Description
ASSEMBLY FOR REVERSIBLE FUEL CELL
Cross Reference to a Related Application
[0001] This application claims priority to European application No. 10174543.8
filed on August 30, 2010, the whole content of this application being
incorporated herein by reference for all purposes.
Technical Field
[0002] The present invention is generally directed to fuel cells and more
specifically to reversible fuel cells and their components.
Background Art
[0003] Fuel cells are electrochemical devices which can convert energy stored in
fuels to electrical energy with high efficiencies by oxidation of a fuel and
reduction of an oxidizing agent. The fuel and the oxidizing agent, undergo
a redox reaction at two isolated electrodes, each containing a catalyst in
contact with an electrolyte. The electrolyte is located between the
electrodes to prevent direct reaction of the two reactants and to conduct
ions from one side of the cell to the other. Advantageously the electrolyte
can be a solid polymer electrolyte.
[0004] A broad range of reactants can be used in fuel cells. For example, the fuel
may be substantially pure hydrogen gas, a gaseous hydrogen-containing
reformate stream, or methanol in a direct methanol fuel cell. The oxidant
may be, for example, substantially pure oxygen or a dilute oxygen stream
such as air.
[0005] On the other hand, an electrolyzer uses electricity to produce different
chemical species, e.g. hydrogen and oxygen from water or chlorine,
sodium hydroxide and hydrogen from an alkaline brine. An electrolyzer
basically involves a fuel cell operating in reverse.
[0006] Fuel cells that allow reversed operation, such that oxidized fuel can be
reduced back to unoxidized fuel using electrical energy as an input, are
generally referred to as "reversible" or "regenerative" fuel cells. The ability
to generate electricity and regenerate fuel makes reversible fuel cells
particularly attractive for electrical energy storage.
[0007] Of particular interest are the so-called unitized regenerative fuel cells, that
is reversible fuel cells wherein both the energy generation mode of
operation (the fuel cell mode) and the electrolysis mode of operation are
carried out within the same cell stack. Because the electroactive
components of such a cell must operate in both electrolysis and fuel cell
modes, it is difficult to optimize them for both.
[0008] As an example US 2003/0068544 A (CISAR, A.) 10/04/2003 discloses an
unitized regenerative hydrogen-oxygen fuel cell wherein the oxygen
electrode comprises an electrocatalyst layer containing a mixture of a
catalyst active for the evolution of oxygen from water and of a catalyst
active for the reduction of oxygen to water. The gas diffusion layer for the
oxygen electrode comprises hydrophobic and hydrophilic regions. With
such a configuration however the transport of water to and from the
differently active electrocatalytic areas of the electrode does not appear to
be optimal.
[0009] Thus, the need still exists for unitized regenerative fuel cells capable to
operate with the highest efficiency both in the fuel cell mode and in the
electrolysis mode.
Summary of invention
[001 0] A first objective of the present invention is an assembly for use in a
reversible fuel cell, in particular in an unitized regenerative fuel cell
provided with optimised activity both when the cell is operated in the
electrolysis mode and in the energy generation mode. An additional
objective of the present invention is a reversible fuel cell comprising the
assembly.
Brief description of drawings
[001 1] Figure 1 is a schematic cross-section of a membrane-electrode assembly
of the invention.
[0012] Figures 2 and 3 are schematic views of the components of a membraneelectrode
assembly according to a first and to a second embodiment of the
invention.
[001 3] Figure 4 is a schematic view of the components of an assembly
comprising a membrane-electrode assembly and gas diffusion layers
according to a further embodiment of the invention.
[0014] Figure 5 is a schematic view of the components of a fuel cell stack
comprising a membrane-electrode assembly, gas diffusion layers and
bipolar plates according to an additional embodiment of the invention.
Description of invention
[0015] First object of the present invention is a membrane-electrode assembly for
a reversible fuel cell. The expression "membrane electrode assembly" is
used herein to refer to an assembly which comprises an ion conductive
membrane disposed between two electrocatalyst layers, each comprising
an appropriate catalyst for facilitating the desired electrochemical reaction,
located adjacent the ion conductive membrane.
