Abstract: An electric component (1) comprising a sensor and/or actuator chip with a substrate (2) on which a passivating layer (3) and senor and/or actuator structure consisting of an active surface area (5a,5b) is arranged. The chip is surrounded by an encapsulation (6) having an opening (7) which forms an access to the at least one active surface area (5a, 5b). A layer stack is arranged on the substrate (2), said stack of layers comprising from the passivating layer (3) to the substrate (2) at least one first strip conductor layer (15), a first electric insulating layer (14), a second strip conductor layer (17) and a second electric insulating layer (16). The first conductor strip layer (15) is fully arranged outside the area of the chip covered by the opening (7). At least one conductor strip of the second conductor strip layer (15) is connected to the sensor and/or actuator structure.
ELECTRICAL COMPONENT
[0001] The invention relates to an electrical component having a sensor and/or actuator
chip, in particular a CMOS chip, that has a substrate on which a passivation layer and at
least one structure that has at least one active surface area for a sensor and/or actuator are
located, and the chip is surrounded by an encapsulation that has at least one opening that
forms an access to the active surface area, of which at least one is present, and to the
passivation layer, and in the opening the chip has an interaction surface that extends, at
least in some areas, over the passivation layer and the active surface area and that in the
operating position is in contact with a liquid or viscous medium, and a first electrical
insulation layer is provided between the passivation layer and the substrate, and a first
conductor track layer is located in some areas between the passivation layer and the first
insulation layer, and a second electrical insulation layer is provided between the first
insulation layer and the substrate, and a second conductor track layer is located between the
first insulation layer and the second insulation layer, and at least one of the conductor
tracks is connected to the sensor and/or actuator structure.
[0002] An electrical component of this type is known from actual practice. It has a
CMOS chip with a semiconductor substrate into which an ion-sensitive field effect
transistor (ISFET) is integrated. The sensor has an active surface area that is configured as
a gate electrode and that can be brought into contact with a liquid medium in order to detect
ions contained in this medium. A plurality of conductor track layers made of aluminum, in
which the conductor tracks and/or sections of conductor tracks extend, are located on the
substrate. Conductor track sections of conductor tracks that extend across to a plurality of
conductor track layers are connected to each other by means of through-contacts. An
electrical insulation layer is provided between each of the conductor track layers as well as
between the lowermost conductor track layer, which is located closest to the substrate, and
the substrate. A passivation layer is located as a cover layer on the stack of layers
comprising the conductor track layers and the insulation layers. The circuit tracks connect
the drain and source of the ISFET with bond pads that are spaced apart from the drain and
source and are located on the surface of the CMOS chip.
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[0003] The CMOS chip is encapsulated with a plastic casting compound that is in close
contact with the chip and that has an opening that is connected to the active surface area
and into which the liquid medium may be filled. Thus, the medium [typo in German]
comes into contact with the chip at an interaction surface that extends across a part of the
passivation later and the active surface area. The conductor track layers and the insulation
layers in each case extend into the area of the chip that is covered by the interaction surface.
The passivation layer and the insulation layers serve as corrosion protection for the circuit
track layers in order to prevent the circuit track layers from coming into contact with the
liquid medium. However, it has been found in actual practice that the passivation layer
only provides limited corrosion protection for the conductor track layers, and that the chips
only have a relatively short service life when the opening is filled with a liquid or viscous
medium. If a conductor track comes into contact with the medium, for example due to a
defect in the passivation layer, the entire chip can fail.
[0004] A semiconductor chip that has a silicon substrate on which an array having 16
approximately rectangular electrodes is disposed as disclosed in F. FaBbender et. al.,
Optimization of passivation layers for corrosion protection of silicon-based microelectrode
arrays, Sensors and Actuators B 68 (2000), p. 128-133. The electrodes are connected to
bond pads by means of conductor tracks located in a single conductor track layer. The
conductor track layer is covered by a passivation layer. When the chip is manufactured, a
silicon dioxide layer is generated on the semiconductor substrate with the aid of a
heat-treating process. Trench-like recesses are imparted in this layer at the locations at
which the conductor tracks will later be present. A metal that forms the circuit tracks is
deposited in these recesses. The recessed arrangement of the conductor tracks in the silicon
dioxide layer causes the chip to have an essentially flat surface. The purpose of these is to
prevent mechanical stresses in the passivation layer, which can lead to cracks through
which an analyte that is to be analyzed using the electrodes can come into contact with the
conductor track layer and can cause corrosion on the conductor track layer. The corrosion
resistance of the chip can be improved with this measure, and thus the service life of the
chip can be extended. However, placing the trenches in the silicon dioxide layer located on
the substrate results in a substantial additional expense in the manufacturing of the chip, in
particular with a CMOS process.
