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Drawing Quality Al Killed Rephosphorised Steel Sheets Having Tensile Strength Of 340 440 Mpa

Abstract: The invented product is a steel grade for automotive stamping applications. It is a low carbon based steel composition, strengthened by suitable additions of phosphorus and manganese. The processing schedules, including steel making, hot rolling, cold rolling and annealing, have been determined appropriately so as to achieve desired drawability and strength. The material is also adequately weldable. 8 Chemical composition C% Mn%    S% P% Si%     Al%    N (ppm) 0.04-0.06   0.3-15   0.01   0.05-0.09   0.01   0.04-0.05   35-50 max max Physical processing a) hot charging of slabs to reheat furnace b) slab drop out @ around-1200°C c) finish rolling @ higher than Ar3 temperature - 900 - 910°C d) coiling @ 550 - 560°C e) cold rolling @ 66 - 74% f) batch annealing @ hot spot temperature-700°C - 720°C and cold spot temperature 620 - 640° (table suitably adjusted) g) skin pass rolling @ 1.0% temper elongation 9 Test results (two results are given below for each grade of Al-killed rephos family): SteelGrades Width(mm) Thickness(mm) YS(MPa) UTS (MPa) %EI r-bar Al-killed 1370 0.8 194 346 41 1.75 Rephos 1370 0.8 218 364 39 1.8 340 Desirable properties 155-255 340 min 37 min 1.4 min Al-killed 1220 0.9 268 412 39 1.72 Rephos 1220 1.0 41 257 405 1.68 390 Desirable properties 195-295 390 min 33 min 1.46 min Al-killed 1150 1.8 293 444 36 1.46 Rephos 1150 1.4 310 446 37 1.46 440 Desirable Properties 225-335 440 min 32 min 1.3 min Secondary work embrittlement property: OK upto - 30°C (tested for rephos - 340 and rephos - 390, rephos - 440 was not tested, but expected to show same property due to same phosphorus content as in rephos - 390)

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Notices, Deadlines & Correspondence

Patent Information

Application #
Filing Date
29 June 2007
Publication Number
15/2009
Publication Type
INA
Invention Field
CHEMICAL
Status
Email
Parent Application
Patent Number
Legal Status
Grant Date
2013-02-26
Renewal Date

Applicants

TATA STEEL LIMITED
JAMSHEDPUR

Inventors

1. NOT AVAILABLE
NOT AVAILABLE

Specification

FIELD OF THE INVENTION
The present invention relates to the development of an Al-killed rephosphorised
high strength sheet steel. More particularly the invention relates to a
development of drawing quality Al-killed rephosphorised steel sheets having
Tensile Strength of 340-440 MPa UTS formable and weldable steel sheet,
adaptable to mainly for manufacturing automotive body panels.
BACKGROUND OF THE PRESENT INVENTION
The modern automobile industry is driven by some important factors, such as
(a) Energy saving, or less fuel consumption
(b) Less emission
(c) Improved passenger safety
(d) Low cost manufacturing, etc.

In order to satisfy all these basic conditions, the modern car
manufacturing involves more high strength steel grades, which
should also be combined with certain degree of formability.
The formable high strength steels are usually expensive (high
strength interstitial free steel), and the manufacturing steps requires
special facility like continuous annealing.
The present invention gives a solution to this problem. Chemical
composition and processing route are such that the manufacturing of
this steel grade is less expensive. Moreover, this grade is exclusively
suitable for batch annealing process. Therefore, continuous
annealing facility is not required.
PRIOR ART
Al-killed drawing quality or extra deep drawing quality steels are
known to be excellent materials for automotive stamping
applications. Though the drawability is inferior to that of interstitial

free steels, they find substantial application due to their formability,
combined with the cost advantage. The rephosphorised versions of
this family of steels offer a vital alternative to high strength interstitial
free steels of strength levels, between 340 to 440 MPa UTS. More
importantly, the drawability values of rephosphorised Al-killed grades
are comparable with those of IFHS grades, while IFHS is a non-aging
grade.
This grade has never been manufactured anywhere else in India
before.
Drawbacks connected with hither to known processes and
advantage of the present invention
The worldwide trend is to process high strength formable steel
grades through continuous annealing line, which is the best route for
producing interstitial free high strength steels. In India, there is no
continuous annealing line for processing uncoated steel sheet.

