TITLE:
A method for producing alkaline earth metal salt based soft coatings on
multishaped metallic structures.
FIELD OF THE INVENTION:
This invention relates to a method for producing alkaline earth metal salt
based soft coatings on multishaped metallic structures.
BACKGROUND OF THE INVENTION:
Complex shaped metallic structures are susceptible to corrosion at the edges
and curvature points. The metallic tubes are highly corrosion
susceptible,especially at their weld-able zone because of lacking in same
specification of metal as found in other parts. Therefore, it is necessary to
develop some formulation and methodologyfor mitigate the corrosion
problems in complex shaped metallic structures. Metal to metal friction may
cause the corrosion so wear prevention should also be maintained during
packaging, in online running line, transportation, storage and exposure of
rainy and humid atmosphere.
In recent, many of the coating formulations and non-drying rust preventive oils
have been developed to get better corrosion resistance and lubrication but

now the use of RPO has been obsoleted due to their non-adherence nature
on metals which may again increase the uptake of corrosive ion.
Researchers are advancing to develop the material which can save the time
and improve the performance as well. For this purpose, they are focusing the
material application during formation of steel in running line. Since steel
cutting and cooling consumes a lot of coolant inside and outside as well so the
prepare steel is already has some coolant over it i.e low tensed surfaces. The
challenge is to produce the formulation for low tensed surfaces b) high friction
may occur in running line so the challenge is to produce the formulation for
wear prevention.
For offline application, it is easy to develop the hard dried coatings but they
may be not feasible to the online application. So in this invention, with keeping
the all object, we have produced aalkaline earth metal based
soft/semidrying/drying up to tack free coating formulations which applicable on
low tensed surfaces by forming a dense thin layer, enhancing the water
repellent, reducing the uptake of corrosive ion and excellent wear prevention.
US 4180408 discloses polyvalent metal salts of oxidized and amidified non-
benzenoid hydrocarbon waxes and to use thereof, particularly in carbon paper

inks. The preferred types of oxidized hydrocarbons are the hard waxes such
as microcrystalline wax, C30+ alpha olefin fraction with melting point in the
range of 160°F to 220°F.
US 5155155 describes an oxidized polyethylene wax or other wax in the form
of a salt with a metal selected from groups 1B, 11B, MA, IIIA, 111B, VIB, VIIB
and VIIIB of the Periodic Table of the Elements acts as a photoactivator in a
polymer composition and degrades the latter. The quantity of the additive can
vary from 0.1 to 2.0% by weight, relative to the weight of the composition.
EP 2480612A1 teaches a corrosion-protective composition containing a wax,
an unsubstituted or substituted polyaniline in a doped form and a liquid
paraffin, and articles comprising the composition applied on a substrate,
particularly on steel. It also relates to a process for manufacturing the
composition, wherein i) a first dispersion of a polyaniline in a doped form is
prepared; and ii) the first dispersion of the polyaniline is combined with a wax
component to sufficiently disperse the polyaniline therein, and to the use of
the composition as a single layer coating for the protection against corrosion
of a substrate in need thereof.
EP 2476780 A1 discloses a rust preventive and lubricant non-drying oil
composition metallic parts such as steel plates, bearings, steel spheres, and

guide rails which is having at least one base oil selected from the group
consisting of mineral oils and synthetic oils, an aromatic content of <5% by
volume, a naphthene content of > 30% by volume and < 95% by volume
(CnH2n, CnH2n-2, CnH2n-4 ...), a solvent and rust preventive additives
include (A) sulfonates, (B) esters, (C) sarcosine compounds, (D) nonionic
surfactants, (E) amines, (F) carboxylic acids, (G) aliphatic amine salts, (H)
carboxylates, (I) paraffin waxes, (J) salts of oxidized wax, (K) boron
compounds, (L) alkyl or alkenyl succinic acid derivatives.
US 2573650 reveals improved lubricating grease composition and particularly
to water resistant inorganic gel greases and methods of preparing the same.
Partial esters of p.olyhydric alcohols and partial ethers of polyhydric alcohols
are effective water proofing agents such as mono-esters of glycerol in
hydrogenated castor oil with aerogel and alcohols. Water proofing property
makes such greases of particular interest in the lubrication of bearings
subjected to high temperatures such as in turbo jet engines and in steel rolling
mills.
US1970857 A teaches the development of an impervious formation of salts is
avoided by treating the surface of the plaster with an oily, greasy or non-
volatile fluid or dissolved wax before drying. The surface of the plaster is

