The term "synergistic", as used herein, refers the combined action of two or more active
agents blended together and administered conjointly that is greater than the sum of their individual effects.
"Bioactive amounts” as mentioned herein means that amount which, when applied treatment of crops, is sufficient to effect such treatment.
Therefore an aspect of the present invention provides a synergistic fugicidal compositions comprising bioactive amounts of (A) A fungicide selected from SDHI (Succinate dehydrogenase inhibitors) group or mixture thereof; (B) at least one more fungicide selected from the class of QoI (Quinone outside Inhibitors), QiI-fungicides (Quinone inside Inhibitors), Lipid or transport and membrane synthesis inhibitors, Sterol biosynthesis Inhibitors, Melanin synthesis in cell wall Inhibitors, compound with unknow mode of action, multisite contact fungicides, Ipflufenoquin, Pyridachlometyl or mixture thereof; (C) At least one more compound selected from plant health additive or mixture thereof.

More particularly a further aspect of the present invention provides a synergistic fugicidal compositions comprising bioactive amounts of (A) A fungicide from class of SDHI (Succinate dehydrogenase inhibitors) selected from group of phenyl benzamides, phenyl-oxo-ethyl thiophene amid, pyridinyl-ethyl-benzamides, furan carboxamides, oxathincarboxamides, pyrazole-4-carboxamides, pyridine carboxamides or mixture thereof; (B) at least one more fungicide selected from the class of QoI (Quinone outside Inhibitors), QiI-fungicides (Quinone inside Inhibitors), Lipid or transport and membrane synthesis inhibitors, Sterol biosynthesis Inhibitors, Melanin synthesis in cell wall Inhibitors, compound with unknow mode of action, multisite contact fungicides, Ipflufenoquin, Pyridachlometyl or mixture thereof; (C) At least one plant health additive selected from the group consisting of auxin, cytokinin, ethylene modulators, gibberellins, growth inhibitors, growth retardants, growth stimulators, unclassified growth regulators, micronutrients and biostimulants or mixture thereof.
In an embodiment of the present invention a fungicide from class of SDHI (Succinate dehydrogenase inhibitors) selected from group of phenyl benzamides, phenyl-oxo-ethyl thiophene amid, pyridinyl-ethyl-benzamides, furan carboxamides, oxathincarboxamides, pyrazole-4-carboxamides, pyridine carboxamides or mixture thereof
In an embodiment of the present invention SDHI (Succinate dehydrogenase inhibitors) class of fungicides from group of phenyl benzamides may be selected from benodanil, flutolanil, mepronil.
In an embodiment of the present invention SDHI (Succinate dehydrogenase inhibitors) class of fungicides from group of phenyl-oxo-ethyl thiophene amid is isofetamid.
In an embodiment of the present invention SDHI (Succinate dehydrogenase inhibitors) class of fungicides from group of pyridinyl-ethyl-benzamides is fluopyram.
In an embodiment of the present invention SDHI (Succinate dehydrogenase inhibitors) class of fungicides from group of furan carboxamides is fenfuran.
In an embodiment of the present invention SDHI (Succinate dehydrogenase inhibitors) class of fungicides from group of oxathincarboxamides may be selected from carboxin, oxycarboxin, thiazole carboxamides-thifluzamide.
In an embodiment of the present invention SDHI (Succinate dehydrogenase inhibitors) class of fungicides from group of pyrazole-4-carboxamides may be selected from benzovindiflupyr, bixafen, fluindapyr, fluxapyroxad, furametpyr, inpyrfluxam, isopyrazam, penflufen, penthiopyrad, sedaxane, flubeneteram, pyrapropoyne, inpyrfluxam, isoflucypram, pydiflumetofen.
In an embodiment of the present invention SDHI (Succinate dehydrogenase inhibitors) class of fungicides from group of pyridine carboxamides may be selected from boscalid or pyraziflumid.
In an embodiment of the present invention QoI (Quinone outside Inhibitors) class of fungicides from group of benzyl carbamates is pyribencarb.
In an embodiment of the present invention QoI (Quinone outside Inhibitors) class of fungicides from group of dihydrodioxazines is fluoxastrobin.
In an embodiment of the present invention QoI (Quinone outside Inhibitors) class of fungicides from group of imidazolinones is fenamidone.
In an embodiment of the present invention QoI (Quinone outside Inhibitors) class of fungicides from group of methoxy acrylates may be selected from azoxystrobin, coumoxystrobin, enoxastrobin, flufenoxystrobin, picoxystrobin, pyraoxystrobin.
In an embodiment of the present invention QoI (Quinone outside Inhibitors) class of fungicides from group of methoxy carbamates may be selected from pyraclostrobin, pyrametostrobin, triclopyricarb.
In an embodiment of the present invention QoI (Quinone outside Inhibitors) class of fungicides from group of methoxyacetamide is mandestrobin.
In an embodiment of the present invention QoI (Quinone outside Inhibitors) class of fungicides from group of oximinoacetamides may be selected from dimoxystrobin, fenamistrobin, metominostrobin, orysastrobin.
In an embodiment of the present invention QoI (Quinone outside Inhibitors) class of fungicides from group of oximino acetates may be selected from kresoxim methyl, trifloxystrobin.
In an embodiment of the present invention QoI (Quinone outside Inhibitors) class of fungicides from group of oxazolidinediones is famoxadone.
In an embodiment of the present invention QiI (Quinone inside Inhibitors) class of fungicides from group of cyano imidazole is cyazofamid; from group of sulfamoyltriazol is amisulbrom; from group of picolinamides is fenpicoxamid, florylpicoxamid; from group of tetrazolinones is metyltetraprole.
In an embodiment of the present invention Lipid or transport and membrane synthesis inhibitor class of fungicides from group of dithiolanes is isoprothiolane; from group of phosphorthiolates may be selected from edifenphos, iprobenfos (IBP), pyrazophos; from group of aromatic hydrocarbons (F3) may be selected from biphenyl, chloroneb, dicloran, quintozene, tecnazene, tolcofos methyl, etridiazole; from group of carbamates may be selected from iodocarb, propamocarb, prothiocarb; from group of terpene hydrocarbons is extract from Melaleuca arternifolia (tea tree), plant oils (mixtures); eugenol, geraniol, thymol; from group of amphoteric macrolide antifungal is natamycin (pimaricin); from group of piperidinylthiazoleisoxazolines may be selected from oxathiapipronil, fluoxapipronil, Fluoxapiprolin-s;
In an embodiment of the present invention sterol biosynthesis Inhibitors class of fungicides from group of imidazoles may be selected from oxpoconazole, pefurazoate, procloraz, triflumizole, piperazines-triforine, pyridines-pyrifenox, pyrisoxazole, pyrimidines-fenarimo, naurimol, triazoles-azaconazole, bitertanol, bromuconazole, cyproconazole, difenoconazole, diniconazole, epoxiconazole, etaconazole, fenbuconazole, fluquinconazole, flusilazole, frutriafol, hexaconazole, imibenconazole, ipconazole, mefentrifluconazole, metconazole, myclobutanil, penconazole, propiconazole, prothioconazole, simconazole, tebuconazole, tetraconazole, tiradimefon, tiradimenol, triticonazole.
In an embodiment of the present invention sterol biosynthesis Inhibitors class of fungicides from group of morpholines may be selected from aldimoprh, dedomorph, tridemorph, fenpropimorph; from group of piperidines may be selected from fenpropidin, piperalin.
In an embodiment of the present invention sterol biosynthesis Inhibitors class of fungicides from group of spiroketal amines is spiroxamine; from amino pyrazolinone is fenpyrazamine; from group of hydroxyanilide is fenhexamid; from group of allaylamines may be selected from naftifine, terbinafine, pyributicarb.
In an embodiment of the present invention fungicides from the class Melanin synthesis in cell wall Inhibitors may be selected from fthalide, pyroquilon, tricyclazole, diclycymet, carpropamid, fenoxanil, trifluoroethyl, tolprocarb.
In an embodiment of the present invention fungicides with unknow mode of actionmay be selected from cymoxanil, teclofthalam, -triazoxide, fluslfamide, diclomezine, cyflufenamid, guanindines-dodine, flutianil, ferimzone, tebufloquin, picarbutrazox, validamycin.
In an embodiment of the present invention multisite contact fungicides may be selected from inorganic-copper (copper hydroxide, copper oxychloride, copper (II) sulphate, Bordeaux mixture, copper salicylate, cuprous oxide), sulphur, dithiocarbamates and relatives-ferbam, mancozeb, maneb, metiram, propineb, thiram, zinc thiazole, zineb, ziram, phthalimides-captan, captafol, folpet, chloronitriles (phthalonitriles)-chlorothalonil, sulfamides-dichlofluanid, tolylfluanid, bisguanidines-guazatine, iminoctadine, triazines-anilazine, quinones (anthraquinones)-dithianon, quinoxalines-chinomethionat / quinomethionate, maleimide-fluoroimide, thiocarbamate-methasulfocarb.
In an embodiment of the present invention fungicidesmay also be selected from Ipflufenoquin, Pyridachlometyl.
In an embodiment of the present invention plant health additives from the group of Auxins may be selected Indole acetic acid, Indole butyric acid, alpha-naphthyl acetic acid.
In an embodiment of the present invention plant health additives from the group of Cytokinins may be selected from kinetin, zeatin, 6-benzylaminopurine, dipheylurea, thidiazuron
In an embodiment of the present invention plant health additives from the group of Ethylene modulators may be selected from aviglycine, prohexadione, prohexadione calcium, trinexapac, trinexapac-ethyl, aminoethoxyvinylglycine (AVG).
In an embodiment of the present invention plant health additives from the group of Gibberellins may be selected from gibberelline, gibberellic acid, GA3.
In an embodiment of the present invention plant health additives from the group of Growth inhibitors may be selected from abscisic acid, chlorpropham, flumetralin, jasmonic acid, maleic hydrazide, mepiquat, mepiquat chloride, mepiquatpentaborate.
In an embodiment of the present invention plant health additives from the group of Growth retardants may be selected from chlormequat, chlormequat chloride, paclobutrazol, uniconazole-P.
In an embodiment of the present invention plant health additives from the group of Growth stimulators may be selected from brassinolide, forchlorfenuron, triacontanol, silicic acid, silicyclic acid, Nitrophenolate (sodium para-nitrophenolate, ortho-nitrophenolate, sodium-5-nitroguaiacolate), nitrobenzene.
In an embodiment of the present invention plant health additives from the group of Micronutrients may be selected from Zinc (zinc sulphate heptahydrate ZnSO47H2O, zinc sulphate mono hydrate ZnSO4.H2O, chelated zinc as Zn-EDTA, zinc oxide, Zinc Lactate Gluconate, Zinc Polyflavonoid), Boron (borax-sodium tetraborate, boric acid (H3BO3), di-sodium octa borate tetra hydrate (Na2B8O13.4H2O), di-sodium tetra borate penta hydrate, anhydrous borax, ), Manganese (manganese sulphate), Copper (copper sulphate), Iron (ferrous sulphate, chelated iron as Fe-EDTA), Molybdanum (ammonium molybdate), Magnesium (Magnesium sulphate) or Sulphur (elemental sulphur, boronated sulphur).
In an embodiment of the present invention plant health additives from the group of Biostimulants may be selected from humic acid, potassium humate, fulvic acid, potassium fulvic acid, amino acid, protein hydrolysates, peptides, organic acid, acetylthioproline, thiazolidine carboxylic acid, jasmonic acid, methyl jasmonate, chitosan, chitin, seaweed extract (Ascophyllumnodosum), polyamines, brassinolide, silicon compound-silicic acid, monosilicic acid, orthosilicic acid, disilicic acid, and pyrosilicic acid, silica nanoparticles (10-100 nm), calcium silicate, potassium silicate, sodium silicate), silicyclic acid, lactic acid, phenyllactic acid, fumaric acid, acibenzolar-s-methyl.

Succinate Dehydrogenase Inhibitors Fungicides:

Succinate dehydrogenase inhibitors (SDHIs) are active substances used in fungicidal products to control certain fungi and moulds affecting crops. SDHIs prevent their development by blocking an enzyme involved in cell respiration: succinate dehydrogenase (SDH).

Fluxapyroxad is an aromatic amide class of fungicide. It has a role as a succinate dehydrogenase (quinone) inhibitor and an antifungal agrochemical. It is used to control a number of cereal fungal pathogens including those belonging to the Ascomycetes, Basidiomycetes and Zygomycetes families. It targets the succinate dehydrogenase, one of the enzymes in the respiratory chain within the mitochondria of the fungus.

Thifluzamide is an aromatic amide. It has a role as a succinate dehydrogenase (quinone) inhibitor and an antifungal agrochemical. It has an IUPAC name as N-[2,6-dibromo-4-(trifluoromethoxy)phenyl]-2-methyl-4-(trifluoromethyl)-1,3-thiazole-5-carboxamide. It is an aromatic amide, an aromatic ether, an organofluorine compound, a member of 1,3-thiazoles, a dibromobenzene and an anilide fungicide.

Quinone outside inhibitors (QoI):
Qo inhibitors (QoI), or quinone outside inhibitors, are a group of fungicides used in agriculture. They represent the most important development made in fungicides by the chemicals industry.[citation needed] QoI are chemical compounds which act at the quinol outer binding site of the cytochrome bc1 complex.

QoI's are the resulting fusion of three fungicides families, the well-known family of strobilurins and two new families, represented by fenamidone and famoxadone. Some strobilurins are azoxystrobin, kresoxim-methyl, picoxystrobin, pyraclostrobin, and trifloxystrobin.

Strobilurins are a group of natural products and their synthetic analogs. A number of strobilurins are used in agriculture as fungicides. They are part of the larger group of QoI (Quinone outside Inhibitors) inhibitors, which act to inhibit the respiratory chain at the level of Complex III. Strobilurins are mostly contact fungicides with a long half time as they are absorbed into the cuticle and not transported any further. They have a suppressive effect on other fungi, reducing competition for nutrients; they inhibit electron transfer in mitochondria, disrupting metabolism and preventing growth of the target fungi.

Pyraclostrobin is strobilurin class of fungicide. It has a role as a mitochondrial cytochrome-bc1 complex inhibitor, a xenobiotic, an environmental contaminant and an antifungal agrochemical. It is a member of pyrazoles, a carbamate ester, an aromatic ether, a member of monochlorobenzenes, a methoxycarbanilatestrobilurin antifungal agent and a carbanilate fungicide.

Pyraclostrobin is a member of the strobilurin group of fungicides. The strobilurin fungicides act through inhibition of mitochondrial respiration by blocking electron transfer within the respiratory chain, which in turn causes important cellular biochemical processes to be severely disrupted, and results in cessation of fungal growth.

Azoxystrobin is an aryloxypyrimidine having a 4,6-diphenoxypyrimidine skeleton. It has IUPAC name as methyl (E)-2-[2-[6-(2-cyanophenoxy)pyrimidin-4-yl]oxyphenyl]-3-methoxyprop-2-enoate. An inhibitor of mitochondrial respiration by blocking electron transfer between cytochromes b and c1, it is used widely as a fungicide in agriculture. It has a role as a mitochondrial cytochrome-bc1 complex inhibitor, a xenobiotic, an environmental contaminant, an antifungal agrochemical and a quinone outside inhibitor. It is a nitrile, an aryloxypyrimidine, an enoate ester, an enol ether, a methyl ester and a methoxyacrylatestrobilurin antifungal agent.

Azoxystrobin is a fungicide with protectant, eradicant, translaminar & systemic properties. It powerfully inhibits spore germination &, in addition to its ability to inhibit mycelial growth, also shows antisporulant activity. Acts by inhibiting mitochondrial respiration by blocking electron transfer between cytochrome b & cytochrome c1. Controls pathogenic strains resistant to the 14 demethylase inhibitors, phenylamides, dicarboxamides or benzimidazoles.

Trifloxystrobin is used as an agricultural fungicide and belongs to the class of strobilurin. It has IUPAC name as methyl 2-methoxyimino-2-[2-[[1-[3 (trifluoromethyl) phenyl] ethylidene amino] oxymethyl] phenyl] acetate. As s Strobilurin fungicidal activity, it inhibits mitochondrial respiration by disrupting the cytochrome complex, thus blocking electron transfer.

Multisite fungicide:
Mancozeb is a dithiocarbamate non-systemic agricultural fungicide with multi-site, protective action on contact. It controls many fungal diseases in a wide range of field crops, fruits, nuts, vegetables, and ornamentals. Mancozeb reacts with, and inactivates, the sulfhydryl groups of amino acids and enzymes within fungal cells, resulting in disruption of lipid metabolism, respiration, and production of adenosine triphosphate.
Chlorothalonil a dinitrile that is benzene-1, 3-dicarbonitrile substituted by four chloro groups. A non-systemic fungicide, used to control a range of diseases in a wide variety of crops. It has a role as an antifungal agrochemical. Chlorothalonil reduces deactivates glutathione.

Copper fungicides represent one of the oldest active ingredients developed to fight plant diseases. Copper based plant protection products have, unlike conventional fungicides, low risk of developing resistant fungal strains due to their multilateral mode of action. Copper is used in various forms as an algaecide, bactericide, fungicide and water treatment. Copper fungicides are classified as multisite and act by disrupting cellular proteins. Because of this caracteristic they have grate value in antiresistant strategy in suppression of important fungal diseases. There is less chance of occurrence of phytotoxicity due to good buffer capacity; resistance does not occur; copper residues in crops are below the limit value. Most copper fungicides are applied as foliar sprays although drench applications have been shown to be safe and effective in some situations.

Sterol biosynthesis inhibitors:
Difenoconazole is a member of the class of dioxolanes. A broad spectrum fungicide with novel broad-range activity used as a spray or seed treatment. It has IUPAC name as 1-[[2-[2-chloro-4-(4-chlorophenoxy)phenyl]-4-methyl-1,3-dioxolan-2-yl]methyl]-1,2,4-triazole. It has a role as a sterol 14alpha-demethylase inhibitor and an antifungal agrochemical. It is an aromatic ether, a dioxolane, a member of triazoles, a cyclic ketal, a conazole fungicide and a triazole fungicide. Difenoconazole is applied by foliar spray or seed treatment and acts by interference with the synthesis of ergosterol in the target fungi by inhibition of the 14alpha-demethylation of sterols, which leads to morphological and functional changes in the fungal cell membrane.

Prothiconazole is a member of the class of triazoles that is 1,2,4-triazole-3-thione substituted compounds. It has IUPAC name as 2-[2-(1-chlorocyclopropyl)-3-(2-chlorophenyl)-2-hydroxypropyl]-1H-1,2,4-triazole-3-thione. Prothioconazole is a systemic demethylation inhibitor fungicide which belongs to the triazolinthione class of fungicides. It acts against susceptible fungi through the inhibition of demethylation at position 14 of lanosterol or 24-methylene dihydroano-sterol, both of which are precursors of sterols in fungi; i.e., it works through disruption of ergosterol biosynthesis (Ergosterol, a precursor to Vitamin D2, is an important component of fungal cell walls).

Plant Health Additives:
Plant Growth Additives are defined as small, simple chemicals produced naturally by plants to regulate their growth and development.
Plant Growth Regulators can be of a diverse chemical composition such as gases (ethylene), terpenes (gibberellic acid) or carotenoid derivatives (abscisic acid). They are also referred to as plant growth substances, phytohormones or plant hormones.
Plant growth hormones are organic compounds which are either produced naturally within the plants or are synthesized in laboratories. They profoundly control and modify the physiological processes like the growth, development, and movement of plants.
Gibberellic acid is a simple gibberellin, a pentacyclicditerpene acid promoting growth and elongation of cells. It affects decomposition of plants and helps plants grow if used in small amounts, but eventually plants develop tolerance to it. Gibberellic acid is a very potent hormone whose natural occurrence in plants controls their development. Since GA regulates growth, applications of very low concentrations can have a profound effect while too much will have the opposite effect. Gibberellins have a number of effects on plant development. They can stimulate rapid stem and root growth, induce mitotic division in the leaves of some plants, and increase seed germination rates.
Moreover oral toxicity of Gibberellic acid (GA3) has been evaluated in S. littoralis and L.migratoria insect species. Researchers observed that GA3 caused significant reduction in food consumption in both insect species which led to larval weight loss. GA3 toxicity was also demonstrated by larval mortality due to exuviation difficulties.

