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Cellulose Ether Derivative Fine Particles

Abstract: In a system where phase separation into two phases occurs when an ether cellulose derivative (A), a polymer (B) different from the ether cellulose derivative (A), and an alcohol solvent (C) are mixed together, the two phases including a solution phase mainly containing the ether cellulose derivative (A) and a solution phase mainly containing the polymer (B), the two separated phases containing approximately the same solvent, an emulsion is formed and brought into contact with a poor solvent (D) to provide an ether cellulose derivative microparticle having an average particle diameter of 1 to 1,000 um, a linseed oil absorption of 50 to 1,000 mL/100 g, and an average surface pore size of 0.05 to 5 um.

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Notices, Deadlines & Correspondence

Patent Information

Application #
Filing Date
24 April 2018
Publication Number
18/2018
Publication Type
INA
Invention Field
POLYMER TECHNOLOGY
Status
Email
Parent Application

Applicants

TORAY INDUSTRIES, INC.
1-1, Nihonbashi-Muromachi 2-chome, Chuo-ku, Tokyo 103-8666, Japan

Inventors

1. OTSUBO, Takahiko
c/o Nagoya Plant, Toray Industries, Inc., 9-1, Oe-cho, Minato-ku, Nagoya-shi, Aichi 455-8502, Japan
2. OHTA, Kotoe
c/o Basic Research Center, Toray Industries, Inc., 10-1, Tebiro 6-chome, Kamakura-shi, Kanagawa 248-8555, Japan
3. ECHIGO, Yuji
c/o Nagoya Plant, Toray Industries, Inc., 9-1, Oe-cho, Minato-ku, Nagoya-shi, Aichi 455-8502, Japan
4. TAKEZAKI, Hiroshi
c/o Nagoya Plant, Toray Industries, Inc., 9-1, Oe-cho, Minato-ku, Nagoya-shi, Aichi 455-8502, Japan
5. TAKAKI, Suguru
c/o Basic Research Center, Toray Industries, Inc., 10-1, Tebiro 6-chome, Kamakura-shi, Kanagawa 248-8555, Japan
6. MINAKAMI, Satoshi
c/o Basic Research Center, Toray Industries, Inc., 10-1, Tebiro 6-chome, Kamakura-shi, Kanagawa 248-8555, Japan
7. ITO, Akinori
c/o Mishima Plant, Toray Industries, Inc., 4845, Mishima-shi, Shizuoka 411- 8652, Japan
8. MIYAMA, Hisashi
c/o Tokyo Head Office, Toray Industries, Inc., 1-1, NihonbashiMuromachi 2-chome, Chuo-ku, Tokyo 103-8666, Japan

Specification

WHAT IS CLAIMED IS:
1. An ether cellulose derivative microparticle having:
an average particle diameter of 1 to 1,000 um;
a linseed oil absorption of 50 to 1,000 mL/100 g; and an average surface pore size of 0.05 to 5 um.
2. The ether cellulose derivative microparticle according to claim 1, the ether cellulose derivative microparticle having a pore volume calculated by a mercury intrusion method of 0.05 to 5 cm3/g.
3. The ether cellulose derivative microparticle according to either claim 1 or claim 2, the ether cellulose derivative microparticle having a sphericity of equal to or more than 80.
4. The ether cellulose derivative microparticle according to any one of claims 1 to 3, the ether cellulose derivative microparticle having a particle diameter distribution index of 1 to 3.
5. The ether cellulose derivative microparticle according to any one of claims 1 to 4, the ether cellulose derivative microparticle having a bulk density of 0.05 to 1.0 g/mL.
6. The ether cellulose derivative microparticle according to any one of claims 1 to 5, the ether cellulose derivative microparticle having a degree of crystallinity of equal to or more than 1%.
7. The ether cellulose derivative microparticle according to any one of claims 1 to 6, wherein an ether cellulose derivative constituting the ether cellulose

