.0 98.2 100.6 110.5
T6 78.4 72.8 84.9 77.6
T7 75.6 74.0 83.5 74.7
T8 77.2 3.8 85.6 79.1
T9 78.0 5.2 87.5 83.1
T10 75.4 2.4 82.8 73.2
T11 68.8 84.4 80.9 69.2
T12 69.2 84.8 79.5 66.3
T13 67.8 84.6 81.2 69.9
T14 68.2 85.0 83.4 74.5
T15 67.6 84.0 78.7 64.6
T16 82.8 71.8 91.0 90.4
T17 88.8 28.6 72.7 52.1
T18 80.4 57.4 69.6 45.6
T19 40.6 61.8 63.2 32.2
T20 41.2 63.2 62.4 30.5
T21 49.8 62.4 64.2 34.3
T22 40.6 64.2 65.7 37.4
T23 45.2 60.8 61.9 29.5
T24 0.0 0.0 47.8 0.0

All the present compositions (T1 to T5) provide complete protection against fruit borer larvae and yellow mites. The healthy marketable fruit yield over UTC [untreated check] was obtained higher (>110%) in treatments of present compositions (T1 to T5).

Conclusion: Among the various compositions as shown in Table 1 treatment number T1-T5 are considered to be present inventive compositions which showed excellent synergism and effectiveness against thrips control at 7 DAA and 14 DAA [days after application] for more than 97.6%. Particularly, at 7 DAA the thrips control for T1 to T5 were 100% whereas at 14 DAA the thrips control observed were (T3) 99.2% followed by (T4) 99.0% and (T5) 98.8%. Moreover, the colby’s ratio was found to be >1 which shows strong synergism.

Furthermore, the fruit borer larvae, yellow mites and chilli fruit yield gave exceptional result for T1 to T5 composition i.e. >96.4%. More particularly, for the fruit borer larval control at 7 DAA showed 100% control for T1 to T5. In addition to that, for the yellow mite control at 7 DAA showed (T4) 100%, (T1) 99.8% and (T5) 98.2% control. Further, the number of healthy fruits per plant for T1-T5 were more than 100.6. At last, the increase in fruits over UTC [untreated check] for T1 to T5 were more than 110.5 which shows excellent result when compared with the known formulations in chilli crop.

Example 2 : Insect-pests control in brinjal crop
Crop : Brinjal
Location : Durg, Chhattisgarh
Number of Treatments: 20
Plot size : 40 sq.m.
Crop age : 92 days after transplanting.
Method of application : foliar spray with battery operated backpack sprayer.
Water volume : 500 liter per hectare

Observation Methods:
Damage by Shoot and Fruit borer (Leucinoides orbonalis): The larvae of shoot and fruit borer cause damage to shoots and fruits in brinjal crop. It’s an internal feeder, i.e. bore inside shoot and fruits and causes damage. The efficacy can be assessed by counting the number of healthy and infested shoots, healthy and infested fruits per plant. Record the observations from randomly selected 10 plants per plot.

Fruit counts: Count the number of healthy marketable fruits from 5 plants per plot and calculate increase in healthy fruits over UTC.

Jassid (Amrasca biguttulla biguttula): Count the number of live jassid per leaf, 3 leaves per plant and 10 plants per plot on 7th and 14th DAA. Calculate jassid control (%) as observed control and apply Colby’s formula to calculate synergism.

Composition of Component A 2% + Component B 10% + Component C2 30% SE [T3 of Ex.2]
Chemical composition Function content (% w/w)
Component A Component A 2.00
Component B Component B 10.00
Component C2 Component C 30.00
Polyarylphenyl anionic ether sulfate, ammonium salt Emulsifier-2 3.50
Aromatic solvent C-9 Solvent 10.00
Acrylic graft copolymer Dispersing agent I 3.00
Butyl Polyalkylene Oxide block copolymer Dispersing agent II 4.50
Aluminum magnesium silicate Suspending agent 0.50
Polydimethylsiloxane Anti foaming agent 0.20
1,2-benzisothiazolin-3(2H)-one Preservative 0.15
Citric acid Buffering agent 0.10
Polypropylene glycol Anti freezing agent 5.00
Xanthan gum Thickner 0.15
Diluent water 30.90
Total 100.00
active ingredient on 100% purity basis

Storage stability - Component A 2% + Component B 10% + Component C2 30% SE [T3 of Ex.2]

Laboratory storage stability for 14 days
Parameters Specifications Initial At 54±2 0C At 0±2 0C
Component A 1.90 to 2.20 2.20 2.10 2.2
Component B 9.50 to 10.50 10.30 10.15 10.30
Component C2 28.50 to 31.50 30.50 30.10 30.50
Component A suspensibility (%) 80 98.90 97.50 98.50
Component B suspensibility (%) 80 99.00 97.90 98.60
Component C2 suspensibility (%) 80 98.50 97.60 98.30
pH range (1% aq. Suspension) 4.5 to 7.0 5.50 5.50 5.50
Pourability (%) 95 98.20 98.20 97.80
Specific gravity 1.05-1.10 1.07 1.07 1.07
Viscosity at spindle no.62,20 rpm 350-800 cps 550 560 560
Particle size (micron) D50<3, D90<10 2.1,8.2 2.2,8.5 2.1,8.2
Persistent foam ml (after 1 minute) max. 60 nil nil nil

Room temperature storage stability up to 12 months SE [T3 of Ex. 2]

Parameters Specification Initial 1 month 6 month 12 month
Component A 1.90 to 2.20 2.20 2.20 2.19 2.18
Component B 9.50 to 10.50 10.30 10.30 10.29 10.27
Component C2 28.50 to 31.50 30.50 30.50 30.49 30.47
Component A suspensibility (%) 80 98.90 98.70 98.70 98.50
Component B suspensibility (%) 80 99.00 98.90 98.80 98.70
Component C2 suspensibility (%) 80 98.50 98.40 98.40 98.40
pH range (1% aq. Suspension) 4.5 to 7.0 5.50 5.50 5.50 5.50
Pourability (%) 95 98.20 98.20 98.20 98.20
Specific gravity 1.05-1.10 1.07 1.07 1.07 1.07
Viscosity at spindle no. 62, 20 rpm 350-800 cps 550 550 550 555
Particle size (micron) D50<3, D90<10 2.1,8.2 2.1,8.2 2.1,8.2 2.1,8.2
Persistent foam in ml (after 1 minute) max. 60 nil nil nil nil

The composition of Component A 2% + Component B 10% + Component C2 30% SE meets the all inhouse specifications for storage stability studies in laboratory (at 54 ± 2 °C and at 0 ± 2 °C for 14 days) and room temperature (for 12 months).

Manufacturing process for 100 kg batch of Component A 2% + Component B 10% + Component C2 30% SE [T3 of Ex. 2]

Step 1: Preparation of 2% Gum solution: Xanthan gum (2 kg) and 1,2-benzisothiazoline-3-one (2 kg) were charged into 96 kg water and homogenized it. The said solution should be made 12-18 hour prior to use.
Step 2: EC premix: Aromatic solvent C-9 (10 kg) was added into other vessel while slow stirring. Component B (10 kg), Component C2 technical (30 kg) and polyarylphenyl anionic ether sulfate, ammonium salt (3.5 kg) were added and mixed properly for 30 to 45 minutes.
Step 3: DM water (23.4 kg) and 1,2-propylene glycol (5 kg) were charged into designated vessel and mixed thoroughly.
Step 4: Aluminum magnesium silicate (0.5 kg), acrylic graft copolymer (3 kg), butyl polyalkylene oxide block copolymer (4.5 kg) and polydimethylsiloxane (0.1 kg) were added into the vessel having water and homogenised the contents for 45 to 60 minutes using high shear homogeniser.
Step 5: After the step 4, Component A technical (2 kg) was slowly added to the premix and homogenised to achieve uniform slurry making it ready for grinding.
Step 6: Prior to the grinding half of the quantity of antifoam was added followed by the material to grind in dyno mill till desired particle size is achieved.
Step 7: The remaining polydimethyl siloxane antifoam (0.1 kg) was added upon the completion of grinding process and before sampling for in process analysis.
Step 8: After the step 7, the EC premix was mixed to this milled slurry under slow stirring and homogenized for 30 to 45 minutes.
Step 9: 2% Gum solution (7.5 kg) was added to the final formulation and then sent to QC for quality check.

Table 3: Treatment details [Ex.2]
Treatment Number Treatment compositions gram actives per hectare
T1 Component A 3%+ Component B 15%+ Component C10 20% SE 20+100+133.33
T2 Component A 2%+ Component B 10%+Component C11 30% SE 20+100+300
T3 Component A 2%+ Component B 10%+ Component C2 30% SE 20+100+300
T4 Component A 2%+ Component B 10%+ Component C12 30% SE 20+100+300
T5 Component A 3%+ Component C10 20% SE 20+133.33
T6 Component A 2%+ Component C11 30% SE 20+300
T7 Component A 2%+ Component C2 30% SE 20+300
T8 Component A 2%+ Component C12 30% SE 20+300
T9 Component B 15%+ Component C10 20% SE 100+133.33
T10 Component B 10%+ Component C11 30% SE 100+300
T11 Component B 10%+ Component C2 30% SE 100+300
T12 Component B 10%+ Component C12 30% SE 100+300
T13 Component A 3%+Component B 15% SC 20+100
T14 Component A 10% EC 20
T15 Component B 15% EC 100
T16 Component C10 50% EC 133.33
T17 Component C11 35% EC 300
T18 Component C2 50% EC 300
T19 Component C12 25% EC 300
T20 Untreated Check (UTC) -

T1 to T4 are present compositions, T5 to T13 are known compositions, T14 to T19 are market products.

Table 4a: Control of Jassid in brinjal [Ex.2]

Treatment Number Jassid control (%)
at 7 DAA at 14 DAA
control observed control expected Colby's ratio Synergism (Y/N)
T1 90.0 88.4 1.02 Y 82.4
T2 93.0 89.3 1.04 Y 80.6
T3 94.6 90.1 1.05 Y 88.4
T4 93.8 89.5 1.05 Y 83.6
T5 68.2 70.6 0.97 N 41.4
T6 71.4 72.9 0.98 N 40.8
T7 73.6 75.1 0.98 N 47.2
T8 71.8 73.6 0.98 N 44.8
T9 75.6 77.3 0.98 N 48.6
T10 78.2 79.1 0.99 N 45.2
T11 78.8 80.8 0.97 N 51.0
T12 77.2 79.6 0.97 N 49.6
T13 76.8 79.6 0.96 N 53.2
T14 48.6 32.4
T15 60.4 40.6
T16 42.8 19.4
T17 47.2 16.6
T18 51.6 28.2
T19 48.6 25.0
T20 0.0 0.0

All present compositions (T1 to T4) provide synergistic control of jassid up to 14 DAA in brinjal crop.

Table 4b: Efficacy against shoot and fruit borer damage and yield in brinjal corp [Ex.2]

Treatment Number Shoot damage (%) Fruit damage (%) Healthy fruits per 5 plants Increase (%) in healthy fruits over UTC
T1 0.23 0.11 98.40 242.9
T2 0.16 0.12 100.50 250.2
T3 0.12 0.00 109.30 280.8
T4 0.19 0.00 104.80 265.2
T5 1.18 0.84 76.40 166.2
T6 1.07 0.97 71.90 150.5
T7 0.82 0.52 87.30 204.2
T8 0.96 0.63 81.80 185.0
T9 2.27 2.86 59.80 108.4
T10 1.96 2.64 61.70 115.0
T11 1.32 1.74 67.60 135.5
T12 1.84 1.92 65.30 127.5
T13 0.54 1.13 70.40 145.3
T14 1.37 1.74 67.80 136.2
T15 3.58 4.63 51.50 79.4
T16 9.38 11.26 39.80 38.7
T17 8.26 9.43 42.80 49.1
T18 6.74 7.24 47.80 66.6
T19 7.37 8.85 46.20 61.0
T20 32.82 31.68 28.70 0.0

All present compositions (T1 to T4) provide excellent protection against shoot and fruit borer and produce higher number of marketable fruits.

Conclusion [Ex.2]: Among the various compositions as shown in Table 3, T1 to T4 are the present composition which showed excellent synergism and effectiveness against Jassid control, shoot damage and fruit damage as well as also provided healthy fruits per 5 plants and increament in healthy fruits over UTC. Further, (T3) showed 94.6% followed by (T4) 93.8% and (T2) 93.0% showed Jassid control at 7 DAA. Moreover, (T3) showed 88.4% followed (T4) 83.6% and (T1) 82.4% showed Jassid control at 14 DAA. At last, the colby’s ratio observed was >1 which means strong synergism.

Furthermore, (T3) showed 0.12%, (T2) 0.16% and (T4) 0.19% shoot damage. Further, (T3) and (T4) showed 0% fruit damage. Moreover, (T3) showed 109.30 followed by (T4) 104.80 and (T2) 100.50 healthy fruits per 5 plants. At last, (T3) showed 280.8% followed by (T4) 265.2% and (T2) 250.2% increase in healthy fruits over UTC [untreated check] from which it can be concluded that the present composition T1-T4 showcased effectiveness and synergism in brinjal crop as compared to known compositions and market products.

