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Galvannealed Steel Plate And Method For Manufacturing Same

Abstract: A plating layer containing 7.2-10.6 mass% Fe, 0.2-0.4 mass% Al, and 0.1 mass% N i and the like, the balance comprising Z n and impurities, wherein a galvannealed steel plate having excellent press formability is characterized in being provided with the plating layer in which, in the vertical section of the plating layer, the average thickness of a £, phase is no greater than 0.2 urn, and the average thickness of a T phase that exists in contact with the base steel is no greater than 0.5 urn, and within the T phase, Ni and the like is contained at a ratio within the T phase of at least 0.5 mass%, the phase that exists in contact with the T phase being a mixed phase of a TI phase and a 8 phase, the 8 phase ratio defined in the following equation being at least 10%: 8 phase ratio=( 8 phase/ T phase contact interface length)/( 8 phase/ r phase contact interface length -t Ti Phase / r phase contact interface length) x 100, such that here, the 8 phase/ T phase contact interface length is the length of the interface at which the 8 phase and the T phase are in contact, and the ri phase/T phase contact interface length is the length of the interface at which the Ti Phase and the T phase are in contact.

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Patent Information

Application #
Filing Date
21 October 2015
Publication Number
12/2016
Publication Type
INA
Invention Field
CHEMICAL
Status
Email
remfry-sagar@remfry.com
Parent Application
Patent Number
Legal Status
Grant Date
2024-04-25
Renewal Date

Applicants

NIPPON STEEL & SUMITOMO METAL CORPORATION
6 1 Marunouchi 2 chome Chiyoda ku Tokyo 1008071

Inventors

1. KUROSAKI Masao
c/o NIPPON STEEL & SUMITOMO METAL CORPORATION 6 1 Marunouchi 2 chome Chiyoda ku Tokyo 1008071
2. MAKI Jun
c/o NIPPON STEEL & SUMITOMO METAL CORPORATION 6 1 Marunouchi 2 chome Chiyoda ku Tokyo 1008071
3. YAMANAKA Shintaro
c/o NIPPON STEEL & SUMITOMO METAL CORPORATION 6 1 Marunouchi 2 chome Chiyoda ku Tokyo 1008071
4. TANAKA Hiroyuki
c/o NIPPON STEEL & SUMITOMO METAL CORPORATION 6 1 Marunouchi 2 chome Chiyoda ku Tokyo 1008071

Specification

TECHNICAL FIELD [0001] ., The present invention relates to a galvannealed steel sheet used for press forming of automobiles, home electric appliances, construction materials and the like and a manufacturing method thereof, and particularly relates to a galvannealed steel sheet excellent in slidability (flaking resistance), powdering resistance, and conversion treatability and a manufacturing method thereof. BACKGROUND ART [0002] A galvannealed steel sheet is excellent in weldability and paintability as compared to a galvanized steel sheet. Therefore, the galvannealed steel sheet is widely used in a wide range of fields of automobile vehicle bodies, and further home electric appliances, construction materials, and the like. The alloyed hot-dip galvanized steel sheet to be used for such usages is made available for use after being press formed normally. [0003] In a manufacturing method of the alloyed hotdip galvanized steel sheet, immediately after hot-dip galvanizing is performed on the surface of a steel sheet, heating to the melting point of zinc or higher and holding are performed to make Fe in the steel sheet diffuse into a plating layer. Then, alloying reaction with Zn is caused to generate a Zn-Fe alloy - 1 - phase. However, such an alloyed hot-dip galvanized steel sheet has the disadvantage of being poor in press formability as compared to a cold-rolled steel sheet. [0004] The cause of poor press formability lies in a structure of an alloyed hot-dip galvanizing layer. That is, a Zn-Fe alloy plating layer formed by making Fe in the steel sheet diffuse into the plating layer to cause alloying reaction with Zn is a plating layer composed of a F phase 11, a V% phase 12, a 5 i phase 13, and a £ phase 14 formed on a base iron 10 as schematically illustrated in Fig. 1 normally. Further, this plating layer changes in the order of the F phase —> the Fi phase —*• the 6 phase —» the C phase as the Fe concentration becomes lower. [0005] As for the hardness of these phases, it is about 505 Hv in the Fi phase in Vickers hardness, which is the highest, and next it is about 326 Hv in the r phase, it i.s about 284 to 300 Hv in the fi phase, and it is about 200 Hv in the C phase. Particularly, the T phase and the r i phase existing in a plating layer region close to the surface of the steel sheet (at a plated steel sheet interface) are hard, and in an upper region of the plating layer, the soft C phase is generated. [0006] The £ phase is soft, likely to adhere to a press die, has a high friction coefficient, and is poor in slidability. Therefore, the C phase results in the trigger that causes a phenomenon in which the - 2 - plating