WO 2006/015668 PCT/EP2005/007211
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Catalysts containing tungstate for the synthesis of alkyl mercaptan and method for the production thereof
The present invention relates to a catalyst comprising alkali metal tungstate for the synthesis of alkyl mercaptans from alkanols and hydrogen sulphide, and to a process for preparing this catalyst.
In this patent application, the term alkali is understood to mean the bound alkali metals of the Periodic Table of the Elements or mixtures of at least two alkali metals bound in the tungstates. In this case, caesium occurs only together with a further element of the alkali metal group.
Methyl mercaptan in particular is an industrially important intermediate, for example for the synthesis of methionine and for the synthesis of dimethyl sulphoxide and dimethyl sulphone. It is nowadays prepared predominantly from methanol and hydrogen sulphide by reaction over a catalyst composed of aluminium oxide. The methyl mercaptan is synthesized commonly in the gas phase at temperatures between 3 00 and 500°C and at pressures between 1 and 25 bar.
In addition to the methyl mercaptan formed, the reaction mixture comprises the unconverted starting materials and by-products, for example dimethyl sulphide and dimethyl ether, and also the gases which are inert for the purposes of the reaction, for example methane, carbon monoxide, hydrogen and nitrogen. The methyl mercaptan formed is removed from this reaction mixture.
For the economic viability of the process, a maximum selectivity is required in the catalytic reaction of methanol and hydrogen sulphide to give methyl mercaptan in order to keep the removal of the methyl mercaptan formed from the reaction mixture as uncomplicated and inexpensive as possible. Here, especially the energy demands for the

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cooling of the reaction gas mixture to condense the methyl mercaptan constitute a large cost factor.
To increase activity and selectivity, aluminium oxide as a support is typically admixed with potassium tungstate or caesium tungstate. In this case, the tungstate is commonly used in amounts up to 25% by weight based on the total weight of the catalyst. An improvement of activity and selectivity is also obtained by increasing the molar ratio of hydrogen sulphide to methanol. Typically, molar ratios between 1 and 10 are employed.
However, a high molar ratio also means a high excess of hydrogen sulphide in the reaction mixture and thus the need to conduct large amounts of gas in circulation. To reduce the energy demands required for this purpose, the ratio of hydrogen sulphide to methanol should therefore deviate only slightly from 1.
US Patent 2,820,062 relates to a process for preparing organic thiols, in which a catalyst composed of active aluminium oxide which is admixed with potassium tungstate in an amount of 1.5 to 15% by weight, based on the weight of the catalyst, is used. With this catalyst, good activities and selectivities are achieved at reaction temperatures of 400°C and molar ratios of 2. This US patent mentions various possibilities for the introduction of the potassium tungstate into the aluminium oxide. For instance, it is said to be possible to employ impregnation processes, coprecipitations and pure mixtures. Little significance is attributed to the actual preparation of the catalyst for the economic viability of the synthesis process of methyl mercaptan.
EP 0 832 687 Bl describes the advantages of the use of caesium tungstate (CS2WO4) instead of potassium tungstate (K2WO4) as a promoter. For instance, use of caesium

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tungstate can achieve an enhanced activity with simultaneously good selectivity.
Increasing the caesium tungstate concentration to up to 40% by weight allows the selectivity for methyl mercaptan to be increased to 92% without the activity being disproportionately worsened.
According to the general view, the best selectivity is achieved with catalysts for which the alkali metal/tungsten ratio is equal to 2:1 (A.V. Mashkina et al., React. Kinet. Catal. Lett., Vol. 36, No. 1, 159-164 (1988).
It is an object of the present invention to specify a catalyst and a process for its preparation, which, at low molar ratios of hydrogen sulphide to methanol, features improved activity and selectivity compared to the known catalysts and thus leads to better economic viability of the process.
This object is achieved by the provision of a catalyst comprising a catalytically active alkali metal tungstate which contains bound alkali metals and tungsten with a molar ratio of alkali metals to tungsten of < 2:1, in particular of < 2:1 to 0.9:1, preferably 1.9:1 to 1:1, particularly 1.6:1 to 1:1.
The oxidic composition can be described with the formula AxWOy in which A is alkali metal and x is < 2 to 0.9 and y is 3.4 to < 4.
The bound alkali metal constituent of the tungstate can be composed of one or more elements of the alkali metal group. In this case, caesium occurs only in combination with another alkali metal element.
The catalyst contains the tungstate in an amount of 8 to 45% by weight, in particular 15 to 36% by weight, preferably > 25 to 36% by weight. In the case of a coated

