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Composition In The Foam Form Comprising A Polymeric Structuring Agent

Abstract: h a-object-Kiatter of the invention is a cosmetic composition in. tfa« foam fforar. ccroprising a continuous oily phaso *aci at least one structuring agent for the oily phase chosen from polynseric structuring ageats.

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Patent Information

Application #
Filing Date
08 May 2008
Publication Number
03/2009
Publication Type
INA
Invention Field
GENERAL ENGINEERING
Status
Email
Parent Application

Applicants

L'OREAL
14, RUE ROYALE 75008 PARIS (FR)

Inventors

1. STYCZEN, PATRICE
21 ALLEE DE LA CLAIRIERE 91190 GIFT-SUR-YVETTE (FR)
2. RAY, XAVIER
3 ROUTE DE CHAUFFOURLE BOIS FOURGON 91580 VILLECONIN (FR)
3. GABIN, PHILIPPE
6 AV DU MARECHAL FOCH 91440 BURES SUR YVETTE(FR)

Specification

The present invention relates to a composition in the foam form comprising a continuous liquid fatty phase.
The compositions according to the invention can be compositions for making up or caring for keratinous substances, in particular the skin, lips, eyelashes, eyebrows or nails. The- composition may or tnay not be
coloured.
Bach composition can be a foundation, a face powder, an eye shadow, a concealer, a blusher, a lipstick, a lip balm, a lip gloss, a mascara, an eyeliner or a product for making up the body or colouring the skin.
The care composition can be a product for caring for the eyelashes, lips or akin of the body and face, in particular an antisun product.
Compositions in the foam form which are oil-in-water or wax-in-water emulsions comprising a continuous aqueous phase are known.
However, these compoaitions do not always exhibit the gloss desired by consumers, in particular in the case of lipsticks.
The document US 200S/147390 also teaches compositions comprising oils, waxes and a gas in a minimum amount of 2 0%. However, these compositions do not exhibit a satisfactory foam texture.
A search is chus underway to obtain compositions which exhibit a normal texture, in the foam form, and which exhibit a satisfactory gloss, via the incorporation of a certain amount of oils which make it possible to contribute chese gloss properties.
A search is also underway to formulate compositions comprising a high concent of volatile or nonvolatile

oils ox~ organic 'solvents, BO as to improve the hold and/or the reaistahce to water or to sebum and/or the transfer-free properties of the said compositions.
In addition, the compositions in the foam form must exhibit good stability over time, in particular in terms of homogeneity and appearance of the product.
It is an aim of the present invention to provide another formulation route tor a composition for coating keratinous substances which exhibits a foam texture.
More specifically, a subject-matter of the invention is a cosmetic composition in the foam form comprising a continuous oily phase and at least one structuring agent for the oily phase chosen from polymeric structuring agents.
The term "composition in the foam form" is understood to raeari a composition comprising a gae phase (for example air) in the form of bubbles; another certn is "composition expanded in volume".
The composition in the foam form exhibits a light cextura and is easy to withdraw and to spread over keratinous substances.
Another subject-matter of the invention is a method for coating keratinous substances, comprising the application, to the said keratinous substances, of at least one layer of at least one cosmetic composition in the foam form comprising a continuous oily phase and at least one structuring agent for the oily phase chosen from polymeric structuring agents.
The method for coating keratinous substances according to the invention consists in applying the composition in the foam form to keratinous substances; it differs from the processes of the prior art in that the foam is

not formed in situ on the keratinous substances, that is to say that the foam is not created after application of the said composition. In particular, a delayed-expansion composition, which is a system in which a "volatile" agent is released or formed in the composition after the latter has been applied Co the keratinous substances, is not involved. Specifically, delayed-expanaion compositions are created after exposure of a gel to atmospheric pressure and/or to shearing and/or to a temperature greater than ambient temperature,
Another subject-matter of the invention is a kit for making up and/or for a non therapeutic care of keratinous substances, comprising:
a composition in the foam form comprising a continuous oily phase and at least one structuring agent for the oily phase chosen from polymeric structuring agents, and
an applicator comprising at least one application-component configured in order to apply the composition to the keratinous substances.
D«n.sitv
The composition in the foam form exhibits in particular a density (dEoara) of leas than or equal to 0.95, preferably of less than or equal to 0,9, better still of lass than or equal to 0,8. The density is preferably greater than or equal to 0.2 and better still greater than or equal to 0.3.
The density is measured according to the following protocol: a container, the volume Vo (cm3) of which is known with an accuracy- of ±0.005 cm3 (Vo being of the order of 10 cm3} , is weighed by means of a precision balance to ± 0.00005 g. Its weight is recorded as Wo (g) . This container is carefully filled with the foam until the container overflows. The surface! of the


container is Chen levelled with a. straight blade in order to obtain a perfectly flat foam surface, The weight w Cg) of the container filled with foam is then measured.
The density' corresponds to the ratio of the density of the composition, calculated as follows:
(Formula Removed)
to the density of water (1 g/cnr4) ,
Pagree of ecspyajpipa ia voXsma
The degree of expansion in volume corresponds to the amount of gas incorporated in the composition.
The composition in the foam form advantageously exhibits a degree of expansion in volume of greater than or equal to 10% and preferably of lass than 350%.
The degree of expansion in volume can range, for example, from 10% to 300%, preferably from 30% to 250% ar.d better still from 40% to 200%.
It can in particular be defined by the following formula: ,
Degree of expansion in volume =
(Formula Removed)

The density of the composition before expansion in volume is measured according to the method described above for the foam.
Size of the bubble)?;

A3 the composition according to the invention is in the foam form, it comprises gas bubbles, advantageously air bubbles.
In particular, the air bubbles of the composition exhibit a number-average diameter of less than or equal to 5 ram, for example ranging from 0.1 jun to 5 mm, preferably of less than or- equal to 1 ram and better still of less than or equal to 0,8 trail.
The number-average diameter is determined in the following way: the foam is packaged in a pot as soon as it has finished being prepared, while it is still fluid. The size of the bubbles is observed by taking a 'digital photograph of the surface of the pot 24 h after manufacture or, after opening the packaging, after having levelled the surface, by then counting, over a surface area -of approximately 1 cm2, the number of bubbles using the "Saisara" image processing software-ana by determining their number-average diameter.
Solids content
The compositions according to the invention can advantageously exhibit a content of dry matter (or solids content) of greater than or equal to 60% by weight, with respect to the total weight of the composition, preferably of greater than or equal to 6 5% by weight and better still of greater than or equal to 70% by weight, it being possible for the solids content to range up to 100% by weight, with respect to the total weight of the composition.
The concent of dry matter, that is to say the content of nonvolatile matter, can be measured in various ways. .Mention may be made, for example, of the methods by drying in an oven, the methods by drying by .exposure to infrared radiation and the chemical methods by assaying the water accox~d±ng to the Karl Fischer method.

