Exhaust Purification Device And Exhaust Purification Method For Internal Combustion Engine
Abstract:
The purpose of the invention is to provide an exhaust purification device and an
exhaust purification method for an internal combustion engine in which SCR
catalyst initialization can be performed by increasing an SCR catalyst
temperature in predetermined conditions without any troublesome procedures
or complex calculations. In an exhaust purification device for an internal
combustion engine placed in an exhaust passage of an internal combustion
engine and equipped with an SCR catalyst for purifying NOx in the exhaust of
the internal combustion engine, the device carries out: a sequence in which urea
water is sprayed into the exhaust passage from the upstream side of the SCR
catalyst, and adsorption amount estimation values of NH3 adsorbed on the SCR
catalyst are calculated and accumulated from the sprayed amount of NH3
produced from the urea water and the sprayed amount of NH3 for purifying the
NOx upstream of the SCR catalyst; and a sequence for performing initialization
of the SCR catalyst by raising the SCR catalyst temperature and initializing the
NH3 amount estimation values.
[FIG.3]
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C/O MITSUBISHI HEAVY INDUSTRIES LTD. 16-5 Konan 2 chome Minato ku Tokyo
1088215
Specification
DESCRIPTION
EXHAUST GAS PURIFICATION APPARATUS AND METHOD FOR INTERNAL
COMBUSTION ENGINE
5 TECHNICAL FIELD
[0001] The present invention relates to an exhaust gas purification apparatus and an
exhaust gas purification method for an internal combustion engine. It especially relates to an
exhaust gas purification apparatus and an exhaust gas purification method for an internal
combustion engine employing selective catalytic reduction (SCR), a technique for selectively
10 purifying nitrogen oxide (NOx) in exhaust gas using ammonia as a reducing agent.
BACKGROUND
[0002] To meet the exhaust emission regulations (NOx and PM emission regulations) for
diesel engines, recent techniques reduce NOx and PM by performing various controls such as
15 hardware control, operation control, and temperature control of the engine, and also purify
exhaust gas using an after-treatment device. As an after-treatment device, a diesel
particulate filter (DPF) for collecting particulate matters (PM) and an SCR catalyst for
purifying NOx are often used.
[0003] Using an SCR catalyst, NOx is purified as follows, for instance.
20 1) Urea is injected at an upstream side of the SCR catalyst in response to the amount of
NOx at the upstream side of the SCR, the temperature of the SCR catalyst, the flow rate of the
exhaust gas, or the like. The amount of NOx here is measured by a sensor, or estimated.
2) The injected urea is degraded to ammonia (NH3) to be adsorbed on the SCR catalyst.
3) NOx in the exhaust gas is purified by the adsorbed NH3 when passing through the SCR
25 catalyst.
[0004] Meanwhile, when the amount of NH3 exceeds an amount that can be adsorbed on
the SCR catalyst, NH3 is discharged into the exhaust gas, which is a phenomenon referred to
as NH3 slip. When the amount of NH3 adsorption is small, the NOx purification rate
decreases. Thus, monitoring the amount of NH3 adsorption is important in determining the
purification rate of NOx.
However, it is difficult to measure an actual amount of NH3 adsorption, and thus the
amount of NH3 adsorption is generally estimated on the basis of e.g. a measurement value of
5 NOx sensor mounted to an exhaust duct.
Still, when estimating the amount of NH3 adsorption, an error inevitably occurs due to
various causes. For instance, there may be measurement errors or calculation errors of
various parameters due to decreases in the accuracy of various sensors, for instance. If
subsequent processes are to be continued using data including such errors, the errors would be
10 accumulated, which prevents highly accurate control of the amount of urea injection and
suitable purification of NOx. As a result, it becomes necessary to initialize the amount of
NH3 adsorption.
[0005] Patent Document 1 discloses an exhaust purification apparatus of an internal
combustion engine which initializes the amount of NH3 adsorption.
