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An Agrochemical Combination

Abstract: Described herein are combinations of glufosinate, salts or esters thereof or L-glufosinate, salts or esters thereof with at least two herbicides. The resulting combinations may be synergistic. Also described are compositions, methods of use and kit-of-parts of the same.

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Patent Information

Application #
Filing Date
18 October 2021
Publication Number
16/2023
Publication Type
INA
Invention Field
CHEMICAL
Status
Email
info@indiaip.com
Parent Application

Applicants

UPL LIMITED
UPL House, 610 B/2, Bandra Village, Off Western Express Highway, Bandra E, Mumbai 400051, India,

Inventors

1. LENZ, Giuvan
Rod. SP 143, Km 8,5, Pereiras - SP - 18580-000 - Brazil
2. RAO, Ganesh
UPL Limited, UPL House, 610 B/2, Bandra Village, Off Western Express Highway, Bandra E, Mumbai 400051, India

Specification

FORM 2
THE PATENTS ACT 1970
(39 of 1970)
&
THE PATENT RULES, 2003
COMPLETE SPECIFICATION
[See Section 10 and Rule 13]
Title of the invention: AN AGROCHEMICAL COMBINATION
Name of the Applicant: UPL Limited
Nationality: India
Address: UPL House, 610 B/2, Bandra Village, Off
Western Express Highway, Bandra E, Mumbai 400051, India
The following specification particularly describes the invention and the manner in which it is to be performed.

FIELD OF THE INVENTION
The present invention relates to an herbicidal combination for controlling weeds. More particularly, the present invention relates to synergistic herbicidal combinations, compositions, kits-in-part and method for controlling undesirable weeds.
BACKGROUND OF THE INVENTION
Weeds are undesirable plants that are detrimental to agriculture and significantly affect crop yields. Farmers use various types of herbicides to control weeds. Herbicides with varied modes of action are generally combined, which allows for broader spectrum of control and managing resistance to herbicides. However, the combinations currently known are not sufficient to control the resistant and persistent weeds.
Additionally, the combination of herbicides may not always result in the desired effect. Combinations of herbicides may result in an additive effect or an antagonistic effect. It may also result in phytotoxicity to the crops making it an undesirable combination. Consequently, herbicides need to be carefully selected so that they can be combined to offer a synergistic effect that would control weeds while having no phytotoxic effect on the crop and reduce the chances of the weeds developing resistance to a particular herbicide.
Accordingly, there is a need in the art for a synergistic herbicidal combination, composition, method and kits for protecting crops from persistent weeds, which helps in resistance management, reduces dosage of herbicides used and that has excellent residual effects.
OBJECTIVE OF THE INVENTION
It is an objective of the present invention to provide a synergistic combination for controlling weeds.
It is an objective of the present invention to provide a combination for efficient weed control, weed suppression and eradication.
It is an object of the present invention to provide a combination of highly effective herbicidal actives for selective and non-selective weed control.

It is another object of the present invention to provide a synergistic herbicidal combination to control, suppress or prevent a wide spectrum of weeds and target plants, both dicotyledonous and monocotyledonous, broad-leaved, and grassy weeds.
It is an objective of the present invention to provide a synergistic combination for controlling weeds, comprising glufosinate or L-glufosinate and at least two herbicides selected from nitrophenyl ether, imidazolinone, organophosphorous, dicarboximide, phenoxyacetic, pyridine, cyclohexene oxime, aryloxyphenoxypropionic, triazolone class of herbicides, and/or uracil class of herbicides.
It is an objective of the present invention to provide a composition for controlling weeds, comprising glufosinate or L-glufosinate and at least two herbicides selected from nitrophenyl ether, imidazolinone, organophosphorous, dicarboximide, phenoxyacetic, pyridine, cyclohexene oxime, aryloxyphenoxypropionic, triazolone class of herbicides, and/or uracil class of herbicides.
It is an objective of the present invention to provide solid or liquid formulations for controlling weeds.
It is an objective of the present invention to provide a method of controlling weeds, by application of a synergistic herbicidal combination comprising glufosinate or L-glufosinate and at least two herbicides selected from nitrophenyl ether, imidazolinone, organophosphorous, dicarboximide, phenoxyacetic, pyridine, cyclohexene oxime, aryloxyphenoxypropionic, triazolone class of herbicides, and/or uracil class of herbicides.
It is an objective of the present invention to provide a method for increasing yield in a crop by application of a synergistic combination.
It is an objective of the present invention to provide a method for improving the plant health by application of a synergistic combination at the desired locus.
It is an objective of the present invention to provide a combination or composition for use in controlling undesirable vegetation.

Additionally, it is an object of the invention to provide a method of controlling resistant varieties of weeds with a suitable herbicidal combination.
It is an object of the present invention to provide a combination of highly effective herbicidal actives for an efficient burn-down program.
It is an objective of the present invention to provide a kit-of-parts comprising a plurality of components.
SUMMARY OF THE INVENTION
In an aspect, the present invention provides a combination for controlling the growth of undesirable vegetation, said combination comprising glufosinate, salts or esters thereof, and at least two herbicides selected from:
(a) nitrophenyl ether class of herbicides;
(b) imidazolinone class of herbicides;
(c) organophosphorous class of herbicides;
(d) dicarboximide class of herbicides;
(e) phenoxyacetic class of herbicides;
(f) pyridine class of herbicides;
(g) cyclohexene oxime class of herbicides;
(h) aryloxyphenoxypropionic class of herbicides;
(i) triazolone class of herbicides; and/or
(j) uracil class of herbicides.
In another aspect, there is provided a composition for controlling the growth of undesirable vegetation, the composition comprising glufosinate, salts or esters thereof, at least two herbicides selected from:
(a) nitrophenyl ether class of herbicides;
(b) imidazolinone class of herbicides;
(c) organophosphorous class of herbicides;
(d) dicarboximide class of herbicides;
(e) phenoxyacetic class of herbicides;
(f) pyridine class of herbicides;
(g) cyclohexene oxime class of herbicides;

(h) aryloxyphenoxypropionic class of herbicides;
(i) triazolone class of herbicides; and/or
(j) uracil class of herbicides;
and at least one agrochemically suitable excipient.
In a preferred embodiment, the glufosinate, salts or esters thereof, is L-glufosinate, salts or esters thereof.
Preferably, the second and third herbicides may be selected from within the same class of herbicides.
Preferably, the second and third herbicides may be selected from within different classes of herbicides.
In accordance with another aspect, the weight ratio of glufosinate and the at least two herbicides ranges from 1:100:100 to 100:1:1.
In accordance with another aspect, the weight ratio of glufosinate and the at least two herbicides ranges from 1:75:75 to 75:1:1.
In accordance with another aspect, there is provided a method of controlling the growth of undesirable vegetation, the method comprising treating the locus at which control is desired with a synergistic combination comprising glufosinate, salts or esters thereof, and at least two herbicides selected from:
(a) nitrophenyl ether class of herbicides;
(b) imidazolinone class of herbicides;
(c) organophosphorous class of herbicides;
(d) dicarboximide class of herbicides;
(e) phenoxyacetic class of herbicides;
(f) pyridine class of herbicides;
(g) cyclohexene oxime class of herbicides;
(h) aryloxyphenoxypropionic class of herbicides;
(i) triazolone class of herbicides; and/or
(j) uracil class of herbicides.
Preferably, the second and third herbicides may be selected from within the same class of herbicides.