Growth retardant
Paclobutrazol (PBZ) is a plant growth retardant and triazole fungicide. It is a known antagonist of the plant hormone gibberellin. It acts by inhibiting gibberellin biosynthesis, reducing internodal growth to give stouter stems, increasing root growth, causing early fruitset and increasing seedset in plants such as tomato and pepper. PBZ has also been shown to reduce frost sensitivity in plants. Moreover, paclobutrazol can be used as a chemical approach for reducing the risk of lodging in cereal crops. PBZ is used by arborists to reduce shoot growth and has been shown to have additional positive effects on trees and shrubs. Among those are improved resistance to drought stress, darker green leaves, higher resistance against fungi and bacteria, and enhanced development of roots. Cambial growth, as well as shoot growth, has been shown to be reduced in some tree species.

Growth stimulant
Triacontanol is a fatty alcohol of the general formula C30H62O, also known as melissyl alcohol or myricyl alcohol. It is found in plant cuticle waxes and in beeswax. Triacontanol has been reported to increase the growth of plants by enhancing the rates of photosynthesis, protein biosynthesis, the transport of nutrients in a plant and enzyme activity, reducing complex carbohydrates among many other purposes. The fatty alcohol appears to increase the physiological efficiency of plant cells and boost the potential of the cells responsible for the growth and maturity of a plant.

Brassinolide is a plant hormone. The first isolated brassinosteroid, it was discovered when it was shown that pollen from rapeseed (Brassica napus) could promote stem elongation and cell division. The biologically active component was isolated and named brassinolide.

Silicic acid is important, very important. It acts as a bio-stimulant for the growth of the plant and helps the plant to overcome infections and stress factors like heat, drought and salinity.So, when bio-active silicic acid is added, plants show an improved growth, higher yield, reduced mineral toxicities and better disease and insect resistance. Moreover, silicon stimulates the beneficial micro-organisms in the (top) soil resulting in synergistic effects for the uptake of nutrients by the plant. Moreover, application of silicic acid along with half dose of recommended pesticide as foliar spray increased the grain and straw yield.
Salicylic acid is a monohydroxy benzoic acid that is benzoic acid with a hydroxy group at the ortho position. It has IUPAC name as 2-hydroxybenzoic acid. Salicylic acid is a phenolic phytohormone and is found in plants with roles in plant growth and development, photosynthesis, transpiration, ion uptake and transport. Salicylic acid is involved in endogenous signalling, mediating in plant defence against pathogens. It plays a role in the resistance to pathogens by inducing the production of pathogenesis-related proteins. It is involved in the systemic acquired resistance in which a pathogenic attack on one part of the plant induces resistance in other parts. The signal can also move to nearby plants by salicylic acid being converted to the volatile ester methyl salicylate. Methyl salicylate is taken up by the stomata of the nearby plant, and once deep in the leaf, is converted back to salicylic acid to induce the immune response.
Growth inhibitors
Mepiquat chloride is a quaternary ammonium salt consisting of equimolar amounts of mepiquat cations and chloride anions. It is having IUPAC name as 1,1-dimethylpiperidin-1-ium;chloride. A plant growth regulator, it is used in agriculture to reduce vegetative growth including sprout suppression in garlic, leeks and onions. It has a role as a plant growth retardant and an agrochemical. It is a quaternary ammonium salt and a chloride salt. It contains a mepiquat.
Micronutrients:
Zinc is an essential micronutrient which means it is essential for plant growth and development, but is required in very small quantities. Although zinc requirements vary among crops, zinc leaf concentrations (on a dry matter basis) in the range 20 to 100 mg/kg are adequate for most crops.
Zinc occurs in plants as a free ion, as a complex with a variety of low molecular weight compounds, or as a component of proteins and other macromolecules. In many enzymes, zinc acts as a functional, structural, or regulatory cofactor; a large number of zinc-deficiency disorders are associated with the disruption of normal enzyme activity (including that of key photosynthetic enzymes). Zinc deficiency also increases membrane leakiness as zinc-containing enzymes are involved in the detoxification of membrane-damaging oxygen radicals. Zinc may be involved in the control of gene expression; it appears important in stabilizing RNA and DNA structure, in maintaining the activity of DNA-synthesizing enzymes and in controlling the activity of RNA-degrading enzymes.
Application of zinc may not correct zinc deficiency in alkaline soils because even with the addition of zinc, it may remain unavailable for plant absorption. Foliar applications of zinc as zinc sulphate or as zinc chelate (or other organic complexes) are also widely used, especially with fruit trees and grape vines. Zinc can also be supplied as a seed treatment, or by root-dipping of transplant
The present inventors believe that the combination of the present invention surprisingly results in a synergistic action. The combinations of the present invention allow for a broad spectrum of pest control and has surprisingly improved plant vigour and yield. The broad spectrum of the present combination also provides a solution for preventing the development of resistance.
The synergistic composition has very advantageous curative, preventive and systemic fungicidal properties for protecting cultivated plants. As has been mentioned, said active ingredient composition can be used to inhibit or destroy the pathogens that occur on plants or parts of plants (fruit, blossoms, leaves, stems, tubers, roots) of different crops or useful plants, while at the same time those parts of plants which grow later are also protected from attack by such pathogens. Active ingredient composition has the special advantage of being highly active against diseases in the soil that mostly occur in the early stages of plant development.
The synergistic composition of pesticide are used to protect the crops and plants from fungus and pests. The lists of the major crops includes but are not limited to GMO (Genetically Modified Organism) and Non GMO varieties of Cotton (Gossypium spp.), Paddy (Oryza sativa), Wheat (Triticumaestavum), Barley (Hordeumvulgare), Maize (Zea mays), Sorghum (Sorghum bicolor), Oat (Avena sativa), Pearl millet (Pennisetumglaucum), Sugarcane (Saccharumofficinarum) , Sugarbeet (Beta vulgaris), Soybean (Glycin max), Peanut (Arachishypogaea), Sunflower (Helianthus annuus) , Mustard (Brassica juncea), Rape seed (Brassica napus), Linseed (Linumusitatissimum), Sesame (Sesamumindicum), Green gram (Vignaradiata), Black gram (Vigna mungo), Chickpea (Ciceraritinum), Cowpea (Vignaunguiculata), Redgram (Cajanuscajan), Frenchbean (Phaseolus vulgaris), Indian bean (Lablab purpureus), Horse gram (Macrotylomauniflorum), Field pea (Pisumsativum), Cluster bean (Cyamopsistetragonoloba), Lentils (Lens culinaris), Brinjal (Solanummelongena), Cabbage (Brassica oleracea var. capitata), Cauliflower (Brassica oleracea var. botrytis), Okra (Abelmoschusesculentus) , Onion (Allium cepa L.), Tomato (Solanumlycopersicun) , Potato (Solanumtuberosum) , Sweet potato (Ipomoea batatas), Chilly (Capsicum annum), Garlic (Allium sativum), Cucumber (Cucumissativus), Muskmelons (Cucumismelo), Watermelon (Citrulluslanatus), Bottle gourd (Lagenariasiceraria), Bitter gourd (Momordicacharantia), Radish (Raphanussativus), Carrot (Dacuscarotasubsp. sativus), Turnip (Brassica rapasubsprapa), Apple (Melusdomestica), Banana (Musa spp.), Citrus groups (Citrus spp.), Grape (Vitisvinifera), Guava (Psidiumguajava), Litchi (Litchi chinensis), Mango (Mangiferaindica), Papaya (Carica papaya), Pineapple (Ananascomosus), Pomegranate (Punicagranatum) , Sapota (Manilkarazapota), Tea (Camellia sinensis), Coffea (Coffea Arabica), Turmeric (Curcuma longa), Ginger (Zingiberofficinale), Cumin (Cuminumcyminum), Fenugreek (Trigonellafoenum-graecum), Fennel (Foeniculumvulgare), Coriander (Coriandrumsativum), Ajwain (Trachyspermumammi), Psyllium (Plantago ovate), Black Pepper (Piper nigrum), Stevia (Stevia rebaudiana), Safed musli (Chlorophytumtuberosum), Drum stick (Moringaoleifera), Coconut (Coco nucifera), Mentha ( Mentha spp.), Rose (Rosa spp.), Jasmine (Jasminum spp.), Marigold ( Tagetes spp.), Common daisy (Bellis perennis), Dahlia (Dahlia hortnesis), Gerbera ( Gerbera jamesonii), Carnation (Dianthus caryophyllus), vegetables: solanaceous vegetables such as eggplant, tomato, pimento, pepper, potato, etc., cucurbit vegetables such as cucumber, pumpkin, zucchini, water melon, melon, squash, etc., cruciferous vegetables such as radish, white turnip, horseradish, kohlrabi, Chinese cabbage, cabbage, leaf mustard, broccoli, cauliflower, etc., asteraceous vegetables such as burdock, crown daisy, artichoke, lettuce, etc, liliaceous vegetables such as green onion, onion, garlic, and asparagus, ammiaceous vegetables such as carrot, parsley, celery, parsnip, etc., chenopodiaceous vegetables such as spinach, Swiss chard, etc., lamiaceous vegetables such as Perillafrutescens, mint, basil, etc, strawberry, sweet potato, Dioscorea japonica, colocasia, etc., flowers, foliage plants, turf grasses, fruits: pome fruits such apple, pear, quince, etc, stone fleshy fruits such as peach, plum, nectarine, Prunusmume, cherry fruit, apricot, prune, etc., citrus fruits such as orange, lemon, rime, grapefruit, etc., nuts such as chestnuts, walnuts, hazelnuts, almond, pistachio, cashew nuts, macadamia nuts, etc. berries such as blueberry, cranberry, blackberry, raspberry, etc., grape, kaki fruit, olive, plum, banana, coffee, date palm, coconuts, etc. , trees other than fruit trees; tea, mulberry, flowering plant, trees such as ash, birch, dogwood, Eucalyptus, Ginkgo biloba, lilac, maple, Quercus, poplar, Judas tree, Liquidambar formosana, plane tree, zelkova, Japanese arborvitae, fir wood, hemlock, juniper, Pinus, Picea, and Taxus cuspidate, etc.

The term "health of a plant" or "plant health" is defined as a condition of the plant and/or its products. As a result of the improved health, yield, plant vigor, quality and tolerance to abiotic or biotic stress are increased. Noteworthy, the health of a plant when applying the method according to the invention, is increased independently of the pesticidal properties of the active ingredients used because the increase in health is not based upon the reduced disease pressure but instead on complex physiological and metabolic reactions which result for example in an activation of the plant's own natural defense system. As a result, the health of a plant is increased even in the absence of diseases pressure. Accordingly, in an especially preferred embodiment of the method according to the invention, the health of a plant is increased both in the presence and absence of biotic or abiotic stress factors. The above identified indicators for the health condition of a plant may be interdependent or they may result from each other. An increase in plant vigor may for example result in an increased yield and/or tolerance to abiotic or biotic stress. One indicator for the condition of the plant is the yield. "Yield" is to be understood as any plant product of economic value that is produced by the plant such as grains, fruits in the proper sense, vegetables, nuts, grains, seeds, wood (e.g. in the case of silviculture plants) or even flowers (e.g. in the case of gardening plants, ornamentals). The plant products may in addition be further utilized and/or processed after harvesting.
In an especially preferred embodiment of the invention, the yield of the treated plant is increased.
In another preferred embodiment of the invention, the yield of the plants treated according to the method of the invention, is increased synergistically.
According to the present invention, "increased yield" of a plant, in particular of an agricultural, silvicultural and/or horticultural plant means that the yield of a product of the respective plant is increased by a measurable amount over the yield of the same product of the plant produced under the same conditions, but without the application of the mixture according to the invention.
Increased yield can be characterized, among others, by the following improved proper-ties of the plant: increased plant, weight, increased plant height, increased biomass such as higher overall fresh weight (FW), increased number of flowers per plant, higher grain yield, more tillers or side shoots (branches), larger leaves, increased shoot growth, increased protein content, increased oil content, increased starch content, increased pigment content, increased leaf are index.
According to the present invention, the yield is increased by at least 5 %, preferable by 5 to 10 %, more preferable by 10 to 20 %, or even 20 to 30 % compared to the untreated control plants or plants treated with pesticides in a way different from the method according to the present invention. In general, the yield increase may even be higher.
A further indicator for the condition of the plant is the plant vigor. The plant vigor becomes manifest in several aspects such as the general visual appearance. In another especially preferred embodiment of the invention, the plant vigor of the treated plant is increased. In another preferred embodiment of the invention, the plant vigor of the plants treated according to the method of the invention, is increased synergistically. Improved plant vigor can be characterized, among others, by the following improved properties of the plant: improved vitality of the plant, improved plant growth, improved plant development, improved visual appearance, improved plant stand (less plant verse/lodging), improved emergence, enhanced root growth and/or more developed root system, enhanced nodulation, in particular rhizobium nodulation, bigger leaf blade, bigger size, increased plant weight, increased plant height, increased tiller number, increased number of side shoots, increased number of flowers per plant, increased shoot growth, increased root growth (extensive root system), increased yield when grown on poor soils or unfavorable climate, enhanced photosynthetic activity (e.g. based on increased stomatal conductance and/or increased C02 assimilation rate), increased stomatal conductance, increased C02 assimilation rate, enhanced pigment content (e.g. chlorophyll content), earlier flowering, earlier fruiting, earlier and improved germination, earlier grain maturity, improved self-defense mechanisms, improved stress tolerance and resistance of the plants against biotic and abiotic stress factors such as fungi, bacteria, viruses, heat stress, cold stress, drought stress, UV stress and/or salt stress, less non-productive tillers, less dead basal leaves, less input needed (such as fertilizers or water), greener leaves, complete maturation under shortened vegetation periods, less fertilizers needed, less seeds needed, easier harvesting, faster and more uniform ripening, longer shelf-life, longer panicles, delay of senescence, stronger and/or more productive tillers, better extractability of ingredients, improved quality of seeds (for being seeded in the following seasons for seed production), better nitrogen uptake, improved reproduction, reduced production of ethylene and/or the inhibition of its reception by the plant.
The improvement of the plant vigor according to the present invention particularly means that the improvement of any one or several or all of the above mentioned plant characteristics are improved independently of the pesticidal action of the mixture or active ingredients (components).
Another indicator for the condition of the plant is the "quality" of a plant and/or its products.
In an especially preferred embodiment of the invention, the quality of the treated plant is increased.
In another preferred embodiment of the invention, the quality of the plants treated according to the method of the invention, is increased synergistically.
According to the present invention, enhanced quality means that certain plant characteristics such as the content or composition of certain ingredients are increased or improved by a measurable or noticeable amount over the same factor of the plant produced under the same conditions, but without the application of the mixtures of the present invention. Enhanced quality can be characterized, among others, by following improved properties of the plant or its product: increased nutrient content, increased protein content, increased content of fatty acids, increased metabolite content, increased carotenoid content, increased sugar content, increased amount of essential amino acids, improved nutrient composition, improved protein composition, improved composition of fatty acids, improved metabolite composition, improved carotenoid composition, improved sugar composition, improved amino acids composition, improved or optimal fruit color, improved leaf color, higher storage capacity, higher processability of the harvested products.
Another indicator for the condition of the plant is the plant's tolerance or resistance to biotic and/or abiotic stress factors. Biotic and abiotic stress, especially over longer terms, can have harmful effects on plants. Biotic stress is caused by living organisms while abiotic stress is caused for example by environmental extremes. According to the present invention, "enhanced tolerance or resistance to biotic and/or abiotic stress factors" means (1.) that certain negative factors caused by biotic and/or abiotic stress are diminished in a measurable or noticeable amount as compared to plants exposed to the same conditions, but without being treated with a mixture according to the invention and (2.) that the negative effects are not diminished by a direct action of the mixture according to the invention on the stress factors, e.g. by its fungicidal action which directly destroys the microorganisms or diseases, but rather by a stimulation of the plants' own defensive reactions against said stress factors.
Formulation of the present invention can be in any of the formulations selected from Capsule suspension (CS), Dispersible concentrate (DC), Powder for dry seed treatment (DS), Emulsifiable concentrate (EC), Emulsion, water in oil (EO), Emulsion for seed treatment (ES), Emulsion, oil in water (EW), Flowable suspension/concentrate for seed treatment (FS), Granule/ soil applied (GR), Controlled (Slow or Fast) release granules (CR), Solution for seed treatment (LS), Micro-emulsion (ME), Oil dispersion (OD), Oil miscible flowable concentrate (oil miscible suspension (OF), Oil miscible liquid (OL), Suspension concentrate (= flowable concentrate) (SC), Suspo-emulsion (SE), Water soluble granule (SG), Soluble concentrate (SL), Water soluble powder (SP), Water dispersible granule (WG or WDG), Wettable powder (WP), Water dispersible powder for slurry treatment (WS), A mixed formulation of CS and SC (ZC), A mixed formulation of CS and SE (ZE), A mixed formulation of CS and EW (ZW).
One or more of the active ingredients is encapsulated for various purposes, such as to increase the residual biological activity, or to reduce the acute toxicity, or to obtain a physical or chemically stable water-based formulation. The purpose determines whether the “free” active ingredient and the “release rate” are relevant properties of a specific product.
Further composition fugicidal compositions comprising bioactive amounts of (A) a fungicide from class of SDHI (Succinate dehydrogenase inhibitors) selected from group of phenyl benzamides, phenyl-oxo-ethyl thiophene amid, pyridinyl-ethyl-benzamides, furan carboxamides, oxathincarboxamides, pyrazole-4-carboxamides, pyridine carboxamides or mixture thereof; (B) at least one more fungicide selected from the class of QoI (Quinone outside Inhibitors), QiI-fungicides (Quinone inside Inhibitors), Lipid or transport and membrane synthesis inhibitors, Sterol biosynthesis Inhibitors, Melanin synthesis in cell wall Inhibitors, compound with unknow mode of action, multisite contact fungicides, Ipflufenoquin, Pyridachlometyl or mixture thereof; (C) At least one plant health additive selected from the group consisting of auxin, cytokinin, ethylene modulators, gibberellins, growth inhibitors, growth retardants, growth stimulators, unclassified growth regulators, micronutrients and biostimulants or mixture thereof are present in the said composition in specific fixed ratio.
In further aspect the present invention relates to the synergistic fungicidal composition comprising bioactive amounts of (A) is 0.1 to 35% w/w of the composition; (B) is 0.1 to 45% w/w of the composition; and (C) is 0.001 to 20% w/w of the composition.
Active Ingredients Compound
A Compound
B Compound
C
Examples Fungicide
SDHI (Succinate
dehydrogenase inhibitors) One more Fungicide Plant health additive
% of Active Ingredient
0.1 to 35%
0.1 to 45%
0.001 to 20%

