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Cathode Active Material For Lithium Secondary Battery, Preparation Method Therefor And Lithium Secondary Battery Comprising Same

Abstract: The present invention provides a cathode active material for a lithium secondary battery, comprising particles of a lithium cobalt oxide, wherein the particles of the lithium cobalt oxide comprises, on the particle surface and in a region corresponding to a distance of 0% or more and less than 100% from the particle surface with respect to a distance (r) from the surface to the center of the particle, a lithium defective lithium cobalt oxide, of which the mole ratio of Li/Co is less than 1 and a space group belongs to Fd-3m, and having a cubic crystalline structure. The cathode active material for a lithium secondary battery according to the present invention facilitates intercalation and deintercalation of lithium at the particle surface, thereby improving output characteristics and rate characteristics when applied to a battery. Consequently, excellent lifetime characteristics are exhibited and the amount of generated gas can be minimized even when the cathode active material is a large particle.

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Patent Information

Application #
Filing Date
30 March 2017
Publication Number
37/2017
Publication Type
INA
Invention Field
ELECTRICAL
Status
Email
ipo@knspartners.com
Parent Application
Patent Number
Legal Status
Grant Date
2021-09-17
Renewal Date

Applicants

LG CHEM LTD.
128 Yeoui daero Yeongdeungpo gu Seoul 07336

Inventors

1. JO Chi Ho
LG Chem Research Park 188 Munji ro Yuseong gu Daejeon 34122
2. RYU Ji Hoon
LG Chem Research Park 188 Munji ro Yuseong gu Daejeon 34122
3. KANG Min Suk
LG Chem Research Park 188 Munji ro Yuseong gu Daejeon 34122
4. SHIN Sun Sik
LG Chem Research Park 188 Munji ro Yuseong gu Daejeon 34122
5. JUNG Wang Mo
LG Chem Research Park 188 Munji ro Yuseong gu Daejeon 34122

Specification

[CROSS-REFERENCE TO RELATED APPLICATIONS] [0001] This application claims the benefits of priority from Korean Patent Application No. 2014-0133428 and No. 2014- 0133429, filed on October 2, 2014, and Korean Patent Application No. 2015-0138746, filed on October 1, 2015, the entire contents described in the disclosure of corresponding Korean patent applications are hereby incorporated as a part of the present specification. [TECHNICAL FIELD] [0002] The present invention relates to a positive electrode active material for a lithium secondary battery, a method of preparing the same, and a lithium secondary battery including the same. [BACKGROUND ART] [0003] As technical developments and demands on mobile devices are increasing, demands on secondary batteries as an 1 WO2016/053053 PCT/KR2015/010447 energy source is being rapidly increasing. Among the secondary batteries, lithium secondary batteries having high energy density and voltage, long cycle life, and low selfdischarge rate are commercialized and widely used. [0004] However, the lithium secondary battery has a limitation that the life thereof decreases rapidly via repeating charge and discharge. Particularly, the limitation is more serious at high temperatures. The reason is that an electrolyte may be decomposed due to moisture in the battery or other factors, an active material may be deteriorated, or the internal resistance of the battery may increase. [0005] A positive electrode active material for a lithium secondary battery, which is being actively researched, developed and used, is LiCo02 with a layered structure. LiCo02 may be easily synthesized and has good electrochemical properties including life property, and is the most widely used material. However LiCo02 has low structural stability, and the application thereof to a battery with high capacity is limited. [0006] As the substituents of the positive electrode active material, various lithium transition metal oxides such as LiNi02, LiMn02, LiMn204, or LiFePCu have been developed. LiNi02 has merits of providing the battery properties of high discharge capacity, however is hardly synthesized by a simple solid phase reaction and has low thermal stability and cycle property. In addition, lithium manganese oxides such as LiMn02 or LiMn204 have merits of good thermal stability and low cost, however have limitations of a small capacity and inferior properties at high temperatures. Particularly, for LiMn204, some products are commercialized at low cost; however the life property thereof is not good due to Jahn- Teller distortion owing to Mn3+. Since LiFePCu is inexpensive and safe, a lot of research is being conducted for the use in a hybrid electric vehicle (HEV), however the application thereof to another fields is hard due to low conductivity. [0007] Due to such circumstances, a lithium nickel manganese cobalt oxide, Li (NixCoyMnz) O2 (where x, y, and z are atomic fraction of each independent oxide component elements and satisfy 0

