Abstract: The invention relates to an relates to an improved process for the treatment of wastewater comprising (a) contacting the wastewater with fast settling sludge originating from step (c) in an anaerobic zone to obtain a mixture of wastewater and sludge; (b) subjecting the mixture originating from step (a) and slow settling sludge originating from step (c) to an aerobic zone to obtain a mixture of water and sludge; (c) subjecting a first part of the mixture originating from step (b) to a sludge selection step wherein sludge is selected based on settling velocity and a first portion containing slow settling sludge and a second portion containing fast settling sludge is collected wherein average settling velocity of the fast settling sludge is greater than the settling velocity of the slow settling sludge and wherein the first portion is returned to step (b) and the second portion is returned to step (a); and (d) separating sludge from a second part of the mixture originating from step (b) to obtain treated wastewater. The invention also relates to a system for carrying out this process.
[0001] The present invention relates to an improved process for the treatment of
wastewater, in particular for the secondary treatment of wastewater using micro-
S organisms, and to a system for performing the process.
Background
[0002] Wastewater treatment typically involves several stages. During pnmary
treatment, heavy solids settle on the bottom of a basin and light oily materials
1 0 accumulate on the surface of the water. Heavy solids and light oils are removed and the
primary-treated wastewater is subjected to secondary treatment, wherein dissolved and
suspended biological material is removed. Secondary treatment is typically performed
using microorganisms that convert the biological material to sludge. Typically,
secondary treatment is combined with tertiary treatment, wherein pollutants such as
15 phosphates and nitrates are removed by microorganisms. A combined secondary and
tertiary treatment of wastewater typically involves an anaerobic zone, an anoxic zone
and an aerobic zone, wherein wastewater is contacted with active sludge. The microorganisms
present in the sludge effectuate sludge growth, wherein organic matter is
converted into sludge. Surplus sludge is separated from the treated water by settlement
20 and subsequently discharged from the wastewater treatment plant as waste.
[0003] Processes for the treatment of wastewater are for example known from WO
2008/141413, wherein a mixture of wastewater and sludge, downstream of the
anaerobic and aerobic zones, is led to a fast settler which operates discontinuously.
Settled sludge is transferred to the anaerobic zone and the remainder of the mixture is
25 led to a second settler. An alternative wastewater treatment system is described in US
2014/0144836, wherein part of the sludge formed in the process is subjected to a
gravimetric selector. The heavy sludge is fed back to the process while the light sludge
is subjected to post-treatment. The remaining part of the mixture of sludge and water is
led to a settler and the sludge settled therein is recycled to the start of the treatment
30 process.
[0004] JP 2008/284427 discloses a wastewater treatment method wherein fermented
raw sludge is separated from the organic wastewater to generate an organic acid, and
which organic acids are used to stably and efficiently produce a granular sludge. There
is no separation in until after the final sedimentation step, and this is preceded by a
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granule outflow preventing section which is there to filter out granules having a size
bigger than 0.5 mm. After filtering out the larger parts, all of the sludge is returned to
biological treatment and granule formation/production.
[0005] Nowadays, the formation of sludge granules, opposed to sludge floes, is
5 considered optimal for the treatment of wastewater. Granular sludge has excellent
settling properties. As granular sludge settles many orders of magnitude more quickly
than sludge floes, thus eliminating the need for huge settling tanks wherein the treated
wastewater has to reside for many hours (typically at least 4 h) to be able to separate it
from the sludge. Using granular sludge may reduce the area of a wastewater treatment
10 plant to only one fifth of the original area, which dramatically reduces the
environmental impact of such a plant. The formation of granular sludge is known for
batch-wise wastewater treatment processes, e.g. from WO 98/37027 and WO
2004/024638, and has been successfully implemented in the Nereda wastewater
treatment process. Ever since the first formation of granular sludge, the field has sought
15 for means to enable the formation of granular sludge in a continuous wastewater
treatment process. To date, no such means have been found. The present invention
provides in the need for a continuous wastewater treatment process wherein granular
sludge is formed and/or maintained.
20 Summary of the invention
[0006] The invention relates to an improved process for the treatment of wastewater.
The inventors surprisingly found that wastewater may be treated in continuous fashion
while at the same time sludge granules are formed and/or maintained within the
wastewater treatment system. Such a continuously operable process for the treatment of
25 wastewater wherein sludge granules are effectively formed and maintained is
unprecedented in the art. The invention further concerns a system for performing the
process according to the invention.
[0007] The process according to the invention comprises an anaerobic step (a), an
aerobic step (b), a sludge selection step (c) and a sludge removal step (d). The process
30 involves the selection of fast settling sludge from a part of the sludge originating from
aerobic step (b) and returning that sludge to the anaerobic zone of step (a) where it is
contacted with incoming wastewater. Slow settling sludge is not returned to the
anaerobic zone, but instead to the aerobic zone of step (b). As such, the total sludge
content within the system is guaranteed and at the same time the growth of fast settling
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sludge is promoted while the growth of slow settling sludge is not. Compared to
conventional wastewater treatment, the present process differs in at least one or two
aspects. First of all, only part of the sludge is subjected to a recycle step (sludge
selection step (c) with recycles to steps (a) and (b)) and secondly the recycled fast
5 settling sludge is returned to specifically the anaerobic zone, and not to a different zone
of the wastewater treatment system. The inventors surprisingly found that when these
two features are combined in a continuous process for wastewater treatment, granular
sludge is formed. Prior art wastewater treatment processes, wherein fast settling sludge
is not specifically returned to the anaerobic zone, does not stimulate the growth of
10 specifically this fast settling sludge, such that granular sludge is not formed therein.
[0008] The process according to the invention is a major improvement over prior art
continuous wastewater treatment processes. The improvement over prior art processes
mainly resides in that granular sludge is formed and maintained within the system,
which provides the present process and system with several advantages. First of all, the
15 settling of step (d) may be drastically down-scaled, as granular sludge settles markedly
more quickly than sludge floes. Additionally, the settling of step (d) may employ an
(increased) upflow. Prior art processes do not employ such an upflow, or only at a very
low upflow speed. A faster upflow may be used in the present process while still
maintaining effective separation of sludge and treated water. Secondly, the use of an
20 anoxic tank in between the anaerobic and aerobic zone as well as water/sludge recycles
from the aerobic zone to the anoxic zone and the anaerobic zone are not required while
complete removal of nitrogen compounds from the wastewater is still possible. Also,
the volume of the anaerobic tank may be greatly reduced, as the sludge subjected to the
anaerobic zone is a concentrated stream of granular sludge, compared to diluted
25 floccular sludge in prior art processes. This all is combined with a continuously and
stable operable process, wherein granular sludge is readily maintained. These
advantages lead to a dramatic simplification of wastewater treatment plants, while
keeping the efficacy in purifying the incoming wastewater unabatedly high.
30 List of preferred embodiments
1. A process for the treatment of wastewater, comprising:
(a) contacting the wastewater with fast settling sludge originating from step (c)
in an anaerobic zone, to obtain a mixture of wastewater and sludge;
5
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(b) subjecting the mixture originating from step (a) and slow settling sludge
originating from step (c) to an aerobic zone to obtain a mixture ofwater and
sludge;
(c) subjecting a first part of the mixture originating from step (b) to a sludge
selection step, wherein sludge is selected based on settling velocity and a
first portion containing slow settling sludge and a second portion containing
fast settling sludge are collected, wherein the average settling velocity of the
fast settling sludge is greater than the settling velocity of the slow settling
sludge, and wherein the first portion is returned to step (b) and the second
10 portion is returned to step (a); and
(d) separating sludge from a second part of the mixture originating from step (b),
to obtain treated wastewater.
2. Process according to embodiment 1, wherein the sludge selection of step (c) is
performed in an upflow reactor, which is preferably operated with an upflow in the
15 range of 1 - 25 m/h.
3. Process according to embodiment 1 or 2, wherein step (c) operates with a
substantially constant feed rate of the first part of the mixture of step (b).
4. Process according to any of the preceding embodiments, which is operated
continuously.