The composition of the present invention in addition to bioactive amounts of active ingredients further comprises inactive excipients including but not limited to dispersant or dispersing agent, anti-freezing agent, anti-foam agent, wetting agent, suspension aid, disintegrating agent, thickener, wall forming materials, slow releasing agents and buffering agent.
A wetting agent is a substance that when added to a liquid increases the spreading or penetration power of the liquid by reducing the interfacial tension between the liquid and the surface on which it is spreading. Wetting agents are used for two main functions in agrochemical formulations: during processing and manufacture to increase the rate of wetting of powders in water to make concentrates for soluble liquids or suspension concentrates; and during mixing of a product with water in a spray tank or other vessel to reduce the wetting time of wettable powders and to improve the penetration of water into water-dispersible granules.
Examples of wetting agent used herein for SC (Suspension concentrate) formulation include but not limited to ethylene oxide/propylene oxide block copolymer, polyarylphenyl ether phosphate, ethoxylated fatty alcohol, sodium dioctyl sulfosuccinate, sodium lauryl sulfate and sodium dodecyl benzene sulfonate, alkyldiphenylsulfonates, sodium isopropyl naphthalene sulfonate,alkylnaphthalene sulfonate.
Examples of wetting agent used herein for Oil dispersion (OD) formulation includes but not limited to ethylene oxide/propylene oxide block copolymer, polyarylphenyl ether phosphate, ethoxylated fatty alcohol, sodium dioctyl sulfosuccinate, sodium lauryl sulfate and sodium dodecyl benzene sulfonate, alkyldiphenyl sulfonates, sodium isopropyl naphthalene sulfonate, alkylnaphthalene sulfonate.
Examples of wetting agent used herein for ZC (mixture of SC Suspension concentrate and CS Capsule suspension) formulation includes but not limited to Ethylene oxide/propylene oxide block copolymer, Polyarylphenyl ether phosphate, Ethoxylated Fatty Alcohol, Sodium dioctyl sulfosuccinate, sodium lauryl sulphate and sodium dodecyl benzene sulfonate, alkyl diphenyl sulfonates, sodium isopropyl naphthalene sulfonate, Alkyl naphthalene sulfonate, Octyl phenol ethoxylate, alkyl phenol ethoxylate and aliphatic alcohol ethoxylate or mixture thereof.
Examples of wetting agent used herein for WG (Wettable Granule), WDG (Water Dispersible Granule) formulation includes but not limited to sodium N-methyl-N-oleoyl taurate, alkylated naphtalene sulfonate, sodium salt, mixture of isomers of dibutylnaphthalene sulphonic acid sodium salt, sodium diisopropylnaphthalenesulphonate, sodium Lauryl sulfate, dioctyl sulfate, alkyl naphthalene sulfonates, phosphate esters, sulphosuccinates and nonionics such as tridexyl alcohol ethoxylate, alkyl or alkaryl sulfonates such as alkylbenzene sulfonates, alpha olefin sulfonate and alkyl naphthalene sulfonates, ethoxylated or non-ethoxylated alkyl or alkyaryl carboxylates, alkyl or alkyaryl phosphate esters, alkylpolysaccharide, di or mono alkyl sulfosuccinate derivatives, alpha olefin sulfonates, alkyl naphthalene sulfonates, dialkyl sulphosuccinates, butyl, dibutyl, isopropyl and diisopropyl naphthalene sulfonate salts, C12 alkyl benzene sulfonate or C10-C16 alkyl benzene sulfonate.
Examples of Wetting and spreading agent used herein for SC (Suspension concentrate) formulation, CS (Capsule Suspension), Oil dispersion (OD), SE (Suspo Emulsion) and WG (Wettable Granule), WDG (Water Dispersible Granule) formulation include but not limited to organic silicone type surfactant which includes trisiloxane ethoxylate, polydimethylsiloxane, polyoxyethylene methyl polysiloxane, polyoxyalkylene methyl polysiloxane, polyether polymethyl siloxane copolymer, heptamethyl trisiloxane, Polyalkyleneoxide modified heptamethyl trisiloxane, polyether modified polysiloxane, 10 mole ethylene oxide adduct of octylphenol, or mixture thereof etc; The addition of organic silicone type surfactant works as super wetting agent, speading agent, penetrating agent which improves the bioefficacy. It reduces the wash off/run off from foliage during rainy season, enhance the penetration of active ingredeints into the foliage, improve the availability of active ingredients on lower surface of leaves (i.e. translaminar action), and improve the spray coverage which is very much essential for contact action insecticides. Overall, addition of organic silicone type surfactants increases the bioefficacy and residual control period of the products which helps in reducing the number of pesticidal applications into the crop ecosystem.
A dispersant or a dispersing agent is a substance which adsorbs onto the surface of particles and helps to preserve the state of dispersion of the particles and prevents them from re-aggregating. Dispersants are added to agrochemical formulations to facilitate dispersion and suspension during manufacture, and to ensure the particles re-disperse into water in a spray tank. They are widely used in wettable powders, suspension concentrates and water-dispersible granules. Surfactants that are used as dispersants have the ability to adsorb strongly onto a particle surface and provide a charged or steric barrier to re-aggregation of particles. The most commonly used surfactants are anionic, non-ionic, or mixtures of the two types. For wettable powder formulations, the most common dispersants are sodium lingo sulphonates. In recent years, new types of very high molecular weight polymeric surfactants have been developed as dispersants. These have very long hydrophobic ‘backbones’ and a large number of ethylene oxide chains forming the ‘teeth’ of a ‘comb’ surfactant. These high molecular weight polymers can give very good long-term stability to suspension concentrates because the hydrophobic backbones have many anchoring points onto the particle surfaces.
Examples of dispersants or dispersing agent used herein for SC (Suspension concentrate) formulation include but not limited to alkylated naphthalene sulfonate, sodium salt, sodium salt of naphthalene sulfonate condensate, sodium ligno sulfonate, sodium ploycarboxylate,EO/PO based copolymer, phenol sulfonate, sodium methyl oleoyl taurate, styrene acrylic acid copolymer, propyleneoxide-ethyleneoxide-copolymer, polyethylene glycol 2,4,6-tristyrylphenyl ether, tristyrylphenol-polyglycolether-phosphate, tristyrylphenole with 16 moles EO, tristyrylphenol-polyglycolether-phosphate, oleyl-polyglycolether with ethylene oxide, tallow fattyamine polyethylene oxide, nonylphenol polyglycolether with 9-10 moles ethylene oxide.
Examples of dispersants or dispersing agent used herein for Oil dispersion (OD) formulation includes but not limited to alkyl sulfonates, alkyl benzene sulfonates, alkyl aryl sulfonates, alkylphenolalkoxylates, tristyrylphenol ethoxylates, natural or synthetic fatty ethoxylate alcohols, natural or synthetic fatty acid alkoxylates, natural or synthetic fatty alcohols alkoxylates, alkoxylated alcohols (such as n-butyl alcohol poly glycol ether), block copolymers (such as ethylene oxide-propylene oxide block copolymers and ethylene oxide-butylene oxide block copolymers), fatty acid-polyalkylene glycol condensates, polyamine-fatty acid condensates, polyester condensates, salts of polyolefin condensates, sodium ligno sulfonate, sodium ploycarboxylate,EO/PO based copolymer, phenol sulfonate, sodium methyl oleoyl taurate, styrene acrylic acid copolymer, propyleneoxide-ethyleneoxide-copolymer, polyethylene glycol 2,4,6-tristyrylphenyl ether, tristyrylphenol-polyglycolether-phosphate, tristyrylphenole with 16 moles EO, tristyrylphenol-polyglycolether-phosphate, oleyl-polyglycolether with ethylene oxide, tallow fattyamine polyethylene oxide, nonylphenol polyglycolether with 9-10 moles ethylene oxide.
Examples of dispersants or dispersing agent used herein for ZC (mixture of SC Suspension concentrate and CS Capsule suspension) formulation includes but not limited to Ethoxylated lignosulfonic acid salts, lignosulfonic acid salts, oxidized lignins, lignin salts, salts of styrenemaleic anhydride copolymers, polyvinyl alcohol, salts of partial esters of styrene-maleic anhydride copolymers, partial salts of polyacrylic acid and partial salts of polyacrylic acid terpolymers. the surfactant is lignosulfonate of calcium or sodium or mixtures thereof or a modified kraft lignin with a high sulfonic acid group , dibutylnaphthalenesulfonic acid ,fatty acids, alkyl- and alkylarylsulfonates, alkyl sulfates, lauryl ether sulfates and fatty alcohol sulfates, and salts of sulfated hexa-, hepta- and octadecanols and of fatty alcohol glycol ethers, condensates of sulfonated naphthalene and its derivatives with formaldehyde, condensates of naphthalene or of the naphthalenesulfonic acids with phenol and formaldehyde, polyoxyethylene octylphenol ether, ethoxylated isooctyl-, octyl- or nonylphenol, alkyl phenyl polyglycol ethers, tributyl phenyl polyglycol ethers, alkyl aryl polyether alcohols, is tridecyl alcohol, fatty alcohol/ethylene oxide condensates, ethoxylated castor oil, polyoxyethylene alkyl ethers or polyoxypropylene alkyl ethers, lauryl alcohol polyglycol ether acetate, sorbitol esters, lignin-sulphite waste liquors, and proteins, denatured proteins, polysaccharides , ammonium salts of sulfonates, sulfates, phosphates or carboxylates, alkylarylsulfonates, diphenyl sulfonates, alpha-olefin sulfonates, sulfonates of fatty acids and oils, sulfonates of ethoxylated alkylphenols, sulfonates of condensed naphthalene, sulfonates of dodecyl- and tridecyl benzenes, sulfonates of naphthalene and alkylnaphthalenes, sulfosuccinates or sulfosuccinates, alkoxylates, N-alkylated fatty acid amides, amine oxides, esters or sugar-based surfactants, alkylphenols, amines (e.g. tallow amine), amides, aryl phenols, fatty acids or fatty acid esters which have been alkoxylated. Ethylene oxide and/or propylene oxide may be employed for the alkoxylation, preferably ethylene oxide, polyethylene oxide and polypropylene oxide, polyacids or polybases.
Examples of dispersants or dispersing agent used herein for WG (Wettable Granule), WDG (Water Dispersible Granule) formulation include but not limited to naphthalene sulfonic acid, sodium salt condensated with formaldehyde, polyalcoxylated alkylphenol, naphthalenesulfonic acid formaldehyde condensate, methylnaphtaline-formaldehyde-condensate sodium salt, napthalene condensates, lignosulfonates, polyacrylates and phosphate esters, calcium lignosulfonate,lignin sulfonate sodium salt;
Antifoaming agent for the present formulation is selected from various compounds and selectively used according to the formulation. Generally, there are two types of antifoam agents, namely silicones and non-silicones. Silicones are usually aqueous emulsions of dimethyl poly siloxane while the non-silicone anti-foam agents are water- insoluble oils, such as octanol and nonanol, or silica. In both cases, the function of the anti-foam agent is to displace the surfactant from the air-water interface.
Examples of Antifoaming agent used herein for SC (Suspension concentrate), Oil dispersion (OD) formulation and ZC (mixture of SC Suspension concentrate formulation, include but not limited to silicone oil, silicone compound, C10~C20 saturated fat acid compounds or C8~C10 aliphatic alcohols compound, silicone antifoam emulsion, dimethylsiloxane, polydimethyl siloxane, vegetable oil based antifoam, tallow based fatty acids, polyalkyleneoxide modified polydimethylsiloxane.
Examples of Antifoaming agent used herein for WG (Wettable Granule) formulation includes but not limited to polydimethylsiolxane.
Anti-freezing agent for the present formulation is selected from various compounds and selectively used according to the formulation.
Examples of Anti-freezing agent used herein for SC (Suspension concentrate) and Oil dispersion (OD) formulation and ZC (mixture of SC Suspension concentrate and CS Capsule suspension) formulation include but not limited to ethylene glycol, propane diols, glycerine or the urea, glycol (monoethylene glycol, diethylene glycol, polypropylene glycol, polyethylene glycol), glycerine, urea, magnesium sulfate heptahydrate, sodium chloride.
Disintegrating agent used herein for the WG (Wettable Granule) formulation is selected from citric acid, succinic acid or the sodium bicarbonate.
Preservative used herein for the SC (Suspension concentrate) formulation, Oil dispersion (OD) formulation and ZC (mixture of SC Suspension concentrate and CS Capsule suspension) formulation include but not limited to 1,2-benzisothiazolin-3(2H)-one, sodium salt, Sodium benzoate, 2-bromo-2-nitropropane-1,3-diol, Formaldehyde, Sodium o-phenylphenate, 5-chloro-2-methyl-4-isothiazolin-3-one & 2-methyl-4-isothiazolin-3-one.
Thickeners or gelling agents are used mainly in the formulation of suspension concentrates, emulsions and suspoemulsions to modify the rheology or flow properties of the liquid and to prevent separation and settling of the dispersed particles or droplets. Thickening, gelling, and anti-settling agents generally fall into two categories, namely water-insoluble particulates and water-soluble polymers.
Examples of thickeners used herein for SC (Suspension concentrate) formulation include but not limited to xanthan gum, PVK, carboxymethylcelluloses, polyvinyl alcohols,gelatin, sodium carboxymethylcellulose, hydroxyethylcellulose, sodium polyacrylate, modified starch;
Examples of thickeners used herein for ZC (mixture of SC Suspension concentrate and CS Capsule suspension) formulation include but not limited to Xanthan gum ,Carboxy methyl cellulose, Attapulgite clay, Bentonite clay;
Suspension aid or the suspending agent in the present description denotes a natural or synthetic, organic or inorganic material with which the active substance is combined in order to facilitate its application to the plant, to the seeds or to the soil. This carrier is hence generally inert, and it must be agriculturally acceptable, in particular to the plant being treated. The carrier may be solid (clays, natural or synthetic silicates, silica, resins, waxes, solid fertilizers, and the like or mixtures thereof) or liquid (water, alcohols, ketones, petroleum fractions, aromatic or paraffinic hydrocarbons, chlorinated hydrocarbons, liquefied gases, and the like or mixtures thereof).
Examples of suspending agent used herein for SC (Suspension concentrate) formulation and ZC (mixture of SC Suspension concentrate and CS Capsule suspension) formulation include but not limited to Aluminum Magnesium Silicate, Bentonite clay, Silica, Attapulgite clay.
Carrier for the present formulation is selected from selected from various compounds and selectively used according to the formulation.
Examples of Carrier used herein for Oil dispersion (OD) formulation include but not limited to olive oil, kapok oil, castor oil, papaya oil, camellia oil, palm oil, sesame oil, corn oil, rice bran oil, peanut oil, cotton seed oil, soybean oil, rapeseed oil, linseed oil, tung oil, sunflower oil, safflower oil, palm (Elaeis guineensis) oil, neem (azadirecha indica) oil, eucalyptus oil, karanja (Milletia pinnata/Pongamia pinnata) oil, coconut oil, tall oil, alkyl ester of vegetable oils, (e.g. rapeseed oil methyl ester or rapeseed oil ethyl ester, rapeseed oil propyl esters, rapeseed oil butyl esters, neem oil, tall oil fatty acids esters etc.), diesel, mineral oil, fatty acid amides (e.g. C1 -C3 amines, alkylamines or alkanolamines with C6 - Ci8 carboxylic acids), fatty acids, tall oil fatty acids, alkyl esters of fatty acids (e.g. Ci, Methyl and ethyl oleate, methyl and ethyl soyate, alkyl benzenes and alkylnaphthalenes, polyalkylene glycol ethers, fatty acid diesters, fatty alkylamides and diamides, dialkylene carbonates, ketones and alcohols. The above oil based carrier/diluting agents may be used as solo or mixture of two or more if desired.
Certain vegetables/plant/seed oils as a carrier, increases the bioefficacy and residual control of products through increase in penetration of active ingredients into leaf surface, improves the retention of active ingredietns on leaf surface especially on waxy leaf surface, improves the spreading properties and thereby improves the spray coverage.
Examples of Carrier used herein for WG (Wettable Granule) formulation includes but not limited to china clay, silica, lactose anhydrous, ammonium sulfate, sodium sulfate anhydrous, corn starch, urea, EDTA, urea formaldehyde resin, diatomaceous earth, kaolin, bentonite, kieselguhr, fuller's earth, attapulgite clay,bole, loess, talc, chalk, dolomite, limestone, lime, calcium carbonate, powdered magnesia, magnesium oxide, magnesium sulfate, sodium chloride, gypsum, calcium sulfate, pyrophyllite, silicates and silica gels; fertilizers such as, for example, ammonium sulfate, ammonium phosphate, ammonium nitrate and urea; natural products of vegetable origin such as, for example, grain meals and flours, bark meals, wood meals, nutshell meals and cellulosic powders; and synthetic polymeric materials such as, for example, ground or powdered plastics and resins, bentonites, zeolites, titanium dioxide, iron oxides and hydroxides, aluminium oxides and hydroxides, or organic materials such as bagasse, charcoal, or synthetic organic polymers.
Solvents used herein for the ZC (mixture of SC Suspension concentrate and CS Capsule suspension) formulation includes but not limited to Hydrocarbon solvent such a an aliphatic, cyclic and aromatic hydrocarbons (e.g. toluene, xylene, paraffin, tetrahydronaphthalene, alkylated naphthalene or their derivatives, mineral oil fractions of medium to high boiling point (such as kerosene, diesel oil, coal tar oils)); a vegetable oil such as corn oil, rapeseed oil; a fatty acid ester such as C1-C10-alkylester of a C10-C22-fatty acid; or, methyl- or ethyl esters of vegetable oils such as rapeseed oil methyl ester or corn oil methyl ester, acetophenone, 2-Heptanon , 3-heptanone, 2-hexanone, 5-methyl-2-hexanone , 5-methyl-3-heptanone, 3-methyl-2-hexanone , 4-methyl-2-hexanone, 2-methyl-3-hexanone, 4-methyl-3-hexanone , 5-methyl-3-hexanone , 3-ethyl-2-pentanone , 3,3-dimethyl-2-pentanone , 3,4-dimethyl-2-pentanone, 4,4-dimethyl-2-pentanone , 2,2-dimethyl-3-pentanone , 2,4-dimethyl-3-pentanone, 2-octanone , 2,5-dimethyl-3-hexanone , 2,2-dimethyl-3-hexanone , 3,3-dimethyl-2-hexanone, 3,4-dimethyl-2-hexanone, 4,4-dimethyl-3-hexanone , 3-ethyl-4-methyl-2-pentanone , 2-methyl-3-heptanone, 2-methyl-4-heptanone, 3-methyl-2-heptanone, 3-methyl-4-heptanone, 5-methyl-3-heptanone, 6-methyl-2-heptanone , 6-methyl-3-heptanone, 3-octanone, 4-octanone, 2,2,4-trimethyl-3-pentanone , 3-ethyl-3-methyl-2-pentanone, 5-methyl-2-heptanone, isoprene.
Colorant used herein for the Granule (GR), Soil Applied Granule (SAG), Controlled Release granule (CR) formulation includes but not limited to crystal violet, thalocyano dye chlorinated, aerosol green FFB dye, rodamine, azo compound.
Emulsifying agent used herein for the Oil dispersion (OD) formulation includes but not limited to castor oil ethoxylates, alcohol ethoxylates, fatty acid ethoxylates, sorbitan ester ethoxylates, sulphosuccinate, calcium salts of dodecylbenzene sulphonate, alkylammonium salts of alkylbenzene sulphonate, alkylsulphosuccinate salts, ethylene oxide-propylene oxide block copolymers, ethoxylated alkylamines, ethoxylated alkyl phenols, polyoxyethylenesorbitan monolaurate.
Stabilizers or stabilizing agent used herein for the Oil dispersion (OD) formulation includes but not limited to hectorite clay, aluminum magnesium silicate, bentonite clay, silica, attapulgite clay.
Buffering agent used herein for the ZC (mixture of SC Suspension concentrate and CS Capsule suspension) formulation includes but not limited to Sodium hydroxide, potassium hydroxide, acetic acid, sulphuric acid, hydrochloric acid, ortho phosphoric acid, ammonium hydroxide.
Wall forming material used herein for the ZC (mixture of SC Suspension concentrate and CS Capsule suspension) formulation includes but not limited to Tetramethylene diisocyanate, pentamethylene diisocyanate, hexamethylene diisocyanate, toluene diisocyanate, diphenylmethene-4,4’-diisocyanate, polymethylene polyphenylene isocyanate, 2,4,4’-diphenyl ether tri-isocyanate, 3,3’-dimethyl-4,4’-diphenyl diisocyanate, 3,3’-dimethoxy-4,4’-diphenyl diisocyanate, 1,5-naphthylene diisocyanate and 4,4’4"-triphenylmethane tri-isocyanate, toluene diisocyanate or polymethylene polyphenylisocyanate; Ammonia, hexamine, ethylenediamine, propylene-1,3-diamine, tetramethylenediamine, pentamethylenediamine, 1,6-hexamethylenediamine, diethylenetriamine, triethylene- tetramine, tetra ethylene pentamine, pentaethylenehexamine, 4,9-dioxadodecane-1, 12-diamine, 1,3- phenylenediamine, 2,4- and 2,6-toluenediamine and 4,4’-diaminodiphenylmethane, 1,3-phenylenediamine, 2,4- and 2,6-toluenediamine, 4,4'-diaminodiphenylmethane, 1,5-diaminonaphthalene, 1,3,5-triaminobenzene, 2,4,6-triaminotoluene, 1,3,6-triaminonaphthalene, 2,4,4'-triaminodiphenyl ether, 3,4,5-triamino-1,2,4-triazole and 1,4,5,8-tetraminoanthraquinone.
The process for preparing the present novel synergistic composition can be modified accordingly by any person skilled in the art based on the knowledge of the manufacturing the formulation. However all such variation and modification is still covered by the scope of present invention.
The present invention highlights the synergistic effect of the combination of the at least one fungicide selected from SDHI (Succinate dehydrogenase inhibitors) group or mixture thereof; at least one more fungicide selected from the class of QoI (Quinone outside Inhibitors), QiI-fungicides (Quinone inside Inhibitors), Lipid or transport and membrane synthesis inhibitors, Sterol biosynthesis Inhibitors, Melanin synthesis in cell wall Inhibitors, compound with unknow mode of action, multisite contact fungicides, Ipflufenoquin, Pyridachlometyl or mixture thereof; at least one more compound selected from plant health additive or mixture thereof.
Following the right use of the invented technology and the synergistic fungicidal composition of the invention with a formulations having a multi-pesticide components i.e. pesticide mixture, formulation prepared with an extra care of physical compatibility by purposefully specially selected solvents, dispersing agents, carriers and the surfactants, thickeners, stabilizers etc. exhibits better fungal and pest management and boost plant health.
While the foregoing written description of the invention enables one of ordinary skill to make and use what is considered presently to be the best mode thereof, those of ordinary skill will understand and appreciate the existence of variations, combinations, and equivalents of the specific embodiment, method, and examples herein. The invention should therefore not be limited by the above described embodiment, method, and examples, but by all embodiments and methods within the scope and spirit of the invention. The invention shall now be described with reference to the following specific examples. It should be noted that the example(s) appended below illustrate rather than limit the invention, and that those skilled in the art will be able to design many alternative embodiments without departing from the scope of the present invention.
These and other aspects of the invention may become more apparent from the examples set forth herein below. These examples are provided merely as illustrations of the invention and are not intended to be construed as a limitation thereof.
EXAMPLE 1:
ZC (Mixed formulation of SC and CS) formulation of Thifluzamide 5%+Pyraclostrobin 5% + Orthosilicic acid 2%.
Chemical composition % (w/w)
Thifluzamide a.i. 5.00
Pyraclostrobin a.i. 5.00
Orthosilicic acid acid 2.00
Wetting and spreading agent 3.50
Dispersing agent 1 4.50
Dispersing agent 2 2.00
Solvent 8.00
Wall forming material 1 1.00
Wall forming material 2 0.50
Suspending agent 1.50
Antifoaming agent 0.30
Buffering agent 0.50
Preservative 0.20
Antifreezing agent 5.00
Thickner 0.15
Diluent Water 60.85
Total 100.00