8. The ether cellulose derivative microparticle according to claim 7, wherein the alkyl cellulose comprises ethyl cellulose.
9. A dispersion comprising the ether cellulose derivative microparticle according to any one of claims 1 to 8.
10. A method for producing the ether cellulose derivative microparticle according to any one of claims 1 to 8, the method comprising, in a system where phase separation into two phases occurs when an ether cellulose derivative (A), a polymer (B) different from the ether cellulose derivative (A), and an alcohol solvent (C) are mixed together, the two phases comprising a solution phase mainly comprising the ether cellulose derivative (A) and a solution phase mainly comprising the polymer (B), the two separated phases comprising approximately same solvent:
forming an emulsion of the ether cellulose derivative (A), the polymer (B), and the alcohol solvent (C); and
bringing the emulsion into contact with a poor solvent (D) for the ether cellulose derivative (A) to precipitate the ether cellulose derivative microparticle.
11. The method for producing the ether cellulose derivative microparticle according to claim 10, wherein the ether cellulose derivative (A) comprises an ether cellulose derivative having a degree of crystallinity of equal to or more than 2%.
12. A composite microparticle comprising:
the ether cellulose derivative microparticle according to any one of claims

13. The composite microparticle according to claim 12, wherein the active ingredient comprises at least one selected from a physiologically active substance, a perfume, a sweetener, an acidulant, an antioxidant, a preservative, a disinfectant, a coloring agent, an agricultural chemical, a fertilizer, a repellent, an attractant, a fungicide, a sterilant, a germicide, an antimicrobial agent, an antibacterial agent, a preservative agent, an antiseptic agent, a deodorizer, and a lubricant.
14. The composite microparticle according to claim 12 or 13, the composite microparticle further comprising on a surface a sustained-release layer configured to suppress release of the active ingredient from the composite microparticle.
15. A preparation comprising the composite microparticle according to any one of claims 12 to

Documents

Application Documents

# Name Date
1 201847015487-TRANSLATIOIN OF PRIOIRTY DOCUMENTS ETC. [24-04-2018(online)].pdf 2018-04-24
2 201847015487-STATEMENT OF UNDERTAKING (FORM 3) [24-04-2018(online)].pdf 2018-04-24
3 201847015487-PRIORITY DOCUMENTS [24-04-2018(online)].pdf 2018-04-24
4 201847015487-POWER OF AUTHORITY [24-04-2018(online)].pdf 2018-04-24
5 201847015487-FORM 1 [24-04-2018(online)].pdf 2018-04-24
6 201847015487-DRAWINGS [24-04-2018(online)].pdf 2018-04-24
7 201847015487-DECLARATION OF INVENTORSHIP (FORM 5) [24-04-2018(online)].pdf 2018-04-24
8 201847015487-COMPLETE SPECIFICATION [24-04-2018(online)].pdf 2018-04-24
9 201847015487-COMPLETE SPECIFICATION [24-04-2018(online)]-1.pdf 2018-04-24
10 201847015487-CLAIMS UNDER RULE 1 (PROVISIO) OF RULE 20 [24-04-2018(online)].pdf 2018-04-24
11 201847015487-Verified English translation (MANDATORY) [30-05-2018(online)].pdf 2018-05-30
12 201847015487-Verified English translation (MANDATORY) [30-05-2018(online)]-1.pdf 2018-05-30
13 201847015487-Verified English translation (MANDATORY) [30-05-2018(online)]-1-1.pdf 2018-05-30
14 201847015487-Verified English translation (MANDATORY) [30-05-2018(online)]-1-1-1.pdf 2018-05-30
15 201847015487-Proof of Right (MANDATORY) [30-05-2018(online)].pdf 2018-05-30
16 201847015487-FORM 3 [30-05-2018(online)].pdf 2018-05-30
17 Correspondence by Agent_English Translation And Form3_31-05-2018.pdf 2018-05-31
18 201847015487-FORM 3 [31-05-2018(online)].pdf 2018-05-31
19 201847015487-FORM 3 [26-10-2018(online)].pdf 2018-10-26