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catalyst, these proportions are based on the composition of the coating.
The oxidic compounds composed of alkali metal(s) and tungsten may be impregnated directly onto a support body (supported catalyst).
In the case of the preparation of catalysts in the form of extrudates or mouldings, the pulverulent support is impregnated or mixed with the oxidic composition and the resulting intermediate is subsequently reshaped (unsupported catalyst). When a coated catalyst is prepared, the pulverulent support is impregnated with the catalytically active composition and the resulting mixture is then applied to a preferably inert support core in the form of a coating.
The alkali metal/W ratio preferably ranges from < 1.9:1 to 1:1. The inventive catalysts for the reaction of alkanols with hydrogen sulphide to give alkyl mercaptans thus comprise a superstoichiometric proportion of tungsten compared to the catalyst impregnated with caesium tungstate (Cs2WO4) or potassium tungstate (K2WO4) according to the prior art.
It is found that this higher proportion in the tungstate on the aluminium oxide used with preference in comparison to the stoichiometric alkali metal tungstate used exclusively in the prior art imparts to the catalyst an improved activity with simultaneously improved selectivity. While the increase in the concentration of caesium tungstate (Cs2WO4) on the catalyst merely brings about an increase in the selectivity with simultaneously lower activity, a further increase in the selectivity with simultaneously increased activity is unexpectedly found in the case of the increase in the tungsten content in relation to the alkali metal content. According to the invention, an excellent activity can be achieved at very high loadings with the

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promoter without the activity of the catalyst, as known from the prior art, decreasing. In addition, it has also been found that the activity and selectivity of the catalyst can be adjusted precisely via the alkali metal-tungsten ratio and via the selection of the alkali metals. When mixtures of alkali metals are used, it is additionally possible to replace the comparatively more expensive metals such as caesium or rubidium at least partly with less expensive metals, for example potassium or sodium, without the activity or selectivity of the catalyst being impaired.
The catalyst is used in the form of a supported catalyst in which the surface is impregnated with the catalytically active substance, or of a coated catalyst in which a preferably inert core is surrounded with a mixture of catalytically active substance and support material. In addition, extrudates or mouldings in which the catalytically active substance is mixed with the pulverulent support material before the reshaping or is impregnated with it may be used. The support materials used are the known oxidic inorganic compounds, for example SiO2, TiO2/ ZrO2 and preferably what is known as active aluminium oxide. This material has high specific surface areas between about 10 and 400 m2/g and consists mainly of oxides of the transition series of the crystallographic phases of aluminium oxide (see, for example, Ullmann's Encyclopaedia of Industrial Chemistry of 1985, Vol. Al, pages 561-562) . These transition oxides include ? -, d -, ?-, ?- , ?- and ?-aluminium oxide. All of these crystallographic phases are converted on heating of the aluminium oxide to temperatures above 1100°C to the thermally stable a-aluminium oxide. Active aluminium oxide is supplied commercially for catalytic applications in various qualities and supply forms. Particularly suitable for the preparation of supported catalysts are support bodies composed of granulated or extruded aluminium oxide having particle diameters of 1 to 5 mm, a specific surface area of 180 to