{WO347298.1} - 2 -
[0005] The object of the invention is therefore to provide an electrical component of the
type referred to above that can be manufactured in a cost-effective manner using the
standard semiconductor manufacturing processes but that permits good corrosion
resistance as well as long service life.
[0006] This object is achieved by the elements of patent claim 1.
[0007] In the invention, at least those areas of the first conductor track layer adjacent to
the passivation layer that carry an electrical potential or that are necessary for the electrical
operation of the component are located completely outside of the area of the chip that is
covered by the interaction surface. In the area of the chip that is covered by the interaction
surface, in addition to the passivation layer at least the first insulation layer is then located
between the uppermost conductor track layer that has the least distance to the opening or to
the liquid or viscous medium contained in it and the conductor track layer that is used for
the electrical operation of the component, whereby the corrosion resistance is significantly
improved compared with a chip in which only the passivation layer is provided between
the uppermost conductor track layer and the liquid or viscous medium. Inside of the area of
the chip that is covered by the interaction surface, at least one electrically insulated,
floating partial area of the first conductor track layer, which is not used to carry electrical
voltage and/or current and therefore is not significant to the electrical operation of the
component, may optionally be located. When the chip is manufactured, after the conductor
track, of which there is at least one, of the second conductor track layer is produced, the
first insulation layer is produced on or applied to the chip and after that the first conductor
track layer and the passivation layer are produced on the chip or are applied to it. The
surface structure caused by the contour of the conductor track, of which there is at least one,
on the boundary surface of the insulation layer that is distant from the conductor track is
already significantly flatter and smoother compared with the contour of the conductor track
of the second conductor track layer. This surface structure is smoothed even more by the
passivation layer, so that the passivation layer has a surface that is for the most part flat and
free from abrupt steps or shoulders. This significantly reduces the risk that cracks will form
in the passivation layer when mechanical stresses are present in the chip. The component of
the invention therefore achieves good corrosion resistance and a long service life. The
component chip can be manufactured economically using standard semiconductor
{WO347298.1} - 3 -
manufacturing processes. Providing trenches in the chip surface, which is a complicated
and expensive undertaking, is not necessary. The passivation layer may be comprised of a
plurality of layers, each of which may be made of various materials. This results in even
better corrosion protection. The electrical component may also be a gas sensor in which the
liquid medium that comes into contact with the interaction surface is, for example, a
2-3-nanometer-thick moist layer.
[0008] The object of the invention recited above is also achieved with the elements of
patent claim 2.
[0009] In the invention, at least in the area of the first conductor track layer that is
covered by the interaction surface, the distances between the electrically conductive layer
areas of this conductor track layer that are laterally adjacent to each other and spaced apart
from each other are in each case less than 1.2 times the thickness of the conductor track
layer. This ensures in a simple way that the surface of the passivation layer that is located
on the first conductor track layer and that in the operating position is in contact with the
liquid or viscous medium is for the most part flat in the areas that cover the spacings
between areas of the first conductor track layer. This significantly reduces the risk that
cracks will form in the passivation layer went mechanical stresses are present in the chip.
The electrical component of the invention therefore has good corrosion resistance and a
long service life. The component chip can be manufactured economically using standard
semiconductor manufacturing processes. The interaction surface that is provided for
contact with the medium preferably extends across the entire surface area of the chip that is
covered by the opening of the encapsulation.
[0010] In a preferred embodiment of the invention, the distances between the laterally
adjacent areas of this conductor track layer in each case are less than 1.1 times the
thickness of the first conductor track layer, in particular less than 1.0 times, possibly less
than 0.9 times, and preferably less than 0.8 times this thickness, at the least in the area of
the first conductor track layer covered by the interaction surface. In this case, the electric
component makes even better corrosion resistance possible.