20 5. Process according to any of the preceding embodiments, wherein in step (c) a third
portion containing slow settling sludge is collected, which is discharged as waste
sludge.
6. Process according to any of the preceding embodiments, wherein the mixture
transfers barrier-free from step (a) to (b), from step (b) to (c) and from step (b) to
25 (d).
7. Process according to any of the preceding embodiments, wherein at least part of
the sludge originating from step (d) is returned to step (b).
8. Process according to any of the preceding embodiments, wherein the third portion
of the sludge originating from step (c) and/or at least part of sludge originating
30 from step (d) are subjected to sludge treatment.
9. System for carrying out the process according to any one of embodiments 1 - 8,
compnsmg:
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(a) an anaerobic tank, comprising one or more inlets for receiving wastewater
and for receiving fast settling sludge originating from outlet (c3) and an
outlet (a3) for discharging a mixture ofwastewater and sludge to tank (b);
(b) an aerobic tank, comprising an inlet (b1) for receiving the mixture of
5 wastewater and sludge originating from outlet (a3), an outlet (b2) for
discharging a first part of a mixture of water and sludge to sludge selector
(c), an outlet (b3) for discharging a second part of the mixture of water and
sludge to separator (d) and an inlet (b4) for receiving a mixture of slow
settling sludge originating from outlet ( c2);
10 (c) a sludge selector, comprising an inlet (c1) for receiving the first part ofthe
mixture of water and sludge originating from outlet (b2), an outlet ( c2) for
discharging a first portion of slow settling sludge to tank (b) and an outlet
(c3) for discharging a second portion of fast settling sludge to tank (a) and
means (c4) for selecting sludge based on settling velocity; and
15 (d) a separator for separating sludge from a mixture of sludge and water,
comprising an inlet ( d1) for receiving the second part of the mixture
originating from outlet (b3), a first outlet (d2) for discharging treated water
and a second outlet (d3) for discharging separated sludge,
wherein outlet (a3) is in fluid connection with inlet (b1), outlet (b2) is in fluid
20 connection with inlet (c1), outlet (b3) is in fluid connection with inlet (d1), outlet
(c2) is in fluid connection with inlet (b4) and outlet (c3) is in fluid connection with
an inlet of unit (a).
10. System according to embodiment 9, wherein unit (a) comprises two inlets, a first
inlet (a1) for receiving wastewater and a second inlet (a2) for receiving fast settling
25 sludge originating from outlet (c3), and wherein outlet (c3) is in fluid connection
with inlet ( a2).
11. System according to embodiment 9 or 10, wherein sludge selector (c) is integrated
in aerobic tank (b).
12. System according to any one of embodiments 9- 11, wherein sludge selector (c) is
30 an upflow reactor capable of operating with an upflow speed of 1 - 25 m/h,
preferably an upflow speed varying in the range of 1 - 25 m/h.
13. System according to any one of embodiments 9- 12, wherein the fluid connection
between outlet (c3) and inlet (a2) is equipped with a pump employing an upward
stream of air or liquid or a screw pump.
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14. System according to any one of embodiments 9 - 13, wherein separator (d) is an
upflow reactor capable of operating with an upflow speed of0.5- 10m/h.
15. System according to any one of embodiments 9- 14, wherein outlet (a3) together
with inlet (b 1) take the form of an opening in the bottom part of a wall separating
5 tanks (a) and (b).
Detailed description
[0009] The present invention relates to an improved process for the treatment of
wastewater, and to a system designed to perform the process according to the invention.
10 The skilled person will appreciate that all said below for the process according to the
invention equally applies to the system according to the invention and vice versa.
PROCESS
[0010] The process according to the invention comprises:
15 (a) contacting the wastewater with fast settling sludge originating from step (c) in an
anaerobic zone, to obtain a mixture of wastewater and sludge;
(b) subjecting the mixture originating from step (a) and slow settling sludge
originating from step (c) to an aerobic zone to obtain a mixture of water and
sludge;
20 (c) subjecting a first part of the mixture originating from step (b) to a sludge selection
step, wherein sludge is selected based on settling velocity and a first portion
containing slow settling sludge and a second portion containing fast settling sludge
are collected, wherein the average settling velocity of the fast settling sludge is
greater than the settling velocity of the slow settling sludge, and wherein the first
25 portion is returned to step (b) and the second portion is returned to step (a); and
(d) separating sludge from a second part of the mixture originating from step (b), to
obtain treated wastewater.
[0011] In one embodiment, step (b) is performed directly following step (a), without
any significant further alterations to the mixture of wastewater and sludge obtained in
30 step (a). In one embodiment, step (c) is performed directly following step (b), without
any significant further alterations to the first part of the mixture of water and sludge
obtained in step (b). In one embodiment, step (d) is performed directly following step
(b), without any significant further alterations to the second part of the mixture of water
and sludge obtained in step (b). In one embodiment, step (a) is performed directly
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following step (c), without any significant further alterations to the second portion
containing fast settling sludge obtained in step (c). In one embodiment, step (b) is
performed directly following step (c), without any significant further alterations to the
first portion containing slow settling sludge obtained in step (c). In one embodiment,
5 the mixture that is obtained in step (a) is substantially wholly formed by incoming
wastewater and the fast settling sludge originating from step (c). In one embodiment,
the mixture that is obtained in step (b) is substantially wholly formed by the mixture
originating from step (a), the slow settling sludge originating from step (c) and
optionally sludge originating from step (d). In one embodiment, the sludge of the first
10 portion is slow settling sludge and the first portion could also be referred to as the first
portion of slow settling sludge. In one embodiment, the sludge of the second portion is
fast settling sludge and the second portion could also be referred to as the second
portion of fast settling sludge. In one embodiment, the sludge of the optionally obtained
third portion is slow settling sludge and the third portion could also be referred to as the
15 third portion of slow settling sludge.
[0012] In the process of the invention, wastewater undergoes conventional wastewater
purification with microorganisms, involving phosphate removal, nitrification and
denitrification employing an anaerobic and an aerobic zone as known in the art. In the
20 process according to the invention, wastewater is contacted with fast settling sludge in
the anaerobic zone of step (a). Even though one of the major advantages of the process
according to the invention is that it may be performed continuously, a batches-wise
performance is not excluded. Furthermore, the inventors found that continuous
operation, in particular continuous feeding of fast settling sludge to the anaerobic zone,
25 further optimizes the formation and maintenance of granular sludge within the system.
Continuous nutrient uptake in the anaerobic zone was found to promote granular sludge
formation most optimally. Thus, the present process is preferably a continuous process.
Herein, wastewater is continuously fed to step (a) of the process of the invention, while
treated water is continuously discharged from step (d). When the (waste)water proceeds
30 through the process, in particular steps (a), (b) and (d), microorganisms present in the
sludge convert organic matter present in the wastewater into further sludge. During
especially steps (a) and (b) of the process according to the invention, the conditions are
such that the growth of the sludge is promoted. Thus, the amount of sludge is increased
while only part of the sludge is needed to keep the process running. Thus, in step (c),
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the sludge that is best suited to keep the process running, fast settling sludge, is selected
and returned to step (a). This fast settling sludge, obtained as second portion in step (c),
is granular and has excellent settling properties. The remaining of the sludge, which
settles more slowly and which is obtained as first (and optionally third) portion in step
5 (c) and as separated sludge in step (d), is typically fed to the aerobic zone of step (b)
and/or may be discharged from the process. One of the surprising advantages of the
process according to the invention is that in step (c), the best sludge for running the
process is selected and returned to step (a). Moreover, this is accomplished while not
the complete sludge fraction present at the end of step (b) has to be subjected to such
10 sludge selection, but only part thereof needs to be subjected to sludge selection step (c).
Sludge selection step (c) can for example be performed in an up flow reactor with a
rather high upflow speed, as further described below, while keeping the separation of
desired, fast settling, granular sludge from the undesired, slow settling, floccular sludge
optimal.
