Abstract: The disclosure relates generally to mold compositions and methods of molding and the articles so molded. More specifically the disclosure relates to silicon carbide containing mold compositions silicon carbide containing intrinsic facecoat compositions and methods for casting titanium containing articles and the titanium containing articles so molded. A slurry containing silicon carbide and calcium aluminate is introduced in a mold cavity that contains a fugitive pattern. The slurry is cured in the mold sintered and used for casting a titanium turbine blade.
WE CLAIMS:
1. A method for forming a mold for casting a titanium-containing article,
comprising:
mixing calcium aluminate and silicon carbide with a liquid to produce a slurry, wherein the percentage of solids in the slurry is about 60% to about 80% by weight of the slurry and a viscosity of the slurry is about 30 to about 1500 centipoise;
introducing the slurry into a mold cavity that contains a fugitive pattern; and
allowing the slurry to cure in the mold cavity to form the mold for casting the titanium-containing article.
2. The method of claim 1, wherein the silicon carbide particles are from about 10 microns to about 50 microns in outside dimension.
3. The method of claim 1, wherein the calcium aluminate comprises more than 20%) by weight of the slurry.
4. The method of claim 1, wherein a particle size of the calcium aluminate is less than about 50 microns in outside dimension.
5. The method of claim 1, wherein, the slurry further comprises oxide particles.
6. The method of claim 5, wherein said oxide particles are hollow.
7. The method of claim 5, wherein the oxide particles are selected from a group consisting of aluminum oxide particles, magnesium oxide particles, calcium oxide particles, zirconium oxide particles, titanium oxide particles, silicon oxide particles, and compositions thereof.
8. The method of claim 5, wherein the oxide particles are aluminum oxide particles.
9. The method of claim 8, wherein said aluminum oxide particles comprise from about 30 % by weight to about 68 % by weight of the slurry.
10. The method of claim 8, wherein said aluminum oxide particles are from about 50 microns to about 1500 microns in outside dimension.
11. The method of claim 1, wherein before introducing the slurry into the mold cavity, large scale hollow oxide particles are added to the slurry to form a final calcium aluminate - liquid cement mixture, such that the solids in the slurry are about 70% to about 95% by weight of the slurry.
12. The method of claim 1, further comprising calcium oxide added such that more than about 10% by weight and less than about 50% by weight of the slurry is calcium oxide.
13. The method of claim 1, wherein the percentage of solids in the slurry is
about 60 % to about 78 %.
14. The method of claim 1, further comprising adding less than 2 % silica to the slurry.
15. A method for casting titanium and titanium alloys, comprising:
obtaining an investment casting mold composition comprising calcium aluminate and large scale aluminum oxide, wherein the calcium aluminate and alumina are combined with a liquid and silicon carbide to produce a final calcium aluminate / liquid mixture slurry, and wherein the solids in the final mixture is about 70% to about 95% by weight of the slurry;
pouring said investment casting mold composition into a vessel containing a fugitive pattern;
curing said investment casting mold composition;
removing said fugitive pattern from the mold;
firing the mold;
preheating the mold to a mold casting temperature;
pouring molten titanium or titanium alloy into the heated mold;
solidifying the molten titanium or titanium alloy;
forming a solidified titanium or titanium alloy casting; and
removing the solidified titanium or titanium alloy casting from the mold.
16. The method of claim 15, wherein particles of the aluminum oxide are about 50 microns to about 1500 microns in outside dimension.
17. The method of claim 15, wherein silicon carbide particles are about 10 microns to about 100 microns in outside dimension.
18. The method of claim 15, wherein the silicon carbide is present between 15% to 45% by weight and provides increased thermal conductivity during casting by at least 25% as compared to casting performed without silicon carbide.
19. A turbine blade produced by the process, comprising:
providing an investment casting mold, said mold comprising calcium aluminate, silicon carbide and aluminum oxide;
pouring molten titanium or titanium alloy into the mold;
solidifying the molten titanium or titanium alloy;
forming a solidified titanium or titanium alloy casting; and
removing the solidified titanium or titanium alloy casting from the mold to produce the turbine blade, wherein the turbine blade has an average roughness, Ra, of less than 20 across at least a portion of its surface area.
20. The method of claim 19, wherein silicon carbide particles are about 10 microns to about 100 microns in outside dimension.
21. The method of claim 19, wherein the silicon carbide is present between 15% to 45% by weight and provides increased thermal conductivity during casting
by at least 25% as compared to casting performed without silicon carbide.
22. A method for manufacturing a turbine component, comprising:
making a mold from a mixture comprising calcium aluminate, calcium dialuminate, silicon carbide, mayenite and water, wherein the silicon carbide is present at about 15% to about 45% by weight;
firing the mold;
pouring molten titanium or titanium alloy into the mold;
solidifying the molten titanium or titanium alloy to form a solidified casting; and
removing the casting from the mold.
