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Device Having Reduced Bias Temperature Instability (Bti)

Abstract: A semiconductor device is disclosed along with methods for manufacturing such a device. In certain embodiments, the semiconductor device includes a source electrode formed using a metal that limits a shift, such as due to bias temperature instability, in a threshold voltage of the semiconductor device during operation. In certain embodiments the semiconductor device may be based on silicon carbide.

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Patent Information

Application #
Filing Date
30 July 2013
Publication Number
07/2015
Publication Type
INA
Invention Field
ELECTRONICS
Status
Email
ipr@singhassociates.in
Parent Application
Patent Number
Legal Status
Grant Date
2023-10-30
Renewal Date

Applicants

GENERAL ELECTRIC COMPANY
1 RIVER ROAD, SCHENECTADY, NEW YORK 12345, U.S.A.

Inventors

1. MICHAEL, JOSEPH DARRYL
ONE RESEARCH CIRCLE, BUILDING K1-3A59, NISKAYUNA, NY 12309, U.S.A.
2. ARTHUR, STEPHEN DALEY
ONE RESEARCH CIRCLE, BUILDING K1-3A59, NISKAYUNA, NY 12309, U.S.A.
3. JOHNSON, TAMMY LYNN
ONE RESEARCH CIRCLE, BUILDING K1-3A59, NISKAYUNA, NY 12309, U.S.A.
4. LILIENFELD, DAVID ALAN
ONE RESEARCH CIRCLE, BUILDING K1-3A59, NISKAYUNA, NY 12309, U.S.A.