Example 3: Pod borer larval control and yield in red gram
Crop : Red gram
Location : Udalpur, Vadodara, Gujarat
Treatments : 20
Crop age : 108 days after sowing.
Spray water volume : 480 liters per hectare.
Method of Application: Foliar spray with battery operated knapsack sprayer fitted with hollow cone nozzle.

Observation Methods:
Pod borer (Helicoverpa armigera) larval control (%): Count the number of live larvae per plant. Record observations from 10 plants per plot on 14th days after application.

Pod count: count the number of healthy pods of red gram per plant. Record the observations from 10 plants per plot.
Composition of Component A 3% + Component B 15% + Component C5 20% WG [T2 of Ex. 3]
Chemical composition Function Percent (w/w)
Component A Component A 3.00
Component B Component B 15.00
Component C5 Component C 20.00
Modified Sodium lignosulphonate Dispersing agent I 7.00
Modified polyacrylate copolymer Dispersing agent II 3.00
Sodium isopropyl naphthalene sulfonate Wetting agent 5.00
Polydimethylsiloxane Antifoaming Agent 1.00
Corn Starch Carrier 15.00
China clay Carrier 31.00
Total 100.00
active ingredient on 100% purity basis

Storage Stability: Component A 3%+ Component B 15%+ Component C5 20% WG [T2 of Ex. 3]
Laboratory storage stability for 14 days
Parameters Specifications Initial At 54±2 0C At 0±2 0C
Component A 2.85 to 3.30 3.30 3.18 3.3
Component B 14.25 to 15.75 15.25 15.12 15.25
Component C5 19.00 to 21.00 20.50 20.20 20.5
Component A suspensibility (%) 70 98.40 97.30 98.20
Component B suspensibility (%) 70 98.20 97.50 98.20
Component C5 suspensibility (%) 70 98.80 97.40 98.60
pH range (1% aq. Suspension) 5 to 9 7.50 7.60 7.50
Wettability Max 30 s 10 12 10
Wet Sieve(45 micron) Mini 98.5% 99.5 99.4 99.5
Bulk Density 0.45-0.85 0.5 0.5 0.5
Moisture Content Max 2.0% 1.4 1.2 1.4
Persistent foam ml (after 1 minute) max. 60 nil nil nil

Room temperature storage stability up to 12 months WG
[T2 of Ex. 3]
Parameters Specifications Initial 1 month 6 months 12 months
Component A 2.85 to 3.30 3.30 3.30 3.28 3.26
Component B 14.25 to 15.75 15.25 15.25 15.24 15.22
Component C5 19.00 to 21.00 20.50 20.50 20.48 20.46
Component A suspensibility (%) 70 98.40 98.40 98.40 98.30
Component B suspensibility (%) 70 98.20 98.20 98.10 98.10
Component C5 suspensibility (%) 70 98.80 98.80 98.80 98.70
pH range (1% aq. Suspension) 5 to 9 7.50 7.50 7.50 7.55
Wettability Max 30 s 10 10 10 11
Wet Sieve(45 micron) Mini 98.5% 99.5 99.5 99.5 99.5
Bulk Density 0.45-0.85 0.5 0.5 0.5 0.5
Moisture Content Max 2.0% 1.4 1.4 1.4 1.3
Persistent foam ml (after 1 minute) max. 60 nil nil nil nil
The composition of Component A 3% + Component B 15% + Component C5 20% WG meets the all inhouse specifications for storage stability studies in laboratory (at 54 ± 2 °C and at 0 ± 2 °C for 14 days) and room temperature (for 12 months).

Manufacturing process for 100 kg batch of Component A 3% + Component B 15% + Component C5 20% WG [T2 of Ex. 3]
Step 1 The china clay (31 kg), corn starch (15 kg), silicone antifoam (0.5 kg), sodium isopropyl naphthalene sulfonate (5 kg), modified polyacrylate copolymer (3 kg) and modified sodium lignosulphonate blend (7 kg) were charged into a ribbon or premix blender and homogenized for 30 minutes.
Step 2 The Component A technical (3 kg), Component B technical (15 kg) and Component C5 technical (20 kg) were charged and homogenized for 30 minutes. The above mentioned pre blended material was grinded through jet mill/ air classifier mills. The finely grinded material was blended in post blender till it becomes homogeneous for approximately 1.5 hour.
Step 3 The finely grinded powder was mixed with water (13 kg) containing silicone antifoam (0.5 kg) to form extrudable dough.
Step 4 The dough was passed through extruder to achieve granules of required size.
Step 5 The wet granules were passed through fluidized bed drier to remove extra water (13 kg) and further graded using vibrating screens.
Step 6 The final product was sent to QC for approval.
Step 7 Upon the approval from QC, the material is packed in required package sizes.

Table 5: Treatment details [Ex.3]
Treatment Number Treatment compositions gram actives per hectare
T1 Component A 3.75%+ Component B 18.75%+ Component C13 2% SC 15+75+8
T2 Component A 3%+ Component B 15%+ Component C5 20% WG 15+75+100
T3 Component A 6%+ Component B 30%+ Component C14 15% WG 15+75+37.5
T4 Component A 3%+ Component B 15%+ Component C15 7.5% SE 15+75+37.5
T5 Component A 3.75%+ Component C13 2% SC 15+8
T6 Component A 3%+ Component C5 20% WG 15+100
T7 Component A 6%+ Component C14 15% WG 15+37.5
T8 Component A 3%+ Component C15 7.5% SE 15+37.5
T9 Component B 18.75%+ Component C13 2% SC 75+8
T10 Component B 15%+ Component C5 20% WG 75+100
T11 Component B 30%+ Component C14 15% WG 75+37.5
T12 Component B 15%+ Component C15 7.5% SE 75+37.5
T13 Component A 3%+ Component B 15% SC 15+75
T14 Component A 10% EC 15
T15 Component B 15% EC 75
T16 Component C13 1.9% EC 8
T17 Component C5 24% SC 100
T18 Component C14 15% SC 37.5
T19 Component C15 10% EC 37.5
T20 Untreated Check (UTC) -

T1 to T4 are present compositions, T5 to T13 are known compositions, T14 to T19 are market products.

Table 6: Pod borer larval control and pod yield in red gram [Ex.3]

Treatment Number Pod borer larval control (%) at Number of healthy pods per plant Increase (%) in healthy pods over T20 (UTC)
3 DAA 7 DAA 10 DAA 14 DAA 21 DAA
T1 100.0 100.0 100.0 98.6 97.2 242.7 135.2
T2 100.0 100.0 99.0 98.2 96.6 241.3 133.8
T3 100.0 100.0 100.0 99.2 98.6 248.5 140.8
T4 100.0 100.0 98.8 96.4 94.2 238.3 130.9
T5 96.2 93.6 86.6 69.4 57.6 210.5 104.0
T6 96.1 92.8 84.2 69.2 58.0 208.7 102.2
T7 97.4 94.2 85.6 70.8 58.8 213.8 107.2
T8 97.2 91.2 82.0 70.2 57.2 202.4 96.1
T9 93.0 88.6 80.0 62.8 47.8 182.7 77.0
T10 92.2 86.4 79.2 63.2 48.8 178.6 73.1
T11 94.6 89.6 82.2 64.2 50.6 188.5 82.7
T12 94.0 88.8 78.8 64.0 46.6 173.4 68.0
T13 95.4 91.0 81.2 70.2 60.8 171.2 65.9
T14 82.4 79.4 70.8 60.8 52.4 162.7 57.7
T15 70.4 67.4 61.2 48.2 37.2 148.8 44.2
T16 75.4 71.2 64.8 50.8 40.6 158.7 53.8
T17 72.6 68.4 61.8 51.0 40.8 157.3 52.4
T18 80.2 75.6 66.6 52.8 41.2 160.3 55.3
T19 78.8 72.8 62.4 52.2 40.6 147.8 43.2
T20 0.0 0.0 0.0 0.0 0.0 103.2 0.0

All the present compositions (T1 to T4) provide synergistic and residual control of pod borer larvae and also yielded higher number of healthy pods per plant as compared to all known compositions.

Conclusion: Among the various compositions as shown in table 5, T1-T4 are the present compositions which shows phenomenal results in terms of pod borer larval control and pod yield in red gram. In particular, at 3 DAA and and 7 DAA [days after application] T1-T4 showed 100% pod borer larval control. Moreover, at 10 DAA (T1) and (T3) showed 100% control. Further at 14 DAA (T3) showed 99.2% followed by (T1) 98.6% and (T2) 98.2% control. At last but not least at 21 DAA (T3) showed 98.6% followed by (T1) 97.2% and (T2) 96.6% pod borer larval control as compared to the known compositions and market products.

Furthermore, the number of healthy pods per plant were (T3) 248.3 followed by (T1) 242.7 and (T2) 241.3. In addition to that, the increase in healthy pods over T20 UTC [untreated check] were (T3) 140.8% followed by (T1) 135.2% and (T2) 133.8 as compared to the known compositions and market products. The present compositions T1 to T4 proved to possess the effectiveness and synergism to achieve the desired result in red gram crop.

Example 4: Whitefly and fruit borer larval control and yield in tomato
Crop : Tomato
Location : Umreth, Gujarat
Treatments : 11
Crop age : 77 days after transplanting.
Spray water volume : 46010 liters per hectare.
Method of Application : Foliar spray with battery operated knapsack sprayer fitted with hollow cone nozzle.

Observation Methods:
Whitefly (Bemesia tabaci) control (%): Count the number of live whitefly (nymphs and adults) per trifoliate leaves, record the observations from 3 leaves per plant and 10 plants per plot.

Composition of Component A 2.4% + Component B 12% + Component C1 24% SC [T3 of Ex.4]

Chemical composition Function content (% w/w)
Component A Component A 2.40
Component B Component B 12.00
Component C1 Component C 24.00
Methylated seed oil, polyalkyleneoxide modified trisiloxane Super wetting-spreading-penetrating agent 7.50
Ethylene-propylene oxide block copolymer Dispersing agent I 5.00
Sodium naphthalene sulphonate formaldehyde condensates Dispersing agent II 1.25
Aluminum magnesium silicate Suspending agent 0.50
Polydimethylsiloxane Anti foaming agent 0.30
sodium benzoate Preservative 0.20
Polypropylene glycol Anti freezing agent 5.00
Xanthan gum Thickner 0.20
Diluent water 41.65
Total 100.00
active ingredient on 100% purity basis

Storage Stability: Component A 2.4% + Component B 12% + Component C1 24% SC [T3 of Ex.4]
Laboratory storage stability for 14 days
Parameters Specification Initial At 54±2 0C At 0±2 0C
Component A 2.38 to 2.64 2.60 2.45 2.6
Component B 11.40 to 12.60 12.30 12.10 12.30
Component C1 22.80 to 25.20 24.50 24.30 24.5
Component A suspensibility (%) 80 98.60 98.10 98.50
Component B suspensibility (%) 80 98.50 98.30 98.50
Component C1 suspensibility (%) 80 98.70 98.20 98.45
pH range (1% aq. Suspension) 5.5 to 8.0 7.05 7.15 7.05
Pourability (%) 95 98.20 98.00 98.10
Specific gravity 1.05-1.10 1.07 1.07 1.07
Viscosity at spindle no.62,20 rpm 350-800 cps 530 550 550
Particle size (micron) D50<3, D90<10 2.1,8.5 2.1,8.7 2.1,8.7
Persistent foam ml (after 1 minute) max. 60 nil nil nil

Room temperature storage stability up to 12 months- SC [T3 of Ex.4]
Parameters Specification Initial 1 month 6 month 12 month
Component A 2.38 to 2.64 2.60 2.60 2.58 2.56
Component B 11.40 to 12.60 12.30 12.30 12.29 12.27
Component C1 22.80 to 25.20 24.50 24.50 24.49 24.48
Component A suspensibility (%) 80 98.60 98.50 98.50 98.40
Component B suspensibility (%) 80 98.50 98.50 98.50 98.40
Component C1 suspensibility (%) 80 98.70 98.70 98.60 98.60
pH range (1% aq. Suspension) 5.5 to 8.0 7.05 7.05 7.05 7.10
Pourability (%) 95 98.20 98.20 98.20 98.10
Specific gravity 1.05-1.10 1.07 1.07 1.07 1.07
Viscosity at spindle no. 62, 20 rpm 350-800 cps 530 530 530 535
Particle size (micron) D50<3, D90<10 2.1,8.5 2.1,8.5 2.1,8.5 2.1,8.6
Persistent foam in ml (after 1 minute) max. 60 nil nil nil nil
The composition of Component A 2.4% + Component B 12% + Component C1 24% SC meets the all inhouse specifications for storage stability studies in laboratory (at 54 ± 2 °C and at 0 ± 2 °C for 14 days) and room temperature (for 12 months).