15 [0013] Thus, in the process of the invention, fast settling sludge or "heavy sludge" (the
second portion originating from step (c)) is mixed with the incoming wastewater, thus
forming a mixture of wastewater and sludge. This mixture may be formed directly in
the anaerobic zone or a separate selector may be present upstream of the anaerobic
zone wherein the sludge and incoming wastewater are mixed prior to being fed to the
20 anaerobic zone. The mixture of sludge and wastewater resides in the anaerobic zone of
step (a) for a certain amount of time. To the aerobic zone of step (b), a portion of
sludge (the first portion originating from step (c)) is added to the mixture originating
from step (a). This portion typically contains mainly non-granular sludge, as it concerns
the slow settling sludge or "light sludge" from selection step (c). Also, the water that
25 resides in step (b) is already partly treated, as the majority of the organic matter is taken
up by the sludge in step (a). Thus, the mixture that resides in the aerobic zone of step
(b) is referred to as a mixture of sludge and water.
[0014] In one embodiment, the process is advantageously started by mixing the first
batch of incoming wastewater with sludge comprising 25 - 80 wt%, more preferably
30 40-60 wt% of fast settling sludge according to the invention in step (a). A maximum
is preferred in order to optimize the burden of transport. A minimum relative amount of
fast settling sludge helps optimizing the amount of heavy sludge obtained in step (c),
thus rendering it possible to work with reduced size and complexity of sludge selectors
in step (c).
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[0015] The wastewater to be treated with the process according to the invention or in
the system according to the invention typically contains an organic nutrient (organic
matter). Typically, the biochemical oxygen demand (BOD) of the incoming wastewater
is at least 50 mg/L, such as 100- 10000 mg/L. Any type of wastewater, such as sewage
5 water, may be treated according to the invention. The process according to the
invention may thus also be referred to as sewage treatment. The wastewater subjected
to the process according to the invention may be pretreated prior to step (a), such as
wastewater that has received a primary treatment as known in the art, although primary
treatment will not always be necessary to operate the present process efficiently.
10 Typical pretreatment of the wastewater includes one or more of clarification, grit
removal, fat and grease removal and pre-sedimentation.
[0016] The inventors found that the sludge that is formed in and circulates through the
process is mainly granular. In step (c), specifically the fast settling sludge (or "heavy
sludge") is selected and fed to step (a), where it is contacted with the highest
15 concentration of organic nutrients as present in the incoming wastewater. As the uptake
of nutrients by the sludge is promoted by the anaerobic conditions during step (a), the
growth of the granular sludge is stimulated in the process according to the invention.
The sludge contains microorganisms as common for sludge that is present in and
produced by wastewater treatment plants. Although conventional wastewater treatment
20 plants contain sludge floes, the inventors found that with the present configuration of
the wastewater treatment system, the sludge grows in granular form instead of in floes.
Nevertheless, minor amounts of floccular sludge may be present within the wastewater
treatment system according to the invention. As such floccular sludge is not subjected
to step (a), its growth is not promoted and the fraction of floccular sludge typically
25 remains small to negligible. The present process runs smoothly with such minor
amounts of floccular sludge. In view of the presence of microorganisms, the sludge
present in the system according to the invention may also be referred to as "active
sludge". The microorganisms needed for the process according to the invention can be
found in the sludge of conventional wastewater treatment plants. They do not need to
30 be isolated, since the conditions specified ensure that these microorganisms remain part
of the sludge granules. The conditions of the process according to the invention give
rise to the formation of sludge granules, which are significantly larger and denser than
the sludge floes obtained in conventional wastewater treatment plants. The sludge
granules typically have an average settling velocity of above 1 m/h, preferably above 5
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m/h or even above 10 m/h, compared to the settling velocity of at most 1 m/h for sludge
floes. The average settling velocity of sludge suspended in water is defined herein as
the velocity equal to the maximum upflow speed generated in the sludge/water
suspension at which substantially no sludge is present in the top effluent. Settling
5 velocities or settling velocities are commonly determined in the art. A typically
procedure for determining the average settling velocity is the measurement of the speed
in m/h of the downward movement of the sludge front in a non-agitated vessel. This
measurement may occur within the system, e.g. in the anaerobic tank or in the aerobic
tank (when the inflow of oxygen is stopped during the measurement), or a sample of
10 the sludge/water mixture may be transferred to a laboratory vessel. The further measure
well-known in the art for the average settling velocity is the sludge volume index
(SVI). SVI is defined as the volume (in ml) occupied by 1 gram of sludge after a
certain time of settling. Typical values for the ratio of the SVI after 5 minutes of
settling (SVI-5) over the SVI after 30 minutes of settling (SVI-30) for the granular
15 sludge are below 3, typically in the range 2 - 2.8, more typically about 2.5, while
conventional floccular sludge has a SVI-5 I SVI-30 ratio above 3.
[0017] When the concentration of fast settling sludge within the system is relatively
small, e.g. during start-up of the system, the amount of fast settling sludge that is
selected as the second portion in step (c) is relatively small, but since a larger part of
20 sludge will be selected as first portion, the total content of sludge in the system remains
sufficiently high. As only fast settling sludge is subjected to step (a), this sludge portion
will grow in size. The amount of fast settling sludge that is selected as the second
portion in step (c) will thus increase. When the process according to the invention runs
in a steady state, the second portion selected in step (c) will be much larger, while the
25 additional sludge portion, i.e. the first portion selected in step (c) which is added during
step (b), is relatively smaller.
[0018] In order to allow unhindered passage of the fast settling sludge, it is preferred
that the transition between the anaerobic zone of step (a) and the aerobic zone of step
(b) is barrier-free. Likewise, it is preferred that the transition between the aerobic zone
30 of step (b) and the sludge selector of step (c) is barrier-free. Likewise, it is preferred
that the transition between the aerobic zone of step (b) and the separator of step (d) is
barrier-free. In a preferred embodiment, the mixture transfers barrier-free from step (a)
to (b), from step (b) to (c) and from step (b) to (d). Herein, "barrier-free" refers to the
absence of physical barriers, such as height differences (thresholds, raises, etc) and
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pumps, between the various zones, tanks or modules within the system according to the
invention, such that even the fast settling sludge that is formed in the present system is
easily and without hindrance capable of circulating through the system. Since fast
settling sludge has a tendency to accumulate at the bottom of a tank, such an effective
5 flow of the sludge/water mixture is obtained when the transitions between the tanks are
barrier-free. Such barrier-free transitions typically take the form of openings in the wall
separating the units. For efficient circulation of fast settling sludge throughout the
system, it is preferred that the openings are located in the bottom part of the wall. In
other words, an opening exists between the bottom of the units and the wall separating
10 the units. As such, the barriers for the heavy fast settling sludge to circulate through the
system are eliminated as much as possible.
Steps (a) and (b): Anaerobic and aerobic wastewater treatment
[0019] The use of anaerobic and aerobic zones for the treatment of wastewater is
15 known in the art. Herein, a mixture of wastewater and sludge is first subjected to an
anaerobic zone and subsequently transferred to an aerobic zone. As wastewater
treatment typically occurs in tanks, the anaerobic zone may also be referred to as
anaerobic tank and the aerobic zone may also be referred to as the aerobic tank. The
sequence of an upstream anaerobic zone and a downstream aerobic zone is used to
20 convert organic matter present in the wastewater into sludge, which is accomplished by
microorganisms present in the sludge. The use of an anoxic tank in between the
anaerobic and the aerobic zones is not required, as the interior of the sludge granules
remains anaerobic or anoxic throughout the entire process. Also, recycles of
sludge/water mixtures from the aerobic zone to the anoxic zone and/or from the anoxic
25 zone to the anaerobic zone are not required, while purification of the wastewater
remams effective. Eliminating such recycles greatly improves the efficiency of the
process, as mixing of treated wastewater with wastewater that is yet to be treated is
avoided. As such, the concentration of organic nutrients beyond step (a) remains very
low.
