Galvannealed Steel Plate And Method For Manufacturing Same
Abstract:
A plating layer containing 7.2-10.6 mass% Fe, 0.2-0.4 mass% Al, and 0.1 mass% N i and the like, the balance comprising Z n and impurities, wherein a galvannealed steel plate having excellent press formability is characterized in being provided with the plating layer in which, in the vertical section of the plating layer, the average thickness of a £, phase is no greater
than 0.2 urn, and the average thickness of a T phase that exists in contact
with the base steel is no greater than 0.5 urn, and within the T phase, Ni and
the like is contained at a ratio within the T phase of at least 0.5 mass%, the
phase that exists in contact with the T phase being a mixed phase of a TI
phase and a 8 phase, the 8 phase ratio defined in the following equation being
at least 10%: 8 phase ratio=( 8 phase/ T phase contact interface length)/( 8
phase/ r phase contact interface length -t Ti Phase / r phase contact interface
length) x 100, such that here, the 8 phase/ T phase contact interface length is
the length of the interface at which the 8 phase and the T phase are in contact, and the ri phase/T phase contact interface length is the length of the interface
at which the Ti Phase and the T phase are in contact.
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Notices, Deadlines & Correspondence
c/o NIPPON STEEL & SUMITOMO METAL CORPORATION 6 1 Marunouchi 2 chome Chiyoda ku Tokyo
1008071
2. MAKI Jun
c/o NIPPON STEEL & SUMITOMO METAL CORPORATION 6 1 Marunouchi 2 chome Chiyoda ku Tokyo
1008071
3. YAMANAKA Shintaro
c/o NIPPON STEEL & SUMITOMO METAL CORPORATION 6 1 Marunouchi 2 chome Chiyoda ku Tokyo
1008071
4. TANAKA Hiroyuki
c/o NIPPON STEEL & SUMITOMO METAL CORPORATION 6 1 Marunouchi 2 chome Chiyoda ku Tokyo
1008071
Specification
TECHNICAL FIELD
[0001] ., The present invention relates to a
galvannealed steel sheet used for press forming of
automobiles, home electric appliances, construction
materials and the like and a manufacturing method
thereof, and particularly relates to a galvannealed
steel sheet excellent in slidability (flaking
resistance), powdering resistance, and conversion
treatability and a manufacturing method thereof.
BACKGROUND ART
[0002] A galvannealed steel sheet is excellent in
weldability and paintability as compared to a
galvanized steel sheet. Therefore, the galvannealed
steel sheet is widely used in a wide range of fields
of automobile vehicle bodies, and further home
electric appliances, construction materials, and the
like. The alloyed hot-dip galvanized steel sheet to
be used for such usages is made available for use
after being press formed normally.
[0003] In a manufacturing method of the alloyed hotdip
galvanized steel sheet, immediately after hot-dip
galvanizing is performed on the surface of a steel
sheet, heating to the melting point of zinc or higher
and holding are performed to make Fe in the steel
sheet diffuse into a plating layer. Then, alloying
reaction with Zn is caused to generate a Zn-Fe alloy
- 1 -
phase. However, such an alloyed hot-dip galvanized
steel sheet has the disadvantage of being poor in
press formability as compared to a cold-rolled steel
sheet.
[0004] The cause of poor press formability lies in a
structure of an alloyed hot-dip galvanizing layer.
That is, a Zn-Fe alloy plating layer formed by making
Fe in the steel sheet diffuse into the plating layer
to cause alloying reaction with Zn is a plating layer
composed of a F phase 11, a V% phase 12, a 5 i phase
13, and a £ phase 14 formed on a base iron 10 as
schematically illustrated in Fig. 1 normally.
Further, this plating layer changes in the order of
the F phase —> the Fi phase —*• the 6 phase —» the C
phase as the Fe concentration becomes lower.
[0005] As for the hardness of these phases, it is
about 505 Hv in the Fi phase in Vickers hardness,
which is the highest, and next it is about 326 Hv in
the r phase, it i.s about 284 to 300 Hv in the fi
phase, and it is about 200 Hv in the C phase.
Particularly, the T phase and the r i phase existing
in a plating layer region close to the surface of the
steel sheet (at a plated steel sheet interface) are
hard, and in an upper region of the plating layer,
the soft C phase is generated.