Specification

BACKGROUND
The subject matter disclosed herein relates to semiconductor devices and,
more specifically, to improving stability of semiconductor devices.
For a semiconductor device, such as a silicon carbide (Sic) transistor, bias
temperature instability (BTI) may cause substantial variability in device performance.
For example, negative bias temperature instability (NBTI) may result in a significant
change or drift in the threshold voltage of a Sic device when operated under
particular conditions, such as negative bias and/or elevated temperatures, over an
extended period of time. The NBTI in Sic devices is thought to be a result of
interfacial charge trapping (e.g., oxide charges), which may, for example, be induced
by operating the device at an elevated temperature, and under a particular bias
condition, for extended time periods. For example, a Sic metal-oxide-semiconductor
field effect transistor (MOSFET) may experience a threshold voltage shift when
subjected to combined voltage and temperature stressing due to NBTI.
In certain cases, the aforementioned NBTI may shift (e.g., decrease) the
threshold voltage of a Sic device to the point that the device may become conductive
even without an applied gate-source voltage, transforming a normally-off device into
a normally-on device. As such, NBTI significantly impacts the reliability and
performance of Sic devices. An industry-accepted solution to NBTI in Sic devices
has yet to be determined. Accordingly, alleviating the NBTI issue in Sic devices is
especially desirable in order to take advantage of the unique operating characteristics
(e.g., higher operating temperatures, improved mechanical properties, improved
electrical properties, and so forth) that Sic may offer to certain systems and
applications.
BRIEF DESCRIPTION
In one embodiment, a method is provided for manufacturing a
semiconductor device. In accordance with this method, a silicon carbide wafer
suitable for semiconductor manufacture is provided. One or more semiconductor
devices are manufactured on each silicon carbide wafer. A source electrode of each
semiconductor device is formed by depositing a metal that limits a shift in the
threshold voltage of the semiconductor device during operation.
In another embodiment, a metal-oxide field-effect transistor (MOSFET)
device is provided. The MOSFET device includes a gate electrode and a substrate
comprising silicon carbide and having a surface that supports the gate electrode and
defines a surface normal direction. The substrate includes: a drift region including a
first dopant type so as to have a first conductivity type; a well region adjacent to the
drift region and proximal to the surface, wherein the well region includes a second
dopant type so as to have a second conductivity type and a channel region disposed
proximal to the gate electrode; and a source contact region adjacent to the well region,
wherein the source contact region having the first conductivity type. The MOSFET
devices also includes an inter-layer dielectric disposed about the gate electrode and on
a portion of the surface of the substrate, a contact layer disposed on a portion of the
surface of the substrate covering a portion of the source contact region; and a source
electrode disposed over the inter-layer dielectric and in electrical contact with the
source contact region. The source electrode comprises a metal that inhibits a shift in a
threshold voltage of the MOSFET device during operation.
In another embodiment, a semiconductor device is provided. The
semiconductor device comprises: a gate electrode disposed on an insulation layer; a
source electrode, wherein the source electrode comprises a metal that inhibits a shift
in a threshold voltage of the semiconductor device during operation; an inter-layer
dielectric (ILD) disposed between the gate electrode and the insulation layer, and the
source electrode; a source contact region, wherein the source contact region contacts
both the source electrode and a well region and is either n-type or p-type; a silicon
carbide substrate upon which the insulation layer, the source contact region, and the
inter-layer dielectric are disposed, wherein the silicon carbide substrate is either ntype
or p-type; the well region, wherein the well region extends into the silicon
carbide substrate and is either n-type or p-type; and a drain electrode disposed on an
opposite side of the silicon carbide substrate from the gate electrode.
BRIEF DESCRIPTION OF THE DRAWINGS
These and other features, aspects, and advantages of the present invention
will become better understood when the following detailed description is read with
refgrence to the accompanying drawings in which like characters represent like parts
throughout the drawings, wherein:
FIG. 1 is a process flow diagram of a transistor fabrication process in
accordance with certain embodiments of a present technique;
FIG. 2 is a schematic cross-sectional view of a Sic MOSFET, in
accordance with an embodiment of the present approach;
FIG. 3 is a plot of drain current as a function of gate voltage for a
conventional MOSFET before and after voltage and temperature stressing; and
FIG. 4 is a graph comparison of the different threshold voltage shifts that
occur with different metals in the embodiments of the present approach.
DETAILED DESCRIPTION
One or more specific embodiments will be described below. In an effort to
provide a concise description of these embodiments, all features of an actual
implementation may not be described in the specification. It should be appreciated
that in the development of any such actual implementation, as in any engineering or
design project, numerous implementation-specific decisions must be made to achieve
the developers' specific goals, such as compliance with system-related and businessrelated
constraints, which may vary from one implementation to another. Moreover,
it should be appreciated that such a development effort might be complex and time
consuming, but would nevertheless be a routine undertaking of design, fabrication,
and manufacture for those of ordinary skill having the benefit of this disclosure.
When introducing elements of various embodiments of the present
invention, the articles "a," "an," "the," and "said" are intended to mean that there are
one or more of the elements. The terms "comprising," "including," and "having" are