Preferably, the amount of dry matter, commonly referred to as "solids content", of the compositions according co the invention is measured by heating the sample by infrared rays with a wavelength of 2 \m to 3.5 fan. The substances present in the said compositions which have a high vapour pressure evaporate under the effect of this radiation. The measurement of the loss in weight of the sample makes it possible to determine "the solids content" of the composition. Thesa measurements are carried out by means of a Mettler LP16 commercial infrared dryer. This technique is fully described in che documentation of the device supplied by Mettler.
The measurement protocol is as follows:
Approximately 1 g of the composition is spread over a metal dish. The latter, after introduction into the dryer, is subjected to a set temperature of 1206C for one hour. The wet weight of the* sample, corresponding to the starting weight, and the dry weight of the sample, corresponding- to the weight after exposure to the radiation, are measured by means of a precision balance.
The content of dry matter is calculated in the
following way:
Solids content = 100 x (dry weight/wet weight).
Preferably, the composition employed in the method according to the invention, is a leave-in composition.
I/eOtfTIHUOUS 0IX.Y PH&SB
The composition according to the invention comprises a continuous oily phase (or liquid fatty phase). The term "oily phase" is understood to mean, within the meaning of the patent application, a phase composed of one or more nonaqueous fatty substances which are liquid at ambxent tempex*ature (25°C) and atmospheric

pressure (760 tmnHg) , also known as oils or organic solvents, and which are compatible with one another.
The. continuous oily phase can represent from 10 to 95% of the total weight of the composition, preferably from 20 to BS% and better still from 40 to 80% by weight.
The oil can be chosen from volatile oils and/or nonvolatile oils, and their mixtures.
The term "composition comprising an oily continuous phase'1 is understood to mean that the composition esthibits a conductivity, measured at 25°C, of less than 23 juS/cm (raicroSiemens/cm) , the conductivity being measured, for example, using an MPC227 conductivity meter from Mettler Toledo and an Inlab73 0 conductivity measurement cell. The measurement cell is immersed in the composition, BO as to remove the air bubbles liable to be formed between the two electrodes of the call. The conductivity 1B read as soon as the value of the conductivity meter has stabilized. A mean is determined over at least three successive measurements.
The term ""volatile oil" is understood to mean, within the meaning of the invention, an oil capable of evaporating on contact with karatinous substances in less than one hour at ambient temperature and atmospheric pressure. The volatile organic solvent or solvents and the volatile oils of the invention are volatile cosmetic organic solvents and oils which are liquid at ambient temperature and which have a nonzero vapour pressure, at ambient temperature and atmospheric pressure, ranging in particular from 0.13 Pa to 40 000 Pa {10"J to 300 mmHg), .in particular ranging from 1.3 Pa to 13 000 Pa (0.01 Co 100 tnmHg) and more particularly ranging frora 1.3 Pa to 13 0 0 Pa (o.oi to 10 mmHgJ .

The term "nonvolatile oil" is understood Co mean an oil which remains on keratinoue substances at ambient temperature and atmospheric pressure for ac lease several hours and which has in particular a vapour pressure of less than 10"J twtiHg {0.13 Pa),
The oils can be hydrocarbon oils, silicone oils, fiuoriiiated oils or their mixtures.
The term ^hydrocarbon oil" is understood to mean art oil comprising mainly hydrogen and carbon atoms and optionally oxygen, nitrogen, sulphur and phosphorus
atows.
Volatile hydrocarbon oils can be chosen from hydrocarbon oils having from 8 to 16 carbon atoms, in particular branched C8-C16 alkan.es, such as CB-C16 isoalkanes of petroleum origin (also known as isoparaf£ins), such as isododecane (also known as 2 .. 2,4,4, 6-pentamethylheptana) » isodecane or isohexa-decane, for example the oils sold under the Igopar or Bertnethyl trade names, branched C8-C16 esters, isohexyl neopentano&te, and their mixtures. Other volatile hydrocarbon oils, such aa petroleum distillates, in particular those sold under the Shell Sole name by Shell, can also be used. According to one embodiment, the volatile solvent is chosen frora volatile hydrocarbon oils having from 8 to 16 carbon atoms and their mixtures,
Use may also be raade, as volatile oils, of volatile silicones, such as, for example, volatile linear or cyclic silicone oils, in particular those having a viscosity ^ 8 csntistokes (8 x 10"s mVs) and having in particular from 2 to 7 silicon atoms, these silicones optionally comprising alkyl or alkoxy groups having from l to 10 carbon atoms. Mention may in particular be made, aa volatile silicone oil which can be used in the invention, of octamethylcyelotetrasiloxane, degamethyi-