[0016] With reference to Figure 1, the assembly of the invention (1) comprises an
ion conductive membrane ICM having a first and a second surface. A first
electrocatalyst layer E 1 is in contact with the first surface of the membrane
and a second electrocatalyst layer E2 is in contact with the second surface
of the membrane.
[0017] First electrocatalyst layer E 1 comprises at least one discrete electrolysisactive
area (ELE1,) and at least one discrete energy generation-active
area (EG1,). Second electrocatalyst layer comprises at least one discrete
electrolysis-active area (ELE2,) and at least one discrete energy
generation-active area (EG2,). Each one of the discrete electrolysis-active
area(s) ELE1, on first electrocatalyst layer E 1 corresponds and is aligned
with each one of the discrete electrolysis-active area(s) ELE2, on second
electrocatalyst layer E2. Each one of the discrete energy generation-active
area(s) EG1, on first electrocatalyst layer E 1 corresponds and is aligned
with each one of the discrete energy generation-active area(s) EG2, on
second electrocatalyst layer E2.
[0018] The expression "corresponds and is aligned with" referred to a discrete
area on any element of the assembly of the invention is used herein to
indicate that the area has the same size and shape and is aligned with a
corresponding area on the surface of the ion conductive membrane or with
a corresponding area on the surface of the equivalent element on the
opposite side of the ion conductive membrane.
[001 9] Figure 2 shows an embodiment of the assembly ( 1) of the invention
comprising the ion conductive membrane (ICM) and first and second
electrocatalyst layers E 1 and E2. In the embodiment shown in Figure 2
each electrocatalyst layer comprises one discrete electrolysis-active area
(ELE1 and ELE2) and one energy generation-active area (EG1 and EG2).
[0020] Each electrocatalyst layer (E1 and E2) may comprise more than one
electrolysis-active area ELE, and more than one energy generation-active
area EG,.
[0021] Each electrolysis-active area on the first electrocatalyst layer ELE1,
corresponds and is aligned with each electrolysis-active area ELE2, on
second electrocatalyst layer E2, and each energy generation-active area
EG1i corresponds and is aligned with each energy generation-active area
[0022] The total electrolysis-active area on E 1 (å ELE1, ) equals the total
electrolysis-active area on E2 (å ELE2,) and the total energy generationactive
area on E 1 (å EG1,) equals the total energy generation-active area
on E2 (å EG2i). Thus: å ELE1, = å ELE2, and å EG1, = å EG2,.
[0023] There is no limitation on the number, size and shape of the areas of each
type EG, and ELE, in the assembly of the invention provided they form
discrete, individually distinct areas. In general the size of each area will
depend on the size of the assembly although, typically, areas EG, and
ELEi will have a surface of at least 0.01 mm2, even of at least 0.1 mm2,
possibly even greater than 0.5 mm2.
[0024] The number i of each type of area will typically range from 1 to 100,
preferably from 1 to 50, more preferably from 1 to 20. The areas may have
any shape, although regular shapes may be preferred.
[0025] The sum of all of the discrete electrolysis-active areas å ELE1 ,(or å
ELE2i), which corresponds to the extension of electrolysis-active area
ELE1 when i=1 , may be the same or different than the sum of all of the
discrete energy generation-active areas on each of the electrocatalyst
layers å EG1i (or å EG2i).
[0026] In the case of an assembly for use in a hydrogen/oxygen fuel cell typically
å EG1i is greater than å ELE1, and consequently å EG2, is greater than å
ELE2i. Preferably the ratio å EG,/å ELE, ranges from 1.5:1 to 5:1 , more
preferably from 2:1 to 4.5 :1 , even more preferably from 2.5:1 to 4:1 . An
even more preferred ratio may be from 2.8:1 to 3.5:1 .
[0027] In other types of reversible fuel cells the ratio between the energy
generation-active areas and the electrolysis-active areas on each
electrocatalyst layers may be different and will typically depend on the
voltage generated by the reactions in the two modes of operation of the
cell.
[0028] Each discrete electrolysis-active area ELE, is separated from each energy
generation-active area EG, by at least one boundary region BRj. The
number of boundary regions j will depend on the number of energy
generation-active areas and electrolysis-active areas as well as on their
arrangement on the electrocatalyst layers. The boundary region may be a
simple discontinuity in the electrocatalyst layer deriving from the change in
composition or morphology between the electrolysis-active area(s) and the
adjacent energy generation-active area(s).