[0006] The £ phase is soft, likely to adhere to a
press die, has a high friction coefficient, and is
poor in slidability. Therefore, the C phase results
in the trigger that causes a phenomenon in which the
- 2 -
plating layer adheres to a die to peel off when
severe press forming is performed, (which will be
flaking, hereinafter). Further, the V phase and the
r i phase are hard and brittle, to thus result in the
trigger that causes a phenomenon in which the plating
layer turns powdery to peel off during press forming,
(which will be powdering, hereinafter).
[0007] It is important that the slidability should
be good when the galvannealed steel sheet is press
formed. Therefore, in terms of the slidability, as
the plating layer, a film having a high Fe
concentration that is. alloyed to a high alloying
degree, has high hardness, has a high melting point,
and is unlikely to cause adhesion is effective, but
powdering becomes likely to be caused.
[0008] On the other hand, when a plating layer
having a low Fe concentration that is alloyed to a
low alloying degree and suppresses generations of the
r phase and the T i phase is employed in order to
prevent the powdering, the slidability deteriorates
and the flaking becomes likely to be caused.
[0009] In order to improve the press formability of
the galvannealed steel sheet, the properties contrary
to each other, which are slidability and powdering,
are required to be both achieved.
[ 0010] As a technique to improve the press
formability of the galvannealed steel sheet, there
has been so far proposed a method of manufacturing a
Si-based galvannealed steel sheet by performing
_ 3 _
plating in a high-Al bath at a high impregnating
sheet temperature defined.by the relation to the
concentration of Al to suppress alloying reaction,
and then performing an alloying treatment so that an
outlet side sheet temperature becomes higher than
4 9 5 ^ to 52 0°C in an alloying furnace in a highfrequency
induction heating system (see, for example,
Patent Literature 1 ) . Further, there has been also
proposed a manufacturing method of a galvannealed
steel sheet in which hot-dip galvanizing is performed
to be immediately held for 2 to 120 seconds in a
temperature region of 460 to 530^, and then is cooled
to 250°C or lower at a cooling rate of S'C/second or
more to form an alloyed plating layer with a 6 i
single phase (see, for example, Patent Literature 2 ).
Further, in order to achieve both surface slidability
and powdering resistance, there has been also
proposed a manufacturing method of a galvannealed
steel sheet in which in an alloying treatment when
manufacturing the galvannealed steel sheet, a
temperature pattern of the alloying treatment is
determined based on a temperature distribution
obtained by multiplying each temperature (T) and each
time (t) during heating * cooling together and adding
the resultants (see, for example, Patent Literature
3) .
[0011] The object of each of these prior techniques
is to, by controlling the alloying degree, achieve
hardening of an alloyed hot-dip galvanizing layer and
- 4 -
attain achievement of both powdering resistance and
flaking resistance to be disadvantages during press
forming of the galvannealed steel sheet.
[0012] Further, the slidability is greatly affected
by a surface flat portion, and therefore there has
been proposed a technique of obtaining a galvannealed
steel sheet excellent in slidability that has good
powdering resistance even in a plating film with a
lot of t, phases existing in a surface layer by
controlling a surface flat portion (see, for example,
Patent Literature 4 ).
[0013} The object of this technique is to obtain a
galvannealed steel sheet excellent in slidability
that has good powdering resistance even in a plating
film with a lot of C phases existing in a surface
layer by decreasing the alloying degree. However, it
is conceived that further improvement in slidability
resistance is important because the flaking
resistance (slidability resistance) is not sufficient
[0014] Further, as a method of improving press
formability of a zinc-based plated steel sheet
additionally, there has been widely used a method of
applying a high-viscosity lubrication oil. However,
there are caused problems such that because the
lubrication oil is high in viscosity, painting
defects occur in a painting process due to degreasing
failure and press performance becomes unstable due to
a lack of oil during pressing.
[0015] Therefore, there have been proposed a
- 5 -
technique of forming a ZnO-based oxide film on the
surface of a zinc-based plated steel sheet (see, for
example, Patent Literature 5) and a technique of
forming an oxide film of Ni oxide {see, for example,
Patent Literature 6). However, there is a problem
that these oxide films are poor in conversion
treatability.
[0016] Thus, there has been proposed a technique of
forming an Mn-based oxide film as a film whose
conversion treatability is improved {see, for example,
Patent Literature 7 ) . However, in each of these
techniques of forming the oxide-based film, the
relationship with the structure of an alloyed hot-dip.
galvanizing layer has not been examined concretely.