cyclopeatasiloxane, dodecamethylcycloftexasiloxane,
heptaraethylhexyltrisiloxane, heptamethyloctyltri-
siloxane, hexametbyldisiloxane, actairnethyltrisiloxane, dsc&raethyltetrasiloxane, dodeeatttethylpentasiloxane and their mixtures.
Mention may also be made of the volatile linear alkyltrisiloxane oils of general formula (I) CH
i 3
(Formula Removed)
where R represents an alkyl groxip comprising from 2 GO 4 carbon atoms, one or mors hydrogen atoms of which can be substituted by a fluorine or chlorine atom.
Mention may he made, among the oils of general formula (I), of:
3-butyl-1,1,1,3,5,5,5-heptawethyltrisiloxane, 3-propyl-1,1,1,3,5,5,5-heptamafchyltrisiloxane, and 3-ethyl-l,1,1,3,5,5,5-hepta»ethyltrisiloxane, corresponding to the oils of formula (I) for which R is respectively a butyl group, a propyl group or an ethyl group.
'Use may also be made of volatile fluorinated solvents, such as nonafluoromethoxybutane or perfluororoethyl-
cyclopentane.
The composition can comprise at: least one nonvolatile oil, chosen in particular from nonvolatile hydrocarbon oils and/or silicone oils and/or fluorinated oils.
Mention may in particular be made, as nonvolatile hydrocarbon oil, of;
- hydrocarbon oils of vegetable origin, such as trisaters of fatty acids and of glycerol, the fatty acids of which can have varied chain lengths from C4 to
C24, it being possible for these chains to be linear or
branched and saturated or unsaturated; these oils are
in particular wheat germ, sunflower, grape seed,
sesame, maize, apricot ksrnel, castor, ghea, avocado,
i oliv4» soybean, sweet almond, palm, rapeseed,
cottonseed, hazelnut, mae&damla, jojoba, alfalfa,
poppy, pumpkinseed, cucumber, blackcurrant seed,
evening primrose, millet/ bariey, quinaa, rye,
safflower, candlenut, passionflower or musk rose oil;
or even triglycerides of caprylic/capric acids, such as
those sold by Stearinerlas Dubois or thoae aold under
the names Miglyol 810, 812 and 818 by Dynamit Uobel.
- synthetic ethers having from 10 to 40 carbon atoms;
- linear or- branched hydrocarbons of mineral or synthetic origin, such as liquid petrolatum, polydecenes, hydrogenated polyisobutene, such as Parlaam oil, squalane and their mixtures;
- synthetic esters, such as the oils of formula RiCOORj in which R± represents the residue of a linear or branched fatty acid comprising from 1 to 40 carbon atoms and Ra represents a hydrocarbon chain, in particular a branched hydrocarbon chain, comprising from 1 to 40 carbon atoms, provided that Ri + R3 ia > 10, such as, for example, Purcellin oil {cstostearyl octanoate), isopropyl rayriatate, isopropyl palmitate, C12 to CIS alkyl benaoate, hexyl laurate, diisopropyl adipate, isononyl isononanoate, 2-ethylhexyl palmitate, isostearyl isostearatft, octanoat.es, decanoates or ricinoleates of alcohols or of polyalcohols, guch as propylene glycol dioctanoate; hydraxylated estere, such as isostearyl lactate or diisostearyl malate; and pentaerythritol esters,
- fatty alcohols comprising a branched and/or unsaturated carbon chain having from 12 to 26 carbon atoms which are liquid at ambient temperature, such as occyldodecanol, isostearyl alcohol, oleyl alcohol, 2-hexyldecanol, 2-butyloctanol or 2-undecylpentadeeanol;
- higher fatty acids, such as oleic acid, linoleic acid or linolanic acid;
- carbonates;
- acetals;
- citrates;
- and. their mixtures.
The nonvolatile silicone oils which can be used in the composition according to the invention can toe polydiraethylailoxanes (PDMBs) which are nonvolatile, polydimethylsiloxanes comprising pendent alkyl or alkoxy groups and./or alkyl or alkoxy groups at the end of the silicons chain, groups each having from 2 to 24 carbon atoms, phenyl at etl silicones, such as phenyl r.rimethicones, phenyl diroethicon.es, phenyl (triraethyl-siloxy)diphenyisiloxanes, diphenyl dimethicones, diphenyl (methyldiphenyl) tri&i loxanes or (2 -phenyl■■ ethyl)trimethylsiloxysilicates.
The fluorinated oils which can be used in the invention are in particular f luorosilicone oils,. fluorinated polyethers or fluorinated silicones, such as disclosed in the document EP-A-S47 75 2.
According to one embodiment, the oily phase comprises a nonvolatile or, preferably a hydrocarbon oil, in particular an aster oil . This ester oil can be chosen from esters of tnonocarboxylic acids with monoalcohols and polyai cohols,
Advantageously, the said ©star corresponds to the following formula (I):
(Formula Removed)
where RX represents a linear or branched alkyl radical of 1 to 40 carbon atoms, preferably of ? to 19 carbon atoms, which optionally comprises one or more ethylenic double bonds and which is optionally substituted, Rt represents a linear or branched alkyl radical of 1 to 40 carbon atoms, preferably of 3 to 3 0 carbon atoms
and better still off 3 to 20 carbon atoms which optionally coitiprises one or more ethylenic double bonds and which is optionally substituted.
The term "optionally substituted" is understood to mean that Rj and/or R2 can carry one or more sub at ituents chosen, for example, from groups comprising one- or more heteroatotns chosen from O, N and S, such aa amino, amine, alkoxy or hydroxy1,
Preferably, the total number of carbon atoms of Ri 4- R2 is greater than > 9.
Ri can represent the residue of a linear or, preferably, brauached fatty acid, preferably a higher fatty acid, comprising irotn 1 to 40 and better still from 7 to 19 carbon, atoms and Ra can represent a linear ox, preferably, branched hydrocarbon chain comprising from 1 to 40, preferably from 3 to 30 and better still from 3 to 20 carbon atoms. Again, preferably, the number of carbon atoms of- Ri + Rs > 9.
Examples of ~R\ groups are those derived from tatty acids chosen from the group consisting of acetic acid, propionic acid, butyric; acid, caproic acid, caprylic acid, pelargonic acid, c&pric acid, undecanoic acid, lauric acid, rnyristie acid, palmitic acid, stearic acid, isostearic acid, arachidic acid, behenic acid, oleic acid, linolenic acid, linoleic acid, eleostearic acid, arachidonic acid, erucic acid and their mixtures.
Examples of eaters are, for example, Purcellin oil {cetostearyl octanoate), isononyl isononanoatc, isopropyl mystristate, 2-ethylhexyl palmitate, 2-octyl-dodecyl stearate, 2-octyldodecyl ©rucate, isostearyl isostearate and heptahoates, octanoates, decanoates or ricinoleates of alcohols or of polyalcohols, for example of fatty alcohols.
Advantageously, the esters aire chosen from the compounds of the above formula (I) in which Rt represents an unsubstituted linear or branched alkyl group optionally comprising one or more athylenic double bonds and, of 1 to 4 0 carbon atoms, preferably of 7 to 19 carbon atoms, and R2 represents an unaubstituted linear or branched alkyl group optionally comprising one or more ethylenic double bonds and of l to 4 0 carbon atoms, preferably of 3 to 30 carbons and better still of 3 to 20 carbon atoms.
Preferably, Rj is an unaubstituted branched alkyl group of 4 to 1.4 carbon atoms, preferably of 8 to 10 carbon atoms, and Ra is an unsubatituted branched alkyl group of 5 to 15 carbon atoms, prefez-ably of .9 to 11 carbon atoms. Preferably, in the formula (I), Ri-CO- and R2 have the same number of carbon atoms and derive from the same radical, preferably an unaubstituted branched alkyl radical, for example the isononyl radical, that is to say that, advantageously, the ester oil molecule i s symmet rical.
The ester oil will prefex'ably be chosen from the following compounds:
isononyl isononsmoate,
cetostearyl octano&te,
isopropyl myristate,
2-ethylhexyl palmitate,
2-octyldodecyl stearate,
2-octyldodecyl erucate,
isosteryl isosteai'ate.
The oily phase can comprise from 0.5 to 100% by weight, in particular fi"om 1 to 80% by weight, especially from 2 to 30% toy weight and more pairticularly from 2 to 40% by weight of ester oil or oils.
II/STRUCTURING AgEKT
The structuring agent for the oily phase is chosen from polymeric structuring agents.
The .term "polymer" is understood to mean, within the meaning of the invention, a compound having at least 2 repeat units, preferably at least 3 repeat units and better still 10 repeat units-
The polymeric structuring agents can in. particular be from;
A) silicone polymer© comprising at least one unit
comprising;
1} polyorganosiloxanes comprising at least, two groups capable of establishing hydrogen interactions, these two groups being situated, in the chain of the polymer, and/or 2; polyorganosiloxanes comprising at least two groups capable of establishing hydrogen interactions, these two groups being situated on grafts or branchings,
the said groups capable of establishing hydrogen interactions being chosen from ester, amide, aulphonaroide, carbamate, thiocarbatsate, urea, urethane, thiourea,, oxamido, guanidino and biguanidin© groups and their combinations,
B) polyaroide polymers comprising a polymeric backbone having hydrocarbon repeat units provided with at least one nonpendent amide unit and at least one optionally functionalized pendent fatty chain and/or at least one optionally functional!zed end fatty chain which comprise at least 4 carbon atoms and.which are bonded to these hydrocarbon units,
C) olefin copolymers,
D) partially or completely cross!inked organopolysiloxane elastomers of three-dimensional structure,
S) semicrystalline polymers,
F) esters of dextrin and of fatty acid,
and their blends..
The structuring agent or agents can represent front 0.1 to S0% by weight, with respect to the total weight of the composition, preferably from 0.5 to 50% toy weight and more preferably still from 1 to 40% by weight.
The polymeric structuring agent advantageously exhibits & weight-average molecular weight of greater than or equal to 4000, better still of greater than or equal to 5000 and even better still of greater than or equal to SOOO which can. range up to 500 000.
The amount of oily phase structuring agent can be adjusted by s person skilled in the art according to the structuring properties of the said agents.
A) Silicone polymers
The silicone polymers of the composition are preferably solid at ambient temperature {25°C) and atmospheric pressure (760- rranHg) .
The term "polymer" is understood to mean, within the meaning of the invention, a compound having at least 2 repeat units, preferably at least 3 repeat unite and better still 10 repeat units.
The silicone polymers usecl aa structuring agents in the composition of the invention are polymers of the polyorganosiloxane type, auch as, for example, those described in the documents US-A-5 874 069, US-A-5 919 441, OS-A-6 051 216 and US-A-5 381 680.
According to the invention, the polymers used as structuring agent can belong to the following two families:
l) polyorganosiloxanas comprising at least two groups capable of establishing hydrogen interactions,

