Abstract: A welded component a welded gas turbine component and a process of welding a component are disclosed. The welded component includes a first alloy a second alloy and a weld positioned between the first alloy and the second alloy. The weld is formed by a first shim and a second shim being beam welded.
A WELDED COMPONENT A WELDED GAS TURBINE COMPONENT AND A PROCESS OF WELDING A COMPONENT
FIELD OF THE INVENTION
[0001] The present invention is directed to manufactured components and processes of forming manufactured components. More specifically the present invention relates welded components and processes of welding components.
BACKGROUND OF THE INVENTION
[0002] The operating temperature within a gas turbine is both thermally and chemically hostile. Significant advances in high temperature capabilities have been achieved through the development of iron nickel and cobalt-based superalloys and the use of environmental coatings capable of protecting superalloys from oxidation hot corrosion etc. Parts can be fabricated by joining subcomponents including the superalloys. It is desirable to improve weldability based upon liquation and strain age cracking. Improving the weldability can extend the usable life of the parts.
[0003] In the compressor portion of a gas turbine atmospheric air is compressed to 10-25 times atmospheric pressure and adiabatically heated to 700° F - 1250° F (371° C - 677° C) in the process. This heated and compressed air is directed into a combustor where it is mixed with fuel. The fuel is ignited and the combustion process heats the gases to very high temperatures in excess of 3000° F (1650° C). These hot gases pass through the turbine where airfoils fixed to rotating turbine disks extract energy to drive an attached generator which produces electrical power. To improve the efficiency of operation of the turbine combustion temperatures have been raised. Of course as the combustion temperature is raised steps must be taken to prevent thermal degradation of the materials forming the flow path for these hot gases of combustion.
[0004] Certain known alloys may be used for components disposed along the flow path of these hot gases. Certain portions of these components must be able to withstand temperatures higher than other portions of these components. For example certain portions may be resistant to temperatures for adiabatically heated (for example 800° F - 1250° F) and other portions may be further resistant to hot gases heated by the combustion processes (for example in excess of 3000° F). Components made entirely of alloys resistant to the highest temperature may be undesirable by being overly expensive or by failing to include other properties desirable in other portions of the components. Alternatively components made entirely of alloys resistant only to the temperature of the lower temperature portions may fail.
[0005] A welded component a welded gas turbine component and a process of welding a component that do not suffer from one or more of the above drawbacks would be desirable in the art.
BRIEF DESCRIPTION OF THE INVENTION
[0006] According to an exemplary embodiment a welded component includes a first alloy subcomponent a second alloy subcomponent and a weld between the first alloy subcomponent and the second alloy subcomponent. The weld includes a gradient having a transition region.
[0007] According to another exemplary embodiment a welded gas turbine component includes a first alloy a second alloy and a weld positioned between the first alloy and the second alloy. The weld is formed by a first shim and a second shim being beam welded.
[0008] According to another exemplary embodiment a process of welding a component includes positioning a first alloy positioning a second alloy positioning a first shim and a second shim between the first alloy and the second alloy and beam welding the first shim and the second shim to form a weld between the first alloy and the second alloy.
[0009] Other features and advantages of the present invention will be apparent from the following more detailed description of the preferred embodiment taken in conjunction with the accompanying drawings which illustrate by way of example the principles of the invention.
BRIEF DESCRIPTION OF THE DRAWINGS
[0010] FIG. 1 shows a perspective view of a component being welded.
[0011] FIG. 2 shows a schematic side view of a component having a joint gap between a first portion and a second portion.
[0012] FIG. 3 shows a schematic side view of a component having two shims inserted between a first portion and a second portion of the component.
[0013] FIG. 4 shows a schematic side view of a component having a weld formed by beam welding of two shims inserted between a first portion and a second portion of the component.
[0014] FIG. 5 shows a schematic side view of two shims positioned within a component and welded within the component.
[0015] FIG. 6 shows a schematic side view of three shims positioned within a component and welded within the component.
[0016] FIG. 7 shows a schematic side view of two shims positioned within a component and welded within the component.
[0017] FIG. 8 shows a schematic side view of three shims positioned within a component and welded within the component.
[0018] Wherever possible the same reference numbers will be used throughout the drawings to represent the same parts.
