Abstract: Provided are a color developing composition including a compound represented by Formula 1, a lithographic printing plate precursor having at least a layer including the color developing composition, a method for producing a lithographic printing plate in which the lithographic printing plate precursor is used, and a compound represented by Formula 1 which can be preferably used as a color developer.
WE CLAIM:
[Claim 1] A color developing composition, comprising:
a compound represented by the following Formula 1, [Chem 1]
wherein, in Formula 1, Z represents a group represented by Formula 2 or Formula 3, each of R11 to R18 independently represents a hydrogen atom, a halogen atom, -Ra, -ORb, -SRc, or -NRdRe, each of Ra to Re independently represents a hydrocarbon group, each of A1 and A2 independently represents an oxygen atom, a sulfur atom, or a nitrogen atom, R16 is not present in a case in which A1 represents an oxygen atom or a sulfur atom, R18 is not present in a case in which A2 represents an oxygen atom or a sulfur atom, at least two selected from the group consisting of A1, A2, and a plurality of R11 to R18 may be linked to each other to form a
monocycle or a polycycle, n11 and n12 represent the same integer of 0 to 5, and Z1 represents a counter ion for neutralizing a charge,
wherein, in Formula 2 and Formula 3, R19 represents a hydrocarbon group, each of X1 and X2 independently represents an oxygen atom or a sulfur atom, Y represents a group which is represented by Formula 4 and which is capable of cleaving a Y-S bond in Formula 2 or a Y-X2 bond in Formula 3 upon exposure to heat or an infrared ray, and * represents a bonding site with a carbon atom in Formula 1, and
wherein, in Formula 4, each of R41 and R42 independently represents a hydrogen atom or a hydrocarbon group, E represents an onium salt, and • represents a bonding site with a sulfur atom in Formula 2 or a bonding site with X2 in Formula 3.
[Claim 2] The color developing composition according to claim 1, wherein E in Formula 4 is a group represented by the following Formula 5: [Chem 3]
wherein, each of R51’s independently represents a halogen atom, a hydrocarbon group, a hydroxyl group, or -OR53-, R53 represents a hydrocarbon group, a plurality of R51’s may be linked to each other to form a ring, n51 represents an integer of 0 to 4, R52 represents a hydrocarbon group, and Za represents a counter ion that neutralizes a charge.
[Claim 3] The color developing composition according to any one of claims 1 to 2, wherein the compound represented by Formula 1 is a compound represented by the following Formula 6: [Chem 4]
wherein, in Formula 6, Z represents a group represented by Formula 2 or Formula 3, each of R61 to R68 independently represents a hydrogen atom, a halogen atom, -Ra, -ORb, -SRc, or -NRdRe, each of Ra to Re independently represents a hydrocarbon group, each of Ar61 and Ar62 independently represents a group forming a benzene ring or forming a naphthalene ring, each of W61 and W62 independently represents an oxygen atom, a sulfur atom, -CR611R612-, or -NR613-, each of R611 to R613 independently represents a hydrocarbon group, and Zb represents a counter ion that neutralizes a charge,
wherein, in Formula 2 and Formula 3, R19 represents a hydrocarbon group, each of X1 and X2 independently represents an oxygen atom or a sulfur atom, Y represents a group which is represented by Formula 4 and which is capable of cleaving a Y-S bond in Formula 2 or a Y-X2 bond in Formula 3 upon exposure to heat or an infrared ray, and * represents a bonding site with a carbon atom in Formula 1, and
wherein, in Formula 4, each of R41 and R42 independently represents a hydrogen atom or a hydrocarbon group, E represents an onium salt, and • represents a bonding site with a sulfur atom in Formula 2 or a bonding site with X2 in Formula 3.
[Claim 4] The color developing composition according to claim 3, wherein R64 and R68 in Formula 6 represent a group represented by any of the following Formula 7 to Formula 10: [Chem 5]
_|R7i_0_| R72 _R81—C02M81 -R91 —po3M91 -R101-3O3M101
Formula 7 Formula 8 Formula 9 Formula 10
wherein, in Formulae 7 to 10, R71 represents an alkylene group having 2 to 6 carbon atoms, n71 represents an integer of 1 to 45, R72 represents an alkyl group having 1 to 12 carbon atoms or -C(=O)-R73, each of R81, R91, and R101 independently represents an alkylene group having 1 to 12 carbon atoms, R73 represents an alkyl group having 1 to 12 carbon atoms, and each of M81, M91, and M101 represent a hydrogen atom, a Na atom, a K atom, or an onium salt.
[Claim 5] The color developing composition according to any one of claims 1 to 4, further comprising a binder polymer.
[Claim 6] The color developing composition according to any one of claims 1 to 5, further comprising a thermally adhesive particle.
[Claim 7] The color developing composition according to any one of claims 1 to 6, further comprising a polymerization initiator and a polymerizable compound.
[Claim 8] The color developing composition according to any one of claims 1 to 7, further comprising a borate compound.
[Claim 9] A planographic printing plate precursor, comprising:
at least one layer comprising the color developing composition according to any one of claims 1 to 8 on a support.
[Claim 10] A method for producing a planographic printing plate, comprising:
a step of radiating an infrared ray to the planographic printing plate precursor according
to claim 9; and
a step of carrying out on-machine development by supplying at least one selected from
the group consisting of a printing ink and dampening water to the planographic printing plate
precursor to which the infrared ray has been radiated on a printer.