these two groups being situated in the chain of trie polymer, and/or
2} polyorganosiloxanes comprising at least two groups capable of establishing hydrogen interactions, these two groups being situated on grafts or branchings.
The groups capable of establishing hydrogen interactions can be chosen from ester, amide, sulphonamide, carbamate, thiocarbamate, urea, urethane, thiourea, oxamido, guanidino and biguanidino groups and their combinations,
a) According to a first, alternative form, the silicone polymers are polyorganosiloxanes as defined above, the groups capable of establishing hydrogen interactions of which are positioned in the chain of t-.hiS polymer.
The silicone polymers can more particularly be polymers comprising at least one unit corresponding to the
general formula (I)s

(Formula Removed)
in which:
1) R4, Rs, R6 and R7, which are identical or different, represent a group chosen from*.
saturated or unsaturated and linear, branched or cyclic C1 to C40 hydrocarbon groups which can comprise, in their chain, one or more oxygen, sulphur and/or nitrogen atoms and which can be substituted,

partially or completely, by fluorine atoms,
C6 to C15 aryl groups optionally substituted by
one or more d to C4 alky! groups,
polyorganosiloxane chains comprising or not
comprising one or more oxygen, sulphur and/or nitrogen
StOYilS ,
2) the X groups, which are identical or different, represent a linear or branched Cx to C30 alkylenediyl group which can comprise, in its chain/ one or more oxygen and/or nitrogen atoms,
3) Y is a Cx to Cso alkylen© (linear or branched.) , arylsne, cycloalJcylene, alkylarylene or arylalkylene divalent group, saturated or unsaturated, which can comprise one or more; oxygen, sulphur and/or nitrogen a tows and/or carry, as subscituent, one of the following atoms or groups of atoms: fluorine, hydroxyl, C3 to CB cycloal'kyl, C1 to Cao alkyl, C5s to C10 aryl, phenyl optionally substituted 'by 1 to 3 groups of the type Ci to C:s alkyl, Cx to C3 hydroxy alkyl and CN to C8 ami noa1ky1, or
4) Y represents a group corresponding to the formula:
in which;
T represents a saturated or unsaturated and linear or branched trivalent or tetravalent C3 to Q-a. hydrocarbon group which is optionally substituted by a polyorganosiloxane chain and which can comprise one or more atoms chosen from 0, N and S, or T represents a trivalent atom chosen frosts K, P and hi. and
R8 represents a linear ox~ branched d to CB0 alkyl group or a polyorganosiloxane chain, which can comprise one or more ester, amide, urethane, thiocarbaraate, urea, thiourea and/or sulphonamide groups, which may or may not be bonded to another chain

of the polymer,
5) che 9 groups, which are identical or different represent divalent groups chosen from:



(Formula Removed)
where Rs represents a hydrogen atom or a linear or branched CS to C20 alkyl group, provided that at least 5 0% of the R9 groups of the polymer represent a hydrogen atom and that at least two of the <3 groups of the polymer are a group other than:


(Formula Removed)


S) n is an integer ranging from 2 to 500,
preferably from 2 to 200, and m is an integer ranging
frorr. 1 to 1000, preferably from 1 to 700' and better
still from 6 to 2Q0.
According to the invention, 8 0% of the R4, R5, R6 and R7 gx'oups of the polymer are preferably chosen from methyl, ethyl, phenyl and 3,3,3-trifluoropropyl groups.
According to the invention Y can represent: various divalent groups, furthermore optionally comprising one or two free valences in order to establish bonds with other units of the polymer or copolymer. Preferably, Y represents a group chosen from:
a) linear Ci to Cao, preferably C3, to C10, alkylene groups,
b) branched C30 to Cs$ alkylene groups which can comprise rings and noxiconjugated urtsaturations,
c) Cs"Cs cycloalkylene groupB,
d) phenylene groups optionally substituted by one or more C1 to C40 alkyl groups,
e) C1to C40 alkylene groups comprising from 1 to 5 am I.de groups,
* f) C1to C20 alkylene groups comprising one or more substituents chosen from hydroxy!, G3 co C5 cycloalkane, C1 to C3 hydroxyalkyl and C1 to C5 alkylamine groups, g) po.lyorganosiloxa.ne chains of formula:
R5
(Formula Removed)
i in which R4,, R3, R6, R7, T and m are as defined above,

h) polyorganosiloxane chains of formula:

(Formula Removed)
b) According to the second alternative form, the polyorganosiloxanes can ba polymers comprising at least one unit corresponding to the formula (II):