intended to be inclusive and mean that there may.be additional elements other than the
listed elements.
As set forth above, BTI, such as NBTI, presents a challenge to
semiconductor device reliability. It should be appreciated that the physics and
chemistry associated with the BTI phenomenon are complex. As such, while the
exact mechanism of BTI may not be entirely understood in all contexts, present
embodiments provide systems and methods for inhibiting (e.g., reducing, limiting,
alleviating, or otherwise diminishing) BTI, such as NBTI, during the operation of
semiconductor devices (e.g., Sic MOSFETs). In particular, the present approach
involves including a metal as the source electrode of a Sic semiconductor device that
inhibits BTI to tolerable levels (e.g., on the order of tenths of a volt rather than on the
order of several volts). In certain embodiments, a method includes a step in the
semiconductor device manufacturing process where the metal is deposited as the
source electrode. In other embodiments, a Sic semiconductor or a MOSFET device
is provided that includes the metal as a source electrode.
While the following disclosure may be generally focused on NBTI in Sic
MOSFETs, it should be appreciated that the solutions and techniques detailed herein
for mitigating BTI may have applicability to other semiconductor devices, such as
insulated gate bipolar transistors (IGBT), MOS controlled thyristors, and gate
controlled thyristors. For explanatory purposes, a MOS Controlled thyristor (MCT)
may include two MOSFETs built into the structure and may be sensitive to a shift in
threshold voltage (VTH) as a result of BTI effects. It is also contemplated that the
techniques detailed herein will also mitigate the effects related to positive bias
threshold instability (PBTI), which refers to the VTH effects that occur under a
positive bias.
With the foregoing in mind, FIG. 1 illustrates a process flow diagram of the
steps of one example of a transistor fabrication process 10 in accordance with certain
embodiments of the present approach. As represented by block 12, a silicon carbide
wafer may be obtained. In one embodiment the wafer may be heated in a hrnace to
form a layer of silicon dioxide, also called the oxide layer. After the silicon carbide
wafer is obtained and the oxide layer formed, patterns may be created in the oxide
I
layer of the kafer, as represented by block 14.
In one implementation, in order to create the patterned oxide layer, a layer
of photoresist may be applied over the surface of the oxide layer and baked dry. A
mask defining the circuit features of the transistor may be applied to the photoresist,
and the photoresist may be exposed to ultraviolet light. The sections of the
photoresist that are exposed to the ultraviolet light may be softened and washed away
by an alkaline solution. A strong acid may be applied to the wafer, and the sections of
the oxide layer not protected by the photoresist may be dissolved. A solvent may be
then used to clear the photoresist that remains. Therefore, a patterned oxide layer may
remain on the silicon carbide wafer. As will be appreciated, though the above relates
one approach for forming a suitable oxide pattern layer, any other suitable
lithographic approach may be employed to form the desired traces and/or patterns on
the oxide layer (or on other layers) of the device being fabricated.
After the desired oxide pattern is present on the silicon carbide wafer, ntype
and p-type regions may be formed in the silicon carbide, as represented by block
16. For example, in one implementation the n-type and p-type regions (i.e. wells)
may be created by exposing the wafer to an ion beam to implant donor or acceptor
atoms into the silicon carbide surfaces. Different types of atoms create n-type and ptype
wells. For example, a boron ion beam may create a p-type well, while a
phosphorous ion beam may create an n-type well. The patterned oxide layer may be
designed to allow for precise placement of the wells. When fabricating a transistor,
boxes 14 and 16 may be repeated several times to create complex well patterns in the
silicon carbide.
Depending on the device being fabricated, after the wells are in place,
another oxide layer may be formed in the manner described above. A thin insulating
layer may be deposited over a drift region as represented by box 18. In certain
embodiments the insulating layer may be deposited or thermally grown on parts of the
silicon carbide wafer. The insulating layer may be made of silicon dioxide or another
suitable insulator. After the insulating layer is deposited 18, poly silicon may be
deposited over the insulating layer to form a gate electrode, as represented by box 20.
In certain embodiments, an additional low-resistance layer may be deposited over the
poly silicon layer.
Once the poly silicon layer is deposited, an inter-layer dielectric (ILD) may
be deposited over the poly silicon layer as represented by box 22. The ILD may be
used to insulate the poly silicon or metal material of the gate electrode from a source
electrode. A source electrode is then deposited over the ILD, as represented by box
24. As discussed herein, the source electrode may be made of a metal which inhibits
or limits a shift in threshold voltage of a transistor during operation.
With the foregoing example of a fabrication operation in mind, FIG. 2
illustrates a metal-oxide semiconductor field effect transistor (MOSFET) 100, in
accordance with an embodiment of the present approach. In certain embodiments, the
illustrated MOSFET 100 may be a Sic-based MOSFET designed for hightemperature
operation (e.g., above approximately 125 OC, above approximately 175
OC, and/or above approximately 300 "C). Additionally, the illustrated MOSFET 100
may be fabricated using standard microelectronic fabrication processes, such as the
process described above. These processes may include, for example, lithography,
film depositionlgrowth methods (e.g., physical and chemical vapor deposition,
plating, oxidation, etc.), crystal growth methods, and wet and dry etching methods.
The illustrated MOSFET 100 includes a substrate 102, which may be made of a
semiconductor material, such as silicon carbide (Sic). The substrate 102 may be a
semiconductor die or wafer that defines a major surface 104 and a surface normal
direction or "thickness direction," t, which extends normally from the surface and into