Preferably, the second and third herbicides may be selected from within different classes of herbicides.
Preferably, the glufosinate, salts or esters thereof, is L-glufosinate, salts or esters thereof.
Preferably, the second herbicide is selected from the nitrophenyl ether class of herbicides, and the third herbicide is selected from the nitrophenyl ether class of herbicides; or the imidazolinone class of herbicides; or the organophosphorous class of herbicides; or dicarboximide class of herbicides; or phenoxyacetic class of herbicides; or the pyridine class of herbicides; or the cyclohexene oxime class of herbicides; or the aryloxyphenoxypropionic class of herbicides; or the triazolone class of herbicides; or the uracil class of herbicides.
Preferably, the second herbicide is selected from the imidazolinone class of herbicides, and the third herbicide is selected from the nitrophenyl ether class of herbicides; or the imidazolinone class of herbicides; or the organophosphorous class of herbicides; or dicarboximide class of herbicides; or phenoxyacetic class of herbicides; or the pyridine class of herbicides; or the cyclohexene oxime class of herbicides; or the aryloxyphenoxypropionic class of herbicides; or the triazolone class of herbicides; or the uracil class of herbicides.
Preferably, the second herbicide is selected from the organophosphorus class of herbicides, and the third herbicide is selected from the nitrophenyl ether class of herbicides; or the imidazolinone class of herbicides; or the organophosphorous class of herbicides; or dicarboximide class of herbicides; or phenoxyacetic class of herbicides; or the pyridine class of herbicides; or the cyclohexene oxime class of herbicides; or the aryloxyphenoxypropionic class of herbicides; or the triazolone class of herbicides; or the uracil class of herbicides.
Preferably, the second herbicide is selected from the dicarboximide class of herbicides, and the third herbicide is selected from the nitrophenyl ether class of herbicides; or the imidazolinone class of herbicides; or the organophosphorous class of herbicides; or dicarboximide class of herbicides; or phenoxyacetic class of herbicides; or the pyridine class of herbicides; or the cyclohexene oxime class of herbicides; or the aryloxyphenoxypropionic class of herbicides; or the triazolone class of herbicides; or the uracil class of herbicides.
Preferably, the second herbicide is selected from the phenoxyacetic class of herbicides, and the third herbicide is selected from the nitrophenyl ether class of herbicides; or the imidazolinone class of herbicides; or the organophosphorous class of herbicides; or dicarboximide class of herbicides; or phenoxyacetic class of herbicides; or the pyridine class of herbicides; or the

cyclohexene oxime class of herbicides; or the aryloxyphenoxypropionic class of herbicides; or the triazolone class of herbicides; or the uracil class of herbicides.
Preferably, the second herbicide is selected from the pyridine class of herbicides, and the third herbicide is selected from the nitrophenyl ether class of herbicides; or the imidazolinone class of herbicides; or the organophosphorous class of herbicides; or dicarboximide class of herbicides; or phenoxyacetic class of herbicides; or the pyridine class of herbicides; or the cyclohexene oxime class of herbicides; or the aryloxyphenoxypropionic class of herbicides; or the triazolone class of herbicides; or the uracil class of herbicides.
Preferably, the second herbicide is selected from the cyclohexene oxime class of herbicides, and the third herbicide is selected from the nitrophenyl ether class of herbicides; or the imidazolinone class of herbicides; or the organophosphorous class of herbicides; or dicarboximide class of herbicides; or phenoxyacetic class of herbicides; or the pyridine class of herbicides; or the cyclohexene oxime class of herbicides; or the aryloxyphenoxypropionic class of herbicides; or the triazolone class of herbicides; or the uracil class of herbicides.
Preferably, the second herbicide is selected from the aryloxyphenoxypropionic class of herbicides, and the third herbicide is selected from the nitrophenyl ether class of herbicides; or the imidazolinone class of herbicides; or the organophosphorous class of herbicides; or dicarboximide class of herbicides; or phenoxyacetic class of herbicides; or the pyridine class of herbicides; or the cyclohexene oxime class of herbicides; or the aryloxyphenoxypropionic class of herbicides; or the triazolone class of herbicides; or the uracil class of herbicides.
Preferably, the second herbicide is selected from the triazolone class of herbicides, and the third herbicide is selected from the nitrophenyl ether class of herbicides; or the imidazolinone class of herbicides; or the organophosphorous class of herbicides; or dicarboximide class of herbicides; or phenoxyacetic class of herbicides; or the pyridine class of herbicides; or the cyclohexene oxime class of herbicides; or the aryloxyphenoxypropionic class of herbicides; or the triazolone class of herbicides; or the uracil class of herbicides.
Preferably, the second herbicide is selected from the uracil class of herbicides, and the third herbicide is selected from the nitrophenyl ether class of herbicides; or the imidazolinone class of herbicides; or the organophosphorous class of herbicides; or dicarboximide class of herbicides; or phenoxyacetic class of herbicides; or the pyridine class of herbicides; or the cyclohexene oxime class of herbicides; or the aryloxyphenoxypropionic class of herbicides; or the triazolone class of herbicides; or the uracil class of herbicides.

In accordance with another aspect, there is provided a method of controlling the growth of undesirable vegetation, the method comprising treating the locus with a synergistic combination of glufosinate, an herbicide selected from the imidazolinone class of herbicides, and a herbicide selected from the triazolone class of herbicides.
In accordance with another aspect, the weight ratio of glufosinate, the herbicide selected from the imidazolinone class of herbicides, and the herbicide selected from the triazolone class of herbicides ranges from 1:100:100 to 100:1:1.
In accordance with another aspect, the weight ratio of glufosinate, the herbicide selected from the imidazolinone class of herbicides, and the herbicide selected from the triazolone class of herbicides ranges from 1:75:75 to 75:1:1.
In accordance with yet another aspect, the combinations, compositions and methods of the present invention are used for controlling weeds in a range of crops.
In accordance with yet another aspect, there is provided a kit-of-parts comprising a plurality of components that may be admixed before use.
DETAILED DESCRIPTION OF THE INVENTION
Discussed below are some representative embodiments of the present invention. The invention in its broader aspects is not limited to the specific details and representative methods. Illustrative examples are described in this section in connection with the embodiments and methods provided.
For the purposes of the following detailed description, it is to be understood that the invention may assume various alternative variations and step sequences, except where expressly specified to the contrary. Moreover, other than in any operating examples, or where otherwise indicated, all numbers expressing, for example, quantities of materials/ingredients used in the specification are to be understood as being modified in all instances by the term "about" and is meant to encompass variations of ± 10%, ± 5%, ± 1%, ± 0.5%, or even ± 0.1% of the specified value as well as the specified value.
It is to be noted that, as used in the specification, the singular forms "a," "an," and "the" include plural referents unless the context clearly dictates otherwise. Thus, for example, reference to a composition containing “a surfactant” includes a mixture of two or more surfactants. It should

also be noted that the term "‘or” is generally employed in its sense including “and/or” unless the content clearly dictates otherwise. The terms “emulsifier” and “surfactant” mean essentially the same thing and may be used interchangeably. Further, the terms “composition” or “formulation” also mean essentially the same thing and may be used interchangeably.
The terms “preferred” and “preferably” refer to embodiments of the invention that may afford certain benefits, under certain circumstances.
As used herein, the terms “comprising” “including,” “having,” “containing,” “involving,” and the like are to be understood to be open-ended, i.e., to mean including but not limited to.
The expression of various quantities in terms of “%” or “% w/w” means the percentage by weight of the total solution or composition unless otherwise specified.
The terms “plants” and “vegetation” include, but are not limited to, germinant seeds, emerging seedlings, plants emerging from vegetative propagules, and established vegetation. The term ‘plants’ refers to all physical parts of a plant, including seeds, seedlings, saplings, roots, tubers, stems, stalks, foliage and fruits. The term “weed” refers to unwanted vegetation and includes any plant which grows where it is not wanted, including pesticide resistant plants. In the broadest sense, the term "weed" refers to plants which grow in locations in which they are not desired. In other words, a “weed” is a plant in which in the context of a crop is undesirable due to competition for water, nutrients, sunlight, soil, etc. The term may also refer to crop plants which are undesirable at a location.
The terms "undesirable vegetation", "harmful plants", "unwanted plants", "weeds" and "weed species", as used herein, are synonyms.
Typically, the combinations/compositions of the present invention are applied to the targeted weed or to their locus or to the crop/plant. The term “locus” as used herein shall denote the vicinity of a desired crop in which weed control, typically selective weed control is desired. The locus includes the vicinity of desired crop plants wherein the weed infestation has either emerged or is yet to emerge. The term crop shall include a multitude of desired crop plants or an individual crop plant growing at a locus. The said locus could be a weed, an area adjacent to the weed, soil adapted to support growth of the weed, a root of the weed and/or foliage of the weed. The ‘locus’ is intended to include soil, seeds, and seedlings as well as established vegetation.

