Specification
Title of Invention: Electrode assembly and manufacturing method thereof
technical field
[One]
This application claims the benefit of priority based on Korean Patent Application No. 10-2019-0153475 on November 26, 2019, and all contents disclosed in the documents of the corresponding Korean patent applications are incorporated as a part of this specification.
[2]
The present invention relates to an electrode assembly and a method for manufacturing the same, and more particularly, to an electrode assembly manufacturing method and manufacturing method capable of solving problems occurring when attaching the fixing tape by eliminating the conventional fixing tape. It relates to an electrode assembly that can be manufactured.
[3]
background
[4]
A battery for storing electrical energy may be generally divided into a primary battery and a secondary battery. A primary battery is a disposable consumable battery, whereas a secondary battery is a rechargeable battery manufactured using a material in which oxidation and reduction processes between an electric current and a substance are repeatable. That is, when the reduction reaction of the material is performed by the electric current, the power is charged, and when the oxidation reaction is performed on the material, the power is discharged. Such charge-discharge can be repeatedly performed.
[5]
Among various types of secondary batteries, lithium secondary batteries are generally manufactured by mounting an electrode assembly in which a positive electrode, a separator, and an anode are stacked in a case, and lithium ions are produced from the lithium metal oxide of the positive electrode to the negative electrode. As the process of intercalation and deintercalation is repeated, charging and discharging of the lithium secondary battery proceeds.
[6]
In the electrode assembly, a predetermined number of unit cells in which a negative electrode, a separator, and a positive electrode are stacked in a predetermined order are stacked, or a positive electrode, a separator, and a negative electrode are repeatedly stacked one by one to form one electrode assembly. In addition, the electrode assembly is accommodated in a case such as a cylindrical can or a prismatic pouch and manufactured as a secondary battery.
[7]
On the other hand, as a method of manufacturing the electrode assembly, a winding type manufactured by laminating a separator between the negative electrode and the positive electrode and then winding, cutting to have the required width and length, cutting the negative electrode and the positive electrode, and then the negative electrode and the separator , a stack-and-fold type, which is manufactured by stacking anodes so that they are repeated, and a stack-and-fold type, which are manufactured by placing unit cells side by side on a folding separator and then folding from one side, etc. are known.
[8]
In the dual, stacked electrode assembly, as shown in FIG. 1A in which the conventional manufacturing process is simplified, the positive electrode 2, the separator 1, and the negative electrode 3 are stacked by a predetermined number to form a unit cell 10. After being manufactured, the unit cells 10 are stacked by a predetermined number to manufacture the electrode assembly 100 . For reference, in the electrode assembly shown in FIG. 1A, a mono-cell in which a separator/anode/separator/cathode is stacked from the bottom is manufactured as a unit cell 10 and a plurality of stacked doedoe separation membranes/ The half-cell 20 stacked in the electrode (cathode or anode)/separator order is placed on the uppermost layer.
[9]
And, when the unit cells 10 are stacked by a predetermined number, the fixing tape 200 is wound around the electrode assembly 100 so that the electrode assembly 100 is fixed (or the side surfaces are on the upper and lower surfaces) to be bound) to bind the unit cells 10 .
[10]
However, in the structure for binding through the fixing tape 200 in this way, as shown in FIG. 1b , the folding and lifting phenomenon of the separator in the conventional electrode assembly structure occurs, the fixing tape 200 is adhered. There may be a problem in that the end of the separation membrane 1 is folded or lifted by the pressure applied when it is made.
[11]
The folding and lifting of the separator 1 may cause contact between the negative electrode 3 and the positive electrode 2 to cause a short circuit.
[12]
DETAILED DESCRIPTION OF THE INVENTION
technical challenge
[13]
Accordingly, the main object of the present invention is to provide an electrode assembly capable of eliminating the process of additionally adhering a fixing tape after lamination of the electrode assembly is completed, and a method for manufacturing the same, so as to solve the above-described problems.
[14]
means of solving the problem
[15]
The electrode assembly of the present invention for achieving the above object is an electrode assembly in which a negative electrode, a separator, and a positive electrode are repeatedly stacked. ; and the film is characterized in that it is thermally fused to the side formed by laminating a negative electrode, a separator, and a positive electrode. At this time, two or more separation membranes are collected at the ends to form a bonded joint, and the film is thermally bonded to the joint.
[16]
The film is disposed on each of two opposing side surfaces of the side surfaces formed by stacking the negative electrode, the separator, and the positive electrode.
[17]
The film is made of a thermoplastic material that plastically changes when heat and pressure are applied. More specifically, the film is made of a PET (polyethylene terephthalate) material.