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400 m2/g, a total pore volume between 0.3 and 1.2 ml/g, and a bulk density of 300 to 900 g/1. Fir the purposes of the invention, preference is given to using aluminium oxide having a specific surface area of more than 200 m2/g, since the catalytic activity of the finished catalyst rises slightly with increasing surface area of the aluminium oxide. This material is used in powder form preferably for the preferred of the coated catalysts, extrudates or mouldings.
The aqueous impregnation solution for the application of the promoter can be prepared in a simple manner from water-soluble alkali metal and tungsten compounds, in particular tungstic acid (H2WO4) and alkali metal hydroxides. To this end, for example, tungstic acid is suspended in water and dissolved with addition of a base and heating. Alkali metal hydroxide or another alkali metal salt is likewise dissolved in water and combined with the solution of tungstic acid (promoter solution). Also advantageously usable are alkali metal salts whose anions can be driven out without residue by heat treatment, for example nitrates, formates, oxalates, acetates or carbonates. Suitable for stabilizing this solution having a pH of 8 to 14 are inorganic and also organic bases. Preference is given to using those bases which can be driven out without residue by a final heat treatment of the catalyst obtained after the impregnation. These bases preferably include ammonium hydroxide and organic bases, in particular amines. Compared to the prior art, the molar ratio of alkali metals and W when the aqueous impregnation solution is prepared is selected in such a way that, in contrasts to caesium tungstate (Cs2WO4) or potassium tungstate (K2WO4) having an alkali metal/W ratio of 2 to 1, a higher proportion of tungsten, i.e. an alkali metal to W ratio of less than 2 to 1, in particular < 1.9:1 to 0.9:1, is present. In comparison to the known catalysts, this leads to a distinctly increased activity and selectivity of the

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inventive catalysts, in particular at low ratios of hydrogen sulphide and methanol in the reaction gas.
When mixtures of tungstates with mixed alkali metal fractions are used, they are preferably two different alkali metals of the Periodic Table in a ratio between 0.01:1.0 and 1.0:1.0. In this case, the proportion of the less expensive alkali metal is preferably increased to such an extent and simultaneously that of the comparatively more expensive alkali metal reduced in return that no deterioration in the activity or selectivity of the catalyst occurs.
For the application of the promoter solution, various impregnation techniques, such as immersion impregnation, spray impregnation, vacuum impregnation and pore volume impregnation may be used, and the impregnation may also be effected repeatedly. In the case of mouldings, the selected impregnation process has to enable the desired loading amount of the promoter to be applied with good uniformity over the total cross section.
The promoter solution is preferably applied to the shaped bodies by spray or vacuum impregnation in one or two steps. In spray impregnation, the aqueous impregnation solution is sprayed onto the support bodies. In vacuum impregnation, a reduced pressure is generated by means of a vacuum pump in a vessel charged with the shaped bodies. Opening of a hose connection to the aqueous impregnation solution sucks the solution into the vessel until the entire bed of shaped bodies is covered with the solution. After an impregnation time of 0.2 to 2 hours, the solution which has not been absorbed by the material is drained off or poured off.
Predrying at room temperature for a period of 1 to 10 hours allows the initial concentration gradient over the cross section of the shaped bodies to be substantially balanced. Thus, the uniformity of the impregnation over the cross

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section of the catalyst particles is improved. Preference is given to drying the thus obtained catalyst precursors to remove the residual moisture at 100 to 200°C, preferably 100 to 140°C, for the period of 1 to 10 hours. There is then a calcination at 300 to 600°C, preferably 420 to 480°C, for the period of 1 to 20 hours, preferably 1 to 5 hours. This fixes the promoter on the aluminium oxide and decomposes and drives off the base of the impregnation solution. Optionally, the bed of support bodies of the catalyst precursors can be flowed through by a gas stream in the course of the predrying, drying and calcinations, which improves the removal of the residual moisture and of the decomposition gases.
The shaped bodies can also be impregnated in a plurality of stages, in particular two stages.
In a preferred embodiment, the solution used in the first stage then comprises one to two thirds of the intended total amount of alkali metal and tungsten compounds.
When the procedure has a plurality of stages, but at least two stages, the precursor obtained in the first step is optionally not calcined.
Otherwise, the same impregnation, drying and calcination programme as described for the one-stage process proceeds in the second stage.
This multistage impregnation is viable in particular when high loadings are desired and/or the limited solubility of the promoter mixture does not enable the loading in one step.
The possibility also exists of spraying the support bodies repeatedly with the impregnation solution during the impregnation operation (step a from Claim 11) and, between these treatment steps, in each case removing portions of