Therefore, the steel manufacturers are compelled to produce high
strength formable grades through batch annealing only.
Manufacturing of interstitial free based high strength steels through
batch annealing is extremely difficult due to the complex metallurgy
of those grades. Therefore, Al-killed rephosphorised grades, though
slightly inferior in forming property, offer great advantage in terms of
easy processing and expenditure.
The main advantages are:
a) Can be produced through batch annealing route
b) Combination of strength and substantial formability
c) An economic option for automotive industry

OBJECTS OF TH INVENTION
It is therefore an object of the present invention to propose an
improved grade of steel sheet having 340 to 440 MPa UTS, formable
and weldable quality adaptable to manufacture of automotive body
panels which eliminates the disadvantages of prior art.
Another object of the present invention is to propose an improved
grade of steel sheet having 340 to 440 MPa UTS, formable and
weldable quality adaptable to manufacture of automotive body panels
which is applicable and usable for a wide range of automotive
application.
A further object of the present invention is to propose an improved
grade of steel sheet having 340 to 440 MPa UTS, formable and
weldable quality adaptable to manufacture of automotive body panels
which is suitable for producing through batch annealing route.

A still further object of the present invention is to propose an
improved grade of steel sheet 340 to 440 MPa UTS, formable and
weldable quality adaptable to manufacture of automotive body panels
which is cost savings.
A yet further object of the present invention is to propose an
improved grade of steel sheet having 340 to 440 MPa UTS, formable
and weldable quality adaptable to manufacture of automotive body
panels which saves energy consumption.
SUMMARY OF THE INVENTION
The invented product is a steel grade for automotive stamping
applications. It is a low carbon based steel composition,
strengthened by suitable additions of phosphorus and manganese.
The processing schedules, including steel making, hot rolling, cold
rolling and annealing, have been determined appropriately so as to
achieve desired drawability and strength. The material is also
adequately weldable.

Chemical composition
C% Mn% S% P% Si% Al% N (ppm)
0.04-0.06 0.3-1.5 0.01 0.05-0.09 0.01 0.04-0.05 35-50
max max
Physical processing
a) hot charging of slabs to reheat furnace
b) slab drop out @ around-1200°C
c) finish rolling @ higher than Ar3 temperature - 900 - 910°C
d) coiling @ 550 - 560°C
e) cold rolling @ 66 - 74%
f) batch annealing @ hot spot temperature - 700°C - 720°C and cold
spot temperature 620 - 640° (table suitably adjusted)
g) skin pass rolling @ 1.0% temper elongation

Test results (two results are given below for each grade of Al-killed
rephos family):

Secondary work embrittlement property: OK upto - 30°C (tested for
rephos - 340 and rephos - 390, rephos - 440 was not tested, but
expected to show same property due to same phosphorus content as
in rephos - 390)
Variables
(a) Chemical parameters: C, P and Mn - Increase strength of the
steel

(b) Physical parameters: Slab drop out temperature, finish rolling
temperature, coiling temperature, cold reduction and batch
annealing temperature, all have significant effects on final
mechanical properties of all the steel grades.

