FIELD OF INVENTION:
The present invention relates to the liquid soap. The present invention in particular relates to the eco-friendly insecticidal and fungicidal liquid soap for plants comprising terpineol and Ortho Silicic Acid.
DESCRIPTION OF THE RELATED ART:
Many different kinds of pesticides are used to kill insects. Depending on the mode of action, the insecticides can be classified in two broad groups, chemical and physical insecticides. One of the problems found when using chemically acting insecticides is that the insect can build up resistance in succeeding generations. Also they are undesirable because they can collect in food or in water resources and they can be toxic to animals and people.
US20080045587A1 relates to a method for protecting wheat prior to harvest from microbial attack, comprising the step of applying an antimicrobial composition to the surface of the wheat, wherein said antimicrobial composition consists essentially of (i) benzyl alcohol and (ii) propylene glycol. The insecticidal activity of soaps is known (See U.S. Pat. No. 4,904,645 and U.S. Pat. No. 5,030,658). Soaps are naturally occurring materials having no known long-term environmental effects. However high concentrations of soap can be detrimental to the plants themselves. U.S. Pat. No. 4,904,645 discloses an insecticidal solution for application to decorative and crop plants comprising a mixture of alkali metal salts of monocarboxylic acids, pyrethrum, a solvent for the pyrethrum and an antioxidant. U.S. Pat. No. 5,030,658 teaches the use of a sodium or potassium salt of a mixture of monocarboxylic fatty acids and a chelant agent in order to provide an arthropodicidal solution with maximum amount of active soap. U.S. Pat. No. 4,379,168, U.S. Pat. No. 4,933,371 and U.S. Pat. No. 6,004,569 use different components of plant natural oils to kill different invertebrates.
Terpenes are bio-active compounds and there are numerous reports in the literature concerning their effects as antibacterial, antifungal, antihelminthic and antimitotic agents. Various terpenes are used in agriculture for growth inhibition, growth promotion and in the food industry as flavorings and fragrances. Interest in the potential for using terpenes in medical applications is increasing.y^^^Pv^X

U.S. Pat. No. 6,004,569 discloses a pesticide and a method to kill invertebrates, insects, arachnids and larvae thereof. A blend of cinnamic alcohol, eugenol and alpha terpineol is prepared. The blend is mixed with a carrier to produce a uniform mixture. The pesticide comprises a terpene having a six membered carbon ring and at least one oxygenated functional group and a carrier. This Patent talk about mixture of Terpineols, which require emulsifiers as Terpineols are insoluble in water.
US20030060379A1 relates to environmentally friendly soap-based pesticide having improved efficacy against aphids and other insect pests. The pesticide also has insect-repellent properties. The pesticide comprises one or more adjuncts selected from natural oils, evaporation retardants, particulate, physically-active insecticidal materials, and mixtures thereof. Here different natural oils, evaporation retardants or physically active insecticidal compounds added to Soap. This addition is done after soap making.
WO2001013726A1 relates to a pesticide to exterminate terrestrial arthropods comprising as an adive ingredient of the pesticide an arthropodicidally effedive amount of a mixture of the terpene compounds redistilled limonene, beta-ionone, linalool, geraniol, eugenol and one of the terpenes from a group of carvone and myrcene, wherein the ingredients are diluted in solution. These formulations prepared by addition of terpines and terpineols in Shampoo
Insecticidal soaps have many advantages when compared to other insecticides. They are inexpensive to use, are among the safest pesticides, leave no harsh residue, are natural products that are virtually non-toxic to animals and birds, and can be used on vegetables up to harvest. Most beneficial insects are not harmed by soap sprays.
Conventional patent uses benzoic acid, alkali benzoate, lecithins, SLS/SDS, pyrethrins, essential oils and tar as one of the ingredient in insecticidal soap.
Accordingly, there is a need of an improved insecticidal and germicidal liquid
soap for plants which eliminates the use of alcohol for saponification so that
sopanification is done at lower temperature. /^%^KA'.^.,