the substrate 102. It should be appreciated that FIG. 2 is intended to illustrate the
relative positions of the various components in one example of a MOSFET 100 and
should not be construed as implying relative scales or dimensions of these
components.
In the depicted embodiment, the illustrated surface 104 supports a gate
electrode 106. Additionally, the illustrated gate electrode 106 is disposed on an
insulation layer 108 (which may also be referred to as a gate oxide or gate dielectric
layer) that is in direct contact with the surface 104 of the substrate 102. The
insulation layer 108 may generally be made from an electrically insulating material,
such as silicon dioxide (SOz). Furthermore, the illustrated insulation layer 108
extends along the surface 104 and may extend to any point up to the contact layer
126. The gate electrode 106 may include a polycrystalline silicon layer 107, and may
also include a low-resistance layer 109 formed, for example, of electrically
conductive material (e.g., metal andlor silicide). The gate electrode 106 may be
configured to receive a gate voltage, VG.
[0023] The illustrated substrate 102 also defines a second surface 110 that is in
contact with a drain electrode 112, which is generally configured to receive a drain
voltage, VD. It should be noted that FIG. 2 is a schematic cross-sectional view of a
single MOSFET cell and that the full MOSFET device is typically comprised of large
number of cells, situated next to one another, which may share a common gate
electrode 106 and drain electrode 1 12.
The illustrated substrate 102 includes a drift region 114 in addition to a well
region 116, which is disposed adjacent to the drift region 114 and proximal to the
surface 104. The drift region 114 may be doped with a first dopant type and have a
first conductivity type with first majority charge carriers, while the well region 116
may be doped with a second dopant type and have a second conductivity type with
second majority charge carriers. For example, in the Sic substrate 102 the first
dopant type may be one or more of nitrogen and phosphorus ("n-type dopants"), while
the second dopant type may be one or more of aluminum, boron, gallium, and
beryllium ("p-type dopants"), resulting in n-doped and p-doped regions, respectively.
For such an embodiment, the first and second majority charge carriers would be
electrons and holes, respectively.
The illustrated substrate 102 further includes a source contact region 122
having the first conductivity type (e.g., n-type in FIG. 2). The well region 1 16 may be
disposed proximal to the contact region 122 such that the well region 116 may include
therein a channel region 118 disposed proximal to the gate electrode 106. For
example, the channel region 1 18 may extend along the surface 104 under the gate
electrode 106 (where "under" means further along the thickness direction t).
Additionally, a dielectric layer 120, sometimes referred to as an inter-layer dielectric
(ILD), may be disposed over the gate electrode 106 and the insulation layer 108. In
one example the dielectric layer is a material including phosphorous silicate glass
(PSG).
- - - - -- In one embodiment, the source contact region 122 may be disposed
adjacent to the surface 104 and the well region 116 may surround the source contact
region 122. The substrate 102, in certain embodiments, also includes a body contact
region 125 having the second conductivity type (e.g., p-type in FIG. 2). The body
contact region 125 in the illustrated embodiment is disposed adjacent to the well
region 1 16 and to the surface 104.
A source electrode 124 (e.g., formed of metal, such as nickel) may be
disposed over the source contact region 122 and body contact region 125 and may be
configured to receive a source voltage, VS. Further, the source electrode 124 may be
in electrical contract with both the source contact region 122 and body contact region
125. For example, in the illustrated embodiment, electrical contact between the
source electrode 124 and the source contact region 122 and body contact region 125 is
made via a contact layer 126 (e.g., formed of nickel or another suitable metal).
Formation and composition of the source electrode 124 is discussed in greater detail
below.
During operation, the MOSFET 100 may generally act as a switch. When a
voltage difference VDS = VD - VS is applied between the drain electrode 112 and the
source electrode 124, an output current (IDS) between those same electrodes can be
modulated or otherwise controlled by an input voltage VGS applied to the gate
electrode 106, wherein VGS = VG - VS. For gate voltages VG less than a "threshold
voltage" (VTH) of the MOSFET 100, the current IDS remains nominally at about
zero, although a relatively small leakage current may exist even for gate voltages
below the threshold voltage. The threshold voltage VTH is a function of, amongst
other things, the dimensions, materials, and doping levels in the MOSFET 100, and
MOSFETs are typically designed so as to exhibit a predetermined threshold voltage
VTH. Circuits incorporating the MOSFET 100 can then be designed to the expected
(predetermined) threshold voltage VTH.
It should be appreciated that the threshold voltage (VTH) for a MOSFET is
not uniquely defined. There are at least five different techniques for measuring VTH,
and for a specific example, they do not necessarily produce exactly the same results.
The method employed herein is referred to as the "threshold drain current method," in
which the gate voltage at a specified drain current is taken to be the threshold voltage.
- - - - - - Conventional MOSFETs, including Sic MOSFETs, have been found to
experience a shift in the threshold voltage due to NBTI when subjected to a potential
difference between the gate and source electrodes 106, 124 and, particularly, when
subjected to this potential at elevated temperatures and for extended periods of time.
Specifically, as mentioned, negative bias temperature instability (NBTI) is a concern
for Sic devices. Illustrating an example of such a threshold voltage shift, FIG. 3 is a
plot 140 of drain current as a function of gate voltage for a conventional MOSFET
before and after voltage and temperature stressing. That is, FIG. 3 illustrates the
NBTI effect in a stressed Sic MOSFET device lacking a source electrode 124 which