[0011] When the second conductor track layer has at least two electrically conducting
layer areas that are laterally spaced apart from each other, it is advantageous if, at least in
the area of the first conductor track layer covered by the interaction surface, the distances
{WO347298.1} - 4 -
between the laterally adjacent areas of this circuit track layer are each less than 1.2 times
the thickness of the second conductor track layer, in particular less than 1.1 times, in some
cases less than 1.0 times, possibly less than 0.9 times, and preferably less than 0.8 times
this thickness. This makes the surface of the passivation layer even flatter, which reduces
further the risk that a crack will form in the passivation layer when mechanical stresses are
present in the chip. Therefore, the electrical component has an even longer service life.
[0012] It is advantageous for the first conductor track layer to be made of metal,
preferably of aluminum, and for the second conductor track layer to be made of a doped
semiconductor material, preferably polysilicon. The conductor tracks that are made of
aluminum have good electrical conductivity. Since aluminum has relatively low corrosion
resistance, the first conductor track layer, which is close to the surface, is only provided
outside of the area of the chip covered by the interaction surface, and it is located at a
distance to this area. Within the area of the chip covered by the interaction surface, only the
conductor track layer(s) that is (are) made of polysilicon is (are) used to locate the
conductor tracks. The chip therefore has even better corrosion resistance to a liquid or
viscous medium located in the opening. Outside of the chip area that is covered by the
interaction surface, the polysilicon conductor tracks may be connected to the aluminum
conductor tracks. At least one additional conductor track layer of metal and the least one
insulation layer allocated to this conductor track layer may perhaps be disposed between
the first conductor track layer and the second conductor track layer, in other words, the
second conductor track layer does not necessarily need to be the conductor track layer that
is second from the top, and the second insulation layer does not necessarily need to be the
installation layer that is second from the top of the sensor and/or actuator chip.
[0013] In a preferred embodiment of the invention, a structure for an electronic switch,
in particular for an evaluation device, is disposed on the substrate outside of the area
covered by the opening, and said structure is electrically connected to the sensor and/or
actuator structure by means of at least one of the conductor track layers. The switching
apparatus that is comprised of the electronic circuit and the sensor and/or actuator then
allows particularly compact dimensions. Moreover, the switching apparatus may be
manufactured economically in standard production using semiconductor manufacturing
methods.
{WO347298.1} - 5 -
[0014] Examples of embodiments of the invention are explained further below based on
the drawing. The drawing shows:
[0015] Fig. 1 is a partial cross-sectional view through a first example of an embodiment
of the electrical component of the invention, and
[0016] Fig. 2 shows a partial cross-sectional view through a second example of an
embodiment of the component of the invention.
[0017] An electrical component that is identified in its entirety in Fig. 1 by the reference
number 1 has a sensor chip, which has a semiconductor substrate 2 of p-doped silicon, on
which structures for sensors are disposed. As a cover layer, the sensor chip has a
passivation layer 3 that is preferably comprised of silicon nitride and silicon oxide and that
can be several 100 nm to a few urn thick. A sensor structure shown on the left side of Fig. 1
has a precious metal electrode 4a with an active surface area 5a, and a sensor structure
shown on the right side in Fig. 1 has a silicon nitride layer 4b with an active surface area 5b.
The chip is surrounded by an encapsulation 6 that is formed by a casting compound and
that is only partially shown in Figs. 1 and 2. The encapsulation has an opening 7 which
forms an access to the active surface areas 5a, 5b. At least the edge of the encapsulation 6
that surrounds the opening contacts the chip and performs a sealing function. A liquid or
viscous medium 8 that is to be tested and that contacts the chip at an interaction surface that
corresponds to the entire free surface area of the chip 1 that is shown in the embodiment
example shown in Fig. 1 and that covers the opening can be placed in the opening 7.
However, it is also conceivable that the interaction surface only extends across part of the
surface area of the chip 1 that is covered by the opening 7, for example when the chip is
only partially immersed in a liquid medium 8.
[0018] In the example of the embodiment shown in Fig. 1, the electrode 4a is disposed
on a field oxide layer 9 provided on the substrate 2. The electrode 4b is configured as a gate
electrode disposed adjacent to a channel area 10 of a field effect transistor (FET). The
channel area 10 is formed between a p+ source 11 and a p+ drain of the field effect
transistor in an n- doped area 13 that is recessed into the substrate 2. In Fig. 1 one can see
that the source 11 and the drain 12 are located in area 13. On both sides of the channel area
10 the field oxide layer 9 is located on the source 11 and on the drain 12. The field oxide
{WO347298.1} -6-
layer 9 has an interruption in the vicinity of the channel area 10. This is bypassed by the
electrode 4b.