30 [0020] The sludge that is used in step (a) to be contacted with the incoming wastewater
is fast settling sludge obtained as second portion in step (c). This second portion
contains sludge with excellent settling properties, which is selectively collected during
step (c) for use in step (a). In the process according to the invention, this fast settling
sludge is mainly granular, and by subjecting specifically this fast settling sludge to be
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subjected the anaerobic zone with the incoming wastewater, the growth of sludge
granules is selectively promoted. Fast settling sludge is contacted with the incoming
wastewater having the highest content of organic matter, which promotes the growth
thereof As such, the sludge that is present within the wastewater system is mainly or
5 even exclusively in granular form. Keeping the content of fast settling sludge as high as
possible is the main objective of the process according to the invention, as the presence
of fast settling sludge greatly facilitates the further steps of the process, in particular the
separation of step (d). To this end, the recycling of slow settling (non-granular) sludge
to step (a) should be avoided as much as possible. This is accomplished by sludge
10 selection step (c), as described hereinbelow. As such, the slow settling sludge is not
contacted with minute amounts of organic nutrients only, as those are mainly consumed
in step (a), and is thus the growth thereof is restrained as much as possible. Thus, the
growth of fast settling sludge is promoted in step (a), while the growth of slow settling
sludge is reduced as it is not subjected to an anaerobic zone. This effect is further
15 enhanced by the elimination of recycles, as discussed above, as the fast settling sludge
is exposed to the highest possible concentration of organic nutrients during step (a),
while the contact of slow settling sludge with organic matter is limited as much as
possible.
[0021] Wastewater, which is optionally pretreated, is first subjected in step (a) to the
20 anaerobic zone of the wastewater treatment process, wherein it is contacted with the
fast settling sludge that is selectively collected in step (c). Thus, within the anaerobic
zone a mixture of wastewater and fast settling sludge is obtained. In the anaerobic zone,
the presence of molecular oxygen is excluded, although traces of oxygen, such as
oxygen dissolved in the wastewater may be present without hampering the process. The
25 conditions during step (a) are referred to as "anaerobic" as no oxygen is added. Within
the anaerobic zone, the conditions and residence time of the wastewater are such that
the sludge granules are capable of taking up organic nutrients from the incoming
wastewater. These organic nutrients are typically stored within the microorganisms in
the form of polymers, such as poly-beta-hydroxybutyrate (PHB). Typical average
30 residence times for the mixture of sludge and water in the aerobic zone of step (a) are
15 min- 5 h, preferably 30 min- 2 h.
[0022] The mixture of wastewater and sludge obtained at the end of step (a) is then
transferred to the aerobic zone of step (b), to which molecular oxygen is supplied
(aeration), e.g. using aerators as known in the art. The water subjected to step (b) is
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depleted in organic nutrients, compared to the incoming wastewater. Preferably, no
anoxic zone is present in between the anaerobic and the aerobic zones and the aerobic
zone ofstep (b) directly follows the anaerobic zone of step (a). During step (b), at least
one additional sludge fraction is added to the mixture, i.e. the first portion of the sludge
5 originating from step (c). Optionally, at least part of the separated sludge originating
from step (d) is also added during step (b). These additional sludge fractions are
typically added at the beginning of step (b) as common in the art, such that the sludge
resides for a substantial period of time in the aerobic zone. Average residence times of
the mixture of sludge and water in the aerobic zone of step (b) may vary greatly,
10 depending on e.g. the extent and type of pollution in the incoming wastewater, and are
typically 30 min - 3 days, preferably 1 h - 2 days. During step (b), an oxygen
comprising gas, typically air, is introduced in the mixture of sludge and water. Under
such aerobic conditions, ammonium that may be present in the wastewater, is converted
into nitrate and/or nitrite (nitrification). As the interior of the sludge granules remains
15 anaerobic, the stored organic nutrients may be reacted with nitrate or nitrite to form
nitrogen gas (denitrification), which is expelled to the environment. Thus, due to the
presence of sludge in granular form, nitrification and denitrification may occur in the
same zone, eliminating the need of an anoxic zone as well as of recycles from the
aerobic zone to the anoxic zone and of the anoxic zone to the anaerobic zone. Aeration
20 of the aerobic zone is performed at such a rate that the concentration of dissolved
molecular oxygen in the wastewater during step (b) is preferably at least 0. 05 and more
preferably at least 0.1 mg/ml, while it is preferably not higher than 5 mg/ml, more
preferably not higher than 2 mg/ml. Using such an oxygen supply, both the nitrification
and denitrification processes occur effectively and nitrogen is effectively removed from
25 the wastewater.
[0023] The mixture of (waste)water and sludge resides in the anaerobic and aerobic
zones of steps (a) and (b) for a sufficient amount of time to allow effective uptake
and/or removal of organic nutrients, nitrogen and phosphorus from the incoming
wastewater. At the end of step (b), the mixture of sludge and water is divided over a
30 first part that is fed to sludge selection step (c) and a second part that is fed to
separation step (d). In order to operate the process smoothly in continuous mode, it is
preferred that the amount of the mixture that is fed to step (c) remains substantially
constant, while the amount that is led to step (c) varies with the volume of incoming
wastewater in step (a). As such, the sludge selection step is capable of operating
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completely independent of the inflow of wastewater, which is crucial for continuous
operation. Wastewater treatment plants typically have to cope with great variations in
inflow of wastewater. For example, during a period of heavy rainfall, the inflow of
wastewater may be greatly increased compared to during periods of relative drought.
5 Typically, the respective amounts of the first and second part is governed by the area of
the passages, through which the mixture flows from step (b) to step (c) or (d)
respectively. During operation, the respective amounts of the first and second part can
be influenced if desired, by adjusting the operation parameters of the sludge selector in
step (c), such as by adjusting the up flow in the up flow reactor.
10
Step (c): Sludge selection
[0024] In step (c), a first part of the sludge originating from step (b) is subjected to a
sludge selection step, wherein sludge is selected based on settling velocity, and a first
portion of slow settling sludge and a second portion of fast settling sludge are collected.
15 Herein, "selected" refers to the separation of two or more portions of sludge. The
average settling velocity of the second portion is greater than the settling velocity of the
first portion, preferably at least 2 times as high and more preferably at least 5, or even
at least 10 times as high. The first portion is returned to step (b) and the second portion
is returned to step (a). Such sludge selection may be performed by any means known in
20 the art to separate the solid particles in a suspension based on weight or settling
velocity. Suitable sludge selectors include upflow reactors and lamella clarifiers.
Conveniently, an upflow reactor is employed. Such means may be integrated within the
aerobic zone of step (b), or the first part of the sludge may be transferred to the up flow
reactor. Herein, the average settling velocity of the fast settling sludge is typically at
25 least two times as high as the average settling velocity of the slow settling sludge,
preferably at least five times as high or even at least ten times as high. The average
settling velocity of the fast settling sludge is typically above 1 m/h, preferably above 5
mlh, most preferably above 10 mlh, while the average settling velocity of the slow
settling sludge is typically at most 1 m/h, or even less than 0.5 mlh. Settling velocities
30 above 5 m/h or even above 10 mlh are indicative of granular sludge, while sludge floes
typically settle at an average speed of at most 1 m/h. Even though there is no practical
limit to the average settling velocity of the fast settling sludge, it typically is not higher
than 25 m/h. In a preferred embodiment, the settling velocity is varied in the process
within the range of 1 - 25 m/h. This way the built-up of sludge blankets can be
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reduced. In one embodiment, the settling velocity is varied within the above range as a
cyclic event. In case an up flow reactor is used in step (c), the average settling velocity
of the fast settling sludge is preferably defined as greater than the speed of the up flow
at which the upflow reactor operates, while the average settling velocity of the slow
5 settling sludge is then defined as being smaller than the speed of the up flow.