15 That is, in the technique for initializing the amount of NH3 adsorption disclosed in
Patent Document 1, the amount of reducing-agent adsorption on a NOx catalyst is calculated
on the basis of time-series data of balance between supply of the reducing agent to the NOx
catalyst upon adding the reducing agent by a reducing-agent adding means and consumption
of the reducing agent in reducing reaction in the NOx catalyst. Further, the amount of NOx
20 introduced to the NOx catalyst or correlated parameters are calculated. Finally, on the basis
of the calculated result, initialization is executed at a determined timing.
Citation List
Patent Literature
25 [0006]
Patent Document 1 : Japanese Unexamined Patent Application No. 2009-28 1350
SUMMARY
Technical Problem
[0007] As described above, the initialization procedure in Patent Document 1 is
troublesome and associated with complicated calculations.
The present invention was proposed to overcome the above inconvenience. An object
5 of the present invention is to provide an exhaust gas purification apparatus and an exhaust gas
purification method for an internal combustion engine capable of initializing an SCR catalyst
by heating the SCR catalyst under predetermined conditions without troublesome procedures
or complicated calculations.
10 Solution to Problem
[0008] In order to achieve the above object, according to claim 1 of the present invention,
an exhaust gas purification apparatus for an internal combustion engine includes: an SCR
catalyst for purifying NOx in exhaust gas of the internal combustion engine, disposed on an
exhaust-gas passage of the internal combustion engine; and an exhaust gas purification
15 controller part. The exhaust gas purification controller part includes: a NH3 adsorption
amount estimate value calculation part configured to calculate an estimate value of an amount
of NH3 adsorption which is adsorbed on the SCR catalyst, on the basis of an amount of
injection of NH3 produced from urea-aqueous solution injected into the exhaust-gas passage
from an upstream side of the SCR catalyst and an amount of NH3 for purifying NOx at the
20 upstream side of the SCR catalyst; a NOx amount estimate value derivation part configured to
derive an estimate value of an amount of NOx at a downstream side of the SCR catalyst on
the basis of the estimate value of the amount of NH3 adsorption from the NH3 adsorption
amount estimate value calculation part and a temperature of the SCR catalyst; and a SCR
catalyst heating command part configured to heat the SCR catalyst to initialize the amount of
25 NH3 adsorption of the SCR catalyst on the basis of an error between the estimate value of the
amount of NOx from the NOx amount estimate value derivation part and a measurement
value of the amount of NOx at the downstream side of the SCR catalyst.
[0009] To initialize the SCR catalyst, the present invention focuses on the decrease in the
amount of NH3 adsorption upon an increase of the temperature of the SCR catalyst. That is,
the decreasing amount of NH3 adsorption upon an increase in the temperature of the SCR
catalyst means that NH3 would be discharged almost directly, which is defined as initialization
of the SCR catalyst.
5 Since it is difficult to obtain an actual measurement of the amount of NH3 adsorption, it
is estimated from the amount of urea (NH3) injection and the amount of NH3 injection for
purifying the amount of NOx at the upstream side of the SCR catalyst, as in the following
equation.
(Equation 1)
10 Estimate value of the amount of NH3 adsorption (g)
= (the amount of urea injection - the amount of NH3 injection for purification)
Then, from a map showing a relationship between the estimate value of the amount of
NH3 adsorption and the temperature of the SCR catalyst, for instance, the purification rate of
NOx is derived, and this purification rate of NOx and the amount of NOx at the upstream side
15 of the SCR catalyst are calculated to estimate the amount of NOx at the downstream side of
the SCR catalyst.
Next, this estimate value of the amount of NOx at the downstream side of the SCR
catalyst is compared to the actual measurement value of the amount of NOx at the
downstream side of the SCR catalyst. If the error occurring is increasing, it is determined
20 that continuing the subsequent processes with the data including such an error leads to
accumulation of the errors, which makes it impossible to execute highly accurate control of
the amount of urea injection and suitable purification of NOx. As a result, the SCR catalyst
is heated to be initialized.
[OO 101 According to the present invention described in claim 1, the estimate value of the
25 amount of NOx at the downstream side of the SCR catalyst is derived from the estimate value
of the NH3 adsorption from the NH3 adsorption amount estimate value calculation part and
the temperature of the SCR catalyst. The temperature of the SCR catalyst is then increased
side of the SCR catalyst and the measurement value of the amount of NOx at the downstream
side of the SCR catalyst. As a result, the amount of NH3 adsorption decreases.