DETAILED DESCRIPTION OF THE INVENTION
[0019] Provided is a welded component a welded gas turbine component (for example a gas turbine shroud a gas turbine blade or a gas turbine nozzle) and a process of welding a component. Embodiments of the present disclosure have increased fusion weldability have decreased liquation tendency have decreased strain age cracking tendency permit use of portions having otherwise incompatible properties have increased stress resistance have increased ductility and combinations thereof.
[0020] Referring to FIG. 1 a component 100 includes a first portion 102 or subcomponent having a first alloy 104 and a second portion 106 or subcomponent having a second alloy 108. The first portion 102 and the second portion 106 are welded together by using two or more shims 111 forming a weld 110. The weld 110 is formed by a first shim 112 positioned proximal to the first portion 102 and a second shim 114 positioned between the first shim 112 and the second portion 106. The weld 110 is beam welded for example by an energy beam 118 such as an electron beam or laser beam. In further embodiments a third shim 602 or more shims also form the weld 110 (see FIGS. 6 and 8). The shims 111 form a gradient composition within a joint gap 202 (see FIG. 2) positioned between the first portion 102 and the second portion 106 thereby improving the weldability and joint properties of the weld 110.
[0021] FIGS. 2-4 schematically show the first portion 102 and the second portion 106 at various stages of an exemplary process of forming the component 100. FIG. 2 shows a side view of the component 100 with the first portion 102 and the second portion 106 being separate and being arranged to form the joint gap 202. In this embodiment the joint gap 202 completely separates the first portion 102 and the second portion 106. In another embodiment the first portion 102 and the second portion 106 are partially attached and the joint gap 202 extends between the first portion 102 and the second portion 106. Referring to FIG. 3 according to an embodiment of the process upon the first portion 102 and the second portion 106 being positioned the first shim 112 and the second shim 114 are positioned within the joint gap 202 between the first alloy 102 and the second alloy 106. The shims 111 are beam welded (for example electron beam or laser welded) to form the weld 110 shown in FIG. 4.
[0022] The first alloy 104 in the first portion 102 of the component 100 differs in composition from the second alloy 108 in the second portion 106 of the component 100. In one embodiment the first alloy 104 and the second alloy 108 are any suitable superalloys.
[0023] In one embodiment the first alloy 104 or the second alloy 108 includes a nickel-based alloy having by weight up to about 15% chromium up to about 10% cobalt up to about 4% tungsten up to about 2% molybdenum up to about 5% titanium up to about 3% aluminum and up to about 3% tantalum. In a further embodiment the first alloy 104 or the second alloy 108 has a composition by weight of about 14% chromium about 9.5% cobalt about 3.8% tungsten about 1.5% molybdenum about 4.9% titanium about 3% aluminum about 0.1% carbon about 0.01% boron about 2.8% tantalum and a balance of nickel.
[0024] In one embodiment the first alloy 104 or the second alloy 108 includes a nickel-based alloy having by weight up to about 10% chromium up to about 8% cobalt up to about 4% titanium up to about 5% aluminum up to about 6% tungsten and up to about 5% tantalum. In a further embodiment the first alloy 104 or the second alloy 108 has a composition by weight of about 9.8% chromium about 7.5% cobalt about 3.5% titanium about 4.2% aluminum about 6% tungsten about 1.5% molybdenum about 4.8% tantalum about 0.09% carbon about 0.009% boron and a balance of nickel.
[0025] In one embodiment the first alloy 104 or the second alloy 108 includes a nickel-based alloy having by weight up to about 8% cobalt up to about 7% chromium up to about 6% tantalum up to about 7% aluminum up to about 5% tungsten up to about 3% rhenium and up to about 2% molybdenum. In a further embodiment the first alloy 104 or the second alloy 108 has a composition by weight of about 8% cobalt about 7% chromium about 6% tantalum about 6.2% aluminum about 5% tungsten about 3% rhenium about 2% molybdenum about 0.2% hafnium and a balance of nickel.
[0026] In one embodiment the first alloy 104 or the second alloy 108 includes a nickel-based alloy having by weight up to about 10% chromium up to about 8% cobalt up to about 5% aluminum up to about 4% titanium up to about 2% molybdenum up to about 6% tungsten and up to about 5% tantalum. In a further embodiment the first alloy 104 or the second alloy 108 has a composition by weight of about 10% chromium about 8% cobalt about 4.2% aluminum about 3.5% titanium about 2% molybdenum about 6% tungsten about 5% tantalum about 0.5% niobium about 0.2% hafnium and a balance of nickel.