layer adheres to a die to peel off when severe press forming is performed, (which will be flaking, hereinafter). Further, the V phase and the r i phase are hard and brittle, to thus result in the trigger that causes a phenomenon in which the plating layer turns powdery to peel off during press forming, (which will be powdering, hereinafter). [0007] It is important that the slidability should be good when the galvannealed steel sheet is press formed. Therefore, in terms of the slidability, as the plating layer, a film having a high Fe concentration that is. alloyed to a high alloying degree, has high hardness, has a high melting point, and is unlikely to cause adhesion is effective, but powdering becomes likely to be caused. [0008] On the other hand, when a plating layer having a low Fe concentration that is alloyed to a low alloying degree and suppresses generations of the r phase and the T i phase is employed in order to prevent the powdering, the slidability deteriorates and the flaking becomes likely to be caused. [0009] In order to improve the press formability of the galvannealed steel sheet, the properties contrary to each other, which are slidability and powdering, are required to be both achieved. [ 0010] As a technique to improve the press formability of the galvannealed steel sheet, there has been so far proposed a method of manufacturing a Si-based galvannealed steel sheet by performing _ 3 _ plating in a high-Al bath at a high impregnating sheet temperature defined.by the relation to the concentration of Al to suppress alloying reaction, and then performing an alloying treatment so that an outlet side sheet temperature becomes higher than 4 9 5 ^ to 52 0°C in an alloying furnace in a highfrequency induction heating system (see, for example, Patent Literature 1 ) . Further, there has been also proposed a manufacturing method of a galvannealed steel sheet in which hot-dip galvanizing is performed to be immediately held for 2 to 120 seconds in a temperature region of 460 to 530^, and then is cooled to 250°C or lower at a cooling rate of S'C/second or more to form an alloyed plating layer with a 6 i single phase (see, for example, Patent Literature 2 ). Further, in order to achieve both surface slidability and powdering resistance, there has been also proposed a manufacturing method of a galvannealed steel sheet in which in an alloying treatment when manufacturing the galvannealed steel sheet, a temperature pattern of the alloying treatment is determined based on a temperature distribution obtained by multiplying each temperature (T) and each time (t) during heating * cooling together and adding the resultants (see, for example, Patent Literature 3) . [0011] The object of each of these prior techniques is to, by controlling the alloying degree, achieve hardening of an alloyed hot-dip galvanizing layer and - 4 - attain achievement of both powdering resistance and flaking resistance to be disadvantages during press forming of the galvannealed steel sheet. [0012] Further, the slidability is greatly affected by a surface flat portion, and therefore there has been proposed a technique of obtaining a galvannealed steel sheet excellent in slidability that has good powdering resistance even in a plating film with a lot of t, phases existing in a surface layer by controlling a surface flat portion (see, for example, Patent Literature 4 ). [0013} The object of this technique is to obtain a galvannealed steel sheet excellent in slidability that has good powdering resistance even in a plating film with a lot of C phases existing in a surface layer by decreasing the alloying degree. However, it is conceived that further improvement in slidability resistance is important because the flaking resistance (slidability resistance) is not sufficient [0014] Further, as a method of improving press formability of a zinc-based plated steel sheet additionally, there has been widely used a method of applying a high-viscosity lubrication oil. However, there are caused problems such that because the lubrication oil is high in viscosity, painting defects occur in a painting process due to degreasing failure and press performance becomes unstable due to a lack of oil during pressing. [0015] Therefore, there have been proposed a - 5 - technique of forming a ZnO-based oxide film on the surface of a zinc-based plated steel sheet (see, for example, Patent Literature 5) and a technique of forming an oxide film of Ni oxide {see, for example, Patent Literature 6). However, there is a problem that these oxide films are poor in conversion treatability. [0016] Thus, there has been proposed a technique of forming an Mn-based oxide film as a film whose conversion treatability is improved {see, for example, Patent Literature 7 ) . However, in each of these techniques of forming the oxide-based film, the relationship with the