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A Cationized Silicone Composition For Efficient Delivery Of Cationized Silicone

Abstract: N/A

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Patent Information

Application #
Filing Date
29 January 2003
Publication Number
0
Publication Type
INA
Invention Field
CHEMICAL
Status
Email
Parent Application
Patent Number
Legal Status
Grant Date
2007-05-23
Renewal Date

Applicants

HINDUSTAN UNILEVER LIMITED
HINDUSTAN LEVER HOUSE, 165/166, BACKBAY RECLAMATION, MUMBAI - 400 020., MAHARASHTRA

Inventors

1. PAUL SUDIPTO KUMAR
FLAT 502, SPRINGLEAF, SEVEN BUNGALOWS, VERSOVA, ANDHERI (WEST), MUMBAI - 400 061, MAHARASHTRA

Specification

FORM -2 THE PATENTS ACT, 1970 (39 of 1970) COMPLETE SPECIFICATION (See Section 10; RULE 13) IMPROVED POLYMCn COMPOSITION HINDUSTAN LEVER LIMITED, a company incorporated under the Indian Companies Act, 1913 and having its registered office at Hindustan Lever House, 165/166, Backbay Reclamation, Mumbai -400 020, Maharashtra, India The following specification particularly describes the nature of the invention and the manner in which it is to be performed. FIELD OF THE INVENTION: The present invention relates to a Cationised silicone composition and in particular to a Cationised silicon system/composition suitable for deposition of desired amounts of silicones as benefit agents on substrates such as hair, skin and the like from a variety of formulations, in particular rinse-off cleansing/care formulations for cosmetic applications. BACKGROUND OF THE INVENTION: Silicones are known to provide a light, silky feel on hair and skin. However, when silicones are incorporated in bar soaps at very low dosages, they have a tendency to wash off along with the soap, leaving no silicone residue on the skin and hair. When silicones are added to bar soaps in the form of fluids, they tend to become emulsified and the emulsion is washed away and shows no substantivity to skin and hair. Therefore, even very viscous fluids fail to provide the sensory benefits of silicones when applied through bar soaps. Compositions containing silicones also show reduced lather formation. US 5,154,849 discloses a mild skin cleansing composition in the form of a bar comprising from about 0.5% to about 20% of a mixture of a silicone gum and a silicone fluid wherein the gum:fluid ratio is from about 10:1 to about 1:10, preferably from about 4:1 to about 1:4, most preferably from about 3:2 to about 2:3. The silicone component is a skin mildness/moisturising aid which imparts superior, durable conditioning to skin washed with the composition. Processes for preparing a mild skin cleansing toilet bar with this silicone component are disclosed. US 5,661,120 describes detergent bar compositions comprising liquid silicone compounds or emulsions of said compounds which are used in relatively small levels as processing aids. These compounds allow pellets coming off a chill roll or refiner to be less tacky such that they do not readily clog machinery when the pellets are transferred to silos. US 5,981,465 teaches a method for increasing surface deposition of silicone from soap and improving processing characteristics of soap and a corresponding composition are disclosed. The composition includes a fatty alkyl silicone, a fatty silicate ester, a high 2 viscosity lower alkyl silicone fluid, a silicone surfactant, and an organic surfactant. The organic surfactant is one or more of a nonionic, cationic or anionic surfactants . It is also known to use phase transfer catalyst and quaternizing agents, to achieve cationisation of organic polymers and their complexes. Cationised amodimethicone is described in the art. Cationised complexes offer superior substantivity to biological surfaces. Thus considering that silicones are well known to impart desired sensory /cosmetic benefit on deposition on substrates such as skin, hair and the like there has been a constant need in the art to provide for effective silicone delivery systems which could provide for the desired delivery of the silicones on substrates such as from rinse-off formulations and the like. However it has been found that the form of the silicone and its compatibility with the formulation where it is desired to be incorporated is important and it has been extremely difficult to provide for silicones which could be easily incorporated in any variety of formulations for effective delivery on biological substrates. It is found that presently available silicones either are difficult to incorporate in a soap bar