limits the NBTI effect during operation, as discussed herein.
With respect to FIG. 3, a threshold drain current method, which is a
variation of the "sub-threshold technique," may be used when characterizing the
NBTI phenomenon in the Sic MOSFET device. Example test conditions used for
generating the data illustrated in plot 140 of FIG. 3 are set forth below. In certain
embodiments, the test conditions may be such that the transfer curve measurements
are taken on MOSFETs at constant stress temperature. For example, first, the gate
voltage may be held at a constant -20 volts (V) for 15 minutes and the VDS may be
held at 0 V. Then, a small constant voltage may be applied between the source and
drain terminals (e.g., 100 mV) and the gate voltage may be swept from -1 0 V to +10
V, a range large enough to capture the lower current range of the MOSFET (e.g., less
than 0.1 nano-amps in this particular case) up to the saturation current (e.g.,
approximately 16 milli-amps), defining the "post neg" transfer curve 142 depicted in
FIG. 3. A constant voltage gate positive stress bias of +20 V may then be applied to
the gate for an additional 15 minutes, with VDS = 0 V. Finally, a similar reverse
sweep of the gate voltage may be conducted from +10 V to -1 0 V to capture the "post
pos" transfer curve 144 with VDS = 0.1 V.
The use of 10 micro-amps as the threshold drain current of choice for VTH
determination is done for practical reasons. For example, it is small enough to reside
on the linear sub-threshold portion of the semilog transfer curve, and is large enough
to measure accurately and easy to extract from the data. The MOSFET parameters
and test conditions for data collection were as follows: VDS = 0.1 V; Temp = 175 "C;
gate oxide thickness (Tox) = 500 Angstroms, Device Active Area = 0.067 cm2; Area
of one MOS cell = 1.6~-4cmc~h;a nnel width to length ratio (WIL) of one MOS cell =
6900. Scaling the threshold drain current to larger or smaller devices has a linear
dependence on Device Active Area, Area of one MOS cell and W/L. It should be
noted however, that threshold current scales inversely with gate oxide thickness
(Tox) .
Accordingly, FIG. 3 demonstrates the drift or shift in the threshold voltage
(e.g., a shift in the voltage where IDS increases significantly) following positive and
negative gate bias stressing. The vertical scale is the drain current (amps), the
horizontal scale is the gate to source voltage (volts). The threshold voltage shift thus
represents an example of the effects of bias temperature instability (BTI). The VTH
drift is taken as the voltage difference between the VTH positive voltage stress value
and the VTH negative voltage stress value at 10 micro-amps of source to drain
current. In the example illustrated in FIG. 3, the VTH drift is approximately 6.9 V.
In experiments relating to certain embodiments, it was hypothesized that
aluminum as a source electrode metal could be a factor contributing to NBTI - due to
chemical reactivity of aluminum with hydrogen and OH radicals. In one set of
experiments, bits of indium ribbon were used on devices that did not have the final
source metal deposited. In these experiments, indium ribbons were pressed onto the
source pad area of the Sic semiconductor and heated at 125°C. The heating approach
improved indium's adhesion to the Sic semiconductor. Two types of tests were
performed to study the effect of replacing aluminum with indium. The first series of
tests were conducted in a chamber that could be pumped down to a low vacuum, yet
still be raised to 125"C, a temperature sufficient to cause NBTI in the Sic
semiconductors. The second tests were conducted under atmospheric conditions in
heaters heated to 150°C and 175°C. So data was acquired for 125°C in a near
vacuum, 125OC in atmospheric conditions, 150°C in atmospheric conditions, and
175°C in atmospheric conditions. Each test indicated that the use of indium had
alleviated the consequences of NBTI in the Sic semiconductor.
An extension of the experimental work with indium described above was to
include other metals that could potentially demonstrate the same functionality as
indium. In one set of experiments, metals that were good diffusion barriers to
hydrogen were considered for use in forming source electrodes 124. In addition,
another factor considered in evaluating metals to be used in forming source electrodes
124 was that the metals should not produce dissolved atomic hydrogen in silica from
water. Further, if a metal does produce dissolved atomic hydrogen, it should function
as a getter of hydrogen species. For example, titanium and aluminum both produce
hydrogen in water, but titanium is able to getter hydrogen. With this in mind, FIG. 4
shows the benefit of adding a layer of titanium beneath an aluminum layer of the
source electrode. Based upon the characteristics mentioned above, various metals and
metal combinations were chosen to be tested: gold + 10 nanometer nickel, nickel,
tantalum, and aluminum. In one experiment, a 10 nanometer layer of nickel was
chosen as an adhesion layer to aid in gold's adhesion to the semiconductor surface.
Aluminum was employed as a baseline for comparing the NBTI measurements with
the other metals.
To prepare the semiconductor for the alternative metals experiment, a
silicon carbide wafer was removed after the lot reached the pad metal deposition step.
Prior to metal deposition, it was patterned with the standard pad metal pattern but
using a negative lift off resist. The patterned wafer was then laser cut into 12
rectangular pieces of roughly 20 die each. Rows or columns of die were sacrificed to
make the cuts. Various metal layers were then deposited onto the pieces. The metal
layers and thicknesses were as follows: gold (2000 A)lnickel (100 A), nickel (2000
A), tantalum (2000 A), aluminum (2000 A), and aluminum (-100 A). The following
metals were also tested: aluminum (40000 A), aluminum (40000 A)/titanium (200
A), and aluminum (40000 &/titanium (1000 A). Some of the samples had a precleaning
of a 1 minute pre-sputter, while others had a pre-cleaning of a 1 minute presputter,
a wait, and another 1 minute pre-sputter. The goldnickel sample was tested
with both pre-cleaning methods, and the 2000 A sample of aluminum was tested with
no pre-cleaning. The metal samples were deposited with either a MRC643 sputter, a
Perkin-Elmer sputter, or a Temescal sputter. After disposition, the samples were