structure of an alloyed hot-dip. galvanizing layer has not been examined concretely. [0017] In Patent Literature 8, pre-plating has been proposed, but only the powdering resistance has been evaluated and no improvement of the flaking resistance has been made. Further, in Patent Literature 9, a T.2 phase has been proposed, but only the powdering resistance has been evaluated and no improvement of the flaking resistance has been made. Further, in Patent Literature 10, evaluations of the powdering resistance and the slidability have been performed, but further stability is sometimes required at the time of press forming such that a sheet thickness is reduced practically. CITATION LIST PATENT LITERATURE [0018] Patent Literature 1: Japanese Laid-open - 6 - Patent Publication No. 09-165662 Patent Literature 2: Japanese Laid-open Patent Publication No. 2007-131910 Patent Literature 3: Japanese Laid-open Patent Publication No. 2005-054199 Patent Literature 4 : Japanese Laid-open Patent Publication No. 2005-048198 Patent Literature 5: Japanese Laid-open Patent Publication No. 53-060332 Patent Literature 6: Japanese Laid-open Patent Publication No. 03-191093 Patent Literature 7 : Japanese Laid-open Patent Publication No. 03-249182 Patent Literature 8: Japanese Laid-open Patent Publication No. 2010-265525 Patent Literature 9: Japanese Laid-open Patent Publication No. 10-306361 Patent Literature 10: International Publication Pamphlet No. WO 2010/089910 SUMMARY OF INVENTION TECHNICAL PROBLEM [0019] In consideration of the current situations of the prior techniques, an object of the present invention is to provide a galvannealed steel sheet that achieves both flaking resistance (surface slidability} and powdering resistance during press forming and a manufacturing method thereof. SOLUTION TO PROBLEM [0020] In an alloying treatment of alloying hot-dip _ 7 _ galvanizing, when a high-alloying treatment is performed, a lot of F phases and F1 phases are generated and the flaking resistance (surface slidability) during press forming are improved, but the powdering resistance deteriorates. [0021] On the other hand, when a low-alloying treatment is performed in the alloying treatment, V phases and Fi phases are less generated, C phases are increased, and the powdering resistance during press forming is improved, but the surface slidability (flaking resistance) deteriorate. In the galvannealed steel sheet, generation of the F phases and the F ± phases cannot be prevented. [0022] Thus, the present inventors focused on a plating microstructure in the vicinity of a steel sheet and earnestly examined formation of a structure in which a crack does not propagate easily. As a result, they found findings that pre-plating is applied, a heat input during alloying is adjusted, and a content percentage of pre-plating metal to be contained in the F phase is maintained to a fixed value or more, thereby making it possible to fabricate a plating structure excellent in powdering resistance in which crack propagation during working is suppressed, and further controlling an iron content percentage of a plating layer in a predetermined range makes it possible to obtain plating excellent also in flaking resistance. [0023] Further, they found findings that a preplating weight to be provided according to the degree of working that a plated.steel sheet is subjected to is adjusted, thereby making it possible to provide an effect of sufficiently improving the powdering resistance. [0024] The present invention has been made based on the above-described findings, and the gist thereof is as follows. [0025] (1) A galvannealed steel sheet, includes: a base iron; and a plating layer containing 7.2 to 10.6 mass% of Fe, 0.2 to 0.4 mass% of Al, and 0.1 mass% or more in total of one type or more types selected from the group consisting of Ni, Co, Cu, and In, and the balance being composed of Zn and impurities, wherein the plating layer is formed on a surface of the base iron, in a vertical cross-section of the plating layer, an average thickness of a C phase is 0.2 fj,m or less, and an average thickness of T phases existing in contact with the base iron is 0.5 M m or less, wherein in the V phase, the one type or more types selected from the group consisting of Ni, Co, Cu, and In are contained 0.5 mass% or more in total in total in the F phase, and, wherein a phase existing in contact with the T phase is a mixed phase of r i phase and 5 phase, and a d phase - 9 - percentage defined by Expression (1) below is 10% or more. [0026] d phase percentage = (5 phase/T phase contact interface length)/(5 phase/T phase contact interface length + Ti phase/V phase contact interface length) X 100 • • * (1) Here, the 5 phase/F phase contact interface length is the length of the interface at which the 5 phase and the T phase are in contact, and the Fi phase/r phase