[0019] A first electrical insulation layer 14 is located between the passivation layer 3
and the substrate 2. It constitutes an inter-metallic dielectric (IMD). In some areas between
the passivation layer 3 and the first insulation layer 14, a first conductor track layer 15,
which is made of aluminum, is provided. The first conductor track layer 15 has a plurality
of areas configured as conductor tracks. An inter-layer dielectric (ILD), which serves as a
second electrical insulation layer 16, is located between the first insulation layer 14 and the
substrate 2.
[0020] A second conductor track layer 17 is provided between the first insulation layer
14 and the second insulation layer 16. It is made of aluminum and has areas configured as
conductor tracks. As can be seen in Fig. 1, a first conductor track of the second conductor
track layer 17 is connected to the n-doped area 13, a second conductor track is connected to
the source 11, and a third conductor track is connected to the drain 12. Interruptions are
provided in the second insulation layer 16 and the field oxide layer. They are interspersed
in each case with a section of the conductor tracks. The first insulation layer 14 and the
second insulation layer 16 have interruptions 18 on the active surface areas 5a, 5b, of the
electrodes 4a, 4b. These interruptions communicate with the opening 7 in the
encapsulation 6. The second conductor track layer 17 is laterally spaced apart from the
interruptions 18 by the insulation layers 14, 16, and is sealed relative to said insulation
layers. The passivation layer 3 is interspersed with the interruptions 18.
[0021] In Fig. 1 one can see that the first conductor track layer 15 is located completely
outside of the area of the chip that is covered by the opening 7 in the encapsulation 6.
Moreover, the first conductor track layer 15 is laterally separated from the interruptions 18
by the first insulation layer 14 and by the passivation layer 3 and is sealed relative to said
interruptions. It can be clearly seen that the first conductor track layer 15 in the area of the
chip covered by the opening is spaced apart from the opening 7, in a direction that is
normal to the plane of extension of the chip, by the passivation layer 3 and the first
insulation layer 14 located beneath it. Good corrosion resistance is thereby achieved for the
first conductor track layer 15 relative to the medium 8 located in the opening 7. The surface
of the passivation layer 3 that borders the opening 7 is largely flat in the areas that are
{WO347298.1} - 7 -
separated by the interruptions 18, so that the risk of a crack forming in the passivation layer
3 is reduced accordingly when mechanical stresses occur in the chip. A shoulder 19 in the
passivation layer 3 caused by the first conductor track layer 15 on an area of the surface of
the passivation layer 3 facing away from the substrate 2 is covered by the encapsulation 6
and is separated laterally from the opening 7. Thus, if a crack in the passivation layer
happens to form at the shoulder 19, the second conductor track layer 17 is largely sealed off
from the opening 17 by the encapsulation 6 and is thus protected from corrosion caused by
the medium 8.
[0022] The electric component 1 shown in Fig. 1 therefore has a sensor and/or actuator
chip with a substrate 2 on which a passivation layer 3 and a sensor and/or actuation
structure having an active surface region 5a, 5b are disposed. The chip is surrounded by an
encapsulation 6 that has an opening 7 that forms an access to the active surface area 5a, 5b,
of which there is at least one. A stack of layers is located on the substrate 2; beginning with
the passivation layer 3 and extending to the substrate 3, it has at least one first conductor
track layer 15, one first electrical insulation layer 14, one second conductor track layer 17,
and one second electrical insulation layer 16. The first conductor track layer 15 is located
completely outside the area of the chip that is covered by the opening 7. At least one
conductor track of the second conductor track layer 15 is connected to the sensor and/or
actuator structure.
[0023] In the example of an embodiment shown in Fig. 2, a field effect transistor having
a source 11, a drain 12, and the channel area 10 is integrated into the substrate 2. Adjacent
to the channel area 10 the field effect transistor has a gate electrode 4c with an active
surface area 5c. With the aid of the field effect transistor it is possible, for example, to
detect ions located in a medium 8 that is present in the opening and that is in contact with
the gate electrode 4c. A field oxide layer 9, which has an interruption that is adjacent to the
channel area 10 and that is bypassed by the gate electrode 4c, is located at the source 11 and
at the drain 12.