WE CLAIM:
1. Drawing quality Al-killed rephosphorised steel sheets having tensile
strength of 340-440 MPa comprising a steel having following
composition:
%C = 0.40-0.06
%Mn= 0.3-1.5
%S = 0.01 max
%P = 0.05-0.09
%Si = 0.01 max
%AI = 0.04-0.05
N (ppm) = 35-50
characterized in that Al-killed steel by addition of Phosphorus and
Manganese and subsequent heat treatment and Thermo-Mechanical
Treatment develop secondary work embrittlement properties like a
strength of 340-440 MPa, drawability and weldability.
2. The process to convert liquid steel to steel sheet comprising of
following steps:
- manufacturing of slab from the liquid sheet;
- hot charging the slab to reheat furnace;
- finish rolling @ higher than Ar3 temperature 900-910°C;
- coiling @ 550-560;
- cold rolling @ 66-74%;
- batch annealing @ hot spot temperature 700°C and cold spot
temperature 620°C; and
- skin pass rolling @ 1.0% tempered elongation;

characterized in that Al-killed steel having a ferrite microstructure after
hot rolling is being converted to a pancaked ferritic microstructure after
subsequent cold rolling and annealing treatment producing a good
secondary work embrittlement property and weldability.
3. The process to convert liquid steel to steel sheet as substantially described
and illustrated herein.

ABSTRACT

TITLE: DRAWING QUALITY AI-KILLEP REPHOSPHORISED STEEL
SHEETS HAVING TENSILE STRENGTH OF 340-440 PMa
The present invention is provided with a development of drawing quality Al-
killed rephosphorised steel sheets having tensile strength of 340-440 MPa
comprising a steel having the composition %C = 0.04-0.06, %Mn = 0.3-.15,
%S = 0.01 max, %P = 0.05-0.09, %Si = 0.01 max, %AI = 0.04-0.05, N
(ppm) = 35-50; characterized in that Al-killed steel by addition of
Phosphorus and Manganese and subsequent heat treatment and Thermo-
Mechanical Treatment develop secondary work embrittlement properties like
a strength of 340-440 MPa, drawability and weldability.