coated with a grease, wax solution, oil (mineral or vegetable), or a non-volatile
material such as glycerine. It is preferred to use a substance which is soluble
in the water-proofing material, such as mineral oil or petrolatum. The coating
may be applied by dipping, spraying or brushing.
US7381249B2 describes a wax composition for application to a wet surfaces
utilizing a polymeric emulsion i.e dimethyl polysiloxane in water with a cross-
linked copolymer of acrylic acid and C10-30 alkyl acrylate, an organic iso-
paraffinic solvent,acorrosion inhibitor in an amount of from 0.0001 to 3.0 wt.%
by weight based on the total weight of the composition and the remainder of
the composition being water on vehicular exterior painted metal or painted
plastic surface, chrome, stainless steel, plastic moldings, vinyl tops and trim,
fiberglass, and/or rubber surfaces for their rust prevention.
OBJECTS OF THE INVENTION:
An object of the present invention is to propose a method for producing
alkaline earth metal salt based soft coatings on multishaped metallic
structures.

Another object of the present invention is to propose a method for producing
alkaline earth metal salt based coatings with inspired water repellent and anti-
corrosion properties.
Further object of the present invention is to propose a method to produce
alkaline earth metal salt which has lower surface tension required for
applicability on wet or oily surfaces.
Still another object of the present invention is to propose a method to produce
alkaline earth metal salt coating which is long sustainable in heavy frictional
conditions too.
BRiEF DESCRIPTION OF THE ACCOMPANYING DRAWINGS:
Figure 1 shows that FT-IR of Example 1
Figure 2 shows that FTIR of Example 2
Figure 3 shows that electrochemical polarization test of Example 1 and
Example 2
Figure 4 shows that water and acetone contact angle
Figure 5 shows the Chemical structure of (a) calcium/barium bis(2,3-
dinonylnaphthalene-1-sulfonate) (b) calcium/barium bis(2,3-dinonylnaphthalene-1-
carboxylate.

Figure 6: Show the chemical structures of (a) sodium 1,4-bis(2-ethylhexoxy)-1,4-
dioxobutane-2-sulfonate (b) sodium 1,4-bis(2-hexoxy)-1,4-dioxobutane-2-sulfonate
(c) calcium bis(1,3-bis(2-ethylhexoxy)-1,3-dioxopropane-2-sulfonate (d) calcium
bis(1,3-bis(2-hexoxy)-1,3-dioxopropane-2-sulfonate)
BRIEF DESCRIPTION OF THE INVENTION:
According to this invention there is provided a method for producing alkaline
earth metal salt based soft coatings on multishaped metallic structures
comprising; subjecting paraffin wax and metal hydroxide in a ratio of 1:2 to the
step of oxidation to form the resin part, mixing the resin part with non-polar
solvent, adding anti corrosive, surfactant emulsifying, agent and organic
derivative of bentonite clay, subjecting the coating structure to the step of
spraying.
DETAILED DESCRIPTION OF THE INVENTION:
The invention refers to the synthesis of soft coatings having low surface
tension either on low energised or clean multi-shaped metallic surfaces such
as wet/oily, providing wear preventive, water repellent, anticorrosive films. It
comprises the steps of: i. rendering different alkaline earth metal salts/paraffin
wax based oxidized hydrocarbon, synthesized by mixing metal hydroxide to

aliphatic oxidized hydrocarbons ii. rendering non-polar solvents for dissolution
of oxidized hydrocarbon iii. rendering calcium or barium based corrosion
inhibitor iv. rendering derivative of bentonite clay as a thixotropic agent v.
rendering metal dialkylsulfosuccinate salt for excellent emulsifying, filterability
and lubricity vi. putting altogether into a vessel and mixing by mechanical
stirrer at 400 rpm for 30 minutes v. applying this solution on multi-shaped
coolant soaked metallic structures either via spraying, dipping or brushing vii.
curing occurs up to tack free within 20-30 seconds at the temperature range of
25-27°C which provides 3-10 u thick film, enhancing the wear prevention,
corrosion resistance and water repellent properties, preferably on non-
spangled galvanized and non-temper hot rolled carbon steel.
The present invention provides a method of producing soft drying wax or
metal salt based coatings having low surface tension on low energized multi-
shaped metallic structures (especially on non-temper hot rolled carbon steel
and non-spangled galvanized tubes).
According to this invention, the said low energized surfaces are wet, oily and
rusty surfaces. More preferably, coolant soaked surfaces. The coolant
comprises of 2-10 wt. % of oil in 90-98 wt. % of demineralized water