(Formula Removed)
in which:
R* and Rb, which are identical or different, are as defined above for thfe formula (I),
R10 represents a group as defined above for R* and. Rs, or represents the group of formula -x-G-Ria in which X and G are as defined above for the formula (1) and Ria represents a hydrogen atom or a saturated or unsaturated and linear, branched or cyclic Ci to C5« hydrocarbon group which optionally comprises, in its chain, one or more atoms chosen from 0, S and* W and which ia optioaally substituted by one or mora fluorine atoms and/or one or mors hydroxy 1 groups, or a phenyl group optionally substituted by one or more Cj to C« alkyl groups,
R11 represents the group of formula -X-G-Ria in which X, G and R12 are as defined above,
m1i is an integer ranging from 1 to 998, and
a2 is an integer ranging from 2 to 500.
According to the invention, the polymer- used as structuring agent can be a hoiuopolymer,- that is to say a polymer comprising several identical units, in particular units of formula (D or of formula (ii).
According to the invention, use may also be made of a polymer composed of a copolymer comprising several different units of formula (I), that is to say a polymer in which at least one of the values R*r Rs, R£, R\ X, G, Y, m and n is different in one of the units. The copolymer can also be formed from several units of formula ill) in which at least one of the values R4, Rs, RiU, R11, mi and 1% is different in at least one of the units.
Use may also be made of a polymer compz'ising at least one unit of formula (I) and at least ons unit of formula (II) , it being possible for the units of formula (I) and the units of formula (II) to be identical to or different from ona another.
According to an alternative form of the invention, use may also be made of a polymer additionally comprising at least one hydrocarbon unit comprising two groups capable of establishing hydrogen interactions chosen from ester, amide. sulphonamide, carbamate, ^hiocarbamace, urea, urethane, thiourea, oxarai&o, guanidino and biguartidino groups and. their combinations.
These polymers can be block polymers or grafted polymers.
According to an advantageous embodiment of the invention, the groups capable of establishing hydrogen interactions are amide groups of formulae -C(o)NH- and
in this case, the structuring agent can be a polymer comprising at least one unit of formula (III) or (IV) :

(Formula Removed)
in which ,R4, Rs, Es, R7, X, Y, ra and n are as defined
above.

suci
unit can be obtained;
either by a condensation reaction between & silicone comprising ot,co-carboxylic acid ends and one or more diamines, according to the following reaction scheme:

(Formula Removed)
or by reaction of two molecules of a-imaaturated carboxylic acid with a diamine, according no the following reaction scheme:
(Formula Removed)
(Formula Removed)
followed by the addition of a siloxane to the ethylen: unsaturations, according to the following scheme:

+H-

■ S50

-S£H —


(Formula Removed)
in which X1- CCHK) s- corresponds to the X defined above and Y, R4, Rs, R", R7 and m are ae defined abova,
or by reaction of a silicone comprising occo-NHj

ends and of a diacid of formula HOOC-Y-COOH, according co the following reaction scheme:

(Formula Removed)
in these polyaraides of formula (III) or (IV) , m ranges from 1 to 700, in particular from 15 to 500 and especially from 50 to 200 and n ranges in particular from 1 to 500, preferably from 1 to 100 and better still from 4 to 25,
X is preferably a linear or branched alkylene chain having from 1 to 3 0 carbon atoms, in particular froro 1 to 20 carbon atoms, especially from 5 to 15 carbon atoms and more particularly 10 carbon atoms, and
Y' is preferably a linear- or branched alkylene chain or an alkylene chain which can comprise rings and/or unsaturations having from 1 to 40 carbon atoms, in particular from l to 20 carbon atoms and batter still from 2 to 6 carbon atoms, in particular 6 carbon atoms.
In the formulae (HI) and (IV) , the alkylene group representing X or Y can optionally comprise, in its alkylene part, at least one of" the following components •.
1} 1 to 5 amide, urea, urethane or carbamate groups,
2) a C5 or Cs cycloalJcyl group, and
3) a phenylene group optionally substituted by l

Co 3 identical or different Cx to C3 alkyl groups.
in the formulae {III} and (IV) , the alkylene groups c&a
also be substituted by at least one component chosen
from the group consisting of; a hydroxy1 group, a C3 to Cg cycloalkyl group, one to three Ci to C such as chose defined for R* r R", Rs and R'.
In these formulae (III) and (IV), R\ R5, Re and R"' preferably independently represent a liaear or branched Ci to C+o alkyl group, preferably a CH3, C2Hs, n-CjH7 or

isopropyl group, a polyarg&iiosiloxane chain or a phenyl group optionally substituted by one to three methyl or ethyl groups.
As has been, seen above, the polymer can comprise identical or different units of formula (III) or {IV).
Thus, the polymer can be a polya.mide comprising several units of formula (III) or (IV) of different lengths or a. polyamide corresponding to the formula (V) ,•

(Formula Removed)
in which X, Y, n, R4 co R7 have the meanings given above, mj. and ma, which are different, are chosaB within the range extending from 1 to 1000, and p is an integer ranging from 2 to 300.
In this formula, the units can be structured in order to form either a -block copolymer or a random copolymer or an alternative copolymer. In this copolymer, the units may not only be of different lengths but may also have different chemical structures, for example having different Y groups. In this case, the polymer can correspond to the formula (VI):
(Formula Removed)
in which R"1 to R7, X, Y, mlr TO2, n and p have the meanings given above and Yx is other than Y but chosen from the groups defined for Y. Ae above, the different
units can be structured in order to fiorra either a block copolymer ox a random copolymer or an alternating copolymer.
In this first embodiment of the invention, the structuring agent can also be composed of a grafted copolymer. Thus, the polyamide comprising silicone units can be grafted and optionally crosslinked by silicone chains comprising amide groups. Such polymers can be synthesized with trifunctional amines.
this casa, the polymer can comprise at least one

nit

if formula (VIIS

(Formula Removed)
in which X1 and X3, which are identical or different,, have the weaning given for X in the formula (I) , n is aa defined in the formula (I) , Y and T are as defined in the formula (I), R14 to R11 are groups chosen from the same group as the groups R* to R7, mi and ma are numbers lying within the range extending from l to 1000 and p is an integer ranging from 2 to 500.
In the formula (VII), it is preferable for;
p to range from I to 25, better still froro 1 to
R14 to R31 to tm methyl groups,
T to correspond to one of the following
formulae;

(Formula Removed)
in which R is a hydrogen atom or a group chosen from r.he groups defined for R* to R7, and R2S, R24 and RJS are independently linear or branched alkylena groups, more preferably with a formula:

(Formula Removed)
n particulr ith R23 R24 and R15 representing -CH2--CK2-..
ntx sad m2 to range Erom 15 to 500 and better still frow IS to 45,.
Xi and X2 to represent -(CHs)i0--, and
Y to represent -CHK- .
These polyamiaes comprising a grafted silicone unit of formula (VII) cart be copolymerized with silicone polyamides of formula (II) in order to form block
copolymers, alternating copolymers or random
copolymers. The percentage by weight of grafted
silicone -units (VII) in the copolymer can range from
0.5 to 30% by weight.
According to the invention, as has been seen above, the siloxane units can be in the main chain or backbone of the polymer but they can also be present in the grafted or pendent chains. In the main chain, the siloxane units can be in the form of segments as described above. In the pendent or grafted chains, the siloxane units can appear individually or in segments.
According to an alternative embodiment of the invention, use may be made of a copolymer of silicone poly amide and of hydrocarbon polyaraide or of a copolymer comprising units of formula (III) or (IV) and hydrocarbon polyaraide units, in this case, the silicone polyaroide unite can be positioned at the ends of the hydrocarbon polyamide.
According to an advantageous embodiment, the composition comprises at least one poly&imethylsiloxane block polymer of genex'al formula (I) having an index m x## comicalblona
The following compositions were prepared:

(Table Removed)
The procedure used is the sa»e as for the compositions of, Examples I to 5 above.
The parameters? of density and on degree of expansion in volume of each composition were measured according to the protocols described above.