Storage stability-
Thifluzamide 5%+Pyraclostrobin 5%+Orthosilicic acid 2% ZC (Mixed formulation of SC and CS)
Laboratory storage for 14 days
Parameters Specification (in house) Initial At 54±2 0C At 0±2 0C
Thifluzamide content percent by mass 4.75 to 5.50 5.25 5.2 5.21
Pyraclostrobin content percent by mass 4.75 to 5.50 5.25 5.2 5.25
Orthosilicic acid content percent by mass 1.90 to 2.20 2.1 2.1 2.1
Thifluzamide suspensibility percent min. 80 96.14 95.15 96.03
Pyraclostrobin suspensibility percent min. 80 97.16 97.10 96.80
Orthosilicic acid suspesnibility precent min. 80 97.15 97.12 96.80
pH range (1% aq. Suspension) 5.0 to 7.0 5.00 5.00 5.00
Pourability 95% min. 97.4 97.2 97.5
Specific gravity 1.05-1.10 1.05 1.05 1.05
Viscosity at spindle no. 62, 20 rpm 350-800 cps 510 518 520
Particle size (micron) D50<3, D90<10 2.2,8.6 2.4,8.8 2.5,8.9
Persistent foam ml (after 1 minute) max. 60 nil 3 nil
Room temperature storage
Parameters Specification (in house) 1 month 6 month 12 month
Thifluzamide content percent by mass 4.75 to 5.5 5.25 5.25 5.24
Pyraclostrobin content percent by mass 4.75 to 5.5 5.25 5.25 5.24
Orthosilicic acid content percent by mass 1.90 to 2.2 2.10 2.10 2.10
Thifluzamide suspensibility percent min. 80 96.17 95.13 95.32
Pyraclostrobin suspensibility percent min. 80 97.16 96.10 96.20
Orthosilicic acidsuspesnibility precent min. 80 97.13 96.14 96.20
pH range (1% aq. Suspension) 5.0 to 7.0 5.00 5.00 5.00
Pourability 95% min. 97.4 97.4 97.3
Specific gravity 1.05-1.10 1.05 1.05 1.05
Viscosity at spindle no. 62, 20 rpm 350-800 cps 515 520 523
Particle size (micron) D50<3, D90<10 2.2,8.6 2.2,8.6 2.2,8.7
Persistent foam ml (after 1 minute) max. 60 nil nil 2

Procedure: Manufacturing process of ZC (mixture of SC and CS)

Preparation of ZC (mixture of CS and SC) Formulation:
Part A Preparation of CS (Capsule Suspension) formulation
Step 1 Aqueous Phase-Charge water to a stainless-steel vessel equipped with a high speed stirrer. Under agitation, add the wetting agent, dispersing agent 1and dispersing agent 2 into the vessel. Now add 50% quantity of antifoam to avoid foam generation in this vessel.
Step 2 Organic Phase-Charge heavy aromatic hydrocarbons solvent into second stainless-steel reactor. Then, slowly add melted active ingredient into the reactor. Afterwards, charge wall forming material 1 material to the reactor. Continue mixing. Cool the reactor contents to room temperature.
Step 3 Start the high shear disperser of aqueous phase and charge the ‘Organic Solution’ into the ‘Aqueous Phase Solution’ under gravity in specific rate so that required particle size can be achieved and continue to shear for 30 min. Then, start heating the reactor to around 50 °C and stir the formulation under slow rpm for 3-4 hours so that Polymerization reaction gets completed.
Step 4 Now add wall forming material 2 so that residual wall forming material 1 can be consumed and stir for 1 more hour at the same temperature and if required add half quantity of antifoam to remove foam generating due to CO2 during reaction.
Step 5 After the wall polymerization reaction, increase the agitator to high speed. Add the rest half quantity of antifoam to the formulation. Under slight vacuum, allow the mixture to de-gas for approximately 30 minutes to remove CO2 from the solution. Add the linear polysaccharide, preservative and in last freezing agent and mix for some minutes. Add buffering agent for pH adjustment. Check the formulation to specifications
Part B Preparation of SC (Suspension Concentrate) formulation
Step 1 2% Gel Preparation: Charge the required quantity of water to a vessel, equipped with a high shear stirrer and start the agitation. Add the required amount of preservative. Mix until homogenous. Add the required amount of thickener and mix vigorously until it is fully wetted.
Step 2 SC Premix- Charge the required quantity of water to a vessel, equipped with bulk agitator and a high shear homogenizer and start agitation. Add the required amount of ant freezing agent and mix until uniform. Add the antifoaming agent and ensure that it is well dispersed. Add the wetting and dispersing agent and mix until uniform. Ensure that the dispersing agent is fully dispersed.
Step 3 Now add the active ingredient and continue agitating the vessel contents until all components get dissolved. Mill this pre-mix through a Colloid mill and subsequently through a Dyno mill to meet the specified particle size.
Step 4 Now add remaining antifoaming agent to this SC mill base to a vessel, equipped with bulk agitator. Mix until uniform. Add the required amount of 2% aqueous pre-gel and suspending agent and continue agitation until the formulation is homogeneous and has the target viscosity. Mix well.
Part C Preparation of ZC Formulation
Step 1 Charge the required quantity of SC formulation into a vessel, equipped with bulk agitator and start agitation. Add the CS Premix to this slurry and mix slowly until uniform. Add the required amount of 2% pre-gel and continue agitation until the formulation is homogeneous and a target viscosity of around 600-800 m cPs is reached. Mix well.
Step 2 Final product is sent for QC approval.
Step 3 After approval, material is packed in required pack sizes.

EXAMPLE 2:
OD (Oil Dispersion) formulation of Fluxapyroxad 16%+Azoxytrobin 10%+Orthosilicic acid 4%
Chemical composition % (w/w)
Fluxapyroxad a.i. 16.00
Azoxystrobin a.i. 10.00
Ortho silicic acid a.i. 4.00
Wetting and spreading agent 5.00
Dispersing agent 4.50
Emulsifying agent 8.00
Stabilizer 1.50
Antifoaming agent 0.30
Preservative 0.20
Antifreezing agent 5.00
Carrier as solvent 45.50
Total 100.00

Storage stability- Fluxapyroxad 16%+Azoxytrobin 10%+Orthosilicic acid 4% OD (Oil Dispersion) formulation
Laboratory storage for 14 days
Parameters Specification (in house) Initial At 54±2 0C At 0±2 0C
Fluxapyroxad content percent by mass 15.20 to 16.80 16.50 16..20 16.40
Azoxystrobin content percent by mass 9.50 to 10.50 10.30 10.10 10.20
Ortho silicic acid content percent by mass 3.80 to 4.40 4.30 4.10 4.20
Fluxapyroxad suspensibility percent min. 80 97.60 95.20 97.40
Azoxystrobin suspensibility percent min. 80 98.20 96.80 97.80
Ortho silicic acid suspesnibility precent min. 80 98.60 98.40 98.20
pH range (1% aq. Suspension) 5.5 to 8.5 6.80 6.80 6.80
Pourability 95% min. 97.60 97.20 97.50
Specific gravity 1.02-1.08 1.04 1.04 1.04
Viscosity at spindle no. 62, 20 rpm 350-800 cps 650 630 670
Particle size (micron) D50<3, D90<10 2.2,8.6 2.4,8.8 2.5,8.9
Persistent foam ml (after 1 minute) max. 60 nil 2 nil
Room temperature storage
Parameters Specification (in house) 1 month 6 months 12 months
Fluxapyroxad content percent by mass 15.20 to 16.80 16.50 16.40 16.20
Azoxystrobin content percent by mass 9.50 to 10.50 10.30 10.200 10.100
Ortho silicic acid content percent by mass 3.80 to 4.40 4.30 4.20 4.10
Fluxapyroxad suspensibility percent min. 80 97.60 97.40 96.80
Azoxystrobin suspensibility percent min. 80 98.20 97.89 97.20
Ortho silicic acid suspesnibility precent min. 80 98.60 98.50 98.40
pH range (1% aq. Suspension) 5.5 to 8.5 6.80 6.80 6.80
Pourability 95% min. 97.60 97.40 97.20
Specific gravity 1.02-1.08 1.04 1.04 1.04
Viscosity at spindle no. 62, 20 rpm 350-800 cps 650 660 680
Particle size (micron) D50<3, D90<10 2.2,8.6 2.4,8.8 2.5,8.9
Persistent foam ml (after 1 minute) max. 60 nil 2 nil

Procedure: Manufacturing process of Oil dispersion (OD) formulation:

Preparation of Oil dispersion (OD) formulation:
Part A Preparation of the liquid premix
Step 1 Charge Vegetable oil or solvent or both into a vessel with anchor stirrer.
Step 2 Under stirring, add the emulsifier and dispersing agent and stir until all ingredients are dissolved completely.
Part B Preparation of the slurry
Step 1 Now, charge the liquid premix into a second vessel, equipped with a cooling and heating device and a high shear stirrer.
Step 2 Add the active ingredient and homogenize thoroughly. Pre-mill this mixture and finally mill it using a bead mill to achieve a particle size distribution as required by the specification.
Part C Preparation of the Thickener gel
Step 1 Charge the vegetable/plant/seed oil or solvent to the vessel, equipped with a high shear stirrer.
Step 2 Add gradually the thickener which is organophilic clay, maintaining high-shear mixing throughout. Stirring is continued until thoroughly mixed.
Step 3 Under stirring, the thickener activating agent propylene carbonate is added. Allow the gel to swell whilst maintaining mixing.
Part D Preparation of the final formulation
Step 1 Now add the thickener gel or silica and disperse the mixture by using a high shear stirrer.
Step 2 Finally add the recommended wetting and spreading agent or adjuvants (silicone or non-silicone based) to this formulation and disperse by using high shear stirrer.
Step 3 Check the finished formulation to specification.
Step 4 After approval, material is packed in required pack sizes.

EXAMPLE 3:
SC (Suspension Concentrate) formulation of Thifluzamide 15%+ Difenoconazole 20%+ Zinc 5%
Chemical composition % (w/w)
Thifluzamide a.i. 15.00
Difenoconazole a.i. 20.00
Zinc a.i. 5.00
Wetting and spreading agent 3.50
Dispersing agent 1 4.50
Dispersing agent 2 1.00
Suspending agent 2.00
Antifoaming agent 0.30
Preservative 0.20
Antifreezing agent 5.00
Thickner 0.15
Diluent Water 43.35
Total 100.00

Storage stability-
Thifluzamide 15%+Difenoconazole 20%+Zinc 5% SC (Suspension Concentrate)
Laboratory storage for 14 days
Parameters Specification (in house) Initial At 54±2 0C At 0±2 0C
Thifluzamide content percent by mass 14.25 to 15.75 15.50 15.20 15.40
Difenoconazole content percent by mass 19.00 to 21.00 20.50 20.20 20.40
Zinc content percent by mass 4.75 to 5.50 5.40 5.40 5.40
Thifluzamide suspensibility percent min. 80 98.40 97.60 98.40
Difenoconazole suspensibility percent min. 80 97.60 97.20 97.50
Zinc suspesnibility precent min. 80 96.80 96.80 96.80
pH range (1% aq. Suspension) 5.5 to 8.5 6.70 6.50 6.60
Pourability 95% min. 97.80 97.40 97.80
Specific gravity 1.02-1.08 1.04 1.04 1.04
Viscosity at spindle no. 62, 20 rpm 350-800 cps 660 670 660
Particle size (micron) D50<3, D90<10 2.2,8.6 2.4,8.8 2.5,8.9
Persistent foam ml (after 1 minute) max. 60 nil 3 nil
Room temperature storage
Parameters Specification (in house) 1 month 6 months 12 months
Thifluzamide content percent by mass 14.25 to 15.75 15.50 15.30 15.10
Difenoconazole content percent by mass 19.00 to 21.00 20.50 20.30 20.10
Zinc content percent by mass 4.75 to 5.50 5.40 5.40 5.40
Thifluzamide suspensibility percent min. 80 98.40 98.20 97.80
Difenoconazole suspensibility percent min. 80 97.60 97.40 97.20
Zinc suspesnibility precent min. 80 96.80 96.50 96.20
pH range (1% aq. Suspension) 5.5 to 8.5 6.70 6.70 6.70
Pourability 95% min. 97.80 97.70 97.60
Specific gravity 1.02-1.08 1.04 1.04 1.04
Viscosity at spindle no. 62, 20 rpm 350-800 cps 660 670 680
Particle size (micron) D50<3, D90<10 2.2,8.6 2.3,8.9 2.4,9.0
Persistent foam ml (after 1 minute) max. 60 nil 3 nil

Procedure: Manufacturing process of Suspension Concentrate (SC)
Step 1 2% Gel Preparation: Charge the required quantity of water to a vessel, equipped with a high shear stirrer and start the agitation. Add the required amount of preservative. Mix until homogenous. Add the required amount of thickener and mix vigorously until it is fully wetted.
Step 2 Charge the required quantity of water to a vessel, equipped with bulk agitator and a high shear homogenizer and start agitation. Add the required amount of ant freezing agent and mix until uniform. Add the antifoaming agent and ensure that it is well dispersed. Add the wetting and dispersing agent and mix until uniform. Ensure that the dispersing agent is fully dispersed.
Step 3 Now add the active ingredient and continue agitating the vessel contents until all components get dissolved. Mill this pre-mix through a Colloid mill and subsequently through a Dyno mill to meet the specified particle size.
Step 4 Now add remaining antifoaming agent to this SC mill base to a vessel, equipped with bulk agitator. Mix until uniform. Add the required amount of 2% aqueous pre-gel and suspending agent and continue agitation until the formulation is homogeneous and has the target viscosity is reached.
Step 5 Final product is sent for QC approval.
Step 6 After approval, material is packed in required pack sizes.

EXAMPLE 4:
SC (Suspension Concentrate) formulation of Bixafen 8%+Prothioconazole 5%+Brassinolide 0.025%
Chemical composition % (w/w)
Bixafen a.i. 8.00
Prothioconazole a.i. 5.00
Brassinolide a.i. 0.025
Wetting and spreading agent 3.50
Dispersing agent 1 4.50
Dispersing agent 2 1.00
Suspending agent 2.00
Antifoaming agent 0.30
Preservative 0.20
Antifreezing agent 5.00
Thickner 0.15
Diluent Water 70.33
Total 100.00

Storage stability-
Bixafen 8% + Prothioconazole 5% + Brassinolide 0.025% - SC (Suspension Concentrate) formulation

Laboratory storage for 14 days
Parameters Specification (in house) Initial At 54±2 0C At 0±2 0C
Bixafen content percent by mass 7.60 to 8.80 8.50 8.20 8.40
Prothioconazole content percent by mass 4.75 yo 5.50 5.40 5.10 5.30
Brassinolide content percent by mass 0.02375 to 0.0275 0.026 0.026 0.026
Bixafen suspensibility percent min. 80 97.50 97.20 97.40
Prothioconazole suspensibility percent min. 80 96.80 96.20 6.70
Brassinolide suspesnibility precent min. 80 98.50 98.50 98.50
pH range (1% aq. Suspension) 5.5 to 8.5 6.80 6.80 6.80
Pourability 95% min. 98.20 98.20 98.20
Specific gravity 1.02-1.08 1.03 1.03 1.03
Viscosity at spindle no. 62, 20 rpm 350-800 cps 680 680 680
Particle size (micron) D50<3, D90<10 2.2,8.6 2.4,8.8 2.5,8.9
Persistent foam ml (after 1 minute) max. 60 nil 3 nil
Room temperature storage
Parameters Specification (in house) 1 month 6 months 12 months
Bixafen content percent by mass 7.60 to 8.80 8.50 8.40 8.20
Prothioconazole content percent by mass 4.75 yo 5.50 5.40 5.40 5.20
Brassinolide content percent by mass 0.02375 to 0.0275 0.026 0.026 0.026
Bixafen suspensibility percent min. 80 97.50 97.30 97.50
Prothioconazole suspensibility percent min. 80 96.80 96.40 96.80
Brassinolide suspesnibility precent min. 80 98.50 98.50 98.50
pH range (1% aq. Suspension) 5.5 to 8.5 6.80 6.80 6.80
Pourability 95% min. 98.20 98.10 98.10
Specific gravity 1.02-1.08 1.03 1.03 1.03
Viscosity at spindle no. 62, 20 rpm 350-800 cps 680 690 690
Particle size (micron) D50<3, D90<10 2.2,8.6 2.3,8.9 2.4,9.0
Persistent foam ml (after 1 minute) max. 60 nil 3 nil

Procedure: Manufacturing process of Suspension Concentrate (SC) as per Example 3

EXAMPLE 5:
WG (Water dispersible granule/Wettable Granule) formulation of Fluxapyroxad 5% + Copper 50% + Zinc 5%
Chemical composition % (w/w)
Fluxapyroxad a.i. 5.00
Copper a.i. 50.00
Zinc a.i. 5.00
Wetting and spreading agent 3.00
Dispersing agent I 6.00
Dispersing agent II 2.00
Disintegrating agent 0.50
Antifoaming agent 1.00
Carrier 27.50
Total 100.00

Storage stability-
Fluxapyroxad 5%+ Copper 50% +Zinc 5% WG (Water dispersible granule/ Wettable Granule) formulation
Laboratory storage for 14 days
Parameters Specification (in house) Initial At 54±2 0C At 0±2 0C
Fluxapyroxad content percent by mass 4.75 to 5.50 5.40 5.20 5.30
Copper content percent by mass 48.50 to 52.50 52.00 51.00 52.00
Zinc content percent by mass 4.75 to 5.50 5.20 5.20 5.20
Fluxapyroxad suspensibility percent min. 70 98.20 97.80 98.00
Copper suspensibility percent min. 70 95.50 95.10 95.20
Zinc suspensibility percent min. 70 96.60 96.60 96.60
pH range (1% aq. Suspension) 6.0 to 9.0 7.20 7.10 7.20
Wettability sec. max. 60 7 8 8
Wet sieve (45 micron) percent by mass min. 98.5 99.6 99.2 99.5
Bulk density (g/ml) 0.45 to 0.65 0.5 0.5 0.5
Moisture content percent by mass max. max. 2% 2 2 2
Room temperature storage stability up to 12 months
Parameters specification (in house) 1 month 6 months 12 months
Fluxapyroxad content percent by mass 4.75 to 5.50 5.40 5.30 5.20
Copper content percent by mass 48.50 to 52.50 52.00 51.80 51.50
Zinc content percent by mass 4.75 to 5.50 5.20 5.20 5.20
Fluxapyroxad suspensibility percent min. 70 98.20 98.00 97.80
Copper suspensibility percent min. 70 95.50 95.20 94.70
Zinc suspensibility percent min. 70 96.60 96.40 96.20
pH range (1% aq. Suspension) 6.0 to 9.0 7.20 7.20 7.10
Wettability sec. max. 60 7 8 8
Wet sieve (45 micron) percent by mass min. 98.5 99.6 99.3 99.2
Bulk density (g/ml) 0.45 to 0.65 0.5 0.5 0.5
Moisture content percent by mass max. max. 2% 2 2 2

Procedure: Manufacturing process of Water Dispersible Granules (WG) by extrusion method

Step 1 Charge the required quantity of filler, wetting agent, dispersing agent, and suspending agent, & technical in premixing blender for homogenization for 30 minutes.
Step 2 Pre-blended material is then grinded through Jet mill/ air classifier mills. Finely grinded material is blended in post blender till it becomes homogeneous. (Forapprox. 1.5 hr.)
Step 3 Finely grinded powder is mixed with required quantity of water to form extrudable dough.
Step 4 Dough is passed through extruder to get granules of required size.
Step 5 Wet granules are passed through Fluidized bed drier and further graded using vibrating screens.
Step 6 Final product is sent for QC approval.
Step 7 After approval material is packed in required pack sizes.