[18]
In addition, the present invention additionally provides a manufacturing method capable of manufacturing the electrode assembly having the above configuration. The manufacturing method according to the present invention is a method for manufacturing an electrode assembly in which a negative electrode, a separator, and a positive electrode are repeatedly stacked, and a unit cell having a predetermined stacking structure of a negative electrode, a separator, and a positive electrode is manufactured, but the ends of the separator are bonded together to form a junction part A unit cell manufacturing step (S10) of manufacturing to be formed; A film insertion step of inserting the film into the mold (S20); a unit cell stacking step of stacking the unit cells in the mold (S30); and a heat-sealing step (S40) of heat-sealing the film to the junction of the stacked unit cells by applying heat and pressure within the mold.
[19]
In the film inserting step (S20), two films are inserted so as to abut one by one on both side wall surfaces facing each other in the formwork.
[20]
After the film insertion step (S20), the unit cell stacking step (S30) and the heat sealing step (S40) are repeated until the stacking of the predetermined unit cells is completed.
[21]
Alternatively, after the film insertion step (S20), the unit cell stacking step (S30) is repeated until the stacking of the predetermined unit cells is completed, and when the unit cell stacking step (S30) is completed, the stacked unit cells The heat-sealing step (S40) may be repeated so that the film is heat-sealed to each of them.
[22]
In the unit cell manufacturing step (S10), a unit cell is manufactured as a monocell stacked in the order of a separator/cathode/separator/anode or a monocell stacked in the order of a separator/anode/separator/cathode from the bottom. In addition, in the unit cell manufacturing step (S10), the half-cell stacked in the separator/cathode/separator order from the bottom or the half-cell stacked in the separator/anode/separator order is manufactured as a unit cell separately from the monocell.
[23]
And, while the unit cell stacking step (S30) is repeatedly performed, the stacking is made of mono cells, when the unit cell stacking step (S30) is finally performed, the stacking is made of half cells.
[24]
The film is made of a thermoplastic material that plastically changes when heat and pressure are applied, and in the heat-sealing step (S40), the tip of the iron presses and heats the film at the same time to heat-seal it to the unit cell.
[25]
The mold is configured such that the tip of the iron enters or the iron is built in, so that the film is thermally fused within the mold.
[26]
Effects of the Invention
[27]
The present invention having the configuration as described above uses the fixing tape instead of the tape, and the film is fixed by thermal fusion on the side of the electrode assembly (because a pressure smaller than the pressure generated when the fixing tape is attached is applied), It is possible to prevent the separation membrane from being folded or lifted in the conventional structure.
[28]
In particular, in the present invention, since two or more separators are gathered at the ends to form a junction, and the film is thermally fused at the junction, it is possible to prevent the separator from being folded or deformed during thermal fusion. That is, when thermal fusion is performed, the ends of the separators are bonded to each other to limit movement, and the thickness increases at the point where the junction is formed, thereby increasing the thermal fusion area with the film to increase fixing force.
[29]
In addition, in the present invention, since thermal fusion is performed immediately after the unit cells are stacked and proceeds in the order in which the next unit cells are stacked, or thermal fusion can be performed after all stacking of the unit cells is completed, the manufacturing process according to the conditions of the electrode assembly can provide flexibility.
[30]
And, since the iron enters the inside of the mold in which the unit cells are stacked or the iron is built in, the thermal fusion is performed in the mold, the shaking of the unit cells is prevented during the thermal fusion process, so that the thermal fusion can be performed more stably. .
[31]
Brief description of the drawing
[32]
1A is a simplified view of a conventional electrode assembly manufacturing process;
[33]
1B is a view showing a state in which folding and lifting phenomena of a separator occur in a conventional electrode assembly structure;
[34]
Figure 2 is a flow chart of the electrode assembly manufacturing method of the present invention.
[35]
3 is a view showing a state in which a negative electrode, a separator, and a positive electrode are laminated in the unit cell manufacturing step to be manufactured as a unit cell;
[36]
4A is a view showing a cross-sectional view (a) of a mold in the method for manufacturing an electrode assembly of the present invention and a state in which a film is attached to the mold (b);
[37]
FIG. 4b is a view additionally illustrating a state (c) in which a unit cell is seated between the films within the frame shown in FIG. 4a;
[38]
FIG. 4c is a view additionally showing states (c, d, e) in which the iron joins the junction of the film and the unit cell within the form shown in FIG. 4b;
[39]
5 is a plan view, a front view, and a left side view of an electrode assembly manufactured by the method of manufacturing an electrode assembly of the present invention;
[40]
Modes for carrying out the invention
[41]
Hereinafter, based on the accompanying drawings, the present invention will be described in detail so that those of ordinary skill in the art can easily implement it. However, the present invention may be embodied in various different forms and is not limited to the embodiments described herein.