[0024] In this example of an embodiment a first electrical insulation layer 14 is also
located between the passivation layer 3 and the substrate 2. It constitutes an inter-metallic
dielectric (IMD). A first conductor track layer 15, which is made of aluminum and has a
plurality of electrically conductive layer areas 15a, 15b, 15c, is provided in some areas
{WO347298.1} - 8 -
between the passivation layer 3 and the first insulation layer 14. The layer areas 15a, 15b
are configured as conductor tracks. Layer area 15c is not used as a conductor track. In the
area of the first conductor track layer 15 that is covered by the opening 7 and the
passivation layer 3, the distances a between the layer areas 15a, 15b, 15c, which are
laterally adjacent to each other, in each case are less than the thickness of the conductor
tracklayer 15.
[0025] An inter-layer dielectric (ILD), which functions as a second electrical insulation
layer 16, is disposed between the first insulation layer 14 and in the substrate 2. A second
conductor track layer 17, which is made of aluminum, is disposed in some areas between
the first insulation layer 14 and the second insulation layer 16. The second conductor track
layer 17 and the first insulation layer 14 are interspersed with the interruption 18. The
second insulation layer 17 ends at a distance to the interruption 18 and is sealed off from
the interruption 18 by the first insulation layer 14 and the second insulation layer 16.
[0026] The second conductor track layer 17 has a plurality of electrically conductive
layer areas 17a, 17b, 17c. Layer areas 17a, 17b are configured as conductor tracks, while
layer area 17c is not used as a conductor track. In the area of the second conductor track
layer 17 covered by the opening 7 and the passivation layer 3, the distances b between the
laterally adjacent layer areas 17a, 17b, 17c are each less than the thickness of the conductor
track layer 17. This thickness more or less corresponds to the thickness of the first
electrical insulation layer 14, the first conductor track layer 15, and the passivation layer 3.
Because of the small lateral distances a, b between the layer areas 15a, 15b, 15c of the first
conductor track layer 15 or the layer areas 17a, 17b, 17c of the second conductor track
layer 17, the areas of the surface of the passivation layer 3, which correspond to the
orthogonal projection of the spaces between the layer areas 15a, 15b, 15c, 17a, 17b, 17c of
a conductor track layer 15, 17, which are arranged adjacent to each other, are largely flat.
As a consequence, the risk that a crack will form in the passivation layer 3 when
mechanical stresses are present in the chip is reduced accordingly.
[0027] A third electrical insulation layer 20, which is embodied as an oxide layer, is
disposed between the second insulation layer 16 and the field oxide layer 9. In some areas a
third conductor track layer 21, which is comprised of a polysilicon layer and which forms
conductor tracks, is located between this insulation layer and the second insulation layer 16.
{WO347298.1} - 9 -
A fourth conductor track layer 22 is located between the third insulation layer 20 and the
field oxide layer 9. It is also made of a polysilicon layer 22 and has further electrical
conductor tracks.
[0028] It must also be noted that the conductor tracks in conductor track layers 15, 17,
21, 22 may be connected to each other by means of through-contacts. The substrate 2 may
also be made of glass.
{WO347298.1} -10-
Claims
1. An electrical component (1) having a sensor and/or actuator chip, in
particular a CMOS chip, that has a substrate (2) on which a passivation layer (3) and at
least one structure that has at least one active surface area (5a, 5b, 5c) for a sensor and/or
actuator is located, and the chip is surrounded by an encapsulation (6) that has at least one
opening (7) that forms an access to the active surface area (5a, 5b, 5c), of which at least one
is present, and to the passivation layer (3), and in the opening the chip has an interaction
surface that extends, at least in some areas, over the passivation layer (3) and the active
surface area (5a, 5b, 5c) and that in the operating position is in contact with a liquid or
viscous medium, and a first electrical insulation layer (14) is provided between the
passivation layer (3) and the substrate (2), and a first conductor track layer (15) that has at
least one area that is configured as a conductor track is located in some areas between the
passivation layer (3) and the first insulation layer (14), and a second electric insulation
layer (16) is provided between the first insulation layer (14) and the substrate (2), and a
second conductor track layer (17) that has at least one area that is configured as a conductor
track is located between the first insulation layer (14) and the second insulation layer (16),
and at least one of the conductor tracks is connected to the sensor and/or actuator structure,
wherein at least the areas of the first conductor track layer (15) that carry an electrical
potential is [sic: are] located completely outside of the area of the chip covered by the
interaction surface.
