DESC:FIELD OF INVENTION:
The present invention relates to a synergistic a synergistic non-aqueous composition. agrochemical composition. More particularly the present invention relates to a synergistic a synergistic non-aqueous composition composition comprising bioactive amount of (A) Saflufenacil; (B) Atrazine; (C) At least one more herbicide selected from group of herbicides.The present invention further relates to selection of suitable formulation excipients, process of preparation of the said oil dispersion formulation and its application in the field of agriculture.

BACKGROUND OF THE INVENTION:
These days cultivation of crops and agriculture in general is cost intensive. Receiving a high yield from the cultivated crops is a key. Hence, to achieve higher yield, protecting crops from pests and diseases and weeds is vital.
Weeds are indesired or unwanted crop or plant which grows sometimes with the essential or desired crop plant and competes with the desired crop plant from an early stage in growth and development. This results in adverse effect on the growth of crop plant and yield.
In earleir days man power was utilised to remove weeds. Due to research and development in the field of an agriculture now a days chemicals are being used to kill or control the weeds.
It is desirable for the crop protection product to control the harmful plants effectively and, at the same time, to be tolerated by the useful plants in question. Thus selectivity of the crop protection product is essential to selectively kill the unwanted crops and saves the desired crop in the field.
The control of undesired vegetation is extremely important in order to achieve high crop efficiency. In many cases, herbicides have an effect against a spectrum of weeds; however, these herbicides may not be effective on certain type of other weeds, which may also be present in the crop to be protected. Therefore, there is a strong need for mixing two or more herbicides.
Hence, the most effective way to control weeds is the application of herbicide in accordance with the appropriate management practices with proper formulation thereof.
Treating plants with such a weedicide/herbicide(s) in appropriate formulation helps to control the weeds.
Various kinds of agrochemical formulations are developed based upon active ingredients and scope of application thereof. Pesticides for agriculture purpose are available both in the pure form and as well as incorporated into agrochemical formulations, which typically comprise one or more active ingredients (AIs) and additional excipients substances that enhance the effects and facilitate the application thereof, such as carriers, adjuvants or additives. These formulations can be directly applied onto the crops or, more commonly, are applied after being diluted and the spray mixture formed. The formulation type to be used is primarily defined on the basis of physicochemical characteristics of the AI(s) and can be: soluble concentrate (SL), emulsifiable concentrate (EC), emulsion in water (EW), suspension concentrate (SC), suspo-emulsion (SE), micro-emulsion (ME), oil dispersion (OD) or suspension concentrate (SC), dispersible concentrate (DC), capsule suspension (CS), dispersible granules (WG), wettable powder (WP) and others.
The various types of agrochemical formulations are the result of the existence of a large variety of AIs of different chemical natures. For example, a water soluble AI can be easily included into a water based SL while a high melting, water insoluble AI is commonly found in the form of a EC (Emulsifiable concentrate). For this reason, agrochemical formulations are distinct and can contain different inert components.
Oil dispersion (OD) formulations are non-aqueous dispersion intended for dilution into water before use, and represent the most complex of the non-aqueous suspension formulations. Oil dispersion (OD) formulations consist of a suspension of a solid technical in oil. The oil also serve as a carrier or solvent for additives. The oil dispersion is usually dispersed in water prior to spraying. Thus OD formulations are also called as adjuvanted formulation.
In recent years, OD (Oil Dispersion) formulations have been the subject of studies by companies and formulators because of their advantages with respect to the agronomic performance in the field as compared with conventional formulations. Active ingredients (AIs) formulated in different types of formulations usually exhibit different physicochemical characteristics based on type of formulation they are incorporated in. The different performance between them is due to the fact that ODs already contain in their composition oil, such as a mineral or vegetable oil, and emulsifiers, which can act as penetration adjuvants when applied in the field. Penetration adjuvants aid in the absorption of AIs by the plant and, in the case of some conventional formulations, they are used in association with the formulation in the spray mixture, ensuring agronomical effectiveness of the AI. Thus, OD formulations can be deemed “adjuvanted” formulations and do not require additional associated adjuvants to be applied in the field.
Though OD formulation is called as adjuvated formulation it still requires various adjuvants along with formulation excipients. OD formulation presents several challenges in the process of manufacturing and developing stable and effective formulation with choice of proper formulation excipient or adjuvants. To obtain a good and stable formulation over time, optimal formulation additives are required in addition to optimum processes. There were several development and research done in the filed field of formulation development of Oil Dispersion (OD) formulation. Dispersion and activation of active ingredients is the key to the stability of the formulation over time. Solvents or carrier used as a petroleum based or the aromatic solvent we replaced by the solvents in the form of vegetable oils. Vegetable oils application as a formulation excipients in OD formulation further have their own challenges for stable formulation due to stability issue associated with vegetable oil used and corresponding active ingredient. Although various research has been done in formulation development it has got many draw backs as having high dose of active ingredients and thereby maximizing the pesticidal load into the environment. Many OD formulations has less thermal and chemical stability over a broad range of conditions; increases the toxicity hazards to the applicators and thereby decreasing the safety of applicators at the time of handling and spraying the pesticides. Further some OD formulation with less suitable formulation excipients may lead to have less leaf penetration of spray droplets, and increases evaporation loss and minimize the absorption of active ingredients.
Therefore there is further need and scope in the formulation development of the OD formulation comprising one or more active ingredients with better stability profile and increases the synergistic effect of the active ingredients, reduces the toxicity with less introduction of toxic material in environment, which may reduce the dose of the pesticides and eventually produce less chemicals in environment, with better safety profile for contact herbicides.
US20210092955A1 relates to a method of controlling herbicide resistant weeds in crops. A method of controlling herbicide resistant weeds, the method comprising: Treating herbicide resistant weeds with one or more of herbicides selected from the group consisting of saflufenacil, trifludimoxazin, flumioxazin, and ethyl [3-[2-chloro-4-fluoro-5-(1-methyl-6-trifluoromethyl-2,4-dioxo-1,2,3,4-tetrahydropyrimidine-3-yl)phenoxy]-2 pyridyloxy] acetate, wherein the herbicide resistant weeds are PPO-inhibitor resistant weeds having one or more mutations selected from the group consisting of an Arg128Met mutation, an Arg128Gly mutation, an Arg128His mutation, and a Gly399Ala mutation in PPO.
WO2017129141A1 relates to a synergistic herbicidal composition. a synergistic herbicidal composition comprising pyroxasulfone, mesotrione and atrazine as the active components, wherein the weight ratio of pyroxasulfone, mesotrione and atrazine ranges from 1 to 10: 1 to 50: 1 to 100, as well as the use of the synergistic herbicidal composition of present invention for controlling the growth of undesirable plants. The present invention also provides a method of controlling the growth of undesirable plants, which comprises applying the active components pyroxasulfone, mesotrione and atrazine of the synergistic herbicidal composition of present invention to the undesirable plants or their growing locus jointly or separately. The present invention further provides a method of reducing or preventing harm caused by pyroxasulfone when applied to plants, seeds or other reproductive parts of useful crops.
CA2973915 A1 discloses ternary herbicidal combination comprising a) a herbicide A which is 2-chloro-5-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1-(2H)- pyrimidinyl]-4-fluoro-N-[[methyl-(1-methylethyl)-amino]sulfonyl]benzamide, b) a single herbicide B selected from sulfentrazone, flumioxazin, dicamba and their salts and esters, and c) at least one herbicide C different from herbicides A and B which is selected from C.1) herbicides of the group of acetolactate synthase inhibitors, C.2) herbicides of the group of protoporphyrinogen oxidase inhibitors, C.3) herbicides of the group of synthetic auxins, C.4) herbicides of the group of microtubule inhibitors, C.5) herbicides of the group of acetyl-CoA carboxylase inhibitors, C.6) herbicides of the group of photosystem II inhibitors, C.7) herbicides of the group of pigment synthesis inhibitors, and C.8) herbicides of the group of VLCFA inhibitors selected from chloroacetamide herbicides, oxyacetamide herbicides, acetamide herbicides and tetrazolinone herbicides; provided that the herbicidal combination does not include pyroxasulfone; provided that in case the components b) or c) comprise dicamba or one of its salts or esters the herbicidal combination does not include imazapyr or one of its salts; and provided that if component b) is flumioxazin and component c) is 2,4-D, 2,4-D is present as its 2-ethylhexyl ester.
Therefore there is further need to formulate the novel OD formulation which increases the synergistic activities between active ingredients by using the appropriate formulation excipients; enhance the bioefficacy, duration and spectrum of weed control; reduce the doses of active ingredients and thereby minimizing the pesticidal load into the environment; has thermal and chemical stability over a broad range of conditions; reduces the toxicity hazards to the applicators, i.e. improves the safety of applicators at the time of handling and spraying the pesticides; and improves leaf penetration of spray droplets, retard evaporation loss and enhance the absorption of active ingredients.
There is however a need for improvement of OD formulations. Many a times it has been found that single or combination of active ingredients requires a high loading dose for the better results. Further this will create a higher loading of the pesticides in the environment and toxicity to the crop plant. Further many of the OD formulation recipe is prone to lose stability when exposed to the higher temperature. In addition there are higher chances of formulation applied gets evaporated resulting in the loss of the active ingredients before penetration.
Therefore, the key objective of the present invention is to provide novel Oil Dispersion formulations (OD) with enhanced bioefficacy and which and duration of control. Further the objective of the present invention is to provide novel Oil Dispersion formulations (OD) as a non phytotoxic formulation for crop safety and for delay resistance development management with improved combinations of (A) Saflufenacil; (B) Atrazine; (C) At least one more herbicide selected from group of herbicides. Another object of the present invention is to provide a method and a composition for controlling unwanted weeds.
Yet another object of the present synergistic agrochemical Oil Dispersion (OD) composition in percentage by weight: 1-20% of Saflufenacil, 1-30% of Atrazine, 1-30% of at least one more herbicide selected from different group of herbicides or combination thereof that are safe to the targeted crop plant and for delaying the resistance development.
Further object of the present invention is to provide suitable formulation excipients for the present Oil Dispersion formulation in order to produce stable and synergistic formulation.
Another object of the present invention is to provide a method and a composition for the OD formulation.
Embodiment of the present invention can ameliorate one or more of the above mentioned problems.
Inventors of the present invention have surprisingly found that the novel synergistic composition and OD formulation thereof for plant treatment comprising of (A) Saflufenacil; (B) Atrazine; (C) At least one more herbicide selected from different group of herbicide or combination thereof can provide solution to the above mentioned problems.