In consequence, the NH3 injected from the upstream side of the SCR catalyst is not
adsorbed on the SCR catalyst so that the SCR catalyst does not execute NOx purification at
5 all, which means that initialization of the SCR catalyst is achieved.
[0011] Further, according to the present invention described in claim 2, the exhaust gas
purification controller part includes a SCR catalyst initialization necessity determination part
configured to determine necessity of initialization of the SCR catalyst on the basis of an error
between the estimate value of the amount of NOx and the measurement value of the amount
10 of NOx at the downstream side of the SCR catalyst.
[0012] Further, according to the present invention described in claim 3, the SCR catalyst
initialization necessity determination part is configured to determine the necessity of
initialization of the SCR catalyst on the basis of whether a predetermined time has elapsed
after completion of heating of the SCR catalyst.
15 [0013] According to claims 2 and 3, it is possible to issue the SCR catalyst heating
commands for heating the SCR catalyst only when it is necessary to initialize the SCR
catalyst.
[0014] Further, according to the present invention described in claim 4, the exhaust gas
purification controller part includes a SCR catalyst heating capability determination part
20 configured to determine that the heating of the SCR catalyst is possible, when it is determined
that an operation is within an operation range in which the heating is possible and that forced
regeneration of a filter for removing particulate matters in the exhaust gas is unnecessary.
[0015] As a result, it is possible to determine that the heating of the SCR catalyst is
possible when the operation is within the operation range in which the heating is possible and
25 the SCR catalyst is not heated for forced regeneration of the filter for removing particulate
matters. Thus, the SCR catalyst would not be heated unnecessarily.
[0016] Further, according to the present invention described in claim 5, an exhaust gas
purification method is for an internal combustion engine that purifies NOx in exhaust gas in
the internal combustion engine using a SCR catalyst arranged on an exhaust-gas passage of
the internal combustion engine. The exhaust gas purification method includes: a NH3
adsorption amount estimate value calculation step of calculating an estimate value of an
amount of NH3 adsorption which is adsorbed on the SCR catalyst, on the basis of an amount
5 of injection of NH3 produced from urea-aqueous solution injected into the exhaust-gas
passage from an upstream side of the SCR catalyst and an amount of NH3 for purifying NOx
at the upstream side of the SCR catalyst; a SCR catalyst initialization necessity determination
step of deriving an estimate value of an amount of NOx at a downstream side of the SCR
catalyst on the basis of the estimate value of the amount of NH3 adsorption and a temperature
10 of the SCR catalyst, and determining necessity of initialization of the SCR catalyst on the
basis of an error between the estimate value of the amount of NOx and a measurement value
of the amount of NOx at the downstream side of the SCR catalyst; and a SCR catalyst heating
step of heating the SCR catalyst to initialize the amount of NH3 adsorption of the SCR
catalyst.
15 [0017] In this way, it is possible to calculate the estimate value of the amount of NH3
adsorption and then derive the estimate value of the amount of NOx at the downstream side of
the SCR catalyst from the estimate value of NH3 adsorption and the temperature of the SCR
catalyst.
Further, it is possible to obtain an error between the estimate value of the amount of
20 NOx at the downstream side of the SCR catalyst and the measurement value of the amount of
NOx at the downstream side of the SCR catalyst, and then determine the necessity of
initialization of the SCR catalyst from this error.
When it is determined that it is necessary to initialize the SCR catalyst, the SCR catalyst
is heated so that the amount of NH3 adsorption decreases.
25 As a result, NH3 injected from the upstream side of the SCR catalyst is not adsorbed on
the SCR catalyst and the SCR catalyst is in a state where NOx purification cannot be
performed at all, which means that initialization of the SCR catalyst is achieved.
[0018] Further, according to the present invention described in claim 6, before the SCR
catalyst heating step, a SCR catalyst heating capability determination step is executed. This
step determines that heating of the SCR catalyst is possible when it is determined that an
operation is within an operation range in which heating is possible and that forced
regeneration of a filter for removing particulate matters in the exhaust gas is unnecessary.