Procedure: Manufacturing process of Water Dispersible Granules (WG) by spray dried method

Step 1 Charge required quantity of DM water need to be taken in designated vessel for production.
Step 2 Add required quantity of Wetting agent, dispersing agent, antifoam & suspending agents and homogenize the contents for 45 – 60 minutes using high shear homogenizer.
Step 3 Add required quantity technical and homogenized to get uniform slurry ready for grinding.
Step 4 Now material is subjected to grinding in Bead mill till desired particle size is achieved.
Step 5 After grinding process completes the material is sprayed at required temperature.
Step 6 After completion of spray drying process material is collected and sent for QC department approval.
Step 7 After approval material is packed in required pack sizes.

EXAMPLE 6:
Most preferred formulations:
Compound A-SDHI Fungicide Compound B- Fungicide
(s) Compound C-Plant Health additive Active ingredients (%) Formulation Strength (%) Formulation Type
Compound A Compound B Compound C
Thifluzamide Picoxystrobin Ortho silicic acid 10 10 4 24.00 OD
Thifluzamide Pyraclostrobin Ortho silicic acid 5 5 2 12.00 ZC
Thifluzamide Trifloxystrobin Ortho silicic acid 5 5 2 12.00 ZC
Thifluzamide Azoxystrobin Ortho silicic acid 10 10 4 24.00 OD
Fluxapyroxad Picoxystrobin Ortho silicic acid 16 10 4 30.00 OD
Fluxapyroxad Pyraclostrobin Ortho silicic acid 8 5 2 15.00 ZC
Fluxapyroxad Trifloxystrobin Ortho silicic acid 8 5 2 15.00 ZC
Fluxapyroxad Azoxystrobin Ortho silicic acid 16 10 4 30.00 SC
Fluxapyroxad Difenoconazole Salicylic acid 15 10 4 29.00 OD
Fluxapyroxad Tebuconazole Salicylic acid 15 10 4 29.00 OD
Fluxapyroxad Prothioconazole Salicylic acid 7.5 5 2 14.50 ZC
Fluxapyroxad Cyproconazole Salicylic acid 15 10 4 29.00 OD
Fluxapyroxad Epoxiconazole Salicylic acid 7.5 5 2 14.50 ZC
Thifluzamide Difenoconazole Zinc 15 20 5 40.00 SC
Thifluzamide Tebuconazole Zinc 15 20 5 40.00 SC
Thifluzamide Prothioconazole Zinc 15 20 5 40.00 SC
Thifluzamide Azoxystrobin Zinc 15 20 5 40.00 SC
Thifluzamide Copper Zinc 5 50 5 60.00 WG
Thifluzamide Mancozeb Zinc 5 60 5 70.00 WG
Thifluzamide Propineb Zinc 5 60 5 70.00 WG
Thifluzamide Chlorothalonil Zinc 5 60 5 70.00 WG
Fluxapyroxad Copper Zinc 5 50 5 60.00 WG
Fluxapyroxad Mancozeb Zinc 5 60 5 70.00 WG
Fluxapyroxad Propineb Zinc 5 60 5 70.00 WG
Fluxapyroxad Chlorothalonil Zinc 5 60 5 70.00 WG
Bixafen Picoxystrobin Brassinolide 16 10 0.05 26.05 SC
Bixafen Pyraclostrobin Brassinolide 8 5 0.025 13.03 ZC
Bixafen Trifloxystrobin Brassinolide 8 5 0.025 13.03 ZC
Bixafen Difenoconazole Brassinolide 16 10 0.05 26.05 SC
Bixafen Tebuconazole Brassinolide 8 5 0.025 13.03 ZC
Bixafen Prothioconazole Brassinolide 8 5 0.025 13.03 ZC
Thifluzamide Metyltetraprole Ortho silicic acid 5 10 2 17.00 SC
Thifluzamide Tebufloquin Ortho silicic acid 5 10 2 17.00 SC
Thifluzamide Tolprocarb Ortho silicic acid 5 10 2 17.00 SC
Thifluzamide Quinofumelin Ortho silicic acid 5 10 2 17.00 SC
Thifluzamide Dichlorobentiazox Ortho silicic acid 5 10 2 17.00 SC
Thifluzamide Dipymetitrone Ortho silicic acid 5 10 2 17.00 SC
Thifluzamide Fluoxapipronil Ortho silicic acid 5 10 2 17.00 SC
Fluxapyroxad Metyltetraprole Fulvic acid 7.5 8 2.5 18.00 SC
Fluxapyroxad Tebufloquin Fulvic acid 7.5 8 2.5 18.00 SC
Fluxapyroxad Tolprocarb Fulvic acid 7.5 8 2.5 18.00 SC
Fluxapyroxad Quinofumelin Fulvic acid 7.5 8 2.5 18.00 SC
Fluxapyroxad Dichlorobentiazox Fulvic acid 7.5 8 2.5 18.00 SC
Fluxapyroxad Dipymetitrone Fulvic acid 7.5 8 2.5 18.00 SC
Fluxapyroxad Fluoxapipronil Fulvic acid 7.5 8 2.5 18.00 SC
Inpyrfluxam Azoxystrobin Carboxylic acid 10 15 3 28.00 SC
Isopyrazam Azoxystrobin Carboxylic acid 10 15 3 28.00 SC
Penthiopyrad Azoxystrobin Carboxylic acid 12 10 3 25.00 SC
Sedaxane Azoxystrobin Carboxylic acid 10 12 3 25.00 SC
Flubeneteram Azoxystrobin Carboxylic acid 8 15 3 26.00 SC
Isoflucypram Azoxystrobin Carboxylic acid 10 15 3 28.00 SC
Boscalid Azoxystrobin Carboxylic acid 15 10 3 28.00 SC
Pyraziflumid Azoxystrobin Carboxylic acid 8 15 3 26.00 SC
Fluindapyr Azoxystrobin Carboxylic acid 10 15 3 28.00 SC
Pyrapropopyne Azoxystrobin Carboxylic acid 10 15 3 28.00 SC
Benzovindiflupyr Azoxystrobin Carboxylic acid 12 15 3 30.00 SC
Pydiflumetofen Azoxystrobin Carboxylic acid 12 15 3 30.00 SC
Inpyrfluxam Mancozeb Zinc 8 60 5 73.00 WG
Isopyrazam Mancozeb Zinc 8 60 5 73.00 WG
Penthiopyrad Mancozeb Zinc 8 60 5 73.00 WG
Sedaxane Mancozeb Zinc 8 60 5 73.00 WG
Flubeneteram Mancozeb Zinc 6 60 5 71.00 WG
Isoflucypram Mancozeb Zinc 8 60 5 73.00 WG
Boscalid Mancozeb Zinc 10 60 5 75.00 WG
Pyraziflumid Mancozeb Zinc 6 60 5 71.00 WG
Fluindapyr Mancozeb Zinc 8 60 5 73.00 WG
Pyrapropopyne Mancozeb Zinc 8 60 5 73.00 WG
Benzovindiflupyr Mancozeb Zinc 10 60 5 75.00 WG
Pydiflumetofen Mancozeb Zinc 10 60 5 75.00 WG

BIOLOGICAL EXAMPLES:
A synergistic effect exists wherever the action of a combination of active ingredient is greater than the sum of the action of each of the components alone. Therefore, a synergistically effective amount or an effective amount of a synergistic composition or combination is an amount that exhibits greater pesticidal activity than the sum of the pesticidal activities of the individual components.
In the field of agriculture, it is often understood that the term “synergy” is as defined by Colby S.R. in an article entitled “ Calculation of the synergistic and antagonistic responses of herbicide combinations” published in the journal Weeds, 1967, 15, p.20-22, incorporated herein by reference in its entirety. The action expected for a given combination of two or three active components can be calculated as follows:

FIELD BIO-EFFICACY STUDIES:
Field experiments of innovative combinations / ready-mix formulations comprising of (A) SDHI (Succinate dehydrogenase inhibitors); (B) at least one more fungicide selected from the class of QoI (Quinone outside Inhibitors), QiI-fungicides (Quinone inside Inhibitors), Lipid or transport and membrane synthesis inhibitors, Sterol biosynthesis Inhibitors, Melanin synthesis in cell wall Inhibitors, compound with unknow mode of action, multisite contact fungicides, Ipflufenoquin, Pyridachlometyl; (C) At least one more compound from plant health additive, were carried out in different crops to study the synergism and their benefits.
EXAMPLE 07:
Experiment 1: Disease control in Paddy/rice crop
Crops & Varieties : Paddy, MTU 7029
Location : Burdwan, West Bengal
Treatments : 20
Plot size : 6m x 5 m
Time of Application : 40 days after transplanting. Applied 2 sprays at 15 days interval.
Method of Application: Foliar spray with knapsack sprayer fitted with hollow cone nozzle.
Water volume : 500 liter per hectare.
Agronomic Practices : All other agronomic practices for weed control, insect control was followed ss per the requirement.
Observation Methods:
% Sheath blight control : Observations was recorded on disease severity in each treatment before and at 14 days after spray. The observations of severity of sheath blight disease were recorded using 0-9 grade (SES,IRRI 1996). Twenty randomly selected hills were scored as per scale. The percent disease index (PDI) of plants was calculated by the following formula.


Sheath blight disease Grading (0-9 scale) :
Grade Symptoms
0 No incidence
1 Less than 1% sheath area infected
3 1-5% sheath area infected
5 6-25% sheath area infected
7 26-50% sheath area infected
9 51-100% sheath area infected

% Grain discoloration: Count the number of healthy and diseased grains per panicle. Record the observations from 10 panicles randomly selected per plot. Calculate % grain discoloration and % disease control.
The % disease control data used in Colby’s formula to calculate the synergism.
Table 1.Treatment details
Treatment number Treatment details with application Rate (ml or g per Hectare)
T1 Thifluzamide 10%+Picoxystrobin 10%+Orthosilicic acid 4% OD-500 ml (ready-mix)
T2 Thifluzamide 5%+Pyraclostrobin 5%+Orthosilicic acid 2% ZC-1000 ml (ready-mix)
T3 Thifluzamide 5%+Trifloxystrobin 5%+Orthosilicic acid 2% ZC-1000 ml (ready-mix)
T4 Thifluzamide 10%+Azoxystrobin 10%+Orthosilicic acid 4% OD-500 ml (ready-mix)
T5 Ortho silicic acid 2% WP-1000 g+Picoxystrobin 22.52% w/w SC-200 ml (prior art)
T6 Ortho silicic acid 2% WP-1000 g+Pyraclostrobin 20% WG-250 g (prior art)
T7 Ortho silicic acid 2% WP-1000 g+Trifloxystrobin 25% WG-200 g (prior art)
T8 Ortho silicic acid 2% WP-1000 g+Azoxystrobin 23% w/w SC-200 ml (prior art)
T9 Thifluzamide 24% SC-208.3 ml+Picoxystrobin 22.52% w/w SC-200 ml (prior art)
T10 Thifluzamide 24% SC-208.3 ml+Pyraclostrobin 20% WG-250 g (prior art)
T11 Thifluzamide 24% SC-208.3 ml+Trifloxystrobin 25% WG-200 g (prior art)
T12 Thifluzamide 24% SC-208.3 ml+Azoxystrobin 23% w/w SC-200 ml (prior art)
T13 Thifluzamide 24% SC-208.3 ml+Ortho silicic acid 2% WP-1000 g (prior art)
T14 Picoxystrobin 22.52% w/w SC-200 ml
T15 Pyraclostrobin 20% WG-250 g
T16 Trifloxystrobin 25% WG-200 g
T17 Azoxystrobin 23% w/w SC-200 ml
T18 Ortho silicic acid 2% WP-1000 g
T19 Thifluzamide 24% SC-208.3 ml
T20 UTC (Untreated Check)
Picoxystrobin 22.52% w/w (25% w/v) SC, Azoxystrobin 23% w/w (25% w/v) SC

Table 2.
Efficacy against paddy sheath blight (Rhizoctonia solani), grain discoloration (Rhizoctonia spp., Alternaria spp., Helminthosporium spp., Curvularia spp. Etc.)
Treatment number % Sheath blight control % Grain discoloration control Synergism (Y/N) Grain yield (kg/plot)
Obs. Value Cal. Value Colby/s Ratio O/E Obs. Value Cal. Value Colby/s Ratio O/E
T1 98.6 88.45 1.11 98.2 86.94 1.13 Y 16.2
T2 97.4 87.42 1.11 97.6 86.14 1.13 Y 15.9
T3 99.2 88.09 1.13 96.4 85.64 1.13 Y 16.4
T4 97.4 88.63 1.10 96.4 87.08 1.11 Y 16.7
T5 64.6 66.61 0.97 64.4 66.84 0.96 N 12.2
T6 62.2 63.64 0.98 62.6 64.83 0.97 N 11.8
T7 63.8 65.56 0.97 61.6 63.54 0.97 N 12.4
T8 65.8 67.14 0.98 65.6 67.21 0.98 N 12.6
T9 85.4 86.78 0.98 84.8 85.74 0.99 N 13.6
T10 83.4 85.61 0.97 83.6 84.87 0.99 N 13.1
T11 85 86.37 0.98 83.8 84.32 0.99 N 14.2
T12 84.4 86.99 0.97 84.4 85.89 0.98 N 14.6
T13 68.6 69.76 0.98 62.8 63.91 0.98 N 11.2
T14 61.8 63.8 10.3
T15 58.4 61.6 9.9
T16 60.6 60.2 10.2
T17 62.4 64.2 9.2
T18 12.6 8.4 8.6
T19 65.4 60.6 10.4
T20 0.0 0.0 8.1

All the ready-mix combinations (T1, T2, T3 and T4) shows synergistic efficacy (Colby’s ratio > 1) against sheath blight and grain discoloration disease and yielded higher grain in comparison to all prior art treatments (T5 to T13).
EXAMPLE 08:
Experiment 2: Disease control in chilly crop
Crops & Varieties : Chilly, Nisha
Location : Umreth, Gujarat
Treatments : 20
Plot size : 6m x 4 m
Time of Application : 75 days after transplanting. Applied 2 sprays at 15 days interval.
Method of Application: Foliar spray with knapsack sprayer fitted with hollow cone nozzle.
Water volume : 500 liter per hectare.
Agronomic Practices : All other agronomic practices for weed control, insect control was followed ss per the requirement.
Observation Methods:
% Die-back (Colletotrichum capsici) disease control- Observe randomly selected 10 plants per plot and rate disease severity (0-9 grade) of 5 twigs per plant. Calculate disease severity (PDI) and % disease control.
% Fruit rot (Colletotrichum capsici) disease control-Count the number of healthy and diseased fruits per plant. Observe such 10 plants per plot and calculate % disease control (i.e. reduction in fruit rot disease).
Calculate synergism by using % disease control data.
Healthy Fruit Count-Count the number of healthy fruits per plant. Record such observations from 10 plants per plot.

Table 3.
Treatment details for bio efficacy against chilly disease.
Treatment number Treatment details with application Rate (ml or g per Hectare)
T1 Fluxapyroxad 12%+Picoxystrobin 15%+Orthosilicic acid 4% OD-500 ml (ready-mix)
T2 Fluxapyroxad 12%+Pyraclostrobin 15%+Orthosilicic acid 4% SE-500 ml (ready-mix)
T3 Fluxapyroxad 12%+Trifloxystrobin 15%+Orthosilicic acid 4% SE-500 ml (ready-mix)
T4 Fluxapyroxad 12%+Azoxystrobin 15%+Orthosilicic acid 4% OD-500 ml (ready-mix)
T5 Ortho silicic acid 2% WP-1000 g+Picoxystrobin 22.52% w/w SC-300 ml (prior art)
T6 Ortho silicic acid 2% WP-1000 g+Pyraclostrobin 20% WG-375 g (prior art)
T7 Ortho silicic acid 2% WP-1000 g+Trifloxystrobin 25% WG-300 g (prior art)
T8 Ortho silicic acid 2% WP-1000 g+Azoxystrobin 23% w/w SC-300 ml (prior art)
T9 Fluxapyroxad 25% SC-240 ml+Picoxystrobin 22.52% w/w SC-300 ml (prior art)
T10 Fluxapyroxad 25% SC-240 ml+Pyraclostrobin 20% WG-375 g (prior art)
T11 Fluxapyroxad 25% SC-240 ml+Trifloxystrobin 25% WG-300 g (prior art)
T12 Fluxapyroxad 25% SC-240 ml+Azoxystrobin 23% w/w SC-300 ml (prior art)
T13 Fluxapyroxad 25% SC-240 ml+Ortho silicic acid 2% WP-1000 g (prior art)
T14 Picoxystrobin 22.52% w/w SC-300 ml
T15 Pyraclostrobin 20% WG-375 g
T16 Trifloxystrobin 25% WG-300 g
T17 Azoxystrobin 23% w/w SC-300 ml
T18 Ortho silicic acid 2% WP-1000 g
T19 Fluxapyroxad 25% SC-240 ml
T20 UTC (Untreated Check)
Picoxystrobin 22.52% w/w (25% w/v) SC, Azoxystrobin 23% w/w (25% w/v) SC
Table 4.
Bio efficacy against chilly diseases.
Treatment number % Die-back disease control % Fruit rot control Synergism (Y/N) Number of healthy fruits/plants yield (kg/plot)
Obs. Value Cal. Value Colby/s Ratio O/E Obs. Value Cal. Value Colby/s Ratio O/E
T1 94.4 84.59 1.12 92 82.05 1.12 Y 56.6
T2 95.8 85.02 1.13 93.2 82.90 1.12 Y 58.6
T3 92.2 83.87 1.10 90.6 81.20 1.12 Y 55.2
T4 96.2 84.88 1.13 94.2 82.51 1.14 Y 57.8
T5 58.4 60.88 0.96 54.6 56.85 0.96 N 42.4
T6 60.2 61.98 0.97 56.6 58.89 0.96 N 43.2
T7 57.6 59.05 0.98 52.4 54.81 0.96 N 40.6
T8 60.4 61.61 0.98 55.8 57.96 0.96 N 44.2
T9 82.2 83.14 0.99 76.4 80.61 0.95 N 48.6
T10 81.6 83.61 0.98 78.8 81.53 0.97 N 49.2
T11 80.4 82.35 0.98 74.6 79.70 0.94 N 47.2
T12 82.8 83.45 0.99 80.4 81.11 0.99 N 50.4
T13 61.4 63.99 0.96 57.6 61.48 0.94 N 45.6
T14 57.2 53.4 37.2
T15 58.4 55.6 38.4
T16 55.2 51.2 35.6
T17 58 54.6 39.6
T18 8.6 7.4 29.8
T19 60.6 58.4 40.6
T20 0.0 0.0 26.4

All the tested ready-mixcombinations (T1, T2, T3 and T4) shows excellent synergistic efficacy against chillydie-back and fruit rot disease compared to all the prior arts treatments (T5 to T13). Due to synergistic efficacy of combinations against fruit rot diseases, higher fruit yield (healthy fruits/plant) were obtained. The synergistic activities were also noticed through visual observations, means the plant vigor, number of branched, number of fruits, number of flowers, fruit color, shape and size were excellent (means better, higher or more) in innovative synergistic combinations compared to all prior art treatments.