SUMMARY OF INVENTION:
Therefore an aspect of the present invention provides a synergistic agrochemical Oil Dispersion (OD) composition comprising bioactive amount of (A) Saflufenacil; (B) Atrazine; (C) At least one more herbicide selected from group of herbicides or combination thereof; a super wetting-spreading-penetrating agent is polyalkyleneoxide modified heptamethyl trisiloxane; carrier solvent selected from pongamia oil or palm oil or jojoba oil or combination thereof or blend with vegetable oil; along with formulation excipients.
Another apect of the present invention is to provide novel agrochemical Oil Dispersion (OD) composition comprising Saflufenacil present in an amount of 1-20%w/w, Atrazine present in an amount of 1-30%w/w; at least one more herbicide selected from group of herbicides or combination thereof present in an amount of 1-30%w/w.
Further aspect of the present invention is to provide novel agrochemical Oil Dispersion (OD) formulation comprising at least one active ingredient suspended in oil phase shows synergistic activity and stability over wide range of the conditions.
Further aspect of the present synergistic Oil Dispersion (OD) composition is to provide selection of suitable additional formulation excipients selected from category of emulsifying agent, dispersing agent, stabilizers, antifoaming agent, preservative, anti-freezing agent and buffering agents.
Further aspect of the present invention is to provide synergistic agrochemical Oil Dispersion (OD) formulation comprising carrier or solvent selected from Pongamia/karanja/karanj oil; or palm oil; or pongamia oil and palm oil; or pongamia oil and jojoba oil; or palm oil and jojoba oil; or pongamia oil and vegetable oil; or palm oil and vegetable oil; or pongamia oil and palm oil and vegetable oil; or solvent; or both.
In a further embodiment of the present invention, herbicide selected from different group of herbicides. The present synergistic agrochemical Oil Dispersion (OD) composition comprising bioactive amount (A) Saflufenacil; (B) Atrazine; (C) at least one more herbicide compound selected from group of herbicides or combination thereof described herein is obtained by a process comprising a step of preparing the liquid premix by charging the oil or solvent or both followed by adding super wetting-spreading-penetrating agent. The further step is adding the active ingredients into the premixed through milling for the proper size distribution. Further adding the thickening agent followed by stirring the slurry get prepared by milling process to prepare the final formulation. These agrochemical oil dispersion formulations can be used in spray mixtures in agriculture.
DETAILED DESCRIPTION OF THE INVENTION:
Formulation technology in the field of an agriculture is now seen as an “enabling technology” which can provide safe and effective products which are convenient to use. It can also modify the toxicity of active ingredients and improve their ability to target a specific pest. At a time when the discovery of new agrochemical compounds is more difficult and certainly a high risk and expensive operation, formulation technology can extent the useful patent life of an active ingredient. It can also provide a competitive edge by improving product quality of existing formulations, or by introducing a new formulation of an active ingredient.
OD formulations are non-aqueous dispersion intended for dilution into water before use, and represent the most complex of the non-aqueous suspension formulations. Oil dispersion (OD) formulations consist of a suspension of a solid technical in oil. The oil also serve as a carrier or solvent for additives. The oil dispersion is usually dispersed in water prior to spraying.
An Oil Dispersion is a non-aqueous suspension concentrate. It combines a very good biological efficacy with an environmental friendly formulation. The active ingredient is dispersed in oils or methylated or ethylated vegetables oils.
Oil Dispersion formulation comprises with some features as it comprises no aromatic solvent or reduced amount of aromatic solvent; is non-aqueous formulation; non-flammable and low volatility; higher efficiency.
Oil Dispersion (OD) have several advantages over standard formulations. Emulsifiable Concentrate (ECs) formulations are under a strong regulatory pressure to replace toxic and flammable solvents with a less toxic and non-flammable solutions. The novel ODs meets these needs: the oil content gives a favourable eco-toxicological profile guarantying a very high biological efficacy. Further the novel OD formulations are non-toxic and non-flammable formulations. Over the EC formulation the novel OD formulation is having very high biological efficacy and crop safety.
Suspension concentrate (SC) formulations are very safe formulations but the aqueous media is normally not ideal to boost the pesticide’s biological efficacy. As an agriculture growers standard practice, tank mix adjuvants are added to guarantee a higher performance. The novel OD, with its oil content, guarantees the best biological results. For water sensitive active ingredients, the novel OD represents the sole technical solution to liquid formulation. The novel OD formulation over SC formulation is very safe formulation along with high biological performance. Further the novel OD formulation is ideal for all the active ingredients not stable in water.
Water dispersible granules (WDG) formulations are very safe but quite expensive. Optimal biological efficacy requires adjuvants. The novel OD, with its oil content and better particle size distribution, combines high efficacy with better cost. The novel OD formulation over WDG has economic significance as having better efficacy at a lower cost.
OD formulation presents several challenges in preparation and manufacturing phase. To obtain a good and stable formulation over time, optimal formulation additives are required in addition to optimum processes. Particular attention must be given to choice of all the formulation excipients. Its dispersion and activation are key to the stability of the formulation over time.
Some important requirement of the formulation excipients are perfectly dispersible in oil, no phase separation, easy milling, with no agglomeration, excellent oil emulsification, stable dilution, good coverage and penetration, even distribution through the whole formulation, provide the right yield value of active ingredients.
Therefore an aspect of the present invention provides a synergistic agrochemical Oil Dispersion (OD) composition comprising bioactive amount of (A) Saflufenacil; (B) Atrazine; (C) At least one more herbicide selected from different group of herbicide or combination thereof;
More particularly an aspect of the present invention provides a synergistic agrochemical Oil Dispersion (OD) composition comprising bioactive amount of (A) Saflufenacil present in an amount of 1-20%w/w; (B) Atrazine present in an amount of 1-30%w/w; (C) At least one more herbicide selected from different group of herbicide or combination thereof present in an amount of 1-30%w/w.
Further aspect of the present invention is to provide novel agrochemical Oil Dispersion (OD) formulation comprising at least one active ingredient suspended in oil phase shows synergistic activity and stability over wide range of the conditions.
In an especially preferred embodiment of the invention, the yield of the treated plant is increased.
In another preferred embodiment of the invention, the yield of the plants treated according to the method of the invention, is increased synergistically.
The term "synergistic", as used herein, refers the combined action of two or more active
agents blended together and administered conjointly that is greater than the sum of their individual effects.
Further aspect of the present invention is to provide synergistic agrochemical Oil Dispersion (OD) formulation comprising formulation excipients from the category of Super Wetting-spreading-penetrating agent, Solvent, emulsifying agent, dispersing agent, stabilizers, antifoaming agent, preservative, anti-freezing agent and buffering agents.
In an embodiment Super Wetting-spreading-penetrating agent for the present Oil Dispersion formulation is Polyalkyleneoxide modified Heptamethyl trisiloxane (Modified trisiloxane)
In an embodiment Solvent is selected form Pongamia/karanja/karanj (Millettia pinnata/Pongamia pinnata/Pongamia glabra) oil alone or Palm (Elaeis spp.) oil (Palm oil and palm kernel oil) alone or Blend of Pongamia oil and palm oil or Blend of Pongamia oil and Jojoba (Simmondsia chinensis) or Blend of Palm oil and Jojoba oil Blend of Pongamia oil and vegetable oil Blend of Palm oil and vegetable oil Blend of Pongamia oil, Palm oil and vegetable oil. The vegetable oil may be any one or mixture of two or more selected from soybean (Glycine max) oil, groundnut (Arachis hypogaea) oil, rapeseed (Brassica napus subspecies) oil, mustard (Brassica juncea) oil, sesame (Sesamum indicum) oil, Corn (Zea mays) oil, rice (Oryza sativa) bran oil, castor (Ricinum communis) seed oil, cotton (Gossypium hirsutum) seed oil, linseed (Linum usitatissimum), coconut (Cocos nucifera) oil, Kapok (Ceiba pentandra) oil, Papaya (Carica papaya) seed oil, Tea seed (Camellia oleifera) oil, sunflower (Helianthus annuus) oil, safflower (Carthamus tinctorius) seed oil, Eucalyptus (Eucalyptus globulus) oil, Olive (Olea europaea) oil, Jatropha (Jatropha curcas) oil, Garlic acid (Allium sativum), Ginger oil (Zingiber officinale), D-limonene, Citronella oil or Ceylon ironwood (Mesua ferrea) oil, Mahua (Madhuca longifolia) oil.
Prefrebly solvent for the present formulation, the pongamia oil, palm oil, vegetable oil and their mixtures may be alkylated or ethoxylated or epoxylated or esterified. Examples methyl ester of karanj oil, methyl ester of palm oil, methyl ester of karanj oil and soybean oil, methyl ester of palm oil and castor oil, methyl ester of palm oil and rapeseed oil etc.
In an embodiment of the present synergistic agrochemical Oil Dispersion (OD) formulation, (A) Saflufenacil; (B) Atrazine; (C) At least one more herbicide selected from group of herbicides or combination thereof.
In a further embodiment of the present invention, an herbicide compound may be selected from:Inhibitor of Acetyl CoA Carboxylase (ACCase), Inhibitor of Acetolactate Synthase (ALS) or Acetohydroxy Acid Synthase (AHAS), Inhibitor of microtubule assembly Synthetic Auxin, Inhibitor of photosynthesis at photosystem II site A, Inhibitor of photosynthesis at photosystem II site B, Inhibitor of photosynthesis at photosystem II site A; different behavior from group 5, Inhibitor of lipid synthesis; not ACCase inhibition, Inhibitor of 5-enolypyruvyl-shikimate-3-phosphate synthase (EPSPS): Glycine, Inhibitor of glutamine synthetase: Phosphonic acid, Inhibitor of phytoene desaturase (PDS), Inhibitor of 1-deoxy-D-xyulose 5-phosphate synthatase (DOXP synthase), Inhibitor of protoporphyrinogen oxidase (Protox, PPO), Mitosis Inhibitor, Inhibitor of 7,8-dihydro-preroate synthetase (DHP), Inhibitor of indoleacetic acid transport, Inhibitor of cell wall synthesis site A, B and C, Inhibition of cellulose synthesis, Photosystem I electron diverter, Membrane disruptor (uncouplers), Inhibitor of Hydroxyphenyl Pyruvate Dioxygenase (4-HPPD), Tyrosine Aminotransferase, Inhibition of dihydroorotate dehydrogenase(DHODH), HTS (homogentisate solanesyltransferase)-a downstream enzyme of HPPD, VLCAFE inhibitors,Inhibition of lycopene cyclase, Inhibition of Solanesyl Diphosphate Synthase (SDS), Inhibition of serine-threonine protein phosphatase, Herbicide with unknown mode of action.
In a further embodiment of the present invention, an herbicide may be selected from: Inhibitor of Acetyl CoA Carboxylase (ACCase): Aryloxyphenoxy-propionate ('FOPs'): clodinafop-propargyl, cyhalofop-butyl, diclofop, fenoxaprop-P-ethyl, fluazifop-P-butyl, haloxyfop, metamifop, propaquizafop, quizalofop-P-ethyl; Cyclohexanedione ('DIMs'): alloxydim, butroxydim, clethodim, cycloxydim, sethoxydim, tralkoxydim, tepraloxydim; Phenylpyrazoline ('DEN'): pinoxaden.