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the residual moisture at a temperature of up to 12 0°C, before moving on to step b.
In the preparation of the coated catalyst, the powder to be applied as a coating may be calcined before or after the coating. For example, this catalyst type may be prepared according to EP-B-0 068 193. In the preparation of the extrudates or of the mouldings too, the calcinations may be effected before and/or after the reshaping.
Examples
Example 1 (comparative example)
150 g of aluminium oxide I were impregnated with 21.0% by weight of caesium tungstate (Cs2.ow04) with the aid of vacuum impregnation. To this end, the specific procedure was as follows:
To prepare the impregnation solution, 55.7 g of tungstic acid were suspended in 44.5 g of water and dissolved by adding 111.4 g of 25% ammonia solution and heating to 50°C. 74.6 g of Cs (OH).H2O were dissolved in 37.3 g of water and mixed with the first solution. The solution was subsequently stirred in a covered beaker for 48 hours. Thereafter, the solution was made up to a volume of 234 ml with 25 g of water.
The aluminium oxide was initially charged in a glass vessel which was evacuated to 150 mbar. By virtue of the opening of a tap, the impregnation solution was sucked into the evacuated glass vessel until the entire bed of shaped bodies was covered with the solution. After a wait time of 15 minutes and aeration of the glass vessel, the solution which had not been absorbed by the aluminium oxide ran back into the beaker. 79 ml of impregnation solution were absorbed by the aluminium oxide.

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The granules were dried to remove the residual moisture at room temperature in an air current for the period of 1 hour and subsequently at 120°C for 3 hours. Afterward, the granules were calcined at 455°C for 3 hours.
Example 2 (comparative example)
Comparative Example 1 was repeated with 26.3% loading of the aluminium oxide with caesium tungstate (Cs2.oW04) .
Example 3 (comparative example)
Comparative Example 1 was repeated with 19.6% loading of the aluminium oxide with potassium tungstate (K2.oW04) with use of KOH instead of Cs(OH)-H2O.
Example 4
150 g of aluminium oxide (Spheralite 501A) was impregnated in a two-stage impregnation with a total of 26.7% by weight of promoter (K1.6WOy) with the aid of vacuum impregnation. The specific procedure was as follows:
64.5 g of tungstic acid were suspended in 50.7 g of water and dissolved by adding 126.9 g of 25% ammonia solution and heating to 50°C. 22.8 g of KOH were dissolved in 11.5 g of water and mixed with the first solution. The solution was subsequently stirred in a covered beaker for 48 hours. Thereafter, the solution was made up to a volume of 234 ml with 39 g of water. The aluminium oxide was initially charged in a glass vessel which was evacuated to 150 mbar. By virtue of the opening of a tap, the impregnation was sucked in until the entire bed of mouldings was covered with the solution. After a wait time of 15 minutes and aeration of the glass vessel, the solution which had not been absorbed by the aluminium oxide flowed back into the beaker. 76 ml of impregnation solution were absorbed by the aluminium oxide. Subsequently, the granules were dried at