[0025] At the end of step (b), a suspension of sludge in water is present within the
system. Conveniently, the stream of the sludge/water mixture is divided into two parts,
one of which (i.e. the first part) is subjected to step (c) and one (i.e. the second part) to
step (d). Although it is essential that part of the sludge is subjected to step (c), the
10 sludge is conveniently subjected to step (c) as a mixture of sludge and water, as it is
present at the end of step (b). At the end of the aerobic zone of step (b), typically a
passage to the up flow reactor of step (c) is provided, such that the first part of the
sludge can flow unhindered to the upflow reactor. It is not required for proper operation
of the process according to the invention that all the sludge present at the end of step
15 (b) is subjected to sludge selection step (c). As such, the capacity of the sludge selector
employed in step (c) can be reduced, but at the same time a significant portion of fast
settling sludge is collected and returned to step (a), such that granular sludge is
effectively formed and maintained in the system.
[0026] Importantly, step (c) is performed independently from the inflow ofwastewater,
20 which may vary greatly over time. Conveniently, the absolute amount of the first part
of the sludge originating from step (b), which is subjected to step (c), is kept
substantially constant over time. In other words, step (c) is preferably operated with a
substantially constant feed rate of the first part of the mixture of step (b). The
concentrated stream of sludge of the second portion that is obtained in step (c) and
25 returned to step (a) is constant and independent from the flow of incoming wastewater.
As such, the present process is perfectly capable of coping with large variations in
incoming wastewater flows typical for wastewater treatment plants and at the same
time continues to operate smoothly while forming and/or maintaining granular sludge.
The relative amount of the first part of sludge, which is subjected to step (c), may thus
30 vary greatly, depending on the inflow of wastewater during step (a). As appreciated by
the skilled person, the ratio of sludge to waste, that is present in the incoming
wastewater in step (a), should be kept more or less constant, and may depend on the
size of the wastewater treatment plant.
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[0027] By recycling of the fast settling sludge to step (a), this sludge is in contact with
the highest amount of organic matter, i.e. as contained in the incoming wastewater,
which specifically promotes the growth of the fast settling sludge. As such, sludge
granules are formed and subsequently maintained in the system by cycling from step
5 (a), via step (b) to step (c) and subsequently back to step (a). The organic matter present
in the incoming wastewater is converted into granular sludge during step (a), while
slower settling sludge, such as sludge floes, is only subjected to step (b), and thus the
growth thereof is not promoted. Growth promotion of specifically the fast settling
sludge is a marked improvement over prior art wastewater treatment processes. The
10 inventors surprisingly found that selectively promoting the growth of the fast settling
sludge ensures granular sludge is formed and maintained in the system. Herein, it is
essential that the second portion containing fast settling sludge is contacted with the
incoming wastewater prior to being contacted with oxygen, such as in the aerobic zone
of step (b). The fast settling sludge is, together with the incoming wastewater, subjected
15 to the anaerobic zone of step (a). To effectuate this contacting of fast settling sludge
and wastewater in step (a), the second portion may be returned to the anaerobic zone
itself or to a selector located upstream of the anaerobic zone. Such selectors for mixing
incoming wastewater and active sludge are known in the art. Within the selector,
anaerobic conditions are present. Preferably, the second portion is returned directly to
20 the anaerobic zone of step (a).
[0028] The second part of the sludge originating from step (b) is subjected to step (d),
as described hereinbelow. Preferably, the first part of the sludge, which is subjected to
step (c) and the second part of the sludge, which is subjected to step (d), together make
up substantially all of the total amount of sludge present at the end of step (b). Thus, all
25 of the sludge present at the end of step (b) is subjected to step (c) or to step (d). In other
words, it is preferred that the stream of sludge and water is split in two parts at the end
of step (b), a first part that is subjected to step (c) and a second part that is subjected to
step (d). The total amount of sludge that is present at the end of step (b) is formed by
the sludge that originated from step (a) and the sludge that is formed during step (b), as
30 well as the additional sludge fraction that originates as a first portion from step (c) and
that is added during step (b) and optionally the additional sludge fraction that originates
from step (d) and that is added during step (b).
[0029] Sludge selection step (c) involves the collection of at least two portions,
preferably three portions, of the sludge that is subjected to step (c). The first portion
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contains slow settling sludge and the second portion contains fast settling sludge.
Herein, "slow settling" and "fast settling" refers to the average settling velocity of the
sludge in one portion compared to the other portion. Thus, the average settling velocity
of the second portion is greater than the settling velocity of the first portion. The first
5 portion is returned to step (b) and the second portion is returned to step (a), typically
using a pump employing an upward stream of air or liquid, such as an airlift pump, or a
screw pump. Using such a pump, the mechanical stress is eliminated as much as
possible which enables fast circulation of the fast settling sludge through the system
and prevents damage of the sludge granules. Typically, the faster the fast settling
10 sludge is capable of circulating through the system the more granular sludge is formed
and maintained in the system. Typically, the second portion containing the fast settling
sludge is obtained in concentrated form, which reduces the total volume that is
contacted with the wastewater in step (a) is relatively small, such that the total volume
of the anaerobic zone may be significantly reduced, e.g. up to 40% smaller in volume,
15 compared to conventional continuous wastewater treatment facilities. Moreover, in
view of the independence of step (c) from the inflow of wastewater, the present process
enables a continuous flow of high quality sludge to be contacted with the wastewater in
step (a). For the most optimal formation of granular sludge, it is preferred that
substantially all of the fast settling sludge collected as the second portion in step (c) is
20 returned to step (a). As such, the granular sludge is allowed to grow optimally. As
described above, step (c) can operate independently of the wastewater inflow. Thus, the
sludge cycle of consecutive steps (b) -7 (c) -7 (a) is operable independent of
wastewater inflow, which allows for continuous operation of the sludge selection step
and ensures optimal growth of specifically fast settling sludge.
25 [0030] Optionally, a third portion is collected during step (c), which is a waste sludge
stream. The waste sludge stream of the third portion contains slow settling sludge, like
the first portion. Whether or not and to what extent a third portion is collected mainly
depends on the sludge concentration within the system. As such, the sludge
concentration is suitable kept more or less constant and when necessary additional
30 sludge is easily discharged from the system as the third portion. Preferably,
substantially all of the sludge that is subjected to step (c) ends up in the first, second or
optional third portion. The third portion is waste sludge, which is a by-product of the
wastewater treatment according to the invention and is thus discharged from the
system. It may be used or processed as deemed fit. Typically, it is subjected to a sludge
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treatment step as known in the art. The first portion may be combined with settled
sludge originating from step (d), such that a combined sludge fraction containing the
third portion originating from step (c) and settled sludge originating from step (d),
optionally from which sludge that is recycled to step (b) is removed as described below,
5 may be subjected to sludge treatment. Conveniently, the third portion is collected as a
separate portion and is discharged from the sludge separator via a separate outlet
equipped with an additional pump. In one embodiment, the third portion may be used
in inocculate or start up other wastewater treatment processes.
[0031] In a preferred embodiment, an upflow reactor is used for the sludge selection of
10 step (c). Up flow reactors are known in the art and any type may be used in step (c). In
the upflow reactor, the sludge particles are separated based on the speed of settling.
Sludge particles that settle quickly accumulate at the bottom of the upflow reactor.
Since granular sludge has excellent settling properties, it accumulates at the bottom of
the upflow reactor, and from there recycled to step (a) ofthe process according to the
15 invention. Any sludge with weak settling properties, which is advantageously not
contained in the process in large quantities, and which at least should not be recycled to
step (a) of the present process, is collected from higher in the upflow reactor. The
upflow reactor preferably operates with an upflow speed of 1 - 25 m/h, more preferably
2- 15 m/h, most preferably 3 - 8 m/h. Typically, a pump as known in the art, e.g. an
20 axial-flow pump, placed near the top ofthe upflow reactor, is used to effectuate such
upflow. The first portion is collected from the top half of the upflow reactor and a
second portion of the sludge is collected from the bottom of the up flow reactor. In other
words, the outlet for discharging the first portion from the upflow reactor is located at
50 % of the total height of the reactor or above and "from the top half' is synonymous
25 with "from the upper 50%". Thus, the first portion is collected at 50- 100% ofthe
total height of the up flow reactor, preferably at 75 - 100 % of the total height, most
preferably at the top of the reactor. The optional third portion is also collected at the top
half of the upflow reactor. The outlet for discharging the first and optionally third
portion may also take the form of an overflow at the top of the upflow reactor.