[0029] Alternatively, the boundary region BRj may be a discrete region
characterised by a composition different from the composition of any of the
adjacent areas ELE, and EG,. The boundary region BRj may
advantageously have a different composition than each of the adjacent
areas ELE, and EG,. The boundary region may be characterized by a
different electrical conductivity than the adjacent areas, e.g. no or
negligible electrical conductivity.
[0030] Among the systems that may be used in reversible fuel cells the most
environmentally attractive is the hydrogen/oxygen/water system. This
system uses the electrochemical reaction of hydrogen and oxygen to
produce water when operating in the energy generation mode (or fuel cell
mode). Hydrogen and oxygen can be regenerated by the electrolysis of
water when the cell operates in the electrolysis mode.
[0031] Hydrogen/oxygen fuel cells may operate both in an acidic environment,
using an hydrogen ion conductive membrane, and in an alkaline
environment, using an hydroxyl ion conductive membrane.
[0032] The components of the inventive assembly will be described in detail with
reference to hydrogen/oxygen fuel cells although it is well understood that
the assembly of the invention is by no means limited to the use in
hydrogen/oxygen based reversible fuel cells.
[0033] First electrocatalyst layer E 1
[0034] First electrocatalyst layer E 1 is in contact with the first surface of the ion
conductive membrane ICM. First electrocatalyst layer E 1 comprises
discrete electrolysis-active area(s) ELE1 ,and discrete energy generationactive
area(s) EG1,. Each discrete electrolysis-active area ELE1 ,is
separated from each energy generation-active area EG1, by at least one
boundary region BR1j.
[0035] Without being limited by this selection and for the sake of description first
electrocatalyst layer will be hereinafter described as the oxygen electrode
in a hydrogen/oxygen fuel cell. When the cell operates in the fuel-cell
mode, oxygen will be reduced at the energy generation-active area(s)
EG1i producing water. When the cell operates in the electrolysis mode
water will be oxidised at the electrolysis-active area(s) ELE1 , producing
oxygen.
[0036] In general known highly active catalysts for oxygen reduction are poor
catalysts for water oxidation and oxygen evolution. Accordingly, the
catalyst used in the energy generation-active area(s) EG , will typically be
different from the catalyst used in the electrolysis-active area(s) ELEIi of
the oxygen electrode. The choice of catalysts will also be different
depending on the operating environment of the cell, whether acidic or
alkaline.
[0037] When the cell is operated in an acidic environment, a suitable catalyst for
the energy generation-active area(s) EG1, can be selected from metals
such as platinum, palladium, rhodium and alloys thereof. The catalytically
active metals or metal alloys can also contain other elements such as
ruthenium, cobalt, chromium, tungsten, molybdenum, vanadium, iron,
copper, nickel. The metals may be unsupported or supported on suitable
electrically conductive particles. Carbon blacks, graphite or active charcoal
may advantageously be used as supports. A preferred catalyst for the
energy generation-active area(s) EG1, is platinum supported on carbon
black.
[0038] Suitable catalysts for the electrolysis-active area(s) ELE1 , are mixed metal
or mixed metal oxides, comprising for instance ruthenium and iridum
oxides or iridium and titanium oxides, optionally supported on carbon black
or any other suitable support as discussed above.
[0039] When the cell is operated in an alkaline environment, a suitable catalyst
for the energy generation-active area(s) EG1, is for instance silver, both
supported and unsupported. A suitable catalyst for the electrolysis-active
area(s) ELE1, is selected from supported or unsupported nickel. Suitable
supports are as discussed above.
[0040] Typically the electrocatalyst layer comprises a binder in addition to the
catalyst. The binder may be selected among perfluorinated ionically
conductive polymers which are also suitable for the preparation of ion
conductive membranes.