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room temperature for 1 hour and at 12 0°C for 3 hours, and calcined at 455°C for 3 hours.
To carry out the second impregnation, an identical impregnation solution to that in the first step was prepared and applied in the same way by vacuum impregnation to the already laden catalyst from the first step. This was then followed again by drying at room temperature for 1 hour, followed by drying at 120°C for 3 hours. Finally, the catalyst particles were calcined under air at 455°C for 4 hours.
Example 5
150 g of aluminium oxide (Spheralite 501A) was impregnated in a two-stage impregnation with a total of 30.1% by weight of promoter (Rb0.9WOy) with the aid of vacuum impregnation. The specific procedure was as follows:
59.0 g of tungstic acid were suspended in 48.3 g of water and dissolved by adding 110.7 g of 25% ammonia solution and heating to 50°C. 41.5 g of RbOH were dissolved in 17.5 g of water and mixed with the first solution. The solution was subsequently stirred in a covered beaker for 48 hours. Thereafter, the solution was made up to a volume of 234 ml with 25 g of water. The aluminium oxide was initially charged in a glass vessel which was evacuated to 150 mbar. By virtue of the opening of a tap, the impregnation was sucked in until the entire bed of mouldings was covered with the solution. After a wait time of 15 minutes and aeration of the glass vessel, the solution which had not been absorbed by the aluminium oxide flowed back into the beaker. 75 ml of impregnation solution were absorbed by the aluminium oxide. Subsequently, the granules were dried at room temperature for 1 hour and at 12 0°C for 3 hours, and calcined at 455°C for 3 hours.
To carry out the second impregnation, an identical impregnation solution to that in the first step was

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prepared and applied in the same way by vacuum impregnation to the already laden catalyst from the first step. This was then followed again by drying at room temperature for 1 hour, followed by drying at 120°C for 3 hours. Finally, the catalyst particles were calcined under air at 455°C for 4 hours.
Example 6
150 g of aluminium oxide (Spheralite 501A) was impregnated in a two-stage impregnation with a total of 29.4% by weight of promoter (K0.7Cs0.7WOy) with the aid of vacuum impregnation. The specific procedure was as follows:
61.3 g of tungstic acid were suspended in 49.1 g of water and dissolved by adding 122.7 g of 25% ammonia solution and heating to 50°C. 9.8 g of KOH and 29.0 g of Cs(OH)-H2O were dissolved in 14.5 g of water and mixed with the first solution. The solution was subsequently stirred in a covered beaker for 48 hours. Thereafter, the solution was made up to a volume of 234 ml with 47 g of water. The aluminium oxide was initially charged in a glass vessel which was evacuated to 150 mbar. By virtue of the opening of a tap, the impregnation was sucked in until the entire bed of mouldings was covered with the solution. After a wait time of 15 minutes and aeration of the glass vessel, the solution which had not been absorbed by the aluminium oxide flowed back into the beaker. 75 ml of impregnation solution were absorbed by the aluminium oxide. Subsequently, the granules were dried at room temperature for 1 hour and at 12 0°C for 3 hours, and calcined at 455°C for 3 hours.
To carry out the second impregnation, an identical impregnation solution to that in the first step was prepared and applied in the same way by vacuum impregnation to the already laden catalyst from the first step. This was then followed again by drying at room temperature for 1

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hour, followed by drying at 120°C for 3 hours. Finally, the catalyst particles were calcined under air at 455°C for 4 hours.
Example 7
150 g of aluminium oxide (Spheralite 501A) was impregnated in a two-stage impregnation with a total of 31.0% by weight of promoter (Nao.3Cs1.1WOy) with the aid of vacuum impregnation. The specific procedure was as follows:
61.1 g of tungstic acid were suspended in 48.9 g of water and dissolved by adding 122.1 g of 25% ammonia solution and heating to 50°C. 3.2 g of NaOH and 44.6 g of Cs(OH)-H2O were dissolved in 22.3 g of water and mixed with the first solution. The solution was subsequently stirred in a covered beaker for 48 hours. Thereafter, the solution was made up to a volume of 2 34 ml with 40 g of water. The aluminium oxide was initially charged in a glass vessel which was evacuated to 150 mbar. By virtue of the opening of a tap, the impregnation was sucked in until the entire bed of mouldings was covered with the solution. After a wait time of 15 minutes and aeration of the glass vessel, the solution which had not been absorbed by the aluminium oxide flowed back into the beaker. 74 ml of impregnation solution were absorbed by the aluminium oxide. Subsequently, the granules were dried at room temperature for 1 hour and at 120°C for 3 hours, and calcined at 455°C for 3 hours.
To carry out the second impregnation, an identical impregnation solution to that in the first step was prepared and applied in the same way by vacuum impregnation to the already laden catalyst from the first step. This was then followed again by drying at room temperature for 1 hour, followed by drying at 12 0°C for 3 hours. Finally, the catalyst particles were calcined under air at 455°C for 4 hours.