Documents

Application Documents

# Name Date
1 943-KOL-2007-22-02-2023-RELEVANT DOCUMENTS.pdf 2023-02-22
1 943-KOL-2007-REPLY TO EXAMINATION REPORT.pdf 2011-10-07
2 943-KOL-2007-PETITION UNDER RULE 137.pdf 2011-10-07
2 943-KOL-2007-RELEVANT DOCUMENTS [30-09-2021(online)].pdf 2021-09-30
3 943-KOL-2007-RELEVANT DOCUMENTS [26-09-2021(online)].pdf 2021-09-26
3 943-KOL-2007-OTHERS-1.2.pdf 2011-10-07
4 943-KOL-2007-RELEVANT DOCUMENTS [30-03-2020(online)].pdf 2020-03-30
4 943-KOL-2007-OTHERS 1.1.pdf 2011-10-07
5 943-KOL-2007-RELEVANT DOCUMENTS [27-03-2019(online)].pdf 2019-03-27
5 943-KOL-2007-FORM 2-1.1.pdf 2011-10-07
6 943-KOL-2007-RELEVANT DOCUMENTS [06-03-2018(online)].pdf 2018-03-06
6 943-KOL-2007-FORM 1-1.2.pdf 2011-10-07
7 Form 27 [31-03-2017(online)].pdf 2017-03-31
7 943-KOL-2007-FORM 1-1.1.pdf 2011-10-07
8 Other Patent Document [27-03-2017(online)].pdf 2017-03-27
8 943-KOL-2007-EXAMINATION REPORT REPLY RECIEVED 1.1.pdf 2011-10-07
9 943-KOL-2007-DRAWINGS.pdf 2011-10-07
9 943-KOL-2007_EXAMREPORT.pdf 2016-06-30
10 943-KOL-2007-(28-03-2016)-FORM-27.pdf 2016-03-28
10 943-KOL-2007-DRAWINGS-1.1.pdf 2011-10-07
11 943-KOL-2007-(04-11-2015)-FORM-27.pdf 2015-11-04
11 943-KOL-2007-DESCRIPTION (COMPLETE)-1.2.pdf 2011-10-07
12 943-KOL-2007-DESCRIPTION (COMPLETE) 1.1.pdf 2011-10-07
12 943-KOL-2007-FORM-27.pdf 2015-02-03
13 943-KOL-2007-CORRESPONDENCE 1.4.pdf 2012-07-12
13 943-KOL-2007-CORRESPONDENCE-1.3.pdf 2011-10-07
14 943-KOL-2007-CORRESPONDENCE-1.2.pdf 2011-10-07
14 943-KOL-2007-EXAMINATION REPORT.pdf 2012-07-12
15 943-KOL-2007-CORRESPONDENCE-1.1.pdf 2011-10-07
15 943-KOL-2007-FORM 1 1.3.pdf 2012-07-12
16 943-KOL-2007-AMANDED CLAIMS.pdf 2011-10-07
16 943-KOL-2007-FORM 18.pdf 2012-07-12
17 943-KOL-2007-FORM 3.pdf 2012-07-12
17 943-KOL-2007-AMANDED CLAIMS-1.1.pdf 2011-10-07
18 943-KOL-2007-ABSTRACT-1.2.pdf 2011-10-07
18 943-KOL-2007-GPA.pdf 2012-07-12
19 943-KOL-2007-ABSTRACT 1.1.pdf 2011-10-07
19 943-KOL-2007-GRANTED-ABSTRACT.pdf 2012-07-12
20 00943-kol-2007-gpa.pdf 2011-10-07
20 943-KOL-2007-GRANTED-CLAIMS.pdf 2012-07-12
21 00943-kol-2007-form 3.pdf 2011-10-07
21 943-KOL-2007-GRANTED-DESCRIPTION (COMPLETE).pdf 2012-07-12
22 00943-kol-2007-form 2.pdf 2011-10-07
22 943-KOL-2007-GRANTED-DRAWINGS.pdf 2012-07-12
23 00943-kol-2007-form 18.pdf 2011-10-07
23 943-KOL-2007-GRANTED-FORM 1.pdf 2012-07-12
24 943-KOL-2007-GRANTED-FORM 2.pdf 2012-07-12
24 00943-kol-2007-form 1.pdf 2011-10-07
25 00943-kol-2007-description complete.pdf 2011-10-07
25 943-KOL-2007-GRANTED-SPECIFICATION.pdf 2012-07-12
26 00943-kol-2007-correspondence others.pdf 2011-10-07
26 943-KOL-2007-OTHERS 1.3.pdf 2012-07-12
27 00943-kol-2007-correspondence others 1.1.pdf 2011-10-07
27 943-KOL-2007-REPLY TO EXAMINATION REPORT 1.1.pdf 2012-07-12
28 00943-kol-2007-abstract.pdf 2011-10-07
28 00943-kol-2007-claims.pdf 2011-10-07