30 Likewise, the outlet for discharging the second portion from the upflow reactor is
located at 25 % of the total height of the reactor or below and "from the bottom" is
synonymous with "from the lower 25 %", preferably the second portion is collected
from the lower 10 % of the up flow reactor, most preferably the outlet for collecting the
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second portion is located in the bottom of the upflow reactor. Using an upflow reactor,
the second portion of sludge is collected as a concentrated stream of sludge in water.
Step (d): Separation
5 [0032] In step (d), the second part of the mixture of sludge and water originating from
step (b) is separated into sludge and treated water. Typically, the second part is the
remainder of the mixture that is present at the end of step (b) after the first part has
been transferred to the sludge selector. Separation is typically based on settling of the
sludge particles and is preferably performing using a settling tank or an up flow reactor.
10 Step (d) may thus also be referred to as a settling step. The water that is subjected to the
process according to the invention and that is discharged from the separator is referred
to as "treated water". In view of the presence of granular sludge within the wastewater
treatment system, the capacity of the up flow reactor or the settling tank may be downscaled
significantly, compared to wastewater treatment plants wherein sludge floes are
15 used. Separating sludge from water is known in the art.
[0033] In settling step (d), the sludge in the second part of the mixture of sludge and
water originating from step (b) is allowed to settle. Such a settling step, during which
the sludge is separated from the treated water, is common for conventional wastewater
treatment plants. However, because of the presence of granular sludge, instead of
20 sludge floes, the settling tanks wherein step (d) is performed may be much smaller (for
example about one fifth in area for the same wastewater input) compared to the
conventional settling tanks needed for settling sludge floes. The incoming mixture of
water and sludge originating from step (b) resides for a sufficient amount of time in the
settling tank or upflow reactor to allow settlement of the sludge. Once the sludge is
25 essentially settled, the water is clarified from sludge and may be considered clean and
discharged to the environment, although for some applications and/or locations,
additional further treatment such as removal of metals may be desired. Whether or not
further treatment takes place is irrelevant for the present invention.
[0034] Typically, the settling of step (d) occurs in a settling tank. Any type of settling
30 tank known in the art may be used in the present process. Settling tanks typically have a
conical shape with a wide upper part and a narrow bottom. Sludge particles accumulate
at the bottom, from which it is collected, preferably using an outlet located in the
bottom of the settling tank. Treated water is typically discharged via an outlet at the top
of the settling take, preferably using an overflow.
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[0035] In case an up flow reactor is used in step (d), the settling of the sludge is
accelerated using an up flow. Herein, the second part of the mixture of sludge and water
originating from step (b) is subjected to an upflow reactor, wherein the sludge particles
settle at the bottom while the water depleted in sludge emerges at the top of the up flow
5 reactor. This water is discharged as treated water. The upflow reactor preferably
operates with an upflow speed of0.5- 10 m/h, more preferably 1-5m/h. Such upflow
speeds are 2 to 10 times greater as upflow speeds commonly employed in prior art
settling steps, which further improves the efficiency of the present process. Such
upflow speeds can be employed in the present process, as the great majority of the
10 sludge is granular and settles quickly. Using a settling tank or an upflow reactor
operated with such an upflow, all sludge- granular or not- is allowed to settle, such
that the treated water is clarified from all sludge before it is discharged from the
system. Typical residence times of the mixture of sludge and water in the upflow
reactor are 5 min - 2 h, preferably 15 min - 1 h. Such residence times are much shorter
15 than for prior art processes, wherein residence times over 2 h, typically 4 - 10 h, are
common. In view of the granular nature of the sludge, such short residence times still
allow for effective separation of sludge and treated water.
[0036] The sludge that is separated is preferably at least partly returned to the aerobic
zone of step (b). The remainder is a by-product of the wastewater treatment according
20 to the invention and is thus discharged from the system. It may be used or processed as
deemed fit. Advantageously the discharged sludge may be used to start up or improve
settling in other or conventional or granule-based wastewater treatment. Typically,
discharged sludge is subjected to a sludge treatment step as known in the art. As the
sludge obtained by the process according to the invention contain valuable components,
25 these may be extracted from the sludge. The skilled person knows how to determine the
amount of sludge that should be returned to step (b) in order to run the process
effectively.
[0037] The treated water that is discharged from the separator in step (d) is the major
product of the process according to the invention. The treated water is depleted in
30 organic matter (organic nutrients) compared to the incoming wastewater. The treated
water discharged from step (d) may be discharged to the environment, further purified
or used as deemed fit.
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SYSTEM
[0038] The invention further concerns an apparatus or system specifically designed to
implement the process according to the invention. In the system according to the
invention, at least four, preferably at least five or even six, units are in fluid connection
5 with each other. Herein, each unit may be a separate entity or two or more units may be
integrated within a single unit. Preferably, units (b) and (c) are integrated in a single
unit and the remaining units are separate units, which are distinguishable as such in the
system. The system for performing the process according to the invention may also be
referred to as a wastewater treatment plant or sewage treatment plant or may be
10 integrated within a wastewater treatment plant or sewage treatment plant. The system
according to the invention is described with reference to the accompanying figure.
[0039] The system according to the invention comprises:
(a) an anaerobic tank, comprising one or more inlets for receiving wastewater and for
receiving fast settling sludge originating from outlet (c3) and an outlet (a3) for
15 discharging a mixture ofwastewater and sludge to tank (b);
(b) an aerobic tank, comprising an inlet (b1) for receiving the mixture ofwastewater
and sludge originating from outlet (a3), an outlet (b2) for discharging a first part of
a mixture of water and sludge to sludge selector (c), an outlet (b3) for discharging
a second part of the mixture of water and sludge to separator (d) and an inlet (b4)
20 for receiving a mixture of slow settling sludge originating from outlet ( c2);
(c) a sludge selector, comprising an inlet (c1) for receiving the first part of the mixture
of water and sludge originating from outlet (b2), an outlet ( c2) for discharging a
first portion of slow settling sludge to tank (b) and an outlet (c3) for discharging a
second portion of fast settling sludge to tank (a) and means (c4) for selecting
25 sludge based on settling velocity; and
(d) a separator for separating sludge from a mixture of sludge and water, comprising
an inlet ( d1) for receiving the second part of the mixture originating from outlet
(b3), a first outlet (d2) for discharging treated water and a second outlet (d3) for
discharging separated sludge,
30 [0040] In the system according to the invention, the different units are interconnected,
i.e. the outlet of one unit is in fluid connection with the inlet of another unit. As such,
constant flow of fluids, such as sludge/water mixtures, through the system is enabled.
Thus, outlet (a3) is in fluid connection with inlet (b1), outlet (b2) is in fluid connection
with inlet (c1), outlet (b3) is in fluid connection with inlet (d1), outlet (c2) is in fluid
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connection with inlet (b4), and outlet (c3) is in fluid connection with an inlet of unit (a),
preferably with inlet (a2). Outlet (d3) is preferably in fluid connection with inlet (b5),
as described hereinbelow. Herein, fluid connections may for example take the form a
conduit, or the outlet of one unit and the inlet of another unit together form an opening
5 in the wall separating the two units. Preferably, outlet (a3) and inlet (b1) together form
an opening in the wall separating units (a) and (b). Preferably, outlet (b2) and inlet ( c 1)
together form an opening in the wall separating units (b) and (c). Preferably, outlet (b3)
and inlet (d1) together form an opening in the wall separating units (b) and (d). For
efficient circulation of granular sludge throughout the system, it is preferred that the
10 openings are located in the bottom part of the wall. In other words, an opening exists
between the bottom of the units and the wall separating the units. As such, the barriers
for the fast settling sludge to circulate through the system are as much as possible
eliminated.