[0027] In one embodiment the first alloy 104 or the second alloy 108 includes a nickel-based alloy having by weight up to about 10% cobalt up to about 8% chromium up to about 10% tungsten up to about 6% aluminum up to about 3% tantalum and up to about 2% hafnium. In a further embodiment the first alloy 104 or the second alloy 108 has a composition by weight of about 9.5% cobalt about 8% chromium about 9.5% tungsten about 0.5% molybdenum about 5.5% aluminum about 0.8% titanium about 3.0% tantalum about 0.01 zirconium about 0.10 carbon about 1.5% hafnium and a balance of nickel.
[0028] In one embodiment the first alloy 104 the second alloy 108 or the first alloy 104 and the second alloy 108 are alloys capable of withstanding predetermined temperatures (for example temperatures of a gas turbine hot gas path). For example in one embodiment the first alloy 102 is resistant to heat above a first/higher temperature (for example about 1000° F about 1250° F about 1500° F about 2000° F or about 3000° F) and the second alloy 108 is resistant to heat above a second/lower temperature (for example between 800° F and 1250° F about 800° F about 1000° F about 1250° F about 1500° F or about 2000° F). In one embodiment the first temperature is substantially higher than the second temperature. In a further embodiment the second alloy 108 is not resistant to the first/higher temperature. Additionally or alternatively in one embodiment the first alloy 104 the second alloy 108 or the first alloy 104 and the second alloy 108 include single crystal grains directionally-solidified grains or equiaxed grains.
[0029] Referring to FIGS. 2-4 upon being welded the shims 111 have a modified microstructure within the joint gap 202 thereby modifying the properties of the weld 110. The shims 111 are thin bands of material positionable within the joint gap 202. In one embodiment one or more of the shims 111 are flexible and capable of being stored as a roll prior to use. In one embodiment one or more of the shims 111 are a predetermined length (for example a length corresponding to a length of a surface on the first portion 102 or the second portion 106) a predetermined height 304 (for example a height corresponding to a height of the first portion 102 and/or the second portion 106) a predetermined thickness 306 (for example as described below with reference to FIGS. 5-8) or combinations thereof. In one embodiment the shims 111 vary in thickness along the length of the shims 111. In this embodiment thicker portions of the shims 111 correspond to regions of the joint gap 202 benefiting from greater amounts of material and thinner portions of the shims 111 correspond to regions of the joint gap 202 benefiting from the presence of lower amounts of material.
[0030] Referring to FIG. 5 in one embodiment the first shim 112 and the second shim 114 have substantially identical thicknesses 306 (for example about 0.02 inches each about 0.01 inches each or between about 0.01 inches and about 0.03 inches each). Upon receiving the energy from the energy beam 118 the first shim 112 and the second shim 114 form the weld 110 having a gradient 502 including a first region 504 of a first shim material 506 a second region 508 of a second shim material 510 a shim transition region 512 (for example a fusion zone) between the first shim material 506 and the second shim material 510 a first shim-alloy transition region 514 (for example a first heat affected zone) between the first shim material 506 and the first alloy 104 and a second shim-alloy transition region 516 (for example a second heat affected zone) between the second shim material 510 and the second alloy 108. In this embodiment the first region 504 and the second region 508 have substantially identical thicknesses 306.
[0031] Referring to FIG. 6 in one embodiment the first shim 112 the second shim 114 and a third shim 602 (for example a middle shim) have substantially identical thicknesses 306 (for example about 0.02 inches each about 0.01 inches each or between about 0.01 inches and about 0.03 inches each). Upon receiving the energy from the energy beam 118 the first shim 112 the second shim 114 and the third shim 602 form the weld 110 having the gradient 502 including the first region 504 of the first shim material 506 the second region 508 of the second shim material 510 a third region 601 of a third shim material 603 a first shim-shim transition zone 604 (for example a first fusion zone) between the first shim material 506 and the third shim material 603 a second shim-shim transition zone 606 (for example a second fusion zone) between the second shim material 608 and the third shim material 603 the first shim-alloy transition region 514 between the first shim material 506 and the first alloy 104 and the second shim-alloy transition region 516 between the second shim material 510 and the second alloy 108. In this embodiment the first region 504 and the second region 508 have substantially identical thicknesses 306 and the third region 601 has a greater thickness 306.