[0017] In Patent Literature 8, pre-plating has been
proposed, but only the powdering resistance has been
evaluated and no improvement of the flaking
resistance has been made. Further, in Patent
Literature 9, a T.2 phase has been proposed, but only
the powdering resistance has been evaluated and no
improvement of the flaking resistance has been made.
Further, in Patent Literature 10, evaluations of the
powdering resistance and the slidability have been
performed, but further stability is sometimes
required at the time of press forming such that a
sheet thickness is reduced practically.
CITATION LIST
PATENT LITERATURE
[0018] Patent Literature 1: Japanese Laid-open
- 6 -
Patent Publication No. 09-165662
Patent Literature 2: Japanese Laid-open Patent
Publication No. 2007-131910
Patent Literature 3: Japanese Laid-open Patent
Publication No. 2005-054199
Patent Literature 4 : Japanese Laid-open Patent
Publication No. 2005-048198
Patent Literature 5: Japanese Laid-open Patent
Publication No. 53-060332
Patent Literature 6: Japanese Laid-open Patent
Publication No. 03-191093
Patent Literature 7 : Japanese Laid-open Patent
Publication No. 03-249182
Patent Literature 8: Japanese Laid-open Patent
Publication No. 2010-265525
Patent Literature 9: Japanese Laid-open Patent
Publication No. 10-306361
Patent Literature 10: International Publication
Pamphlet No. WO 2010/089910
SUMMARY OF INVENTION
TECHNICAL PROBLEM
[0019] In consideration of the current situations of
the prior techniques, an object of the present
invention is to provide a galvannealed steel sheet
that achieves both flaking resistance (surface
slidability} and powdering resistance during press
forming and a manufacturing method thereof.
SOLUTION TO PROBLEM
[0020] In an alloying treatment of alloying hot-dip
_ 7 _
galvanizing, when a high-alloying treatment is
performed, a lot of F phases and F1 phases are
generated and the flaking resistance (surface
slidability) during press forming are improved, but
the powdering resistance deteriorates.
[0021] On the other hand, when a low-alloying
treatment is performed in the alloying treatment, V
phases and Fi phases are less generated, C phases are
increased, and the powdering resistance during press
forming is improved, but the surface slidability
(flaking resistance) deteriorate. In the
galvannealed steel sheet, generation of the F phases
and the F ± phases cannot be prevented.
[0022] Thus, the present inventors focused on a
plating microstructure in the vicinity of a steel
sheet and earnestly examined formation of a structure
in which a crack does not propagate easily. As a
result, they found findings that pre-plating is
applied, a heat input during alloying is adjusted,
and a content percentage of pre-plating metal to be
contained in the F phase is maintained to a fixed
value or more, thereby making it possible to
fabricate a plating structure excellent in powdering
resistance in which crack propagation during working
is suppressed, and further controlling an iron
content percentage of a plating layer in a
predetermined range makes it possible to obtain
plating excellent also in flaking resistance.
[0023] Further, they found findings that a preplating
weight to be provided according to the degree
of working that a plated.steel sheet is subjected to
is adjusted, thereby making it possible to provide an
effect of sufficiently improving the powdering
resistance.
[0024] The present invention has been made based on
the above-described findings, and the gist thereof is
as follows.
[0025] (1) A galvannealed steel sheet, includes: a
base iron; and a plating layer containing 7.2 to 10.6
mass% of Fe, 0.2 to 0.4 mass% of Al, and 0.1 mass% or
more in total of one type or more types selected from
the group consisting of Ni, Co, Cu, and In, and the
balance being composed of Zn and impurities,
wherein
the plating layer is formed on a surface of the
base iron, in a vertical cross-section of the plating
layer, an average thickness of a C phase is 0.2 fj,m
or less,
and an average thickness of T phases existing in
contact with the base iron is 0.5 M m or less,
wherein
in the V phase, the one type or more types
selected from the group consisting of Ni, Co, Cu, and
In are contained 0.5 mass% or more in total in total
in the F phase, and,
wherein
a phase existing in contact with the T phase is
a mixed phase of r i phase and 5 phase, and a d phase
- 9 -
percentage defined by Expression (1) below is 10% or
more.
[0026] d phase percentage = (5 phase/T phase
contact interface length)/(5 phase/T phase contact
interface length + Ti phase/V phase contact interface
length) X 100 • • * (1)
Here, the 5 phase/F phase contact interface
length is the length of the interface at which the 5
phase and the T phase are in contact, and the Fi
phase/r phase contact interface length is the length
of the interface at which the r i phase and the T
phase are in contact.