In an embodiment of the present invention, an herbicide may be selected from Acetolactate Synthase inhibitors(ALS) or Acetohydroxy Acid Synthase inhibitors (AHAS): Sulfonylurea: amidosulfuron, azimsulfuron, bensulfuron methyl, chlorimuron ethyl, chlorsulfuron, cinosulfuron, cloransulfuron methyl, cyclosulfamuron, ethametsulfuron methyl, ethoxysulfuron, flazasulfuron, flucetosulfuron, flupyrsulfuron methyl sodium, foramsulfuron, halosulfuron methyl, imazosulfuron, iodosulfuron, mesosulfuron, metazosulfuron, metsulfuron mehtyl, nicosufulfuron, primisulfuron methyl, propyrisulfuron, prosulfuron, pyrazosulfuron ethyl, rimsulfuron, rimsulfuron, sulfometuron methyl, sulfosulfuron, thifensulfuron-methyl, triasulfuron, tribenuron methyl, trifloxysulfuron, triflusulfuron methyl; Pyrimidinyl benzoate: bispyribac-sodium, pyribenzoxim, pyrithiobac sodium; Triazolopyrimidine: cloransulam-methyl, diclosulam, florasulam, flumetsulam, penoxsulam, pyroxsulam; Triazolinone-flucarbazone-sodium, propoxycarbazone-sodium, thiencarbazone-methyl; Imidazolinone: imazamethabenz methyl, Imazamox, imazapic, imazapyr, imazaquin, imazethapyr; Sulfonanilides: triafamone, pyrimisulfan.
In an embodiment of the present invention, an herbicide may be selected from microtubule assembly inhibitors: Dinitroaniline: benefin, trifluralin, ethafluralin, oryzalin, pendimethalin, prodiamine; Benzoic acid: DCPA; Pyridine: dithiopyr, thiazopyr; Benzamide: pronamide.
In an embodiment of the present invention, an herbicide may be selected from Synthetic Auxin: Phenoxy carboxylic acid: 2, 4-D, 2, 4-DB, dichloroprop, MCPA, MCPB, mecoprop; Pyrimidine carboxylic acid: aminocyclopyrachlor; Pyridine carboxylic acid: aminopyralid, lopyralid, florpyrauxifen benzyl, fluroxypyr, picloram, triclopyr; Benzoic acid: dicamba; Quinoline carboxylic acid: quinclorac; other: halauxifen methyl.
In an embodiment of the present invention, an herbicide may be selected from Inhibitor of photosynthesis at photosystem II site A: Phenyl carbamate: desmedipham, phenmedipham; Pyridazinone: pyrazon; Triazine: ametryn, cyanazine, desmetryn, prometon, prometryn, propazine, simazine, simetryn, terbumeton, terbuthylazine, trietazine; Triazinone: hexazinone, metamitron, metribuzin; Triazolinone: amicarbazone; Urea: metoxuron; Uracil: bromacil, terbacil.
In an embodiment of the present invention, an herbicide may be selected from Inhibitor of photosynthesis at photosystem II site B: Benzothiadiazinone: bentazone; Nitrile: bromoxynil, ioxynil; Phenyl-pyridazine: pyridate.
In an embodiment of the present invention, an herbicide may be selected from Inhibitor of photosynthesis at photosystem II site A; different behavior from group 5: Amide: propanil; Urea: chlorotoluron, dimefuron, diuron, fluometuron, isoproturon, linuron, methibenzuron, monolinuron, siduron, tebuthiuron.
In an embodiment of the present invention, an herbicide may be selected from Inhibitor of lipid synthesis; not ACCase inhibition: Benzofuran: ethofumesate; Phosphorodithioate: bensulie; Thiocarbamate: butylate, cycloate, EPTC, esprocarb, molinate, pebulate, prosulfocarb, thiobencarb, triallate, vernolate.
In an embodiment of the present invention, an herbicide may be selected from Inhibitor of 5-enolypyruvyl-shikimate-3-phosphate synthase (EPSPS): Glycine: Glyphosate.
In an embodiment of the present invention, an herbicide may be selected from Inhibitor of glutamine synthetase: Phosphonic acid: glufosinate.
In an embodiment of the present invention, an herbicide may be selected from Inhibitor of phytoene desaturase (PDS): Pyridinecarboxamide: diflufenican, picolinafen; Pyridazinone: norflurazon; others: beflubutamid, fluridone, flurochloridone, flurtamone.
In an embodiment of the present invention, an herbicide may be selected from Inhibitor of 1-deoxy-D-xyulose 5-phosphate synthatase (DOXP synthase): Isoxazolidinone: clomazone.
In an embodiment of the present invention, an herbicide may be selected from Inhibitor of protoporphyrinogen oxidase (Protox, PPO): Dipheylether: aclifluorfen, bifenox, fluoroglycofen, fomesafen, lactofen, oxyfluorfen; Triazolinone: azafenidin, carfentrazone-ethyl, flufenpyr-ethyl, sulfentrazone; Pyrimidinedione: butafenacil; N-phenylphthalimide: flumiclorac, flumioxazin; N-Phenyl-imide: trifludimoxazin; Thiadiazole: fluthiacet-methyl; Oxadiazole: oxadiargyl, oxadiazon; Phenylpyrazole: pyraflufen-ethyl, other: pyraclonil; Uracil: tiafenacil; Pyrazole: cyclopyranil.
In an embodiment of the present invention, an herbicide may be selected from Mitosis Inhibitor: Chloroacetamide: acetochlor, alachlor, butachlor, dimethenamid, metazachlor, pretilachlor, propachlor, S-metolachlor, thenylchlor; Tetrazolinone: fentrazamide; Oxyacetamide: flufenacet, mefenacet; Acetamide: napropamide; other: anilofos; Carbamate: carbetamide.
In an embodiment of the present invention, an herbicide may be selected from Inhibitor of 7, 8-dihydro-preroate synthetase (DHP): Carbamate: asulam.
In an embodiment of the present invention, an herbicide may be selected from Inhibitor of indoleacetic acid transport: Phthalamate semicarbazone: diflufenzopyr, naptalam.
In an embodiment of the present invention, an herbicide may be selected from Inhibitor of cell wall synthesis: site A: Nitrile: dichlobenil; site B: Benzamide: isoxaben; site C: Alkylazines: indaziflam, triaziflam.
In an embodiment of the present invention, an herbicide may be selected from Inhibition of cellulose synthesis: Triazolocarboxamide: flupoxam; nitriles: dichlobenil, chlorthiamide.
In an embodiment of the present invention, an herbicide may be selected from Photosystem I electron diverter: Pyridiniums: cyperquat, diquat, morfamquat, paraquat.
In an embodiment of the present invention, an herbicide may be selected from Membrane disruptor (uncouplers): Dinitrophenol: dinoterb.
In an embodiment of the present invention, an herbicide may be selected from Inhibitor of Hydroxyphenyl Pyruvate Dioxygenase (4-HPPD): Pyrazole: bipyrazone, cypyrafluone, fenpyrazone, tripyrasulfone, benzofenap, pyrasulfotole, pyrazolynate, pyrazoxyfen, tolpyralate; Benzoylbicyclooctanedione: benzobicyclon; Triketone: mesotrione, tembotrione, sulcotrione, tefuryltrione, fenquinotrione, lancotrione sodium, benquitrione, dioxopyritrione; Isoxazoles: isoxaflutole; bicyclo ring compound: bicyclopyrone; others: topramezone, rimisoxafen. Tyrosine Aminotransferase: cinmethylin, methiozolin.
In an embodiment of the present invention, an herbicide may be selected from Inhibition of dihydroorotate dehydrogenase (DHODH): tetflupyrolimet. HTS (homogentisate solanesyltransferase)-a downstream enzyme of HPPD: cyclopyrimorate.
In an embodiment of the present invention, an herbicide may be selected from Very Long Chain Fatty Acid Inhibitors: Isoxazoline: pyroxasulfone, fenoxasulfone; Triazolinone: ipfencarbazone; Trifluoromethansulfonanilides: dimesulfazet.
In an embodiment of the present invention, an herbicide may be selected from Inhibition of lycopene cyclase: amitrole.
In an embodiment of the present invention, an herbicide may be selected from Inhibition of Solanesyl Diphosphate Synthase (SDS): aclonifen.
In an embodiment of the present invention, an herbicide may be selected from Inhibition of serine-threonine protein phosphatase: endothall.
In an embodiment of the present invention, an herbicide with unknown mode of action: bromobutide, pelargonic acid, diphenamid, naproanilide, napropamide, copper (salt), epyrifenacil, bixlozone, dietholate, dicyclonon, naphthalic anhydride, mephenate, flurazole, cyometrinil.
The synergistic agrochemical Oil Dispersion (OD) composition comprising bioactive amount of (A) Saflufenacil; (B) Atrazine; (C) At least one more herbicide selected from different group of herbicides or combination is most suitable against wide range of weed flora. A herbicidal synergistic composition of present invention controls all kind of monocots, dicots and sedges weeds. The present synergistic herbicidal combinations also controls annual and perennial weeds. The most common weeds controlled by present inventions are Abutilon indicum, Acalypha indica, Acanthospermum hispidum, Achyranthes aspera, Aerva tomentosa, Ageratum conyzoides, Alhagi camelorum, Amaranthus hybridus, Amaranthus spinosus, Amaranthus viridis, Ammannia baccifera, Anagallis arvensis, Argemone mexicana, Artemisia nilagiricia, Asphodelus tenuifolius, Avena fatua, Avena ludoviciana, Bidens pilosa, Boerhaavia diffusa, Boerhavia repanda, Brachiaria mutica, Brassica kaber, Bromus tectorum, Calotropis gigantea, Cannabis sativa, Carthamus axyacantha, Cassia tora, Celosia argentea, Centella asiatica, Chenopodium album, Chenopodium murale, Chloris barbata, Chrozophora rottlerii, Cichorium intybus, Cirsium arvense, Clitoria ternatea, Cnicus arvensis, Commelina benghalensis, Commelina communis, Convolvulus arvensis, Conyza canadensis, Corchorus acutangulus, Coronopus didymus, Crotalaria serice, Cucumis callosus, Cuscuta campestris, Cuscuta chinensis, Cynodon dactylon, Cyanotis axillaris, Cyperus esculenthus, Cyperus iria, Cyperus rotundus, Dactyloctenium aegyptium, Datura stramonium, Daucus carota, Digera arvensis, Digitaria sanguinalis, Dinebra retroflexa, Echinochola colonum, Echinochola crusgalli, Eclipta alba, Eichhornia crassipes, Elephantopus scaber, Eleusine indica, Eragrostis major, Euphorbia geniculata, Euphorbia hirta, Fimbristylis miliacea, Fumaria indica, Gynandropsis gynandra, Heliotropium indicum, Indigofera glandulosa, Ipomea aquatica, Lantana camara, Lathyrus aphaca, Launaea asplenifolia, Launaea nudicaulis, Leucas aspera, Ludwigia parviflora, Marsilea quadrifoliata, Medicago denticulate, Mimosa pudica, Melilotus alba, Melilotus indica, Ocimum canum, Oenothera biennis, Opuntia dillenil, Orobanche ramosa, Oryza longistaminata, Oryza sativa, Oxalis corniculata, Oxalis latifolia, Parthenium hysterophorus, Paspalum sanguinale, Phalaris minor, Phyllanthus niruri, Physalis minima, Polypogon monspeliensis, Portulaca oleracea, Prosopis juliflora, Rumex dentatus, Saccharum spontaneum, Stearia glauca, Seteria viridis, Sida spinosa, Silene antirrhina, Sisymbrium irio, Solanum nigrum, Solanum surattense, Sonchus oleraceous, Sorghum halepense, Spergula arvensis, Sphenocleazeylanica Gaertn, Striga asiatica, Tagetes minuta, Trianthema monogyna, Trianthema portulacastrum, Tribulus terrestris, Trigonelia polycerata, Vernonia cinerea, Vicia sativa and Xanthium strumarium.
The present inventors believe that the combination of the present invention synergistic agrochemical Oil Dispersion (OD) composition comprising bioactive amount of (A) Saflufenacil present in an amount of 1-20%w/w; (B) Atrazine present in an amount of 1-30%w/w; (C) at least one more herbicide selected from group of herbicides or combination thereof present in an amount of 1-30%w/w surprisingly results in a synergistic action.
The combination of the present invention allows for a broad spectrum of Weeds (grasses, broad leaf and sedges) control and has surprisingly improved plant vigour and yield. The broad spectrum of the present combination also provides a solution for preventing the development of resistance.
Examples of the crops on which the present compositions may be used include GMO (Genetically Modified Organism) and Non GMO traits, hybrids and conventional varieties of Cotton (Gossypium spp.), Paddy (Oryza sativa), Wheat (Triticum aestavum), Barley (Hordeum vulgare), Maize (Zea mays), Sorghum (Sorghum bicolor), Oat (Avena sativa), Pearl millet (Pennisetum glaucum), Sugarcane (Saccharum officinarum), Sugarbeet (Beta vulgaris), Soybean (Glycin max), Groundnut/Peanut (Arachis hypogaea), Sunflower (Helianthus annuus), Mustard (Brassica juncea), Rape seed (Brassica napus), Sesame (Sesamum indicum), Green gram (Vigna radiata), Black gram (Vigna mungo), Chickpea (Cicer aritinum), Cowpea (Vigna unguiculata), Red gram (Cajanus cajan), French bean (Phaseolus vulgaris), Indian bean (Lablab purpureus), Horse gram (Macrotyloma uniflorum), Field pea (Pisum sativum), Cluster bean (Cyamopsis tetragonoloba), Lentils (Lens culinaris), Brinjal (Solanum melongena), Cabbage (Brassica oleracea var. capitata), Cauliflower (Brassica oleracea var. botrytis), Okra (Abelmoschus esculentus), Onion (Allium cepa L.), Tomato (Solanum lycopersicun), Potato (Solanum tuberosum), Sweet potato (Ipomoea batatas), Chilly (Capsicum annum), Bell pepper (Capsicum annum), Garlic (Allium sativum), Cucumber (Cucumis sativus), Muskmelons (Cucumis melo), Watermelon (Citrullus lanatus), Bottle gourd (Lagenaria siceraria), Bitter gourd (Momordica charantia), Radish (Raphanus sativus), Carrot (Dacus carota subsp. sativus), Turnip (Brassica rapa rapa), Apple (Melus domestica), Banana (Musa spp.), Citrus groups (Citrus spp.), Grape (Vitis vinifera), Guava (Psidium guajava), Mango (Mangifera indica), Papaya (Carica papaya), Pineapple (Ananas comosus), Pomegranate (Punica granatum), Sapota (Manilkara zapota), Tea (Camellia sinensis), Coffea (Coffea Arabica), Turmeric (Curcuma longa), Ginger (Zingiber officinale), Cumin (Cuminum cyminum), Black Pepper (Piper nigrum), Mentha ( Mentha spp.), Rose (Rosa spp.), Jasmine (Jasminum spp.), Marigold ( Tagetes spp.), Common daisy (Bellis perennis), Dahlia (Dahlia hortnesis), Gerbera ( Gerbera jamesonii), Carnation (Dianthus caryophyllus).