[42]
In order to clearly describe the present invention, parts irrelevant to the description are omitted, and the same reference numerals are assigned to the same or similar elements throughout the specification.
[43]
In addition, the terms or words used in the present specification and claims should not be construed as being limited to conventional or dictionary meanings, and the inventor appropriately defines the concept of the term in order to best describe his invention. It should be interpreted as meaning and concept consistent with the technical idea of ​​the present invention based on the principle that it can be done.
[44]
The present invention relates to an electrode assembly in which a negative electrode 3, a separator 1, and a positive electrode 2 are repeatedly stacked, and a manufacturing method thereof. Explain.
[45]
[46]
first embodiment
[47]
[48]
The present invention provides a method for manufacturing an electrode assembly as a first embodiment. As described in FIG. 2 showing the sequence of the electrode assembly manufacturing method according to the present invention, the manufacturing method according to this embodiment is a unit cell manufacturing step (S10), a film insertion step (S20), a unit cell stacking step (S30) , including a heat-sealing step (S40).
[49]
In the unit cell manufacturing step (S10), a unit cell 10 having a predetermined stacked structure of the negative electrode 3, the separator 1, and the positive electrode 2 is manufactured, but the ends of the separator 1 are bonded to each other to form a junction ( 1a) is prepared to form.
[50]
That is, as shown in FIG. 3 showing that the cathode 3, the separator 1, and the anode 2 are stacked to form a unit cell 10, a monocell having a predetermined stacking structure and A half cell is prepared as a unit cell. The monocell has a structure in which a separator (1)/anode (2)/separator (1)/cathode (3) is stacked in order from the bottom as shown, or a separator (1)/cathode (3)/ from the bottom The separator (1)/anode (2) may have a stacked structure in the order. In addition, a half cell in which the uppermost electrode (anode or cathode) is removed from the monocell is additionally provided. The half-cell has a structure in which the separator (1)/cathode (3)/separator (1) is stacked in order from the bottom so that the separator (1) is placed on the uppermost layer after lamination of the monocell is completed, or the separator (1)/ It has a structure in which the anode (2)/separator (1) are stacked in the order. Accordingly, since the stacking of the half cells is made after the stacking of the monocells is completed, the electrode assembly stacked according to the present invention has a structure in which the separator is placed on the lowermost layer and the uppermost layer.
[51]
On the other hand, the unit cell 10 made of the mono-cell and half-cell has a structure in which the separator 1 has a larger area than the positive electrode 2 and the negative electrode 3 and the ends protrude from both sides as shown. . In this unit cell manufacturing step (S10), the ends of the separation membranes 1 are bonded to each other to form a junction 1a. The bonding portion 1a does not necessarily have to be formed at all of the protruding ends of the separator 1, but is preferably formed at the ends facing the film 30 when the unit cells 10 are stacked.
[52]
4a to 4c show a cross-sectional view (a) of a mold (M) in the method for manufacturing an electrode assembly of the invention, a state in which the film (3) is attached in the mold (M) (b), and the films in the mold (M) (30) A state in which the unit cell 10 is seated (c) and a state in which the iron (G) bonds the film 30 and the junction part 1a of the unit cell 10 in the form (M) (d) , e) are shown respectively.
[53]
Referring to FIGS. 4A to 4C , in the film inserting step S20 , the films 30 are disposed on both inner peripheral surfaces facing each other within the mold M. The mold (M) is manufactured to a size that allows the stacking of the unit cells 10 therebetween in a state in which the film 30 is disposed, and is manufactured to have sufficient rigidity. The mold (M) may be configured such that the internal space in which the unit cells 10 are stacked is made in a hexahedral shape, and a gripper for transporting and stacking the unit cells 10 when the unit cells 10 are stacked. .
[54]
And, in the form (M), the film 30 may be arranged in a state of being temporarily fixed to the inner circumferential surface of the form (M) so that the vertically erected state is maintained before thermal fusion is performed. That is, the form (M) may be provided with tongs, a holder, etc. for temporarily fixing the film, or the film 30 is a form in which an adhesive having a relatively weak adhesive force is applied to the surface before arrangement. (M) can be placed in. As for the means for temporarily fixing the film 30 , other known methods may be applied if the film 30 can be easily separated from the inner circumferential surface of the mold M after the electrode assembly is manufactured.