29 00943-kol-2007-abstract.pdf 2011-10-07
29 00943-kol-2007-claims.pdf 2011-10-07
30 00943-kol-2007-correspondence others 1.1.pdf 2011-10-07
30 943-KOL-2007-REPLY TO EXAMINATION REPORT 1.1.pdf 2012-07-12
31 00943-kol-2007-correspondence others.pdf 2011-10-07
31 943-KOL-2007-OTHERS 1.3.pdf 2012-07-12
32 00943-kol-2007-description complete.pdf 2011-10-07
32 943-KOL-2007-GRANTED-SPECIFICATION.pdf 2012-07-12
33 00943-kol-2007-form 1.pdf 2011-10-07
33 943-KOL-2007-GRANTED-FORM 2.pdf 2012-07-12
34 00943-kol-2007-form 18.pdf 2011-10-07
34 943-KOL-2007-GRANTED-FORM 1.pdf 2012-07-12
35 00943-kol-2007-form 2.pdf 2011-10-07
35 943-KOL-2007-GRANTED-DRAWINGS.pdf 2012-07-12
36 943-KOL-2007-GRANTED-DESCRIPTION (COMPLETE).pdf 2012-07-12
36 00943-kol-2007-form 3.pdf 2011-10-07
37 00943-kol-2007-gpa.pdf 2011-10-07
37 943-KOL-2007-GRANTED-CLAIMS.pdf 2012-07-12
38 943-KOL-2007-ABSTRACT 1.1.pdf 2011-10-07
38 943-KOL-2007-GRANTED-ABSTRACT.pdf 2012-07-12
39 943-KOL-2007-ABSTRACT-1.2.pdf 2011-10-07
39 943-KOL-2007-GPA.pdf 2012-07-12
40 943-KOL-2007-AMANDED CLAIMS-1.1.pdf 2011-10-07
40 943-KOL-2007-FORM 3.pdf 2012-07-12
41 943-KOL-2007-AMANDED CLAIMS.pdf 2011-10-07
41 943-KOL-2007-FORM 18.pdf 2012-07-12
42 943-KOL-2007-CORRESPONDENCE-1.1.pdf 2011-10-07
42 943-KOL-2007-FORM 1 1.3.pdf 2012-07-12
43 943-KOL-2007-CORRESPONDENCE-1.2.pdf 2011-10-07
43 943-KOL-2007-EXAMINATION REPORT.pdf 2012-07-12
44 943-KOL-2007-CORRESPONDENCE 1.4.pdf 2012-07-12
44 943-KOL-2007-CORRESPONDENCE-1.3.pdf 2011-10-07
45 943-KOL-2007-DESCRIPTION (COMPLETE) 1.1.pdf 2011-10-07
45 943-KOL-2007-FORM-27.pdf 2015-02-03
46 943-KOL-2007-DESCRIPTION (COMPLETE)-1.2.pdf 2011-10-07
46 943-KOL-2007-(04-11-2015)-FORM-27.pdf 2015-11-04
47 943-KOL-2007-(28-03-2016)-FORM-27.pdf 2016-03-28
47 943-KOL-2007-DRAWINGS-1.1.pdf 2011-10-07
48 943-KOL-2007-DRAWINGS.pdf 2011-10-07
48 943-KOL-2007_EXAMREPORT.pdf 2016-06-30
49 943-KOL-2007-EXAMINATION REPORT REPLY RECIEVED 1.1.pdf 2011-10-07
49 Other Patent Document [27-03-2017(online)].pdf 2017-03-27
50 943-KOL-2007-FORM 1-1.1.pdf 2011-10-07
50 Form 27 [31-03-2017(online)].pdf 2017-03-31
51 943-KOL-2007-RELEVANT DOCUMENTS [06-03-2018(online)].pdf 2018-03-06
51 943-KOL-2007-FORM 1-1.2.pdf 2011-10-07
52 943-KOL-2007-RELEVANT DOCUMENTS [27-03-2019(online)].pdf 2019-03-27
52 943-KOL-2007-FORM 2-1.1.pdf 2011-10-07
53 943-KOL-2007-RELEVANT DOCUMENTS [30-03-2020(online)].pdf 2020-03-30
53 943-KOL-2007-OTHERS 1.1.pdf 2011-10-07
54 943-KOL-2007-RELEVANT DOCUMENTS [26-09-2021(online)].pdf 2021-09-26
54 943-KOL-2007-OTHERS-1.2.pdf 2011-10-07
55 943-KOL-2007-PETITION UNDER RULE 137.pdf 2011-10-07
55 943-KOL-2007-RELEVANT DOCUMENTS [30-09-2021(online)].pdf 2021-09-30
56 943-KOL-2007-22-02-2023-RELEVANT DOCUMENTS.pdf 2023-02-22
56 943-KOL-2007-REPLY TO EXAMINATION REPORT.pdf 2011-10-07

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