(Table Removed)
Satiraglea XI to 131 Coiourlaas ooaipositioa»
The following compositions were prepared:

The procedure used is Che same as for the compositions of Examples l to 5 above.
The parameters of density and of degree of expansion in volume of each composition were measured according to the protocols described above,,

(Table Removed)

Exaaplgs ' 14 to 17 a

(Table Removed)
The procedure need is the same as for the compositions of Examples 1 to 5 above.
The parameters of density and of degree of expansion in volume of each composition were measured according to the protocols described above.

(Table Removed)

1. Cosmetic composition in the foam form comprising a continuous oily phase and at least one structuring agent for the oily phase chosen from polymeric structuring agents.
2. Composition according to Claim 1, characterized, in that it exhibits a density of less than or equal to 0.95.
3. Composition according to Claim 2, characterized in that it exhibits a density of less than or equal to o.g, better still of less than or-equal to 0.8.
4. Composition according to Claim 2 or 3, characterized in that it exhibits a density of greater than or equal to 0.2 and better still of greater than or equal to 0.3.
5. Composition according to one of the preceding claims, characterized in that it exhibits a degree of expansion in volume of greater than or equal to
10% .
6. Composition according to Claim 5, characterized in that it exhibits a degree of expansion in volume of less than 350%.
7. Composition according to Claim 5 or s, characterized in that it exhibits a degree of expansion in volume ranging from 10% to 3 0 0%, preferably from 30% to 250% and better still from
40% to 200%.
S. Composition according to one of the preceding claims, characterised in that the structuring agent, or agents for the oily phase are present in a content ranging from 0.1 to 60% by weight, with

respect to the total weight of the composition, better still from O.S to 50% toy weight and even better still from l to 4 0% by weight.
9. Composition according to one of the preceding
claims, characterized in that the structuring
agent for the oily phase is chosen from:
A) silicone polymers comprising at least one-unit comprising!
1) polyorganoailoxanes comprising at least two groups capable of establishing hydrogen interactions, these two groups being situated in the chain, of the polymer, and/or
2) polyorganosiloxanes comprising at least two groups capable of establishing hydrogen interactions, these two groups being situated on grafts or branchings, the said gsroups capable of establishing hydrogen interactions being chosen from ester, amide, sulphonamide, carbamate, thiocarbatnate, urea, ur ethane, thiourea, oxatnido, guanidin© and biguanidirto groups and their combinations, B') polyamide polymers comprising a) a polymeric backbone having. hydrocarbon repeat units provided with at least one nonpendent amide unit and, optionally, b) at least one optionally functionalized pendent fatty chain and/or at least one optionally functionalized end fatty chain which comprise at least 4 carbon atoms and which are bonded to these hydrocarbon units,
C) olefin copo1ymers,
D) organopolysiioxana elastomers,
E) setnicrystalline polymers,
F) asters of dextrin and of fatty acid,
and their blend®-
10. Composition according to the preceding claim, in

which the silicone polymer comprises at least one unit corresponding to the formula
(Formula Removed)
in which:
1) R4, R5, Rs and R7, which are identical or
different, represent a group chosen from:
- saturated, or unsaturated and linear, branched or cyclic C1 to C40 hydrocarbon groups which can comprise, in their chain, one or more oxygen, sulphur and/or nitrogen atoms and which can be substituted, partially or completely, by fluorine atoms,
- C6 to cl0 aryl groups optionally substituted by one or more C1 to C4 alkyl groups,
- polyorganosiloxane chains comprising or not comprising one or more oxygen, sulphur and/or nitrogen atoms,

2) the X groups, which are identical or different, represent a linear or branched C1 to C30 alkylenediyl group which can comprise, in its chain, one or more oxygen and/or nitrogen atoms,
3) 1 is a C1 to C50 alkylene (linear ox-branched} , arylene, cycloalkyiene, alkylarylene or arylalkylene divalent group, saturated or unsaturated, which can comprise one or roore oxygen, sulphur and/ox: nitrogen atoms and/or carry, as substituent, one of the following atoms or groups of atoms-, fluorine, hydroxy1, C3 to Ce cycloalkyl, Ct to C40 alkyl, C5 to C10 aryl, phenyl optionally substituted by 1 to 3 groups of the type C1 to C3 alkyl, C1 to C3 hydroxyalkyl and C1 to
C6 aminoalkyl, or
4} Y represents a group corresponding to
the formula:
(Formula Removed)
in which:
- T represents a saturated or unsaturated and linear or branched trivalent or tetravalent C3 to C21 hydrocarbon group which. is optionally substituted by a polyorgarsosiloxane chain and which can comprise one or more atoms chosen from O, N and S, or T represents a triwlent atom chosen from N, P and Al, and
- R8 represents a linear or branched C1 to C5o alkyl group or a polyorganosiloxane chain, which can comprise one ox- more ester, amide, urethane, thiocarba.ma.te, urea, thiourea and/or sulphonamide groups, which may or way not be bonded to another chain of the polymer,
5) the G groups, which are identical or different, represent divalent groups chosen from:
(Formula Removed)

where R9 represents a hydrogen atom or a linear ox branched C1 to C2o alkyl group, provided that at least 50% of the R8 groups of the polymer represent a hydrogen atom and that at least two of the G groups of the polymer are a group other than t
(Formula Removed)
6} n is an Integer ranging from 2 to 500,
preferably from 2 to 200, and m is an integer ranging from 1 to 1000, preferably from 1 to 70 0 and better still from s to 200.
.1. Composition according to Claim 10, in which Y represents a group chosen from;
a) linear C1 to C20, preferably C1 to C10 alkylene groups,
h) branched C30 to C55 alKylene groups which
can comprise rings and nonconjugated unsaturat ions,.
c) C5-C6 cycloalkylene groups,
d) phenylene groups optionally substituted by one or more C1 to C40 alkyl groups,
e) C1 to C20 alkylene groups comprising from i to 5 amide groups,
f) C1 to C2 alkylene' groups comprising one or more substituenfcs chosen from hydxoxyl, C3 to Cs cycloalkane, C1 to C3 hydraxyalkyl and c1 to C« alkylamine groups,
g) polyorganosiloxane chains of formula:

(Formula Removed)


in which R4 , R5 R6, R7 T and tn are as defined in Claim 10, and
h) polyorganosiloxane chains of formula:RS (Formula Removed)