Crops are to be understood as also including those crops which have been rendered tolerant to herbicides or classes of herbicides (e.g. ALS-, GS-, EPSPS-, PPO-, ACCase- and HPPD-inhibitors) by conventional methods of breeding or by genetic engineering. An example of a crop that has been rendered tolerant to imidazolinones, e.g. imazamox, by conventional methods of breeding is Clearfield® summer rape (canola). Examples of crops that have been rendered tolerant to herbicides by genetic engineering methods include e.g. glyphosate- and glufosinate-resistant maize varieties commercially available under the trade names RoundupReady® and LibertyLink®.

Crops are also to be understood as being those which have been rendered resistant to harmful insects by genetic engineering methods, for example Bt maize (resistant to European corn borer), Bt cotton (resistant to cotton boll weevil) and also Bt potatoes (resistant to Colorado beetle). Examples of Bt maize are the Bt 176 maize hybrids of NK® (Syngenta Seeds). The Bt toxin is a protein that is formed naturally by Bacillus thuringiensis soil bacteria. Examples of toxins, or transgenic plants able to synthesise such toxins, are described in EP-A-451 878, EP-A-374 753, WO 93/07278, WO 95/34656, WO 03/052073 and EP-A-427 529. Examples of transgenic plants comprising one or more genes that code for an insecticidal resistance and express one or more toxins are KnockOut® (maize), Yield Gard® (maize), NuCOTIN33B® (cotton), Bollgard® (cotton), NewLeaf® (potatoes), NatureGard® and Protexcta®. Plant crops or seed material thereof can be both resistant to herbicides and, at the same time, resistant to insect feeding (“stacked” transgenic events). For example, seed can have the ability to express an insecticidal Cry3 protein while at the same time being tolerant to glyphosate.

Crops are also to be understood to include those which are obtained by conventional methods of breeding or genetic engineering and contain so-called output traits (e.g. improved storage stability, higher nutritional value and improved flavour).

Other useful plants include turf grass for example in golf-courses, lawns, parks and roadsides, or grown commercially for sod, and ornamental plants such as flowers or bushes.

The present OD (Oil Dispersion) formulation comprising bioactive amount of (A) Saflufenacil; (B) Atrazine; (C) At least one more herbicide selected from different group of herbicides or combination thereof provides:
• Improve leaf penetration of spray droplets, retard evaporation loss and enhance the absorption of active ingredients
• Increase spreading properties on leaf surfaces, better wetting of waxy leaf surfaces
• Increase penetration of active ingredients into the leaf surfaces and thereby improves the efficacy against tough to kill weeds.
• Improve rain fast properties
• Increases the synergistic activities between active ingredients
• Improves the residual control i.e. enhance the duration of control.
• With the novel OD formulation, we can reduce the doses of active ingredients and thereby minimizing the pesticidal load into the environment.
• Novel OD formulations are without aromatic solvent, so its safe to the applicator and reducing the loading of aromatic solvent into the environment.
• Due to High flash point (smoke points) of Pongamia (>220 Celcius), Palm oil (>240 C), Jojoba oil (>290 C), the novel recipe of OD formulations are more stable and safer for storage at elevated temperature.
• The novel recipe of OD formulations has thermal and chemical stability over a broad range of conditions.
• The novel recipe of OD formulations has better pourability, so it will minimize the wastage.
• The novel recipe of OD formulations are stable with wider pH range.
• With the innovative OD formulation, we can reduces the toxicity hazards to the applicators, i.e. improves the safety of applicators at the time of handling and spraying the pesticides.

The process for preparing the present synergistic oil dispersion formulation can be modified accordingly by any person skilled in the art based on the knowledge of manufacturing the formulation. However, all such variations and modifications are covered by the scope of the present invention.
The composition of the present invention in addition to bioactive amounts of active ingredients further comprises inactive excipients including but not limited to Super Wetting-spreading-penetrating agent, carrier or solvent, dispersant or dispersing agent, emulsifying agent, anti-freezing agent, anti-foam agent, preservatives and buffering agent.
Examples of super wetting-spreading-penetrating agent used herein for present OD (Oil Dispersion) formulation include but not limited to Polyalkyleneoxide modified Heptamethyl trisiloxane (Modified trisiloxane).
Polyalkyleneoxide modified heptamethyltrisiloxane can improve the penetration effect of pesticides and reduce the spray volume. It is used in the fields of pesticides, herbicides, insecticides, acaricides, fungicides, plant growth regulating agents, and other aspects. (Polyalkyleneoxide modified heptamethyltrisiloxane, a registered product of GE Silicones)

Molecular formula: (C2H4O)n•C11H30O3Si3
Examples of Carrier or solvents used herein for present Oil dispersion (OD) formulation include but not limited to Pongamia/karanja/karanj (Millettia pinnata/Pongamia pinnata/Pongamia glabra) oil alone; or Palm (Elaeis spp.) oil (Palm oil and palm kernel oil) alone; or Blend of Pongamia oil and palm oil; or Blend of Pongamia oil and Jojoba (Simmondsia chinensis); or Blend of Palm oil and Jojoba oil; or Blend of Pongamia oil and vegetable oil; or Blend of Palm oil and vegetable oil; or Blend of Pongamia oil, Palm oil and vegetable oil; the vegetable oil may be any one or mixture of two or more selected from soybean (Glycine max) oil, groundnut (Arachis hypogaea) oil, rapeseed (Brassica napus subspecies) oil, mustard (Brassica juncea) oil, sesame (Sesamum indicum) oil, Corn (Zea mays) oil, rice (Oryza sativa) bran oil, castor (Ricinum communis) seed oil, cotton (Gossypium hirsutum) seed oil, linseed (Linum usitatissimum), coconut (Cocos nucifera) oil, Kapok (Ceiba pentandra) oil, Papaya (Carica papaya) seed oil, Tea seed (Camellia oleifera) oil, sunflower (Helianthus annuus) oil, safflower (Carthamus tinctorius) seed oil, Eucalyptus (Eucalyptus globulus) oil, Olive (Olea europaea) oil, Jatropha (Jatropha curcas) oil, Garlic acid (Allium sativum), Ginger oil (Zingiber officinale), D-limonene, Citronella oil or Ceylon ironwood (Mesua ferrea) oil, Mahua (Madhuca longifolia) oil.
All the solvents or combination or blend thereof, used hereby for the present OD formulation may be present in their alkylated or ethoxylated or epoxylated or esterified form. Examples include methyl ester of karanj oil, methyl ester of palm oil, methyl ester of karanj oil and soybean oil, methyl ester of palm oil and castor oil, methyl ester of palm oil and rapeseed oil etc.
All the said oils used as a carrier or diluent are procured from the vendor based in Gujarat State.
Pongamia oil is derived from the seeds of the Millettia pinnata tree, which is native to tropical and temperate Asia. Millettia pinnata, also known as Pongamia pinnata or Pongamia glabra, is common throughout Asia and thus has many different names in different languages, many of which have come to be used in English to describe the seed oil derived from M. pinnata; Pongamia is often used as the generic name for the tree and is derived from the genus the tree was originally placed in. Other names for this oil include honge oil, kanuga oil, karanja oil, and pungai oil.
Pongamia oil is extracted from the seeds by expeller pressing, cold pressing, or solvent extraction. The oil is yellowish-orange to brown in colour. It has a high content of triglycerides, and its disagreeable taste and odour are due to bitter flavonoid constituents including karanjin, pongamol, tannin and karanjachromene. The physical properties of crude pongamia oil are as flash point of the pongamia oil is 225°C.
Its fruits are used in abdominal remedies. Its seeds are used in tumor treatment. Oil is used for curing rheumatism. Leaves are used against Micrococcus. Their leaves juices are used for the treatment of diarrhea cold and cough. It has curative effect for leucoderma and itches. Its oil is used as a lubricant, water paint binder. Utilization of Seed Cake as a Manure for having the proper N, P & K content and ratio. As a material for biogas (Methane) production. As a Material for Producing Proteins for Food, Pharmaceutical and Industrial Applications by Chemical and Biochemical Technologies. Production of Soluble Fibers for Food Uses.
It is medium sized tree and is found throughout India. The tree is drought resistant. Major producing countries are East Indies, Philippines, and India. The oil content varies from 27- 39%.Its cake is used as pesticide and fertilizer. The deoiled cake when applied to soil, has pesticidal value, especially against nematodes and also helps in improving soil fertility. Karanja is often planted in home steads as a shade or ornamental tree and in avenue planting along roadside and canals. It is preferred species help in controlling soil erosion and binding sand dunes due to its dense network of lateral roots.
Palm oil is an edible vegetable oil derived from the mesocarp (reddish pulp) of the fruit of the oil palms, primarily the African oil palm Elaeis guineensis, and to a lesser extent from the American oil palm Elaeis oleifera and the maripa palm Attalea maripa.
The use of palm oil in food and beauty products has attracted the concern of environmental groups; the high oil yield of the trees has encouraged wider cultivation, leading to the clearing of forests in parts of Indonesia and Malaysia to make space for oil-palm monoculture. This has resulted in significant acreage losses of the natural habitat of the three surviving species of orangutan. One species in particular, the Sumatran orangutan, has been listed as critically endangered.
Jojoba oil is the liquid produced in the seed of the Simmondsia chinensis (jojoba) plant, a shrub, which is native to southern Arizona, southern California, and northwestern Mexico. The oil makes up approximately 50% of the jojoba seed by weight. The terms "jojoba oil" and "jojoba wax" are often used interchangeably because the wax visually appears to be a mobile oil, but as a wax it is composed almost entirely (~97%) of mono-esters of long-chain fatty acids and alcohols (wax ester), accompanied by only a tiny fraction of triglyceride esters. This composition accounts for its extreme shelf-life stability and extraordinary resistance to high temperatures, compared with true vegetable oils.
The term "vegetable oil" can be narrowly defined as referring only to substances that are liquid at room temperature, or broadly defined without regard to a substance's state (liquid or solid) at a given temperature. While a large majority of the entries in this list fit the narrower of these definitions, some do not qualify as vegetable oils according to all understandings of the term.
Vegetable oils are triglycerides extracted from plants. Some of these oils have been part of human culture for millennia. Edible vegetable oils are used in food, both in cooking and as supplements. Many oils, edible and otherwise, are burned as fuel, such as in oil lamps and as a substitute for petroleum-based fuels. Some of the many other uses include wood finishing, oil painting, and skin care.
Vegetable oils, or vegetable fats, are oils extracted from seeds or from other parts of fruits. Like animal fats, vegetable fats are mixtures of triglycerides. Soybean oil, grape seed oil, and cocoa butter are examples of fats from seeds. Olive oil, palm oil, and rice bran oil are examples of fats from other parts of fruits. In common usage, vegetable oil may refer exclusively to vegetable fats which are liquid at room temperature. Vegetable oils are usually edible; non-edible oils derived mainly from petroleum are termed mineral oils.
Most, but not all vegetable oils are extracted from the fruits or seeds of plants. For instance, palm oil is extracted from palm fruits, while soybean oil is extracted from soybean seeds. Vegetable oils may also be classified by grouping oils extracted from similar plants, such as "nut oils". Although most plants contain some oil, only the oil from certain major oil crops complemented by a few dozen minor oil crops is widely used and traded.
Oils from plants are used for several different purposes. Edible vegetable oils may be used for cooking, or as food additives. Many vegetable oils, edible and otherwise, are burned as fuel, for instance as a substitute for petroleum-based fuels. Some may be also used for cosmetics, medical purposes, wood finishing, oil painting, formulation ingredient in many pharmaceutical or agricultural formulations and other industrial purposes.
The vegetable Oil for preparing blend with karanj oil or palm oil or jojoba oil used herein as solvent or carrier for present Oil dispersion (OD) formulation include but not limited to any one or mixture of two or more selected from soybean (Glycine max) oil, groundnut (Arachis hypogaea) oil, rapeseed (Brassica napus subspecies) oil, mustard (Brassica juncea) oil, sesame (Sesamum indicum) oil, Corn (Zea mays) oil, rice (Oryza sativa) bran oil, castor (Ricinum communis) seed oil, cotton (Gossypium hirsutum) seed oil, linseed (Linum usitatissimum), coconut (Cocos nucifera) oil, Kapok (Ceiba pentandra) oil, Papaya (Carica papaya) seed oil, Tea seed (Camellia oleifera) oil, sunflower (Helianthus annuus) oil, safflower (Carthamus tinctorius) seed oil, Eucalyptus (Eucalyptus globulus) oil, Olive (Olea europaea) oil, Jatropha (Jatropha curcas) oil, Garlic acid (Allium sativum), Ginger oil (Zingiber officinale), D-limonene, Citronella oil or Ceylon ironwood (Mesua ferrea) oil, Mahua (Madhuca longifolia) oil.
Examples of cosolvents used herein optionally for present Oil dispersion (OD) formulation include but not limited to cyclohexanone, acetophenone, NMP (N-methyl pyrrolidinone), dimethyl sulfoxide, benzyl alcohol, butanol, n-octanol, n-propanol, 2-ethyl hexanol, tetrahydro furfuryl alcohol, isophorone, fatty acid dimethyl amide, 2-hexylethyl lactate and propylene carbonate.
A dispersant or a dispersing agent is a substance which adsorbs onto the surface of particles and helps to preserve the state of dispersion of the particles and prevents them from re-aggregating. Examples of dispersing agent used herein for used herein for present OD (Oil Dispersion) formulation include but not limited to condensed naphthalene sulfonate, propoxylated Ethoxylated copolymer monoalkylether (ethylhexanol), alkyl sulfonates, alkyl benzene sulfonates, alkyl aryl sulfonates, alkylphenolalkoxylates, tristyrylphenol ethoxylates, natural or synthetic fatty ethoxylate alcohols, natural or synthetic fatty acid alkoxylates, natural or synthetic fatty alcohols alkoxylates, alkoxylated alcohols (such as n-butyl alcohol poly glycol ether), block copolymers (such as ethylene oxide-propylene oxide block copolymers and ethylene oxide-butylene oxide block copolymers), fatty acid-polyalkylene glycol condensates, polyamine-fatty acid condensates, polyester condensates, salts of polyolefin condensates, sodium ligno sulfonate, sodium ploycarboxylate, EO/PO based copolymer, phenol sulfonate, sodium methyl oleoyl taurate, styrene acrylic acid copolymer, propyleneoxide-ethyleneoxide-copolymer, polyethylene glycol 2,4,6-tristyrylphenyl ether, tristyrylphenol-polyglycolether-phosphate, tristyrylphenole with 16 moles EO, tristyrylphenol-polyglycolether-phosphate, oleyl-polyglycolether with ethylene oxide, tallow fattyamine polyethylene oxide, nonylphenol polyglycolether with 9-10 moles ethylene oxide.
Emulsifying agent used herein for the present Oil dispersion (OD) formulation includes but not limited to castor oil ethoxylates, alcohol ethoxylates, fatty acid ethoxylates, sorbitan ester ethoxylates, ethoxylated sorbitol oleates, sulphosuccinate, calcium salts of dodecylbenzene sulphonate, alkylammonium salts of alkylbenzene sulphonate, alkylsulphosuccinate salts, ethylene oxide-propylene oxide block copolymers, ethoxylated alkylamines, ethoxylated alkyl phenols, polyoxyethylenesorbitan monolaurate.
Antifoaming agent for the present formulation is selected from various compounds and selectively used according to the formulation. Generally, there are two types of antifoam agents, namely silicones and non-silicones. Silicones are usually aqueous emulsions of dimethyl poly siloxane while the non-silicone anti-foam agents are water- insoluble oils, such as octanol and nonanol, or silica. In both cases, the function of the anti-foam agent is to displace the surfactant from the air-water interface.
Examples of Antifoaming agent used herein for present Oil dispersion (OD) formulation include but not limited to silicone oil, silicone compound, C10~C20 saturated fat acid compounds or C8~C10 aliphatic alcohols compound, silicone antifoam emulsion, dimethyl siloxane, poly dimethyl siloxane, vegetable oil based antifoam, tallow based fatty acids, polyalkylene oxide modified polydimethylsiloxane.
Examples of Anti-freezing agent used herein for present Oil dispersion (OD) formulation include but not limited ethylene glycol, propane diols, glycerine or the urea, glycol (Monoethylene glycol, Diethylene glycol, Polypropylene glycol, Polyethylene glycol), glycerine, urea, magnesium sulfate heptahydrate, sodium chloride.
Preservative used herein for the present Oil dispersion (OD) formulation include but not limited to 1,2-benzisothiazolin-3(2H)-one, sodium salt, sodium benzoate, 2-bromo-2-nitropropane-1,3-diol, formaldehyde, sodium o-phenylphenate, 5-chloro-2-methyl-4-isothiazolin-3-one & 2-methyl-4-isothiazolin-3-one, Butyl hydroxyl toluene.
Stabilizers or stabilizing agent used herein for the present Oil dispersion (OD) formulation includes but not limited to hectorite clay, aluminum magnesium silicate, bentonite clay, silica, attapulgite clay.
Examples of buffering agent used herein for present Oil dispersion (OD) formulation is selected Citric acid, sodium carbonate, sodium bicarbonate, sulphuric acid, hydrochloric acid, sodium hydroxide, potassium hydroxide, acetic acid, sorbic acid.
While the foregoing written description of the invention enables one of ordinary skill to make and use what is considered presently to be the best mode thereof, those of ordinary skill will understand and appreciate the existence of variations, combinations, and equivalents of the specific embodiment, method, and examples herein. The invention should therefore not be limited by the above described embodiment, method, and examples, but by all embodiments and methods within the scope and spirit of the invention. The invention shall now be described with reference to the following specific examples. It should be noted that the example(s) appended below illustrate rather than limit the invention, and that those skilled in the art will be able to design many alternative embodiments without departing from the scope of the present invention.
These and other aspects of the invention may become more apparent from the examples set forth herein below. These examples are provided merely as illustrations of the invention and are not intended to be construed as a limitation thereof.
EXAMPLE 1:
OD (Oil Dispersion) formulation of Saflufenacil 2% + Atrazine 20% + Topramezone 0.67% OD (Recipe: A)
Ingredients Percent (w/w)
Saflufenacil a.i. 2.00
Atrazine a.i. 20.00
Topramezone a.i. 0.67
Dispersing agent Tristyrylphenol-polyglycolether-phosphate 3.00
Emulsifying agent Octylphenol ethoxylate 6.00
Stabilizer Bentonite clay 1.50
Antifoaming agent Polydimethyl siloxane 0.30
Preservative 1,2-benzisothiazolin-3(2H)-one 0.30
Antifreezing agent Glycerine 6.00
Super wetting-spreading-penetrating agent Polyalkyleneoxide modified Heptamethyltrisiloxane 6.00
Carrier as solvent Methyl ester of Palm oil 54.23
Total 100.00
Active ingredients on the basis of 100% purity
Storage stability- Storage stability-Saflufenacil 2%+Atrazine 20%+Topramezone 0.67% OD (Recipe-A).
Laboratory storage for 14 days
Parameters Specification (in house) Initial At 54±2 0C At 0±2 0C
Saflufenacil a.i.(%) 1.90 to 2.20 2.25 2.18 2.25
Atrazine a.i.(%) 19.0 to 21.0 20.50 20.30 20.48
Topramezone (%) 0.636 to 0.737 0.71 0.69 0.71
Saflufenacil suspensibility (%) 80 98.95 98.25 98.90
Atrazine suspensibility (%) 80 97.99 97.50 97.90
Topramezone suspensibility (%) 80 98.50 98.20 98.45
pH range (1% aq. Suspension) 5.0 to 7.5 6.50 6.70 6.55
Pourability 95% min. 97.50 97.30 97.45
Specific gravity 1.00-1.10 1.05 1.05 1.05
Viscosity at spindle no. 62, 20 rpm 350-800 cps 600 630 610
Particle size (micron) D50<3, D90<10 2.5,8.5 2.7,8.8 2.6,8.7
Persistent foam ml (after 1 minute) max. 60 nil 2 nil
Room temperature storage
Parameters Specification (in house) 1 month 6 months 12 months
Saflufenacil a.i.(%) 1.90 to 2.20 2.25 2.25 2.22
Atrazine a.i.(%) 19.0 to 21.0 20.50 20.50 20.39
Topramezone (%) 0.636 to 0.737 0.71 0.71 0.70
Saflufenacil suspensibility (%) 80 98.95 98.95 98.25
Atrazine suspensibility (%) 80 97.99 97.99 97.79
Topramezone suspensibility (%) 80 98.50 98.50 98.20
pH range (1% aq. Suspension) 5.0 to 7.5 6.50 6.50 6.50
Pourability 95% min. 97.50 97.50 97.50
Specific gravity 1.00-1.05 1.05 1.05 1.05
Viscosity at spindle no. 62, 20 rpm 350-800 cps 600 600 610
Particle size (micron) D50<3, D90<10 2.5,8.5 2.5,8.5 2.7,8.7
Persistent foam ml (after 1 minute) max. 60 nil nil 2