5 [0019] In this way, it is possible to determine that the heating of the SCR catalyst is
possible when the operation is within an operation range in which the heating is possible and
that the SCR catalyst is not heated for the forced regeneration of a filter for removing
particulate matters in the exhaust gas. As a result, the SCR catalyst is not heated
unnecessarily.
10 [0020] According to the present invention described in claim 7, in the SCR catalyst
initialization necessity determination step, the SCR catalyst is determined to be necessary
when a cumulative value of NOx errors is smaller than a lower limit of an error, or when the
cumulative value of NOx errors is greater than an upper limit of an error.
[0021] In this way, it is possible to determine that the initialization of the SCR catalyst is
15 necessary when the cumulative value of NOx error is smaller than the lower limit of an error,
or when the cumulative value of NOx errors is greater than the upper limit of an error.
[0022] Further, according to the present invention described in claim 8, in the SCR
catalyst initialization necessity determination step, the SCR catalyst is determined to be
necessary when a predetermined time has elapsed after determining completion of the heating
20 of the SCR catalyst.
[0023] In this way, when a predetermined time has elapsed after determining completion
of the heating of the SCR catalyst, it may be considered that purification by the SCR catalyst
is considerably executed so that the NOx errors has been accumulated, and to determine that
the initialization of the SCR catalyst is necessary.
25 [0024] Further, according the present invention described in claim 9, in the SCR catalyst
heating step, an inlet temperature of a filter for removing particulate matters that collects
particulate matters in the exhaust gas at the upstream side of the SCR catalyst is controlled by
a control used upon forced regeneration of the filter for removing particulate matters.
[0025] In this way, it is possible to simplify the control of the inlet temperature of the
filter for removing PM.
[0026] Further, according to the present invention described in claim 10, the inlet
temperature of the filter for removing particulate matters is controlled on the basis of a target
5 inlet temperature that is different from one used upon forced regeneration of the filter for
removing particulate matters.
[0027] In this way, it is possible to restrict the inlet temperature of the filter for removing
PM to be low, and thus to reduce oil dilution.
[0028] Further, according to the present invention described in claim 11, the inlet
10 temperature is increased to the target inlet temperature at a predetermined increase rate from a
start of temperature increase.
[0029] In this way, it is possible to restrict NH3 slip.
[0030] Further, according the present invention described in claim 12, the inlet
temperature is increased to the target inlet temperature in a plurality of stages from the start of
15 the temperature increase.
[003 11 In this way, it is possible to reduce NH3 slip and oil dilution.
[0032] Further, according to the present invention described in claim 13, the target inlet
temperature is corrected by the temperature of the SCR catalyst or a temperature at the
upstream side of the SCR catalyst.
20 [0033] Further, according to the present invention described in claim 14, the inlet
temperature of the filter for removing particulate matters is controlled on the basis of an outlet
temperature of the filter for removing particulate matters.
[0034] Further, according to the present invention described in claim 15, the inlet
temperature of the filter for removing particulate matters is controlled on the basis of the
25 temperature at the upstream side of the SCR catalyst.
[0035] Further, according to the present invention described in claim 16, the inlet
temperature of the filter for removing particulate matters is controlled on the basis of the
temperature of the SCR catalyst.
[0036] According to the above claims 12 to 16, it is possible to heat the SCR catalyst
securely even in a cold place.
Advantageous Effects
5 [0037] According to the present invention, it is possible to achieve initialization of the
SCR catalyst by calculating the estimate value of the amount of NH3 adsorption, deriving the
estimate value of the amount of NOx at the downstream side of the SCR catalyst, determining
the necessity of the initialization of the SCR catalyst on the basis of the error between the
estimate value of the amount of NOx at the downstream side of the SCR catalyst and the
10 measurement value of the amount of NOx at the downstream side of the SCR catalyst, and
heating the SCR catalyst. Thus, it is no longer necessary to execute the troublesome steps
and complicated calculations, unlike the conventional techniques.