In any aspect or embodiment described hereinbelow, the phrase comprising may be replaced by the phrases “consisting of’ or “consisting essentially of’ or “consisting substantially of’. In these aspects or embodiment, the combination or composition described includes or comprises or consists of or consists essentially of or consists substantially of the specific components recited therein, to the exclusion of other herbicides or fungicides or insecticide or plant growth promoting agents or adjuvants, or excipients not specifically recited therein.
The present invention, in all its aspects, is described in detail as follows:
Glufosinate (phosphinothricin; DL-homoalanin-4-yl(methyl)phosphinic acid) is a racemic phosphinico amino acid (Hoerlein, G. 1994; glufosinate (Phosphinothricin), a natural amino acid with unexpected herbicidal properties. Rev. of Environmental Contamination and Toxicology 138, 73 - 145). Its ammonium salt (glufosinate-ammonium) is widely used as a non-selective herbicide and is the active ingredient of the commercial herbicide formulations BastaTM, BusterTM, ChallengeTM, ConquestTM, DashTM, FinalTM, FinaleTM, LibertyTM and
IgniteTM. The L-isomer of glufosinate is a structural analogue of glutamate and, therefore, is a competitive inhibitor of the enzyme glutamine synthetase (GS) of bacteria and plants (Bayer et al, 1972, Phosphinothricin and phosphinothricyl-alanyl-alanin. Helv. Chim. Acta 55, 224 -239; Leason et al., 1982, Inhibition of pea leaf glutamine synthetase by methioninsulfoximine, Phosphinothricin and other glutamate analogs. J. Phytochem. 21, 855 - 857). The D-isomer is not a GS inhibitor and is not herbicidally active.

Fig. 1. Chemical structures of D-glufosinate and L-glufosinate.
It has surprisingly been found by the present inventors that a range of weeds can be completely controlled by the combination of glufosinate, salts or esters thereof, and at least two herbicides selected from:
(a) nitrophenyl ether class of herbicides;
(b) imidazolinone class of herbicides;
(c) organophosphorous class of herbicides;
(d) dicarboximide class of herbicides;

(e) phenoxyacetic class of herbicides;
(f) pyridine class of herbicides;
(g) cyclohexene oxime class of herbicides;
(h) aryloxyphenoxypropionic class of herbicides;
(i) triazolone class of herbicides; and/or
(j) uracil class of herbicides.
More surprisingly, it was found that this combination, between glufosinate, salts or esters thereof, and at least two herbicides provided synergistic effect in controlling a range of weeds. The degree of synergistic enhancement in efficacy of the above combination towards control of weeds was unpredictable and unexpected.
As used herein, the term “glufosinate” refers to any molecule which is a racemic phosphinico amino acid or a salt thereof. The term also includes forms and isomers of glufosinate such as glufosinate-p (L-glufosinate), D-glufosinate, and sodium, potassium or ammonium salts thereof. The term can generically refer to any form of glufosinate or its salt such as solvates, hydrates, anhydrous form, polymorph forms, pseudo polymorph forms, amorphous form or mixture thereof.
Preferably, the herbicide glufosinate, salts or esters thereof, used in any aspect or embodiment described herein may be replaced by, or used interchangeably as, its L-isomer i.e. L-glufosinate, salts or esters thereof.
As used herein, the term “L-glufosinate” refers to the L-isomer of glufosinate or a salt thereof. The L-isomer of glufosinate is a structural analogue of glutamate and, therefore, is a competitive inhibitor of the enzyme glutamine synthetase (GS) of bacteria and plants. The L-enantiomer of glufosinate acts by inhibition of glutamine synthetase thereby causing accumulation of toxic levels of ammonium ion and indirectly stopping photosynthesis. It is also known as phosphinothricin or (S)-2-amino-4-(hydroxy(methyl)phosphonoyl)butanoic acid. The term as used herein includes free acid form, salts and ester forms of L-glufosinate. The term very commonly covers derivatives such as salts and esters of L-glufosinate. The term can generically refer to any form of L-glufosinate or its salt such as free acid, solvates, hydrates, anhydrous form, polymorph forms, pseudo polymorph forms, amorphous form or mixture thereof, and sodium, potassium or ammonium salts. The term “L-glufosinate or a salt thereof” encompasses any salt of L-glufosinate, preferable sodium, potassium and ammonium salts. The salts of L-glufosinate such as monosodium salt, disodium salt, monopotassium salt,

dipotassium salt, calcium salt, ammonium salt, -NH3(CH3)+ salt, -NH2(CH3)2+ salt, -NH(CH3)3+salt, -NH(CH3)2(C2H4OH)+ salt, and -NH2(CH3)(C2H4OH)+ salt are included in the definition. The agronomically acceptable salts include L-glufosinate-ammonium, L-glufosinate-sodium, and L-glufosinate-potassium. The term may also refer to an isomeric (racemic) mixture of L-glufosinate, D-glufosinate and salts thereof, wherein the content of L-glufosinate or a salt thereof in the mixture is 70% or greater, preferably 80% or greater and more preferably 90% or greater. Typically, the ratio of L-glufosinate: D-glufosinate can be in the range from about 95:5 to about 99.9:0.1.
Therefore, in an embodiment, the preferred glufosinate, salts or esters thereof herbicide is L-glufosinate, salts or esters thereof.
The term ‘herbicide’ as used herein denotes a compound which controls or modifies the growth of plants. The term ‘herbicidally effective amount’ indicates the quantity of such a compound or combination of such compounds which is capable of producing a controlling or modifying effect on the growth of plants. Controlling effects include all deviation from natural development, for example: killing, retardation, leaf burn, albinism, dwarfing etc.
In an embodiment, the present invention provides an herbicidal combination comprising glufosinate, salts or esters thereof, and at least two herbicides selected from:
(a) nitrophenyl ether class of herbicides;
(b) imidazolinone class of herbicides;
(c) organophosphorous class of herbicides;
(d) dicarboximide class of herbicides;
(e) phenoxyacetic class of herbicides;
(f) pyridine class of herbicides;
(g) cyclohexene oxime class of herbicides;
(h) aryloxyphenoxypropionic class of herbicides;
(i) triazolone class of herbicides; and/or
(j) uracil class of herbicides.
In an embodiment, the present invention provides an herbicidal combination for controlling the growth of undesirable vegetation, said combination comprising glufosinate, salts or esters thereof, and at least two herbicides selected from:
(a) nitrophenyl ether class of herbicides;
(b) imidazolinone class of herbicides;

(c) organophosphorous class of herbicides;
(d) dicarboximide class of herbicides;
(e) phenoxyacetic class of herbicides;
(f) pyridine class of herbicides;
(g) cyclohexene oxime class of herbicides;
(h) aryloxyphenoxypropionic class of herbicides;
(i) triazolone class of herbicides; and/or
(j) uracil class of herbicides.
In a preferred embodiment, glufosinate, salts or esters thereof is L-glufosinate, salts or esters thereof.
In an embodiment, the present invention provides an herbicidal combination for controlling the growth of undesirable vegetation, said combination comprising L-glufosinate, salts or esters thereof, and at least two herbicides selected from:
(a) nitrophenyl ether class of herbicides;
(b) imidazolinone class of herbicides;
(c) organophosphorous class of herbicides;
(d) dicarboximide class of herbicides;
(e) phenoxyacetic class of herbicides;
(f) pyridine class of herbicides;
(g) cyclohexene oxime class of herbicides;
(h) aryloxyphenoxypropionic class of herbicides;
(i) triazolone class of herbicides; and/or
(j) uracil class of herbicides.
Preferably, the second and third herbicides may be selected from within the same class of herbicides.
Preferably, the second and third herbicides may be selected from within different classes of herbicides.
Preferably, the glufosinate, salts or esters thereof may be L-glufosinate, salts or esters thereof.
Preferably, the second herbicide is selected from the nitrophenyl ether class of herbicides, and the third herbicide is selected from the nitrophenyl ether class of herbicides; or the imidazolinone class of herbicides; or the organophosphorous class of herbicides; or