The novel OD formulation recipe of Saflufenacil 2%+Atrazine 20%+Topramezone 0.67% OD (Recipe: A) meets the all in-house specifications for storage stability studies in laboratory (at 54±2 C & At 0±2 C for 14 days) and room temperature (for 12 months).
Manufacturing process for 100 kg batch of Saflufenacil 2%+Atrazine 20%+Topramezone 0.67% OD (Recipe-A).
Step 1: 15% Bentonite clay Solution Preparation:
Add 15 kg of Bentonite clay in to 85 kg of Methyl ester of Palm oill and also and homogenized till it gets completely dissolved. It must be kept for 12-18 hour prior to use.
Step 2: OD Premix:
Charge 44.23 kg of Methyl ester of Palm oil into a designated vessel for OD production.
Now add 3.0 kf of Tristyrylphenol-polyglycolether-phosphate, 6.0 kg of Octylphenol ethoxylater, 6.0 kg of Glycerine, 0.3 kg of 1,2-benzisothiazolin-3(2H)-one and 0.15 kg of Polydimethyl siloxane homogenise the contents for 45 – 60 minutes using high shear homogeniser.
Add 7.5 kg of Saflufenacil technical, 10.0 kg of Atrazine technical and 0.75 kg of Metsulfuron methyl technical, into this premix and homogenized for 30-45 minutes.
Add remaining 0.15 kg of Silicon antifoam, 6.0 kg of Polyalkyleneoxide modified Heptamethyltrisiloxane and 10 kg of 15 % Bentonite solution after milling to avoid foaming.
Step 3: Send this final formulation to QC for quality check.

Conventional OD
Saflufenacil 2% + Atrazine 20% + Topramezone 0.67% OD (Recipe:B) conventional OD.

Ingredients Percent (w/w)
Saflufenacil a.i. 2.00
Atrazine a.i. 20.00
Topramezone a.i. 0.67
Synthetic fatty ethoxylate alcohols 6.00
Alkylphenol
alkoxylate 6.00
Silicon dioxide 2.00
Polydimethylsiloxane 0.30
1,2-Benzisothiazolin-
3-one 0.30
Propylene glycol 6.00
Methyl Soyate 56.73
Total 100.00
Active ingredients on the basis of 100% purity.
EXAMPLE 2:
Novel OD formulation without wetting agent
Saflufenacil 2%+Atrazine 20%+Topramezone 0.67% OD (Recipe: C)

Ingredients Percent (w/w)
Saflufenacil a.i. 2.00
Atrazine a.i. 20.00
Topramezone a.i. 0.67
Tristyrylphenol-polyglycolether-phosphate 3.00
Octylphenol ethoxylate 6.00
Silica 1.50
Polydimethyl siloxane 0.30
1,2-benzisothiazolin-3(2H)-one 0.30
Polypropylene glycol 6.00
Methyl ester of Palm oil 60.23
Total 100.00
Active ingredients on the basis of 100% purity.
Saflufenacil 6%+Atrazine 60%+Topramezone 2% WG (Recipe: D) conventional WG
Ingredients Percent (w/w)
Saflufenacil a.i. 6.00
Atrazine a.i. 60.00
Topramezone a.i. 2.00
Sodium salt of naphthalene sulfonate condensate 8.00
Sodium Lauryl sulfate 3.00
Sodium ligno sulfonate 2.00
Corn starch 5.00
Polydimethyl siloxane 0.75
China Clay 13.25
Total 100.00
Active ingredients on the basis of 100% purity.
Saflufenacil 2.4% + Atrazine 24% + Topramezone 0.8% SC (Recipe: E) conventional SC
Ingredients Percent (w/w)
Saflufenacil a.i. 2.40
Atrazine a.i. 24.00
Topramezone a.i. 0.80
Styrene acrylic acid copolymer 3.00
Sodium dioctyl sulfosuccinate 1.00
Sodium salt of naphthalene sulfonate condensate 2.50
Polydimethyl siloxane 0.30
Polypropylene glycol 6.00
1,2-benzisothiazolin-3(2H)-one 0.15
Xanthan gum 0.15
Water 59.70
Total 100.00
Active ingredients on the basis of 100% purity.
Saflufenacil 2.4% + Atrazine 24% + Topramezone 0.8% SE (Recipe: F) conventional SE
Ingredients Percent (w/w)
Saflufenacil a.i. 2.40
Atrazine a.i. 24.00
Topramezone a.i. 0.80
Sodium salt of naphthalene sulfonate condensate 3.00
Synthetic fatty ethoxylate alcohols 4.50
Aromatic solvent C-9 10.00
Polydimethylsiloxane 0.30
1,2-Benzisothiazolin-3-one 0.20
Propylene glycol 6.00
Xanthan gum 0.20
Water 48.60
Total 100.00
Active ingredients on the basis of 100% purity.