individually soaked in acetone in an ultrasonic bath. The acetone removed the resist
pattern and the metal deposited on it. The pieces then received ST22 and PRSlOOO
solvent cleans and were stored in a dry box in a cleanroom prior to testing for NBTI.
The results of the experiment are given in FIG. 4, in which a graph shows a
comparison of different threshold voltage shifts for different source pad electrode
metal types. The variable "N" above the data points represents the number of
measurements taken. For the aluminum samples at 200 nm, two data points appear on
the graph. The first Al (200 nm) data point represents the data set which included a
single sample that had a voltage threshold shift value of 4.42 V. The data point
labeled "Al - no outlier" contains the same data set with the outlier removed. Each of
the metals (except for aluminum) compared on the graph have threshold voltage shifts
of close to 0.25 V. The metals have a deviation of only about 0.05 to 0.2 V. On the
other hand, aluminum has threshold voltages of close to 0.75 V for the 200 nm sample
(no outlier), and close to 6.6 V for the 4000 nm sample. Both the 200 nm aluminum
(no outlier) and the 4000 nm aluminum metals have large deviations of about 0.5 V
and 1.5 V respectively. It should be appreciated that since BTI effects may induce a
threshold voltage shift of several volts (e.g., 2 V to 6 V) in typical Sic MOSFETs, use
of a source electrode 124 as discussed herein may afford a substantial improvement to
device reliability.
The results of the experiment would suggest that indium is a suitable
material for limiting the threshold voltage shift, though the method of application
differed from the other metals tested, so a true comparison was difficult. Also, with
the Al-only pad metal, NBTI measurements at 175" were between 2-4 times more
than any of the other pad metals attempted in the experiment for comparable metal
thicknesses. In terms of reliability, the alternative pad metals were within 0.1-0.2 V
of each other and showed a narrower variation than the pure aluminum. The
alternative pad metals also showed a relatively narrow variation when compared with
the baseline metal type. The 2000 A aluminum sample shows approximately a 6.5
times lower NBTI shift than the 40000 1$ aluminum sample. The lower NBTI shift
may be a reflection of reducing the thickness of the sample by a factor of twenty. The
aluminum (40000 A)/titanium (200 A) combination showed comparable NBTI shifts
with the rest of the metals. The observation that the smaller amount of titanium had a
small NBTI shift suggested that, in certain experiments, titanium was not acting
primarily as a hydrogen getter, but simply as a barrier between the aluminum and the
dielectric layers of the MOSFET. In the conducted experiments, gold did have a low
NBTI shift, but the NBTI shift was slightly larger than the shifts of indium, nickel, or
tantalum. Therefore, as discussed herein, separating the aluminum pad metal, when
present as a source pad 124, from physical contact with the dielectric layer results in a
reduction of the NBTI shift in MOSFETs. Alternatively, other metals, such as those
discussed above, may be used to form the source pad 124 and to achieve a reduction
in the NBTI shift.
Therefore, as discussed herein, manufacturing a MOSFET with certain
source electrode metals will largely inhibit or limit the drift Nustrated in FIG. 3. In
accordance with certain embodiments, the source electrode 124 may be comprised of
a metal that limits a shift in the threshold voltage of the MOSFET device during
operation. In certain embodiments, the metal may not produce dissolved atomic
hydrogen in silica from water molecules. Further, the metal may be a diffusion
barrier to hydrogen. In certain embodiments, the metal may serve as a method of
keeping an aluminum pad metal from physical contact with a dielectric layer of a
MOSFET. The metal may be deposited by using a sputtering method of depositing
thin films or any other suitable deposition technique. For example, in certain
embodiments, the source electrode 124 may be comprised of a thin film or layer (e.g.,
2000 A) of nickel (Ni) or a thin film or layer (e.g., 2000 A ) of tantalum. In other
embodiments, the source electrode 124 may be comprised of a combination of metal
layers. For example, the source electrode 124 may be comprised of a thin film or
layer (e.g., 2000 A) of gold (Au) layered with a thin film or layer (e.g., 100 A ) of Ni,
or a film or layer (e.g., 40000 A) of aluminum layered with a thin film or layer (e.g.,
200 A ) of titanium. In certain embodiments, one of the layers of metal may be used
as an adhesion layer to improve the contact of the source electrode 124 with the
MOSFET. As will be appreciated, the various metals for use as or with a source
electrode 124 as discussed herein merely represent examples of some such suitable
metals or materials. Therefore, other metals or materials, alone or in combination
with one another, may also be used to limit the effects of BTI (both positive and
negative) as discussed herein and are encompassed by the present disclosure.
Technical effects of embodiments include a semiconductor device (e.g., a
silicon carbide (Sic) device) designed to inhibit a shift in a threshold voltage of the
semiconductor device during operation. In certain implementations, the
semiconductor device includes a gate electrode disposed on an insulation layer, a
source electrode, an inter-layer dielectric, a substrate, a well region, a source contact
region, and a drain electrode. The source electrode is chosen to be a metal that
inhibits a shift in a threshold voltage of the semiconductor device during operation.
This written description uses examples to disclose the invention, including
the best mode, and also to enable any person skilled in the art to practice the
invention, including making and using any devices or systems and performing any
incorporated methods. The patentable scope of the invention is defined by the claims,
and may include other examples that occur to those skilled in the art. Such other
examples are intended to be within the scope of the claims if they have structural
elements that do not differ from the literal language of the claims, or if they include
equivalent structural elements with insubstantial differences from the literal languages
of the claims.

