FORM-2
THE PATENTS ACT, 1970
COMPLETE SPECIFICATION
SECTION 10

TITLE

A SEALED TANK INTENDED FOR CARRYING OUT METHANE FERMENTATION TREATMENTS OF LIQUID EFFLUENT

APPLICANTS

DEGREMONT*
183 AVENUE
DE18JUIN1940
F-92508
RUIEL- MALMAISON,
FRANCE
A FRENCH COMPANY

The following Specification particularly describes the nature of this invention and the manner
in which it is to be performed :-

The present invention relates to a sealed tank intended for carrying out methane fermentation treatments on liquid effluent such as sludges, manures, urban or industrial effluents, for example, or for storing a medium in a corrosive environment.
This invention is particularly applicable to sealed chambers or tanks in which methane fermentation treatments are performed on liquid effluents at various concentrations. It is known that methane fermentation, sometimes known as "digestion", is a bacterial process that threats the organic matter of the following kinds of effluent: sludges from purification stations, swine manure from pig farms, urban waste water or water from industrial processes. The ultimate purpose of the methane fermentation varies widely: the production of methane for use as energy, the stabilization of fermentation, the reduction of the mass of organic matter, the reduction of carbon-containing pollutants for compliance with standards prior to discharge into the environment, etc.
A methane fermentation chamber or digester is generally in the form of a sealed tank comprising a concrete base on which there rests a steel or concrete shell ring covered by a dome, the said tank being filled with a sludge or manure liquor.
The bacterial processes carried out in these methane fermentation chambers or
digesters produce a biogas made up essentially of methane and carbon dioxide,
but also containing corrosive gases including, in particular, hydrogen sulphide.
It is therefore necessary for the materials of which the methane fermentation
constructions or digesters are made
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(common steels and concrete) to be sealed against the corrosive gases and for them to be able to withstand the corrosion that these cause.
At the present time, surfaces of a construction in contact with corrosive gases are protected by coatings of epoxy pitch, polyurethane or other equivalent painted-on treatments. These coatings have a number of drawbacks and so, in the case of concrete
constructions:
there is the need ..to apply the coating to perfectly
dry concrete, this resulting in a waiting time of 28 days after the civil engineering work has been completed,
- there is the need to prepare the entire surface in order to remove any chalking and in order to repair any imperfections in the stonework,
- there is the need, because of the enclosed nature of the construction, to install a sizeable air renewal system and to operate with a solvent-free paint,
- there is the need for rigorous use of protective clothing when using epoxy pitch, contact with which is dangerous. An increasing number of countries are banning this substance because of this. Polyurethane involves fewer restrictions, but is more expensive,
- there is the risk of the coating becoming torn and the protection therefore becoming ruined if the concrete cracks by a few tenths of a millimetre,
3 5 - there is a risk that the coating will lift through the ingress of moisture into the concrete from unprotected surfaces.
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In the case of steel constructions, the constraints on renewing the air and protecting the person applying the coating are the same. What is more, there is also the need to peen the surface before this kind of paint coating can be applied.
A steel construction can also be provided by the use of a steel sheet covered with a protective layer of glass. Aside for its higher cost, this technique demands special precautions through out the duration of the work, so as to avoid any cracking in the layer of glass. In addition, the difference in expansion that there is between steel and glass leads to a risk of cracking in heated buildings, this being of particular concern in the case of methane fermentation constructions operating at 35°C. Finally, the mastic seals used to seal the joins between the sheets are not good at resisting corrosion from the gases.
It has therefore become perfectly apparent that, in the prior art, producing a device for protecting methane fermentation constructions is awkward and involves a number of uncertainties detrimental to the life of the constructions.
In another field, there are flexible gas holders for storing the biogas that results from the methane processes. These gas holders are fixed to a concrete footing and consist of a double membrane: an inner membrane producing a sealed chamber intended to receive the biogas, and an outer membrane enveloping the inner membrane and which, when pressurized, applies a given pressure to the volume of biogas contained in the inner membrane. These flexible gas holders can also be installed directly on a conventional digester of the type specified hereinabove, in place of the dome.
GB-A-2 162 195 describes a fixing for a membrane for a fermentation
reactor, of the gas holder type, employing
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an inflatable bulge inserted in a metal profile section. This publication of the prior art does not envisage means for providing a seal between the metal profile section and the wall of the reactor and, this being the case, the problem resulting from the corrosion due to the corrosive gas is not solved.
Starting from this state of the art, the present invention proposes to produce a methane fermenter/digester covered with a dome of the flexible gas holder type in which the shell ring of the methane fermenter/digester is protected by means which are economical and reliable over time.
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2D
The present invention proposes to provide a solution to the problems of the devices of the prior art recalled hereinabove, by setting itself as objectives to avoid the use of a corrosion-proof coating on those parts of the construction which are exposed to the corrosive environment and also to eliminate the need to make a seal between the upper part of the shell ring and the means intended for covering the latter, particularly a sealed double membrane.
2 5 In consequence, the subject of this invention is a
sealed tank intended for carrying out methane fermentation treatments on liquid effluent such as sludges, manures, urban or industrial effluents, for example, or for storing a medium in a corrosive
3 0 environment, comprising a concrete footing, a steel or
concrete shell ring and a sealed and corrosion-resistant dome consisting of a double membrane: an inner membrane delimiting, with the surface of the liquid effluent contained in the said shell ring, a 35 sealed chamber intended to receive the biogas that results from the methane fermentation, or the said corrosive environment, and an outer membrane enveloping the inner membrane and which, when pressurized, applies a given pressure to the volume of biogas or of

corrosive environment contained in the said chamber, the said sealed tank being characterized in that the said inner membrane is extended downwards by a skirt, the lower part of which is submerged below the level of liquid effluent contained in the tank so as thus to seal the chamber delimited above the said level, the said skirt being fixed, around its entire periphery, below the level of liquid effluent, to the interior wall of the said shell ring by a seal pressed against the said wall, using flat stainless steel bars which are fixed into the wall, it being possible, for example, for this fixing to be achieved using bolts, fitted with sealing washers known as "bonded seal" washers.
According to the invention, the 'said seal is preferably made of a synthetic material, such as neoprene in particular.
Other features and advantages of the invention will become apparent from the description given hereinafter with reference to the appended * drawing which illustrates one exemplary embodiment thereof, with no limitation implied.
In the accompanying drawing:
- Figure 1 is a diagrammatic view in vertical section depicting a digester according to the present invention, and
- Figures 2 and 3 are detailed views, also in vertical section on a larger scale, illustrating two exemplary embodiments of means envisaged by the invention for positioning and fixing the skirt of the inner membrane on the shell ring of the tank.
Referring to Figure 1, this depicts a construction for methane fermentation employing the present invention.