BRIEF DESCRIPTION OF DRAWINGS
15 [0038] FIG. 1 is a schematic system diagram according to the first embodiment of an
internal combustion engine for implementing an exhaust gas purification method for an
internal combustion engine according to the present invention.
FIG 2 is a partial configuration diagram schematically illustrating an exhaust gas
purification apparatus in the internal combustion engine of FIG. 1.
20 FIG. 3 is a flowchart of an SCR catalyst initializing process according to the first
embodiment.
FIG. 4 is a graph of the amount of NH3 that can be adsorbed, related to a temperature of
the SCR catalyst.
FIG. 5 is a graph of a time-series change comparing the estimated value and the actual
25 value of the amount of NH3 adsorption, and of a corresponding change in the temperature of
the SCR catalyst.
FIG. 6 is a graph of an example of an increase at a predetermined rate of the temperature
of the SCR catalyst to a target temperature from a DPF inlet temperature at execution of the
control of the DPF inlet temperature, upon increasing the temperature of the SCR catalyst in
the second embodiment.
FIG. 7 is a graph of an example of a two-stage increase of the temperature to the target
temperature from the DPF inlet temperature.
5 FIG. 8 is a graph of an example of a multi-stage increase of the temperature to the target
temperature from the DPF inlet temperature.
FIG. 9 is a schematic graph of correction of a DPF inlet target temperature according to
the third embodiment.
FIG. 10 is a block diagram of a flow of a specific correcting step for correcting the DPF
10 inlet target temperature as illustrated in FIG. 9.
DETAILED DESCRIPTION
[0039] An exhaust gas purification apparatus and an exhaust gas purification method for
an internal combustion engine according to the present embodiment will be described below
15 in detail listing various embodiments and referring to the accompanying drawings.
[0040] (First embodiment)
FIG. 1 illustrates an example of an intake-and-exhaust system and an electrical system
of an internal combustion engine 1 including an exhaust gas purification apparatus of the first
embodiment.
20 The internal combustion engine 1 includes an intake-and-exhaust system in which an
intake duct 3, an exhaust duct 4, and an EGR duct 5 are connected to an engine body 2. A
compressor and a turbine of a turbocharger 6 are disposed on the flow path of the exhaust duct
4 so as to be interposed between the upstream side of the intake duct 3 and the vicinity of the
outlet of the engine. An intercooler 7 is disposed on the intake duct 3. Further, the intake
25 duct 3 includes an intake throttle valve 8, while the EGR duct 5 includes an EGR valve 9.
Moreover, an exhaust gas purification apparatus serving as an after-treatment device for
exhaust gas is connected to the exhaust duct 4 so as to communicate with the exhaust duct 4.
[0041] An electronic control unit (ECU, i.e., engine control unit) is provided for the
intake-and-exhaust system of the above engine body 2, as a part constituting the electrical
system. The ECU 11 receives sensor outputs from various sensors (described below)
disposed on the engine body 2, the intake duct 3, the exhaust duct 4, the EGR duct 5, and the
exhaust gas purification apparatus 10. The ECU 11 also receives acceleration input signals
5 and signals from DCU, which will be described below. In addition to executing the
predetermined signal processing and calculation processing, the ECU 11 executes the
essentials of the present invention, such as a step for determining the SCR catalyst
initialization, determination of whether it is possible to heat the SCR catalyst, and heating of
the SCR catalyst, which will be described below.
10 An in-vehicle battery 13 is electrically connected to the ECU 11 via a key switch Sw.
A starter motor MSt is electrically connected to the in-vehicle battery 13 via the key switch Sw.
[0042] An injector, a common-rail pressure sensor, a combustion temperature sensor, a
crank sensor, a cam sensor, a water temperature sensor, a hydraulic pressure switch, or the like,
none of which is illustrated, are connected to the engine body 2 to communicate signals with
15 theECU11.
An airflow meter m,f and an intake temperature sensor S,nt are disposed at the upstream
side of the intake duct 3. The intake throttle valve 8, an intake absolute pressure sensor S,,
and an intake temperature sensor Slnta re disposed on the downstream side of the intake duct 3,
which is the inlet side of the engine body 2.