12, Composition according to any one of Claims 9 to
11, in which the polymer comprises at least one
unit of formula (III) ox (IV}:
(Formula Removed)
in which R4, R5, R6.. R7, X,. Y, m and n are as defined in Claim 10.
13. Composition according to one of Claims 10 to 12,
in which X and/or Y represent an alkylene group
comprising, in its alkylane part, at least one of
the following components:
1) i to 5 amide, urea, urethane or carbamate groups,
2) a C5 or C6 eye1oalky1 group, and
3) a phenylene group optionally substituted by 1 to 3 identical or different C1 to C3 alkyl groups,
and/or substituted by at least one component chosen from the group consisting of:
- a hydroxy1 group,
- a C3 to C8 cycloalkyl group,
- one to three c1 to C40 aikyl groups,
- a phenyl group optionally substituted by one to three C1 to C3 alkyl groups,
- a C1 to C3 hydroxyal3cyl group, and
- a C1 to C5 aminoalkyl group.
Compos it ion according to any one of Claims 10 to 13, in which Y represents:
where RB represents a polyorganosiloxane chain and T represents a group of formula:
(Formula Removed)
in which a, h and c are independently integers ranging from 1 to 10 and R13 is a hydrogen atom or a group such as those defined for R*, Rs, R6 and R'
in Claim 10.
Composition according to any one of Claims 10 to 14, in which R'!, Es, Rs and R7 independently represent a linear or branched Ci to OJO alkyl group, preferably a CHS, C2H5, n-C3H7 or isopropyl group, a polyorganosiloxane chain or a phenyl group optionally substituted by one to three
- a hydroxy! group,
- a C1 to C8 Cycloalkyl group,
- one to three C1 to C40 alkyl groups,
- a phenyl group optionally substituted by one to three C1 to C3 alkyl groups,
- a C1, to C3 hydxoxyalkyl group, and
- a C1 to C6 aminoalkyl group.
A. Composition according to any one of Claims 10 to 13, in which Y represents:
where R8 represents a polyorganosiloxane chain and T represents a group of formula:•
(Formula Removed)
in which a, b and c are independently integers ranging from 1 to 10 and R13 is a hydrogen atom or a group such as those defined for R*, R*, Re and R! in Claim 10.
15, Composition according to any one of Claims 10 to 14, in which R\, Rs,, Rs and R7 independently represent a linear or branched Ci to C40 alkyl group, preferably a CH3, C2H5, n-C3H7 or isopropyl group, a polyorganosiloxane chain or a phenyl group optionally substituted by one to three

methyl or ethyl groups.
Composition according to Claim 10 characterized in that it comprises at least one polydimethyleiloxaae block polymer of general formula (I) having an index rn of approximately
100 .
Composition according to one of the preceding claims, characterized in that the structuring agent is chosen from polyamide polymers comprising a} a polymer backbone having hydrocarbon repeat units provided with at lease one noapsndent amide unit and, opcionally, b) at least one optionally functionalized pendent fatty chain and/or at least one optionally functionalized end fatty chain which comprise at least 4 carbon atoms and which ara bonded to these hydrocarbon units.
Composition accoarding to the preceding claim, characterised in that the fatty chains represent from 40 to 98% and better still from 50 to 95% of the total number of the amide units and fatty chains,
Composition according to either of Claims 17 and
18, characterized in that the fatty chains
comprise from 6 to 12 0 carbon atoms and batter
still from s to 120 carbon atoms.
Composition according to one of Claims 17 to IS, characterized in that; the pendent fatty chains are bonded directly to at least one of the nitrogen atoms of the amide units.
Composition according to one of Claims 17 to 20, characterized in that the average molar mass of the polyamide is less than 100 000.

Composition according to one of Claims 17 to 21, characterized in that the average molar mass of the polyamide ranges from 1000 to 100 000, preferably from 1000 to 50 000 and bettor still from 1000 to 30 000.
Composition according to one of Claims 17 to 22, characterized in that the end fatty chain or chains are bonded to the backbone via bonding groups.
Composition according to Claim 23, characterized in that the bonding groups are ester groups,
Composition according to one of Claims 17 to 24, characterized, in that the fatty chain or chains comprise from.12 to 68 carbon atoms.
Composition according to one of Claims 17 to 25, characterized in that the polyamide is chosen from polyamides of following formula (A):
(Formula Removed)

in which;
n is an integer ranging from 1 to 30,
R1 independently represents, in each case, a
fatty chain and is chosen from an alkyl or
alkeayl group having at least 1 carbon atom and
in particular from 4 to 24 carbon atoms;
R2 independently represents, in each case, a
hydrocarbon radical comprising from l to 52
carbon atoms;
R'3 independently represents, in each case, an
organic group comprising at least one atom

chosen from carbon, hydrogen or nitrogen atoms, provided that R'3 comprises at least 3 carbon atoms;
R'4 independently represents, in. each case; <& hydrogen atom, an alkyl group comprising from 1 to 10 carbon atoms or a direct bond to at least one group chosen from R'3 and another Rf4, so that, when the said group is another R4, the nitrogen atom to which both R'3 and R4 are bonded forma part of a heterocyclic structure defined by R4N-R'3, provided that at least 50% of the R' 4 groups represent a hydrogen atom, and
L represents a, bonding group chosen from eater., ether, amine, urea;, urethane, thioester, thioether, thiourea and thiourethane groups, optionally substituted by at least one R1 group.
Composition according to one of Claims 17 to 26, characterized in that the polyamide is chosen from polyamides of following-formula (B) :

(Formula Removed)
in which:
m denotes an integral number of amide units such, that the number of ester groups represents from 10% to 5 0% of the total number of the ester and amide groups;
R1 is in each case independently an alkyl or alkenyl group having at least 4 carbon atoms and in particular from 4 to 24 carbon atoms; R2 independently represents, in. each caste, a C4

to C42 hydrocarbon group, provided that 5 0% of the R3 groups represent a G30 to c42 hydrocarbon group;
R3 independently represents, in. each case, an organic group provided with at least 2 carbon atoms, with hydrogen atoms and optionally with one or raore oxygen or nitrogen atoms; and R4 independently represents, in each case, a hydrogen atom, a C1 to C10 alkyl group or a direct bond to R3 or to another R4, so that the nitrogen, atom to which both R3 and R4 ara bonded forms part of a heterocyclic structure defined by R4-N-R3, with at: least 50% of the R4 groups representing a hydrogen atom,
Composition according to one of the preceding claims, characterized in that the structuring agent is chosen from olefin copolymers.
Composition according to the preceding claim, characterized in that the olefin copolymer is a block copolymer cnosen from diblock, triblock, multiblock, radial and star copolymers and their
blends.
Composition according to Claim 2 8 or 2.9, characterized in that the olefin copolymer is chosen from hydrocarbon block copolymers formed by a polymerization of monomers having in particular one or two athylenic unsaturations and. having from 2 to 5 carbon atoms,
Composition according co one of Claims 28 to 30, characterized in that the copolymer is chosen from copolymers formed by a polymerization of styrene and of olefin, the olefin being chosen from ethylene, propylene, butadiene or isoprene.
Composition according to one of Claims 2 3 to 31,