We Claim:
1. A method for manufacturing a semiconductor device, comprising:
providing a silicon carbide wafer suitable for semiconductor manufacture;
manufacturing one or more semiconductor devices on each silicon carbide
wafer;
forming a source electrode of each semiconductor device by depositing a
metal that limits a shift in the threshold voltage of the semiconductor device during
operation.
2. The method of claim 1, wherein the metal is a diffusion barrier to hydrogen.
3. The method of claim 1, wherein the metal does not produce dissolved atomic
hydrogen in silica from water molecules.
4. The method of claim I, wherein the semiconductor device comprises a metaloxide-
semiconductor field-effect transistor (MOSFET).
5. The method of claim 1, wherein the semiconductor device comprises an
insulated gate bipolar transistor (IGBT), a MOS controlled thyristor, or a gate
controlled thyristor.
6. The method of claim 1, wherein the shift in the threshold voltage of the
semiconductor device results from bias temperature instability (BTI) in the
semiconductor device when operating the semiconductor device at elevated
temperatures, elevated bias, or both.
7. The method of claim 1, wherein the shift in threshold voltage of the
semiconductor device during operation is less than 1 V.
8. The method of claim 1, wherein the source electrode is comprised of a
combination of metal layers.
9. A semiconductor device comprising:
a gate electrode disposed on an insulation layer;
a source electrode, wherein the source electrode comprises a metal that
inhibits a shift in a threshold voltage of the semiconductor device during operation;
an inter-layer dielectric (ILD) disposed between the gate electrode and
the insulation layer, and the source electrode;
a source contact region, wherein the source contact region contacts
both the source electrode and a well region and is either n-type or p-type;
a silicon carbide substrate upon which the insulation layer, the source
contact region, and the inter-layer dielectric are disposed, wherein the silicon carbide
substrate is either n-type or p-type;
the well region, wherein the well region extends into the silicon
carbide substrate and is either n-type or p-type; and
a drain electrode disposed on an opposite side of the silicon carbide
substrate from the gate electrode.
10. The semiconductor device of claim 9, wherein the source electrode metal is a
diffusion barrier to hydrogen.
11. The semiconductor device of claim 9, wherein the source electrode metal does
not produce dissolved atomic hydrogen in silica from water molecules.
12. The semiconductor device of claim 9, wherein the shift in the threshold
voltage of the semiconductor device results from bias temperature instability (BTI) in
the semiconductor device when operating the semiconductor device at elevated
temperatures, elevated bias, or both.
13. The semiconductor device of claim 9, wherein the shift in threshold voltage of
the semiconductor device during operation is less than 1 V.
14. The semiconductor device of claim 9, wherein the source electrode is
comprised of a combination of metal layers.
15. The semiconductor device of claim 9, wherein the semiconductor device
comprises a metal-oxide field-effect transistor (MOSFET) device, which further
comprises: a substrate comprising silicon carbide and having a surface that supports
the gate electrode and defines a surface normal direction, wherein the substrate
includes:
a drift region including a first dopant type so as to have a first
conductivity type; and
a well region adjacent to the drift region and proximal to the surface,
wherein the well region includes a second dopant type so as to have a second
conductivity type and a channel region disposed proximal to the gate electrode.
16. The semiconductor device of claim 15, wherein the source electrode metal is a
diffusion barrier to hydrogen.
17. The semiconductor device of claim 15, wherein the source electrode metal
does not produce dissolved atomic hydrogen in silica from water molecules. The
semiconductor device of claim 15, wherein the shift in the threshold voltage of the
MOSFET device results from bias temperature instability (BTI) in the MOSFET
device when operating the MOSFET device at elevated temperatures, elevated bias, or
both.
18. The semiconductor device of claim 15, wherein the shift in threshold voltage
of the MOSFET device during operation is less than 1 V.
19. The semiconductor device of claim 15, wherein the source electrode is
comprised of a combination of metal layers.
MANISHA SINIGH NAIR
Agent for the Applicant [IN/PA-7401
LEX ORBIS
Intellectual Property Practice
70917 10, Tolstoy House,
15- 17, Tolstoy Marg,
New Delhi- 1 1000 1