[0041] In an embodiment of the assembly of the invention, areas EG1, and ELE1,
on first electrocatalytic layer E 1 may additionally differ in their water affinity
characteristics. To improve the presence of water at the surface of
electrolysis-active area(s) ELE1,, where water is oxidised producing
oxygen, a hydrophilic surface may be preferred. On the other hand energy
generation-active area(s) EG1, are preferably hydrophobic, to facilitate the
removal of water which is produced by the reduction of oxygen taking
place at the electrocatalyst layer. The different properties could be
obtained for instance by using different binders in the preparation of each
discrete area on the electrocatalyst layer.
[0042] Second electrocatalyst layer E2
[0043] Second electrocatalyst layer E2 is in contact with the second surface of
the ion conductive membrane ICM. Second electrocatalyst layer E2
comprises discrete electrolysis-active area(s) ELE2, and discrete energy
generation-active area(s) EG2,. Each discrete electrolysis-active area
ELE2, is separated from each energy generation-active area EG2, by at
least one boundary region BR¾.
[0044] Second electrocatalyst layer will be hereinafter described as the hydrogen
electrode of a hydrogen/oxygen fuel cell. Thus, when the cell is operating
in the fuel-cell mode hydrogen will be oxidised at the energy generationactive
area(s) EG2, producing hydrogen ions. When the cell is operating in
the electrolysis mode hydrogen ions will be reduced at the electrolysisactive
area(s) ELE2, producing hydrogen.
[0045] Suitable catalysts for the energy generation-active area(s) EG2, in a
hydrogen/oxygen fuel cell operating in an acidic environment are for
instance platinum or equimolar mixtures of rhodium and ruthenium oxides.
Said catalysts may be unsupported or supported as described above.
Additionally, to facilitate the access of hydrogen to the energy generationactive
area(s) EG2, said areas may be provided with high permeability to
gases. A suitable catalyst for the electrolysis-active area(s) ELE2, is
platinum supported on carbon black.
[0046] When the hydrogen/oxygen fuel cell operates in an alkaline environment a
suitable catalyst for both the energy generation-active area(s) EG2, and
the electrolysis-active area(s) ELE2, is nickel, unsupported or supported as
described above.
[0047] Areas EG2, and ELE2, on second electrocatalytic layer E2 may additionally
differ in other properties, such as their water affinity characteristics or their
gas transmission properties as mentioned above. These different
properties could be obtained for instance by using different binders or
additives in the preparation of the different areas of the electrocatalytic
layer.
[0048] The ion conductive membrane
[0049] The role of the electrolyte in an electrochemical cell is to advantageously
allow the passage of ions from one side of the cell to the other to maintain
the neutral balance on each side of the cell without allowing the direct
reaction of the active species. The electrolyte, or preferably the ion
conductive membrane, may be either cationic or anionic in nature.
[0050] In a first design of a hydrogen/oxygen fuel cell, operating in an acidic
environment, the ion conductive membrane has to allow hydrogen ions to
pass through it while at the same creating a barrier towards the
permeation of hydrogen and oxygen from one side of the cell to the other.
Thus, in such a cell the electrolyte is anionic in nature.
[0051] In a second design of a hydrogen/oxygen fuel cell, operating in an alkaline
environment, the ion conductive membrane has to allow hydroxyl ions to
pass through it while at the same creating a barrier towards the reactants.
Thus, in such a cell the electrolyte is cationic in nature.
[0052] Typically the ion conductive membrane comprises an ion conductive
polymeric material, although ion conductive membranes made of liquids or
gels could also be used in the assembly of the invention.
[0053] Any suitable ion conductive polymeric material may be used in the
assembly of the present invention. In general, perfluorinated polymers
comprising ionic groups are preferably used as ion conductive materials in
fuel cells due to their chemical and thermal resistance.
[0054] Anionic polymeric materials are generally selected among the copolymers
of tetrafluoroethylene and one or more fluorinated monomers comprising
an ion exchange group, such as sulfonic acid, carboxylic acid, phosphoric
acid groups. More generally anionic polymeric materials may be selected
among the copolymers of tetrafluoroethylene and one or more fluorinated
monomers comprising a precursor group for sulfonic acid, such as
F2C=CF-O-CF2-CF2-SO2F; F2C=CF-O-[CF2-CXF-O]n-CF2-CF2-SO2F
wherein X= CI, F or CF3 and n=1-10; F C=CF-O-CF -CF -CF -SO F;
F C=CF-O-CF -CF -CF -CF -SO F; F C=CF-Ar-SO F wherein Ar is an
aryl ring. Suitable materials are for instance those marketed by E.I.