2. An electrical component (1) having a sensor and/or actuator chip, in
particular a CMOS chip, that has a substrate (2) on which a passivation layer (3) and at
least one structure that has at least one active surface area (5a, 5b, 5c) for a sensor and/or
actuator is located, and the chip is surrounded by an encapsulation (6) that has at least one
opening (7) that forms an access to the active surface area (5a, 5b, 5c), of which at least one
is present, and to the passivation layer (3), and in the opening the chip has an interaction
surface that extends, at least in some areas, over the passivation layer (3) and the active
surface area (5a, 5b, 5c) and that in the operating position is in contact with a liquid or
viscous medium, and a first electrical insulation layer (14) is provided between the
{WO347298.1} - 11 -
passivation layer (3) and the substrate (2), and a first conductor track layer (15) that has at
least two laterally separated electrically conductive layer areas (15a, 15b, 15c) is is located
in some areas between the passivation layer (3) and the first insulation layer (14), and a
second electrical insulation layer (16) is provided between the first insulation layer (14)
and the substrate (2), and a second conductor track layer (17) is located between the first
insulation layer (14) and the second insulation layer (16), wherein at least in the area of the
first conductor track layer (15) that is covered by the interaction surface the distances (a)
between the laterally adjacent, electrically conductive layer areas (15a, 15b, 15c) in each
case are smaller that 1.2 times the thickness of this conductor track layer (15).
3. The electrical component (1) of claim 2, wherein, at the least in the
area of the first conductor track layer (15) covered by the interaction surface, the distances
(a) between the laterally adjacent areas (15a, 15b, 15c) of this conductor track layer (15) in
each case are less than 1.1 times the thickness of the first conductor track layer (15), in
particular less than 1.0 times, possibly less than 0.9 times, and preferably less than 0.8
times this thickness.
4. The electrical component (1) of one of claims 1 to 3, wherein the
second conductor track layer (17) has at least two laterally separated electrically
conductive layer areas (17a, 17b, 17c), at the least in the area of the second conductor track
layer (17) covered by the interaction surface, the distances (b) between the laterally
adjacent areas (17a, 17b, 17c) of this conductor track layer (17) in each case are less than
1.2 times the thickness of the first conductor track layer (17), in particular less than 1.1
times, in some cases less than 1.0 times, possibly less than 0.9 times, and preferably less
than 0.8 times this thickness.
5. The electrical component (1) of one of claims 1 to 4, wherein the
first conductor track layer is comprised of metal, preferably aluminum, and the second
conductor track layer is comprised of a doped semiconductor material, preferably
polysilicon.
{WO347298.1} - 12 -
6. The (1) electrical component (1) of one of claims 1 to 5, wherein a
structure for an electronic circuit, in particular a structure for an evaluation device, is
located on the substrate (2) outside of the area covered by the opening (7), and said
structure is electrically connected to the sensor and/or actuator structure by means of at
least one of the conductor track layers (15,17).
{WO347298.1} - 13 -
An electric component (1) comprising a sensor and/or actuator chip with a substrate (2)
on which a passivating layer (3) and senor and/or actuator structure consisting of an
active surface area (5a,5b) is arranged. The chip is surrounded by an encapsulation (6)
having an opening (7) which forms an access to the at least one active surface area
(5a, 5b). A layer stack is arranged on the substrate (2), said stack of layers comprising
from the passivating layer (3) to the substrate (2) at least one first strip conductor layer
(15), a first electric insulating layer (14), a second strip conductor layer (17) and a
second electric insulating layer (16). The first conductor strip layer (15) is fully arranged
outside the area of the chip covered by the opening (7). At least one conductor strip of
the second conductor strip layer (15) is connected to the sensor and/or actuator
structure.