20 The EGR valve 9 is disposed on the EGR duct 5.
A DOC inlet temperature sensor Sdolnt, a DPF inlet temperature sensor Sdplnt, a DPF
differential pressure sensor Sdp,a DPF outlet temperature sensor Sdpouat, NOx sensor SnI,a n
exhaust temperature sensor (not illustrated), a NOx sensor S ~aZre each disposed on the
exhaust gas purification apparatus 10 at the downstream side of the exhaust duct 4, arranged
25 in this order from the upstream side. The details will be described later.
The signals of the NOx sensor S,,, the exhaust temperature sensor St, and the NOx
sensor Snz are transmitted the ECU 11. Further, the turbocharger 6 and the intake throttle
valve 8 are driven by the ECU 11.
[0043] Next, in reference to FIG. 2 further illustrating the exhaust gas purification
apparatus 10 in the above internal combustion engine 1, the essential configuration of the
present invention will be described in detail. The configuration around the engine body 2 is
as described above, and thus not explained herein.
5 The exhaust gas purification apparatus 10 first includes an oxidation catalyst 20, which
is a diesel oxidation catalyst (DOC) herein, disposed on the upstream side of the exhaust duct
4 constituting the exhaust-gas passage connected to the engine body 2. The exhaust gas
purification apparatus 10 also includes a SCR catalyst 21 for purifying NOx in the exhaust
gas of the engine body 2, disposed at the downstream side of the oxidation catalyst 20, and
10 another oxidation catalyst 22 for removing excess ammonia discharged from the SCR catalyst
21, disposed at the downstream side of the SCR catalyst 21. Further, a diesel particulate
filter (DPF) 23 may be disposed between the oxidation catalyst 20 and the SCR catalyst 21 at
the downstream side of the oxidation catalyst 20. The DPF 23 is a filter for removing
particulate matters (PM) that collects PM in the exhaust gas. In FIG. 1, the DPF 23 and the
15 DOC 20 are integrally accommodated.
A urea injection unit 24 for injecting urea-aqueous solution is disposed at the
downstream side of the DPF 23, which is also the upstream side of the SCR catalyst 21.
Although not illustrated in detail, the urea injection unit 24 includes an electromagnetic
injection valve 24v and a tank 24t for storing urea-aqueous solution. The electromagnetic
20 injection valve 24v has an injection nozzle disposed inside the exhaust duct 4.
When the urea injection unit 24 injects urea-aqueous solution into the exhaust duct 4
I through the electromagnetic injection valve 24v, chemical reaction that begins with
evaporation caused by exhaust heat and leads to hydrolysis produces ammonia NH3 which
serves as a direct reducing agent. NH3 and NOx in the exhaust gas react while passing
I 25 through the SCR catalyst 21 to change into nitrogen N2 and water H20. With this reaction,
purification of NOx is executed.
Further, in this case, detection signals from the NOx sensors S,,, Sn2 disposed on the
upstream and downstream sides, respectively, of the SCR catalyst 21 are transmitted to the
ECU 11 through CAN, so that the amount of injection of the urea-aqueous solution is
controlled in accordance with the important engine parameters such as the operation
temperature and the engine speed.
In the above internal combustion engine 1, the ECU 11 executes steps such as the
5 predetermined signal processing and calculation processing, and the NOx purifying
processing of the exhaust gas purification apparatus 10 in response to sensor outputs from the
various sensors disposed on the engine body 2, the intake duct 3, the exhaust duct 4, the EGR
duct 5, and the exhaust gas purification apparatus 10, and to the acceleration input signals.
[0044] The ECU 11 includes an exhaust gas purification controller part 11C for executing
10 the steps of the NOx purification process.
The exhaust gas purification controller part 11C includes a NH3 adsorption amount
estimate value calculation part A, a NOx amount estimate value derivation part B, a SCR
catalyst heating command part C, a SCR catalyst initialization necessity determination part D,
a SCR catalyst heating capability determination part E, and a SCR catalyst heating completion
15 determination part F.