Manufacturing process for 100 kg batch of Component A 2.4% + Component B 12% + Component C1 24% SC [T3 of Ex.4]
Step 1 Preparation of 2% Gum solution: The xanthan gum (2.0 kg) and sodium benzoate (2.0 kg) were charged into 96.0 kg water and homogenized it. The said solution should be made 12-18 hour prior to use.
Step 2 DM water (31.65 kg) and 1,2-propylene glycol (5 kg) were charged into designated vessel and mixed thoroughly.
Step 3 Sodium naphthalene sulphonate formaldehyde condensates (1.25 kg), ethylene-propylene oxide block copolymer (5.00 kg) and aluminum magnesium silicate (0.5 kg) were added into the vessel having water and homogenised the contents for 45 – 60 minutes using high shear homogeniser.
Step 4 Following step 3, Component A technical (2.40 kg), Component B technical (12.0kg) and Component C1 technical (24.0 kg) were added slowly to this premix and homogenized to achieve uniform slurry ready for grinding.
Step 5 Polydimethylsiloxane (0.15 kg) was added prior to the grinding containing half of the quantity and then the material was subjected to grind in dyno mill till desired particle size is achieved.
Step 6 Remaining polydimethyl siloxane (0.15 kg) antifoam was added after the completion of grinding process and before sampling for in process analysis.
Step 7 2% Xanthum gum solution (10 kg) and methylated seed oil, polyalkyleneoxide modified trisiloxane (7.5 kg) were added to this formulation and homogenized for 30 minutes.
Step 8 The final formulation was sent to QC for quality check.

Table 7: Whitefly control in tomato crop [Ex.4]

Treatment compositions gram actives per hectare Whitefly control (%) at 5 DAA
control observed control expected Colby's ratio Synergism (Y/N)
T1-Component A 3%+ Component B 15%+ Component C16 7.5% OD 18+90+45 84.2 77.5 1.09 Y
T2- Component A 3%+ Component B 15%+ Component C17 10% OD 18+90+60 89.8 81.7 1.10 Y
T3-Component A 2.4%+Component B 12%+Component C1 24% SC 18+90+180 92.6 85.7 1.08 Y
T4-Component A 3%+ Component B 15%+ Component C18 10% SE 18+90+60 94.8 85.8 1.11 Y
T5-Component A 10% EC 18 21.4
T6- Component B 15% EC 90 48.6
T7-Component C16 15% OD 45 44.2
T8-Component C17 24% SC 60 54.8
T9- Component C1 50% WP 180 64.6
T10- Component C18 10% EC 60 64.8
T11-Untreated Check (UTC) - 0.0

T1 to T8 are innovative compositions, T9 to T18 are known compositions, T19 to T25 are market products. All the present compositions (T1 to T4) provide synergistic control of whitefly in tomato. Abbreviation: DC dispersible concentrate.

Conclusion: Among the various compositions, T1 to T4 are the present composition which shows its effective result on whitefly control. In particular, (T4) showed 94.8% followed by (T3) 92.6% and (T2) 89.8% whitefly control at 5 DAA [days after application] as compared to the other T5 to T10 which are single component bearing composition and T11 i.e. UTC. At last, the Colby’ ratio for T1-T4 was >1 which shows stronger synergism of the components of the composition on tomato crop.

Example 5: Fruit borer larval control in okra
Crop : Okra
Location : Sonipat, Haryana
Treatments : 20
Crop age : 75 days after sowing.
Spray water volume : 460 liters per hectare.
Method of Application: Foliar spray with battery operated knapsack sprayer fitted with hollow cone nozzle.

Observation Methods:

Jassid (Amrasca biguttulla biguttula): Count the number of live jassid per leaf, 3 leaves per plant and 10 plants per plot on 7th and 14th DAA. Calculate jassid control (%) as observed control and apply Colby’s formula to calculate synergism.

Fruit borer (Helicoverpa armigera) larvae: The numbers of live larvae per plant were counted. The observations from 10 plants per plot were recorded. The larval control (%) was calculated by using given formula.

Table 8: Treatment details [Ex.5]

Treatment Number Treatment compositions gram actives per hectare
T1 Component A 8%+ Component B 30%+Component C19 30% WG 20+75+75
T2 Component A 8%+ Component B 30%+Component C20 25% WG 20+75+62.5
T3 Component A 8%+ Component B 30%+ Component C21 30% WG 20+75+75
T4 Component A 8%+ Component B 30%+ Component C22 15% WG 20+75+37.5
T5 Component A 8%+ Component C19 30% WG 20+75
T6 Component A 8%+ Component C20 25% WG 20+62.5
T7 Component A 8%+ Component C21 30% WG 20+75
T8 Component A 8%+ Component C22 15% WG 20+37.5
T9 Component B 30%+ Component C19 30% WG 75+75
T10 Component B 30%+ Component C20 25% WG 75+62.5
T11 Component B 30%+ Component C21 30% WG 75+75
T12 Component B 30%+ Component C22 15% WG 75+37.5
T13 Component A 8%+ Component B 30% WG 20+75
T14 Component A 10% EC 20
T15 Component B 15% EC 75
T16 Component C19 20% SP 75
T17 Component C20 50% WDG 62.5
T18 Component C21 25% WG 75
T19 Component C22 20% SG 37.5
T20 Untreated Check (UTC) -

T1 to T4 are present compositions, T5 to T13 are known compositions, T14 to T19 are market products.

Table 9: Jassid and Fruit borer larval control in okra crop [Ex.5]
Treatment Number Jassid control (%) Fruit borer larval control (%) at 14 DAA
at 7 DAA at 14 DAA
control observed control expected Colby's ratio control observed control expected Colby's ratio Synergism (Y/N)
T1 91.2 82.7 1.10 73.6 63.7 1.16 Y 97.8
T2 92.8 86.1 1.08 77.2 68.9 1.12 Y 96.2
T3 92.0 86.7 1.06 80.4 70.3 1.14 Y 95.8
T4 91.4 86.1 1.06 78.8 69.0 1.14 Y 93.4
T5 61.8 63.4 0.98 37.8 42.8 0.88 N 69.8
T6 68.6 70.6 0.97 48.2 51.2 0.94 N 71.6
T7 70.2 71.9 0.98 48.4 53.4 0.91 N 70.4
T8 69.4 70.5 0.98 46.6 51.3 0.91 N 68.8
T9 66.0 67.2 0.98 44.6 46.7 0.95 N 58.4
T10 71.4 73.8 0.97 50.2 54.5 0.92 N 60.2
T11 72.8 74.9 0.97 52.4 56.5 0.93 N 59.6
T12 71.2 73.7 0.97 50.8 54.6 0.93 N 57.2
T13 72.4 75.1 0.96 51.0 56.6 0.90 N 86.4
T14 47.2 31.8 68.2
T15 52.8 36.4 54.6
T16 30.6 16.2 12.6
T17 44.4 28.4 18.4
T18 46.8 31.6 16.4
T19 44.2 28.6 11.2
T20 0.0 0.0 0.0

All the present compositions (T1 to T4) provide synergistic control of jassid and fruit borer larvae in okra crops.

Conclusion: Among the various compositions, the present compositions are T1 to T4 as shown in table 8. The present compositions proved its effectiveness against Jassid control at 7 and 14 DAA [days after application] as well as fruit borer larval control at 14 DAA. Moreover, for jassid control at 7 DAA (T2) showed 92.8% followed by (T3) 92.0% and (T4) 91.4%. Furthermore, jassid control at 14 DAA (T3) showed 80.4% followed by (T4) 78.8% and (T2) 77.2%. Further, the colby’s ratio of the present compositions were >1 which shows stronger synergism.

In addition to that, (T1) showed 97.8% followed by (T2) 96.2% and (T3) 95.8% fruit borer larval control at 14 DAA. Hence, as explained above the present compositions proved to provide the jassid control and fruit borer larval control in okra crop.

Example 6: Pod borer larval control and yield in chickpea
Crop : Chickpea
Location : Devas, Madhya Pradesh
Treatments : 20
Crop age : 88 days after sowing.
Spray water volume : 400 liters per hectare.
Method of Application: Foliar spray with battery operated knapsack sprayer fitted with hollow cone nozzle.

Observation Methods:

Pod borer (Helicoverpa armigera) larval control (%): Count the number of live larvae per plant. Record observations from 10 plants per plot on 14th days after application.

Pod count: count the number of healthy pods of red gram per plant. Record the observations from 10 plants per plot.

Table 10: Treatment details [Ex.6]
Treatment Number Treatment compositions gram actives per hectare
T1 Component A 3%+ Component B15%+ Component C23 10% SC 15+75+50
T2 Component A 3%+ Component B15%+ Component C24 6% SC 15+75+30
T3 Component A 6%+ Component C23 20% SC 15+50
T4 Component A 6%+ Component C24 12% SC 15+30
T5 Component B 15%+ Component C23 10% SC 75+50
T6 Component B 15%+ Component C24 6% SC 75+30
T7 Component A 3%+ Component B 15% SC 15+75
T8 Component A 10% EC 15
T9 Component B15% EC 75
T10 Component C23 45% SC 50
T11 Component C24 12% SC 30
T12 Untreated Check (UTC) -

T1 and T2 are present compositions, T3 and T7 are known compositions, T8 to T11 are market products.

Table 11a: Pod borer larval control in chickpea [Ex.6]
Treatment Number Pod borer larval control (%)
at 7 DAA at 14 DAA
control observed control expected Colby's ratio Synergism (Y/N) control observed control expected Colby's ratio Synergism (Y/N)
T1 100.0 98.4 1.02 Y 100.0 90.5 1.11 Y
T2 100.0 98.6 1.01 Y 100.0 91.4 1.09 Y
T3 95.2 94.6 1.01 Y 77.8 81.2 0.96 N
T4 96.4 95.3 1.01 Y 80.2 83.0 0.97 N
T5 92.2 91.7 1.01 Y 70.4 75.2 0.94 N
T6 93.4 92.8 1.01 Y 72.2 77.6 0.93 N
T7 95.0 94.2 1.01 Y 75.4 80.6 0.94 N
T8 80.6 61.6
T9 70.2 49.4
T10 72.2 51.0
T11 75.8 55.8
T12 0.0 0.0

Both the present compositions (T1 and T2) provide synergistic larval control of gram pod borer.

Table 11b: Pod borer count [Ex.6]
Treatment Number Number of healthy fruits per plant Increase (%) in fruits over UTC

T1 72.6 139.6
T2 76.1 151.2
T3 58.9 94.4
T4 62.7 106.9
T5 55.2 82.2
T6 56.8 87.5
T7 55.7 83.8
T8 50.9 68.0
T9 45.3 49.5
T10 48.6 60.4
T11 51.8 71.0
T12 30.3 0.0

Both the present compositions (T1 and T2) provide increase in number of healthy fruits per plant and increase in fruits over UTC [untreated check]

Conclusion: Among the various compositions as shown in table 10 the present compositions T1 and T2 showcases the pod borer larval control and pod borer count. Further, the present compositions (T1) and (T2) showed 100% pod borer larval control at 7 DAA and 14 DAA [days after application]. Moreover, the colby’s ratio was =1 for the present compositions which shows stronger synergism as compared to the known compositions and market products.

In addition to that, the present compositions T1 and T2 proved highest number of healthy fruits per plant i.e. >72.6 as well as the increase in fruits over UTC were >139.6% in chickpea crop as compared to known compositions and market products.

Example 7: Thrips and pink bollworm control in cotton crop
Crop : Cotton
Location : Hisar, Haryana
Treatments : 24
Crop age : 70 days after sowing.
Spray water volume : 450 liters per hectare.
Method of Application : Foliar spray with battery operated knapsack sprayer fitted with hollow cone nozzle.

Observation Methods:

Thrips (mixed infestation of Scirtothrips dorsalis and Thrips parvispinus): The numbers of live thrips were counted by shaking the twigs on black piece of paper. The observations were recorded from 3 twigs per plant and 10 plants per plot on 7 and 14 DAA (days after application). Calculate thrips control (%) as observed and apply Colby’s formula to calculate synergism.

Pink bollworm: Count the number of rosetted flowers (flowers become closed after pink bollworm larvae infestation) per plant, record the observation from 10 plants per plot.

Fruiting bodies count: Count the number of healthy fruiting bodies (squares, flowers, and balls) per plant, record the observations from 5 plants (tagged) per plot and represent the data number of healthy fruiting bodies per plant.