preferably 2-5 wt. % oil in 95-98 wt. % of demineralized water more preferably
4 wt. % oil in 96 wt. % of demineralized water.
The present invention provides 15-50 wt. % of calcium salt of oxidized
hydrocarbon resin which is synthesized by mixing of calcium hydroxide/barium
hydroxide and oxidized hydrocarbon containing
methylmonostearate/monopalmatate/monomargaratein the ratio of 1:2, 1,2-
ethanedioldistearate/dipalmatate/dimargarate in the ratio of 1:1 and 1,2,3-
propane trioltristearate/tripalmatate/trimargarate in the ratio of 3:2. The
measured quantity of oxidized hydrocarbon and calcium hydroxide/barium
hydroxide is taken into the reactor and heat it up to 100-120°C. The drying
effect is due to high melting point of calcium salt/barium salt of oxidized wax.
Remove the heat source and add 20-60 wt. % of toluene and 10-40 wt. % of
xylene (non-polar solvents) with continuous stirring. Stirring is continued for an
hour till it forms clear solution. Add sulfosuccinate surfactant/sulfomalonate
surfactant about 0.05-2 wt. % followed by 1-3 wt. % of organic derivative of
bentonite clay as an anti-settling agent. The final as-obtained solution is clear
solution. About 0.5-3 wt. % of barium dinonyl naphthalene sulfonate/calcium
dinonyl naphthalene carboxylate/ calcium dinonyl naphthalene sulfonate in
mineral oil is added for enhancement in corrosion resistance. Chemical

reactions of metal salt (calcium or barium) based coating solution are shown
in reaction 1, 2 and 3.



The calcium salt/barium salt based oxidized hydrocarbon coating solution in
which the said calcium salt/barium salt based oxidized hydrocarbon based
resin is having at least one formula (CnH2n+1COO)2Ca/(CnH2n+1COO)2Ba in
which ester chain contains
CnH2n+1COO)3C3H5/(CnH2n+1COD)2C2H4/CnH2n+1COOCH3.
Hereto, n is15/16/17 and M is Calcium/Barium.
If n=15 and M is calcium or barium, then the said compound 1 is
(C15H31COO)3C3H5which named as "2,3-di(hexadecanoyloxy) propyl
hexadecanoate",
the said compound 4, 7 and 10 is
(C15H31COO)2Ca/(C15H31COO)2Ba which named as "calcium/barium salt of
hexadecanoate",

the said compound 5 is
(C15H31COO)2G2H4 which named as"2-hexadecanoyloxy ethyl
hexadecanoate",
the said compound 8 is
C15H31COOCH3 which named as "methyl hexadecanoate".
If n=16and M is calcium or barium, then the said compound 1 is
(C16H33COO)3C3H5 which named as "2,3-di(heptadecanoyloxy) propyl
heptadecanoate",
the said compound 4, 7 and 10 is
(C16H33COO)2Ca/(C16H33COO)2Ba which named as "calcium/barium salt of
heptadecanoate",
the said compound 5 is
(C16H33COO)2C2H4 which named as "2-heptadecanoyloxy ethyl
heptadecanoate",

the said compound 8 is
C16H33COOCH3 which named as"methyl heptadecanoate".
If n=17 and and M is calcium or barium, then the said compound 1 is
(C17H35COO)3C3H5 which named as "2,3-di(octadecanoyloxy) propyl
octadecanoate",
the said compound 4, 7 and 10 is
(C17H35COO)2Ca/(C17H35COO)2Ba which named as "calcium/barium salt of
octadecanoate",
the said compound 5 is
(C17H35COO)2C2H4 which named as "2-octadecanoyloxy ethyl octadecanoate",
the said compound 8 is
C16H33COOCH3 which named as "methyl octadecanoate".
Compound 1 crosslinks with compound 2, compound 5 crosslinks with
compound 2, compound 8 crosslinks with compound 2 at the temperature
range of 100-120°Cand produced calcium/barium salt based oxidized
hydrocarbon more particularly "calcium/barium salt of hexadecanoate,
calcium/barium salt of heptadecanoate and calcium/barium salt of
octadecanoate".