The NH3 adsorption amount estimate value calculation part A calculates an estimate
value of the amount of NH3 adsorption that is adsorbed on the SCR catalyst, on the basis of
the amount of NH3 injection produced from urea-aqueous solution injected into the exhaustgas
passage 4 from the upstream side of the SCR catalyst, and the amount of NH3 injection
20 for purifying NOx at the upstream side of the SCR catalyst.
The NOx amount estimate value derivation part B derives an estimate value of the
amount of NOx at the downstream side of the SCR catalyst on the basis of the estimate value
of the amount of NH3 adsorption from the NH3 adsorption amount estimate value calculation
part, and the temperature of the SCR catalyst.
25 The SCR catalyst heating command part C initializes the SCR catalyst by heating the
SCR catalyst to initialize the estimate value of the NH3 adsorption, on the basis of an error
between the estimate value of the amount of NOx from the NOx amount estimate value
derivation part and a measurement value of the amount of NOx at the downstream side of the
SCR catalyst.
The SCR catalyst initialization necessity determination part D determines necessity of
initialization of the SCR catalyst, on the basis of the error between the estimate value of the
amount of NOx and the measurement value of the amount of NOx at the downstream side of
5 the SCR catalyst, on the basis of whether a predetermined time has elapsed after completing
heating of the SCR catalyst, or on the basis of the measurement value of the amount of NOx
at the downstream side of the SCR catalyst.
The SCR catalyst heating capability determination part E determines that it is possible
to heat the SCR catalyst when forced regeneration of the filter for removing the particulate
10 matters in the exhaust gas is unnecessary and the operation is within an operation range in
which the heating is possible.
Further, the exhaust gas purification controller part includes the SCR catalyst heating
completion determination part F.
[0045] The first embodiment of the exhaust gas purification apparatus for implementing
15 the exhaust gas purification method for an internal combustion engine according to the
present invention is as described above. Next, the steps of the NOx purification process of
the exhaust gas purification apparatus 10 will be described along with a series of operations of
the above internal combustion engine 1. The series of operations of the internal combustion
engine 1 will be schematically described because it is not an essential part of the present
20 invention.
When the key switch Sw is turned on, electric current is applied to the ECU 11 from the
in-vehicle battery 13, so that the starter motor Mst is driven to rotate the crank shaft of the
engine body 2. As a result, fuel is injected into the cylinder through the injector in response
to a command from the ECU 11, thereby starting the engine. At this point, the combustion
25 air drawn in through the intake duct 3 is changed into air having a high pressure and a high
temperature by a compressor of the turbocharger 6, and then cooled by the intercooler 7 to be
supplied into the cylinder inside the engine body 2, while high-pressure fuel is injected into
the cylinder through the common rail Cr and the fuel injection valve Vf. As a result,
combustion is started.
The combustion gas is discharged into the exhaust gas purification apparatus 10 through
the exhaust duct 4 while rotating the turbine of the turbocharger 6. Further, a part of the
exhaust gas is re-circulated into the cylinder of the engine body 2 through the EGR duct 5 to
5 be combusted again.
[0046] Exhaust gas that has been supplied to the exhaust gas purification apparatus 10
through the exhaust duct 4 passes through the DOC 20 being an oxidation catalyst and DPF
23 in sequence, where the non-combusted portion of the PM in the exhaust gas is combusted
and the PM is removed, and then passes through the SCR catalyst 21. As a result, NOx in
10 the exhaust gas is purified. Further, excess ammonia discharged from the SCR catalyst 21 is
removed by the oxidation catalyst 22 at the downstream side of the SCR catalyst 21, before
the exhaust gas is finally discharged. When the exhaust gas passes through the SCR catalyst
21, urea-aqueous solution is injected into the exhaust duct 4 through the electromagnetic
injection valve 24v at the urea injection unit 24, so that ammonia NH3 serving as a direct
15 reducing agent is produced by chemical reaction that begins from evaporation caused by
exhaust heat and leads to hydrolysis. NH3 and NOx in the exhaust gas reacts while passing
through the SCR catalyst 21 and then changes into nitrogen N2 and water H20. This
reaction makes it possible to purify NOx.