dicarboximide class of herbicides; or phenoxyacetic class of herbicides; or the pyridine class of herbicides; or the cyclohexene oxime class of herbicides; or the aryloxyphenoxypropionic class of herbicides; or the triazolone class of herbicides; or the uracil class of herbicides.
Preferably, the second herbicide is selected from the imidazolinone class of herbicides, and the third herbicide is selected from the nitrophenyl ether class of herbicides; or the imidazolinone class of herbicides; or the organophosphorous class of herbicides; or dicarboximide class of herbicides; or phenoxyacetic class of herbicides; or the pyridine class of herbicides; or the cyclohexene oxime class of herbicides; or the aryloxyphenoxypropionic class of herbicides; or the triazolone class of herbicides; or the uracil class of herbicides.
Preferably, the second herbicide is selected from the organophosphorus class of herbicides, and the third herbicide is selected from the nitrophenyl ether class of herbicides; or the imidazolinone class of herbicides; or the organophosphorous class of herbicides; or dicarboximide class of herbicides; or phenoxyacetic class of herbicides; or the pyridine class of herbicides; or the cyclohexene oxime class of herbicides; or the aryloxyphenoxypropionic class of herbicides; or the triazolone class of herbicides; or the uracil class of herbicides.
Preferably, the second herbicide is selected from the dicarboximide class of herbicides, and the third herbicide is selected from the nitrophenyl ether class of herbicides; or the imidazolinone class of herbicides; or the organophosphorous class of herbicides; or dicarboximide class of herbicides; or phenoxyacetic class of herbicides; or the pyridine class of herbicides; or the cyclohexene oxime class of herbicides; or the aryloxyphenoxypropionic class of herbicides; or the triazolone class of herbicides; or the uracil class of herbicides.
Preferably, the second herbicide is selected from the phenoxyacetic class of herbicides, and the third herbicide is selected from the nitrophenyl ether class of herbicides; or the imidazolinone class of herbicides; or the organophosphorous class of herbicides; or dicarboximide class of herbicides; or phenoxyacetic class of herbicides; or the pyridine class of herbicides; or the cyclohexene oxime class of herbicides; or the aryloxyphenoxypropionic class of herbicides; or the triazolone class of herbicides; or the uracil class of herbicides.
Preferably, the second herbicide is selected from the pyridine class of herbicides, and the third herbicide is selected from the nitrophenyl ether class of herbicides; or the imidazolinone class of herbicides; or the organophosphorous class of herbicides; or dicarboximide class of herbicides; or phenoxyacetic class of herbicides; or the pyridine class of herbicides; or the

cyclohexene oxime class of herbicides; or the aryloxyphenoxypropionic class of herbicides; or the triazolone class of herbicides; or the uracil class of herbicides.
Preferably, the second herbicide is selected from the cyclohexene oxime class of herbicides, and the third herbicide is selected from the nitrophenyl ether class of herbicides; or the imidazolinone class of herbicides; or the organophosphorous class of herbicides; or dicarboximide class of herbicides; or phenoxyacetic class of herbicides; or the pyridine class of herbicides; or the cyclohexene oxime class of herbicides; or the aryloxyphenoxypropionic class of herbicides; or the triazolone class of herbicides; or the uracil class of herbicides.
Preferably, the second herbicide is selected from the aryloxyphenoxypropionic class of herbicides, and the third herbicide is selected from the nitrophenyl ether class of herbicides; or the imidazolinone class of herbicides; or the organophosphorous class of herbicides; or dicarboximide class of herbicides; or phenoxyacetic class of herbicides; or the pyridine class of herbicides; or the cyclohexene oxime class of herbicides; or the aryloxyphenoxypropionic class of herbicides; or the triazolone class of herbicides; or the uracil class of herbicides.
Preferably, the second herbicide is selected from the triazolone class of herbicides, and the third herbicide is selected from the nitrophenyl ether class of herbicides; or the imidazolinone class of herbicides; or the organophosphorous class of herbicides; or dicarboximide class of herbicides; or phenoxyacetic class of herbicides; or the pyridine class of herbicides; or the cyclohexene oxime class of herbicides; or the aryloxyphenoxypropionic class of herbicides; or the triazolone class of herbicides; or the uracil class of herbicides.
Preferably, the second herbicide is selected from the uracil class of herbicides, and the third herbicide is selected from the nitrophenyl ether class of herbicides; or the imidazolinone class of herbicides; or the organophosphorous class of herbicides; or dicarboximide class of herbicides; or phenoxyacetic class of herbicides; or the pyridine class of herbicides; or the cyclohexene oxime class of herbicides; or the aryloxyphenoxypropionic class of herbicides; or the triazolone class of herbicides; or the uracil class of herbicides.
In an embodiment, said combinations of the present disclosure are tank-mix combinations.
In an embodiment, nitrophenyl ether class herbicide is selected from the group consisting of oxyfluorfen, acifluorfen, aclonifen, bifenox, chlomethoxyfen, chlornitrofen, etnipromid, fluorodifen, fluoroglycofen, fluoronitrofen, fomesafen, fucaomi, furyloxyfen, halosafen, lactofen, nitrofen, nitrofluorfen, and combinations thereof.

In a preferred embodiment, the nitrophenyl ether class herbicide is oxyfluorfen.
In a preferred embodiment, the nitrophenyl ether class herbicide is acifluorfen.
In a preferred embodiment, the nitrophenyl ether class herbicide is fomesafen.
In a preferred embodiment, the nitrophenyl ether class herbicide is aclonifen.
In an embodiment, the imidazolinone class herbicide is selected from the group consisting of imazethapyr, imazamethabenz, imazamox, imazapic, imazapyr, imazaquin and combinations thereof.
In a preferred embodiment, the imidazolinone class herbicide is imazethapyr.
In a preferred embodiment, the imidazolinone class herbicide is imazamox.
In a preferred embodiment, the imidazolinone class herbicide is imazapyr.
In a preferred embodiment, the imidazolinone class herbicide is imazapic.
In an embodiment, the organophosphorous class of herbicide is selected from the group
consisting of glyphosate, amiprofos-methyl, amiprophos, anilofos, bensulide, bilanafos,
butamifos, clacyfos, 2,4-DEP (2,4-Dichlorophenoxyethylphosphite), DMPA (O-(2,4-
Dichlorophenyl) O-Methyl Isopropylphosphoramidothioate), EBEP (ethyl bis(2-
ethylhexyl)phosphinate), fosamine, huangcaoling, piperophos, shuangjiaancaolin and
combinations thereof.
In a preferred embodiment, the organophosphorous class herbicide is glyphosate.
In an embodiment, the dicarboximide class herbicide is selected from the group consisting of flumioxazin, cinidon-ethyl, flumezin, flumiclorac, flumipropyn, and combinations thereof.
In a preferred embodiment, the dicarboximide class herbicide is flumioxazin.
In an embodiment, the phenoxyacetic class herbicide is selected from the group consisting of clacyfos, 2,4-D, 4-CPA (p-Chlorophenoxyacetic acid), 3,4-DA, MCPA (2-METHYL-4-CHLOROPHENOXYACETIC ACID), MCPA-thioethyl, 2,4,5-T, and combinations thereof.
In a preferred embodiment, the phenoxyacetic class herbicide is 2,4-D.
In a preferred embodiment, the phenoxyacetic class herbicide is MCPA.