[0041] Unit (a) is an anaerobic tank or vessel as known in the art, wherein wastewater
15 and sludge are contacted. Unit (a) comprises one or more inlets for receiving
wastewater and for receiving sludge from outlet (c3) of unit (c). The one or more inlets
may for example be two inlets, one for receiving the incoming wastewater and one for
receiving the sludge, or one inlet for receiving a mixture of the incoming wastewater
and the sludge. In one embodiment, the incoming wastewater, which may originate
20 from a pretreatment facility, and the sludge originating from outlet (c3) of unit (c) are
mixed upstream of unit (a), typically in a selector, and unit (a) comprises one inlet for
receiving the mixture of wastewater and sludge from the selector. In another, more
preferred, embodiment, unit (a) comprises an inlet (a1) for receiving wastewater, which
may originate from a pretreatment facility, and an inlet ( a2) for receiving sludge from
25 outlet (c3) of unit (c). In unit (a), wastewater and granular sludge are contacted to
effectuate uptake of organic nutrients present in the wastewater into the sludge
particles, thus enabling sludge growth. Outlet (a3) of unit (a) is for discharging the
mixture of wastewater and granular sludge to unit (b). Outlet ( a3) together with inlet
(b1) typically take the form of an opening in the wall, preferably in the bottom part
30 thereof, separating tanks (a) and (b).
[0042] Unit (b) is an aerobic tank or vessel as known in the art, wherein the mixture of
wastewater and granular sludge originating from unit (a) is received via inlet (b1).
Outlet (a3) is in fluid connection with inlet (b1), preferably in the form of an opening in
the bottom of the wall separating both units. Unit (b) further comprises an outlet (b2)
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for discharging a first part of a water/sludge mixture to an up flow reactor (c) and an
outlet (b3) for discharging a second part of the water/sludge mixture to unit (d),
wherein the second part is typically the remainder of the water/sludge mixture. Outlet
(b2) together with inlet (c1) typically take the form of an opening in the wall,
5 preferably in the bottom part thereof, separating tank (b) and up flow reactor (c). Outlet
(b3) together with inlet ( d1) typically take the form of an opening in the wall,
preferably in the bottom part thereof, separating tank (b) and separator (d). Unit (b)
further comprises an inlet (b4) for receiving the third portion of the sludge originating
from outlet ( c2) of unit (c), and preferably a further inlet (b5) for receiving at least part
10 of the separated sludge originating from unit (d). In unit (b), wastewater and granular
sludge are (further) contacted to effectuate nitrification and denitrification. Being an
aerobic tank, unit (b) further comprises means as known in the art for introducing
oxygen, typically air, into the tank.
[0043] Unit (c) is a sludge selector, such as a lamella clarifiers or an up flow reactor.
15 Unit (c) be integrated in unit (b) or may be located downstream thereof, preferably it is
integrated in the aerobic tank of unit (b). Unit (c) comprises an inlet (c1) for receiving
the first part of the water/sludge mixture from unit (b). Unit (c) further contains means
(c4) for selecting sludge based on settling velocity, wherein the first part of the
water/sludge mixture is subjected to sludge selection. Unit (c) contains at least two
20 outlets, a first outlet ( c2) for discharging a first portion of the sludge from the system
and a second outlet (c3) for discharging a second portion of the sludge. Outlet (c2) is in
fluid connection with inlet (b4). Outlet (c3) is in fluid connection with inlet (a2). The
connection between outlet (c3) and inlet (a2) is preferably equipped with a pump,
which is capable of pumping the second portion of sludge to the anaerobic tank of unit
25 (a). Preferably, a pump employing an upward stream of air or liquid, such as an airlift
pump, or a screw pump is used, such that mechanical stress of the fast settling sludge is
as much as possible eliminated. Unit (c) preferably comprises a third outlet ( c5) for
discharging a third portion of the sludge. Outlet ( c5) is for discharging waste sludge
from the system according to the invention, and may be in fluid connection with a
30 sludge treatment facility. The fluid connection originating from outlet ( c5) may be
joined with the fluid connection from outlet ( d3 ), wherein the streams originating from
both outlets are combined in a single stream which may be in fluid connection with a
sludge treatment facility.
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[0044] In a preferred embodiment, unit (c) is an up flow reactor. In the up flow reactor,
inlet (c1) is preferably located in or near the bottom of reactor (c), more preferably in
the lower 25 % of the total height of the reactor. In one embodiment, the upflow
reactor (c) may comprise a pump, typically an axial-flow pump, located near the top,
5 such as at 75% of the total height of the reactor or above, preferably at at least 90% of
the total height of the reactor. If such a pump is used, it is preferably capable of
operating the upflow reactor with an upflow speed of 1 - 25 m/h, more preferably 2 -
15 m/h, most preferably 3-8m/h. In any case it is preferred that upflow speed can be
varied within the above ranges, preferably to avoid sludge blankets. Outlet ( c2) is
10 located in the top half of the up flow reactor and outlet ( c3) in the lower 25 % of the
reactor. Thus, outlet ( c2) for discharging a first portion of the sludge to unit (b) is
located at 50% of the total height of the reactor or above, preferably at 75 - 100% of
the total height, most preferably at the top of the reactor. Outlet (c3) for discharging a
second portion of the sludge to unit (a) is located at 25 % of the total height of the
15 reactor or below, preferably at 0 - 10 % of the total height, most preferably in the
bottom of the reactor. Outlet ( c5) for discharging a third portion of the sludge is, when
present, located in the top half of the upflow reactor, preferably at 75 - 100% of the
total height, most preferably at the top of the reactor. Outlet ( c4) may be equipped with
an additional pump or may take the form of an overflow.
20 [0045] Unit (d) is a separator for separating sludge from treated water. The separator is
preferably a settling tank or an upflow reactor, more preferably an upflow reactor. Any
settling tank or any upflow reactor as known in the art may be used. Typical settling
tanks have a conical shape with a narrow bottom and a wide top. When an upflow
reactor is used, it is preferably capable of operating with an upflow speed of 0.5 - 10
25 m/h, more preferably 1 - 5 m/h. Unit (d) comprises an inlet ( d1) for receiving the
second part of the water/sludge mixture from unit (b). Inlet ( d1) is typically located
near the bottom of the separator. Outlet (b3) is in fluid connection with inlet (d1). Unit
(d) further comprises a first outlet ( d2) for discharging treated water, which is typically
an overflow, and a second outlet (d3) for discharging settled sludge. The second outlet
30 (d3) is typically located near the bottom or even in the bottom of the separator, and is
preferably in fluid connection with inlet (b5) of unit (b). As such, at least part of the
settled sludge is conveniently returned to the aerobic tank of unit (b). The fluid
connection originating from outlet (d3) may comprise means to discharge part ofthe
settled sludge from the system as waste sludge, which may be combined with the fluid
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connection originating from outlet ( c5) and which may be in fluid connection with a
sludge treatment facility.
[0046] In a preferred embodiment, the system according to the invention comprises:
(a) an anaerobic tank, comprising an inlet (a1) for receiving wastewater, an inlet (a2)
5 for receiving fast settling sludge from outlet (c3) of unit (c) and an outlet (a3) for
discharging a mixture of wastewater and sludge;
(b) an aerobic tank, comprising an inlet (b1) for receiving the mixture ofwastewater
and sludge originating from outlet (a3), an outlet (b2) for discharging a first part of
a mixture of water and sludge to sludge selector (c), an outlet (b3) for discharging
10 a second part of the mixture of water and sludge to separator (d), an inlet (b4) for
receiving a mixture of water and sludge from outlet ( c2) and an inlet (b5) for
receiving sludge from outlet (d3);
(c) an up flow reactor capable of operating with an up flow speed of 1 - 25 m/h,
comprising an inlet (c1) for receiving the first part of the mixture of water and
15 sludge originating from outlet (b2), an outlet (c2), located in the top half of the
up flow reactor, for discharging a first portion of slow settling sludge to tank (b), an
outlet ( c3), located in or near the bottom of the up flow reactor for discharging a
second portion of fast settling sludge to tank (a) and an outlet (c5), located in the
top half of the upflow reactor, for discharging a third portion of slow settling
20 sludge to tank (b); and
(d) an up flow reactor for separating sludge from treated water, capable of operating
with an upflow speed of 0.5 - 10 m/h, comprising an inlet (d1) for receiving the
second part of the mixture of water and sludge from outlet (b3), a first outlet ( d2)
for discharging treated water and a second outlet ( d3) for discharging separated
25 sludge,
wherein outlet (a3) is in fluid connection with inlet (b1), outlet (b2) is in fluid
connection with inlet (c1), outlet (b3) is in fluid connection with inlet (d1), outlet (c2)
is in fluid connection with inlet (b4), outlet (c3) is in fluid connection with inlet (a2)
and outlet (d3) is in fluid connection with inlet (b5).