Documents

Application Documents

# Name Date
1 2267-del-2013-Correspondence-Others-(06-08-2013).pdf 2013-08-06
1 2267-DEL-2013-FORM 4 [20-12-2024(online)].pdf 2024-12-20
1 2267-DEL-2013-IntimationOfGrant30-10-2023.pdf 2023-10-30
2 2267-del-2013-GPA.pdf 2014-02-19
2 2267-DEL-2013-IntimationOfGrant30-10-2023.pdf 2023-10-30
2 2267-DEL-2013-PatentCertificate30-10-2023.pdf 2023-10-30
3 2267-DEL-2013-CLAIMS [27-12-2019(online)].pdf 2019-12-27
3 2267-del-2013-Form-5.pdf 2014-02-19
3 2267-DEL-2013-PatentCertificate30-10-2023.pdf 2023-10-30
4 2267-del-2013-Form-3.pdf 2014-02-19
4 2267-DEL-2013-DRAWING [27-12-2019(online)].pdf 2019-12-27
4 2267-DEL-2013-CLAIMS [27-12-2019(online)].pdf 2019-12-27
5 2267-del-2013-Form-2.pdf 2014-02-19
5 2267-DEL-2013-FER_SER_REPLY [27-12-2019(online)].pdf 2019-12-27
5 2267-DEL-2013-DRAWING [27-12-2019(online)].pdf 2019-12-27
6 2267-del-2013-Form-1.pdf 2014-02-19
6 2267-DEL-2013-FORM 3 [27-12-2019(online)].pdf 2019-12-27
6 2267-DEL-2013-FER_SER_REPLY [27-12-2019(online)].pdf 2019-12-27
7 2267-DEL-2013-Information under section 8(2) (MANDATORY) [27-12-2019(online)].pdf 2019-12-27
7 2267-DEL-2013-FORM 3 [27-12-2019(online)].pdf 2019-12-27
7 2267-del-2013-Drawings.pdf 2014-02-19
8 2267-del-2013-Description (Complete).pdf 2014-02-19
8 2267-DEL-2013-Information under section 8(2) (MANDATORY) [27-12-2019(online)].pdf 2019-12-27
8 2267-DEL-2013-OTHERS [27-12-2019(online)].pdf 2019-12-27
9 2267-del-2013-Correspondence-others.pdf 2014-02-19
9 2267-DEL-2013-OTHERS [27-12-2019(online)].pdf 2019-12-27
9 2267-DEL-2013-PETITION UNDER RULE 137 [27-12-2019(online)].pdf 2019-12-27
10 2267-del-2013-Claims.pdf 2014-02-19
10 2267-DEL-2013-FORM 4(ii) [02-09-2019(online)].pdf 2019-09-02
10 2267-DEL-2013-PETITION UNDER RULE 137 [27-12-2019(online)].pdf 2019-12-27
11 2267-DEL-2013-AMENDED DOCUMENTS [07-08-2019(online)].pdf 2019-08-07
11 2267-del-2013-Assignment.pdf 2014-02-19
11 2267-DEL-2013-FORM 4(ii) [02-09-2019(online)].pdf 2019-09-02
12 2267-del-2013-Abstract.pdf 2014-02-19
12 2267-DEL-2013-AMENDED DOCUMENTS [07-08-2019(online)].pdf 2019-08-07
12 2267-DEL-2013-FORM 13 [07-08-2019(online)].pdf 2019-08-07
13 Other Document [08-07-2016(online)].pdf 2016-07-08
13 2267-DEL-2013-RELEVANT DOCUMENTS [07-08-2019(online)].pdf 2019-08-07
13 2267-DEL-2013-FORM 13 [07-08-2019(online)].pdf 2019-08-07
14 2267-DEL-2013-FER.pdf 2019-03-29
14 2267-DEL-2013-RELEVANT DOCUMENTS [07-08-2019(online)].pdf 2019-08-07
14 Form 18 [08-07-2016(online)].pdf 2016-07-08
15 2267-DEL-2013-FER.pdf 2019-03-29
15 Form 13 [08-07-2016(online)].pdf 2016-07-08
16 2267-DEL-2013-FER.pdf 2019-03-29
16 Form 13 [08-07-2016(online)].pdf 2016-07-08
16 Form 18 [08-07-2016(online)].pdf 2016-07-08
17 Form 18 [08-07-2016(online)].pdf 2016-07-08
17 Other Document [08-07-2016(online)].pdf 2016-07-08
17 2267-DEL-2013-RELEVANT DOCUMENTS [07-08-2019(online)].pdf 2019-08-07
18 2267-DEL-2013-FORM 13 [07-08-2019(online)].pdf 2019-08-07
18 Other Document [08-07-2016(online)].pdf 2016-07-08
18 2267-del-2013-Abstract.pdf 2014-02-19
19 2267-del-2013-Abstract.pdf 2014-02-19
19 2267-DEL-2013-AMENDED DOCUMENTS [07-08-2019(online)].pdf 2019-08-07
19 2267-del-2013-Assignment.pdf 2014-02-19
20 2267-del-2013-Assignment.pdf 2014-02-19
20 2267-del-2013-Claims.pdf 2014-02-19
20 2267-DEL-2013-FORM 4(ii) [02-09-2019(online)].pdf 2019-09-02
21 2267-DEL-2013-PETITION UNDER RULE 137 [27-12-2019(online)].pdf 2019-12-27
21 2267-del-2013-Correspondence-others.pdf 2014-02-19
21 2267-del-2013-Claims.pdf 2014-02-19
22 2267-del-2013-Correspondence-others.pdf 2014-02-19
22 2267-del-2013-Description (Complete).pdf 2014-02-19
22 2267-DEL-2013-OTHERS [27-12-2019(online)].pdf 2019-12-27
23 2267-del-2013-Description (Complete).pdf 2014-02-19
23 2267-del-2013-Drawings.pdf 2014-02-19
23 2267-DEL-2013-Information under section 8(2) (MANDATORY) [27-12-2019(online)].pdf 2019-12-27
24 2267-del-2013-Form-1.pdf 2014-02-19
24 2267-DEL-2013-FORM 3 [27-12-2019(online)].pdf 2019-12-27
24 2267-del-2013-Drawings.pdf 2014-02-19
25 2267-DEL-2013-FER_SER_REPLY [27-12-2019(online)].pdf 2019-12-27
25 2267-del-2013-Form-1.pdf 2014-02-19
25 2267-del-2013-Form-2.pdf 2014-02-19
26 2267-DEL-2013-DRAWING [27-12-2019(online)].pdf 2019-12-27
26 2267-del-2013-Form-2.pdf 2014-02-19
26 2267-del-2013-Form-3.pdf 2014-02-19
27 2267-DEL-2013-CLAIMS [27-12-2019(online)].pdf 2019-12-27
27 2267-del-2013-Form-3.pdf 2014-02-19
27 2267-del-2013-Form-5.pdf 2014-02-19
28 2267-del-2013-Form-5.pdf 2014-02-19
28 2267-del-2013-GPA.pdf 2014-02-19
28 2267-DEL-2013-PatentCertificate30-10-2023.pdf 2023-10-30
29 2267-del-2013-Correspondence-Others-(06-08-2013).pdf 2013-08-06
29 2267-del-2013-GPA.pdf 2014-02-19
29 2267-DEL-2013-IntimationOfGrant30-10-2023.pdf 2023-10-30
30 2267-del-2013-Correspondence-Others-(06-08-2013).pdf 2013-08-06
30 2267-DEL-2013-FORM 4 [20-12-2024(online)].pdf 2024-12-20

Search Strategy

1 Search_2267DEL2013_24-12-2018.pdf
1 Search_2_2267del2013_29-03-2019.pdf
2 Search_2267DEL2013_24-12-2018.pdf
2 Search_2_2267del2013_29-03-2019.pdf

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