About 0.5-3 wt. % of barium dinonyl naphthalene sulfonate ((C28H43SO3)2Ba) /
calcium dinonylnaphthalene carboxylate ((C28H43COO)2Ca) /calcium dinonyl
naphthalene sulfonate ((C28H43SO3)2Ca) in mineral oil is used as ah anti-
corrosion additive in the ratio of 5:1 as shown in below structure.
About 0.05 - 2 wt. % of sulfosuccinate /sulfomalonate surfactant is used as an
emulsifying agent sulfosuccinate / sulfomalonate of calcium and sodium metal,
having the formula
C8H17-OOC-CH-(S03Na)CH2-COO-C8H17: dioctyl sulfosuccinate sodium salt
or sodium 1,4-bis(2-ethylhexoxy)-1,4-dioxobutane-2-sulfonate
C6H13-OOC-CH-(S03Na)CH2-COO-C6H13: dihexyl sulfosuccinate sodium salt
or sodium 1,4-bis(2-hexoxy)-1,4-dioxobutane-2-sulfonate;
(C8H17-OOC-CH-(S03)CH2-COO-C8H17)2Ca: dioctyl sulfomalonate calcium
salt or calcium bis(1,3-bis(2-ethylhexoxy)-1,3-dioxopropane-2-sulfonate
(C6H13-OOC-CH-(S03)CH2-COO-C6H13)2Ca: dihexyl sulfomalonate calcium
salt or calcium bis(1,3-bis(2-hexoxy)-1,3-dioxopropane-2-sulfonate) as shown
in below structures.
Typical properties of calcium/barium salt of oxidized hydrocarbon resin part
Melting point (ASTM D 87-09) = 100-120°C
Sp. gravity @15.6 °C (ASTM D 891-09) = 0.960 ± 0.1
% Non-volatile matter (ASTM D 1353-13) = 99 ± 1

The metal salt/wax based soft coatings in which the said application methods
are wiping, brushing, spraying and dipping, preferably spraying. The curing is
done 20-30 seconds at the temperature range of 25°-27°C and formadense
structure of coating for water repellence, high sustainability in heavy frictional
conditions (wear preventive) and corrosion resistance as described in Table 1.
EXAMPLES:
Example 1:
The present invention is to develop the formulation having 28.75 wt. %
calcium salt of oxidized hydrocarbon i.e calcium salt of octadecanoate which
is produced by the controlled oxidation of 2, 3-di(octadecanoyloxy) propyl
octadecanoate (paraffin wax) with calcium hydroxide salt (1:2) in a reactor at
120°C for 35 minutes.This is the resin part, providing lubricity, fast cures up to
tack free and film forming ability. This resin part is mixed with 68 wt. % of non-
polar solvent which is used for the dissolution of calcium salt of
octadecanoate. Particularly, 40 wt. % of toluene and 28 wt. % of xylene is
used. About 2 wt. % of calcium dinonyl naphthalene carboxylate in flaxseed oil
(1:5) is used to providing anticorrosion and water repellence properties. It also

provides 10 % waxy nature. About0.25 wt. % of anionic dioctylsulfosuccinate
surfactant, more specifically sodium dioctylsulfosuccinatefor excellent
emulsifying, filterability, and lubricity with dispersing ability is added then 1
wt.% of organic derivative of bentonite clay is mixed as a rheological modifier
for improving flow, levelling properties andsagging on vertical surfaces. This
coating solution is preferably applied by spraying method of 5 micron thick
which cures up to tack free within 20 seconds at 27°C.
Example 2
The present invention is to develop the formulation having 28.75 wt. % barium
salt of oxidized hydrocarbon i.ebarium salt of octadecanoate which is
produced by the controlled oxidation of selected 2,3-di(octadecanoyloxy)
propyl octadecanoate (paraffin wax) with barium hydroxide salt (1:2) in a
reactor at 120°C for 35 minutes. This is the resin part, providing lubricity, fast
curing up to tack free and film forming ability. This resin part is mixed with 68
wt. % of non-polar solvent which is used for the dissolution of barium salt of
octadecanoate. Particularly, 40 wt. % of toluene and 28 wt. % of xylene is
used. About 2 wt. % of bariumdinonyl naphthalene sulfonate in flaxseed oil is

used to providing anticorrosion and water repellence properties. It also
provides 10 % waxy nature. About 0.25 wt. % of anionic sulfosuccinate
surfactant, more specifically dioctylsulfomalonate calcium salt for excellent
emulsifying, filterability and lubricity with dispersing ability is added then 1 wt.
% organic derivative of bentonite clay is mixed as a rheological modifier for
improving flow, levelling properties and controls sagging on vertical surfaces.
This coating solution is applied by spraying method of 5 micron thick which
cures up to tack free within 20 seconds at 27°C.
Hereto, both invention is useful for automobile industry (Bolts, threaded parts,
tire trims, shock absorber and handle bar), oil industry (inside the condenser
box,' condenser oil), gas industry (Coal handling equipment, inside air and
water tanks), structural applications, plumbing applications.
The properties and ingredients of both inventions are shown in Table 1 and 2
respectively. Obtained FT-IRpeaks of resin part i.e oxidized hydrocarbon and
coating solutionsof both inventionsis demonstrated by FT-IR pictogram shown
in Fig. 1 and Fig.2.