DuPont under the trade name Nafion®, those marketed by Solvay Solexis
under the trade name Aquivion® or those marketed by Asahi Glass Co.
under the trade name Flemion®. Fluorine-free, ion conductive polymeric
materials such as sulfonated polyether ketones or aryl ketones or aciddoped
polybenzimidazoles could also be used.
[0055] Cationic polymeric materials are generally selected from polymers,
preferably fluorinated polymers, comprising amino or acrylic acid ion
exchange groups.
[0056] The ion conductive polymeric material typically has an equivalent weight of
no more than 1700 g/eq, more typically of no more than 1500 g/eq, more
typically of no more than 1200 g/eq, and most typically of no more than
1000 g/eq. The ion conductive polymeric material typically has an
equivalent weight of at least 380 g/eq, preferably at of least 500 g/eq,
more preferably of at least 600 g/eq.
[0057] EP-A-1323744, EP-A-1 179548, EP-A-1 167400, EP-A-1589062, EP-A-
1702670, EP-A-1 702688 disclose suitable ion conductive polymer
materials and ion conductive membranes for use in the assembly of the
invention.
[0058] The ion conductive membrane may consist of the polymer electrolyte or it
may comprise the polymer electrolyte impregnated or coated on a suitable
porous support. For instance, US 5635041 describes an impregnated
membrane comprising an expanded polytetrafluoroethylene support.
Impregnated membranes are also described in US 484931 1.
[0059] In a first embodiment of the inventive assembly the ion conductive
membrane has the same composition throughout its extension.
[0060] In a second embodiment the ion conductive membrane is divided in
discrete areas, typically corresponding and aligned with each of the
electrolysis-active area couples (ELE1, and ELE2,) and each of the energy
generation-active area couples (EG1, and EG2,) on electrocatalyst layers
E 1 and E2 on the first and second surfaces of the ion conductive
membrane. The areas may have the same or different composition.
[0061] With reference to Figure 3 the area of the ion conductive membrane in
contact with the electrolysis-active areas on electrocatalyst layers E 1 and
E2 is indicated as ICMELE whereas the area of the ion conductive
membrane in contact with the energy generation-active areas on
electrocatalyst layers E 1 and E2 is indicated as ICMEG. It is understood
that the number of areas ICMELE and ICMEG on the ion conductive
membrane will correspond to the number of electrolysis-active areas and
energy generation-active areas in the electrcatalyst layers E 1 and E2.
[0062] For instance ion conductive polymeric materials with different equivalent
weights could be used in the electrolysis-active areas and energy
generation-active areas ICMELEI and ICMEGI of the ion conductive
membrane.
[0063] In a further embodiment each electrolysis-active area ICMELEI is separated
from each energy generation-active area ICMEGI by a boundary region
ICMBRJ which will typically correspond to the boundary region between
each electrolysis-active area and each energy generation-active area on
the electrocatalyst layers (BR1j and BR¾, respectively).
[0064] Boundary region(s) ICMBRJ may be a simple discontinuity in the ion
conductive membrane deriving from the change in composition or
morphology between the electrolysis-active area(s) and the adjacent
generation-active area(s). Alternatively, the boundary region ICMBRJ may
be a discrete region characterised by a composition different from the
composition of any of the adjacent areas ICMELEI and ICMEGI.
[0065] The boundary region ICMBRJ may advantageously have a different
composition than each of the areas ICMELEI and ICMEGI. The boundary
region may be characterized by a different ionic conductivity than the
adjacent areas, e.g. no or negligible ionic conductivity. Alternatively the
boundary region may have different water affinity properties than the
adjacent areas. Still alternatively the boundary region may have different
gas transmission properties. For instance, boundary region(s) ICM BRJ
could be characterized by lower ionic conductivity and lower water
adsorption properties than each of the adjacent areas ICMELEI and ICMEGI.