EXAMPLE 3-6:
Novel OD formulations covering different concentration of super wetting-spreading-penetrating agent
Saflufenacil 1.5%+Atrazine 10%+ Sulfentrazone 12% OD
Example 3 Example 4 Example 5 Example 6
Recipe:
SAM1 Recipe:
SAM2 Recipe:
SAM3 Recipe:
SAM4
Ingredients Percent (w/w) Percent (w/w) Percent (w/w) Percent (w/w)
Saflufenacil a.i. 1.50 1.50 1.50 1.50
Atrazine a.i. 10.00 10.00 10.00 10.00
Sulfentrazone a.i. 12.00 12.00 12.00 12.00
Dispersing agent Synthetic fatty ethoxylate alcohols 3.00 3.50 4.00 4.50
Emulsifying agent Sorbitan ester 10 ethoxylates 6.00 9.00 7.00 8.00
Stabilizer Bentonite clay 1.50 1.50 1.50 1.50
Antifoaming agent Polydimethyl siloxane 0.30 0.30 0.30 0.30
Preservative 1,2-benzisothiazolin-3(2H)-one 0.30 0.30 0.30 0.30
Antifreezing agent Glycerine 6.00 6.00 6.00 6.00
Super wetting-spreading-penetrating agent Polyalkyleneoxide modified Hepta-methyltrisiloxane 5.00 7.50 10.00 12.50
Carrier as solvent Methyl ester of Palm oil and castor oil 54.40 48.40 47.40 43.40
Total 100.00 100.00 100.00 100.00
Active ingredients on the basis of 100% purity.
Storage stability- Saflufenacil 1.5% + Atrazine 10% + Sulfentrazone 12% OD
All the recipes of novel OD formulation Saflufenacil 1.5% + Atrazine 10% + Sulfentrazone 12% OD meets the in-house specifications for storage stability studies in laboratory (at 54±2 C & at 0±2 C for 14 days) and room temperature (for 12 months).
Manufacturing process for 100 kg batch of Saflufenacil 1.5%+Atrazine 10% + Sulfentrazone 12% OD (Recipe:SAM2)
Step 1: 15% Bentonite clay Solution Preparation:
Add 15 kg of Bentonite clay in to 85 kg of Methyl ester of Palm oil and castor oil and also and homogenized till it gets completely dissolved. It must be kept for 12-18 hour prior to use.
Step 2: OD Premix:
Charge 38.40 kg of Methyl ester of Palm oil and castor oil into a designated vessel for OD production.
Now add 3.5 kg of Synthetic fatty ethoxylate alcohols, 9.0 kg of Sorbitan ester 10 ethoxylates, 6.0 kg of Glycerine, 0.3 kg of 1,2-benzisothiazolin-3(2H)-one and 0.15 kg of Polydimethyl siloxane homogenise the contents for 45 – 60 minutes using high shear homogeniser.
Add 1.50 kg of Saflufenacil technical, 10.0 kg of Atrazine technical and 12.0 kg of Sulfentrazone technical, into this premix and homogenized for 30-45 minutes.
Add remaining 0.15 kg of Silicon antifoam, 7.50 kg of Polyalkyleneoxide modified Heptamethyltrisiloxane and 10 kg of 15 % Bentonite solution after milling to avoid foaming.
Step 3: Send this final formulation to QC for quality check.

EXAMPLE 7:
Novel OD Recipe
Saflufenacil 2%+Atrazine 20%+Mesotrione 2% OD (Recipe: P)

Ingredients Percent (w/w)
Saflufenacil a.i. 2.00
Atrazine a.i. 20.00
Mesotrione a.i. 2.00
Dispersing agent Propoxylated Ethoxylated copolymer monoalkylether 3.00
Emulsifying agent Fatty acid ethoxylates 6.00
Stabilizer Bentonite clay 1.00
Antifoaming agent Polydimethyl siloxane 0.50
Preservative 1,2-benzisothiazolin-3(2H)-one 0.30
Antifreezing agent Propane diols 6.00
Super wetting-spreading-penetrating agent Polyalkyleneoxide modified Heptamethyltrisiloxane 6.00
Carrier as solvent Methyl ester of karanj oil 53.20
Total 100.00
Active ingredients on the basis of 100% purity.
EXAMPLE 8:
Novel OD Recipe
Saflufenacil 2%+Atrazine 20%+Tembotrione 2% OD (Recipe: Q)

Ingredients Percent (w/w)
Saflufenacil a.i. 2.00
Atrazine a.i. 20.00
Tembotrione a.i. 2.00
Tristyrylphenol ethoxylates, 6.00
Alkylsulphosuccinate salts, 3.00
Hectorite clay 1.50
Polydimethyl siloxane 0.30
1,2-benzisothiazolin-3(2H)-one 0.20
Polypropylene glycol 6.00
Polyalkyleneoxide modified Heptamethyltrisiloxane 7.50
Methyl ester of Karanj oil and soybean oil 51.50
Total 100.00

EXAMPLE 9:
Novel OD Recipe
Saflufenacil 2%+Atrazine 20%+Tolpyralate 1.33% OD (Recipe: R)

Ingredients Percent (w/w)
Saflufenacil a.i. 2.00
Atrazine a.i. 20.00
Tolpyralate a.i. 1.33
Propyleneoxide-ethyleneoxide-copolymer 3.50
Polyoxyethylene sorbitan monolaurate 6.00
Aluminium magnesium silicate 1.00
Polydimethyl siloxane 0.50
1,2-benzisothiazolin-3(2H)-one 0.30
Glycerine 6.00
Polyalkyleneoxide modified Heptamethyltrisiloxane 8.00
Methyl ester of palm oil and rapeseed oil 51.37
Total 100.00
Active ingredients on the basis of 100% purity.
EXAMPLE 10:
Novel OD formulation with and without Super-wetting-spreading-penetrating agent
Saflufenacil 2.5%+Atrazine 16.67%+Halosulfuron methyl 1.5% OD (Recipe: SAH-OD-1)
Ingredients Percent (w/w)
Saflufenacil a.i. 2.50
Atrazine a.i. 16.67
Halosulfuron methyl a.i. 1.50
Dispersing agent Synthetic fatty ethoxylate alcohols 3.00
Emulsifying agent Alkylphenol alkoxylate 6.00
Stabilizer Silicon dioxide 1.50
Antifoaming agent Polydimethylsiloxane 0.30
Preservative 1,2-Benzisothiazolin-3-one 0.30
Antifreezing agent Propylene glycol 6.00
Super wetting-spreading-penetrating agent Polyalkyleneoxide modified Heptamethyltrisiloxane 7.50
Carrier as solvent Methyl ester of Palm oil 54.73
Total 100.00

EXAMPLE 11:
Novel OD formulation with and without super-wetting-spreading-penetrating agent
Saflufenacil 2.5%+Atrazine 16.67%+Halosulfuron methyl 1.5% OD (Recipe: SAH-OD-2)
Ingredients Percent (w/w)
Saflufenacil a.i. 2.50
Atrazine a.i. 16.67
Halosulfuron methyl a.i. 1.50
Synthetic fatty ethoxylate alcohols 6.00
Alkylphenolalkoxylate 6.00
Silicon dioxide 1.50
Polydimethylsiloxane 0.30
1,2-Benzisothiazolin-3-one 0.30
Propylene glycol 6.00
Methyl ester of Palm oil 59.23
Total 100.00

EXAMPLE 12:
The preferred novel OD compositions are:
Compound A Compound B Compound
C Active ingredients (%) Formulation Strength (%)
Compound A Compound B Compound C
Saflufenacil Atrazine Topramezone 2 20 0.67 22.67
Saflufenacil Atrazine Mesotrione 2 20 2 24.00
Saflufenacil Atrazine Tembotrione 2 20 2 24.00
Saflufenacil Atrazine Tolpyralate 2 20 1.33 23.33
Saflufenacil Atrazine Metsulfuron methyl 3 20 0.2 23.20
Saflufenacil Atrazine Chlorimuron ethyl 3 20 0.2 23.20
Saflufenacil Atrazine Halosulfuron methyl 2.5 16.67 1.5 20.67
Saflufenacil Atrazine Clomazone 1.5 10 12 23.50
Saflufenacil Atrazine Sulfentrazone 1.5 10 12 23.50
Active ingredients on the basis of 100% purity.
BIOLOGICAL EXAMPLES:
The synergistic pesticide action of the inventive mixtures can be demonstrated by the experiments below. A synergistic effect exists wherever the action of a combination (ready-mix) or tank mix of active ingredient is greater than the sum of the action of each of the components alone. Therefore a synergistically effective amount or an effective amount of a synergistic composition or combination is an amount that exhibits greater pesticide activity than the sum of the pesticide activities of the individual components.
In the field of agriculture, it is often understood that the term “synergy” is as defined by Colby S.R. in an article entitled “ Calculation of the synergistic and antagonistic responses of herbicide combinations” published in the journal Weeds, 1967, 15, p.20-22, incorporated herein by reference in its entirety. The action expected for a given combination of two or three active components can be calculated as follows:

The objective of the present studies were to study the synergism between saflufenacil + Atrazine + one more herbicide selected from different groups.
Experimental study-
Example 1: Weed control in Sugarcane. Saccharum officinarum.
Crops: Sugarcane
No. of Treatments: 20
Plot size: 40 sq. mt.
Application Time: Early post emergence, 2 to 6 leaf stage of weeds, crop at 24 days after planting.
Spray Volume: 400 liter water per hectare
Application Equipment: Manually operated knapsack sprayer fitted with flat fat nozzle
Weed control(%): Species wise weed count recorded by using 0.25 m2 (50 cm x 50 cm) quadrant treatment wise in minimum 5 places randomly selected in the plot. The average of each variable was used together with the sum of all the variables per plot to calculate the percentage of control.

The % weed control (observed value) data used in Colby’s formula to calculate the synergism.
Phytotoxicity: The observations on crop safety i.e. phytotoxicity or adverse effect of treatments were recorded at regular interval. All the visual phytotoxicity symptoms like plant yellowing, leaf scorching, tip burning, bleaching, necrosis, stunting, crinkling, epinasty, hyponasty recorded by rating (0 to 10 score) the entire plot in comparison with untreated control (UTC) plot. Following rating were adopted. Score 0=No injury, Score 1=1 to 10%, Score 2=11 to 20%, Score 3=21 to 30%.......Score 10=91 to 100% Phytotoxicity.

Table 1: Treatment details.
Treatment number Treatment details Rate (gai/h)
T1 Saflufenacil 2%+Atrazine 20%+Topramezone 0.67% OD (Recipe:A), 3000 ml 60+600+20
T2 Saflufenacil 2%+Atrazine 20%+Mesotrione 2% OD (Recipe:P), 3000 ml 60+600+60
T3 Saflufenacil 2%+Atrazine 20%+Tembotrione 2% OD (Recipe: Q), 3000 ml 60+600+60
T4 Saflufenacil 2%+Atrazine 20%+Tolpyralate 1.33% OD (Recipe: R), 3000 ml 60+600+40
T5 Saflufenacil 70% WG+Atrazine 50% WP* 60+600
T6 Saflufenacil 70% WG+Topramezone 33.6% SC* 60+20
T7 Saflufenacil 70% WG+Mesotrione 10% SC* 60+60
T8 Saflufenacil 70% WG+Tembotrione 34.4% SC* 60+60
T9 Saflufenacil 70% WG+Tolpyralate 40% SC* 60+40
T10 Atrazine 30%+Topramezone 1% SC, 2500 ml 750+25
T11 Atrazine 22.7%+Mesotrione 2.27% SC, 3500 ml 794.5+79.45
T12 Atrazine 50% WP+Tembotrione 34.4% SC* 750+25
T13 Atrazine 50% WP+Tolpyralate 40% SC* 720+40
T14 Saflufenacil 70% WG* 60
T15 Atrazine 50% WP* 600
T16 Topramezone 33.6% w/v SC* 20
T17 Mesotrione 10% w/v SC* 60
T18 Tembotrione 34.4% w/w, 42% w/v SC* 60
T19 Tolpyralate 35.7% w/w, 40% w/v SC* 40
T20 Untreated control (UTC) -

gai/h-gram active ingredient per hectare, OD oil dispersion, SC suspension concentrate, EC emulsifiable concentrate, WG wettable granule, WP wettable powder.
T1 to T4 are novel OD compositions, T5 to T9 are known tank mixes, T10 & T11 are conventional ready mix composition, T12 & T13 are known tank mixes.
*Non ionic surfactant @ 2 ml/l of spray volume was added.
Weed flora composition observed in trial plot- Grassy weeds (Echinochloa colona, Dactyloctenium aegyptiana), Broad leaf weeds (Digera arvensis, Trianthema monogyna).