[0027] (2) A manufacturing method of a galvannealed
steel sheet to manufacture the galvannealed steel
sheet that is subjected to press working with a sheet
thickness reduction percentage (%) of 5% or more, the
method includes:
calculating a necessary pre-plating weight (g/m2)
based on the sheet thickness reduction percentage (%)
during press working of the galvannealed steel sheet
according to Expression (2) below, pre-plating with
the calculated necessary pre-plating weight (g/m2) or
more in total of one type or more types selected from
the group consisting of Ni, Co, Cu, and In on a base
iron, and dipping the pre-plated base iron into a
plating bath containing 0.1 to 0.3 mass% of Al to
perform galvanizing thereon; and
next after the temperature reaching a maximum
temperature at the exit of a heating furnace,
- 10 -
performing slow cooling in a soaking furnace
adjusting a temperature integral value S calculated
by Expression (3) below in a range of 300 or more to
less than 800 and performing an alloying treatment.
Necessary pre-plating weight (g/m2) = 0.0222
X sheet thickness reduction percentage (%) -
0.0625 (2
S = (Tii - To) X ti/2
+ C (Tlt - T0) + the Fi phase —*• the 6 phase —» the C
phase as the Fe concentration becomes lower.
[0005] As for the hardness of these phases, it is
about 505 Hv in the Fi phase in Vickers hardness,
which is the highest, and next it is about 326 Hv in
the r phase, it i.s about 284 to 300 Hv in the fi
phase, and it is about 200 Hv in the C phase.
Particularly, the T phase and the r i phase existing
in a plating layer region close to the surface of the
steel sheet (at a plated steel sheet interface) are
hard, and in an upper region of the plating layer,
the soft C phase is generated.
[0006] The £ phase is soft, likely to adhere to a
press die, has a high friction coefficient, and is
poor in slidability. Therefore, the C phase results
in the trigger that causes a phenomenon in which the
- 2 -
plating layer adheres to a die to peel off when
severe press forming is performed, (which will be
flaking, hereinafter). Further, the V phase and the
r i phase are hard and brittle, to thus result in the
trigger that causes a phenomenon in which the plating
layer turns powdery to peel off during press forming,
(which will be powdering, hereinafter).
[0007] It is important that the slidability should
be good when the galvannealed steel sheet is press
formed. Therefore, in terms of the slidability, as
the plating layer, a film having a high Fe
concentration that is. alloyed to a high alloying
degree, has high hardness, has a high melting point,
and is unlikely to cause adhesion is effective, but
powdering becomes likely to be caused.
[0008] On the other hand, when a plating layer
having a low Fe concentration that is alloyed to a
low alloying degree and suppresses generations of the
r phase and the T i phase is employed in order to
prevent the powdering, the slidability deteriorates
and the flaking becomes likely to be caused.
[0009] In order to improve the press formability of
the galvannealed steel sheet, the properties contrary
to each other, which are slidability and powdering,
are required to be both achieved.
[ 0010] As a technique to improve the press
formability of the galvannealed steel sheet, there
has been so far proposed a method of manufacturing a
Si-based galvannealed steel sheet by performing
_ 3 _
plating in a high-Al bath at a high impregnating
sheet temperature defined.by the relation to the
concentration of Al to suppress alloying reaction,
and then performing an alloying treatment so that an
outlet side sheet temperature becomes higher than
4 9 5 ^ to 52 0°C in an alloying furnace in a highfrequency
induction heating system (see, for example,
Patent Literature 1 ) . Further, there has been also
proposed a manufacturing method of a galvannealed
steel sheet in which hot-dip galvanizing is performed
to be immediately held for 2 to 120 seconds in a
temperature region of 460 to 530^, and then is cooled
to 250°C or lower at a cooling rate of S'C/second or
more to form an alloyed plating layer with a 6 i
single phase (see, for example, Patent Literature 2 ).
Further, in order to achieve both surface slidability
and powdering resistance, there has been also
proposed a manufacturing method of a galvannealed
steel sheet in which in an alloying treatment when
manufacturing the galvannealed steel sheet, a
temperature pattern of the alloying treatment is
determined based on a temperature distribution
obtained by multiplying each temperature (T) and each
time (t) during heating * cooling together and adding
the resultants (see, for example, Patent Literature
3) .