[0066] Gas diffusion layers
[0067] In a typical fuel cell design gas diffusion layers are placed in contact with
each electrocatalyst layer, to bring gaseous reactants (e.g. oxygen and
hydrogen) to the electrocatalyst layers and at the same time to create an
electrical contact with the remaining components of the fuel cell, e.g
bipolar plates. The gas diffusion layers are typically porous to allow the
passage of gaseous reactants and they include electrically conductive
particles to impart electrical conductivity.
[0068] The assembly of the invention may further comprise a first gas diffusion
layer GDL1 in contact with the surface of electrocatalyst layer E 1 not in
contact with the ion conductive membrane and a second gas diffusion
layer GDL2 in contact with the surface of electrocatalyst layer E2 not in
contact with the ion conductive membrane.
[0069] Gas diffusion layers GDL1 and GDL2 may have the same composition and
structure or they may be different.
[0070] In an embodiment of the invention gas diffusion layer GDL1 in contact with
electrocatalyst layer E 1 is divided in discrete areas, typically
corresponding in size and aligned with each of the electrolysis-active
areas (GDLI ELEI) and each of the energy generation-active areas
(GDLI EGI) on the first electrocatalyst layer E 1.
[0071] With reference to Figure 4 the area of the gas diffusion layer in contact
with the electrolysis-active area on each of the electrocatalyst layers is
indicated as GDLELE whereas the area of the gas diffusion layer in contact
with the energy generation-active areas on each of the electrocatalyst
layers is indicated as GDLEG . It is understood that, when present, the
number of areas GDLELE and GDLEG on the gas diffusion layers will
correspond to the number of electrolysis-active areas and energy
generation-active areas on the electroactive layers.
[0072] Each electrolysis-active area GDLELEI is separated from each energy
generation-active area GDLEGI by a boundary region GDLBRJ which will
typically correspond to the boundary region between each electrolysisactive
area and each energy generation-active area on each of the
electroactive layers (BR1j and BR¾, respectively).
[0073] Boundary region(s) GDLBRJ may be a simple discontinuity in the gas
diffusion layer deriving from the change in composition or morphology
between the electrolysis-active area(s) and the adjacent generation-active
area(s). Alternatively, the boundary region GDLBRJ may be a discrete
region characterised by a composition different from the composition of
any of the adjacent areas GDLELEI and GDLEGI.
[0074] The boundary region GDLBRJ may advantageously have a different
composition than each of the areas GDLELEI and GDLEGI . The boundary
region may be characterized by a different electrical conductivity than the
adjacent areas, e.g. no or negligible electrical conductivity. Alternatively
the boundary region may have different water affinity properties than the
adjacent areas. Still alternatively the boundary region may have different
gas transmission properties. For instance, boundary region(s) GDLBRJ
could be characterized by no or negligible electrical conductivity than each
of the adjacent areas GDLELEI and GDLEGI.
[0075] In the specific embodiment shown in Figure 4 , gas diffusion layer GDL1
comprises an electrolysis-active area GDLI ELE and an energy generationactive
area GDLI EG, separated by a boundary region GDLI BR.
[0076] To improve to delivery of water to electrolysis-active area ELE1 area
GDLI ELE is preferably hydrophilic. Energy generation-active area on the
gas diffusion layer GDLI EG may advantageously be hydrophobic.
[0077] Similarly, gas diffusion layer GDL2 comprises an electrolysis-active area
GDL 2ELE and an energy generation-active area GDL 2EG, separated by a
boundary region GDL 2BR. Areas GDL 2ELE and GDL 2EG may have the
same or different composition and/or properties. Electrolysis-active area
GDL 2ELE may be hydrophilic and energy generation-active area on the gas
diffusion layer GDL 2EG may advantageously be hydrophobic.
[0078] Typically GDL 2EG will be provided with higher gas transport properties
than GDL 2ELE to allow the flow of hydrogen towards the surface of the
energy generation-active area EG2.
[0079] Preparation of the assembly
[0080] The electrocatalyst layers E 1 and E2 can be applied to the ion conductive
membrane or the gas diffusion layers GDL1 and GDL2 by various
conventional methods.