because of their high viscosity or when incorporated the composition does not offer perceivable benefits. OBJECTS OF THE INVENTION: It has thus been the basic objective of the present invention to provide for a silicone delivery system suitable for incorporation in a wide range of cosmetic or other rinse-off formulations which would serve for effective delivery of the silicone(s) for desired benefit attributes. Another object of the present invention is to provide for cationised silicones and/or cationised silicone delivery systems which would provide the desired flexibility to incorporate cationic silicones either as such or through dispersions or emulsions using nonionic, cationic and anionic surfactants in bar soap formulations. Yet another object of the present invention is directed to provide cationised silicones and/or cationised silicone delivery systems which would provide for desired delivery 3 ind retention of the silicone actives on any biological substrate even when delivered ram rinse-off formulations. 'et further object of the present invention is directed to provide cationised silicones ind/or cationised silicone delivery systems which can be used as such or as an smulsion or dispersion and added to soap noodles or converted to a granular additive with conventional fillers and added directly to soap. SUMMARY OF THE INVENTION: Thus according to the basic aspect of the present invention there is provided a cationised silicone delivery system comprising a cationised silicone active selected from one or more of (a) a cationised fatty alkyl silicone copolymer; (b) cationised dimethiconol complex and (c) cationised high viscosity lower alkyl silicone fluid with or without cationised silicone gum blend. In accordance with a preferred aspect the cationised silicone delivery system comprise a selective synergistic blend of (a) 15 - 50 parts of a cationised fatty alkyl silicone copolymer; (b) 5 - 50 cationised dimethiconol complex and (c) 1 - 50 parts of a cationised high viscosity lower alkyl silicone fluid and cationised silicone gum blend. In accordance with another preferred aspect the cationised silicone delivery system comprise a selective synergistic blend of (a) 15 - 50 parts of a cationised fatty alkyl silicone copolymer; (b) 5 -50 cationised dimethiconol complex and (c) 1 -50 parts of a cationised high viscosity lower alkyl silicone fluid and cationised silicone gum blend and (d) 2-10 parts of an organic surfactant. In the above disclosed cationised silicone delivery system, for the cationised fatty alkyl silicone copolymer, alkyl is defined as a branched or straight alkyl chain containing 10 to 80 carbon atoms, and fatty is defined as a fatty acid with a straight chain containing 10 to 30 carbon atoms. The viscosity range of the fatty alkyl silicone copolymer is 0.5 x 105 to 5 x 106cp (centi poise). Preferred alkyl chain contains 60 carbon atoms and the preferred fatty acid contains 16 to 18 carbon atoms. The preferred viscosity range for the polymer is 1 x 105 to 1 x 106cp. 4 The cationised dimethiconol complex has a viscosity range from 1 x 10 to 50 x 10 cp and preferably 10 x 106 to 20 x 106 cp. The cationised high viscosity lower alkyl silicone fluid has a viscosity range of 0.5 x 106 - 600 x 106 cp. The blend of fluid to gum is x : 1, with x varying from 0.1 to 20 and preferably 1. The organic surfactant can be selected from the group of nonionic, cationic and anionic surfactants. In accordance with another aspect of the present invention there is provided process for producing the cationised silicone system of toe invention -comprising providing the said cationised silicone actives selected from one or more of (a) a cationised fatty alkyl silicone copolymer; (b) cationised dimethiconol complex and (c) cationised a high viscosity lower alkyl silicone fluid with or without cationised silicone gum blend following conventional cationizing process. The cationisation process is described hereunder. In a 1500ml reactor, 1000g of silicone fluid (mix of cationised fatty alkyl silicone copolymer, cationised dimethiconol complex and cationised a high viscosity lower alkyl silicone fluid with or without cationised silicone gum blend, in the required ratios) and 100g of iso-propyl alcohol are thoroughly mixed usjng mechanical stirrer. The process is conducted in an inertpmosphere with nitrogen blanketingj^fter heating to 70 C, 10g /q"uaternizing catalystjand 10g dimethylsulphate mixture are added. The fgacto)r Is maintained at 70 C for 4 hrs under nitrogen atmosphere. After the