EXAMPLE 09:
Experiment 3-Bioefficacy against tomato diseases
Crops & Varieties : Tomato, Himsikhar
Location : Umreth, Gujarat
Treatments : 20
Plot size : 6m x 4 m
Time of Application : 80 days after transplanting. Applied 2 sprays at 15 days interval.
Method of Application: Foliar spray with knapsack sprayer fitted with hollow cone nozzle.
Water volume : 550 liter per hectare.
Agronomic Practices : All other agronomic practices for weed control, insect control was followed ss per the requirement.
Observation Methods:
% Early blight (Alternaria solani) disease control- Observe randomly selected 100 leaflet per plot and rate disease severity (0-9 grade). Calculate disease severity (PDI) and % disease control.
% Leaf spot (Septoria lycopersici)disease control-Observe randomly selected 100 leaflet per plot and rate disease severity (0-9 grade). Calculate disease severity (PDI) and % disease control.
Calculate synergism by using % disease control data.
Healthy Fruit Count-Count the number of healthy fruits per plant. Record such observations from 10 plants per plot.
Table 5.
Treatment details for bio efficacy against tomato diseases.
Treatment number Treatment details with application Rate (ml or g per Hectare)
T1 Thifluzamide 15%+Difenoconazole 20%+Zinc 5% SC-500 ml (ready-mix)
T2 Thifluzamide 15%+Tebuconazole 20%+Zinc 5% SC-500 ml (ready-mix)
T3 Thifluzamide 15%+Prothioconazole 20%+Zinc 5% SC-500 ml (ready-mix)
T4 Thifluzamide 15%+Azoxystrobin 20%+Zinc 5% SC-500 ml (ready-mix)
T5 Zinc 12% WP-208.3 g+Difenoconazole 25% EC-400 ml (prior art)
T6 Zinc 12% WP-208.3 g+Tebuconazole 25% WG-400 g (prior art)
T7 Zinc 12% WP-208.3 g+Prothioconazole 25% EC-400 ml (prior art)
T8 Zinc 12% WP-208.3 g+Azoxystrobin 23% w/w SC-400 ml (prior art)
T9 Thifluzamide 24% SC-312.5 ml+Difenoconazole 25% EC-400 ml (prior art)
T10 Thifluzamide 24% SC-312.5 ml+Tebuconazole 25% WG-400 g (prior art)
T11 Thifluzamide 24% SC-312.5 ml+Prothioconazole 25% EC-400 ml (prior art)
T12 Thifluzamide 24% SC-312.5 ml+Azoxystrobin 23% w/w SC-400 ml (prior art)
T13 Thifluzamide 24% SC-312.5 ml+Zinc 12% WP-208.3 g (prior art)
T14 Difenoconazole 25% EC-400 ml
T15 Tebuconazole 25% WG-400 g
T16 Prothioconazole 25% EC-400 ml
T17 Azoxystrobin 23% w/w SC-400 ml
T18 Zinc 12% WP-208.3 g
T19 Thifluzamide 24% SC-312.5 ml
T20 UTC (Untreated Check)

Table 6.
Bio efficacy against tomato diseases.
Treatment number % Early blight disease control % Leaf spot diseasecontrol Synergism (Y/N) Number of Healthy Fruits per plant
Obs. Value Cal. Value Colby's Ratio Obs. Value Cal. Value Colby's Ratio
T1 97.8 87.13 1.12 93.2 83.09 1.12 Y 38.6
T2 96.4 86.89 1.11 96.2 85.00 1.13 Y 35.2
T3 98.2 86.70 1.13 94.8 85.83 1.10 Y 34.6
T4 98.6 87.75 1.12 97.6 86.37 1.13 Y 37.4
T5 60.6 61.71 0.98 56.8 58.35 0.97 N 24.4
T6 59.2 60.98 0.97 61.4 63.04 0.97 N 25.6
T7 58.2 60.43 0.96 63.8 65.11 0.98 N 24.8
T8 62.4 63.54 0.98 65.2 66.42 0.98 N 25.6
T9 84.4 85.96 0.98 80.6 81.97 0.98 N 29.4
T10 83.6 85.69 0.98 82.4 84.00 0.98 N 30.6
T11 83.2 85.48 0.97 83.4 84.90 0.98 N 28.4
T12 84.6 86.63 0.98 82.8 85.47 0.97 N 31.2
T13 67.8 69.22 0.98 60.8 61.92 0.98 N 28.6
T14 58.2 55.6 19.8
T15 57.4 60.6 20.4
T16 56.8 62.8 21.6
T17 60.2 64.2 23.4
T18 8.4 6.2 17.4
T19 66.4 59.4 22.6
T20 0.0 0.0 15.6

All the tested ready-mix combinations (T1, T2, T3 and T4) shows excellent synergistic efficacy against tomato early blight and septoria leaf spot disease and also produces higher number of healthy fruits compared to all the prior arts treatments (T5 to T13). The synergistic activities were also noticed through visual observations, means the plant vigor, number of branched, number of fruits, number of flowers, fruit color, shape and size were excellent (means better, higher or more) in innovative synergistic combinations compared to all prior art treatments.

EXAMPLE 10:
Experiment 4: Disease control in Paddy/rice crop
Crops & Varieties : Paddy, Swarna
Location : Raipur, Chhattisgarh
Treatments : 20
Plot size : 6m x 5 m
Time of Application : 45 days after transplanting. Applied 2 sprays at 15 days interval.
Method of Application: Foliar spray with knapsack sprayer fitted with hollow cone nozzle.
Water volume : 500 liter per hectare.
Agronomic Practices : All other agronomic practices for weed control, insect control was followed ss per the requirement.
Observation Methods:
% Sheath blight control : Same as per Experiment 1.
% Grain discoloration control : Same as per Experiment 2.

Table 7.
Treatment details
Treatment number Treatment details with application Rate (ml or g per Hectare)
T1 Fluxapyroxad 15%+Difenoconazole 10%+Salicylic acid 4% OD-500 ml (ready-mix)
T2 Fluxapyroxad 15%+Tebuconazole 10%+Salicylic acid 4% OD-500 ml (ready-mix)
T3 Fluxapyroxad 7.5%+Prothioconazole 5%+Salicylic acid 2% ZC-1000 ml (ready-mix)
T4 Fluxapyroxad 15%+Cyproconazole 10%+Salicylic acid 4% OD-500 ml (ready-mix)
T5 Salicylic acid 2% WP-1000 g+Difenoconazole 25% EC-200 ml (prior art)
T6 Salicylic acid 2% WP-1000 g+Tebuconazole 25% WG-200 g (prior art)
T7 Salicylic acid 2% WP-1000 g+Prothioconazole 25% EC-200 ml (prior art)
T8 Salicylic acid 2% WP-1000 g+Cyproconazole 25% EC-200 ml (prior art)
T9 Fluxapyroxad 25% SC-300 ml+Difenoconazole 25% EC-200 ml(prior art)
T10 Fluxapyroxad 25% SC-300 ml+Tebuconazole 25% WG-200 g(prior art)
T11 Fluxapyroxad 25% SC-300 ml+Prothioconazole 25% EC-200 ml(prior art)
T12 Fluxapyroxad 25% SC-300 ml+Cyproconazole 25% EC-200 ml(prior art)
T13 Fluxapyroxad 25% SC-300 ml+Salicylic acid 2% WP-1000 g (prior art)
T14 Difenoconazole 25% EC-200 ml
T15 Tebuconazole 25% WG-200 g
T16 Prothioconazole 25% EC-200 ml
T17 Cyproconazole 25% EC-200 ml
T18 Salicylic acid 2% WP-1000 g
T19 Fluxapyroxad 25% SC-300 ml
T20 UTC (Untreated Check)

Table 8.
Bio efficacy against rice diseases.
Treatment number % Sheath blight control % Grain discoloration control Syner
gism (Y/N) Grain yield (kg/plot)
Obs. Value Cal. Value Colby's Ratio Obs. Value Cal. Value Colby's Ratio
T1 97.4 89.01 1.09 98.4 88.78 1.11 Y 16.8
T2 95.6 88.24 1.08 97.6 87.95 1.11 Y 16.6
T3 98.8 89.19 1.11 99.6 88.50 1.13 Y 17.1
T4 94.4 88.66 1.06 95.2 87.33 1.09 Y 16.3
T5 64.8 67.49 0.96 68.4 70.32 0.97 N 11.8
T6 63.6 65.21 0.98 66.6 68.12 0.98 N 11.7
T7 66.2 68.01 0.97 68.2 69.59 0.98 N 12.2
T8 63.8 66.44 0.96 65.4 66.47 0.98 N 11.3
T9 86.8 87.43 0.99 86.2 87.75 0.98 N 13.6
T10 85.2 86.55 0.98 85.4 86.85 0.98 N 13.2
T11 85.8 87.63 0.98 85.8 87.45 0.98 N 13.9
T12 84.6 87.02 0.97 84.2 86.17 0.98 N 12.8
T13 68.6 70.46 0.97 64.0 65.38 0.98 N 11.5
T14 62.8 67.6 9.6
T15 60.2 65.2 9.3
T16 63.4 66.8 10.2
T17 61.6 63.4 9.1
T18 12.6 8.4 7.8
T19 66.2 62.2 9.8
T20 0.0 0.0 7.2

The ready-mix combinations (T1, T2, T3 and T4) shows excellent synergistic efficacy against rice sheath blight and grains discoloration and also produces higher grain yield compared to all the prior arts treatments (T5 to T13).

EXAMPLE 11:
Experiment 5: Potato early blight disease control
Crops & Varieties : Potato, Locker
Location : Deesa, Gujarat
Treatments : 20
Plot size : 10 m x 4 m
Time of Application : 50 days after transplanting. Applied 2 sprays at 10 days interval.
Method of Application: Foliar spray with knapsack sprayer fitted with hollow cone nozzle.
Water volume : 500 liter per hectare.
Agronomic Practices : All other agronomic practices for weed control, insect control was followed ss per the requirement.
Observation Methods:
% Early blight (Alternaria solani) control : Same as per Experiment 3.
Table 9.
Treatment details
Treatment number Treatment details with application Rate (ml or g per Hectare)
T1 Fluxapyroxad 5%+Copper 50%+Zinc 5% WG-1250 g (ready mix)
T2 Fluxapyroxad 5%+Mancozeb 60%+Zinc 5% WG-1250 g (ready mix)
T3 Fluxapyroxad 5%+Propineb 60%+Zinc 5% WG-1250 g (ready mix)
T4 Fluxapyroxad 5%+Chlorothalonil 60%+Zinc 5% WG-1250 g (ready mix)
T5 Copper Oxychloride 50% WP-1250 g+Zinc 12% WP-520.8 g (prior art)
T6 Mancozeb 75% WP-1000 g+Zinc 12% WP-520.8 g (prior art)
T7 Propineb 70% WP-1071 g+Zinc 12% WP-520.8 g (prior art)
T8 Chlorothalonil 75% WP-1000 g+Zinc 12% WP-520.8 g (prior art)
T9 Fluxapyroxad 25% SC-250 ml+Copper Oxychloride 50% WP-1250 g (prior art)
T10 Fluxapyroxad 25% SC-250 ml+Mancozeb 75% WP-1000 g (prior art)
T11 Fluxapyroxad 25% SC-250 ml+Propineb 70% WP-1071 g (prior art)
T12 Fluxapyroxad 25% SC-250 ml+Chlorothalonil 75% WP-1000 g (prior art)
T13 Fluxapyroxad 25% SC-250 ml+Zinc 12% WP-520.8 g (prior art)
T14 Copper Oxychloride 50% WP-1250 g
T15 Mancozeb 75% WP-1000 g
T16 Propineb 70% WP-1071 g
T17 Chlorothalonil 75% WP-1000 g
T18 Zinc 12% WP-520.8 g
T19 Fluxapyroxad 25% SC-250 ml
T20 UTC (Untreated Check)

Table 10.
Bio efficacy against Potato Early blight disease
Treatment number % Early blight disease control Synergism (Y/N)
Observed Value Calculated Value Colby's Ratio (Observed value/
Calculated value)
T1 92.2 84.87 1.09 Y
T2 95.2 85.95 1.11 Y
T3 94.6 85.55 1.11 Y
T4 93.2 85.35 1.09 Y
T5 57.2 59.77 0.96 N
T6 60.8 62.64 0.97 N
T7 60.2 61.57 0.98 N
T8 58.4 61.03 0.96 N
T9 81.6 83.16 0.98 N
T10 82.6 84.36 0.98 N
T11 81.8 83.91 0.97 N
T12 82.0 83.68 0.98 N
T13 65.2 66.24 0.98 N
T14 55.2
T15 58.4
T16 57.2
T17 56.6
T18 10.2
T19 62.4
T20 0.0
The ready-mix treatments (T1, T2, T3 and T4) provides synergistic control of early blight disease of potato in comparison to all prior art treatments (T5 to T13).

EXAMPLE 12:
Experiment 6: Disease control in Groundnut
Crops & Varieties : Groundnut, GG-2
Location : Idar, Gujarat
Treatments : 28
Plot size : 8m x 4 m
Time of Application : 75 days after sowing. Applied 2 sprays at 15 days interval.
Method of Application: Foliar spray with knapsack sprayer fitted with hollow cone nozzle.
Water volume : 500 liter per hectare.
Agronomic Practices : All other agronomic practices for weed control, insect control was followed ss per the requirement.
Observation Methods:
% Leaf spot/Tikka disease (Cercospora arachidicola): Observe randomly selected 100 leaflet per plot and rate disease severity (0-9 grade). Calculate disease severity (PDI) and % disease control.
% Rust disease control (Puccinia arachidis): Observe randomly selected 100 leaflet per plot and rate disease severity (0-9 grade). Calculate disease severity (PDI) and % disease control.
Calculate synergism by using % disease control data.
Pod count at harvest-Count the number of pods per plant at the time of harvest. Record such observations from 10 plants per plot and workout the average.
Table 11.
Treatment details for bio efficacy against groundnut diseases
Treatment number Treatment details with application Rate (ml or g per Hectare)
T1 Bixafen 16%+Picoxystrobin 10%+Brassinolide 0.05% SC-500 ml (ready-mix)
T2 Bixafen 8%+Pyraclostrobin 5%+Brassinolide 0.025% ZC-1000 ml (ready-mix)
T3 Bixafen 8%+Trifloxystrobin 5%+Brassinolide 0.025% ZC-1000 ml (ready-mix)
T4 Bixafen 16%+Difenoconazole 10%+Brassinolide 0.05% SC-500 ml (ready-mix)
T5 Bixafen 8%+Tebuconazole 5%+Brassinolide 0.025% ZC-1000 ml (ready-mix)
T6 Bixafen 8%+Prothioconazole 5%+Brassinolide 0.025% SC-1000 ml (ready-mix)
T7 Picoxystrobin 25% WG-200 g+Brassinolide 0.1% L-250 ml (prior art)
T8 Pyraclostrobin 20% WG-250 g+Brassinolide 0.1% L-250 ml (prior art)
T9 Trifloxystrobin 25% WG-200 g+Brassinolide 0.1% L-250 ml (prior art)
T10 Difenoconazole 25% EC-200 ml+Brassinolide 0.1% L-250 ml (prior art)
T11 Tebuconazole 25% WG-200 g+Brassinolide 0.1% L-250 ml (prior art)
T12 Prothioconazole 25% EC-200 ml+Brassinolide 0.1% L-250 ml (prior art)
T13 Bixafen 12.5% EC-640 ml+Picoxystrobin 25% WG-200 g (prior art)
T14 Bixafen 12.5% EC-640 ml+Pyraclostrobin 20% WG-250 g (prior art)
T15 Bixafen 12.5% EC-640 ml+Trifloxystrobin 25% WG-200 g (prior art)
T16 Bixafen 12.5% EC-640 ml+Difenoconazole 25% EC-200 ml (prior art)
T17 Bixafen 12.5% EC-640 ml+Tebuconazole 25% WG-200 g (prior art)
T18 Bixafen 12.5% EC-640 ml+Prothioconazole 25% EC-200 ml (prior art)
T19 Bixafen 12.5% EC-640 ml+Brassinolide 0.1% L-250 ml (prior art)
T20 Picoxystrobin 25% WG-200 g
T21 Pyraclostrobin 20% WG-250 g
T22 Trifloxystrobin 25% WG-200 g
T23 Difenoconazole 25% EC-200 ml
T24 Tebuconazole 25% WG-200 g
T25 Prothioconazole 25% EC-200 ml
T26 Brassinolide 0.1% L-250 ml
T27 Bixafen 12.5% EC-640 ml
T28 UTC (Untreated Check)

Table 12.
Bio efficacy against Groundnut diseases
Treatment number % Leaf spot disease control % Rust disease control Synergism (Y/N) Number of Pods per plant
Obs. Value Cal. Value Colby's Ratio Obs. Value Cal. Value Colby's Ratio
T1 94.2 84.51 1.11 91.2 84.55 1.08 Y 46.8
T2 95.6 85.37 1.12 92.6 85.15 1.09 Y 47.2
T3 93.4 84.04 1.11 92.2 84.10 1.10 Y 45.7
T4 90.4 83.49 1.08 92.6 85.22 1.09 Y 42.8
T5 89.4 82.63 1.08 89.4 84.55 1.06 Y 43.5
T6 91.8 83.72 1.10 90.6 85.52 1.06 Y 44.7
T7 61.6 62.93 0.98 58.8 60.59 0.97 N 33.4
T8 63.8 64.99 0.98 61 62.11 0.98 N 35.2
T9 60.2 61.81 0.97 57.8 59.44 0.97 N 33.7
T10 58.8 60.50 0.97 60.6 62.30 0.97 N 31.6
T11 57.2 58.44 0.98 58.8 60.59 0.97 N 30.8
T12 59.8 61.06 0.98 62 63.06 0.98 N 29.8
T13 81.2 83.45 0.97 81.4 83.77 0.97 N 38.7
T14 82.4 84.37 0.98 82.6 84.40 0.98 N 36.9
T15 81.2 82.95 0.98 81.6 83.30 0.98 N 39.4
T16 80.8 82.36 0.98 82.2 84.48 0.97 N 38.6
T17 80.2 81.44 0.98 81.4 83.77 0.97 N 35.7
T18 81.2 82.61 0.98 82.6 84.79 0.97 N 39.1
T19 59.8 60.88 0.98 60.8 62.68 0.97 N 38.2
T20 60.4 58.6 25.8
T21 62.6 60.2 26.7
T22 59.2 57.4 28.7
T23 57.8 60.4 25.6
T24 55.6 58.6 24.9
T25 58.4 61.2 25.6
T26 6.4 4.8 19.6
T27 58.2 60.8 26.4
T28 0.0 0.0 16.8

All the ready-mix treatment (T1 to T6) provides synergistic control of leaf spot/tikka disease and rust disease control in groundnut and also produces higher number of pods per plant in comparison to all prior art treatments (T7 to T19).