The present invention aims to provide an ecofreindly insecticidal and fungicidal liquid soap for plants in which sopanification is done at lower temperature by using terpineol and OSA (Ortho Silicic Acid).
OBJECTS OF THE INVENTION:
The principal object of the present invention is to provide an ecofreindly insecticidal and fungicidal liquid soap for plants in which sopanification is done at lower temperature by using terpineol and OSA (Ortho Silicic Acid).
Another object of the present invention is to provide an effective insecticidal and fungicidal liquid soap which enhances the plant growth by killing harmful insects and germs of plant.
SUMMARY OF THE INVENTION:
The present invention provides an ecofreindly insecticidal and fungicidal liquid soap for plants in which sopanification is done at lower temperature by using terpineol and OSA (Ortho Silicic Acid). The soap is composed essentially of water, fatty acids derived from animal and plant origin oils, source of potassium base, terpineols and OSA. The animal oil is fish oil, more specifically sulphited fish oil and or refined fish oil. Plant oils are such as without limitation castor oil, cotton seed oil, cedar wood oil, moringa oil, Indian beech seed oil, coconut oil, free fatty acids (C-10 to C-20).
Terpineols i.e. monoterpene alcohols (specially alpha-terpineol, beta-terpineol gamma-terpineol and 4-terpineol individually or in mixture) is being that not only help to saponification at lower temperature but also brace the soap with fungicidal activity.
BREIF DESCRIPTION OF THE DRAWINGS:
It is to be noted, however, that the appended drawings illustrate only typical
embodiments of this invention and are therefore not to be considered for
limiting of its scope, for the invention may admit to other equally effective
embodiments. 4%'z ^S! -4^.

Figure 1 shows effect of Potassium soap in control of white fly in brinjal Figure 2 shows effect of Potassium soap in control of aphids in cotton Figure 3 shows effect of Potassium soap in control of jassids in cotton Figure 4 shows effect of Potassium soap in control of thrips in cotton Figure 5 shows effect of Potassium soap in control of white flies in cotton
DETAILED DESCRIPTION OF THE INVENTION:
The present invention provides an ecofriendly insecticidal and fungicidal liquid soap for plants in which saponification is done at lower temperature by using terpineol and OSA (Ortho Silicic Acid). The soap is clear and transparent soap composition in liquid form, aims to provide insecticidal and fungicidal properties.
The soap is composed essentially of water, fatty acids derived from animal and plant origin oils, source of potassium base, terpineols and OSA. The animal oil is fish oil, more specifically sulphited fish oil and or refined fish oil. Plant oils are such as without limitation castor oil, cotton seed oil, cedar wood oil, moringa oil, Indian beech seed oil, coconut oil, free fatty acids (C-10 to C-20).
Terpineols i.e. monoterpene alcohols (specially alpha-terpineol, beta-terpineol gamma-terpineol and 4-terpineol individually or in mixture) is being that not only help to saponification at lower temperature but also brace the soap with fungicidal activity.
Fatty acids derived from animal origin and plant origin oils, mixed together in
proportion explained in recipes and heated to constant temperature between 60-
95°C. On achieving desired temperature mixture of terpineols added in percentage
of 0.5-7.0% w/w, after stirring for 2-5 minutes solution of potassium lye added
slowly with continues stirring and constant temperature. After addition of
potassium lye stirring continues until batch passes soap test. Source of potassium
lye used is derived from potassium hydroxide. The potassium lye volume is
calculated on the basis of standard saponification values of individual oils and
fatty acid Table 1. /^':^^7^
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Table 1:

Ingredients Recipe 1 Recipe 2 Recipe 3 Recipe 4 Recipe 5
Sulphited Fish Oil 1.0-10% - 1.0-10% 1.0-10% -
Refined Fish Oil - 1.0-10% - - 1.0-10%
Castor Oil 10-50% 10-50% - 10-50% 5.0-40%
Moringa Oil 1.0-8.0% - 1.0-8.0% 5.0-40% 1.0-8.0%
Cedarwood Oil 0.2-3.0% 0.2-3.0% 0.2-3.0% - -
Cotton Seed Oil - 1.0-8.0% 10-50% - 10-50%
Indian beech Seed oil - - - 0.2-3.0% 0.2-3.0%
Karanj Oil 5.0-40% 5.0-40% 5.0-40% - -
Coconut Oil - 0.5-7.0% - 1.0-8.0% 0.5-7.0%
Stearic acid 0.5-7.0% - 0.5-7.0% 0.5-7.0% -
Potassium Lye 5.0-20% 5.0-20% 5.0-20% 5.0-20% 5.0-20%
Mixture of Terpineols 0.5-7.0% 0.5-7.0% 0.5-7.0% 0.5-7.0% 0.5-7.0%
Water 15-55% 15-55% 15-55% 15-55% 15-55%
Ortho Silicic Acid 0.01-0.50% 0.01-0.50% 0.01-0.50% 0.01-0.50% 0.01-0.50%
Temperature 60-95°C 60-95°C 60-95°C 60-95°C 60-95°C
Stirring Time (Hours) 2-6 2-6 2-6 2-6 2-6
Stirring Speed (RPM) 80-300 80-300 80-300 80-300 80-300
pH 9-12 9-12 9-12 9-12 9-12
Mixtures of terpineols used in recipes are prepared just before additions. Terpineols i.e. monoterpene alcohols, especially alpha-terpineol, beta-terpineol gamma-terpineol and 4-terpineol used individually or in the form of following mixtures (table 2). Table 2:

Terpineols Mi x 1 Mi x2 Mix
3 Mix 4 Mix
5 Mix 6 Mix
7 Mix 8 Mix 9 Mi
X
10 Mi
X
11
alpha-terpineol 10 0% - - - 25% 50% 50% 50% - - -
beta-terpineol - 100 % - - 25% . 50% - - 50% 50 % -
gamma-terpineol 100 % 25% 50% 50% 50 %
4-terpineol - - - 100 % 25% - - 50% - 50 % 50 %
Effect of Potassium Soap in Control of White Fly in Brinjal (fig 1)
Analysis on efficacy of Potassium soap were conducted on the field during the
Kharif. Crop- Brinjal, Application method- Foliar, Number of applications- 01,

Stage of application- Flowering/disease outbreak. Number of plants per treatment-20 and treatments: Control, 2) Potassium Soap (5ml/L)5 3) Synthetic Insecticide (0.3g/L). Data is collected from 5 plants from each treatment and control. Data recorded on 0, 1, 3, 5 and 7th day after spraying.
Effect of Potassium Soap in Control of Aphids in Cotton (fig 2) Analysis on efficacy of Potassium soap were conducted on the field during the Kharif-2018. Crop- Cotton, Application method- Foliar, Number of applications-01, Number of replication- 02, Stage of application- Flowering and Boll formation. Number of plants per treatment- 15, Treatments: 1) Control, 2) Potassium Soap (5ml/L), 3) Synthetic Insecticide (0.3g/L) Data is collected from 5 plants from each replication i.e. 10 plants from treatment and control. Data
th
recorded on 0, 1, 3, 5 and 7 day after spraying.
Effect of Potassium Soap in Control of Jassids in Cotton (fig 3) Analysis on efficacy of Potassium soap were conducted on the field during the Kharif-2018. Crop- Cotton, Application method- Foliar, Number of applications-01, Number of replication- 02, Stage of application- Flowering and Boll formation. Number of plants per treatment- 15, Treatments: 1) Control, 2) Potassium Soap (5ml/L), 3) Synthetic Insecticide (0.3g/L). Data is collected from 5 plants from each replication i.e. 10 plants from treatment and control. Data recorded on 0, 1, 3, 5 and 7th day after spraying.
Effect of Potassium Soap in Control of Thrips in Cotton (fig 4) Analysis on efficacy of Potassium soap were conducted on the field during the Kharif-2018. Crop- Cotton, Application method- Foliar, Number of applications-01, Number of replication- 02, Stage of application- Flowering and Boll formation. Number of plants per treatment- 15, Treatments: 1) Control, 2) Potassium Soap (5ml/L), 3) Synthetic Insecticide (0.3g/L) Data is collected from 5 plants from each replication i.e. 10 plants from treatment and control. Data recorded on 0, 1, 3, 5 and 7th day after spraying.
Effect of Potassium Soap in Control of White Flies in Cotton (fig 5)