23. The method of claim 22, further comprising hollow aluminum oxide particles that are larger than about 50 microns.
24. The method of claim 22, wherein silicon carbide particles are about 10 microns to about 100 microns in outside dimension.
25. The method of claim 22, wherein the silicon carbide is present between 15% to 45% by weight and provides increased thermal conductivity during casting by at least 25% as compared to casting performed without silicon carbide.
| # | Name | Date |
|---|---|---|
| 1 | Priority Document [14-06-2016(online)].pdf | 2016-06-14 |
| 2 | Power of Attorney [14-06-2016(online)].pdf | 2016-06-14 |
| 3 | Form 5 [14-06-2016(online)].pdf | 2016-06-14 |
| 4 | Form 3 [14-06-2016(online)].pdf | 2016-06-14 |
| 5 | Form 18 [14-06-2016(online)].pdf_46.pdf | 2016-06-14 |
| 6 | Form 18 [14-06-2016(online)].pdf | 2016-06-14 |
| 7 | Drawing [14-06-2016(online)].pdf | 2016-06-14 |
| 8 | Description(Complete) [14-06-2016(online)].pdf | 2016-06-14 |
| 9 | 201647020308.pdf | 2016-06-18 |
| 10 | 201647020308-Power of Attorney-060716.pdf | 2016-07-28 |
| 11 | Other Patent Document [15-11-2016(online)].pdf | 2016-11-15 |
| 12 | Correspondence by Agent_Notarized Assignment_GPA_17-11-2016.pdf | 2016-11-17 |
| 13 | 201647020308-FER.pdf | 2018-07-27 |
| 14 | 201647020308-OTHERS [26-01-2019(online)].pdf | 2019-01-26 |
| 15 | 201647020308-FER_SER_REPLY [26-01-2019(online)].pdf | 2019-01-26 |
| 16 | 201647020308-CORRESPONDENCE [26-01-2019(online)].pdf | 2019-01-26 |
| 17 | 201647020308-COMPLETE SPECIFICATION [26-01-2019(online)].pdf | 2019-01-26 |
| 18 | 201647020308-CLAIMS [26-01-2019(online)].pdf | 2019-01-26 |
| 19 | 201647020308-ABSTRACT [26-01-2019(online)].pdf | 2019-01-26 |
| 20 | 201647020308-HearingNoticeLetter.pdf | 2019-01-28 |
| 21 | 201647020308-RELEVANT DOCUMENTS [26-02-2019(online)].pdf | 2019-02-26 |
| 22 | 201647020308-FORM 13 [26-02-2019(online)].pdf | 2019-02-26 |
| 23 | 201647020308-FORM-26 [27-02-2019(online)].pdf | 2019-02-27 |
| 24 | Correspondence by Agent_Form26_28-02-2019.pdf | 2019-02-28 |
| 25 | 201647020308-Written submissions and relevant documents (MANDATORY) [05-03-2019(online)].pdf | 2019-03-05 |
| 26 | 201647020308-RELEVANT DOCUMENTS [05-03-2019(online)].pdf | 2019-03-05 |
| 27 | 201647020308-RELEVANT DOCUMENTS [05-03-2019(online)]-1.pdf | 2019-03-05 |
| 28 | 201647020308-PETITION UNDER RULE 137 [05-03-2019(online)].pdf | 2019-03-05 |
| 29 | 201647020308-PETITION UNDER RULE 137 [05-03-2019(online)]-1.pdf | 2019-03-05 |
| 30 | Correspondence by Applicant_Assignment_13-03-2019.pdf | 2019-03-13 |
| 31 | Assignment_After Filing_13-03-2019.pdf | 2019-03-13 |
| 32 | 201647020308-Response to office action (Mandatory) [20-03-2019(online)].pdf | 2019-03-20 |
| 33 | Marked Up Claims_Granted 309747_23-03-2019.pdf | 2019-03-23 |
| 34 | Drawings_Granted 309747_23-03-2019.pdf | 2019-03-23 |
| 35 | Description_Granted 309747_23-03-2019.pdf | 2019-03-23 |
| 36 | Claims_Granted 309747_23-03-2019.pdf | 2019-03-23 |
| 37 | Abstract_Granted 309747_23-03-2019.pdf | 2019-03-23 |
| 38 | 201647020308-PatentCertificate23-03-2019.pdf | 2019-03-23 |
| 39 | 201647020308-IntimationOfGrant23-03-2019.pdf | 2019-03-23 |
| 1 | 201647020308_26-07-2018.pdf |