Whereas, in all bioefficacy study cm-centimetre, m- meter, g-gram, kg-kilogram, ml-millilitre, sq.mt. square meter (m2), DASDays after sowing, DAP Days after planting, DATP Days after transplanting, DAA Days after application, spp.-species, sr.no. series number, Ob. Value-observed value, Cal.Value-calculated value. GR/Gr- Granule/soil applied granule, GR-SLGranule Slow release, SC Suspension concentrate, SE Suspo emulsion, OD Oil dispersion, SL Soluble liquid, WG/WDG-Water dispersible granule, WP Wettable powder, SG Soluble granule, L Liquid, SL Soluble liquid, EC Emulsifiable concentrate.
Visual observations and summary of all bio-efficacy field trials:
The field trials results shows many benefits/advantages of ready mix formulations comprising of (A) A fungicide selected from SDHI (Succinate dehydrogenase inhibitors) group; (B) at least one more fungicide selected from the class of QoI (Quinone outside Inhibitors), QiI-fungicides (Quinone inside Inhibitors), Lipid or transport and membrane synthesis inhibitors, Sterol biosynthesis Inhibitors, Melanin synthesis in cell wall Inhibitors, compound with unknow mode of action, multisite contact fungicides, Ipflufenoquin, Pyridachlometyl or mixture thereof; (C) At least one more compound selected from plant health additive.
All synergistic ready mixtures of the present invention shows excellent field trial results, shows synergistic control of plant diseases, provides higher level of disease control (increase % control), provides effective control of different diseases at a time, provides longer duration of control (residual control), increases plant growth, vigor, height, produces a greater number of tillers, shoots, branches, flowers, fruits, pods, square, bolls, seeds, grains etc. and overall biomass of the crop, which directly increases the yield of the crop.
The increase in bio efficacy, residual control and plant growth were also observed due to novelty and innovation in the recipe of OD (oil dispersion), ZC (mixture of CS and SC), SE (suspo emulsion), SC (suspension concentrate) and WG (wettable granule) formulations.

We claim;

[CLAIM 1].An agrochemical composition comprising:
a. at least one fungicide selected from class of SDHI (Succinate dehydrogenase inhibitors) group in an amount of 0.1 to 35% by weight or mixture thereof;
b. at least one more fungicide selected from the class of QoI (Quinone outside Inhibitors), QiI-fungicides (Quinone inside Inhibitors), Lipid or transport and membrane synthesis inhibitors, Sterol biosynthesis Inhibitors, Melanin synthesis in cell wall Inhibitors, compound with unknow mode of action, multisite contact fungicides, Ipflufenoquin, Pyridachlometyl in an amount of 0.1 to 45% by weight or mixture thereof;
c. one more compound selected from plant health additive or mixture thereof in an amount of 0.001 to 20% by weight or mixture thereof;
d. inactive formulation excipients.

[CLAIM 2]. The agrochemical composition as claimed in claim 1 wherein, the composition comprising:
a. a fungicide from class of SDHI (Succinate dehydrogenase inhibitors) selected from group of phenyl benzamides, phenyl-oxo-ethyl thiophene amid, pyridinyl-ethyl-benzamides, furan carboxamides, oxathincarboxamides, pyrazole-4-carboxamides, pyridine carboxamides or mixture thereof;
b. at least one more fungicide selected from the class of QoI (Quinone outside Inhibitors), QiI-fungicides (Quinone inside Inhibitors), Lipid or transport and membrane synthesis inhibitors, Sterol biosynthesis Inhibitors, Melanin synthesis in cell wall Inhibitors, compound with unknow mode of action, multisite contact fungicides, Ipflufenoquin, Pyridachlometyl or mixture thereof;
c. at least one plant health additive selected from the group consisting of auxin, cytokinin, ethylene modulators, gibberellins, growth inhibitors, growth retardants, growth stimulators, unclassified growth regulators, micronutrients and biostimulants or mixture thereof.

[CLAIM 3]. The agrochemical composition as claimed in claim 1 and claim 2 wherein a fungicide from class of SDHI (Succinate dehydrogenase inhibitors)
from group of phenyl benzamides is selected from benodanil, flutolanil, mepronil;
from group of phenyl-oxo-ethyl thiophene amid is isofetamid;
from group of pyridinyl-ethyl-benzamides is fluopyram;
from group of furan carboxamides is fenfuran;
from group of oxathin carboxamides is selected from carboxin, oxycarboxin, thiazolecarboxamides-thifluzamide;
from group of pyrazole-4-carboxamides is selected from benzovindiflupyr, bixafen, fluindapyr, fluxapyroxad, furametpyr, inpyrfluxam, isopyrazam, penflufen, penthiopyrad, sedaxane, flubeneteram, pyrapropoyne, inpyrfluxam, isoflucypram, pydiflumetofen; from group of pyridine carboxamides is selected from boscalid or pyraziflumid.

[CLAIM 4]. The agrochemical composition as claimed in claim 1 and claim 2 wherein a fungicide
from QoI (Quinone outside Inhibitors) class of fungicides from group of benzyl carbamates is pyribencarb;
from QoI (Quinone outside Inhibitors) class of fungicides from group of dihydrodioxazines is fluoxastrobin;
from QoI (Quinone outside Inhibitors) class of fungicides from group of imidazolinones is fenamidone;
from QoI (Quinone outside Inhibitors) class of fungicides from group of methoxy acrylates may be selected from azoxystrobin, coumoxystrobin, enoxastrobin, flufenoxystrobin, picoxystrobin, pyraoxystrobin;
from QoI (Quinone outside Inhibitors) class of fungicides from group of methoxy carbamates may be selected from pyraclostrobin, pyrametostrobin, triclopyricarb;
from QoI (Quinone outside Inhibitors) class of fungicides from group of methoxyacetamide is mandestrobin;
from QoI (Quinone outside Inhibitors) class of fungicides from group of oximinoacetamides may be selected from dimoxystrobin, fenamistrobin, metominostrobin, orysastrobin;
from QoI (Quinone outside Inhibitors) class of fungicides from group of oximino acetates may be selected from kresoxim methyl, trifloxystrobin;
from QoI (Quinone outside Inhibitors) class of fungicides from group of oxazolidinediones is famoxadone;
from QiI (Quinone inside Inhibitors) class of fungicides from group of cyano imidazole is cyazofamid; from group of sulfamoyltriazol is amisulbrom;
from group of picolinamides is fenpicoxamid, florylpicoxamid; from group of tetrazolinones is metyltetraprole;
from lipid or transport and membrane synthesis inhibitor class of fungicides from group of dithiolanes is isoprothiolane; from group of phosphorthiolates is selected from edifenphos, iprobenfos (IBP), pyrazophos; from group of aromatic hydrocarbons (F3) is selected from biphenyl, chloroneb, dicloran, quintozene, tecnazene, tolcofos methyl, etridiazole; from group of carbamates is selected from iodocarb, propamocarb, prothiocarb; from group of terpene hydrocarbons is extract from Melaleuca arternifolia (tea tree), plant oils (mixtures); eugenol, geraniol, thymol; from group of amphoteric macrolide antifungal is natamycin (pimaricin); from group of piperidinyl thiazole isoxazolines is selected from oxathiapipronil, fluoxapipronil, Fluoxapiprolin-s;
from sterol biosynthesis Inhibitors class of fungicides from group of imidazoles is selected from oxpoconazole, pefurazoate, procloraz, triflumizole, piperazines-triforine, pyridines-pyrifenox, pyrisoxazole, pyrimidines-fenarimo, naurimol, triazoles-azaconazole, bitertanol, bromuconazole, cyproconazole, difenoconazole, diniconazole, epoxiconazole, etaconazole, fenbuconazole, fluquinconazole, flusilazole, frutriafol, hexaconazole, imibenconazole, ipconazole, mefentrifluconazole, metconazole, myclobutanil, penconazole, propiconazole, prothioconazole, simconazole, tebuconazole, tetraconazole, tiradimefon, tiradimenol, triticonazole;
from sterol biosynthesis Inhibitors class of fungicides from group of morpholines is selected from aldimoprh, dedomorph, tridemorph, fenpropimorph; from group of piperidines is selected from fenpropidin, piperalin;
from sterol biosynthesis Inhibitors class of fungicides from group of spiroketal amines is spiroxamine; from amino pyrazolinone is fenpyrazamine; from group of hydroxyanilide is fenhexamid; from group of allaylamines is selected from naftifine, terbinafine, pyributicarb;
from the class Melanin synthesis in cell wall Inhibitors is selected from fthalide, pyroquilon, tricyclazole, diclycymet, carpropamid, fenoxanil, trifluoroethyl, tolprocarb;
fungicides with unknow mode of action is selected from cymoxanil, teclofthalam, -triazoxide, fluslfamide, diclomezine, cyflufenamid, guanindines-dodine, flutianil, ferimzone, tebufloquin, picarbutrazox, validamycin;
from multisite contact fungicides is selected from inorganic-copper (copper hydroxide, copper oxychloride, copper (II) sulphate, Bordeaux mixture, copper salicylate, cuprous oxide), sulphur, dithiocarbamates and relatives-ferbam, mancozeb, maneb, metiram, propineb, thiram, zinc thiazole, zineb, ziram, phthalimides-captan, captafol, folpet, chloronitriles (phthalonitriles)-chlorothalonil, sulfamides-dichlofluanid, tolylfluanid, bisguanidines-guazatine, iminoctadine, triazines-anilazine, quinones (anthraquinones)-dithianon, quinoxalines-chinomethionat/ quino methionate, maleimide-fluoroimide, thiocarbamate-methasulfocarb;
Ipflufenoquin; Pyridachlometyl;

[CLAIM 5]. The agrochemical composition as claimed in claim 1 and claim 2 wherein a plant health additive
from the group of Auxins is selected Indole acetic acid, Indole butyric acid, alpha-naphthyl acetic acid;
from the group of Cytokinins is selected from kinetin, zeatin, 6-benzylaminopurine, dipheylurea, thidiazuron;
from the group of Ethylene modulators is selected from aviglycine, prohexadione, prohexadione calcium, trinexapac, trinexapac-ethyl, aminoethoxyvinylglycine (AVG);
from the group of Gibberellins is selected from gibberelline, gibberellic acid, GA3;
from the group of Growth inhibitors is selected from abscisic acid, chlorpropham, flumetralin, jasmonic acid, maleic hydrazide, mepiquat, mepiquat chloride, mepiquatpentaborate;
from the group of Growth retardants is selected from chlormequat, chlormequat chloride, paclobutrazol, uniconazole-P;
from the group of Growth stimulators is selected from brassinolide, forchlorfenuron, triacontanol, salicylic acid, Nitrophenolate (sodium para-nitrophenolate, ortho-nitrophenolate, sodium-5-nitroguaiacolate), nitrobenzene;
from the group of Micronutrients is selected from Zinc (zinc sulphate heptahydrate ZnSO47H2O, zinc sulphate mono hydrate ZnSO4.H2O, chelated zinc as Zn-EDTA, zinc oxide, Zinc Lactate Gluconate, Zinc Polyflavonoid), Boron (borax-sodium tetraborate, boric acid (H3BO3), di-sodium octa borate tetra hydrate (Na2B8O13.4H2O), di-sodium tetra borate penta hydrate, anhydrous borax, ), Manganese (manganese sulphate), Copper (copper sulphate), Iron (ferrous sulphate, chelated iron as Fe-EDTA), Molybdanum (ammonium molybdate), Magnesium (Magnesium sulphate) or Sulphur (elemental sulphur, boronated sulphur);
from the group of Biostimulants is selected from humic acid, potassium humate, fulvic acid, potassium fulvic acid, amino acid, protein hydrolysates, peptides, organic acid, acetylthioproline, thiazolidine carboxylic acid, jasmonic acid, methyl jasmonate, chitosan, chitin, seaweed extract (Ascophyllumnodosum), polyamines, brassinolide, silicon compound-silicic acid, monosilicic acid, orthosilicic acid, disilicic acid, and pyrosilicic acid, silica nanoparticles (10-100 nm), calcium silicate, potassium silicate, sodium silicate), silicyclic acid, lactic acid, phenyllactic acid, fumaric acid, acibenzolar-s-methyl.

[CLAIM 6]. The agrochemical composition as claimed in claim 1 wherein, the formulation for the said composition is selected from Capsule suspension (CS), Dispersible concentrate (DC), Powder for dry seed treatment (DS), Emulsifiable concentrate (EC), Emulsion, water in oil (EO), Emulsion for seed treatment (ES), Emulsion, oil in water (EW), Flowable suspension/concentrate for seed treatment (FS), Granule/ soil applied (GR), Controlled (Slow or Fast) release granules (CR), Solution for seed treatment (LS), Micro-emulsion (ME), Oil dispersion (OD), Oil miscible flowable concentrate (oil miscible suspension (OF), Oil miscible liquid (OL), Suspension concentrate (= flowable concentrate) (SC), Suspo-emulsion (SE), Water soluble granule (SG), Soluble concentrate (SL), Water soluble powder (SP), Water dispersible granule (WG or WDG), Wettable powder (WP), Water dispersible powder for slurry treatment (WS), A mixed formulation of CS and SC (ZC), A mixed formulation of CS and SE (ZE), A mixed formulation of CS and EW (ZW).

[CLAIM 7]. The agrochemical composition as claimed in claim 1-claim 6 wherein, the preferred composition for the Oil Dispersion (OD) formulation comprises:
i. Oil Dispersion (OD) formulation Thifluzamide 10% + Picoxystrobin 10% + Ortho silicic acid 4%
ii. Oil Dispersion (OD) formulation Thifluzamide 10% + Azoxystrobin 10% + Ortho silicic acid 4%
iii. Oil Dispersion (OD) formulation Fluxapyroxad 16% + Picoxystrobin 10% + Ortho silicic acid 4%
iv. Oil Dispersion (OD) formulation Fluxapyroxad 15% + Difenoconazole 10% + Salicylic acid 4%
v. Oil Dispersion (OD) formulation Fluxapyroxad 15% + Tebuconazole 10% + Salicylic acid 4%
vi. Oil Dispersion (OD) formulation Fluxapyroxad 15% + Cyproconazole 10% + Salicylic acid 4%

[CLAIM 8]. The agrochemical composition as claimed in claim 1 and claim 7,
wherein, the Oil Dispersion (OD) formulation comprises:
i. a fungicide from class of SDHI (Succinate dehydrogenase inhibitors) in an amount of 0.1 to 35% by weight of the composition is selected from Fluxapyroxad and Thifluzamide;
ii. a fungicide in an amount of 0.1 to 45% by weight of the composition selected from Picoxystrobin, Azoxystrobin, Difenoconazole, Tebuconazole and Cyproconazole;
iii. a plant health additive in an amount of 0.001 to 20% by weight selected from Orthosilicic acid and salicylic acid.
iv. Wetting agent in an amount of 2 to 6 % by weight;
v. Dispersing agent in an amount of 2 to 8 % by weight;
vi. Emulsifying agent in an amount of 6 to 10 % by weight;
vii. Stabilizer in an amount of 0.5 to 4% by weight;
viii. Antifoaming agent in an amount of 0.1 to 1.5 % by weight;
ix. Preservative in an amount of 0.1 to 0.5 % by weight;
x. Antifreezing agent in an amount of 2 to 6 % by weight;
xi. Carrier as solvent in an amount of 40 to 70% by weight.

[CLAIM 9]. The agrochemical composition as claimed in claim 8, wherein wetting agent is selected from ethylene oxide/propylene oxide block copolymer, polyaryl phenyl ether phosphate, ethoxylated fatty alcohol, sodium dioctyl sulfosuccinate, sodium lauryl sulfate and sodium dodecyl benzene sulfonate, alkyl diphenyl sulfonates, sodium isopropyl naphthalene sulfonate, alkyl naphthalene sulfonate.

[CLAIM 10]. The agrochemical composition as claimed in claim 8, wherein emulsifying agent is selected from castor oil ethoxylates, alcohol ethoxylates, fatty acid ethoxylates, sorbitan ester ethoxylates, sulphosuccinate, calcium salts of dodecyl benzene sulphonate, alkyl ammonium salts of alkyl benzene sulphonate, alkyl sulphosuccinate salts, ethylene oxide-propylene oxide block copolymers, ethoxylated alkylamines, ethoxylated alkyl phenols, polyoxyethylene sorbitan monolaurate.

[CLAIM 11]. The agrochemical composition as claimed in claim 8, wherein dispersing agent is selected from alkyl sulfonates, alkyl benzene sulfonates, alkyl aryl sulfonates, alkyl phenol alkoxylates, tristyryl phenol ethoxylates, natural or synthetic fatty ethoxylate alcohols, natural or synthetic fatty acid alkoxylates, natural or synthetic fatty alcohols alkoxylates, alkoxylated alcohols (such as n-butyl alcohol poly glycol ether), block copolymers (such as ethylene oxide-propylene oxide block copolymers and ethylene oxide-butylene oxide block copolymers), fatty acid-polyalkylene glycol condensates, polyamine-fatty acid condensates, polyester condensates, salts of polyolefin condensates, sodium ligno sulfonate, sodium ploy carboxylate, EO/PO based copolymer, phenol sulfonate, sodium methyl oleoyl taurate, styrene acrylic acid copolymer, propylene oxide-ethylene oxide-copolymer, polyethylene glycol 2,4,6-tristyrylphenyl ether, tristyryl phenol-poly glycol ether-phosphate, tristyryl phenole with 16 moles EO, tristyryl phenol-poly glycol ether-phosphate, oleyl-polyglycol ether with ethylene oxide, tallow fatty amine polyethylene oxide, nonyl phenol poly glycol ether with 9-10 moles ethylene oxide.

[CLAIM 12]. The agrochemical composition as claimed in claim 8, wherein antifoaming agent is selected from silicone oil, silicone compound, C10~C20 saturated fat acid compounds or C8~C10 aliphatic alcohols compound, silicone antifoam emulsion, dimethyl siloxane, poly dimethyl siloxane, vegetable oil based antifoam, tallow based fatty acids, poly alkylene oxide modified polydimethylsiloxane.

[CLAIM 13]. The agrochemical composition as claimed in claim 8, wherein Carrier as solvent or diluting agent is selected from vegetable or plant or seed oil or its alkylated oil or alkylated oil of vegetable oil, alkylated oil (alkylated vegetable oil) may be methylated or ethylated oil of the vegetable oil, wherein vegetable oil are olive oil, kapok oil, castor oil, papaya oil, camellia oil, palm oil, sesame oil, corn oil, rice bran oil, peanut oil, cotton seed oil, soybean oil, groundnut oil, rapeseed oil, linseed oil, tung oil, sunflower oil, safflower oil, palm (Elaeis guineensis) oil, neem (azadirecha indica) oil, eucalyptus oil, karanja (Milletia pinnata/Pongamia pinnata) oil, coconut oil, alkyl ester of vegetable oils, (e.g. rapeseed oil methyl ester or rapeseed oil ethyl ester, rapeseed oil propyl esters, rapeseed oil butyl esters, neem oil, tall oil fatty acids esters etc.), diesel, mineral oil, fatty acid amides (e.g. C1 -C3 amines, alkylamines or alkanolamines with C6 - Ci8 carboxylic acids), fatty acids, tall oil fatty acids, alkyl esters of fatty acids (e.g. Ci, Methyl and ethyl oleate, methyl and ethyl soyate, alkyl benzenes and alkylnaphthalenes, polyalkylene glycol ethers, fatty acid diesters, fatty alkylamides and diamides, dialkylene carbonates, ketones and alcohols or mixture thereof.