Composition of Component A 3%+ Component B 15%+Component C3 2.5% ZC [T1 of Ex.7]
Chemical composition Function content (% w/w)
Component A Component A 3.00
Component B Component B 15.00
Component C3 Component C 2.50
Mixture of heavy aromatic hydrocarbons Solvent 3.20
4,4'-diphenylmethane diisocyanate Wall forming material 1 0.25
Diethylene triamine Wall forming material 2 0.15
Alkylbenzene sulfonate calcium salts Emulsifier-I 0.12
Tristyrylphenol polyethoxyester phosphate Emulsifier-II 3.50
Acrylic graft copolymer Dispersing agent I 2.50
Sodium naphthalene sulphonate formaldehyde condensate Dispersing agent II 0.16
Attapulgite clay Suspending agent 1.50
Polydimethylsiloxane Anti foaming agent 0.30
1,2-benzisothiazolin-3(2H)-one Preservative 0.20
Polypropylene glycol Anti freezing agent 5.00
Xanthan gum Thickner 0.20
Diluent water 62.42
Total 100.00

Storage stability- Component A 3%+ Component B 15%+ Component C3 2.5% ZC [T1 of Ex.7]
Laboratory storage stability for 14 days
Parameters Specifications Initial At 54±2 0C At 0±2 0C
Component A 2.85 to 3.30 3.25 3.18 3.25
Component B 14.25 to 15.75 15.50 15.25 15.50
Component C3 2.375 to 2.75 0 2.66 2.53 2.66
Component A suspensibility (%) 80 98.90 98.91 98.90
Component B suspensibility (%) 80 99.00 99.10 99.00
Component C3 suspensibility (%) 80 98.85 98.80 98.80
pH range (1% aq. Suspension) 5.5 to 8.0 6.90 6.90 6.90
Pourability (%) 95 98.20 98.20 98.20
Specific gravity 1.05-1.10 1.03 1.03 1.03
Viscosity at spindle no.62,20 rpm 350-800 cps 510 510 510
Particle size (micron) D50<3, D90<10 2.1,8.0 2.1,8.0 2.1,8.0
Persistent foam ml (after 1 minute) max. 60 nil nil nil

Room temperature storage stability up to 12 months ZC [T1 of Ex.7]
Parameters Specifications Initial 1 month 6 month 12 month
Component A 2.85 to 3.30 3.25 3.25 3.24 3.23
Component B 14.25 to 15.75 15.50 15.50 15.49 15.46
Component C3 2.375 to 2.75 0 2.66 2.66 2.64 2.60
Component A suspensibility (%) 80 98.90 98.90 98.90 98.91
Component B suspensibility (%) 80 99.00 99.00 99.00 99.10
Component C3 suspensibility (%) 80 98.85 98.80 98.80 98.80
pH range (1% aq. Suspension) 5.5 to 8.0 6.90 6.90 6.90 6.90
Pourability (%) 95 98.20 98.20 98.20 98.20
Specific gravity 1.05-1.10 1.03 1.03 1.03 1.03
Viscosity at spindle no. 62, 20 rpm 350-800 cps 510 510 510 510
Particle size (micron) D50<3, D90<10 2.1,8.0 2.1,8.0 2.1,8.0 2.1,8.0
Persistent foam in ml (after 1 minute) max. 60 nil nil nil nil

The composition of Component A 3%+ Component B 15%+ Component C3 2.5% ZC meets the all inhouse specifications for storage stability studies in laboratory (at 54 ± 2 °C and at 0 ± 2 °C for 14 days) and room temperature (for 12 months).

Manufacturing process for 100 kg batch of Component A 3%+ Component B 15%+ Component C3 2.5% ZC [T1 of Ex.7]
Step 1: Preparation of 2% Gum solution: The Xanthan gum (2 kg) and 1,2-benzisothiazoline-3-one (2 kg) were charged into 96 kg water and homogenized it. The said solution must be made 12 to 18 hours prior use.
Step 2: CS premix: The mixture of aromatic hydrocarbon (3.2 kg) solvent was added into other vessel having slow stirring. The Component C3 technical (2.5 kg) and alkylbenzene sulfonate calcium salts (0.12 kg), 4,4'-diphenylmethane diisocyanate (0.25 kg) were added and mixed properly for 30 to 45 minutes. The premix was added containing 20 kg DM water and sodium naphthalene sulphonate formaldehyde condensate (0.16 kg) under high stirring. The diethylene triamine (0.15 kg) was added and stirred at 50 degree for 3 hours. At last, the 2% gel solution (2 kg) was added.
Step 3: 36.92 kg of DM water and 1,2-propylene glycol (5 kg) were charged into designated vessel and mixed thoroughly.
Step 4: The aluminum magnesium silicate (0.5 kg), acrylic graft copolymer (2.5 kg), tristyrylphenol polyethoxyester phosphate (3.5 kg) and polydimethylsiloxane (0.1 kg) were added into the vessel containing water and homogenized for 45 to 60 minutes using high shear homogenizer.
Step 5: The Component B technical (15 kg) and Component A technical (3 kg) were added slowly to the premix and homogenised to achieve uniform slurry for grinding.
Step 6: Half of the quantity of antifoam was added prior to grind and the material was subjected to grind in dyno mill till desired particle size is achieved.
Step 7: The remaining polydimethyl siloxane antifoam (0.1 kg) was added upon the completion of the grinding process and prior the sampling for in process analysis.
Step 8: The CS premix was mixed to the milled slurry under slow stirring and homogenized for 30 to 45 minutes.
Step 9: The 2% gum solution (5.5 kg) was added to the final formulation and sent to QC for quality check.

Table 12: Treatment details [Ex.7]
Treatment Number Treatment compositions gram actives per hectare
T1 Component A 3%+ Component B 15%+ Component C3 2.5% ZC 22.5+112.5+18.75
T2 Component A 3%+ Component B 15%+ Component C25 8% SC 22.5+112.5+60.00
T3 Component A 3%+ Component B 15%+ Component C26 8% SE 22.5+112.5+60.00
T4 Component A 6%+ Component B 30%+ Component C27 4% SE 22.5+112.5+15.00
T5 Component A 3%+ Component B 15%+ Component C28 2% SC 22.5+112.5+15.00
T6 Component A 3%+ Component C3 2.5% ZC 22.5+18.75
T7 Component A 3%+ Component C25 8% SC 22.5+60.00
T8 Component A 3%+Component C26 8% SE 22.5+60.00
T9 Component A 6%+ Component C27 4% SE 22.5+15.00
T10 Component A 3%+ Component C28 2% SC 22.5+15.00
T11 Component B 15%+ Component C3 2.5% SE 112.5+18.75
T12 Component B 15%+ Component C25 8% SE 112.5+60.00
T13 Component B 15%+ Component C26 8% EC 112.5+60.00
T14 Component B 30%+ Component C27 4% EC 112.5+15.00
T15 Component B 15%+ Component C28 2% SC 112.5+15.00
T16 Component A 3%+ Component B 15% SC 22.5+112.5
T17 Component A 10% EC 22.5
T18 Component B 15% EC 112.5
T19 Component C3 5% EC 18.75
T20 Component C25 10% EC 60
T21 Component C26 10% EC 60
T22 Component C27 11% EC 15
T23 Component C28 2.45% SC 15
T24 Untreated Check (UTC) -

T1 to T5 are present compositions, T6 to T16 are known compositions, T17 to T23 are market products.

Table 13: Control of thrips in cotton [Ex.7]
Treatment Number Thrips control (%)
at 7 DAA at 14 DAA
control observed control expected Colby's ratio Synergism (Y/N) control observed control expected Colby's ratio Synergism (Y/N)
T1 100.0 96.2 1.04 Y 99.2 88.8 1.12 Y
T2 100.0 96.2 1.04 Y 99.4 88.9 1.12 Y
T3 100.0 96.1 1.04 Y 98.8 88.4 1.12 Y
T4 100.0 96.0 1.04 Y 96.6 88.0 1.10 Y
T5 100.0 95.8 1.04 Y 95.8 87.8 1.09 Y
T6 88.6 87.3 1.01 Y 73.2 75.1 0.98 N
T7 88.2 87.1 1.01 Y 71.4 75.3 0.95 N
T8 87.4 86.8 1.01 Y 70.8 74.2 0.95 N
T9 87.8 86.7 1.01 Y 69.6 73.3 0.95 N
T10 86.4 85.9 1.01 Y 68.8 72.8 0.95 N
T11 85.2 84.6 1.01 Y 69.2 71.5 0.97 N
T12 85.0 84.4 1.01 Y 67.4 71.8 0.94 N
T13 94.8 84.0 1.13 Y 65.2 70.5 0.92 N
T14 94.6 83.8 1.13 Y 64.4 69.4 0.93 N
T15 83.2 82.9 1.00 Y 63.8 68.9 0.93 N
T16 94.8 92.7 1.02 Y 77.4 82.4 0.94 N
T17 75.4 60.8
T18 70.2 55.2
T19 48.4 36.4
T20 47.6 37.0
T21 46.2 34.2
T22 45.8 31.8
T23 42.6 30.6
T24 0.0 0.0

All the present compositions (T1 to T5) show synergism in terms of thrips control and provide residual on 7th and 14th days, whereas known formulations (T6 to T16) show synergism on 7th day only and do not provide residual control. All the present compositions (T1 to T5) show strong synergism as compared to known formulations (T6 to T16). Higher the Colby’s ratio means stronger the synergism.

Table 14: Pink bollworm incidence and fruiting bodies count [Ex.7]

Treatment Number Number of rossetted flower (due to pink bollworm infestation) per 5 plants on 20 DAA Average number of fruiting bodies per plant Increase (%) in fruiting bodies over UTC (T24)

T1 0.0 82.3 112.1
T2 0.0 84.3 117.3
T3 0.0 82.1 111.6
T4 0.0 80.5 107.5
T5 0.0 80.1 106.4
T6 8.7 63.8 64.4
T7 7.2 67.2 73.2
T8 7.1 66.5 71.4
T9 7.8 63.7 64.2
T10 8.8 61.6 58.8
T11 9.7 60.9 57.0
T12 9.1 62.5 61.1
T13 9.2 60.3 55.4
T14 9.5 59.4 53.1
T15 10.3 57.8 49.0
T16 6.8 72.8 87.6
T17 11.9 56.3 45.1
T18 13.2 55.8 43.8
T19 27.6 50.3 29.6
T20 22.5 51.2 32.0
T21 26.3 50.7 30.7
T22 28.7 50.3 29.6
T23 29.3 48.6 25.3
T24 43.5 38.8 0.0

All the present compositions (T1 to T5) provide excellent protection against pink bollworm larvae and produce higher number of fruiting bodies per plant.

Conclusion: Among the various compositions as shown in table 12, the present compositions T1 to T5 proved its efficacy against thrips control, pink bollworm incidence and increment in fruiting bodies count. Further, the present compositions (T1) to (T5) showed 100% control at 7 DAA [days after application]. Moreover, (T2) showed 99.4% followed by (T1) 99.2% and (T3) 98.8% thrips control at 14 DAA as compared to the known compositions and market products. Furthermore, the Colby’s ratio for the present compositions shows >1 colby’s ratio depicting stronger synergism of the present compositions.

In addition to that the present compositions T1 to T5 proved 0% rossetted flower [due to pink bollworm infestation] per 5 plants on 20 DAA. Moreover, (T2) showed 84.3 followed by (T1) 82.3 and (T3) 82.1 average number of fruiting bodies per plant. At last, (T2) proved 117.3% followed by (T1) 112.1% and (T3) 111.6% of increase in fruiting bodies over UTC [untreated check] (T24) on cotton crop.

Example 8: Control of stem borer in rice.
Crop : Rice
Location : Kurud, Chhattisgarh
Treatments : 20
Spray water volume : 500 liters per hectare.
Method of Application : Foliar spray with battery operated knapsack sprayer fitted with hollow cone nozzle.

Observation Methods:
Stem borer control:

The infestation by stem borer was observed as dead heart (DH) symptoms during vegetative phase and as white ear (WE) during reproductive phase. The stem borer infestation/incidence during vegetative stage recorded by counting number of dead heart (infested tiller) per hill (infested+healthy tillers). The white ear (WE) symptoms during reproductive phase recorded by counting number of white ear and productive ear per hill.

The percent DH and WE incidence calculated by using formulae described below:

Productive tiller count : Count the number of productive tillers per hill. Record observations from 10 hills per plot at the time of harvesting.

Table 15: Treatment details [Ex.8]
Treatment Number Treatment compositions gram actives per hectare
T1 Component A 4%+ Component B 24%+ Component C29 5% SC 20+120+25
T2 Component A 2%+ Component B 12%+Component C30 8% SC 20+120+80
T3 Component A 1%+ Component B 6%+ Component C31 20% WG 20+120+400
T4 Component A 1%+ Component B 6%+ Component C32 20% WG 20+120+400
T5 Component A 4%+ Component C29 5% SC 20+25
T6 Component A 2%+Component C30 8% SC 20+80
T7 Component A 1%+ Component C31 20% WG 20+400
T8 Component A 1%+ Component C32 20% WG 20+400
T9 Component B 24%+ Component C29 5% SC 120+25
T10 Component B 12%+ Component C30 8% SC 120+80
T11 Component B 6%+ Component C31 20% WG 120+400
T12 Component B 6%+ Component C32 20% WG 120+400
T13 Component A 4%+ Component B 24% SC 20+120
T14 Component A 10% EC 20
T15 Component B 15% EC 120
T16 Component C29 10% SC 25
T17 Component C30 10% SC 80
T18 Component C31 50% SP 400
T19 Component C32 50% SP 400
T20 Untreated Check (UTC) -

T1 to T4 are present compositions, T5 to T13 are known compositions, T14 to T19 are market products.

