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Catalytic Method For The Preparation Of Perfluoroalkoxy Substituted Arenes And Heteroarenes

Abstract: The present invention is directed to methods for the preparation of (CnF2n+1)O-substituted arenes and heteroarenes and the direct perfluoralkoxylation of arenes and heteroarenes with a (CnF2n+1)O-group, respectively, characterized in that a peroxide reagent according to the general formula (I): (OCnF2n+1)2 (I) is fragmented in the presence of an electron transferring catalyst under (CnF2n+1)O-radical formation, and said (CnF2n+1)O-radical then substitutes a C-H bond of an arene or heteroarene C-H bond with a (CnF2n+1)O-group, wherein in the above formulae, n is an integer in the range from 1 to 4.

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Patent Information

Application #
Filing Date
18 September 2023
Publication Number
40/2023
Publication Type
INA
Invention Field
CHEMICAL
Status
Email
Parent Application

Applicants

SOLVAY SA
Rue de Ransbeek, 310 1120 Bruxelles

Inventors

1. HASENSTAB-RIEDEL, Sebastian
Ernst Thälmann Strasse 84 14532 Kleinmacknow
2. HOPKINSON, Matthew
Platz des 4. Juli 12 14167 Berlin
3. DIX, Stefan
Moldaustr. 17 10319 Berlin
4. GOLZ, Paul
Richard-Wagner Str. 14 15234 Frankfurt
5. SCHMID, Jonas Rachid
Barbarossastr. 2 10781 Berlin
6. PERNICE, Holger
Heilshorner Strasse 36B 28790 Schwanewede
7. GUTMANN, Sebastian
Stresemannallee 31E 30173 Hannover

Specification

Documents

Application Documents

# Name Date
1 202347062535-STATEMENT OF UNDERTAKING (FORM 3) [18-09-2023(online)].pdf 2023-09-18
2 202347062535-PROOF OF RIGHT [18-09-2023(online)].pdf 2023-09-18
3 202347062535-PRIORITY DOCUMENTS [18-09-2023(online)].pdf 2023-09-18
4 202347062535-FORM 1 [18-09-2023(online)].pdf 2023-09-18
5 202347062535-DRAWINGS [18-09-2023(online)].pdf 2023-09-18
6 202347062535-DECLARATION OF INVENTORSHIP (FORM 5) [18-09-2023(online)].pdf 2023-09-18
7 202347062535-COMPLETE SPECIFICATION [18-09-2023(online)].pdf 2023-09-18
8 202347062535-FORM-26 [29-12-2023(online)].pdf 2023-12-29
9 202347062535-PETITION UNDER RULE 137 [01-08-2024(online)].pdf 2024-08-01
10 202347062535-FORM 3 [01-08-2024(online)].pdf 2024-08-01