[0011] The object of each of these prior techniques
is to, by controlling the alloying degree, achieve
hardening of an alloyed hot-dip galvanizing layer and
- 4 -
attain achievement of both powdering resistance and
flaking resistance to be disadvantages during press
forming of the galvannealed steel sheet.
[0012] Further, the slidability is greatly affected
by a surface flat portion, and therefore there has
been proposed a technique of obtaining a galvannealed
steel sheet excellent in slidability that has good
powdering resistance even in a plating film with a
lot of t, phases existing in a surface layer by
controlling a surface flat portion (see, for example,
Patent Literature 4 ).
[0013} The object of this technique is to obtain a
galvannealed steel sheet excellent in slidability
that has good powdering resistance even in a plating
film with a lot of C phases existing in a surface
layer by decreasing the alloying degree. However, it
is conceived that further improvement in slidability
resistance is important because the flaking
resistance (slidability resistance) is not sufficient
[0014] Further, as a method of improving press
formability of a zinc-based plated steel sheet
additionally, there has been widely used a method of
applying a high-viscosity lubrication oil. However,
there are caused problems such that because the
lubrication oil is high in viscosity, painting
defects occur in a painting process due to degreasing
failure and press performance becomes unstable due to
a lack of oil during pressing.
[0015] Therefore, there have been proposed a
- 5 -
technique of forming a ZnO-based oxide film on the
surface of a zinc-based plated steel sheet (see, for
example, Patent Literature 5) and a technique of
forming an oxide film of Ni oxide {see, for example,
Patent Literature 6). However, there is a problem
that these oxide films are poor in conversion
treatability.
[0016] Thus, there has been proposed a technique of
forming an Mn-based oxide film as a film whose
conversion treatability is improved {see, for example,
Patent Literature 7 ) . However, in each of these
techniques of forming the oxide-based film, the
relationship with the structure of an alloyed hot-dip.
galvanizing layer has not been examined concretely.
[0017] In Patent Literature 8, pre-plating has been
proposed, but only the powdering resistance has been
evaluated and no improvement of the flaking
resistance has been made. Further, in Patent
Literature 9, a T.2 phase has been proposed, but only
the powdering resistance has been evaluated and no
improvement of the flaking resistance has been made.
Further, in Patent Literature 10, evaluations of the
powdering resistance and the slidability have been
performed, but further stability is sometimes
required at the time of press forming such that a
sheet thickness is reduced practically.
CITATION LIST
PATENT LITERATURE
[0018] Patent Literature 1: Japanese Laid-open
- 6 -
Patent Publication No. 09-165662
Patent Literature 2: Japanese Laid-open Patent
Publication No. 2007-131910
Patent Literature 3: Japanese Laid-open Patent
Publication No. 2005-054199
Patent Literature 4 : Japanese Laid-open Patent
Publication No. 2005-048198
Patent Literature 5: Japanese Laid-open Patent
Publication No. 53-060332
Patent Literature 6: Japanese Laid-open Patent
Publication No. 03-191093
Patent Literature 7 : Japanese Laid-open Patent
Publication No. 03-249182
Patent Literature 8: Japanese Laid-open Patent
Publication No. 2010-265525
Patent Literature 9: Japanese Laid-open Patent
Publication No. 10-306361
Patent Literature 10: International Publication
Pamphlet No. WO 2010/089910
SUMMARY OF INVENTION
TECHNICAL PROBLEM
[0019] In consideration of the current situations of
the prior techniques, an object of the present
invention is to provide a galvannealed steel sheet
that achieves both flaking resistance (surface
slidability} and powdering resistance during press
forming and a manufacturing method thereof.
SOLUTION TO PROBLEM
[0020] In an alloying treatment of alloying hot-dip
_ 7 _
galvanizing, when a high-alloying treatment is
performed, a lot of F phases and F1 phases are
generated and the flaking resistance (surface
slidability) during press forming are improved, but
the powdering resistance deteriorates.
[0021] On the other hand, when a low-alloying
treatment is performed in the alloying treatment, V
phases and Fi phases are less generated, C phases are
increased, and the powdering resistance during press
forming is improved, but the surface slidability
(flaking resistance) deteriorate. In the
galvannealed steel sheet, generation of the F phases
and the F ± phases cannot be prevented.