[55]
In addition, the mold (M) is a slit (not shown) through which the iron (G) can enter vertically so that the iron (G) can enter when the film (30) and the unit cell (10) are thermally fused. ), etc., may have a structure in which the iron (G) is slidably mounted in the form (M).
[56]
In the state where the film 30 is placed in the mold M and the operation of the iron G is ready, the next unit cell lamination step S30 is performed. In the unit cell stacking step (S30), the unit cells 10 are stacked in the mold M at a fixed position between the two films 30 . In this case, the unit cell 10 is a mono cell as described above, but the stacking is made so that the separator 1 is placed on the lower side.
[57]
Then, a heat-sealing step (S40) of heat-sealing the film 30 to the bonding portion 1a of the stacked unit cells 10 by applying heat and pressure within the mold M is performed.
[58]
In this embodiment, two films 30 are inserted so as to abut one by one on both side wall surfaces facing each other in the form M, and the thermal fusion is simultaneously performed on each of both side wall surfaces of the form M.
[59]
On the other hand, in Figure 4c, after the film insertion step (S20), until the stacking of the predetermined unit cells 10 is completed, if one unit cell 10 is laminated, the unit cell 10 is thermally fused, and It is shown that the unit cell stacking step (S30) and the heat-sealing step (S40) are repeated so that the stacking and thermal fusion of the unit cells 10 of the next sequence are performed.
[60]
However, since there is no change in position between the films 30 in the unit cell 10 within the mold M, after lamination of all unit cells 10 is completed without thermal fusion, the lower layer is From the unit cell 10 of (or from the unit cell of the upper layer) may be manufactured so that the thermal fusion of each unit cell 10 is sequentially made. That is, in the present invention, the order of the unit cell stacking step (S30) and the thermal fusion step (S40) can be changed flexibly.
[61]
And, as described above, while the unit cell stacking step (S30) is repeatedly performed, the stacking is made with mono cells, but when the unit cell stacking step (S30) is finally performed, the stacking is made with half cells. . Accordingly, the electrode assembly manufactured in this way has a structure in which the separator 1 is disposed on the uppermost layer and the lowermost layer.
[62]
Meanwhile, in the present invention, the film 30 is made of a thermoplastic material that undergoes plastic change when heat and pressure are applied. For example, the film may be made of a PET (polyethylene terephthalate) material.
[63]
In the heat-sealing step (S40), the end of the iron (G) presses and heats the film 30 at the same time to heat-seal it to the junction part 1a of the unit cell 10, but the applied temperature and pressure are the film ( 30) may vary depending on the thickness and material or the relative position and size of the joint. At this time, the form (M) is configured such that the end of the iron (G) enters or the iron (G) is built-in as described above, so that the thermal fusion of the film (30) is performed within the form (M).
[64]
[65]
second embodiment
[66]
[67]
The present invention provides an electrode assembly that can be manufactured by the manufacturing method according to the first embodiment as a second embodiment.
[68]
The electrode assembly provided in this embodiment is an electrode assembly in which the negative electrode 3, the separator 1, and the positive electrode 2 are repeatedly stacked, and the negative electrode 3, the separator 1, and the positive electrode 2 are stacked and formed. It includes a film 30 disposed to cover any one of the side surfaces, wherein the film 30 is thermally fused to the side formed by laminating a negative electrode 3, a separator 1, and a positive electrode 2 do it with
[69]
That is, referring to FIG. 5 showing a plan view, a front view, and a left side view of an electrode assembly manufactured by the method of manufacturing an electrode assembly of the present invention, the negative electrode 3 and the positive electrode 2 according to the present invention are protruded to one side. It has a negative electrode tab 3a and a positive electrode tab 2a, respectively. The positive electrode tab 2a and the negative electrode tab 3a are configured to protrude opposite to each other, and each side of the electrode assembly includes two sides forming a right angle with the side from which the positive electrode tab 2a and the negative electrode tab 3a protrude. It has a configuration in which the film 30 is attached.
[70]
[71]
The present invention having the configuration as described above uses the fixing tape instead of the tape, and the film 30 is heat-sealed and fixed on the side of the electrode assembly, so that the pressure smaller than the pressure generated when the conventional fixing tape is attached. Since it is applied, it is possible to prevent the folding or lifting of the separation membrane 1 occurring in the conventional structure.