Table 16: Control of stem borer, leaf folder and productive tillers in rice crop [Ex.8]

Treatment Number Stem borer Incidence (%) No. of productive tillers at harvest Increase (%) in productive tillers over UTC
Dead Heart symptoms White ear symptoms
T1 0.00 0.00 271.6 52.2
T2 0.00 0.00 278.7 56.1
T3 0.00 0.00 284.2 59.2
T4 0.00 0.00 286.7 60.6
T5 2.26 1.15 243.1 36.2
T6 2.07 1.06 248.3 39.1
T7 1.92 0.98 255.8 43.3
T8 1.86 0.93 258.0 44.5
T9 3.16 1.96 230.7 29.2
T10 2.86 1.72 233.3 30.7
T11 2.44 1.28 236.5 32.5
T12 2.32 1.21 238.6 33.7
T13 2.28 1.87 228.2 27.8
T14 4.88 3.89 222.6 24.7
T15 7.86 5.87 213.5 19.6
T16 6.24 4.97 218.3 22.3
T17 5.18 4.22 221.7 24.2
T18 4.74 3.54 224.8 25.9
T19 4.65 3.38 226.5 26.9
T20 14.74 12.32 178.5 0.0

All the present compositions (T1 to T4) provide complete protection against rice stem borer (in terms of dead heart and white ear) and produce higher number of productive tillers per hill, which are directly contributing to the grain yield.

Conclusion: Among the various compositions as shown in table 15, the present compositions T1 to T4 proves its effectiveness against stem borer incidence [dead heart and white ear symptoms], leaf folder and increase in productive tillers. The present compositions T1 to T4 showed 0% stem borer incidence i.e. dead heart and white ear symptoms. Furthermore, the number of productive tillers at harvest were (T4) 286.7 followed by (T3) 284.2 and (T2) 278.7 number of productive tillers at harvest. At last, the increase in productive tillers over UTC were >52.2% for T1 to T4 as compared to known compositions and market products in rice crop.

Overall field trials summary:
The present compositions of Component A + Component B+ Component C shows synergism in terms of insect-pests control and produces more fruits, flowers, and grains, increases spectrum of control, reduces number of pesticidal applications under field conditions

More particularly, the present invention also refers to the below mentioned preferred components:

Most Preferred formulations
Sr. No. Comp
onent A Comp
onent B Comp
onent C active ingredients(%) Formula
tion Strength (%) Formu
lation
Comp
onent A Comp
onent B Comp
onent C
1. Component A Component B Component C3 3 15 2.5 20.50 ZC
2. Component A Component B Component C25 3 15 8 26.00 SC
3. Component A Component B Component C26 3 15 8 26.00 SE
4. Component A Component B Component C27 6 30 4 40.00 SE
5. Component A Component B Component C28 3 15 2 20.00 SC
6. Component A Component B Component C10 3 15 20 38.00 SE
7. Component A Component B Component C11 2 10 30 42.00 SE
8. Component A Component B Component C2 2 10 30 42.00 SE
9. Component A Component B Component C12 2 10 30 42.00 SE
10. Component A Component B Component C23 3 15 10 28.00 SC
11. Component A Component B Component C24 3 15 6 24.00 SC
12. Component A Component B Component C16 3 15 7.5 25.50 OD
13. Component A Component B Component C17 3 15 10 28.00 OD
14. Component A Component B Component C1 2.4 12 24 38.40 SC
15. Component A Component B Component C18 3 15 10 28.00 SE
16. Component A Component B Component C19 8 30 30 68.00 WG
17. Component A Component B Component C20 8 30 25 63.00 WG
18. Component A Component B Component C21 8 30 30 68.00 WG
19. Component A Component B Component C22 8 30 15 53.00 WG
20. Component A Component B Component C13 3.75 18.75 2 24.50 SC
21. Component A Component B Component C5 3 15 20 38.00 WG
22. Component A Component B Component C14 6 30 15 51.00 WG
23. Component A Component B Component C15 3 15 7.5 25.50 SE
24. Component A Component B Component C6 3 15 2.5 20.50 SC
25. Component A Component B Component C7 3 15 3 21.00 SC
26. Component A Component B Component C8 3 15 7.5 25.50 SC
27. Component A Component B Component C4 3 15 2.5 20.50 OD
28. Component A Component B Component C9 3 15 9 27.00 SC
29. Component A Component B Component C29 4 24 5 33.00 SC
30. Component A Component B Component C30 2 12 8 22.00 SC
31. Component A Component B Component C31 1 6 20 27.00 WG
32. Component A Component B Component C32 1 6 20 27.00 WG
33. Component A Component B Component C33 3 15 10 28.00 OD
34. Component A Component B Component C34 3 15 10 28.00 OD
35. Component A Component B Component C35 3 15 7.5 25.50 OD
36. Component A Component B Component C36 3 15 1 19.00 SE
37. Component A Component B Component C37 3 15 10 28.00 SC
38. Component A Component B Component C38 3 15 15 33.00 SC
39. Component A Component B Component 39 3 15 12 30.00 SC
40. Component A Component B Component C40 3 15 10 28.00 EC
41. Component A Component B Component C44 2 12 12 26.00 SC

The process for preparing the ternary insecticidal composition can be modified accordingly by any person skilled in the art based on the knowledge of the manufacturing the formulation. However, all such variation and modification is still covered by the scope of present invention.
Application to the seeds is carried out before sowing, either directly on the seeds or after having pregerminated the latter. Suitable application methods include inter alia soil treatment, seed treatment, in furrow application, and foliar application. Soil treatment methods include drenching the soil, drip irrigation (drip application onto the soil), dipping roots, tubers or bulbs, or soil injection. Seed treatment techniques include seed dressing, seed coating, seed dusting, seed soaking, and seed pelleting. In furrow applications typically include the steps of making a furrow in cultivated land, seeding the furrow with seeds, applying the pesticidally active composition to the furrow, and closing the furrow. Foliar application refers to the application of the pesticidally active composition to plant foliage, e.g. through spray equipment.
The rates of application vary within wide limits and depend on the nature of the soil, the method of application, the crop plant, the pest to be controlled, the prevailing climatic conditions, and other factors governed by the method of application, the time of application and the target crop.

The present invention is suitable for use in protecting crops, plants, plant propagation materials, such as seeds, or sailor water, in which the plants are growing, from attack or infestation by animal pests. Therefore, the present invention also relates to a plant protection method, which comprises contacting crops, plants, plant propagation materials, such as seeds, or soil or water, in which the plants are growing, to be protected from attack or infestation by animal pests, with an insecticidally effective amount of the present invention.
The present invention is also suitable for use in combating or controlling animal pests. Therefore, the present invention also relates to a method of combating or controlling animal pests, which comprises contacting the animal pests, their habitat, breeding ground, or food supply, or the crops, plants, plant propagation materials, such as seeds, or soil, or the area, material or environment in which the animal pests grow, with an insecticidally effective amount of the present invention.
The lists of crops on which the insecticidal composition of the present invention is used include, but not limited to GMO (Genetically Modified Organism) and Non GMO traits, hybrids and conventional varieties of Cotton (Gossypium spp.), Paddy (Oryza sativa), Wheat (Triticum aestavum), Barley (Hordeum vulgare), Maize (Zea mays), Sorghum (Sorghum bicolor), Oat (Avena sativa), Pearl millet (Pennisetum glaucum), Sugarcane (Saccharum officinarum), Sugarbeet (Beta vulgaris), Soybean (Glycin max), Groundnut/Peanut (Arachis hypogaea), Sunflower (Helianthus annuus), Mustard (Brassica juncea), Rape seed (Brassica napus), Sesame (Sesamum indicum), Green gram (Vigna radiata), Black gram (Vigna mungo), Chickpea (Cicer aritinum), Cowpea (Vigna unguiculata), Red gram (Cajanus cajan), French bean (Phaseolus vulgaris), Indian bean (Lablab purpureus), Horse gram (Macrotyloma uniflorum), Field pea (Pisum sativum), Cluster bean (Cyamopsis tetragonoloba), Lentils (Lens culinaris), Brinjal (Solanum melongena), Cabbage (Brassica oleracea var. capitata), Cauliflower (Brassica oleracea var. botrytis), Okra (Abelmoschus esculentus), Onion (Allium cepa L.), Tomato (Solanum lycopersicun), Potato (Solanum tuberosum), Sweet potato (Ipomoea batatas), Chilli (Capsicum annum), Bell pepper (Capsicum annum), Garlic (Allium sativum), Cucumber (Cucumis sativus), Muskmelons (Cucumis melo), Watermelon (Citrullus lanatus), Bottle gourd (Lagenaria siceraria), Bitter gourd (Momordica charantia), Radish (Raphanus sativus), Carrot (Dacus carota subsp. sativus), Turnip (Brassica rapa rapa), Apple (Melus domestica), Banana (Musa spp.), Citrus groups (Citrus spp.), Grape (Vitis vinifera), Guava (Psidium guajava), Mango (Mangifera indica), Papaya (Carica papaya), Pineapple (Ananas comosus), Pomegranate (Punica granatum), Sapota (Manilkara zapota), Tea (Camellia sinensis), Coffea (Coffea Arabica), Turmeric (Curcuma longa), Ginger (Zingiber officinale), Cumin (Cuminum cyminum), Black Pepper (Piper nigrum), Mentha (Mentha spp.), Rose (Rosa spp.), Jasmine (Jasminum spp.), Marigold (Tagetes spp.), Common daisy (Bellis perennis), Dahlia (Dahlia hortnesis), Gerbera (Gerbera jamesonii), Carnation (Dianthus caryophyllus).

Crops are to be understood as also including those crops which have been rendered tolerant to herbicides or classes of herbicides (e.g. ALS-, GS-, EPSPS-, PPO-, ACCase- and HPPD-inhibitors) by conventional methods of breeding or by genetic engineering. An example of a crop that has been rendered tolerant to imidazolinones, e.g. imazamox, by conventional methods of breeding is Clearfield® summer rape (canola). Examples of crops that have been rendered tolerant to herbicides by genetic engineering methods include e.g. glyphosate- and glufosinate-resistant maize varieties commercially available under the trade names RoundupReady® and LibertyLink®.

Crops are also to be understood as being those which have been rendered resistant to harmful insects by genetic engineering methods, for example Bt maize (resistant to European corn borer), Bt cotton (resistant to cotton boll weevil) and also Bt potatoes (resistant to Colorado beetle). Examples of Bt maize are the Bt 176 maize hybrids of NK® (Syngenta Seeds). The Bt toxin is a protein that is formed naturally by Bacillus thuringiensis soil bacteria. Examples of toxins, or transgenic plants able to synthesise such toxins, are described in EP-A-451 878, EP-A-374 753, WO 93/07278, WO 95/34656, WO 03/052073 and EP-A-427 529. Examples of transgenic plants comprising one or more genes that code for an insecticidal resistance and express one or more toxins are KnockOut® (maize), Yield Gard® (maize), NuCOTIN33B® (cotton), Bollgard® (cotton), NewLeaf® (potatoes), NatureGard® and Protexcta®. Plant crops or seed material thereof can be both resistant to herbicides and, at the same time, resistant to insect feeding (“stacked” transgenic events). For example, seed can have the ability to express an insecticidal Cry3 protein while at the same time being tolerant to glyphosate.

Other useful plants include turf grass for example in golf-courses, lawns, parks and roadsides, or grown commercially for sod, and ornamental plants such as flowers or bushes.

The ternary insecticidal composition of the present invention is used to control insects-pests and plant parasitic mites infesting crop plants. The major insects pests are belongs to the order Hemiptera, for example, rice leafhopper/green leaf hopper (GLH) Nephotettix nigropictus, rice brown plant hopper (BPH) Nilaparvata lugen, rice backed plant hopper (WBPH) Sogatella furcifera, Apple Mealy bug Phenococcus aceris, bean aphid Aphis fabae, black citrus aphid Toxoptera aurantii, citrus black scale Saissetia oleae, cabbage aphid Brevicoryne brassicae, Lipaphis erysimi, citrus red scale Aonidiella aurantii, yellow scale Aonidiella citrine, citrus mealybug Planococcus citri, corn leaf aphid Rhopalosiphum maidis, aphid Aphis gossypii, jassid Amrasca biguttula biguttla, mealy bug Planococcus spp. and Pseudococcus spp., cotton stainer Dysdercus suturellus, whitefly Bemisia tabaci, cowpea aphid Aphis crassivora, grain aphid Sitobion avenae, golden glow aphid Uroleucon spp., grape mealybug Pseudococcus maritimus, green peach aphid Myzus persicae, greenhouse whitefly Trialeurodes vaporariorum, papaya mealy bug Pracoccus marginatus, pea aphid Acyrthosiphon pisum, sugarcane mealybug Saccharicoccus sacchari, potato aphid Myzus persicae, potato leaf hopper Empoasca fabae, cotton whitefly Bemisia tabaci, tarnished plant bug Lygus lineolaris, wooly apple aphid Eriosoma lanigerum, mango hopper Amritodus atkinsoni, Idioscopus spp.; order Lepidoptera, army worm Mythimna unipuncta, asiatic rice borer Chilo suppressalis, bean pod borer Maruca vitrata, beet armyworm Spodoptera exigua, black cutworm Agrotis ipsilon, bollworm Helicoverpa armigera, cabbage looper Trichoplusia ni, codling moth Cydia pomonella, croton caterpillar Achea janata, diamond backmoth Plutella xylostella, cabbage worm Pieris rapae, pink bollworm Pectinophora gossypiella, sugarcane borer Diatraea saccharalis, sugarcane early shoot borer Chilo infuscatellus tobacco budworm Heliothis virescens, tomato fruit worm Helicoverpa zea, velvet bean caterpillar Anticarsia gemmatalis, yellow stem borer Scirpophaga incertulas, spotted bollworm Earias vittella, rice leaffolder Cnaphalocrocis medinalis, pink stem borer Sesamia spp., tobacco leafeating caterpillar Spodoptera litura; brinjal fruit and shoot borer Leucinodes orbonalis, bean pod borer Maruca vitrata, Maruca testulalis, armyworm Mythimna separata, cotton pinkbollworm Pectinophora gossypiella, citrus leafminer Phyllocnistis citrella, cabbage butterfly Pieris bras-sicae, diamond backmoth Plutella xylostella, paddy stem borer Scirpophaga excerptallis, Scirpophaga incertulas, Scirpophaga innotata, wheat stem borer Sesamia inferens, Sitotroga cerealella, Spilosoma obliqua, fall armyworm Spodoptera frugiperda, Spodoptera littoralis, Spodoptera litura, Trichoplusia ni, Tryporyza nivella, Tryporyza incertulas, Tuta absoluta.