Documents

Application Documents

# Name Date
1 108-mum-2003-abstract.pdf 2018-08-08
1 108-mum-2003-form-pct-isa-210(29-01-2003).pdf 2003-01-29
2 108-MUM-2003-CLAIMS(GRANTED)-(23-5-2007).pdf 2018-08-08
2 108-mum-2003-form 3(29-01-2003).pdf 2003-01-29
3 108-mum-2003-form 1(29-01-2003).pdf 2003-01-29
3 108-mum-2003-claims.pdf 2018-08-08
4 108-mum-2003-power of attorney(19-03-2003).pdf 2003-03-19
4 108-MUM-2003-CORRESPONDENCE(IPO)-(16-7-2007).pdf 2018-08-08
5 108-mum-2003-form 5(27-01-2004).pdf 2004-01-27
5 108-mum-2003-correspondence(ipo).pdf 2018-08-08
6 108-mum-2003-form 3(27-01-2004).pdf 2004-01-27
6 108-MUM-2003-CORRESPONDENCE(RENEWAL PAYMENT LETTER)-(5-2-2010).pdf 2018-08-08
7 108-mum-2003-form 2(granted)-(27-01-2004).pdf 2004-01-27
7 108-mum-2003-correspondence.pdf 2018-08-08
8 108-MUM-2003-DESCRIPTION(GRANTED)-(23-5-2007).pdf 2018-08-08
9 108-mum-2003-description(granted).pdf 2018-08-08
9 108-mum-2003-form 19(27-01-2004).pdf 2004-01-27
10 108-mum-2003-correspondence-2-(27-01-2004).pdf 2004-01-27
10 108-mum-2003-form 1.pdf 2018-08-08
11 108-mum-2003-claims(granted)-(27-01-2004).pdf 2004-01-27
11 108-MUM-2003-FORM 2(GRANTED)-(23-5-2007).pdf 2018-08-08
12 108-mum-2003-form 2(granted).pdf 2018-08-08
13 108-mum-2003-correspondence(ipo)-(07-02-2005).pdf 2005-02-07
13 108-MUM-2003-FORM 2(TITLE PAGE)-(GRANTED)-(23-5-2007).pdf 2018-08-08
14 108-mum-2003-canclled pages(28-02-2005).pdf 2005-02-28
14 108-MUMNP-2003-CORRESPONDENCE (PRIORITY DOCUMENTS).pdf 2018-08-08
15 108-MUM-2003-CORRESPONDENCE(RENEWAL PAYMENT LETTER)-(26-12-2008).pdf 2008-12-26
15 108-mum-2003-correspondence-1-(12-01-2006).pdf 2006-01-12
16 108-MUM-2003-CORRESPONDENCE(RENEWAL PAYMENT LETTER)-(26-12-2008).pdf 2008-12-26
16 108-mum-2003-correspondence-1-(12-01-2006).pdf 2006-01-12
17 108-MUMNP-2003-CORRESPONDENCE (PRIORITY DOCUMENTS).pdf 2018-08-08
17 108-mum-2003-canclled pages(28-02-2005).pdf 2005-02-28
18 108-mum-2003-correspondence(ipo)-(07-02-2005).pdf 2005-02-07
18 108-MUM-2003-FORM 2(TITLE PAGE)-(GRANTED)-(23-5-2007).pdf 2018-08-08
19 108-mum-2003-form 2(granted).pdf 2018-08-08
20 108-mum-2003-claims(granted)-(27-01-2004).pdf 2004-01-27
20 108-MUM-2003-FORM 2(GRANTED)-(23-5-2007).pdf 2018-08-08
21 108-mum-2003-correspondence-2-(27-01-2004).pdf 2004-01-27
21 108-mum-2003-form 1.pdf 2018-08-08
22 108-mum-2003-description(granted).pdf 2018-08-08
22 108-mum-2003-form 19(27-01-2004).pdf 2004-01-27
23 108-MUM-2003-DESCRIPTION(GRANTED)-(23-5-2007).pdf 2018-08-08
24 108-mum-2003-form 2(granted)-(27-01-2004).pdf 2004-01-27
24 108-mum-2003-correspondence.pdf 2018-08-08
25 108-MUM-2003-CORRESPONDENCE(RENEWAL PAYMENT LETTER)-(5-2-2010).pdf 2018-08-08
25 108-mum-2003-form 3(27-01-2004).pdf 2004-01-27
26 108-mum-2003-form 5(27-01-2004).pdf 2004-01-27
26 108-mum-2003-correspondence(ipo).pdf 2018-08-08
27 108-mum-2003-power of attorney(19-03-2003).pdf 2003-03-19
27 108-MUM-2003-CORRESPONDENCE(IPO)-(16-7-2007).pdf 2018-08-08
28 108-mum-2003-form 1(29-01-2003).pdf 2003-01-29
28 108-mum-2003-claims.pdf 2018-08-08
29 108-mum-2003-form 3(29-01-2003).pdf 2003-01-29
29 108-MUM-2003-CLAIMS(GRANTED)-(23-5-2007).pdf 2018-08-08
30 108-mum-2003-form-pct-isa-210(29-01-2003).pdf 2003-01-29
30 108-mum-2003-abstract.pdf 2018-08-08

ERegister / Renewals

3rd: 28 Aug 2007

From 29/01/2005 - To 29/01/2006

4th: 28 Aug 2007

From 29/01/2006 - To 29/01/2007

5th: 28 Aug 2007

From 29/01/2007 - To 29/01/2008

6th: 27 Dec 2007

From 29/01/2008 - To 29/01/2009

7th: 26 Dec 2008

From 29/01/2009 - To 29/01/2010

8th: 04 Dec 2009

From 29/01/2010 - To 29/01/2011