contact interface length is the length of the interface at which the r i phase and the T phase are in contact. [0027] (2) A manufacturing method of a galvannealed steel sheet to manufacture the galvannealed steel sheet that is subjected to press working with a sheet thickness reduction percentage (%) of 5% or more, the method includes: calculating a necessary pre-plating weight (g/m2) based on the sheet thickness reduction percentage (%) during press working of the galvannealed steel sheet according to Expression (2) below, pre-plating with the calculated necessary pre-plating weight (g/m2) or more in total of one type or more types selected from the group consisting of Ni, Co, Cu, and In on a base iron, and dipping the pre-plated base iron into a plating bath containing 0.1 to 0.3 mass% of Al to perform galvanizing thereon; and next after the temperature reaching a maximum temperature at the exit of a heating furnace, - 10 - performing slow cooling in a soaking furnace adjusting a temperature integral value S calculated by Expression (3) below in a range of 300 or more to less than 800 and performing an alloying treatment. Necessary pre-plating weight (g/m2) = 0.0222 X sheet thickness reduction percentage (%) - 0.0625 (2 S = (Tii - To) X ti/2 + C (Tlt - T0) + the Fi phase —*• the 6 phase —» the C phase as the Fe concentration becomes lower. [0005] As for the hardness of these phases, it is about 505 Hv in the Fi phase in Vickers hardness, which is the highest, and next it is about 326 Hv in the r phase, it i.s about 284 to 300 Hv in the fi phase, and it is about 200 Hv in the C phase. Particularly, the T phase and the r i phase existing in a plating layer region close to the surface of the steel sheet (at a plated steel sheet interface) are hard, and in an upper region of the plating layer, the soft C phase is generated. [0006] The £ phase is soft, likely to adhere to a press die, has a high friction coefficient, and is poor in slidability. Therefore, the C phase results in the trigger that causes a phenomenon in which the - 2 - plating layer adheres to a die to peel off when severe press forming is performed, (which will be flaking, hereinafter). Further, the V phase and the r i phase are hard and brittle, to thus result in the trigger that causes a phenomenon in which the plating layer turns powdery to peel off during press forming, (which will be powdering, hereinafter). [0007] It is important that the slidability should be good when the galvannealed steel sheet is press formed. Therefore, in terms of the slidability, as the plating layer, a film having a high Fe concentration that is. alloyed to a high alloying degree, has high hardness, has a high melting point, and is unlikely to cause adhesion is effective, but powdering becomes likely to be caused. [0008] On the other hand, when a plating layer having a low Fe concentration that is alloyed to a low alloying degree and suppresses generations of the r phase and the T i phase is employed in order to prevent the powdering, the slidability deteriorates and the flaking becomes likely to be caused. [0009] In order to improve the press formability of the galvannealed steel sheet, the properties contrary to each other, which are slidability and powdering, are required to be both achieved. [ 0010] As a technique to improve the press formability of the galvannealed steel sheet, there has been so far proposed a method of manufacturing a Si-based galvannealed steel sheet by performing _ 3 _ plating in a high-Al bath at a high impregnating sheet temperature defined.by the relation to the concentration of Al to suppress alloying reaction, and then performing an alloying treatment so that an outlet side sheet temperature becomes higher than 4 9 5 ^ to 52 0°C in an alloying furnace in a highfrequency induction heating system (see, for example, Patent Literature 1 ) . Further, there has been also proposed a manufacturing method of a galvannealed steel sheet in which hot-dip galvanizing is performed to be immediately held for 2 to 120 seconds in a temperature region of 460 to 530^, and then is cooled to 250°C or lower at a cooling rate of S'C/second or more to form an alloyed plating layer with a 6 i single phase (see, for example, Patent Literature 2 ). Further, in order to achieve both surface slidability and powdering resistance, there has been also proposed a manufacturing method of a galvannealed steel sheet in which in an alloying treatment when manufacturing the galvannealed steel sheet, a temperature pattern of the alloying treatment is determined based on a temperature distribution obtained by multiplying each temperature (T) and each time (t) during heating * cooling together and adding the resultants (see, for example, Patent Literature 3) . [0011] The object of each of these prior techniques is to, by controlling the alloying degree, achieve