[0047] When exhaust gas passes through the DOC 20 and the DPF 23 of the exhaust gas
20 purification apparatus 10, the temperature of the exhaust gas is detected by the DOC inlet
temperature sensor Sdpintth, e DPF inlet temperature sensor Sdpintth, e DPF differential pressure
sensor Sdp,a nd the DPF outlet pressure sensor Sdpoutarn d then transmitted to the ECU 11 in
sequence. Next, when the exhaust gas passes through the SCR catalyst 21, detection signals
from NOx sensor Snl, the exhaust temperature sensor, and the NOx sensor Sn2 are transmitted
25 to the ECU 11.
[0048] The exhaust gas purification controller part 11C of the ECU 11 executes the
processing steps illustrated in FIG. 3 on the basis of the received detection signals.
Specifically, it executes (1) SCR catalyst initialization determination step, (2) SCR catalyst
heating capability determination, (3) SCR catalyst heating, and (4) SCR catalyst heating
completion determination step.
First, the NH3 adsorption amount estimate value calculation part A calculates the
amount of NH3 adsorption (step Sl). As described above, the amount of NH3 that can be
5 adsorbed on the SCR catalyst varies depending on the temperature of the SCR catalyst. For
instance, FIG. 4 illustrates a relationship between the temperature of the SCR catalyst and the
amount of NH 3 that can be adsorbed. Specifically, the amount of NH3 that can be adsorbed
reaches its peak at a predetermined temperature (approximately 200 "C) and then declines
after exceeding this predetermined temperature. As the temperature rises higher, the amount
10 of adsorption approaches zero, where NH3 is hardly adsorbed. The amount of NH3
adsorption can be obtained by the following equation.
Estimate value of the amount of NH3 adsorption (g)
= 5 (the amount of urea injection - the amount of NH3 injection for purification)
The amount of urea injection here is the amount of NH3 injected from the urea injection
15 unit 24 at the upstream side of the SCR catalyst 21, while the amount of NH3 injection for
purification here is the amount of NH3 required for purification. These amounts are obtained
by predetermined calculations.
At the same time, the NOx amount estimate value derivation part B derives an estimate
value of the amount of NOx at the downstream side of the SCR catalyst, on the basis of the
20 estimate value of the NH3 adsorption from the NH3 adsorption amount estimate value
calculation part A, and the temperature of the SCR catalyst.
The above estimate value of the amount of NOx corresponds to the estimate value of the
NH3 adsorption, and thus can be represented by a curve of the estimate value of the NH3
adsorption as indicated by the dotted line in FIG. 5.
25 On the other hand, the measurement value of the amount of NOx at the downstream side
of the SCR catalyst is assumed as being the actual amount of NH3 adsorption, as indicated by
the solid line. FIG. 5 also illustrates the temperature of the SCR catalyst.
FIG. 5, as described above, illustrates that the difference increases between the estimate
value of the amount of NH3 adsorption, which is the estimate value of the NOx amount at the
downstream side of the SCR catalyst, and the actual amount of NH3 adsorption, which is the
measurement value of the amount of NOx at the downstream side of the SCR catalyst.
[0049] Next, in step S2, the exhaust gas purification controller part 11C of the ECU 11
5 executes the step of determining necessity of the SCR catalyst initialization.
Note that the SCR catalyst initialization is determined to be necessary when one of the
conditions (1) to (3) below is met. Specifically, the SCR catalyst initialization necessity
determination part D determines the following conditions.
(1) When an error of NOx at the outlet of the SCR catalyst is large
10 This means that, as illustrated in FIG. 5, as a result of purification of the exhaust gas
having proceeded, the difference between the estimate ,value of the NH3 adsorption, which is
the estimate value of the amount of NOx at the downstream side of the SCR catalyst, and the
actual amount of NH3 adsorption, which is the measurement value of the amount of NOx at
the downstream side of the SCR catalyst, has been accumulated, and then the error of NOx at
15 the outlet of the SCR catalyst has exceeded a predetermined threshold value. Specifically,
the lower limit of the error > the cumulative value of the NOx error, or
the upper limit of the error