Claims
1. A process for the treatment of wastewater, comprising:
(a) contacting the wastewater with fast settling sludge originating from step (c)
in an anaerobic zone, to obtain a mixture of wastewater and sludge;
5 (b) subjecting the mixture originating from step (a) and slow settling sludge
10
originating from step (c) to an aerobic zone to obtain a mixture ofwater and
sludge;
(c) subjecting a first part of the mixture originating from step (b) to a sludge
selection step, wherein sludge is selected based on settling velocity and a
first portion containing slow settling sludge and a second portion containing
fast settling sludge are collected, wherein the average settling velocity of the
fast settling sludge is greater than the settling velocity of the slow settling
sludge, and wherein the first portion is returned to step (b) and the second
portion is returned to step (a); and
15 (d) separating sludge from a second part of the mixture originating from step (b),
to obtain treated wastewater.
2. Process according to embodiment 1, wherein the sludge selection of step (c) is
performed in an upflow reactor, which is preferably operated with an upflow in the
range of 1 - 25 m/h.
20 3. Process according to embodiment 1 or 2, wherein step (c) operates with a
substantially constant feed rate of the first part of the mixture of step (b).
4. Process according to any of the preceding embodiments, which is operated
continuously.
5. Process according to any of the preceding embodiments, wherein in step (c) a third
25 portion containing slow settling sludge is collected, which is discharged as waste
sludge.
6. Process according to any of the preceding embodiments, wherein the mixture
transfers barrier-free from step (a) to (b), from step (b) to (c) and from step (b) to
(d).
30 7. Process according to any of the preceding embodiments, wherein at least part of
the sludge originating from step (d) is returned to step (b).
8. Process according to any of the preceding embodiments, wherein the third portion
of the sludge originating from step (c) and/or at least part of sludge originating
from step (d) are subjected to sludge treatment.
wo 2017/025345 27 PCT /EP2016/068055
9. System for carrying out the process according to any one of embodiments 1 - 8,
compnsmg:
(a) an anaerobic tank, comprising one or more inlets for receiving wastewater
and for receiving fast settling sludge originating from outlet (c3) and an
5 outlet (a3) for discharging a mixture ofwastewater and sludge to tank (b);
10
15
20
(b) an aerobic tank, comprising an inlet (b1) for receiving the mixture of
wastewater and sludge originating from outlet (a3), an outlet (b2) for
discharging a first part of a mixture of water and sludge to sludge selector
(c), an outlet (b3) for discharging a second part of the mixture of water and
sludge to separator (d) and an inlet (b4) for receiving a mixture of slow
settling sludge originating from outlet ( c2);
(c) a sludge selector, comprising an inlet (c1) for receiving the first part ofthe
mixture of water and sludge originating from outlet (b2), an outlet ( c2) for
discharging a first portion of slow settling sludge to tank (b) and an outlet
(c3) for discharging a second portion of fast settling sludge to tank (a) and
means (c4) for selecting sludge based on settling velocity; and
(d) a separator for separating sludge from a mixture of sludge and water,
comprising an inlet ( d1) for receiving the second part of the mixture
originating from outlet (b3), a first outlet (d2) for discharging treated water
and a second outlet (d3) for discharging separated sludge,
wherein outlet (a3) is in fluid connection with inlet (b1), outlet (b2) is in fluid
connection with inlet (c1), outlet (b3) is in fluid connection with inlet (d1), outlet
(c2) is in fluid connection with inlet (b4) and outlet (c3) is in fluid connection with
an inlet of unit (a).
25 10. System according to embodiment 9, wherein unit (a) comprises two inlets, a first
inlet (a1) for receiving wastewater and a second inlet (a2) for receiving fast settling
sludge originating from outlet (c3), and wherein outlet (c3) is in fluid connection
with inlet ( a2).
11. System according to embodiment 9 or 10, wherein sludge selector (c) is integrated
30 in aerobic tank (b).
12. System according to any one of embodiments 9- 11, wherein sludge selector (c) is
an up flow reactor capable of operating with an up flow speed of 1 - 25 m/h.
wo 2017/025345 28 PCT /EP2016/068055
13. System according to any one of embodiments 9- 12, wherein the fluid connection
between outlet (c3) and inlet (a2) is equipped with a pump employing an upward
stream of air or liquid or a screw pump.
14. System according to any one of embodiments 9 - 13, wherein separator (d) is an
5 upflow reactor capable of operating with an upflow speed of0.5- 10m/h.
10
15. System according to any one of embodiments 9- 14, wherein outlet (a3) together
with inlet (b 1) take the form of an opening in the bottom part of a wall separating
tanks (a) and (b).
| # | Name | Date |
|---|---|---|
| 1 | 201817004946-STATEMENT OF UNDERTAKING (FORM 3) [09-02-2018(online)].pdf | 2018-02-09 |
| 2 | 201817004946-FORM 1 [09-02-2018(online)].pdf | 2018-02-09 |
| 3 | 201817004946-DRAWINGS [09-02-2018(online)].pdf | 2018-02-09 |
| 4 | 201817004946-DECLARATION OF INVENTORSHIP (FORM 5) [09-02-2018(online)].pdf | 2018-02-09 |
| 5 | 201817004946-COMPLETE SPECIFICATION [09-02-2018(online)].pdf | 2018-02-09 |
| 6 | abstract.jpg | 2018-03-05 |
| 7 | 201817004946.pdf | 2018-03-24 |
| 8 | 201817004946-Proof of Right (MANDATORY) [04-05-2018(online)].pdf | 2018-05-04 |
| 9 | 201817004946-FORM-26 [04-05-2018(online)].pdf | 2018-05-04 |
| 10 | 201817004946-Power of Attorney-090518.pdf | 2018-05-15 |
| 11 | 201817004946-OTHERS-090518.pdf | 2018-05-15 |
| 12 | 201817004946-Correspondence-090518.pdf | 2018-05-15 |
| 13 | 201817004946-FORM 3 [27-08-2018(online)].pdf | 2018-08-27 |
| 14 | Correspondence-251018.pdf | 2018-10-27 |
| 15 | 201817004946-FORM-26 [16-11-2018(online)].pdf | 2018-11-16 |
| 16 | 201817004946-Power of Attorney-191118.pdf | 2018-11-27 |
| 17 | 201817004946-Correspondence-191118.pdf | 2018-11-27 |
| 18 | 201817004946-FORM 18 [02-08-2019(online)].pdf | 2019-08-02 |
| 19 | 201817004946-PETITION UNDER RULE 137 [26-11-2020(online)].pdf | 2020-11-26 |
| 20 | 201817004946-OTHERS [26-11-2020(online)].pdf | 2020-11-26 |
| 21 | 201817004946-FER_SER_REPLY [26-11-2020(online)].pdf | 2020-11-26 |
| 22 | 201817004946-DRAWING [26-11-2020(online)].pdf | 2020-11-26 |
| 23 | 201817004946-CLAIMS [26-11-2020(online)].pdf | 2020-11-26 |
| 24 | 201817004946-ABSTRACT [26-11-2020(online)].pdf | 2020-11-26 |
| 25 | 201817004946-PatentCertificate09-02-2021.pdf | 2021-02-09 |
| 26 | 201817004946-IntimationOfGrant09-02-2021.pdf | 2021-02-09 |
| 27 | 201817004946-FER.pdf | 2021-10-18 |
| 1 | searchE_24-04-2020.pdf |