Table 2: Weed population in UTC (untreated plot). Average weed count /0.25 sq.m.
15 DAA 30 DAA
Echinochloa colona Dactyloctenium aegyptiana Digera arvensis Trianthema mongyna Echinochloa colona Dactyloctenium aegyptiana Digera arvensis Trianthema mongyna
12.2 8.4 9.2 2.6 18.8 9.6 10.2 8.6

Table 3: Weed control in Sugarcane crop.

Treatment number Weed control (%)
15 DAA 30 DAA
Observed Expected Colby's ratio Observed Expected Colby's ratio Synergism (Y/N)
T1 100.0 93.13 1.07 98.6 87.31 1.13 Y
T2 100.0 92.62 1.08 97.4 86.30 1.13 Y
T3 100.0 92.89 1.08 98.2 86.64 1.13 Y
T4 100.0 93.44 1.07 97.6 87.54 1.11 Y
T5 82.8 80.47 70.2 71.93
T6 86.6 84.79 74.4 76.68
T7 84.8 83.67 72.8 74.82
T8 85.2 84.28 73.6 75.44
T9 86.6 85.48 75.8 77.09
T10 87.8 84.09 75.0 75.41
T11 88.4 82.91 72.8 73.45
T12 84.6 83.55 69.6 74.11
T13 86.4 84.81 70.8 75.85
T14 56.8 48.4
T15 54.8 45.6
T16 64.8 54.8
T17 62.2 51.2
T18 63.6 52.4
T19 66.4 55.6
T20 0.0 0.0
DAA Days After application.
All the novel OD compositions (T1 to T4) provides synergistic residual control of mixed weeds flora. None of the treatment shows any kind of phytotoxicity symptoms.

Experimental study-
Example 2: Weed control in maize, Zea mays.
Crops: Sugarcane
No. of Treatments: 20
Plot size: 40 sq. mt.
Application Time: Early post emergence, weeds at 2 to 4 leaf stage, crop at 18 days after planting.
Spray Volume: 400 liter water per hectare
Application Equipment: Manually operated knapsack sprayer fitted with flat fat nozzle
Weed count: Count the number of weeds from 50 cm x 50 cm (0.25 sq.m.)spot, record the observations from 5 spots per plot.
Weed control (%): as given Example 1.
Shoot count: Count the number of effective shoot per 1 meter row length (mrl).
Record the observations from 10 spots per plot.

Table 4: Treatment details.
Treatment number Treatment details Rate (gai/h)
T1 Saflufenacil 3%+Atrazine 20%+
Metsulfuron methyl 0.2% OD 75+500+5
T2 Saflufenacil 2.5%+Atrazine 16.67%+Halosulfuron methyl 1.5% OD (Recipe: SAH-OD-1) 75+500+45
T3 Saflufenacil 1.5%+Atrazine 10%+Sulfentrazone 12% OD (Recipe:SAM2) 75+500+600
T4 Saflufenacil 1.5%+Atrazine 10%+Clomazone 12% OD 75+500+600
T5 Saflufenacil 70% WG+Atrazine 50% WP* 75+500
T6 Saflufenacil 70% WG+Metsulfuron methyl 20% WP* 75+5
T7 Saflufenacil 70% WG+Halosulfuron methyl 75% WG* 75+45
T8 Saflufenacil 70% WG+Sulfentrazone 48% SC* 75+600
T9 Saflufenacil 70% WG+Clomazone 50% EC* 75+600
T10 Atrazine 50% WP+Metsulfuron methyl 20% WP* 500+5
T11 Atrazine 50% WP+Halosulfuron methyl 75% WG* 500+45
T12 Atrazine 50% WP+Sulfentrazone 48% SC* 500+600
T13 Atrazine 50% WP+Clomazone 50% EC 600+600
T14 Saflufenacil 70% WG* 75
T15 Atrazine 50% WP 500
T16 Metsulfuron methyl 20% WP* 5
T17 Halosulfuron methyl 75% WG* 45
T18 Sulfentrazone 39.6% w/w (48% w/v) SC* 600
T19 Clomazone 50% EC 600
T20 Untreated control (UTC) -

T1 to T4 are novel OD compositions, T5 to T13 are known tank mixes.
*Non-ionic surfactant @ 2 ml/l of spray volume was added.

The weed flora, population and composition observed in trials plot as below.
Table 5: weed flora composition and population in trial plot.
Weed group weed species Average weed count/0.25 sq.m.
20 DAA 40 DAA 60 DAA
Grassy weeds Echinochloa colonum 3.2 7.4 12.8
Brachiaria repens 0.0 3.6 6.4
Broad leaf weeds Trianthema monogyna 12.8 23.4 28.6
Tribulus terristris 0.0 5.2 8.2
Xanthium spp. 0.0 2.6 3.6
Sedges Cyperus rotundus 5.2 6.8 10.4

Table 6: Residual weed control in Sugarcane.
Treatment number Weed control (%) Number of shoots per mrl Increase(%) in shoots over T20
20 DAA 40 DAA 60 DAA
T1 100.0 94.4 88.40 40.3 59.3
T2 100.0 93.6 83.80 41.7 64.8
T3 100.0 97.8 90.80 42.7 68.8
T4 100.0 98.2 92.60 43.5 71.9
T5 88.2 74.6 61.40 33.7 33.2
T6 85.6 70.8 56.80 35.3 39.5
T7 82.4 66.6 54.20 35.1 38.7
T8 87.2 72.4 60.80 38.7 53.0
T9 88.6 73.2 57.80 37.5 48.2
T10 81.4 67.8 55.60 31.5 24.5
T11 77.6 64.6 53.20 32.3 27.7
T12 84.4 70.4 59.20 34.7 37.2
T13 85.2 71.2 60.40 33.9 34.0
T14 66.4 55.8 40.6 29.5 16.6
T15 60.2 50.6 32.6 28.5 12.6
T16 51.8 44.4 30.8 26.7 5.5
T17 40.6 33.2 22.6 27.7 9.5
T18 58.6 50.6 38.6 30.7 21.3
T19 60.4 51.4 37.4 29.8 17.8
DAA Days after application.
All the novel OD compositions (T1 to T4) provides synergistic residual control of mixed weeds flora up to 60 days after application. The number of effective shoots (which are directly contributing to the cane yield) are also observed higher in all the novel OD compositions (T1 to T4).

Experimental study-
Example 3: Bio efficacy comparison of Novel OD compositions with conventional compositions.
Crops: Sugarcane
No. of Treatments: 7
Plot size: 50 sq. mt.
Application Time: 30 days after planting.
Spray Volume: 400 liter water per hectare.
Application Equipment: Manually operated knapsack sprayer fitted with flat fat nozzle
Weed control (%): as given in Example 1.
Table 7: Treatment details
Treatment number Treatment details Rate (gai/h)
T1 Saflufenacil 2%+Atrazine 20%+Topramezone 0.67% OD (Recipe:A), 3000 ml 60+600+20
T2 Saflufenacil 2%+Atrazine 20%+Topramezone 0.67% OD (Recipe:B), 3000 ml 60+600+20
T3 Saflufenacil 6%+Atrazine 60%+Topramezone 2% WG (Recipe:D), 1000 g 60+600+20
T4 Saflufenacil 2.4%+Atrazine 24%+Topramezone 0.8% SC (Recipe:E), 2500 ml 60+600+20
T5 Saflufenacil 2.4%+Atrazine 24%+Topramezone 0.8% SE (Recipe:F), 2500 ml 60+600+20
T6 Saflufenacil 70% WG+Atrazine 50% WP+Topramezone 33.6% SC 60+600+20
T7 Untreated control (UTC) -

T1-novel OD composition, T2 conventional OD, T3 conventional WG, T4 conventional SC, T5 conventional SE, T6 on farm tank mixes.

Weed flora in trial plot: Grassy weeds (Brachiaria mutica, Dinebra spp.,), Broad leaf weeds (Trianthema monogyna, Parthenium hysterophorus, Portulaca oleracea), Sedges (Cyperus rotundus).

Table 8: Weed control in sugarcane
Treatment number Weed control (%)
15 DAA 30 DAA T1 provides higher weed control
T1 100.0 99.2 Over at 15 DAA at 30 DAA
T2 94.2 86.8 T2 (conventional OD) 5.8 12.4
T3 92.6 84.2 T3 (conventional WG) 7.4 15.0
T4 95.8 89.6 T4 (conventional SC) 4.2 9.6
T5 94.2 87.4 T5 (conventional SE) 5.8 11.8
T6 88.6 80.8 T6 (tank mixes) 11.4 18.4
T7 0.0 0.0

The novel OD composition (T1-Saflufenacil 2%+Atrazine 20%+Topramezone 0.67%) provides higher weed control as compared all the known conventional treatments i.e., T2, T3, T4, T5 and T6.

Experimental study-
Example 4: Weed control in fallow land.
Crops: Non crop area (fallow land)
No. of Treatments: 6
Plot size: 200 sq. mt.
Application Time: On full grown weeds.
Spray Volume: 420 liter water per hectare
Application Equipment: Manually operated knapsack sprayer fitted with flat fat nozzle
Weed count: Count the number of weeds from 50 cm x 50 cm (0.25 sq.m.)spot, record the observations from 5 spots per plot.
Weed control (%): as given Example 1.
Table 9: Treatment details
Treatment number Treatment details Rate (gai/h)
T1 Saflufenacil 2.5%+Atrazine 16.67%+Halosulfuron methyl 1.5% OD (Recipe: SAH-OD-1), 3000 ml 75+500+45
T2 Saflufenacil 2.5%+Atrazine 16.67%+Halosulfuron methyl 1.5% OD (Recipe: SAH-OD-1), 2400 ml 60+400+36
T3 Saflufenacil 7.5%+Atrazine 50%+Halosulfuron methyl 4.5% WG, 1000 g 75+500+45
T4 Saflufenacil 7.5%+Atrazine 50%+Halosulfuron methyl 4.5% WG, 800 g 60+400+36
T5 Saflufenacil 70% WG+Atrazine 50% WP+Halosulfuron methyl 75% WG 75+500+45
T6 Saflufenacil 70% WG+Atrazine 50% WP+Halosulfuron methyl 75% WG 60+400+36

T1 & T2 novel OD composition, T3&T4 conventional WG formulation, T5&T6 conventional on farm tank mixes.

Table 10: weed control in fallow land.
Treatment number 20 DAA Drop in efficacy
T1 100.0 T1-T2=6.8
T2 93.2
T3 98.4 T3-T4=13.8
T4 84.6
T5 91.4 T5-T6=18.0
T6 73.4

The field trial results shows that when the dose of novel OD composition reduced (from 3000 ml/h to 2400 ml/h) by 20%, the weed control was reduced only 6.8%, where as it was 13.8% in conventional WG and on farm tank mixes. The novel OD composition provides higher weed control in comparison with conventional WG and on farm tank mixes.
Experimental study-
Example 5: Spreading properties study:
Method: Spreading properties test conducted by preparing 1% solution (1 ml formulation in 100 ml water). Drop the solution on leaf surface of weed (Xanthium spp. leaf) and measure the spreading diameter (mm) after 30 seconds. Spreading diameter measured by graph paper.
Table 11: spreading properties study.
Compositions Room temperature storage
1 month 6 months 12 months
(Spreading diameter in millimetres)
Saflufenacil 2.5%+Atrazine 16.67%+Halosulfuron methyl 1.5% OD (Recipe: SAH-OD-1) 22 21 20
Saflufenacil 2.5%+Atrazine 16.67%+Halosulfuron methyl 1.5% OD (Recipe: SAH-OD-2) 12 10 9
Saflufenacil 2.5%+Atrazine 16.67%+Halosulfuron methyl 1.5% SC (conventional) 11 9 8
Saflufenacil 5%+Atrazine 33.33%+Halosulfuron methyl 3% WG (coventional) 7 6 5

The composition of Saflufenacil 2.5%+Atrazine 16.67%+ Halosulfuron methyl 1.5% (Recipe: SAH-OD-1) shows excellent spreading properties. This will improves the bio-efficacy under field condition, ensures quick control of target weeds and also improves the rainfast properties during rainy days.

Summary of the biological experiments:
• Excellent synergistic weed control of grassy, broad leaf weeds and sedges.
• Improved bio-efficacy against tough to kill weeds.
• Residual weed control.
• Excellent crop safety to maize and sugarcane.
• Increases in yield attributing parameters.
,CLAIMS:CLAIMS
We claim;
[CLAIM 1]. A synergistic Oil Dispersion agrochemical composition comprising:
a. Saflufenacil present in amount of 1% - 20% w/w;
b. Atrazine present in amount of 1% - 30% w/w;
c. a herbicide compound selected from group of herbicide present in an amount of present in amount of 1% - 30% w/w;
d. a super wetting-spreading-penetrating agent is polyalkylene oxide modified heptamethyl trisiloxane present in an amount of 1% to 20% w/w;
e. carrier solvent selected from pongamia oil, palm oil, jojoba oil or combination thereof or blend thereof with vegetable oil present in an amount of 10% to 80% w/w; and
one or more formulation excipients.