In an embodiment, pyridine class herbicide is selected from the group consisting of triclopyr, aminopyralid, cliodinate, clopyralid, diflufenican, dithiopyr, florpyrauxifen, flufenican, fluroxypyr, halauxifen, haloxydine, picloram, picolinafen, pyriclor, pyroxsulam, thiazopyr, xyloxadine, and combinations thereof.
In a preferred embodiment, the pyridine class herbicide is triclopyr.
In a preferred embodiment, the pyridine class herbicide is diflufenican.
In a preferred embodiment, the pyridine class herbicide is flufenican.
In a preferred embodiment, the pyridine class herbicide is fluroxypyr.
In a preferred embodiment, the pyridine class herbicide is picloram.
In a preferred embodiment, the pyridine class herbicide is pyroxsulam.
In an embodiment, the cyclohexene oxime class herbicide is selected from the group consisting of clethodim, alloxydim, butroxydim, cloproxydim, cycloxydim, profoxydim, sethoxydim, tepraloxydim, tralkoxydim, and combinations thereof.
In a preferred embodiment, the cyclohexene oxime class herbicide is clethodim.
In an embodiment, the aryloxyphenoxypropionic class herbicide is selected from the group consisting of haloxyfop, chlorazifop, clodinafop, clofop, cyhalofop, diclofop, fenoxaprop, fenoxaprop-P, fenthiaprop, fluazifop, fluazifop-P, haloxyfop-P, isoxapyrifop, kuicaoxi, metamifop, propaquizafop, quizalofop, quizalofop-P, quizalofop-ethyl, quizalofo-P-tefuryl, trifop, and combinations thereof.
In a preferred embodiment, the aryloxyphenoxypropionic class herbicide is haloxyfop or haloxyfop-P.
In a preferred embodiment, the aryloxyphenoxypropionic class herbicide is clodinafop.
In a preferred embodiment, the aryloxyphenoxypropionic class herbicide is fenoxaprop or fenoxaprop-P.
In a preferred embodiment, the aryloxyphenoxypropionic class herbicide is quizalofop or quizalofop-P.
In a preferred embodiment, the aryloxyphenoxypropionic class herbicide is quizalofop-ethyl or quizalofop-P-tefuryl.

In an embodiment, the triazolone class herbicide is selected from the group consisting of carfentrazone, amicarbazone, bencarbazone, flucarbazone, ipfencarbazone, propoxycarbazone, sulfentrazone, thiencarbazone and combinations thereof.
In a preferred embodiment, the triazolone class herbicide is carfentrazone.
In a preferred embodiment, the triazolone class herbicide is amicarbazone.
In a preferred embodiment, the triazolone class herbicide is flucarbazone.
In a preferred embodiment, the triazolone class herbicide is ipfencarbazone.
In a preferred embodiment, the triazolone class herbicide is sulfentrazone.
In an embodiment, the uracil class herbicide is selected from the group consisting of bromacil, isocil, lenacil, terbacil, benzfendizone, butafenacil, epyrifenacil, flupropacil, saflufenacil, tiafenacil, and combinations thereof.
In a preferred embodiment, the uracil class herbicide is saflufenacil.
In an embodiment, the present invention provides a combination for controlling the growth of undesirable vegetation, said combination comprising glufosinate, salts or esters thereof and at least two herbicides, wherein the weight ratio of glufosinate, salts or esters thereof and the at least two herbicides ranges from 1:100:100 to 100:1:1.
In an embodiment, the present invention provides a combination for controlling the growth of undesirable vegetation, said combination comprising L-glufosinate, salts or esters thereof and at least two herbicides, wherein the weight ratio of L-glufosinate, salts or esters thereof and the at least two herbicides ranges from 1:100:100 to 100:1:1.
In an embodiment, the present invention provides a combination for controlling the growth of undesirable vegetation, said combination comprising glufosinate, salts or esters thereof and at least two herbicides, wherein the weight ratio of glufosinate, salts or esters thereof and the at least two herbicides ranges from 1:75:75 to 75:1:1.
In an embodiment, preferably, the weight ratio of glufosinate, salts or esters thereof and the at least two herbicides ranges from 1:50:50 to 50:1:1.
More preferably, the weight ratio between glufosinate, salts or esters thereof and the at least two herbicides ranges from 1:25:25 to 25:1:1, more preferably 1:10:10 to 10:1:1.

In a preferred embodiment, the weight ratio between glufosinate, salts or esters thereof and the at least two herbicides ranges from 1:5:5 to 5:1:1, even more preferably 1:2:2 to 2:1:1.
In an embodiment, the present invention provides a combination for controlling the growth of undesirable vegetation, said combination comprising L-glufosinate, salts or esters thereof and at least two herbicides, wherein the weight ratio of L-glufosinate, salts or esters thereof and the at least two herbicides ranges from 1:75:75 to 75:1:1.
In an embodiment, preferably, the weight ratio of L-glufosinate, salts or esters thereof and the at least two herbicides ranges from 1:50:50 to 50:1:1.
More preferably, the weight ratio between L-glufosinate, salts or esters thereof and the at least two herbicides ranges from 1:25:25 to 25:1:1, more preferably 1:10:10 to 10:1:1.
In a preferred embodiment, the weight ratio between L-glufosinate, salts or esters thereof and the at least two herbicides ranges from 1:5:5 to 5:1:1.
In an embodiment, the present invention provides a combination for controlling the growth of undesirable vegetation, said combination comprising glufosinate, salts or esters thereof and at least two herbicides, wherein the weight ratio of glufosinate, salts or esters thereof and one of the two herbicides ranges from 1:100 to 100:1.
Preferably, the weight ratio of glufosinate, salts or esters thereof and one of the two herbicides ranges from 1:75 to 75:1, more preferably 1:50 to 50:1 and even more preferably 1:25 to 25:1.
In a yet another preferred embodiment, the weight ratio of glufosinate, salts or esters thereof and one of the two herbicides ranges from 1:10 to 10:1, more preferably 1:5 to 5:1 and even more preferably 1:2 to 2:1.
In an embodiment, the present invention provides a combination for controlling the growth of undesirable vegetation, said combination comprising L-glufosinate, salts or esters thereof and at least two herbicides, wherein the weight ratio of L-glufosinate, salts or esters thereof and one of the two herbicides ranges from 1:100 to 100:1.
Preferably, the weight ratio of L-glufosinate, salts or esters thereof and one of the two herbicides ranges from 1:75 to 75:1, more preferably 1:50 to 50:1 and even more preferably 1:25 to 25:1.
In a yet another preferred embodiment, the weight ratio of L-glufosinate, salts or esters thereof and one of the two herbicides ranges from 1:10 to 10:1, more preferably 1:5 to 5:1.

According to an embodiment, the combinations of the present invention are illustrated below in Table 1.
Table 1: Exemplary combinations of glufosinate, salts or esters thereof or L-glufosinate, salts or esters thereof with at least two herbicides

Herbicide 1 Herbicide 2 Herbicide 3 Ratio of Herbicide 1:Herbicide 2 in combination and Herbicide 1:Herbicide 3 in combination Ratio of Herbicide 2:Herbicide 3 in combination
glufosinate, salts nitrophenyl nitrophenyl ether 100:1 to 1:100, 100:1 to 1:100,
or esters thereof ether herbicide herbicide different preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, from component 1 more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts nitrophenyl imidazolinone 100:1 to 1:100, 100:1 to 1:100,
or esters thereof ether herbicide herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts nitrophenyl organophosphoro 100:1 to 1:100, 100:1 to 1:100,
or esters thereof ether herbicide us herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts nitrophenyl dicarboximide 100:1 to 1:100, 100:1 to 1:100,
or esters thereof ether herbicide herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, preferably 1:25 to 25:1,

even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts nitrophenyl phenoxyacetic 100:1 to 1:100, 100:1 to 1:100,
or esters thereof ether herbicide herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts nitrophenyl pyridine herbicide 100:1 to 1:100, 100:1 to 1:100,
or esters thereof ether herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts nitrophenyl cyclohexene 100:1 to 1:100, 100:1 to 1:100,
or esters thereof ether herbicide oxime herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts nitrophenyl aryloxyphenoxypr 100:1 to 1:100, 100:1 to 1:100,
or esters thereof ether herbicide opionic herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts nitrophenyl triazolone 100:1 to 1:100, 100:1 to 1:100,
or esters thereof ether herbicide herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, preferably 1:25 to 25:1,