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Example 8 (use example)
The catalysts were tested with regard to their performance data in the synthesis of methyl mercaptan from hydrogen sulphide and methanol.
The synthesis was carried out in a stainless steel tube of internal diameter 18 mm and a length of 500 mm. The catalyst bed of in each case 76 ml was secured in the reaction tube on both sides by inert beds of glass spheres. The reaction tube was heated to the reaction temperature of about 320°C using a jacket comprising a thermal oil.
The experimental conditions can be taken from the following list:
GHSV: 1300 h-1 (based on standard conditions)
LHSV: 0.84 h-1 (based on liquid MeOH)
Reaction temperature: 320°C
Mass ratio
H2S/MeOH: 1.9
Pressure: 9 bar
The reaction mixture comprising the products methyl mercaptan, dimethyl sulphide and dimethyl ether, and comprising the unconverted starting materials methanol and hydrogen sulphide is analyzed by online gas chromatography.
When the tungsten fraction in relation to the alkali metal fraction in the catalyst is increased, a distinct increase in activity can be seen with simultaneously improved selectivity. In comparison to the prior art, this leads to a yield increase of up to 10%. The selectivity can be increased to up to ~ 96.5% by adjusting the alkali metal-tungstate ratio, and the methanol conversion rises. In the industrial scale synthesis of methyl mercaptan, this also leads to considerable cost savings in the removal of the

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reaction products from unconverted methanol and byproducts .
In addition, the results of Examples 4 to 7 show that at least a portion of the alkali metals can be exchange for one another in order to selectively adjust the activity and selectivity of the catalyst or in order to save raw material costs in the catalyst synthesis.
Table 1: Experimental results

CE1: Catalyst according to Comparative Example 1 * multistage impregnation

CatalystExample Alkali metal mol. alkali metal:W ratio Loading [% by wt.] Methanol conversion [%] Selectivity [%] Yield [%]
CE1 CE2 CE3 Cs Cs K 2:1 2:1 2:1 21.0 26.3 19.6 82.4 79.5 76.0 93.3 94.7 95.2 76.9 75.2 72.4
E4*> E5*> E6*> E7*> K Rb K, Cs Na, Cs 1.6:1 0.9:1 1.4:1 1.4:1 26.7 30.1 29.4 31.0 85.6 73.2 88.5 88.4 95.1 96.6 95.4 95.8 81.4 70.7 84.4 84.7

WO 2006/015668 PCT/EP2005/007211
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Claims:
1. Catalyst comprising a catalytically active tungstate
which contains at least one chemically bound alkali metal and tungsten with a molar ratio of alkali metal to tungsten of < 2:1, caesium occurring only in combination with another alkali element.
2. Catalytically active tungstate according to Claim 1
which contains at least two alkali metals and tungsten in a molar ratio of the sum of the alkali metals to tungsten of < 2:1.
3. Catalyst according to Claims 1 and 2, consisting of a
coated catalyst in which a support core is coated with
the catalytically active tungstate of with a support
material impregnated with this tungstate.
4. Catalyst according to Claims 1 and 2, in which the
support material impregnated with the catalytically
active tungstate has been processed to give an
unsupported catalyst.
5. Catalyst according to Claims 1 and 2, in which the
surface of a support body is impregnated with a
catalytically active oxidic composition composed of
alkali metals and tungsten with a molar ratio of
alkali metal(s) to tungsten of < 2:1.
6. Catalyst according to Claims 1 to 5, characterized in
that the molar ratio of alkali metal(s) to tungsten in
the tungstate is < 2:1 to 0.9:1.