[CLAIM 2]. The synergistic Oil Dispersion agrochemical composition as claimed in claim 1, wherein a herbicide compound is selected from clodinafop-propargyl, cyhalofop-butyl, diclofop, fenoxaprop-P-ethyl, fluazifop-P-butyl, haloxyfop, metamifop, propaquizafop, quizalofop-P-ethyl; alloxydim, butroxydim, clethodim, cycloxydim, sethoxydim, tralkoxydim, tepraloxydim; pinoxaden, amidosulfuron, azimsulfuron, bensulfuron methyl, chlorimuron ethyl, chlorsulfuron, cinosulfuron, cloransulfuron methyl, cyclosulfamuron, ethametsulfuron methyl, ethoxysulfuron, flazasulfuron, flucetosulfuron, flupyrsulfuron methyl sodium, foramsulfuron, halosulfuron methyl, imazosulfuron, iodosulfuron, mesosulfuron, metazosulfuron, metsulfuron mehtyl, nicosufulfuron, primisulfuron methyl, propyrisulfuron, prosulfuron, pyrazosulfuron ethyl, rimsulfuron, rimsulfuron, sulfometuron methyl, sulfosulfuron, thifensulfuron-methyl, triasulfuron, tribenuron methyl, trifloxysulfuron, triflusulfuron methyl; bispyribac-sodium, pyribenzoxim, pyrithiobac sodium; cloransulam-methyl, diclosulam, florasulam, flumetsulam, penoxsulam, pyroxsulam; Triazolinone-flucarbazone-sodium, propoxycarbazone-sodium, thiencarbazone-methyl; Imidazolinone: imazamethabenz methyl, Imazamox, imazapic, imazapyr, imazaquin, imazethapyr; Sulfonanilides: triafamone, pyrimisulfan, benefin, trifluralin, ethafluralin, oryzalin, pendimethalin, prodiamine; DCPA; dithiopyr, thiazopyr; pronamide, 2, 4-D, 2, 4-DB, dichloroprop, MCPA, MCPB, mecoprop; Pyrimidine carboxylic acid: aminocyclopyrachlor; aminopyralid, lopyralid, florpyrauxifen benzyl, fluroxypyr, picloram, triclopyr; dicamba; halauxifen methyl, desmedipham, phenmedipham; Pyridazinone: pyrazon; ametryn, cyanazine, desmetryn, prometon, prometryn, propazine, simazine, simetryn, terbumeton, terbuthylazine, trietazine; hexazinone, metamitron, metribuzin; amicarbazone; metoxuron; bromacil, terbacil; bentazone; bromoxynil, ioxynil; pyridate; propanil; chlorotoluron, dimefuron, diuron, fluometuron, isoproturon, linuron, methibenzuron, monolinuron, siduron, tebuthiuron; ethofumesate; Phosphorodithioate: bensulie; Thiocarbamate: butylate, cycloate, EPTC, esprocarb, molinate, pebulate, prosulfocarb, thiobencarb, triallate, vernolate; Glyphosate; glufosinate, diflufenican, picolinafen; Pyridazinone: norflurazon; others: beflubutamid, fluridone, flurochloridone, flurtamone, clomazone, aclifluorfen, bifenox, fluoroglycofen, fomesafen, lactofen, oxyfluorfen; azafenidin, carfentrazone-ethyl, flufenpyr-ethyl, sulfentrazone; butafenacil, flumiclorac, flumioxazin; trifludimoxazin; fluthiacet-methyl; oxadiargyl, oxadiazon; pyraflufen-ethyl, pyraclonil; tiafenacil; cyclopyranil, acetochlor, alachlor, butachlor, dimethenamid, metazachlor, pretilachlor, propachlor, S-metolachlor, thenylchlor; fentrazamide; flufenacet, mefenacet; napropamide; anilofos; carbetamide, asulam, diflufenzopyr, naptalam, indaziflam, triaziflam, dichlobenil, chlorthiamide; cyperquat, diquat, morfamquat, paraquat; dinoterb; bipyrazone, cypyrafluone, fenpyrazone, tripyrasulfone, benzofenap, pyrasulfotole, pyrazolynate, pyrazoxyfen, tolpyralate; benzobicyclon; mesotrione, tembotrione, sulcotrione, tefuryltrione, fenquinotrione, lancotrione sodium, benquitrione, dioxopyritrione; isoxaflutole; bicyclo ring compound: bicyclopyrone; topramezone, rimisoxafen; cinmethylin, methiozolin; Tetflupyrolimet; cyclopyrimorate; pyroxasulfone, fenoxasulfone; ipfencarbazone; dimesulfazet; amitrole; aclonifen; endothall; bromobutide, pelargonic acid, diphenamid, naproanilide, napropamide, copper (salt), epyrifenacil, bixlozone, dietholate, dicyclonon, naphthalic anhydride, mephenate, flurazole, cyometrinil.

[CLAIM 3]. The synergistic Oil Dispersion agrochemical composition as claimed in claim 2, wherein herbicide compound is selected most preferred from topramezone, mesotrione, tembotrione, tolpyralate, metsulfuron methyl, chlorimuron ethyl, halosulfuron methyl, clomazone, sulfentrazone

[CLAIM 4]. The synergistic Oil Dispersion agrochemical composition as claimed in claim 1-claim 3, wherein preferred combinations of active ingredients in the said Oil Dispersion agrochemical composition comprises:
i. Saflufenacil 2%+atrazine 20%+ topramezone 0.67%;
ii. Saflufenacil 2%+atrazine 20%+ mesotrione 2%;
iii. Saflufenacil 2%+atrazine 20%+ tembotrione 2%;
iv. Saflufenacil 2%+atrazine 20%+ tolpyralate 1.33%;
v. Saflufenacil 3%+atrazine 20%+ metsulfuron methyl 0.2%;
vi. Saflufenacil 3%+atrazine 20%+ chlorimuron ethyl 0.2%;
vii. Saflufenacil 2.5%+atrazine 16.67%+ halosulfuron methyl 1.5%;
viii. Saflufenacil 1.5%+atrazine 10%+ clomazone1 2%;
ix. Saflufenacil 1.5%+atrazine 10%+ sulfentrazone 12%.

[CLAIM 5]. The synergistic Oil Dispersion agrochemical composition as claimed in claim 1, wherein solvent is a carrier oil phase selected from pongamia oil; or palm oil; or pongamia oil and palm oil; or pongamia oil and jojoba oil; or palm oil and jojoba oil; or pongamia oil and vegetable oil; or palm oil and vegetable oil; or pongamia oil and palm oil and vegetable oil; and alkylated or ethoxylated or epoxylated or esterified forms thereof selected from methyl ester of karanj oil, methyl ester of palm oil, methyl ester of karanj oil and soybean oil, methyl ester of palm oil and castor oil, methyl ester of palm oil and rapeseed oil.

[CLAIM 6]. The synergistic Oil Dispersion agrochemical composition as claimed in claim 1, wherein vegetable oil may be selected from one or mixture of two or more selected from soybean (Glycine max) oil, groundnut (Arachis hypogaea) oil, rapeseed (Brassica napus subspecies) oil, mustard (Brassica juncea) oil, sesame (Sesamum indicum) oil, Corn (Zea mays) oil, rice (Oryza sativa) bran oil, castor (Ricinum communis) seed oil, cotton (Gossypium hirsutum) seed oil, linseed (Linum usitatissimum), coconut (Cocos nucifera) oil, Kapok (Ceiba pentandra) oil, Papaya (Carica papaya) seed oil, Tea seed (Camellia oleifera) oil, sunflower (Helianthus annuus) oil, safflower (Carthamus tinctorius) seed oil, Eucalyptus (Eucalyptus globulus) oil, Olive (Olea europaea) oil, Jatropha (Jatropha curcas) oil, Garlic acid (Allium sativum), Ginger oil (Zingiber officinale), D-limonene, Citronella oil or Ceylon ironwood (Mesua ferrea) oil, Mahua (Madhuca longifolia) oil.

[CLAIM 7]. The synergistic Oil Dispersion agrochemical composition as claimed in claim 1, wherein formulation excipients are selected from category of emulsifying agent present in amount of 2% - 12% w/w; dispersing agent present in amount of 1 % - 10% w/w; stabilizer present in amount of 0.1% - 4 % w/w; antifoaming agent present in amount of 0.01% - 2 % w/w; preservative present in amount of 0.1% - 4 % w/w; anti-freezing agent present in amount of 0.5% - 10 % w/w; optionally buffering agents present in amount of 0.1% - 4 % w/w.

[CLAIM 8]. The synergistic Oil Dispersion agrochemical composition as claimed in claim 7, wherein an emulsifying agent is selected from castor oil ethoxylates, alcohol ethoxylates, fatty acid ethoxylates, sorbitan ester ethoxylates, sulphosuccinate, calcium salts of dodecylbenzene sulphonate, alkylammonium salts of alkylbenzene sulphonate, alkylsulphosuccinate salts, ethylene oxide-propylene oxide block copolymers, ethoxylated alkylamines, ethoxylated alkyl phenols, polyoxyethylene sorbitan monolaurate.

[CLAIM 9]. The synergistic Oil Dispersion agrochemical composition as claimed in claim 7, wherein dispersing agent is selected from preparation of condensed naphthalene sulfonate, Propoxylated Ethoxylated copolymer monoalkylether (ethylhexanol), alkyl sulfonates, alkyl benzene sulfonates, alkyl aryl sulfonates, alkylphenolalkoxylates, tristyrylphenol ethoxylates, natural or synthetic fatty ethoxylate alcohols, natural or synthetic fatty acid alkoxylates, natural or synthetic fatty alcohols alkoxylates, alkoxylated alcohols (such as n-butyl alcohol poly glycol ether), block copolymers (such as ethylene oxide-propylene oxide block copolymers and ethylene oxide-butylene oxide block copolymers), fatty acid-polyalkylene glycol condensates, polyamine-fatty acid condensates, polyester condensates, salts of polyolefin condensates, sodium ligno sulfonate, sodium ploycarboxylate, EO/PO based copolymer, phenol sulfonate, sodium methyl oleoyl taurate, acrylic copolymer blend, styrene acrylic acid copolymer, propyleneoxide-ethyleneoxide-copolymer, polyethylene glycol 2,4,6-tristyrylphenyl ether, tristyrylphenol-polyglycolether-phosphate, tristyrylphenole with 16 moles EO, tristyrylphenol-polyglycolether-phosphate, oleyl-polyglycolether with ethylene oxide, tallow fattyamine polyethylene oxide, nonylphenol polyglycolether with 9-10 moles ethylene oxide.

[CLAIM 10]. The synergistic Oil Dispersion agrochemical composition as claimed in claim 7, wherein stabilizer is selected from hectorite clay, aluminium magnesium silicate, bentonite clay, silica, silicon dioxide, attapulgite clay.

[CLAIM 11]. The synergistic Oil Dispersion agrochemical composition as claimed in claim 7, wherein antifoaming agent is selected from silicone oil, silicone compound, C10~C20 saturated fat acid compounds or C8~C10 aliphatic alcohols compound, silicone antifoam emulsion, dimethylsiloxane, polydimethyl siloxane.

[CLAIM 12]. The synergistic Oil Dispersion agrochemical composition as claimed in claim 7, wherein anti-freezing agent is selected from ethylene glycol, propane diols, glycerine or the urea, glycol (Monoethylene glycol, Diethylene glycol, Propylene glycol, Polypropylene glycol, Polyethylene glycol), glycerine, urea, magnesium sulfate heptahydrate, sodium chloride.

[CLAIM 13]. The synergistic Oil Dispersion agrochemical composition as claimed in claim 7, wherein preservative is selected from 1,2-benzisothiazolin-3(2H)-one, sodium salt, sodium benzoate, 2-bromo-2-nitropropane-1,3-diol, formaldehyde, sodium o-phenylphenate, 5-chloro-2-methyl-4-isothiazolin-3-one & 2-methyl-4-isothiazolin-3-one, Butyl hydroxyl toluene.

[CLAIM 14]. The synergistic Oil Dispersion agrochemical composition as claimed in claim 7, wherein optionally buffering agent is selected Citric acid, sodium carbonate, sodium bicarbonate, sulphuric acid, hydrochloric acid, sodium hydroxide, potassium hydroxide, acetic acid, sorbic acid.

Dated this 20th day of January 2023