even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts nitrophenyl uracil herbicide 100:1 to 1:100, 100:1 to 1:100,
or esters thereof ether herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts imidazolinone nitrophenyl ether 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts imidazolinone imidazolinone 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide herbicide different preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, from component 1 more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts imidazolinone organophosphoro 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide us herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts imidazolinone dicarboximide 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, preferably 1:25 to 25:1,

even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts imidazolinone phenoxyacetic 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts imidazolinone pyridine herbicide 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts imidazolinone cyclohexene 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide oxime herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts imidazolinone aryloxyphenoxypr 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide opionic herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts imidazolinone triazolone 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, preferably 1:25 to 25:1,

even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts imidazolinone uracil herbicide 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts organophosph nitrophenyl ether 100:1 to 1:100, 100:1 to 1:100,
or esters thereof orous herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, herbicide more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts organophosph imidazolinone 100:1 to 1:100, 100:1 to 1:100,
or esters thereof orous herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, herbicide more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts organophosph organophosphoro 100:1 to 1:100, 100:1 to 1:100,
or esters thereof orous us herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, herbicide different from more preferably 1:50 to more preferably 1:50 to
salts or esters component 1 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts organophosph dicarboximide 100:1 to 1:100, 100:1 to 1:100,
or esters thereof orous herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, herbicide more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, preferably 1:25 to 25:1,

even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts organophosph phenoxyacetic 100:1 to 1:100, 100:1 to 1:100,
or esters thereof orous herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, herbicide more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts organophosph pyridine herbicide 100:1 to 1:100, 100:1 to 1:100,
or esters thereof orous preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, herbicide more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts organophosph cyclohexene 100:1 to 1:100, 100:1 to 1:100,
or esters thereof orous oxime herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, herbicide more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts organophosph aryloxyphenoxypr 100:1 to 1:100, 100:1 to 1:100,
or esters thereof orous opionic herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, herbicide more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts organophosph triazolone 100:1 to 1:100, 100:1 to 1:100,
or esters thereof orous herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, herbicide more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, preferably 1:25 to 25:1,

even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts organophosph uracil herbicide 100:1 to 1:100, 100:1 to 1:100,
or esters thereof orous preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, herbicide more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts dicarboximide nitrophenyl ether 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts dicarboximide imidazolinone 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts dicarboximide organophosphoro 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide us herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts dicarboximide dicarboximide 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide herbicide different preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, from component 1 more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, preferably 1:25 to 25:1,

even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts dicarboximide phenoxyacetic 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts dicarboximide pyridine herbicide 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts dicarboximide cyclohexene 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide oxime herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts dicarboximide aryloxyphenoxypr 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide opionic herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts dicarboximide triazolone 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, preferably 1:25 to 25:1,

even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts dicarboximide uracil herbicide 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts phenoxyacetic nitrophenyl ether 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts phenoxyacetic imidazolinone 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts phenoxyacetic organophosphoro 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide us herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts phenoxyacetic dicarboximide 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, preferably 1:25 to 25:1,

even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts phenoxyacetic phenoxyacetic 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide herbicide different preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, from component 1 more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts phenoxyacetic pyridine herbicide 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts phenoxyacetic cyclohexene 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide oxime herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts phenoxyacetic aryloxyphenoxypr 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide opionic herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts phenoxyacetic triazolone 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, preferably 1:25 to 25:1,

even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts phenoxyacetic uracil herbicide 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts pyridine nitrophenyl ether 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts pyridine imidazolinone 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts pyridine organophosphoro 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide us herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts pyridine dicarboximide 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, preferably 1:25 to 25:1,

even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts pyridine phenoxyacetic 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts pyridine pyridine herbicide 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide different from preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, component 1 more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts pyridine cyclohexene 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide oxime herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts pyridine aryloxyphenoxypr 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide opionic herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts pyridine triazolone 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, preferably 1:25 to 25:1,

even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts pyridine uracil herbicide 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts cyclohexene nitrophenyl ether 100:1 to 1:100, 100:1 to 1:100,
or esters thereof oxime herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, herbicide more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts cyclohexene imidazolinone 100:1 to 1:100, 100:1 to 1:100,
or esters thereof oxime herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, herbicide more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts cyclohexene organophosphoro 100:1 to 1:100, 100:1 to 1:100,
or esters thereof oxime us herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, herbicide more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts cyclohexene dicarboximide 100:1 to 1:100, 100:1 to 1:100,
or esters thereof oxime herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, herbicide more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, preferably 1:25 to 25:1,

even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts cyclohexene phenoxyacetic 100:1 to 1:100, 100:1 to 1:100,
or esters thereof oxime herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, herbicide more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts cyclohexene pyridine herbicide 100:1 to 1:100, 100:1 to 1:100,
or esters thereof oxime preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, herbicide more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts cyclohexene cyclohexene 100:1 to 1:100, 100:1 to 1:100,
or esters thereof oxime oxime herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, herbicide different from more preferably 1:50 to more preferably 1:50 to
salts or esters component 1 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts cyclohexene aryloxyphenoxypr 100:1 to 1:100, 100:1 to 1:100,
or esters thereof oxime opionic herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, herbicide more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts cyclohexene triazolone 100:1 to 1:100, 100:1 to 1:100,
or esters thereof oxime herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, herbicide more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, preferably 1:25 to 25:1,

even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts cyclohexene uracil herbicide 100:1 to 1:100, 100:1 to 1:100,
or esters oxime preferably 1:75 to 75:1, preferably 1:75 to 75:1,
thereofor L- herbicide more preferably 1:50 to more preferably 1:50 to
glufosinate, salts 50:1, even more 50:1, even more
or esters thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts aryloxyphenox nitrophenyl ether 100:1 to 1:100, 100:1 to 1:100,
or esters thereof ypropionic herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, herbicide more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts aryloxyphenox imidazolinone 100:1 to 1:100, 100:1 to 1:100,
or esters thereof ypropionic herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, herbicide more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts aryloxyphenox organophosphoro 100:1 to 1:100, 100:1 to 1:100,
or esters thereof ypropionic us herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, herbicide more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts aryloxyphenox dicarboximide 100:1 to 1:100, 100:1 to 1:100,
or esters thereof ypropionic herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, herbicide more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, preferably 1:25 to 25:1,

even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts aryloxyphenox phenoxyacetic 100:1 to 1:100, 100:1 to 1:100,
or esters thereof ypropionic herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, herbicide more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts aryloxyphenox pyridine herbicide 100:1 to 1:100, 100:1 to 1:100,
or esters thereof ypropionic preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, herbicide more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts aryloxyphenox cyclohexene 100:1 to 1:100, 100:1 to 1:100,
or esters thereof ypropionic oxime herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, herbicide more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts aryloxyphenox aryloxyphenoxypr 100:1 to 1:100, 100:1 to 1:100,
or esters thereof ypropionic opionic herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, herbicide different from more preferably 1:50 to more preferably 1:50 to
salts or esters component 1 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts aryloxyphenox triazolone 100:1 to 1:100, 100:1 to 1:100,
or esters thereof ypropionic herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, herbicide more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, preferably 1:25 to 25:1,

even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts aryloxyphenox uracil herbicide 100:1 to 1:100, 100:1 to 1:100,
or esters thereof ypropionic preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, herbicide more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts triazolone nitrophenyl ether 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts triazolone imidazolinone 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts triazolone organophosphoro 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide us herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts triazolone dicarboximide 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, preferably 1:25 to 25:1,

even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts triazolone phenoxyacetic 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts triazolone pyridine herbicide 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts triazolone cyclohexene 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide oxime herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts triazolone aryloxyphenoxypr 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide opionic herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts triazolone triazolone 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide herbicide different preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, from component 1 more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, preferably 1:25 to 25:1,

even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts triazolone uracil herbicide 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts uracil nitrophenyl ether 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts uracil imidazolinone 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts uracil organophosphoro 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide us herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts uracil dicarboximide 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, preferably 1:25 to 25:1,

even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts uracil phenoxyacetic 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts uracil pyridine herbicide 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts uracil cyclohexene 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide oxime herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts uracil aryloxyphenoxypr 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide opionic herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts uracil triazolone 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide herbicide preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, preferably 1:25 to 25:1,

even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
glufosinate, salts uracil uracil herbicide 100:1 to 1:100, 100:1 to 1:100,
or esters thereof herbicide different from preferably 1:75 to 75:1, preferably 1:75 to 75:1,
or L-glufosinate, component 1 more preferably 1:50 to more preferably 1:50 to
salts or esters 50:1, even more 50:1, even more
thereof preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:25 to 25:1, even more preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
Preferably, the following exemplary combinations of the invention as illustrated in Table 2 were synergistic:
Table 2