Documents

Application Documents

# Name Date
1 Power of Attorney [30-03-2017(online)].pdf 2017-03-30
2 Form 5 [30-03-2017(online)].pdf 2017-03-30
3 Form 3 [30-03-2017(online)].pdf 2017-03-30
4 Form 1 [30-03-2017(online)].pdf 2017-03-30
5 Drawing [30-03-2017(online)].pdf 2017-03-30
6 Description(Complete) [30-03-2017(online)].pdf_154.pdf 2017-03-30
7 Description(Complete) [30-03-2017(online)].pdf 2017-03-30
8 201717011388.pdf 2017-04-03
9 abstract.jpg 2017-06-06
10 201717011388-Proof of Right (MANDATORY) [18-07-2017(online)].pdf 2017-07-18
11 201717011388-OTHERS-210717.pdf 2017-08-01
12 201717011388-Correspondence-210717.pdf 2017-08-01
13 201717011388-FORM 3 [30-08-2017(online)].pdf 2017-08-30
14 201717011388-FORM 18 [30-01-2018(online)].pdf 2018-01-30
15 201717011388-Information under section 8(2) (MANDATORY) [27-11-2018(online)].pdf 2018-11-27
16 201717011388-FORM 3 [27-11-2018(online)].pdf 2018-11-27
17 201717011388-Information under section 8(2) (MANDATORY) [16-09-2019(online)].pdf 2019-09-16
18 201717011388-FORM 3 [16-09-2019(online)].pdf 2019-09-16
19 201717011388-FORM 3 [22-11-2019(online)].pdf 2019-11-22
20 201717011388-FORM 3 [24-11-2020(online)].pdf 2020-11-24
21 201717011388-certified copy of translation [18-03-2021(online)].pdf 2021-03-18
22 201717011388-certified copy of translation [18-03-2021(online)]-1.pdf 2021-03-18
23 201717011388-PETITION UNDER RULE 137 [23-07-2021(online)].pdf 2021-07-23
24 201717011388-PETITION UNDER RULE 137 [23-07-2021(online)]-1.pdf 2021-07-23
25 201717011388-OTHERS [26-07-2021(online)].pdf 2021-07-26
26 201717011388-FER_SER_REPLY [26-07-2021(online)].pdf 2021-07-26
27 201717011388-CLAIMS [26-07-2021(online)].pdf 2021-07-26
28 201717011388-Retyped Pages under Rule 14(1) [10-09-2021(online)].pdf 2021-09-10
29 201717011388-2. Marked Copy under Rule 14(2) [10-09-2021(online)].pdf 2021-09-10
30 201717011388-RELEVANT DOCUMENTS [15-09-2021(online)].pdf 2021-09-15
31 201717011388-FORM 13 [15-09-2021(online)].pdf 2021-09-15
32 201717011388-PatentCertificate17-09-2021.pdf 2021-09-17
33 201717011388-IntimationOfGrant17-09-2021.pdf 2021-09-17
34 201717011388-FER.pdf 2021-10-17
35 201717011388-POWER OF AUTHORITY [21-11-2022(online)].pdf 2022-11-21
36 201717011388-FORM-16 [21-11-2022(online)].pdf 2022-11-21
37 201717011388-ASSIGNMENT WITH VERIFIED COPY [21-11-2022(online)].pdf 2022-11-21
38 201717011388-RELEVANT DOCUMENTS [21-08-2023(online)].pdf 2023-08-21

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1 2021-01-2511-03-36E_25-01-2021.pdf

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