[CLAIM 14]. The agrochemical composition as claimed in claim 1-claim 6 wherein, the preferred composition for the ZC formulation comprises:
i. Mixed formulation (ZC) of Bixafen 8% + Pyraclostrobin 5% + Brassinolide 0.025%
ii. Mixed formulation (ZC) of Bixafen 8% + Trifloxystrobin 5% + Brassinolide 0.025%
iii. Mixed formulation (ZC) of Bixafen 8% + Tebuconazole 5% + Brassinolide 0.025%
iv. Mixed formulation (ZC) of Bixafen 8% + Prothioconazole 5% + Brassinolide 0.025%
v. Mixed formulation (ZC) of Thifluzamide 5% + Pyraclostrobin 5% + Ortho silicic acid 2%
vi. Mixed formulation (ZC) of Thifluzamide 5% + Trifloxystrobin 5% + Ortho silicic acid 2%
vii. Mixed formulation (ZC) of Fluxapyroxad 08% + Pyraclostrobin 5% + Ortho silicic acid 2%
viii. Mixed formulation (ZC) of Fluxapyroxad 08% + Trifloxystrobin 5% + Ortho silicic acid 2%
ix. Mixed formulation (ZC) of Fluxapyroxad 16% + Azoxystrobin 10% + Ortho silicic acid 4%
x. Mixed formulation (ZC) of Fluxapyroxad 7.5% + Prothioconazole 5% + Salicylic acid 2%
xi. Mixed formulation (ZC) of Fluxapyroxad 7.5% + Epoxiconazole 5% + Salicylic acid 2%

[CLAIM 15]. The agrochemical composition as claimed in claim 13, wherein (ZC) formulation comprises:
i. a fungicide from class of SDHI (Succinate dehydrogenase inhibitors) in an amount of 0.1 to 35% by weight of the composition is selected from Bixafen, Thifluzamide, Fluxapyroxad;
ii. a fungicide in an amount of 0.1 to 45% by weight of the composition selected from Pyraclostrobin, Trifloxystrobin Azoxystrobin, Prothiconazole, Tebuconazole and Epoxiconazole;
iii. a plant health additive in an amount of 0.001 to 20% by weight selected from Brassinolide, Orthosilicic acid and salicylic acid.
iv. Wetting agent in an amount of 2 to 6 % by weight;
v. Dispersing agent 1 in an amount of 2 to 8 % by weight;
vi. Dispersing agent 2 in an amount of 1to 3 % by weight;
vii. Solvent in an amount of 6 to 10 % by weight;
viii. Wall forming material 1 in an amount of 0.1 to 3 % by weight;
ix. Wall forming material 2 in an amount of 0.1 to 2 % by weight;
x. Suspending agent in an amount of 1 to 3 % by weight;
xi. Antifoaming agent in an amount of 0.1 to 1.0 % by weight
xii. Buffering agent in an amount of 0.1 to 2.0 % by weight;
xiii. Preservative in an amount of 0.05 to 1.0 % by weight;
xiv. Antifreezing agent in an amount of 4 to 8 % by weight
xv. Thickner in an amount of 0.05 to 2.0 % by weight
xvi. Diluent Water in an amount of 40 to 70 % by weight

[CLAIM 16]. The agrochemical composition as claimed in 14 wherein, suspending agent is selected from Aluminum Magnesium Silicate, Bentonite clay, Silica, Attapulgite clay.

[CLAIM 17]. The agrochemical composition as claimed in 14 wherein, wetting agent is selected from Ethylene oxide/propylene oxide block copolymer, Polyarylphenyl ether phosphate, Ethoxylated Fatty Alcohol, Sodium dioctyl sulfosuccinate, sodium lauryl sulphate and sodium dodecyl benzene sulfonate, alkyl diphenyl sulfonates, sodium isopropyl naphthalene sulfonate, Alkyl naphthalene sulfonate, Octyl phenol ethoxylate, alkyl phenol ethoxylate and aliphatic alcohol ethoxylate or mixture thereof.

[CLAIM 18]. The agrochemical composition as claimed in claim 14 wherein, wall forming agent is selected from Tetramethylene diisocyanate, pentamethylene diisocyanate, hexamethylene diisocyanate, toluene diisocyanate, diphenylmethene-4,4’-diisocyanate, polymethylene polyphenylene isocyanate, 2,4,4’-diphenyl ether tri-isocyanate, 3,3’-dimethyl-4,4’-diphenyl diisocyanate, 3,3’-dimethoxy-4,4’-diphenyl diisocyanate, 1,5-naphthylene diisocyanate and 4,4’4"-triphenylmethane tri-isocyanate, toluene diisocyanate or polymethylene polyphenylisocyanate; Ammonia, hexamine, ethylenediamine, propylene-1,3-diamine, tetramethylenediamine, pentamethylene diamine, 1,6-hexamethylenediamine, diethylenetriamine, triethylene- tetramine, tetra ethylene pentamine, pentaethylenehex amine, 4,9-dioxadodecane-1, 12-diamine, 1,3- phenylene diamine, 2,4- and 2,6-toluenediamine and 4,4’-diaminodiphenylmethane, 1,3-phenylenediamine, 2,4- and 2,6-toluenediamine, 4,4'-diaminodiphenylmethane, 1,5-diaminonaphthalene, 1,3,5-triaminobenzene, 2,4,6-triaminotoluene, 1,3,6-triaminonaphthalene, 2,4,4'-triaminodiphenyl ether, 3,4,5-triamino-1,2,4-triazole and 1,4,5,8-tetraminoanthraquinone.

[CLAIM 19]. The agrochemical composition as claimed in claim 1-claim 6 wherein, the preferred composition for the Suspension Concentrate (SC) formulation comprises:
i. Suspension Concentrate (SC) formulation of Thifluzamide 15% + Difenoconazole 20% + Zinc 5%
ii. Suspension Concentrate (SC) formulation of Thifluzamide 15% + Tebuconazole 20% + Zinc 5%
iii. Suspension Concentrate (SC) formulation of Thifluzamide 15% + Prothioconazole 20% + Zinc 5%
iv. Suspension Concentrate (SC) formulation of Thifluzamide 15% + Azoxystrobin 20% + Zinc 5%
v. Suspension Concentrate (SC) formulation of Bixafen 16% + Picoxystrobin 10% + Brassinolide 0.05%
vi. Suspension Concentrate (SC) formulation of Bixafen 16% + Difenoconazole 10% + Brassinolide 0.05%
vii. Suspension Concentrate (SC) formulation of Thifluzamide 5% + Metyltetraprole 10% + Ortho silicic acid 2%
viii. Suspension Concentrate (SC) formulation of Thifluzamide 5% + Tebufloquin 10% + Ortho silicic acid 2%
ix. Suspension Concentrate (SC) formulation of Thifluzamide 5% + Tolprocarb 10% + Ortho silicic acid 2%
x. Suspension Concentrate (SC) formulation of Thifluzamide 5% + Quinofumelin 10% + Ortho silicic acid 2%
xi. Suspension Concentrate (SC) formulation of Thifluzamide 5% + Dichlorobentiazox 10% + Ortho silicic acid 2%
xii. Suspension Concentrate (SC) formulation of Thifluzamide 5% + Dipymetitrone 10% +Ortho silicic acid 2%
xiii. Suspension Concentrate (SC) formulation of Thifluzamide 5% + Fluoxapipronil 10% + Ortho silicic acid 2%
xiv. Suspension Concentrate (SC) formulation of Fluxapyroxad 7.5% + Metyltetraprole 8% + Fulvic acid 2.5%
xv. Suspension Concentrate (SC) formulation of Fluxapyroxad 7.5% + Tebufloquin 8% + Fulvic acid 2.5%
xvi. Suspension Concentrate (SC) formulation of Fluxapyroxad 7.5% + Tolprocarb 8% + Fulvic acid 2.5%
xvii. Suspension Concentrate (SC) formulation of Fluxapyroxad 7.5% + Quinofumelin 8% + Fulvic acid 2.5%
xviii. Suspension Concentrate (SC) formulation of Fluxapyroxad 7.5% + Dichlorobentiazox 8% + Fulvic acid 2.5%
xix. Suspension Concentrate (SC) formulation of Fluxapyroxad 7.5% + Dipymetitrone 8% + Fulvic acid 2.5%
xx. Suspension Concentrate (SC) formulation of Fluxapyroxad 7.5% + Fluoxapipronil 8% + Fulvic acid 2.5%
xxi. Suspension Concentrate (SC) formulation of Inpyrfluxam 10% + Azoxystrobin 15% + Carboxylic acid 3%
xxii. Suspension Concentrate (SC) formulation of Isopyrazam 10% + Azoxystrobin 15% + Carboxylic acid 3%
xxiii. Suspension Concentrate (SC) formulation of Penthiopyrad 12% + Azoxystrobin 10% + Carboxylic acid 3%
xxiv. Suspension Concentrate (SC) formulation of Sedaxane 10% + Azoxystrobin 12% + Carboxylic acid 3%
xxv. Suspension Concentrate (SC) formulation of Flubeneteram 8% + Azoxystrobin 15% + Carboxylic acid 3%
xxvi. Suspension Concentrate (SC) formulation of Isoflucypram 10% + Azoxystrobin 15% + Carboxylic acid 3%
xxvii. Suspension Concentrate (SC) formulation of Boscalid 15% + Azoxystrobin 10% + Carboxylic acid 3%
xxviii. Suspension Concentrate (SC) formulation of Pyraziflumid 8% + Azoxystrobin 15% + Carboxylic acid 3%
xxix. Suspension Concentrate (SC) formulation of Fluindapyr 10% + Azoxystrobin 15% + Carboxylic acid 3%
xxx. Suspension Concentrate (SC) formulation of Pyrapropopyne 10% + Azoxystrobin 15% + Carboxylic acid 3%
xxxi. Suspension Concentrate (SC) formulation of Benzovindiflupyr 12% + Azoxystrobin 15% + Carboxylic acid 3%
xxxii. Suspension Concentrate (SC) formulation of Pydiflumetofen 12% + Azoxystrobin 15% + Carboxylic acid 3%

[CLAIM 20]. The agrochemical composition as claimed in claim 1 and claim 7, wherein the Suspension Concentrate (SC) formulation comprises:
i. a fungicide from class of SDHI (Succinate dehydrogenase inhibitors) in an amount of 0.1 to 35% by weight of the composition is selected from Thifluzamide, Bixafen, Fluxapyroxad, Inpyrfluxam, Isopyrazam, Penthiopyrad, Sedaxane, Flubeneteram,, Isoflucypram, Boscalid, Pyraziflumid, Fluindapyr, Pyrapropopyne, Benzovindiflupyr, Pydiflumetofen;
ii. a fungicide in an amount of 0.1 to 45% by weight of the composition selected from Difenoconazole, Tebuconazole and Tebuconazole, Prothioconazole,Azoxystrobin, Picoxystrobin, Tebufloquin, Tolprocarb, Quinofumelin, Dichlorobentiazox, Dipymetitrone, Fluoxapipronil Tolprocarb, Dichlorobentiazox, Dipymetitrone, Fluoxapipronil, Azoxystrobin;
iii. a plant health additive in an amount of 0.001 to 20% by weight selected from Zinc (zinc oxide, zinc lactate gluconate, zinc polyflavonoid), Orthosilicic acid, Brassinolide, Fulvic acid , carboxylic acid and salicylic acid;
iv. Wetting agent in an amount of 2 to 6 % by weight;
v. Dispersing agent 1 in an amount of 2 to 8 % by weight;
vi. Dispersing agent 2 in an amount of 1to 3 % by weight;
vii. Suspending agent in an amount of 0.2 to 4.0 % by weight;
viii. Antifoaming agent in an amount of 0.1 to 1.5 % by weight;
ix. Preservative in an amount of 0.1 to 0.5 % by weight;
x. Antifreezing agent in an amount of 2 to 6 % by weight;
xi. Thickner in an amount of 0.1 to 1.0 % by weight;
xii. Diluent Water in an amount of 40 to 70 % by weight.

[CLAIM 21]. The agrochemical composition as claimed in claim 19, wherein wetting agent wetting agent is selected from ethylene oxide/propylene oxide block copolymer, polyaryl phenyl ether phosphate, ethoxylated fatty alcohol, sodium dioctyl sulfosuccinate, sodium lauryl sulfate and sodium dodecyl benzene sulfonate, alkyl diphenyl sulfonates, sodium isopropyl naphthalene sulfonate, alkyl naphthalene sulfonate.

[CLAIM 22]. The agrochemical composition as claimed in claim 19, wherein dispersing agent is selected from alkylated naphthalene sulfonate, sodium salt, sodium salt of naphthalene sulfonate condensate, sodium ligno sulfonate, sodium ploycarboxylate, EO/PO based copolymer, phenol sulfonate, sodium methyl oleoyl taurate, styrene acrylic acid copolymer, propylene oxide-ethylene oxide-copolymer, polyethylene glycol 2,4,6-tristyrylphenyl ether, tristyryl phenol-polyglycol ether-phosphate, tristyryl phenole with 16 moles EO, tristyryl phenol-polyglycol ether-phosphate, oleyl-polyglycol ether with ethylene oxide, tallow fatty amine polyethylene oxide, nonylphenol polyglycol ether with 9-10 moles ethylene oxide.

[CLAIM 23]. The agrochemical composition as claimed in claim 19, wherein suspending agent is selected from aluminum magnesium silicate, bentonite clay, silica, attapulgite clay.

[CLAIM 24]. The agrochemical composition as claimed in claim 19, wherein anti-freezing agent is selected from ethylene glycol, propane diols, glycerine or the urea, glycol (monoethylene glycol, diethylene glycol, polypropylene glycol, polyethylene glycol), glycerine, urea, magnesium sulfate heptahydrate, sodium chloride.

[CLAIM 25]. The agrochemical composition as claimed in claim 1-claim 6 wherein, the preferred composition for the Water Dispersible Granule (WG) formulation comprises:
i. Water Dispersible Granule (WG) formulation of Thifluzamide 5% + Copper 60% + Zinc 5%
ii. Water Dispersible Granule (WG) formulation of Thifluzamide 5% + Mancozeb 60% + Zinc 5%
iii. Water Dispersible Granule (WG) formulation of Thifluzamide 5% + Propineb 60% + Zinc 5%
iv. Water Dispersible Granule (WG) formulation of Thifluzamide 5% + Chlorothalonil 60% + Zinc 5%
v. Water Dispersible Granule (WG) formulation of Fluxapyroxad 5% + Copper 60% + Zinc 5%
vi. Water Dispersible Granule (WG) formulation of Fluxapyroxad 5% + Mancozeb 60% + Zinc 5%
vii. Water Dispersible Granule (WG) formulation of Fluxapyroxad 5% + Propineb 60% + Zinc 5%
viii. Water Dispersible Granule (WG) formulation of Fluxapyroxad 5% + Chlorothalonil 60%+ Zinc 5%
ix. Water Dispersible Granule (WG) formulation of Inpyrfluxam 8% + Mancozeb 60% + Zinc 5%
x. Water Dispersible Granule (WG) formulation of Isopyrazam 8% + Mancozeb 60% + Zinc 5%
xi. Water Dispersible Granule (WG) formulation of Penthiopyrad 8% + Mancozeb 60% + Zinc 5%
xii. Water Dispersible Granule (WG) formulation of Sedaxane 8% +Mancozeb 60% + Zinc 5%
xiii. Water Dispersible Granule (WG) formulation of Flubeneteram 8% + Mancozeb 60% + Zinc 5%
xiv. Water Dispersible Granule (WG) formulation of Isoflucypram 8% + Mancozeb 60% + Zinc 5%
xv. Water Dispersible Granule (WG) formulation of Boscalid 10% + Mancozeb 60% + Zinc 5%
xvi. Water Dispersible Granule (WG) formulation of Pyraziflumid 6% + Mancozeb 60% + Zinc 5%
xvii. Water Dispersible Granule (WG) formulation of Fluindapyr 8% + Mancozeb 60% + Zinc 5%
xviii. Water Dispersible Granule (WG) formulation of Pyrapropopyne 8% + Mancozeb 60% + Zinc 5%
xix. Water Dispersible Granule (WG) formulation of Benzovindiflupyr 10% + Mancozeb 60% + Zinc 5%
xx. Water Dispersible Granule (WG) formulation of Pydiflumetofen 10% + Mancozeb 60% + Zinc 5%

[CLAIM 26]. The agrochemical composition as claimed in claim 1 and claim 7, wherein the Water Dispersible Granule (WG) formulation comprises:
i. a fungicide from class of SDHI (Succinate dehydrogenase inhibitors) in an amount of 0.1 to 35% by weight of the composition is selected from Fluxapyroxad, Inpyrfluxam, Isopyrazam, Penthiopyrad, Sedaxane, Flubeneteram, Boscalid, Pyraziflumid, Pyrapropopyne, Benzovindiflupyr, Pydiflumetofen;
ii. a fungicide in an amount of 0.1 to 45% by weight of the composition selected from Mancozeb, Propineb, Chlorothalonil, Copper;
iii. a plant health additive in an amount of 0.001 to 20% by weight selected from Zinc (zinc sulphate heptahydrate ZnSO47H2O, zinc sulphate mono hydrate ZnSO4.H2O, chelated zinc as Zn-EDTA, zinc oxide, zinc lactate gluconate, zinc polyflavonoid).
iv. Wetting agent in an amount of 2 to 6 % by weight;
v. Dispersing agent I in an amount of 2 to 8 % by weight;
vi. Dispersing agent II in an amount of 1to 3 % by weight;
vii. Disintegrating agent in an amount of 0.2 to 0.8 % by weight;
viii. Antifoaming agent in an amount of 0.1 to 1.5 % by weight;
ix. Carrier in an amount of 50 to 80 % by weight.

[CLAIM 27]. The agrochemical composition as claimed in claim 25 wherein, dispersing agent is selected from naphthalene sulfonic acid, sodium salt condensated with formaldehyde, poly alcoxylated alkyl phenol, naphthalene sulfonic acid formaldehyde condensate, methyl naphtaline-formaldehyde-condensate sodium salt, naphthalene condensates, lingo sulfonates, poly acrylates and phosphate esters, calcium lingo sulfonate, lignin sulfonate sodium salt.

[CLAIM 28]. The agrochemical composition as claimed in claim 25 wherein, wetting agents is selected from sodium N-methyl-N-oleoyl taurate, alkylated naphthalene sulfonate, sodium salt, mixture of isomers of dibutyl naphthalene sulphonic acid sodium salt, sodium di-isopropyl naphthalene sulphonate, sodium Lauryl sulfate, dioctyl sulfate, alkyl naphthalene sulfonates, phosphate esters, sulphosuccinates and non-ionic such as tridexyl alcohol ethoxylate, alkyl or alkaryl sulfonates such as alkyl benzene sulfonates, alpha olefin sulfonate and alkyl naphthalene sulfonates, ethoxylated or non-ethoxylated alkyl or alkaryl carboxylates, alkyl or alkyaryl phosphate esters, alkyl polysaccharide, di or mono alkyl sulfosuccinate derivatives, alpha olefin sulfonates, alkyl naphthalene sulfonates, dialkyl sulphosuccinates, butyl, dibutyl, isopropyl and diisopropyl naphthalene sulfonate salts, C12 alkyl benzene sulfonate or C10-C16 alkyl benzene sulfonate.

[CLAIM 29]. The agrochemical composition as claimed in claim 25, wherein disintegrating agent is selected from citric acid, succinic acid or the sodium bicarbonate.

[CLAIM 30]. The agrochemical composition as claimed in claim 1 and claim 6, wherein SC (Suspension concentrate) formulation, ZC (mixture of CS and SC), CS (Capsule Suspension), SE (Suspo Emulsion), WG (Wettable Granule), WDG (Water Dispersible Granule) and Oil dispersion (OD) formulation further comprises of wetting and spreading agent as an organic silicone type surfactant and is selected from trisiloxane ethoxylate, polydimethylsiloxane, polyoxyethylene methyl polysiloxane, polyoxyalkylene methyl polysiloxane, polyether polymethyl siloxane copolymer heptamethyl trisiloxane, Polyalkyleneoxide modified heptamethyl trisiloxane, polyether modified polysiloxane, 10 mole ethylene oxide adduct of octylphenol, or mixture thereof etc; Addition of organic silicone type surfactant works as super wetting agent, speading agent and penetrating agent which improves the bioefficacy of the products.