| # | Name | Date |
|---|---|---|
| 1 | 1732-KOLNP-2007 CORRESPONDENCE.pdf | 2017-05-03 |
| 1 | abstract-01732-kolnp-2007.jpg | 2011-10-07 |
| 2 | 1732-KOLNP-2007-FIRST EXAMINATION REPORT.pdf | 2016-09-29 |
| 2 | 1732-kolnp-2007-form 18.pdf | 2011-10-07 |
| 3 | 1732-KOLNP-2007_EXAMREPORT.pdf | 2016-06-30 |
| 3 | 1732-KOLNP-2007-CORRESPONDENCE.pdf | 2011-10-07 |
| 4 | 1732-KOLNP-2007-(24-02-2014)-ABANDONED LETTER.pdf | 2014-02-24 |
| 4 | 01732-kolnp-2007-priority document.pdf | 2011-10-07 |
| 5 | 01732-kolnp-2007-pct request form.pdf | 2011-10-07 |
| 5 | 01732-kolnp-2007-abstract.pdf | 2011-10-07 |
| 6 | 01732-kolnp-2007-international search report.pdf | 2011-10-07 |
| 6 | 01732-kolnp-2007-claims.pdf | 2011-10-07 |
| 7 | 01732-kolnp-2007-international publication.pdf | 2011-10-07 |
| 7 | 01732-kolnp-2007-correspondence others 1.1.pdf | 2011-10-07 |
| 8 | 01732-kolnp-2007-gpa.pdf | 2011-10-07 |
| 8 | 01732-kolnp-2007-correspondence others 1.2.pdf | 2011-10-07 |
| 9 | 01732-kolnp-2007-correspondence others 1.3.pdf | 2011-10-07 |
| 9 | 01732-kolnp-2007-form 5.pdf | 2011-10-07 |
| 10 | 01732-kolnp-2007-correspondence others 1.4.pdf | 2011-10-07 |
| 10 | 01732-kolnp-2007-form 3.pdf | 2011-10-07 |
| 11 | 01732-kolnp-2007-correspondence others.pdf | 2011-10-07 |
| 11 | 01732-kolnp-2007-form 2.pdf | 2011-10-07 |
| 12 | 01732-kolnp-2007-description complete.pdf | 2011-10-07 |
| 12 | 01732-kolnp-2007-form 1.pdf | 2011-10-07 |
| 13 | 01732-kolnp-2007-drawings.pdf | 2011-10-07 |
| 14 | 01732-kolnp-2007-description complete.pdf | 2011-10-07 |
| 14 | 01732-kolnp-2007-form 1.pdf | 2011-10-07 |
| 15 | 01732-kolnp-2007-correspondence others.pdf | 2011-10-07 |
| 15 | 01732-kolnp-2007-form 2.pdf | 2011-10-07 |
| 16 | 01732-kolnp-2007-correspondence others 1.4.pdf | 2011-10-07 |
| 16 | 01732-kolnp-2007-form 3.pdf | 2011-10-07 |
| 17 | 01732-kolnp-2007-form 5.pdf | 2011-10-07 |
| 17 | 01732-kolnp-2007-correspondence others 1.3.pdf | 2011-10-07 |
| 18 | 01732-kolnp-2007-correspondence others 1.2.pdf | 2011-10-07 |
| 18 | 01732-kolnp-2007-gpa.pdf | 2011-10-07 |
| 19 | 01732-kolnp-2007-international publication.pdf | 2011-10-07 |
| 19 | 01732-kolnp-2007-correspondence others 1.1.pdf | 2011-10-07 |
| 20 | 01732-kolnp-2007-international search report.pdf | 2011-10-07 |
| 20 | 01732-kolnp-2007-claims.pdf | 2011-10-07 |
| 21 | 01732-kolnp-2007-pct request form.pdf | 2011-10-07 |
| 21 | 01732-kolnp-2007-abstract.pdf | 2011-10-07 |
| 22 | 1732-KOLNP-2007-(24-02-2014)-ABANDONED LETTER.pdf | 2014-02-24 |
| 22 | 01732-kolnp-2007-priority document.pdf | 2011-10-07 |
| 23 | 1732-KOLNP-2007_EXAMREPORT.pdf | 2016-06-30 |
| 23 | 1732-KOLNP-2007-CORRESPONDENCE.pdf | 2011-10-07 |
| 24 | 1732-kolnp-2007-form 18.pdf | 2011-10-07 |
| 24 | 1732-KOLNP-2007-FIRST EXAMINATION REPORT.pdf | 2016-09-29 |
| 25 | 1732-KOLNP-2007 CORRESPONDENCE.pdf | 2017-05-03 |
| 25 | abstract-01732-kolnp-2007.jpg | 2011-10-07 |