[Claim 11 ] A compound represented by the following Formula 1,
[Chem 6]
wherein, in Formula 1, Z represents a group represented by Formula 2 or Formula 3, each of R11 to R18 independently represents a hydrogen atom, a halogen atom, -Ra, -ORb, -SRc, or -NRdRe, each of Ra to Re independently represents a hydrocarbon group, each of A1 and A2 independently represents an oxygen atom, a sulfur atom, or a nitrogen atom, R16 is not present in a case in which A1 represents an oxygen atom or a sulfur atom, R18 is not present in a case in which A2 represents an oxygen atom or a sulfur atom, at least two selected from the group consisting of A1, A2, and a plurality of R11 to R18 may be linked to each other to form a monocycle or a polycycle, n1 1 and n12 represent the same integer of 0 to 5, and Z1 represents a counter ion for neutralizing a charge,
wherein, in Formula 2 and Formula 3, R19 represents a hydrocarbon group, each of X1 and X2 independently represents an oxygen atom or a sulfur atom, Y represents a group which is represented by Formula 4 and which is capable of cleaving a Y-S bond in Formula 2 or a Y-X2 bond in Formula 3 upon exposure to heat or an infrared ray, and * represents a bonding site with a carbon atom in Formula 1, and
wherein, in Formula 4, each of R41 and R42 independently represents a hydrogen atom or a hydrocarbon group, E represents an onium salt, and • represents a bonding site with a sulfur atom in Formula 2 or a bonding site with X2 in Formula 3.
| # | Name | Date |
|---|---|---|
| 1 | 201947007400.pdf | 2019-02-26 |
| 2 | 201947007400-TRANSLATIOIN OF PRIOIRTY DOCUMENTS ETC. [26-02-2019(online)].pdf | 2019-02-26 |
| 3 | 201947007400-STATEMENT OF UNDERTAKING (FORM 3) [26-02-2019(online)].pdf | 2019-02-26 |
| 4 | 201947007400-REQUEST FOR EXAMINATION (FORM-18) [26-02-2019(online)].pdf | 2019-02-26 |
| 5 | 201947007400-PROOF OF RIGHT [26-02-2019(online)].pdf | 2019-02-26 |
| 6 | 201947007400-PRIORITY DOCUMENTS [26-02-2019(online)].pdf | 2019-02-26 |
| 7 | 201947007400-POWER OF AUTHORITY [26-02-2019(online)].pdf | 2019-02-26 |
| 8 | 201947007400-FORM 18 [26-02-2019(online)].pdf | 2019-02-26 |
| 9 | 201947007400-FORM 1 [26-02-2019(online)].pdf | 2019-02-26 |
| 10 | 201947007400-DECLARATION OF INVENTORSHIP (FORM 5) [26-02-2019(online)].pdf | 2019-02-26 |
| 11 | 201947007400-COMPLETE SPECIFICATION [26-02-2019(online)].pdf | 2019-02-26 |
| 12 | 201947007400-CLAIMS UNDER RULE 1 (PROVISIO) OF RULE 20 [26-02-2019(online)].pdf | 2019-02-26 |
| 13 | Description Complete_Fomr 1_07-03-2019.pdf | 2019-03-07 |
| 14 | 201947007400-FORM 3 [03-04-2019(online)].pdf | 2019-04-03 |
| 15 | 201947007400-FER.pdf | 2019-12-19 |
| 16 | 201947007400-PETITION UNDER RULE 137 [15-06-2020(online)].pdf | 2020-06-15 |
| 17 | 201947007400-OTHERS [15-06-2020(online)].pdf | 2020-06-15 |
| 18 | 201947007400-Information under section 8(2) [15-06-2020(online)].pdf | 2020-06-15 |
| 19 | 201947007400-FORM 3 [15-06-2020(online)].pdf | 2020-06-15 |
| 20 | 201947007400-FER_SER_REPLY [15-06-2020(online)].pdf | 2020-06-15 |
| 21 | 201947007400-CLAIMS [15-06-2020(online)].pdf | 2020-06-15 |
| 22 | 201947007400-Annexure [15-06-2020(online)].pdf | 2020-06-15 |
| 23 | 201947007400-ABSTRACT [15-06-2020(online)].pdf | 2020-06-15 |
| 24 | 201947007400-FORM-26 [29-10-2020(online)].pdf | 2020-10-29 |
| 25 | 201947007400-Correspondence to notify the Controller [29-10-2020(online)].pdf | 2020-10-29 |
| 26 | 201947007400-Written submissions and relevant documents [16-11-2020(online)].pdf | 2020-11-16 |
| 27 | 201947007400-Retyped Pages under Rule 14(1) [16-11-2020(online)].pdf | 2020-11-16 |
| 28 | 201947007400-2. Marked Copy under Rule 14(2) [16-11-2020(online)].pdf | 2020-11-16 |
| 29 | 201947007400-PatentCertificate27-11-2020.pdf | 2020-11-27 |
| 30 | 201947007400-IntimationOfGrant27-11-2020.pdf | 2020-11-27 |
| 31 | 201947007400-US(14)-HearingNotice-(HearingDate-02-11-2020).pdf | 2021-10-17 |
| 32 | 201947007400-RELEVANT DOCUMENTS [14-09-2022(online)].pdf | 2022-09-14 |
| 33 | 201947007400-RELEVANT DOCUMENTS [16-09-2023(online)].pdf | 2023-09-16 |
| 1 | 201947007400searchreport_10-12-2019.pdf |