[0081] Electrocatalyst layers E 1 and E2 could be applied to the first and second
surfaces of the ion conductive membrane by standard coating or printing
techniques, using different compositions for each of the electrolysis-active
areas ELE, and each of the energy generation-active areas EG,.
[0082] Alternatively, each electrocatalyst layer E 1 and E2 could be applied, using
different compositions for each of the electrolysis-active areas ELE, and
each of the energy generation-active areas EG,, first to the surface of the
corresponding gas diffusion layer (GDL1 or GDL2) and then placed in
contact with the first or second surface of the ion conductive membrane
using known hot pressing or lamination techniques.
[0083] Several methods could be used to fabricate ion conductive membranes
having discrete electrolysis-active areas and energy generation-active
areas ICMELE and ICMEG. For instance in the case of membranes
comprising an ion conductive polymer impregnated onto a porous support,
different ion conductive polymer solutions or dispersions could be used to
impregnate different areas of the porous support.
[0084] Alternatively, when the ion conductive membrane is made of an extruded
film of the ion conductive polymer, parallel discrete electrolysis-active
areas and energy generation-active areas could be directly obtained by
extruding different types of ion conductive polymers through appropriate
extrusion dies, such as those described in US3807918.
[0085] Gas diffusion layers comprising discrete electrolysis-active areas and
energy generation-active areas could be obtained, for example, by
bonding alternating strips of hydrophobic and hydrophilic gas diffusion
material to an electrocatalyst coated membrane to produce a striped
pattern. Alternating bands of gas diffusion materials having different
properties could be deposited onto a common substrate.
[0086] Alternatively, sub-assemblies comprising all of the energy generationactive
portions of the assembly, that is EG 1/ICMEG/EG2 or optionally
GDL EG/EG 1 /ICMEG/EG 2/GDL2EG, and all of the electrolysis-active
portions of the assembly, that is ELE 1/ICMELE/ELE 1 or
GDL ELE/ELE 1/ICMELE/ELE2/GDL2ELE, could be manifactured separately
and then assembled together by means of suitable adhesives or gaskets.
[0087] The assembly of the invention, comprising membrane-electrode assembly
(1) sandwiched between gas diffusion layers GDL1 and GDL2 may further
comprise a first and a second bipolar plate (BP1 and BP2) positioned on
each side and in contact with first and second gas diffusion layers,
respectively, as shown in Figure 5.
[0088] Bipolar plates are suitably shaped sheets made of electrically conductive
materials impervious to the cell reactants, such as graphite or metals.
Bipolar plates are typically provided with grooves and/or channels for
distributing reactants to the electrocatalyst layers.
[0089] First and second bipolar plates may each comprise at least one discrete
electrolysis-active area (BPELEI) and at least one discrete energy
generation-active area (BPEGI), each of them corresponding in size and
aligned with each of the electrolysis-active areas (GDLELEI) and each of the
energy generation-active areas (GDLEGI) on the first and second gas
diffusion layers.
[0090] An assembly comprising a membrane-electrode assembly, gas diffusion
layers and bipolar plates is typically referred to as a fuel cell stack.
Preferably the fuel cell stack of the invention is a single block.
[0091] Additional elements, such as gasket, seals and the like, may be present in
the assembly or stack of the invention as conventionally known in the art.
[0092] The assembly of the invention is suitable for use in a reversible fuel cell.
[0093] The assemblies of the invention have been described with reference to the
drawings as a planar assembly, however other configurations are possible
and within the scope of the present claims, in particular a configuration
wherein the discrete energy generation-active and electrolysis-active
portions of the assembly would be arranged around the circumference of a
cylindrically shaped assembly.
[0094] Should the disclosure of any patents, patent applications, and publications
which are incorporated herein by reference conflict with the description of
the present application to the extent that it may render a term unclear, the
present description shall take precedence.