hardening of an alloyed hot-dip galvanizing layer and - 4 - attain achievement of both powdering resistance and flaking resistance to be disadvantages during press forming of the galvannealed steel sheet. [0012] Further, the slidability is greatly affected by a surface flat portion, and therefore there has been proposed a technique of obtaining a galvannealed steel sheet excellent in slidability that has good powdering resistance even in a plating film with a lot of t, phases existing in a surface layer by controlling a surface flat portion (see, for example, Patent Literature 4 ). [0013} The object of this technique is to obtain a galvannealed steel sheet excellent in slidability that has good powdering resistance even in a plating film with a lot of C phases existing in a surface layer by decreasing the alloying degree. However, it is conceived that further improvement in slidability resistance is important because the flaking resistance (slidability resistance) is not sufficient [0014] Further, as a method of improving press formability of a zinc-based plated steel sheet additionally, there has been widely used a method of applying a high-viscosity lubrication oil. However, there are caused problems such that because the lubrication oil is high in viscosity, painting defects occur in a painting process due to degreasing failure and press performance becomes unstable due to a lack of oil during pressing. [0015] Therefore, there have been proposed a - 5 - technique of forming a ZnO-based oxide film on the surface of a zinc-based plated steel sheet (see, for example, Patent Literature 5) and a technique of forming an oxide film of Ni oxide {see, for example, Patent Literature 6). However, there is a problem that these oxide films are poor in conversion treatability. [0016] Thus, there has been proposed a technique of forming an Mn-based oxide film as a film whose conversion treatability is improved {see, for example, Patent Literature 7 ) . However, in each of these techniques of forming the oxide-based film, the relationship with the structure of an alloyed hot-dip. galvanizing layer has not been examined concretely. [0017] In Patent Literature 8, pre-plating has been proposed, but only the powdering resistance has been evaluated and no improvement of the flaking resistance has been made. Further, in Patent Literature 9, a T.2 phase has been proposed, but only the powdering resistance has been evaluated and no improvement of the flaking resistance has been made. Further, in Patent Literature 10, evaluations of the powdering resistance and the slidability have been performed, but further stability is sometimes required at the time of press forming such that a sheet thickness is reduced practically. CITATION LIST PATENT LITERATURE [0018] Patent Literature 1: Japanese Laid-open - 6 - Patent Publication No. 09-165662 Patent Literature 2: Japanese Laid-open Patent Publication No. 2007-131910 Patent Literature 3: Japanese Laid-open Patent Publication No. 2005-054199 Patent Literature 4 : Japanese Laid-open Patent Publication No. 2005-048198 Patent Literature 5: Japanese Laid-open Patent Publication No. 53-060332 Patent Literature 6: Japanese Laid-open Patent Publication No. 03-191093 Patent Literature 7 : Japanese Laid-open Patent Publication No. 03-249182 Patent Literature 8: Japanese Laid-open Patent Publication No. 2010-265525 Patent Literature 9: Japanese Laid-open Patent Publication No. 10-306361 Patent Literature 10: International Publication Pamphlet No. WO 2010/089910 SUMMARY OF INVENTION TECHNICAL PROBLEM [0019] In consideration of the current situations of the prior techniques, an object of the present invention is to provide a galvannealed steel sheet that achieves both flaking resistance (surface slidability} and powdering resistance during press forming and a manufacturing method thereof. SOLUTION TO PROBLEM [0020] In an alloying treatment of alloying hot-dip _ 7 _ galvanizing, when a high-alloying treatment is performed, a lot of F phases and F1 phases are generated and the flaking resistance (surface slidability) during press forming are improved, but the powdering resistance deteriorates. [0021] On the other hand, when a low-alloying treatment is performed in the alloying treatment, V phases and Fi phases are less generated, C phases are increased, and the powdering resistance during press forming is improved, but the surface slidability (flaking resistance) deteriorate. In the galvannealed steel sheet, generation of the F phases and the F ± phases cannot be prevented. [0022] Thus, the present inventors focused on a plating microstructure in the vicinity of a steel sheet and earnestly examined formation of a structure in which a crack does not propagate easily. As a result, they found findings that pre-plating is applied, a heat input during alloying is adjusted, and a content percentage