characterized in that the olefin copolymer is chosen from optionally hydrogenated copolymers comprising styrena blocks and comprising ethylene/C3-C4 alkylane blocks.
Composition according to any one of Clairas 28 to 32, characterized in that the oily structuring agent is chosen rxoffi styrene-butylene/ethylene-styrene triblock copolymers.
Composition according to any one of the preceding claims,. characterized in that it comprises a structuring agent chosen from esters of dextrin and of fatty acid.
Composition according to Claim 34, characterised in that the ester of dextrin and of fatty acid(s) corresponds to the formula (C):
(Formula Removed)

in which:
n is art integer ranging from 3 to 200,
the Ri, R2 and R3 radicals, which are identical or
different, are chosen from hydrogen or an acyl
group (R-C0-) in which the R radical is a
saturated or unsaturated arid linear or branched
hydrocarbon group having from 5 to 29 carbon
atoms, with the proviso that at least one of the
said R1, R2 or R3 radicals is other than hydrogen.
Composition according to Claim 35, characterized

in that at least two of the said R1., R2 or R3 radicals are identical and other than hydrogen.
Composition according to Claim 35 or 36i, characterized in chat the ester of dextrin and of fatty acid has a degree of substitution of less than or equal to 2.5 on the basis of one glucose unit, in particular varying from 1,5 to 2.5 and especially from 2 to 2.5.
Composition according to Claim 35, characterized in than n varies from 25 to 50 in the formula (C).
Composition according to any one of Claims 35 to 38, characterized in that the acyl group is chosen from caprylyl, caproyl, lauroyl, myristyl, palmityl, stearyl, eicosanyl, docosanoyl, isovaleryl, 2-ethylbutyryl, ethylmethylacetyl, i soheptanyl, 2-ethylnexanyl, i sononanyl, isodecanyl, isotridecanyl, isorayristyl, isopalmityl, isostearyl, isohexanyl, deeenyl, dodecenyl, tetradecenyl, myristyl, hexadecenoyl, palmitoleyl, oleyl, elaidyl, eiooaenyl, sorbyl, linoleyl, linolenyl, punicyl, arachidonyl and stearolyl radicals and their mixtures.
Composition according to any one of Claims 35 to 33, characterized in that the ester of dextrin and of fatty acid(s) comprises at least dextrin palmitate..
Composition according to any one of Claims 35 to 40, characterized in that the weight-average molecular weight of the ester of dextrin and of fatty acid {si varies from 10 000 to 150 000, in particular from 12 000 to 100 000, indeed even from 15 000 to 80 000,
Composition according to any one of the preceding

claims, characterised in that the continuous oily phase comprisee at least one oil chosen from volatile or nonvolatile oils.
composition according to any one of the preceding claims, characterised in that the continuous oily phase comprises at least one nonvolatile oil.
Composition according to one of the preceding claims, characterised in that it comprises at least one ester oil chosen from esters of monocarboxylic acids with monoalcohols or polyalcohols.
Composition according to Claim 44, characterized in that the said ester corresponds to the following formula:
(Formula Removed)
where
R1 represents a linear or branched alkyl radical of 1 to 4 0 carbon atoms,, preferably of 7 to 19 carbon atoms, which optionally comprises one or more ethylenic double bonds and which is optionally substituted,
R2 represents a linear or branched alkyl radical of 1 to 40 carbon atoms, preferably of 3 to 30 carbon atoms and better still of 3 to 20 carbon atoms which optionally comprises one or more ethylenic double bonds and which is optionally substituted.
Composition according to Claim 44 or 45, characterized in that the ester oil is chosen from the following compounds: isononyl isononanoate, cetostearyl octanoate, isopropyl myrietate, 2~ efchylhexyl palmitate, 2-octyldodecyl scearate, 2-octyldodecyl erucate, isostearyl isostearate and

heptanoates, octanoates, daeanoates or ricinoleates of alcohols or polyaleoholg.
Composition according to any one of Claims 4 4 to 46.. characterized in that the oily phase comprises from 0.5 to 100% by weight, in particular from 1 to 80% by weight, especially from 2 to 50% by weight and more particularly from 2 to 40% by weight of the eater oil or oils.
Composition according to any one of the preceding claims,- characterized in that the continuous oily phase comprises ax least one volatile oil.
Composition according to the preceding claim, characterized in. chat the volatile oil is a hydrocarbon oil.
Composition according to one of 'the preceding claims, characterized in that the continuous oily phase represents from 10 to S5% of the total weight of the composition, preferably from 20 to 85% and better still from 40 to 80%.
Composition according to any one of the preceding claims, characterized in that it exhibits a content of water and/or water-soluble solvent(s) of leas than or equal to 15% by weight, with respect to the total weight of the composition, preferably of lees than or equal to 10% by weight, better still of less than or equal to 5% by weight and even better still of less than or equal to 3% by weight.
Composition according to any one of Claims 1 to 50, characterized in that it is anhydrous.
Composition according to one of the preceding claims, characterized in. that it comprises at

least one wax or one pasty fatty substance.
Composition according to Claim 53, characterized in that the wax is present in a content ranging from 0.1 to 50% by weight, with respect to the total weight of the composition, in particular from 0.5 to 35% by weight.
Method for coating keratinous substances, comprising the application, to the said keratinous substances, of at least one layer of at least one composition according to any one of Claims 1 to
54 .
Method for coating keratinous substances, comprising the application, to the said keratinous substances, of at least one layer of at least one cosmetic composition in the foam form comprising a continuous oily phase and at least one structuring agent for the oily phase choaen from polymeric structuring agents.
Kit for making up and/or for the nonthsrapeutic care of keratinous substances, comprising:
a container comprising a composition in the* foam form exhibiting a continuous oily phase anal at least one structuring agent for the oily phase chosen from polymeric structuring agents, and
an applicator comprising at least one application component configured in ox'der to apply the composition to keratinous substances.

Documents

Application Documents

# Name Date
1 1153-del-2008-abstract.pdf 2011-08-21
1 1153-del-2008-form-5.pdf 2011-08-21
2 1153-del-2008-claims.pdf 2011-08-21
2 1153-del-2008-form-3.pdf 2011-08-21
3 1153-del-2008-correspondence-others.pdf 2011-08-21
3 1153-del-2008-form-2.pdf 2011-08-21
4 1153-del-2008-description (complete).pdf 2011-08-21
4 1153-del-2008-form-1.pdf 2011-08-21
5 1153-del-2008-description (complete).pdf 2011-08-21
5 1153-del-2008-form-1.pdf 2011-08-21
6 1153-del-2008-correspondence-others.pdf 2011-08-21
6 1153-del-2008-form-2.pdf 2011-08-21
7 1153-del-2008-claims.pdf 2011-08-21
7 1153-del-2008-form-3.pdf 2011-08-21
8 1153-del-2008-abstract.pdf 2011-08-21
8 1153-del-2008-form-5.pdf 2011-08-21