7. Catalyst according to Claim 6, characterized in that
the ratio ranges from 1.9:1 to 1:1.
8. Catalyst according to Claims 1 to 5, characterized in
that the oxidic composition corresponds to the general
formula
AxWOy in which

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A: is at least one alkali metal
(caesium only in combination with another alkali metal) x: is 0.9 to < 2 y: is 3.4 to < 4
9. Catalyst according to one or more of Claims 1 to 8,
characterized in that it comprises the tungstate in an
amount of 8 to 45% by weight, preferably 2 0 to 3 6% by
weight.
10. Catalyst according to one or more of Claims 1 to 9,
characterized in that the support body or the support
material consists of an oxidic inorganic compound.
11. Catalyst according to Claim 10, characterized in that
the support body or the support material consists of
aluminium oxide (A12O3) .
12. Catalyst according to Claim 10, characterized in that
the support material has a specific surface area of
180 to 400 m2/g (BET) and a total pore volume of 0.3
to 1.2 ml/g.
13. Catalyst according to Claims 1 and 3 to 12,
characterized in that the alkali metal is potassium.
14. Catalyst according to Claims 1 and 3 to 12,
characterized in that the alkali metal is rubidium.
15. Catalyst according to Claims 2 to 12, characterized in
that the alkali metals are potassium and caesium.
16. Catalyst according to Claims 2 to 12, characterized in
that the alkali metals are sodium and caesium.
17. Catalyst according to Claims 2 to 12, characterized in
that the alkali metals are rubidium and caesium.

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18. Catalyst according to Claims 2 to 9, characterized in
that the alkali metals are sodium and potassium.
19. Catalyst according to Claims 2 to 12, characterized in
that the alkali metals are rubidium and potassium.
20. Process for preparing a catalyst comprising alkali
metal tungstate, in which the following process steps
are carried out:

a) impregnation of the support body or of the
support material with an aqueous solution which
comprises soluble alkali metal and tungsten
compounds in the desired molar alkali metal/W
ratio,
b) predrying of the resulting impregnated shaped
body or of the finely divided support material
(catalyst precursor) at room temperature,
c) optional drying at 10 0 to 200°C to remove the
residual moisture,
d) subsequent calcining at temperatures of 300 to
600°C for the period of 2 to 10 hours and
e) obtaining the supported catalyst or the
impregnated finely divided support material with
a content of 8 to 45% by weight, preferably 15 to
3 6% by weight, of a promoter of the general
composition AxWOy in which A, x and y are each as
defined above, and subsequently
f) the finely divided impregnated support material
is suspended with addition of known assistants
and applied to an inert support core or extruded
and compressed.

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21. Process according to Claim 20, characterized in that
steps a to c and optionally d are repeated at least
once.
22. Process according to Claim 20, characterized in that,
in the case of repeated impregnation, the impregnation
solution used first comprises one to two thirds of the
intended total amount of alkali metals and tungsten.
23. Process according to Claim 20, characterized in that
the support bodies or the support material are sprayed
repeatedly with the impregnation solution and portions
of the residual moisture are removed at a temperature
up to 120°C between these treatment steps, before
moving on to treatment step b).
24. Process according to Claim 20, characterized in that
the catalyst is heat-treated after the application of
the impregnated support material to the core after the
extrusion or compression.
25. Process for preparing alkyl mercaptans by reacting
alkanols and hydrogen sulphide in the presence of the
catalyst according to Claims 1 to 19.
26. Process according to Claim 25 for preparing methyl
mercaptan by reacting methyl alcohol and hydrogen
sulphide.