Cathode Active Material For Lithium Secondary Battery, Preparation Method Therefor And Lithium Secondary Battery Comprising Same
Abstract:
The present invention provides a cathode active material for a lithium secondary battery, comprising particles of a lithium cobalt oxide, wherein the particles of the lithium cobalt oxide comprises, on the particle surface and in a region corresponding to a distance of 0% or more and less than 100% from the particle surface with respect to a distance (r) from the surface to the center of the particle, a lithium defective lithium cobalt oxide, of which the mole ratio of Li/Co is less than 1 and a space group belongs to Fd-3m, and having a cubic crystalline structure. The cathode active material for a lithium secondary battery according to the present invention facilitates intercalation and deintercalation of lithium at the particle surface, thereby improving output characteristics and rate characteristics when applied to a battery. Consequently, excellent lifetime characteristics are exhibited and the amount of generated gas can be minimized even when the cathode active material is a large particle.
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Notices, Deadlines & Correspondence
LG Chem Research Park 188 Munji ro
Yuseong gu
Daejeon 34122
2. RYU Ji Hoon
LG Chem Research Park 188 Munji ro
Yuseong gu
Daejeon 34122
3. KANG Min Suk
LG Chem Research Park 188 Munji ro
Yuseong gu
Daejeon 34122
4. SHIN Sun Sik
LG Chem Research Park 188 Munji ro
Yuseong gu
Daejeon 34122
5. JUNG Wang Mo
LG Chem Research Park 188 Munji ro
Yuseong gu
Daejeon 34122
Specification
[CROSS-REFERENCE TO RELATED APPLICATIONS]
[0001] This application claims the benefits of priority from
Korean Patent Application No. 2014-0133428 and No. 2014-
0133429, filed on October 2, 2014, and Korean Patent
Application No. 2015-0138746, filed on October 1, 2015, the
entire contents described in the disclosure of corresponding
Korean patent applications are hereby incorporated as a part
of the present specification.
[TECHNICAL FIELD]
[0002] The present invention relates to a positive electrode
active material for a lithium secondary battery, a method of
preparing the same, and a lithium secondary battery including
the same.
[BACKGROUND ART]
[0003] As technical developments and demands on mobile
devices are increasing, demands on secondary batteries as an
1
WO2016/053053 PCT/KR2015/010447
energy source is being rapidly increasing. Among the
secondary batteries, lithium secondary batteries having high
energy density and voltage, long cycle life, and low selfdischarge
rate are commercialized and widely used.
[0004] However, the lithium secondary battery has a
limitation that the life thereof decreases rapidly via
repeating charge and discharge. Particularly, the limitation
is more serious at high temperatures. The reason is that an
electrolyte may be decomposed due to moisture in the battery
or other factors, an active material may be deteriorated, or
the internal resistance of the battery may increase.
[0005] A positive electrode active material for a lithium
secondary battery, which is being actively researched,
developed and used, is LiCo02 with a layered structure.
LiCo02 may be easily synthesized and has good electrochemical
properties including life property, and is the most widely
used material. However LiCo02 has low structural stability,
and the application thereof to a battery with high capacity
is limited.
[0006] As the substituents of the positive electrode active
material, various lithium transition metal oxides such as
LiNi02, LiMn02, LiMn204, or LiFePCu have been developed.
LiNi02 has merits of providing the battery properties of high
discharge capacity, however is hardly synthesized by a simple
solid phase reaction and has low thermal stability and cycle
property. In addition, lithium manganese oxides such as
LiMn02 or LiMn204 have merits of good thermal stability and
low cost, however have limitations of a small capacity and
inferior properties at high temperatures. Particularly, for
LiMn204, some products are commercialized at low cost;
however the life property thereof is not good due to Jahn-
Teller distortion owing to Mn3+. Since LiFePCu is inexpensive
and safe, a lot of research is being conducted for the use in
a hybrid electric vehicle (HEV), however the application
thereof to another fields is hard due to low conductivity.
[0007] Due to such circumstances, a lithium nickel manganese
cobalt oxide, Li (NixCoyMnz) O2 (where x, y, and z are atomic
fraction of each independent oxide component elements and
satisfy 0