From the order Coleoptera, for example, apple twig borer Amphicerus spp., corn root worm Diabrotica virgifera, cucumber beetle diabrotica balteata, boll weevil Anthonomus grandis, grape flea beetle Altica chalybea, grape root worm Fidia viticola, grape trunk borer Clytoleptus albofasciatus, radish flea beetle Phyllotreta armoraciae, maize weevil Sitophilus zeamais, northern corn rootworm Diabrotica barberi, rice water weevil Lissorhoptrus oryzophilus, Anthonomus grandis, Bruchus lentis, Diabrotica semipunctata, Diabrotica virgifera, Dicladispa armigera, Epila-chna varivestis, various species of white grubs are Holotrichia bicolor, Holotrichia consanguinea, Holotrichia serrata, Leptinotarsa decemlineata, Phyllotreta chrysocephala, Popillia japonica etc; from the order Orthoptera, for example, Gryllotalpa spp., Locusta spp., and Schistocerca is spp.; from the order

Thysanoptera, for example, Frankliniella spp., Thrips palmi, Thrips tabaci, Thrips parvispinus and Scirtothrips dorsalis; termites (Isoptera), e.g. Calotermes flavicollis, Coptotermes formosanus, Heterotermes aureus, Leucotermes flavipes, Microtermes obesi, Odontotermes obesus, Reticulitermes flavipes, Termes natalensis; from the order Heteroptera, for example, Dysdercus spp., Leptocorisa spp., from the order Hymenoptera, for example, Solenopsis spp.; from the order Diptera, for example, Antherigona soccata, Dacus spp., Liriomyza spp., Melanagromyza spp.

The major plant parasitic mites are from the order Acarina, for example, Aceria mangiferae, Brevipalpus spp., Eriophyes spp., Oligonychus mangiferus, Oligonychus punicae, Panonychus citri, Panonychus ulmi, Chilli yellow mite-Polyphagotarsonemus latus, Tarsonemus spp., Red spider mite-Tetranychus urticae, Tetranychus cinnabarinus.

The present invention has been described with reference to specific embodiment which is merely illustrative and not intended to limit the scope of the invention as defined in the present complete specification.
,CLAIMS:We claim:
1. A ternary composition comprising:
A) Component A: 3-[benzoyl(methyl)amino] -N- [2-bromo-4-(1,1,1,2,3,3,3-heptafluoropropan-2-yl)-6-(trifluoromethyl)phenyl]-2-fluorobenzamide in an amount of 1 to 20 w/w%;
B) Component B: 4-chloro-5-ethyl-2-methyl-N-[[4-(4-methylphenoxy)phenyl]methyl]pyrazole-3-carboxamide in an amount of 5 to 30 w/w%; and
C) at least one compound selected from group of Component C in an amount of 1 to 50 w/w% and agrochemically acceptable excipients.

2. The ternary composition as claimed in claim 1 wherein, Component C is selected from the group consisting of 1-tert-butyl -3- (2,6-diisopropyl-4-phenoxyphenyl) thiourea, 4-bromo-2-chloro -1- [ethoxy (propylsulfanyl) phosphoryl] oxybenzene, [(R)-cyano-(3-phenoxyphenyl) methyl] (1S,3S) -3- [(Z) -2- chloro- 3,3,3- trifluoroprop -1- enyl] -2,2 dimethylcyclopropane-1-carboxylate, tert-butyl4- [[(E-(1,3-dimethyl-5-phenoxypyrazol-4 yl) methylideneamino] oxymethyl] benzoate, N’-tert-butyl-N’-(3,5-dimethylbenzoyl)-3-methoxy-2-methylbenzohydrazide, (4S,5S)-5-(4-chlorophenyl)-N-cyclohexyl-4-methyl-2 oxo-1,3-thiazolidine-3-carboxamide, 4-(4-tert-butyl-2-ethoxyphenyl)-2-(2,6-difluorophenyl)-4,5-dihydro-1,3-oxazole, 4-bromo-2-(4-chlorophenyl)-1-(ethoxymethyl)-5-(trifluoromethyl)-pyrrole-3-carbonitrile, [(E)-2-(4-tert-butylphenyl)-2-cyano-1-(2,4,5-trimethylpyrazol-3-yl)ethenyl] 2,2-dimethylpropanoate, ethyl 2-dimethoxyphosphinothioylsulfanyl -2- phenylacetate, 6-chloro-3-(diethoxyphosphinothioylsulfanylmethyl) -1,3-benzoxazol-2-one, diethoxy-quinoxalin-2-yloxy-sulfanylidene-?5-phosphane, benzoic acid; (1'R,2R,3S,4’S,6S,8’R,10’E,12’S,13’S,14’E,16’E,20’R,21’R,24’S)-2) [(2S)-butan-2-yl] -21',24'-dihydroxy-12'-[(2R,4S,5S,6S) -4- methoxy-5-[(2S,4S,5S,6S)-4-methoxy-6-methyl -5- (methylamino)oxan-2-yl]oxy-6-methyloxan-2-yl]oxy-3,11',13',22'-tetramethylspiro [2,3-dihydropyran-6,6'-3,7,19-trioxatetracyclo [15.6.1.14,8.020,24] pentacosa-10,14,16,22-tetraene]-2'-one, methyl (4aS)-7-chloro-2-[methoxycarbonyl- [4-(trifluoromethoxy)phenyl]carbamoyl]-3,5-dihydroindeno[1,2 e][1,3,4]oxadiazine-4a-carboxylate, N-[[3-chloro-4- [1,1,2-trifluoro -2-(trifluoromethoxy)ethoxy]phenyl]carbamoyl] -2,6-difluorobenzamide, [3-(2,5-dimethylphenyl)-8-methoxy-2-oxo-1-azaspiro[4.5]dec-3-en-4-yl] ethyl carbonate, [2-oxo-3-(2,4,6-trimethylphenyl) -1- oxaspiro[4.4]non-3-en-4-yl] 3,3-dimethylbutanoate, 2-[1-(4-phenoxyphenoxy)propan-2-yloxy]pyridine, N-[(6-chloropyridin-3-yl)methyl] -N’-cyano-N-methylethanimidamide, 1-[(2-chloro-1,3-thiazol-5-yl)methyl]-3-methyl -2- nitroguanidine, (NE)-N-[3-[(2-chloro-1,3-thiazol-5-yl)methyl]-5-methyl-1,3,5-oxadiazinan -4-ylidene] nitramide, 1-methyl-2-nitro-3-(oxolan-3-ylmethyl)guanidine, mixture of 50–95% (2R,3aS,5aR,5bS,9S,13S,14R,16aS,16bR) -2- [(6-deoxy-2,3,4-tri-O-methyl-a-L-mannopyranosyl)oxy] -13- {[4-(dimethylamino)-2,3,4,6-tetradeoxy-ß-D-erythropyranosyl]oxy} -9- ethyl 2,3,3a,5a,5b,6,7,9,10,11,12,13,14,15,16a,16b-hexadecahydro-14-methyl-1H-as-indaceno[3,2-d]oxacyclododecine-7,15-dione and 50–5% (2S,3aR,5aS,5bS,9S,13S,14R,16aS,16bS) -2- [(6-deoxy-2,3,4-tri-O-methyl-a-L-mannopyranosyl)oxy] -13- {[4-(dimethylamino)-2,3,4,6-tetradeoxy-ß-D-erythropyranosyl]oxy} -9- ethyl 2,3,3a,5a,5b,6,7,9,10,11,12,13,14,15,16a,16b- hexadecahydro -4,14-dimethyl- 1H-as-indaceno[3,2-d] oxacyclododecine-7,15-dione, (2R,5R,9R,10S,14R,15S,19S)-15-[(2R,5S,6R)-5-(dimethylamino) -6-methyloxan-2-yl]oxy -7- [(2R,3R,4R,5S,6S)-4-ethoxy-3,5-dimethoxy-6-methyloxan-2-yl]oxy-19-ethyl -14- methyl-20 oxatetracyclo[10.10.0.02,10.05,9] docos-11-ene-13,21-dione, (2-methyl-3-phenylphenyl)methyl (1R,3R)-3-[(Z)-2-chloro-3,3,3-trifluoroprop-1-enyl] -2,2- dimethylcyclopropane-1 carboxylate, [cyano-(3-phenoxyphenyl)methyl] 2,2,3,3-tetramethylcyclopropane-1-carboxylate, [(S)-cyano-(3-phenoxyphenyl)methyl] (1R,3R)-3-(2,2-dibromoethenyl)-2,2-dimethylcyclopropane -1- carboxylate, [(R)-cyano-(4-fluoro-3-phenoxyphenyl)methyl] (1S)-3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropane -1- carboxylate, 4-oxo-1-(pyrimidin-5-ylmethyl) -3- [3-(trifluoromethyl)phenyl]pyrido[1,2-a]pyrimidin-1-ium-2-olate, N-[1-[(6-chloropyridin-3-yl)methyl]pyridin-2-ylidene] -2,2,2-trifluoroacetamide, S-[3-carbamoylsulfanyl -2- (dimethylamino)propyl] carbamothioate;hydrochloride, N,N-dimethyltrithian -5- amine;oxalic acid, [3-(2,4-dichlorophenyl)-2-oxo-1-oxaspiro[4.5]dec-3-en-4-yl] 2,2-dimethylbutanoate, [3-(4-chloro-2,6-dimethylphenyl)-8-methoxy-1-methyl-2-oxo-1,8-diazaspiro[4.5]dec-3-en-4-yl] ethyl carbonate, 2-(4-chloro-2,6-dimethylphenyl)-1-hydroxy-9,12-dioxa -4-azadispiro[4.2.48.25]tetradec-1-en-3-one, dimethyl (1S,4S,5R,6S,7S,8R,11S,12R,14S,15R)-12-acetyloxy-4,7-dihydroxy-6-[(1S,2S,6S,8S,9R,11S)-2-hydroxy-11-methyl -5,7,10-trioxatetracyclo[6.3.1.02,6.09,11]dodec-3-en-9-yl]-6-methyl-14-[(E) -2-methylbut-2-enoyl]oxy-3,9dioxatetracyclo[6.6.1.01,5.011,15]pentadecane-4,11-dicarboxylate, 3,6-bis(2-chlorophenyl)-1,2,4,5-tetrazine, 2-methoxyethyl 2-(4-tert-butylphenyl)-2-cyano-3-oxo-3-[2-(trifluoromethyl) phenyl]propanoate, propan-2-yl N-(2-methoxy-5-phenylanilino) carbamate, [2-ethyl-3,7-dimethyl-6-[4-(trifluoromethoxy)phenoxy]quinolin-4-yl] methyl carbonate, N-tert-butyl-N'-(4-ethylbenzoyl)-3,5-dimethylbenzohydrazide.

3. The ternary composition as claimed in claim 1 wherein, the agrochemically acceptable excipients are selected from the group consisting of wetting-spreading-penetrating agent(s), dispersing agent(s), suspending agent(s), anti freezing agent(s), thickner(s), preservative(s), emulsifier(s), anti foaming agent(s), buffering agent(s), rheology modifier(s), wetting agent(s), carrier(s) and solvent(s).

4. The ternary composition as claimed in claim 1 wherein, the composition is in the form of suspension concentrate (SC), suspo emulsion (SE), oil dispersion (OD), wettable granule/ water dispersible granule (WG/WDG) and mixed formulation (ZC).