Herbicide 1 Herbicide 2 Herbicide 3 Ratio of Herbicide 1:Herbicide 2 in combination and Herbicide 1:Herbicide 3 in combination Ratio of Herbicide 2:Herbicide 3 in combination
Glufosinate, Oxyfluorfen Acifluorfen 100:1 to 1:100, preferably 100:1 to 1:100, preferably
salts or esters 1:75 to 75:1, more 1:75 to 75:1, more
thereof or L- preferably 1:50 to 50:1, preferably 1:50 to 50:1,
glufosinate, even more preferably 1:25 even more preferably 1:25
salts or esters to 25:1, even more to 25:1, even more
thereof preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
Glufosinate, Oxyfluorfen Fomesafen 100:1 to 1:100, preferably 100:1 to 1:100, preferably
salts or esters 1:75 to 75:1, more 1:75 to 75:1, more
thereof or L- preferably 1:50 to 50:1, preferably 1:50 to 50:1,
glufosinate, even more preferably 1:25 even more preferably 1:25
salts or esters to 25:1, even more to 25:1, even more
thereof preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
Glufosinate, Oxyfluorfen Aclonifen 100:1 to 1:100, preferably 100:1 to 1:100, preferably
salts or esters 1:75 to 75:1, more 1:75 to 75:1, more
thereof or L- preferably 1:50 to 50:1, preferably 1:50 to 50:1,
glufosinate, even more preferably 1:25 even more preferably 1:25

salts or esters to 25:1, even more to 25:1, even more
thereof preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
Glufosinate, Oxyfluorfen Imazethapyr 100:1 to 1:100, preferably 100:1 to 1:100, preferably
salts or esters 1:75 to 75:1, more 1:75 to 75:1, more
thereof or L- preferably 1:50 to 50:1, preferably 1:50 to 50:1,
glufosinate, even more preferably 1:25 even more preferably 1:25
salts or esters to 25:1, even more to 25:1, even more
thereof preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
Glufosinate, Oxyfluorfen Imazamox 100:1 to 1:100, preferably 100:1 to 1:100, preferably
salts or esters 1:75 to 75:1, more 1:75 to 75:1, more
thereof or L- preferably 1:50 to 50:1, preferably 1:50 to 50:1,
glufosinate, even more preferably 1:25 even more preferably 1:25
salts or esters to 25:1, even more to 25:1, even more
thereof preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
Glufosinate, Oxyfluorfen Imazapyr 100:1 to 1:100, preferably 100:1 to 1:100, preferably
salts or esters 1:75 to 75:1, more 1:75 to 75:1, more
thereof or L- preferably 1:50 to 50:1, preferably 1:50 to 50:1,
glufosinate, even more preferably 1:25 even more preferably 1:25
salts or esters to 25:1, even more to 25:1, even more
thereof preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
Glufosinate, Oxyfluorfen Glyphosate 100:1 to 1:100, preferably 100:1 to 1:100, preferably
salts or esters 1:75 to 75:1, more 1:75 to 75:1, more
thereof or L- preferably 1:50 to 50:1, preferably 1:50 to 50:1,
glufosinate, even more preferably 1:25 even more preferably 1:25
salts or esters to 25:1, even more to 25:1, even more
thereof preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
Glufosinate, Oxyfluorfen Flumioxazin 100:1 to 1:100, preferably 100:1 to 1:100, preferably
salts or esters 1:75 to 75:1, more 1:75 to 75:1, more
thereof or L- preferably 1:50 to 50:1, preferably 1:50 to 50:1,
glufosinate, even more preferably 1:25 even more preferably 1:25
salts or esters to 25:1, even more to 25:1, even more
thereof preferably 1:10 to 10:1 and most preferably 1:5 to 5:1. preferably 1:10 to 10:1 and most preferably 1:5 to 5:1.
Glufosinate, Oxyfluorfen 2,4-D 100:1 to 1:100, preferably 100:1 to 1:100, preferably
salts or esters 1:75 to 75:1, more 1:75 to 75:1, more

We Claim:
1. An herbicidal combination comprising glufosinate, salts or esters thereof, and at least
two herbicides selected from:
(a) nitrophenyl ether class of herbicides;
(b) imidazolinone class of herbicides;
(c) organophosphorous class of herbicides;
(d) dicarboximide class of herbicides;
(e) phenoxyacetic class of herbicides;
(f) pyridine class of herbicides;
(g) cyclohexene oxime class of herbicides;
(h) aryloxyphenoxypropionic class of herbicides;
(i) triazolone class of herbicides; and/or
(j) uracil class of herbicides.
2. The combination as claimed in claim 1, wherein the glufosinate, salts or esters thereof is L- glufosinate, salts or esters thereof.
3. The combination as claimed in claim 1, wherein the second and third herbicides are selected from within the different classes of herbicides.
4. The combination as claimed in claim 1, wherein the second and third herbicides are selected from within the same class of herbicides.
5. The combination as claimed in claim 1, wherein the weight ratio of glufosinate, salts or esters thereof and the at least two herbicides ranges from 1:100:100 to 100:1:1.
6. The combination as claimed in claim 1, wherein the weight ratio of glufosinate, salts or esters thereof and one of the two herbicides ranges from 1:100 to 100:1.
7. The combination as claimed in claim 1, wherein:
(a) the nitrophenyl ether class herbicide is selected from the group consisting of
oxyfluorfen, acifluorfen, aclonifen, bifenox, chlomethoxyfen, chlornitrofen, etnipromid, fluorodifen, fluoroglycofen, fluoronitrofen, fomesafen, fucaomi,

furyloxyfen, halosafen, lactofen, nitrofen, nitrofluorfen, and combinations thereof;
(b) the imidazolinone class herbicide is selected from the group consisting of imazethapyr, imazamethabenz, imazamox, imazapic, imazapyr, imazaquin, and combinations thereof;
(c) the organophosphorous class herbicide is selected from the group consisting of glyphosate, amiprofos-methyl, amiprophos, anilofos, bensulide, bilanafos, butamifos, clacyfos, 2,4-DEP, DMPA ((O-(2,4-dichlorophenyl) O-methyl isopropylphosphoramidothioate)), EBEP (ethyl bis(2-ethylhexyl)phosphinate), fosamine, glufosinate-P, piperophos, and combinations thereof;
(d) the dicarboximide class herbicide is selected from the group consisting of cinidon-ethyl, flumezin, flumiclorac, flumioxazin, flumipropyn, and combinations thereof;
(e) the phenoxyacetic class herbicide is selected from the group consisting of clacyfos, 4-CPA (p-Chlorophenoxyacetic acid), 2,4-D, 3,4-DA, MCPA (2-methyl-4-chlorophenoxyacetic acid), MCPA-thioethyl, 2,4,5-T and combinations thereof;
(f) the pyridine class herbicide is selected from the group consisting of aminopyralid, cliodinate, clopyralid, diflufenican, dithiopyr, florpyrauxifen, flufenican, fluroxypyr, halauxifen, haloxydine, picloram, picolinafen, pyriclor, pyroxsulam, thiazopyr, triclopyr, xyloxadine, and combinations thereof;
(g) the cyclohexene oxime class herbicide is selected from the group consisting of alloxydim, butroxydim, clethodim, cloproxydim, cycloxydim, profoxydim, sethoxydim, tepraloxydim, tralkoxydim, and combinations thereof;
(h) the aryloxyphenoxypropionic class herbicide is selected from the group
consisting of chlorazifop, clodinafop, clofop, cyhalofop, diclofop, fenoxaprop, fenoxaprop-P, fenthiaprop, fluazifop, fluazifop-P, haloxyfop, haloxyfop-P, isoxapyrifop, metamifop, propaquizafop, quizalofop, quizalofop-P, quizalofop-P-tefuryl, quizalofop-ethyl, trifop, and combinations thereof;
(i) the triazolone class herbicide is selected from the group consisting of
amicarbazone, bencarbazone, carfentrazone, flucarbazone, ipfencarbazone, propoxycarbazone, sulfentrazone, thiencarbazone and combinations thereof; and/or