[0032] Referring to FIG. 7 in one embodiment the first shim 112 and the second shim 114 have different thicknesses 306 (for example the first shim 112 having a thickness of about 0.01 inches and the second shim 114 having a thickness of about 0.02 inches or the first shim 112 having a thickness of about 0.02 inches and the second shim 114 having a thickness of about 0.03 inches). Upon receiving the energy from the energy beam 118 the first shim 112 and the second shim 114 form the weld 110 having the gradient 502 including the first region 504 of the first shim material 506 the second region 508 of the second shim material 510 the shim transition region 512 between the first shim material 506 and the second shim material 510 the first shim-alloy transition region 514 between the first shim material 506 and the first alloy 104 and the second shim-alloy transition region 516 between the second shim material 510 and the second alloy 108. In this embodiment the first region 504 and the second region 508 have different thicknesses 306.
[0033] Referring to FIG. 8 in one embodiment the first shim 112 and the second shim 114 have substantially identical thicknesses 306 and the third shim 602 has a different thickness 306 (for example the first shim 112 and the second shim 114 having thicknesses of about 0.01 inches and the third shim 602 having a thickness of about 0.02 inches or the first shim 112 and the second shim 114 having thicknesses of about 0.02 inches and the third shim 602 having a thickness of about 0.03 inches). Upon receiving the energy from the energy beam 118 the first shim 112 the second shim 114 and the third shim 602 form the weld 110 having the gradient 502 including the first region 504 of the first shim material 506 the second region 508 of the second shim material 510 the third region 601 of the third shim material 603 the first shim-shim transition zone 604 between the first shim material 506 and the third shim material 603 the second shim-shim transition zone 606 between the second shim material 510 and the third shim material 603 the first shim-alloy transition region 514 between the first shim material 506 and the first alloy 104 and the second shim-alloy transition region 516 between the second shim material 510 and the second alloy 108. In this embodiment the first region 504 and the second region 508 have substantially identical thicknesses 306 and the third region 601 has a greater thickness 306.
[0034] The shims 111 are selected and positioned corresponding to one or more of the properties and/or compositions of the first alloy 104 and/or the second alloy 108 and the properties and/or compositions of adjacent shims. For example in one embodiment the first shim 112 includes a composition and/or property compatible with the first alloy 104 and is positioned proximal to the first portion 102 including the first alloy 104. For example in one embodiment the composition include Al Ti or any other suitable component at a predetermined concentration for compatibility. In this embodiment the second shim 114 includes a composition and/or property compatible with the second alloy 108 and is positioned proximal to the second portion 106 including the second alloy 108. In one embodiment the first shim 112 and the second shim 114 include compatible compositions and are positioned adjacent to each other for welding. In another embodiment the third shim 602 is positioned between the first shim 112 and the second shim 114 and includes a composition providing additional desired properties (for example strength and/or compatibility with each of the first shim 112 and the second shim 114).
[0035] In one embodiment the shims 111 are selected and positioned based upon chemistry of the alloys. For example in one embodiment the first alloy 104 is a casting superalloy and the first shim 112 includes low aluminum content (for example by weight below about 3% with about 0% titanium below about 2.5% with about 1% titanium below about 2% with about 2% titanium or linear interpolations or extrapolations thereof). In this embodiment material within the fusion boundary (for example the shim transition zone 512 the first shim-shim transition zone 604 the second shim-shim transition zone 606 or combinations thereof) is within the weldable material range thereby reducing or eliminating strain age cracking in the heat affected zone of the first alloy 104.
[0036] In one embodiment the first alloy 104 is a casting superalloy and one or more of the shims 111 is selected for high ductility (for example based upon elongation being between about 30% and about 65% or between about 55% and about 65%). In this embodiment the weld 110 is resistant to liquation cracking such as centerline cracking. In another embodiment one or more of the shims 111 is selected to include low gamma prime volume.
[0037] In one embodiment at least one of the first shim material 506 the second shim material 510 and the third shim material 603 has a composition by weight of about 20% to about 24% chromium about 3% iron about 0.3% to about 1% magnesium about 1% to about 3% molybdenum about 0.2% to about 0.5% aluminum and a remainder nickel.
[0038] In one embodiment at least one of the first shim material 506 the second shim material 510 and the third shim material 603 has a composition by weight of about 20% to about 24% chromium about 3% iron about 1% magnesium about 8% to about 10% molybdenum about 1% silicon and a remainder nickel.
[0039] In one embodiment at least one of the first shim material 506 the second shim material 510 and the third shim material 603 has a composition by weight of about 14.5% to about 16.5% chromium about 4% to about 7% iron about 1% magnesium about 15% to about 17% molybdenum about 0.8% silicon and a remainder nickel.