Analysis on efficacy of Potassium soap were conducted on the field during the Kharif-2018. Crop- Cotton, Application method- Foliar, Number of applications-01, Number of replication- 02, Stage of application- Flowering and Boll formation. Number of plants per treatment- 15, Treatments: 1) Control, 2) Potassium Soap (5ml/L), 3) Synthetic Insecticide (0.3g/L). Data is collected from 5 plants from each replication i.e. 10 plants from treatment and control. Data recorded on 0, 1, 3, 5 and 7 day after spraying.
To analyze the effect of Potassium soap in control of Pathogenic Fungal Organisms (table 3), in-vitro studies were carried out for screening of fungicidal activity of Potassium Soap. Potassium Soap is diluted at 0.5% and I % concentration and inoculated on PDA plate at the time of fungal inoculation. Data collected on 7 Day after inoculation and % inhibition calculated as compared to Control plate (where fungal organism inoculated without any treatment). Table 3: Effect of Potassium Soap on growth of pathogenic Fungi (on 7th Day after Inoculation)

Organisms KSOP

0.5% Concentration 1.0% Concentration
Sclerotioum spp. 95% Inhibition 100% Inhibition
Fusarium spp. 100% Inhibition 100% Inhibition
Ceratocystis spp. 100% Inhibition 100% Inhibition

Numerous modifications and adaptations of the system of the present invention will be apparent to those skilled in the art, and thus it is intended by the appended claims to cover all such modifications and adaptations which fall within the true spirit and scope of this invention.
Privi Life Sciences Pvt Ltd>^ ^.
Dated .V.L.day of. J.^?.., 2019

WE CLAIM:
1. An ecofriendly insecticidal and fungicidal liquid soap for plants comprising of water, fatty acids derived from animal and plant origin oils, source of potassium base, terpineols and OSA.
2. The ecofriendly insecticidal and fungicidal liquid soap for plants as claimed in claim 1 wherein the method of preparing insecticidal and fungicidal liquid soap includes following steps:

a) Fatty acids derived from animal origin and plant origin oils, mixed together and heated to constant temperature between 60-95°C.
b) On achieving desired temperature mixture of terpineols added in percentage of 0.5-7.0% w/w,
c) After stirring for 2-5 minutes solution of potassium lye added slowly with continues stirring and constant temperature.
d) After addition of potassium lye stirring continues until batch passes soap test.
e) The potassium lye volume is calculated on the basis of standard saponification values of individual oils and fatty acid.

3. The ecofriendly insecticidal and fungicidal liquid soap for plants as claimed in claim 1 wherein saponification is done at lower temperature by using terpineol and OSA (Ortho Silicic Acid).
4. The ecofriendly insecticidal and fungicidal liquid soap for plants as claimed in claim 1 wherein the animal oil is sulphited fish oil and or refined fish oil.

5. The ecofriendly insecticidal and fungicidal liquid soap for plants as claimed in claim 1 wherein plant oils are castor oil, cotton seed oil, cedar wood oil, moringa oil, Indian beech seed oil, coconut oil, free fatty acids (C-10 to C-20).
6. The ecofriendly insecticidal and fungicidal liquid soap for plants as claimed in claim 1 wherein the ingredients/ combination of ingredients use are Sulphited Fish Oil 1.0-10%, Refined Fish Oil 1.0-10%, Castor Oil 10-50%, Moringa Oil 1.0-8.0%, Cedarwood Oil 0.2-3.0%, Cotton Seed Oil 1.0-50%, Indian beech Seed oil 0.2-3.0%, Karanj Oil 5.0-40%, Coconut Oil 0.2-8.0% Stearic acid 0.5-7.0%, Potassium Lye 5.0-20%, Mixture of Terpineols 0.5-7.0%, Water 15-55%, Ortho Silicic Acid 0.01-0.50%, at temperature 60-95°C, Stirred for 2-6 Hours, stirring speed (RPM) 80-300, and pH 9-12