(j) the uracil class herbicide is selected from the group consisting of bromacil,
isocil, lenacil, terbacil, benzfendizone, butafenacil, epyrifenacil, flupropacil, saflufenacil, tiafenacil, and combinations thereof.
8. The combination as claimed in claim 1, wherein:
(a) the nitrophenyl ether class herbicide is oxyfluorfen;
(b) the imidazolinone class herbicide is selected from imazethapyr, imazapic, imazapyr or combinations thereof;
(c) the organophosphorous class of herbicide is glyphosate;
(d) the dicarboximide class herbicide is flumioxazin;
(e) the phenoxyacetic class herbicide is 2,4-D;
(f) the pyridine class herbicide is triclopyr;
(g) the cyclohexene oxime class herbicide is clethodim;
(h) the aryloxyphenoxypropionic class herbicide is haloxyfop;
(i) the triazolone class herbicide is carfentrazone; and/or
(j) the uracil class herbicide is saflufenacil.
9. The combination as claimed in claim 1, wherein glufosinate, salts or esters thereof, is present in an amount in the range of 100 to 400 g ai/L, preferably 180 to 380 g ai/L.
10. The combination as claimed in claim 1, wherein:

(a) the nitrophenyl ether class herbicide present in an amount in the range of 100 to 400 g ai/L;
(b) the imidazolinone class herbicide present in an amount in the range of 10 to 250 g ai/L or 100 – 1000 g ai/L;
(c) the organophosphorous class herbicide present in an amount in the range of 200 to 1000 g ai/L;
(d) the dicarboximide class herbicide present in an amount in the range of 200 – 800 g ai/L;
(e) the phenoxyacetic class herbicide present in an amount in the range of 200 to 1200 g ai/L;
(f) the pyridine class herbicide present in an amount in the range of 300 – 1000 g ai/L;

(g) the cyclohexene oxime class herbicide present in an amount in the range of 100
– 400 g ai/L;
(h) the aryloxyphenoxypropionic class herbicide present in an amount in the range
of 1 to 250 g ai/L;
(i) the triazolone class herbicide present in an amount in the range of 100 – 800 g
ai/L; and/or
(j) the uracil class herbicide present in an amount in the range of 1 – 1000 g ai/L.
11. An herbicidal composition comprising the combination as claimed in claim 1-10, and at least one agrochemically suitable excipient.
12. The composition as claimed in claim 11, wherein the composition is a tank-mix composition.
13. A method of controlling the growth of undesirable vegetation at a locus, the method comprising treating the locus with an herbicidal combination or a composition as claimed in claims 1 – 12.
14. The method as claimed in claim 13, wherein the glufosinate is applied at an application rate of 50 - 350 g ai/h, preferably 100 g ai/h to 250 g ai/h.
15. The method as claimed in claim 13, wherein at least two herbicides are selected from

(a) the nitrophenyl ether class herbicide applied at an application rate of 5-250 g ai/h;
(b) the imidazolinone class herbicide applied at an application rate of 5-200 g ai/h;
(c) the organophosphorous class herbicide applied at an application rate of 100-800 g ai/h;
(d) the dicarboximide class herbicide applied at an application rate of 1 to 200 g ai/h;
(e) the phenoxyacetic class herbicide applied at an application rate of 50 – 400 g ai/h;
(f) the pyridine class herbicide applied at an application rate of 50-500 g ai/h;

(g) the cyclohexene oxime class herbicide applied at an application rate of 1-150
g ai/h;
(h) the aryloxyphenoxypropionic class herbicide applied at an application rate of
1 -150 g ai/h;
(i) the triazolone class herbicide applied at an application rate of 0.5-100 g ai/h;
and/or
(j) the uracil class herbicide applied at an application rate of 10-150 g ai/h.
16. An herbicidal combination comprising glufosinate, salts or esters thereof, or L-glufosinate, salts or esters thereof, a pyridine class herbicide and an uracil class herbicide.
17. The combination as claimed in claim 16, wherein the pyridine class herbicide is triclopyr.
18. The combination as claimed in claim 16, wherein the uracil class herbicide is saflufenacil.
19. An herbicidal combination comprising glufosinate, salts or esters thereof, or L-glufosinate, salts or esters thereof, a phenoxyacetic class herbicide and an uracil class herbicide.
20. The combination as claimed in claim 19, wherein the phenoxyacetic class herbicide is 2,4-D.
21. The combination as claimed in claim 19, wherein the uracil class herbicide is saflufenacil.
22. An herbicidal combination comprising glufosinate, salts or esters thereof, or L-glufosinate, salts or esters thereof, and two herbicides selected from the imidazolinone class herbicides.

23. The combination as claimed in claim 22, wherein the imidazolinone herbicides are imazapic and imazapyr.

Documents

Application Documents

# Name Date
1 202121047126-STATEMENT OF UNDERTAKING (FORM 3) [18-10-2021(online)].pdf 2021-10-18
2 202121047126-PROVISIONAL SPECIFICATION [18-10-2021(online)].pdf 2021-10-18
3 202121047126-POWER OF AUTHORITY [18-10-2021(online)].pdf 2021-10-18
4 202121047126-FORM 1 [18-10-2021(online)].pdf 2021-10-18
5 202121047126-DECLARATION OF INVENTORSHIP (FORM 5) [18-10-2021(online)].pdf 2021-10-18
6 202121047126-FORM-26 [16-11-2021(online)].pdf 2021-11-16
7 202121047126-Proof of Right [17-11-2021(online)].pdf 2021-11-17
8 202121047126-Covering Letter [03-12-2021(online)].pdf 2021-12-03
9 202121047126-REQUEST FOR CERTIFIED COPY [07-03-2022(online)].pdf 2022-03-07
10 202121047126-CORRESPONDENCE(IPO)-(CERTIFIED COPY)-(14-03-2022).pdf 2022-03-14
11 202121047126-FORM 18 [17-10-2022(online)].pdf 2022-10-17
12 202121047126-CORRESPONDENCE-OTHERS [17-10-2022(online)].pdf 2022-10-17
13 202121047126-COMPLETE SPECIFICATION [17-10-2022(online)].pdf 2022-10-17
14 202121047126-FORM 3 [20-01-2023(online)].pdf 2023-01-20
15 202121047126-FER.pdf 2023-10-05
16 202121047126-OTHERS [04-04-2024(online)].pdf 2024-04-04
17 202121047126-Information under section 8(2) [04-04-2024(online)].pdf 2024-04-04
18 202121047126-FORM-26 [04-04-2024(online)].pdf 2024-04-04
19 202121047126-FORM 3 [04-04-2024(online)].pdf 2024-04-04
20 202121047126-FER_SER_REPLY [04-04-2024(online)].pdf 2024-04-04
21 202121047126-COMPLETE SPECIFICATION [04-04-2024(online)].pdf 2024-04-04
22 202121047126-CLAIMS [04-04-2024(online)].pdf 2024-04-04
23 202121047126-ABSTRACT [04-04-2024(online)].pdf 2024-04-04
24 202121047126-ORIGINAL UR 6(1A) FORM 26-290424.pdf 2024-05-03

Search Strategy

1 SearchStrategyE_04-10-2023.pdf