5. The ternary composition as claimed in claim 3 wherein, the wetting-spreading-penetrating agent(s) for suspension concentrate (SC) is selected from methylated seed oil, polyalkyleneoxide modified trisiloxane, trisiloxane ethoxylate, heptamethyl trisiloxane, polyalkyleneoxide modified heptamethyl trisiloxane, polyether modified polysiloxane, polyalkyleneoxide modified trisiloxane, polyalkyleneoxide modified polydimethylsiloxane and mixture thereof.

6. The ternary composition as claimed in claim 3 wherein, the dispersing agent(s) for suspension concentrate (SC) is selected from ethylene-propylene oxide block copolymer, sodium naphthalene sulphonate formaldehyde condensates, naphthalenesulfonic acid, sodium salt condensate with formaldehyde, alkylated naphthalene sulfonate, sodium salt, sodium salt of naphthalene sulfonate condensate, sodium ligno sulfonate, sodium polycarboxylate, EO/PO based copolymer, phenol sulfonate, sodium methyl oleoyl taurate, styrene acrylic acid copolymer, propylene oxide-ethylene oxide-copolymer, polyethylene glycol 2,4,6-tristyrylphenyl ether, tristyrylphenol-polyglycol ether-phosphate, tristyrylphenole with 16 moles EO, tristyrylphenol-polyglycol ether-phosphate, oleyl-polyglycol ether with ethylene oxide, tallow fatty amine polyethylene oxide, nonylphenol polyglycol ether with 9-10 moles ethylene oxide and mixture thereof.

7. The ternary composition as claimed in claim 3 wherein, the suspending agent(s) for suspension concentrate (SC) is selected from aluminum magnesium silicate, bentonite clay, silica, attapulgite clay and mixture thereof.

8. The ternary composition as claimed in claim 3 wherein, the anti foaming agent(s) for suspension concentrate (SC) is selected from polydimethylsiloxane, silicone antifoam emulsion, dimethyl siloxane, vegetable oil based antifoam, tallow based fatty acids and mixture thereof.

9. The ternary composition as claimed in claim 3 wherein, the preservative(s) for suspension concentrate (SC) is selected from sodium benzoate, 1,2-benzisothiazolin-3(2H)-one, sodium salt, 2-bromo-2-nitropropane-1,3-diol, formaldehyde, sodium o-phenyl phenate, 5-chloro-2-methyl-4-isothiazolin-3-one, 2-methyl-4-isothiazolin-3-one and mixture thereof.

10. The ternary composition as claimed in claim 3 wherein, the anti freezing agent(s) for suspension concentrate (SC) is selected from polypropylene glycol, ethylene glycol, propane diol, glycerine, urea, glycol, monoethylene glycol, diethylene glycol, polyethylene glycol, magnesium sulfate heptahydrate, sodium chloride and mixture thereof.

11. The ternary composition as claimed in claim 3 wherein, the thickner(s) for suspension concentrate (SC) is selected from xanthan gum, PVK, carboxymethyl celluloses, polyvinyl alcohols, gelatin, sodium carboxymethylcellulose, hydroxyethyl cellulose, sodium polyacrylate, modified starch, acacia gum and mixture thereof.

12. The ternary composition as claimed in claim 3 wherein, the emulsifier(s) for suspo emulsion (SE) is seleted from polyarylphenyl anionic ether sulfate, ammonium salt, salts of dodecylbenzene sulphonate, Ca-salts, amine salts, sulphonates of C11-C16 alkylbenzenes, alkylether sulphates, alkylphenoletherphosphates, ester phosphates, non-ionic surfactants, alkoxylated alcohols, alkylphenols, ethoxylated fatty acids, ethoxylated vegetable oil, ethoxylated castor oil, fatty acid esters, sorbitol and their ethoxylated derivative, ethoxylated amines, condensate of glycerol, catanionic emulsifiers, cationic amine, combination with an alkylsulphonate or ether sulphonate or ether phosphate, alkoxylated alcohol, alkoxylated alkylphenol, ethoxylated fatty acids, ethoxylated vegetable oil, ethoxylated tristyrylphenol, tristyrlphenol with 16 moles EO, tristyrylphenol-polyglycolether-phosphate, fatty acid esters of sorbitol and ethoxylated derivative, ethoxylated amine, condensate of glycerol, sulfonated alkylbenzene in the range C11-C16 and salt thereof, alkylether sulphate, alkyletherphosphate, alkylphenoletherphosphate, salts of phosphate ester of ethoxylated tristyrylphenol, salt of sulphated ether of ethoxylated tristyrylphenol, catanionic system, alkylsulphonate, alkylethersulphonate, ether sulphate, ether phosphate, alkyletherphosphate, nonylphenol polyethoxy ethanol, castor oil polyglycol ether, polyadduct of ethylene oxid, polypropylene, tributyl phenoxy polyethoxy ethanol, octyl phenoxy polyethoxy ethanol and mixture thereof.

13. The ternary composition as claimed in claim 3 wherein, the dispersing agent(s) for suspo emulsion (SE) is seleted from acrylic graft copolymer, butyl polyalkylene oxide block copolymer, polyester, polyamide, poly-carbonate, polyurea, polyurethane, acrylic polymer, acrylic graft copolymer, styrene copolymer, butadiene copolymer, polysaccharide, starch and derivative, cellulose derivative, vinylalcohol, vinylacetate, vinylpyrrolidone polymer and copolymer, polyether, epoxy, phenolic resin, melamine resin, polyolefin and define copolymer, acrylate polymer, poly(methacrylate), poly(ethyl methacrylate), poly(methylmethacrylate), acrylate copoylmer, styrene-acrylic copolymer, poly(styrene-co maleic anhydride), cellulosic polymer, ethyl cellulose, cellulose acetate, cellulose acetatebutyrate, acetylated mono, di, and triglyceride, poly(vinylpyrrolidone), vinyl acetate polymers and copolymer, poly(alkylene glycol), styrene butadiene copolymer, poly(orthoesters), alkyd resin, biodegradable polyester, starch, polylactic acid starch blend, polylactic acid, poly(lactic acid-glycolic acid) copolymer, polydioxanone, cellulose ester, ethyl cellulose, cellulose acetate butyrate, starch ester, starch esteraliphatic polyester blend, modified corn starch, polycaprolactone, poly(namylmethacrylate), wood rosin, polyanhydride, polyvinylalcohol, polyhydroxybutyratevalerate, biodegradable aliphatic polyester, polyhydroxybutyrate, alkylated naphthalene sulfonate, sodium salt, sodium salt of naphthalene sulfonate condensate, sodium salt of alkyl naphthalene sulfonate, sodium ligno sulfonate, sodium ploycarboxylate, EO/PO block copolymer, phenol sulfonate, sodium methyl oleoyl taurate, styrene acrylic acid copolymer, propyleneoxide-ethyleneoxide-copolymer, polyethylene glycol 2,4,6-tristyrylphenyl ether, tristyrylphenol-polyglycolether-phosphate, tristyrylphenole with 16 moles EO, tristyrylphenol-polyglycolether-phosphate, oleyl-polyglycolether with ethylene oxide, tallow fattyamine polyethylene oxide, nonylphenol polyglycolether with 9-10 moles ethylene oxide and mixture thereof.

14. The ternary composition as claimed in claim 3 wherein, the suspending agent(s) for suspo emulsion (SE) is seleted from aluminum magnesium silicate, bentonite clay, silica, silicone dioxide, attapulgite clay and mixture thereof.

15. The ternary composition as claimed in claim 3 wherein, the anti foaming agent(s) for suspo emulsion (SE) is seleted from polydimethylsiloxane, silicone oil, silicone compound, C10~C20 saturated fat acid compound, C8~C10 aliphatic alcohol compound, silicone antifoam emulsion, dimethylsiloxane, vegetable oil based antifoam, tallow based fatty acids, polyalkyleneoxide modified polydimethylsiloxane and mixture thereof.

16. The ternary composition as claimed in claim 3 wherein, the preservative(s) for suspo emulsion (SE) is seleted from 1,2-benzisothiazolin-3(2H)-one, propionic acid and its sodium salt, sorbic acid and its sodium or potassium salt, benzoic acid and its sodium salt, p-hydroxy benzoic acid sodium salt, methyl p-hydroxy benzoate, biocide, sodium benzoate, 1,2-benzisothiazoline-3-one, 2-methyl-4-isothiazolin-3-one, 5-chloro-2-methyl-4-isothiazolin-3-one, potassium sorbate, para hydroxy benzoate and mixture thereof.

17. The ternary composition as claimed in claim 3 wherein, the buffering agent(s) for suspo emulsion (SE) is seleted from citric acid, calcium hydroxyapatite, potassium dihydrogen phosphate, sodium hydroxide, carbonated apatite, calcium carbonate, sodium bicarbonate, tricalcium phosphate, calcium phosphate, carbonated calcium phosphate, amine monomer, lactate dehydrogenase, magnesium hydroxide and mixture thereof.

18. The ternary composition as claimed in claim 3 wherein, the anti freezing agent(s) for suspo emulsion (SE) is seleted from polypropylene glycol, ethylene glycol, propane diol, glycerine, urea, glycol, monoethylene glycol, diethylene glycol, polypropylene glycol, polyethylene glycol, glycerine, urea, magnesium sulfate heptahydrate, sodium chloride and mixture thereof.

19. The ternary composition as claimed in claim 3 wherein, the thickner(s) for suspo emulsion (SE) is seleted from xanthan gum, montmorillonite, bentonite, magnesium aluminum silicate, attapulgite, guar gum, locust bean gum, carrageenam, xanthan gum, alginates, methyl cellulose, sodium carboxymethyl cellulose (SCMC), hydroxyethyl cellulose (HEC), modified starch, polyacrylate, polyvinyl 20 alcohol and polyethylene oxide and mixture thereof.

20. The ternary composition as claimed in claim 3 wherein, the solvent(s) for suspo emulsion (SE) is seleted from aromatic solvent C-9, water, water soluble alcohol, dihydroxy alcohol ether, methanol, ethanol, n-propanol, isopropanol, n-butanol, tert-butanol, polyethylene glycol, sorbitol, glucitol, dihydroxy alcohol ether, dihydroxy alcohol alkyl ether, dihydroxy alcohol aryl ether, ethylene glycol methyl ether, diethylene glycol methyl ether, propylene glycol methyl ether, di-propylene glycol methyl ether, ethylene glycol ethyl ether, diethylene glycol ethyl ether, propylene glycol ethyl ether, di-propylene glycol ethyl ether, ethylene glycol phenyl ether, 5 diethylene glycol phenyl ether, propylene glycol phenyl ether, di-propylene glycol phenyl ether, hydrocarbon, n-pentane, hexane, cyclohexane, methylcyclohexane, heptane, isooctane, benzene, toluene, xylene, isophorone, ester solvent, methyloleate, dimethylamide, morpholineamide derivative of C6-C16 fatty acid, mono-alkylene carbonate, ethylene carbonate, propylene carbonate, butylene carbonate, dimethylsulfoxide (DMSO), 2-ethylhexanol, n-butanol, n-alkylpyrrolidone, fatty acid dimethyl ester, fatty acid ester, dibasic ester, aromatic hydrocarbon, aliphatic hydrocarbon, dimethylamide, C8-dimethylamide, C10-dimethylamide, C12-dimethylamide, ethylene glycol, propylene glycol, polyalkylene glycol, aromatic hydrocarbon, methylpyrrolidinone (NMP), dimethylformamide (DMF), dimethylisosorbide (DMI), isophorone, acetophenone, 1,3-dimethyl-2-imidazolidonone, lactate ester, dimethyl, diethylcarbonate, alcohol, methanol, ethanol, iso-propanol, n-propanol, n-butanol, iso-butanol, tert-butanol, methyl L-lactate, 2-ethylhexyl L-lactate, ethyl L-lactate, n-butyl L-lactate, octyl phenol ethoxylate and mixture thereof.

21. The ternary composition as claimed in claim 3 wherein, the emulsifier(s) for mixed formulation (ZC) is seleted from alkylbenzene sulfonate calcium salt, tristyrylphenol polyethoxyester phosphate and mixture thereof.