[0040] In one embodiment at least one of the first shim material 506 the second shim material 510 and the third shim material 603 includes a nickel-based alloy having by weight up to about 22% chromium up to about 13% cobalt up to about 3% iron and up to about 9% molybdenum. In a further embodiment at least one of the first shim material 506 the second shim material 510 and the third shim material 603 has a composition by weight of about 22% chromium about 12.5% cobalt about 1.1% aluminum 0.1% carbon about 3% iron about 1% manganese about 1% silicon about 0.6% titanium about 9% molybdenum and a balance of nickel.
[0041] In one embodiment at least one of the first shim material 506 the second shim material 510 and the third shim material 603 includes a nickel-based alloy having by weight up to about 3% iron up to about 20% chromium up to about 3% manganese. In a further embodiment at least one of the first shim material 506 the second shim material 510 and the third shim material 603 has a composition by weight of about 3% iron about 20% chromium about 0.5% silicon about 3% manganese about 0.7% titanium about 0.1% carbon and a balance of nickel.
[0042] In one embodiment at least one of the first shim material 506 the second shim material 510 and the third shim material 603 includes a nickel-based alloy having by weight up to about 22% chromium up to about 14% tungsten and up to about 2% molybdenum. In a further embodiment at least one of the first shim material 506 the second shim material 510 and the third shim material 603 has a composition by weight of about 0.1% carbon about 1% iron about 22% chromium about 14% tungsten about 1.5% molybdenum about 0.5% manganese about 0.4% silicon about 0.3% aluminum about 0.02% lanthanide about 0.004% boron and a balance of nickel.
[0043] While the invention has been described with reference to a preferred embodiment it will be understood by those skilled in the art that various changes may be made and equivalents may be substituted for elements thereof without departing from the scope of the invention. In addition many modifications may be made to adapt a particular situation or material to the teachings of the invention without departing from the essential scope thereof. Therefore it is intended that the invention not be limited to the particular embodiment disclosed as the best mode contemplated for carrying out this invention but that the invention will include all embodiments falling within the scope of the appended claims.
CLAIMS
What is claimed is:
1. A welded component comprising:
a first alloy subcomponent;
a second alloy subcomponent; and
a weld between the first alloy subcomponent and the second alloy subcomponent;
wherein the weld includes a gradient having a transition region.
2. The welded component of claim 1 wherein the first alloy subcomponent and the second alloy subcomponent have same composition.
3. The welded component of claim 1 wherein the first alloy subcomponent has a first composition and the second alloy subcomponent has a second composition the first composition differing from the second composition.
4. The welded component of claim 3 wherein the first composition is a nickel-based alloy including by weight up to about 15% chromium up to about 10% cobalt up to about 4% tungsten up to about 2% molybdenum up to about 5% titanium up to about 3% aluminum and up to about 3% tantalum.
5. The welded component of claim 3 wherein the first composition is a nickel-based alloy including by weight up to about 10% chromium up to about 8% cobalt up to about 4% titanium up to about 5% aluminum up to about 6% tungsten and up to about 5% tantalum.
6. The welded component of claim 3 wherein the first composition is a nickel-based alloy including by weight up to about 8% cobalt up to about 7% chromium up to about 6% tantalum up to about 7% aluminum up to about 5% tungsten up to about 3% rhenium and up to about 2% molybdenum
7. The welded component of claim 3 wherein the first composition is a nickel-based alloy including by weight up to about 10% chromium up to about 8% cobalt up to about 5% aluminum up to about 4% titanium up to about 2% molybdenum up to about 6% tungsten and up to about 5% tantalum.
8. The welded component of claim 3 wherein the first composition is nickel-based alloy including by weight up to about 10% cobalt up to about 8% chromium up to about 10% tungsten up to about 6% aluminum up to about 3% tantalum and up to about 2% hafnium.
9. The welded component of claim 1 wherein the gradient includes a first region of a first shim material formed by a first shim a second region of a second shim material formed by a second shim a first shim-alloy transition region between the first shim material and the first alloy subcomponent and a second shim-alloy transition region between the second shim material and the second alloy subcomponent.
10. The welded component of claim 9 wherein the first region and the second region have substantially identical thicknesses.