[0022] Thus, the present inventors focused on a
plating microstructure in the vicinity of a steel
sheet and earnestly examined formation of a structure
in which a crack does not propagate easily. As a
result, they found findings that pre-plating is
applied, a heat input during alloying is adjusted,
and a content percentage of pre-plating metal to be
contained in the F phase is maintained to a fixed
value or more, thereby making it possible to
fabricate a plating structure excellent in powdering
resistance in which crack propagation during working
is suppressed, and further controlling an iron
content percentage of a plating layer in a
predetermined range makes it possible to obtain
plating excellent also in flaking resistance.
[0023] Further, they found findings that a preplating
weight to be provided according to the degree
of working that a plated.steel sheet is subjected to
is adjusted, thereby making it possible to provide an
effect of sufficiently improving the powdering
resistance.
[0024] The present invention has been made based on
the above-described findings, and the gist thereof is
as follows.
[0025] (1) A galvannealed steel sheet, includes: a
base iron; and a plating layer containing 7.2 to 10.6
mass% of Fe, 0.2 to 0.4 mass% of Al, and 0.1 mass% or
more in total of one type or more types selected from
the group consisting of Ni, Co, Cu, and In, and the
balance being composed of Zn and impurities,
wherein
the plating layer is formed on a surface of the
base iron, in a vertical cross-section of the plating
layer, an average thickness of a C phase is 0.2 fj,m
or less,
and an average thickness of T phases existing in
contact with the base iron is 0.5 M m or less,
wherein
in the V phase, the one type or more types
selected from the group consisting of Ni, Co, Cu, and
In are contained 0.5 mass% or more in total in total
in the F phase, and,
wherein
a phase existing in contact with the T phase is
a mixed phase of r i phase and 5 phase, and a d phase
- 9 -
percentage defined by Expression (1) below is 10% or
more.
[0026] d phase percentage = (5 phase/T phase
contact interface length)/(5 phase/T phase contact
interface length + Ti phase/V phase contact interface
length) X 100 • • * (1)
Here, the 5 phase/F phase contact interface
length is the length of the interface at which the 5
phase and the T phase are in contact, and the Fi
phase/r phase contact interface length is the length
of the interface at which the r i phase and the T
phase are in contact.
[0027] (2) A manufacturing method of a galvannealed
steel sheet to manufacture the galvannealed steel
sheet that is subjected to press working with a sheet
thickness reduction percentage (%) of 5% or more, the
method includes:
calculating a necessary pre-plating weight (g/m2)
based on the sheet thickness reduction percentage (%)
during press working of the galvannealed steel sheet
according to Expression (2) below, pre-plating with
the calculated necessary pre-plating weight (g/m2) or
more in total of one type or more types selected from
the group consisting of Ni, Co, Cu, and In on a base
iron, and dipping the pre-plated base iron into a
plating bath containing 0.1 to 0.3 mass% of Al to
perform galvanizing thereon; and
next after the temperature reaching a maximum
temperature at the exit of a heating furnace,
- 10 -
performing slow cooling in a soaking furnace
adjusting a temperature integral value S calculated
by Expression (3) below in a range of 300 or more to
less than 800 and performing an alloying treatment.
Necessary pre-plating weight (g/m2) = 0.0222
X sheet thickness reduction percentage (%) -
0.0625 (2
S = (Tii - To) X ti/2
+ C (Tlt - T0) +
Documents
Orders
Section
Controller
Decision Date
Application Documents
#
Name
Date
1
9886-DELNP-2015-IntimationOfGrant25-04-2024.pdf
2024-04-25
1
Priority Document [21-10-2015(online)].pdf
2015-10-21
2
9886-DELNP-2015-PatentCertificate25-04-2024.pdf
2024-04-25
2
Power of Attorney [21-10-2015(online)].pdf
2015-10-21
3
Form 5 [21-10-2015(online)].pdf
2015-10-21
3
9886-DELNP-2015-Written submissions and relevant documents [29-01-2024(online)].pdf
2024-01-29
4
Form 3 [21-10-2015(online)].pdf
2015-10-21
4
9886-DELNP-2015-PETITION UNDER RULE 138 [22-12-2023(online)].pdf
2023-12-22
5
Form 18 [21-10-2015(online)].pdf
2015-10-21
5
9886-DELNP-2015-FORM 3 [15-12-2023(online)].pdf
2023-12-15
6
Form 1 [21-10-2015(online)].pdf
2015-10-21
6
9886-DELNP-2015-Correspondence to notify the Controller [08-12-2023(online)].pdf