22. The ternary composition as claimed in claim 3 wherein, the dispersing agent(s) for mixed formulation (ZC) is seleted from acrylic graft copolymer, sodium naphthalene sulphonate formaldehyde condensate, ethoxylated lignosulfonic acid salts, lignosulfonic acid salts, oxidized lignin, lignin salt, salt of styrenemaleic anhydride copolymer, polyvinyl alcohol, salt of partial ester of styrene-maleic anhydride copolymer, partial salt of polyacrylic acid, partial salts of polyacrylic acid terpolymer, lignosulfonate, modified kraft lignin, dibutylnaphthalenesulfonic acid, fatty acid, alkyl and alkylarylsulfonate, alkyl sulfate, lauryl ether sulfate and fatty alcohol sulfate, salt of sulfated hexa-, hepta- and octadecanol, fatty alcohol glycol ether, condensate of sulfonated naphthalene and its derivative with formaldehyde, condensate of naphthalene, naphthalenesulfonic acid with phenol and formaldhyde, polyoxyethylene octylphenol ether, ethoxylated isooctyl-, octyl-, nonylphenol, alkyl phenyl polyglycol ether, tributyl phenyl polyglycol ether, alkyl aryl polyether alcohol, tridecyl alcohol, fatty alcohol/ethylene oxide condensate, ethoxylated castor oil, polyoxyethylene alkyl ether, polyoxypropylene alkyl ether, lauryl alcohol polyglycol ether acetate, sorbitol ester, lignin-sulphite waste liquor, protein, denatured protein, polysaccharide, ammonium salt of sulfonate, sulfates, phosphate or carboxylate, alkylarylsulfonate, diphenyl sulfonate, alpha-olefin sulfonate, sulfonate of fatty acid and oil, sulfonate of ethoxylated alkylphenol, sulfonate of condensed naphthalene, sulfonate of dodecyl, tridecyl benzene, sulfonate of naphthalene, alkylnaphthalene, sulfosuccinate, alkoxylate, N-alkylated fatty acid amide, amine oxide, ester, sugar-based surfactant, alkylphenol, amine, tallow amine, amide, aryl phenol, fatty acid, fatty acid ester, ethylene oxide, propylene oxide, polyethylene oxide, polypropylene oxide, polyacid, polybase and mixture thereof.

23. The ternary composition as claimed in claim 3 wherein, the suspending agent(s) for mixed formulation (ZC) is seleted from attapulgite clay, aluminium magnesium silicate, bentonite clay, silica and mixture thereof.

24. The ternary composition as claimed in claim 3 wherein, the anti foaming agent(s) for mixed formulation (ZC) is seleted from polydimethylsiloxane, silicone oil, silicone compound, C10~C20 saturated fat acid compounds, C8~C10 aliphatic alcohols compound, silicone antifoam emulsion, dimethyl siloxane, polydimethyl siloxane, vegetable oil based antifoam, tallow based fatty acids, polyalkyleneoxide modified polydimethylsiloxane and mixture thereof.

25. The ternary composition as claimed in claim 3 wherein, the preservative(s) for mixed formulation (ZC) is seleted from 1,2-benzisothiazolin-3(2H)-one, sodium salt, sodium benzoate, 2-bromo-2-nitropropane-1,3-diol, formaldehyde, sodium o-phenyl phenate, 5-chloro-2-methyl-4-isothiazolin-3-one, 2-methyl-4-isothiazolin-3-one and mixture thereof.

26. The ternary composition as claimed in claim 3 wherein, the anti freezing agent(s) for mixed formulation (ZC) is seleted from polypropylene glycol, ethylene glycol, propane diol, glycerine, urea, glycol, monoethylene glycol, diethylene glycol, polyethylene glycol, magnesium sulphate heptahydrate, sodium chloride and mixture thereof.

27. The ternary composition as claimed in claim 3 wherein, the thickner(s) for mixed formulation (ZC) is seleted from xanthan gum, carboxy methyl cellulose, attapulgite clay, bentonite clay and mixture thereof.

28. The ternary composition as claimed in claim 3 wherein, the wall forming material(s) for mixed formulation (ZC) is seleted from 4,4’-diphenylmethane diisocyanate, diethylene triamine, tetramethylene diisocyanate, pentamethylene diisocyanate, hexamethylene di-isocyanate, toluene di-isocyanate, 4,4’-diphenylmethane diisocyanate (MDI), polymethylene polyphenylene isocyanate, 2,4,4’-diphenyl ether tri-isocyanate, 3,3’-dimethyl-4,4’-diphenyl diisocyanate, 3,3’-dimethoxy-4,4’-diphenyl diisocyanate, 1,5-naphthylene diisocyanate, 4,4’4"-triphenylmethane tri-isocyanate, toluene diisocyanate or polymethylene polyphenylisocyanate, polyurethane comprising of polyfunctional iso cyanate and a polyamine in polarized form

29. The ternary composition as claimed in claim 3 wherein, the solvent(s) for mixed formulation (ZC) is seleted from mixture of heavy aromatic hydrocarbons, hydrocarbon solvent such a an aliphatic, cyclic and aromatic hydrocarbons (for example toluene, xylene, paraffin, tetrahydronaphthalene, alkylated naphthalene or their derivatives, mineral oil fractions of medium to high boiling point (such as kerosene, diesel oil, coal tar oils)); a vegetable oil such as corn oil, rapeseed oil; a fatty acid ester such as C1-C10-alkylester of a C10-C22-fatty acid; or, methyl or ethyl esters of vegetable oils such as rapeseed oil methyl ester or corn oil methyl ester, acetophenone, 2-heptanon, 3-heptanone, 2-hexanone, 5-methyl-2-hexanone, 5-methyl-3-heptanone, 3-methyl-2-hexanone, 4-methyl-2-hexanone, 2-methyl-3-hexanone, 4-methyl-3-hexanone, 5-methyl-3-hexanone, 3-ethyl-2-pentanone, 3,3-dimethyl-2-pentanone, 3,4-dimethyl-2-pentanone, 4,4-dimethyl-2-pentanone, 2,2-dimethyl-3-pentanone, 2,4-dimethyl-3-pentanone, 2-octanone, 2,5-dimethyl-3-hexanone, 2,2-dimethyl-3-hexanone, 3,3-dimethyl-2-hexanone, 3,4-dimethyl-2-hexanone, 4,4-dimethyl-3-hexanone, 3-ethyl-4-methyl-2-pentanone, 2-methyl-3-heptanone, 2-methyl-4-heptanone, 3-methyl-2-heptanone, 3-methyl-4-heptanone, 5-methyl-3-heptanone, 6-methyl-2-heptanone, 6-methyl-3-heptanone, 3-octanone, 4-octanone, 2,2,4-trimethyl-3-pentanone, 3-ethyl-3-methyl-2-pentanone, 5-methyl-2-heptanone, isoprene and mixture thereof.

30. The ternary composition as claimed in claim 3 wherein, the emulsifier(s) for oil dispersion (OD) is seleted from polyoxyethylene sorbitol hexaoleate, ethoxylated sorbitan ester, castor oil ethoxylate, alcohol ethoxylate, fatty acid ethoxylate, sulphosuccinate, calcium salt of dodecylbenzene sulphonate, alkylammonium salt of alkylbenzene sulphonate, alkylsulphosuccinate salt, ethylene oxide-propylene oxide block copolymer, ethoxylated alkylamine, ethoxylated alkyl phenol, polyoxyethylene sorbitan monolaurate and mixture thereof.

31. The ternary composition as claimed in claim 3 wherein, the dispersing agent(s) for oil dispersion (OD) is seleted from salt of polyolefin condensate, styrene acrylic polymer, alkyl sulfonate, alkyl benzene sulfonate, alkyl aryl sulfonate, alkylphenolalkoxylate, tristyrylphenol ethoxylate, natural or synthetic fatty ethoxylate alcohol, natural or synthetic fatty acid alkoxylate, natural or synthetic fatty alcohol alkoxylate, alkoxylated alcohol, n-butyl alcohol poly glycol ether, block copolymer, ethylene oxide-propylene oxide block copolymer, ethylene oxide-butylene oxide block copolymers, fatty acid-polyalkylene glycol condensate, polyamine-fatty acid condensate, polyester condensate, salts of polyolefin condensate, sodium ligno sulfonate, sodium ploycarboxylate, EO/PO based copolymer, phenol sulfonate, sodium methyl oleoyl taurate, styrene acrylic acid copolymer, propyleneoxide-ethyleneoxide-copolymer, polyethylene glycol 2,4,6-tristyrylphenyl ether, tristyrylphenol-polyglycolether-phosphate, tristyrylphenole with 16 moles EO, tristyrylphenol-polyglycolether-phosphate, oleyl-polyglycolether with ethylene oxide, tallow fattyamine polyethylene oxide, nonylphenol polyglycolether with 9-10 moles ethylene oxide and mixture thereof.

32. The ternary composition as claimed in claim 3 wherein, the solvent(s) for oil dispersion (OD) is methylated seed oil, vegetable oil, plant, seed or tree oil, alkylated or ethoxylated or esterified, methylated vegetable oil, ethylated vegetable oil, olive oil, kapok oil, castor oil, papaya oil, camellia oil, sesame oil, corn oil, rice bran oil, cotton seed oil, soybean oil, groundnut oil, rapeseed-mustard oil, linseed oil, tung oil, sunflower oil, safflower oil, coconut oil, alkyl ester of vegetable oils, methyl ester, ethyl ester, propyl ester or butyl ester of vegetable oils, polyalkyleneoxide modified polydimethylsiloxane alkylphenol ethoxylate, rapeseed oil methyl ester, rapeseed oil ethyl ester, rapeseed oil propyl esters, rapeseed oil butyl esters, soybean oil methyl ester, soybean oil ethyl ester, soybean oil propyl ester, soybean oil butyl ester, castor oil methyl ester, castor oil ethyl ester, castor oil propyl ester, castor oil butyl ester, cotton seed oil methyl ester, cotton seed oil ethyl ester, cotton seed oil butyl ester, cotton seed oil propyl ester, tall oil fatty acids esters-tallow methyl ester, tallow ethyl ester, tallow propyl ester, bio-diesel, mineral oil, aromatic solvents, isoparaffin, base solvent, fatty acid amides, C1-C3 amines, alkylamines, alkanolamines with C6–C18 carboxylic acids, fatty acids, alkyl esters of fatty acids, methyl and ethyl oleate, methyl, ethyl soyate, alkyl benzenes, alkylnaphthalenes, polyalkylene glycol ethers, fatty acid diesters, fatty alkylamides and diamides, dialkylene carbonates, ketones and alcohols and mixture thereof.

33. The ternary composition as claimed in claim 3 wherein, the rheology modifier for oil dispersion (OD) is bentonite clay.

34. The ternary composition as claimed in claim 3 wherein, the dispersing agent(s) for water dispersible granule/ wettable granule (WG/WDG) is selected from modified sodium lignosulphonate, modified polyacrylate copolymer, alkylnaphthalene sulfonate sodium salt, sodium polycarboxylate, naphthalene sulfonic acid, sodium salt condensate with formaldehyde, polyalcoxylated alkylphenol, naphthalene sulfonic acid formaldehyde condensate, methyl naphthalene-formaldehyde-condensate sodium salt, naphthalene condensate, lignosulfonate, polyacrylate, phosphate ester, calcium lignosulfonate, lignin sulfonate sodium salt and mixture thereof.

35. The ternary composition as claimed in claim 3 wherein, the wetting agent(s) for water dispersible granule/ wettable granule (WG/WDG) is selected from sodium isopropyl naphthalene sulfonate, sodium N-methyl-N-oleoyl taurate, alkylated naphthalene sulfonate, sodium salt, mixture of isomer of dibutyl naphthalene sulphonic acid sodium salt, sodium di-isopropyl naphthalene sulphonate, sodium lauryl sulfate, dioctyl sulfate, alkyl naphthalene sulfonate, phosphate ester, sulphosuccinate, non-ionic, tridecyl alcohol ethoxylate, alkyl or alkaryl sulfonate, alkylbenzene sulfonate, alpha olefin sulfonate, alkyl naphthalene sulfonate, ethoxylated or non-ethoxylated alkyl or alkaryl carboxylate, alkyl or alkaryl phosphate ester, alkyl polysaccharide, di or mono alkyl sulfosuccinate derivative, alpha olefin sulfonate, alkyl naphthalene sulfonate, dialkyl sulphosuccinate, butyl, dibutyl, isopropyl, di-isopropyl naphthalene sulfonate salt, C12 alkyl benzene sulfonate or C10-C16 alkyl benzene sulfonate, organosilicon surfactant, trisiloxane ethoxylate, polydimethylsiloxane, polyoxyethylene methyl polysiloxane, polyoxyalkylene methyl polysiloxane, polyether polymethyl siloxane copolymer, trisiloxane heptamethyl, polyalkyleneoxide modified heptamethyl trisiloxane, polyether modified polysiloxane and mixture thereof.

36. The ternary composition as claimed in claim 3 wherein, the antifoaming agent for water dispersible granule/ wettable granule (WG/WDG) is polydimethylsiloxane.

37. The ternary composition as claimed in claim 3 wherein, the carrier(s) for water dispersible granule/ wettable granule (WG/WDG) is selected from corn starch, china clay, silica, lactose anhydrous, ammonium sulfate, sodium sulfate anhydrous, urea, EDTA, urea formaldehyde resin, diatomaceous earth, kaolin, kieselguhr, fuller's earth, attapulgite clay, bole, loess, talc, chalk, dolomite, limestone, lime, calcium carbonate, powdered magnesia, magnesium oxide, magnesium sulphate, sodium chloride, gypsum, calcium sulphate, pyrophyllite, silicate, silica gel, ammonium sulphate, ammonium phosphate, ammonium nitrate, grain meal, flour, bark meal, wood meals, nutshell meal, cellulosic powder, synthetic polymeric material, ground or powdered plastic, resin, bentonite, zeolite, titanium dioxide, iron oxide and hydroxide, aluminium oxide and hydroxide, bagasse, charcoal, synthetic organic polymer and mixture thereof.