11. The welded component of claim 9 wherein the first region and the second region have different thicknesses.
12. The welded component of claim 9 wherein the first shim is a nickel-based alloy including by weight up to about 22% chromium up to about 13% cobalt up to about 3% iron and up to about 9% molybdenum.
13. The welded component of claim 9 wherein the first shim is a nickel-based alloy including by weight up to about 3% iron up to about 20% chromium and up to about 3% manganese.
14. The welded component of claim 9 wherein the first shim is a nickel-based alloy including by weight up to about 22% chromium up to about 14% tungsten and up to about 2% molybdenum.
15. The welded component of claim 1 wherein the gradient includes a first region of a first shim material formed by a first shim a second region of a second shim material formed by a second shim a third region of a third shim material formed by a third shim the first shim-shim transition region between the first shim material and the third shim material a second shim-shim transition region between the second shim material and the third shim material a first shim-alloy transition region between the first shim material and the first alloy subcomponent and a second shim-alloy transition region between the second shim material and the second alloy subcomponent.
16. The welded component of claim 15 wherein the first region and the third region have different thicknesses.
17. The welded component of claim 1 wherein the component is a gas turbine component.
18. A welded gas turbine component comprising:
a first alloy;
a second alloy; and
a weld positioned between the first alloy and the second alloy;
wherein the weld is formed by a first shim and a second shim being beam welded.
19. A process of welding a component comprising:
positioning a first alloy;
positioning a second alloy;
positioning a first shim and a second shim between the first alloy and the second alloy; and
beam welding the first shim and the second shim to form a weld between the first alloy and the second alloy.
20. The process of claim 19 wherein the beam welding is electron beam welding.
| # | Name | Date |
|---|---|---|
| 1 | Power of Authority.pdf | 2012-05-02 |
| 2 | Form-5.pdf | 2012-05-02 |
| 3 | Form-3.pdf | 2012-05-02 |
| 4 | Form-1.pdf | 2012-05-02 |
| 5 | Drawings.pdf | 2012-05-02 |
| 6 | 1059-del-2012-Correspondence-Others-(19-06-2012).pdf | 2012-06-19 |
| 7 | 1059-del-2012-Assignment-(19-06-2012).pdf | 2012-06-19 |
| 8 | 1059-del-2012-Correspondence-Others-(04-10-2012).pdf | 2012-10-04 |
| 9 | GPOA_GEC.pdf ONLINE | 2015-03-09 |
| 10 | 247941 Form 13.pdf ONLINE | 2015-03-09 |
| 11 | GPOA_GEC.pdf | 2015-03-13 |
| 12 | 247941 Form 13.pdf | 2015-03-13 |
| 13 | 1059-DEL-2012-FER.pdf | 2019-03-05 |
| 14 | 1059-DEL-2012-RELEVANT DOCUMENTS [13-05-2019(online)].pdf | 2019-05-13 |
| 15 | 1059-DEL-2012-FORM 13 [13-05-2019(online)].pdf | 2019-05-13 |
| 16 | 1059-DEL-2012-OTHERS [19-08-2019(online)].pdf | 2019-08-19 |
| 17 | 1059-DEL-2012-FER_SER_REPLY [19-08-2019(online)].pdf | 2019-08-19 |
| 18 | 1059-DEL-2012-DRAWING [19-08-2019(online)].pdf | 2019-08-19 |
| 19 | 1059-DEL-2012-CORRESPONDENCE [19-08-2019(online)].pdf | 2019-08-19 |
| 20 | 1059-DEL-2012-CLAIMS [19-08-2019(online)].pdf | 2019-08-19 |
| 21 | 1059-DEL-2012-ABSTRACT [19-08-2019(online)].pdf | 2019-08-19 |
| 22 | 1059-DEL-2012-PatentCertificate18-08-2021.pdf | 2021-08-18 |
| 23 | 1059-DEL-2012-IntimationOfGrant18-08-2021.pdf | 2021-08-18 |
| 24 | 1059-DEL-2012-RELEVANT DOCUMENTS [22-09-2023(online)].pdf | 2023-09-22 |
| 25 | 1059-DEL-2012-POWER OF AUTHORITY [26-02-2024(online)].pdf | 2024-02-26 |
| 26 | 1059-DEL-2012-FORM-16 [26-02-2024(online)].pdf | 2024-02-26 |
| 27 | 1059-DEL-2012-ASSIGNMENT WITH VERIFIED COPY [26-02-2024(online)].pdf | 2024-02-26 |
| 1 | 1059del2012ss_10-04-2018.pdf |