Claims
1. Assembly for an electrochemical cell comprising: an ion conductive membrane
having first and second surface; a first electrocatalyst layer in contact with the
first surface of the membrane said first electrocatalyst layer comprising at least
one discrete electrolysis-active area (ELE 1,) and at least one discrete energy
generation-active area (EG 1,) ; a second electrocatalyst layer in contact with
the second surface of the membrane said second electrocatalyst layer
comprising at least one discrete electrolysis-active area (ELE2,) and at least
one discrete energy generation-active area (EG2,) ; wherein each of the at least
one discrete electrolysis-active area (ELE 1,) on said first electrocatalyst layer
corresponds and is aligned with each of the at least one discrete electrolysisactive
area (E LE2,) on said second electrocatalyst layer and wherein each of
the at least one discrete energy generation-active area (EG 1,) on said first
electrocatalyst layer corresponds and is aligned with each of the at least one
discrete energy generation-active area (EG2,) on said second electrocatalyst
layer.
2 . Assembly according to claim 1 wherein the ion conductive membrane
comprises at least one discrete area corresponding and aligned with each of
the electrolysis-active areas (ELE 1, and E LE2,) on said first and second
electrocatalyst layer and at least one discrete area corresponding and aligned
with each of the energy generation-active areas (EG 1, and EG2,) on said first
and second electrocatalyst layer.
3 . Assembly according to claim 1 or 2 further comprising a first gas diffusion layer
(GDL1 ) in contact with the surface of said first electrocatalyst layer not in
contact with the ion conductive membrane and a second gas diffusion layer
(GDL2) in contact with the surface of said second electrocatalyst layer not in
contact with the ion conductive membrane.
4 . Assembly according to claim 3 wherein said first gas diffusion layer (GDL1 )
comprises at least one discrete electrolysis-active area (GDLI ELEI)
corresponding and aligned with each of the at least one electrolysis-active
areas on the first electrocatalyst layer and at least one discrete energy
generation-active area (GDLI EGI) corresponding and aligned with each of the
at least one energy generation-active areas on the first electrocatalyst layer.
5 . Assembly according to claim 3 or 4 wherein said second gas diffusion layer
(GDL2) comprises at least one discrete electrolysis-active area (GDL2ELEI)
corresponding and aligned with each of the at least one electrolysis-active
areas on the second electrocatalyst layer and at least one discrete energy
generation-active area (GDL2EGI) corresponding and aligned with each of the
at least one energy generation-active areas on the second electrocatalyst
layer.
6 . Assembly according to claim 4 or 5 wherein the at least one discrete
electrolysis-active area on the first and/or second gas diffusion layer is
hydrophilic and wherein the at least one discrete energy generation-active area
on the first and/or second gas diffusion layer is hydrophobic.
7 . Assembly according to any one of claims 3 to 6 comprising a first bipolar plate
in contact with the first gas diffusion layer and a second bipolar plate in contact
with the second gas diffusion layer, said first and second bipolar plates each
optionally comprising at least one discrete energy generation-active area and
at least one discrete electrolysis-active area corresponding and aligned with
each of the at least one electrolysis-active and energy generation-active areas
on the first and second gas diffusion layers.
8. Assembly according to any preceding claim comprising at least one boundary
region between each discrete energy generation-active areas and each
discrete electrolysis-active areas on said first and second electrocatalyst
layers, and/or on said ion conductive membrane and/or on said first and
second gas diffusion layers and/or on said first and second bipolar plates.
9. Assembly according to claim 8 wherein said at least one boundary region has
a composition different from the composition of any of the adjacent energy
generation-active areas and electrolysis-active areas.
10. Assembly according to any preceding claim wherein said electrolysis-active
areas on said first and second electrocatalyst layers comprise catalysts
suitable for the electrolysis of water.
11. Assembly according to any one of the preceding claims wherein said energy
generation-active areas on said first and second electrocatalyst layers
comprise catalysts suitable for the production of water from hydrogen and
oxygen.
12. Assembly according to claims 9 or 10 wherein the ratio between the sum of all
of the discrete energy generation-active areas on said first or second
electrocatalyst layer and the sum of all of the discrete electrolysis-active areas
on said first or second electrocatalyst layer is in the range from 1.5:1 to 5:1 .
13. Assembly according to claim 11 wherein the ratio is in the range from 2.8:1 to
3.5:1 .
14. Fuel cell comprising the assembly of any one of claims 1 to 13.
15. Use of the assembly according to any one of claims 1 to 13 in a reversible fuel
cell.