In present invention, the film properties of both coating solutions are
approximately same, only the difference in corrosion resistance of the film to
the non-spangled galvanized substrate as shown by Fig.3 and Table 2. The
present invention is providing the coating solutions, exhibiting good corrosion
resistance. Calcium and barium based coated surfaces showed good
corrosion resistance in the range of 10-8 factor.
According to the ASTM D 2266, both inventions provide excellent lubricity and
wear prevention determined by four ball wear test method. The low level of
coefficient of friction (example 1: 0.0912; example 2: 0.0932) between coated
steel to steel (steel rollers) at 1200 rpm for 60 minutes in ultrasonic vibrator at
75 degree temperature by supplying the test load of 40 Kg and measure the
wear scars (average scar diameter of three test balls is 0.49 mm in example 1
and 0.63 mm in example 2) on the three balls fixed in ball cup with one ball
fixed in ball chuck below the three balls into the ultrasonic vibrator. The void
between balls is filled by coating solution (example 1 and 2).
The present invention provides the coating solution, having low or same
surface energy required to be applied on coolant drenched metallic surface
and water repellent properties required for providing water hydrophobicity.

The present invention provides the surface energy of coated galvanized
sample which is deduced by considering two liquid's contact angle on coated
substrate (One liquid is water and another is acetone) and their polar,
nonpolar components. Both coating solution (example 1 and 2) show lower
surface tension {Example 1:3.39mN/m (45.46 - 42.07) and Example 2:
4.14mN/n (45.46 - 41.32)} than the surface tension of coolant (51.89-45.46 =
6.43mN/m) which indicates the coating applicability on coolant drenched
surface. So both coating solution's surface tension and coated surface energy
is lower than solution of coolant's surface tension and coolant soaked surface
energy which is desired property for coating applicability on wet/coolant
soaked surface.
The said coated sample of example 1 and 2exhibits water repellent properties
(contact angle of coated sample of example 1:109.7° and example 2: 109.1°)

WE CLAIM:
1. A method for producing alkaline earth metal salt based soft coatings on low
energized multishaped metallic structures comprising;
subjecting paraffin wax or oxidized hydrocarbon and metal hydroxide in a ratio
of either 1:2, 3:2 or 1:1 to the step of oxidation to form a resin part at 100 -
120°C temperature in a reactor for 35 minutes.
mixing the 15 - 50 wt.% of the resin part with a non-polar solvent comrising 20
- 60 wt.% of toluene and 10 -40 wt.% of xylene,
adding 0.5 - 3 wt. % of an anti-corrosive, 0.05 - 2 wt. % of a surfactant or
emulsifying agent and 1- 3 wt. % of an organic derivative of bentonite clay as
an antisettling agent,
subjecting the coating structure to the step of spraying/brushing/dipping.
2. The method as claimed in claim 1, wherein said low energized surfaces
are wet, oily and rusty surfaces, preferably, coolant soaked surfaces.
3. The method as claimed in claim 2, wherein the coolant comprises of 2-
10 wt. % of oil in 90-98 wt. % of demineralized water, preferably 2-5 wt. % oil
in 95-98 wt. % of demineralized water, more preferably 4 wt. % oil in 96 wt. %
of demineralized water.

4. The method as claimed in claim 1 wherein the said metal hydroxide is
selected from calcium hydroxide and barium hydroxide.
5. The method as claimed in claim 1, wherein the said oxidized hydrocarbon
is having at least one formula (CnH2n+1COO)3C3H5/(CnH2n+1COO)2C2H4/
CnH2n+1COOCH3 which provide more polarity than simple fatty acids due to
their chemical nature and have a greater film forming ability. Here n varies
from 15 to 17.
6. The method as claimed in claim 5, wherein the said oxidized hydrocarbon
is (C15H31COO)3C3H5 "2,3-di(hexadecanoyloxy) propyl hexadecanoate" or "
1,2,3-propanetriol trimargarate";
(C15H31COO)2C2H4 "2- hexadecanoyloxy ethyl hexadecanoate" or " 1,2-
ethanediol dimargarate";
C15H31COOCH3 "methyl hexadecanoate" or "methyl monomargarate".
7. The method as claimed in claim 5, wherein the said oxidized hydrocarbon
is
(C16H33COO)3C3H5 "2,3-di(heptadecanoyloxy) propyl heptadecanoate" or
1,2,3-propanetriol tripalmatate";
(C16H33COO)2C2H4 "2- heptadecanoyloxy ethyl heptadecanoate" or 1,2-
ethanediol dipalmatate";
C16H33COOCH3 "methyl heptadecanoate" or "methyl monopalmatate".