[72]
In particular, in the present invention, since two or more separation membranes 1 are gathered at the ends to form a junction 1a and the film 30 is thermally fused at the junction 1a, the separation membrane 1 is folded or deformed during thermal fusion. problems can be prevented. That is, when thermal fusion is performed, the ends of the separators 1 are bonded to each other to limit movement, and the thickness increases at the point where the junction 1a is formed to increase the thermal fusion area with the film 30 to increase the fixing force. can
[73]
In addition, in the present invention, thermal fusion is performed immediately after the unit cells 10 are stacked and proceeds in the order in which the next unit cells 10 are stacked, or thermal fusion is performed after all stacking of the unit cells 10 is completed. Therefore, it is possible to provide flexibility in the manufacturing process according to the conditions of the electrode assembly.
[74]
And, since the iron (G) enters the inside of the mold (M) in which the stacking of the unit cells (10) is made or the iron (G) is built-in and thermal fusion is performed in the mold (M), the unit in the thermal fusion process The shaking of the cell 10 is prevented, so that thermal fusion can be performed more stably.
[75]
In the above, although the present invention has been described with reference to limited embodiments and drawings, the present invention is not limited thereto, and it is described below with the technical idea of ​​the present invention by those of ordinary skill in the art to which the present invention pertains. Various implementations are possible within the scope of equivalents of the claims to be made.

Claims

[Claim 1]
In an electrode assembly in which a negative electrode, a separator, and a positive electrode are repeatedly stacked, a film disposed to cover any one of the side surfaces formed by stacking a negative electrode, a separator, and a positive electrode; An electrode assembly, characterized in that it is heat-sealed to the side formed by lamination.
[Claim 2]
According to claim 1, wherein the film is an electrode assembly, characterized in that the electrode assembly, characterized in that disposed on each of the two opposite sides of the side formed by stacking the negative electrode, the separator, and the positive electrode.
[Claim 3]
The electrode assembly according to claim 1, wherein the film is made of a thermoplastic material that plastically changes when heat and pressure are applied.
[Claim 4]
The electrode assembly according to claim 3, wherein the film is made of a PET (polyethylene terephthalate) material.
[Claim 5]
The electrode assembly according to claim 1, wherein two or more separators are collected at the ends to form a bonded joint, and a film is thermally bonded to the joint.
[Claim 6]
As a method for manufacturing an electrode assembly in which a negative electrode, a separator, and a positive electrode are repeatedly stacked, a unit cell having a predetermined stacking structure of a negative electrode, a separator, and a positive electrode is manufactured, but the ends of the separator are bonded to each other to form a junction. step (S10); A film insertion step of inserting the film into the mold (S20); a unit cell stacking step of stacking the unit cells in the mold (S30); and a heat-sealing step (S40) of heat-sealing the film to the junction of the stacked unit cells by applying heat and pressure within the mold.
[Claim 7]
The method according to claim 6, wherein in the film inserting step (S20), two films are inserted so as to abut one by one on both side wall surfaces facing each other within the mold.
[Claim 8]
The electrode according to claim 7, wherein after the film inserting step (S20), the unit cell stacking step (S30) and the thermal fusion step (S40) are repeated until the stacking of the predetermined unit cells is completed. A method for manufacturing an assembly.
[Claim 9]
According to claim 7, After the film insertion step (S20), the unit cell stacking step (S30) is repeated until the stacking of predetermined unit cells is completed, and when the unit cell stacking step (S30) is completed, lamination A method of manufacturing an electrode assembly, characterized in that the heat-sealing step (S40) is repeated so that the film is heat-sealed to each of the unit cells.
[Claim 10]
The method according to claim 6, wherein in the unit cell manufacturing step (S10), a monocell stacked in the order of separator/cathode/separator/anode from the bottom or monocells stacked in the order of separator/anode/separator/cathode to manufacture unit cells A method of manufacturing an electrode assembly, characterized in that.
[Claim 11]
The method according to claim 10, wherein in the unit cell manufacturing step (S10), the half-cells stacked in the separator/cathode/separator order from the bottom or the half cells stacked in the separator/positive electrode/separator order are manufactured as unit cells separately from the mono cells. And, while the unit cell stacking step (S30) is repeatedly performed, the stacking is made with mono cells, characterized in that when the unit cell stacking step (S30) is finally performed, the stacking is made with half cells A method of manufacturing an electrode assembly.
[Claim 12]
The method according to claim 6, wherein the film is made of a thermoplastic material that plastically changes when heat and pressure are applied, and in the thermal fusion step (S40), the tip of the iron presses and heats the film at the same time to heat it to the unit cell. A method of manufacturing an electrode assembly, characterized in that.
[Claim 13]
13. The method of claim 12, wherein the mold is configured such that the tip of the iron enters or the iron is built in, so that thermal fusion of the film is performed within the mold.