8. The method as claimed in claim 5, wherein the said oxidized hydrocarbon
is
(C17H35COO)3C3H5, "2,3-di(octadecanoyloxy) propyl octadecanoate" or
"1,2,3-propanetriol tristearate";
(C17H35COO)2C2H4"2- octadecanoyloxy ethyl octadecanoate" or "1,2-
ethanediol distearate";
C17H35COOCH3 "methyl octadecanoate" or "methyl monostearate".
9. The method as claimed in claim 1, wherein said resin part is
One of the following:
(C15H31COO)2Ca/(C15H31COO)2Ba, "calcium/barium salt of hexadecanoate";
(C16H33COO)2Ca/(C16H33COO)2Ba, 'calcium/barium salt of heptadecanoate",
(C17H35COO)2Ca/(C17H35COO)2Ba, "calcium/barium salt of octadecanoate",
10. The method as claimed in claim 1, wherein the anti-corrosive agent is
alkaline earth metal dinonyl naphthalene sulfonate/carboxylate in flaxseed
oil in the ratio of 5:1.
11. The method as claimed in claim 10, wherein the anti-corrosive agent is
calcium dinonyl naphthalene sulfonate having the formula:
(C28H43SO3)2Ca.

12. The method as claimed in claim 10, wherein the anti-corrosive agent is
calcium dinonyl naphthalene carboxylate having the formula:
(C28H43COO)2Ca.
13. The method as claimed in claim 10, wherein the anti-corrosive agent is
dinonyl naphthalene sulfonate barium salt having the formula
(C28H43SO3)2Ba.

14. The method as claimed in claim 1, wherein the said surfactant used is
anionic sulfosuccinate / sulfomelonate of calcium and sodium metal.
15. The method as claimed in claim 14, wherein the
sulfosuccinate/sulfomalonate is oil soluble structures such as
C8H17-OOC-CH-(SO3Na)CH2-COO-C8H17: dioctyl sulfosuccinate sodium salt
or sodium 1,4-bis(2-ethylhexoxy)-1,4-dioxobutane-2-sulfonate;
C6H13-OOC-CH-(SO3Na)CH2-COO-C6H13: dihexyl sulfosuccinate sodium salt
or sodium 1,4-bis(2-hexoxy)-1,4-dioxobutane-2-sulfonate;
(C8H17-OOC-CH-(SO3)CH2-COO-C8H17)2Ca: dioctyl sulfomalonate calcium
salt or calcium bis(1,3-bis(2-ethylhexoxy)-1,3-dioxopropane-2-sulfonate
(C6H13-OOC-CH-(S03)CH2-COO-C6H13)2Ca: dihexyl sulfomalonate calcium
salt or calcium bis(1,3-bis(2-hexoxy)-1,3-dioxopropane-2-sulfonate).
16. The method as claimed in claim 1, wherein said organic derivative of
bentonite clay is betone 34.

17. The method as claimed in claim 1, wherein the coating solution is
applied either by spraying, brushing or dipping of 3-10 micron thickness
which cures up to tack free within 20-30 seconds at the temperature range
o f25-27°C.
18. The method as claimed in claim 1, wherein the said coating solution on
low energized multishaped metallic structures exhibits lubrication
properties in the range of 0.090 to 0.095 friction co-efficient as per Four
ball wear test method.
19. The method as claimed in claim 1, wherein the said coating solution on
low energized multishaped metallic structures exhibits anticorrosion
properties in terms of corrosion rate of 1 * 10-3 to 5* 10-3 mm/y.
20. The method as claimed in claim 1, wherein the said coating solution on
low energized multishaped metallic structures exhibits water repellent
properties in the range of 109° to 110° in terms of water contact angle.
21. The method as claimed in claim 1, wherein the coolant soaked
energized surface has energy in the range of 51 to 52.5 mN/m.