of pre-plating metal to be contained in the F phase is maintained to a fixed value or more, thereby making it possible to fabricate a plating structure excellent in powdering resistance in which crack propagation during working is suppressed, and further controlling an iron content percentage of a plating layer in a predetermined range makes it possible to obtain plating excellent also in flaking resistance. [0023] Further, they found findings that a preplating weight to be provided according to the degree of working that a plated.steel sheet is subjected to is adjusted, thereby making it possible to provide an effect of sufficiently improving the powdering resistance. [0024] The present invention has been made based on the above-described findings, and the gist thereof is as follows. [0025] (1) A galvannealed steel sheet, includes: a base iron; and a plating layer containing 7.2 to 10.6 mass% of Fe, 0.2 to 0.4 mass% of Al, and 0.1 mass% or more in total of one type or more types selected from the group consisting of Ni, Co, Cu, and In, and the balance being composed of Zn and impurities, wherein the plating layer is formed on a surface of the base iron, in a vertical cross-section of the plating layer, an average thickness of a C phase is 0.2 fj,m or less, and an average thickness of T phases existing in contact with the base iron is 0.5 M m or less, wherein in the V phase, the one type or more types selected from the group consisting of Ni, Co, Cu, and In are contained 0.5 mass% or more in total in total in the F phase, and, wherein a phase existing in contact with the T phase is a mixed phase of r i phase and 5 phase, and a d phase - 9 - percentage defined by Expression (1) below is 10% or more. [0026] d phase percentage = (5 phase/T phase contact interface length)/(5 phase/T phase contact interface length + Ti phase/V phase contact interface length) X 100 • • * (1) Here, the 5 phase/F phase contact interface length is the length of the interface at which the 5 phase and the T phase are in contact, and the Fi phase/r phase contact interface length is the length of the interface at which the r i phase and the T phase are in contact. [0027] (2) A manufacturing method of a galvannealed steel sheet to manufacture the galvannealed steel sheet that is subjected to press working with a sheet thickness reduction percentage (%) of 5% or more, the method includes: calculating a necessary pre-plating weight (g/m2) based on the sheet thickness reduction percentage (%) during press working of the galvannealed steel sheet according to Expression (2) below, pre-plating with the calculated necessary pre-plating weight (g/m2) or more in total of one type or more types selected from the group consisting of Ni, Co, Cu, and In on a base iron, and dipping the pre-plated base iron into a plating bath containing 0.1 to 0.3 mass% of Al to perform galvanizing thereon; and next after the temperature reaching a maximum temperature at the exit of a heating furnace, - 10 - performing slow cooling in a soaking furnace adjusting a temperature integral value S calculated by Expression (3) below in a range of 300 or more to less than 800 and performing an alloying treatment. Necessary pre-plating weight (g/m2) = 0.0222 X sheet thickness reduction percentage (%) - 0.0625 (2 S = (Tii - To) X ti/2 + C (Tlt - T0) +

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# Name Date
1 9886-DELNP-2015-IntimationOfGrant25-04-2024.pdf 2024-04-25
1 Priority Document [21-10-2015(online)].pdf 2015-10-21
2 9886-DELNP-2015-PatentCertificate25-04-2024.pdf 2024-04-25
2 Power of Attorney [21-10-2015(online)].pdf 2015-10-21
3 Form 5 [21-10-2015(online)].pdf 2015-10-21
3 9886-DELNP-2015-Written submissions and relevant documents [29-01-2024(online)].pdf 2024-01-29
4 Form 3 [21-10-2015(online)].pdf 2015-10-21
4 9886-DELNP-2015-PETITION UNDER RULE 138 [22-12-2023(online)].pdf 2023-12-22
5 Form 18 [21-10-2015(online)].pdf 2015-10-21
5 9886-DELNP-2015-FORM 3 [15-12-2023(online)].pdf 2023-12-15
6 Form 1 [21-10-2015(online)].pdf 2015-10-21
6 9886-DELNP-2015-Correspondence to notify the Controller [08-12-2023(online)].pdf 2023-12-08
7 Drawing [21-10-2015(online)].pdf 2015-10-21
7 9886-DELNP-2015-US(14)-ExtendedHearingNotice-(HearingDate-14-12-2023).pdf 2023-11-15
8 Description(Complete) [21-10-2015(online)].pdf 2015-10-21
8 9886-delnp-2015-REQUEST FOR ADJOURNMENT OF HEARING UNDER RULE 129A [08-11-2023(online)].pdf 2023-11-08
9 9886-DELNP-2015-US(14)-ExtendedHearingNotice-(HearingDate-15-11-2023).pdf 2023-10-16
9 9886-DELNP-2015.pdf 2015-10-24
10 9886-DELNP-2015-REQUEST FOR ADJOURNMENT OF HEARING UNDER RULE 129A [12-10-2023(online)].pdf 2023-10-12
10 Other Document [17-12-2015(online)].pdf 2015-12-17
11 9886-DELNP-2015-US(14)-ExtendedHearingNotice-(HearingDate-17-10-2023).pdf 2023-09-19
11 Marked Copy [17-12-2015(online)].pdf 2015-12-17
12 9886-DELNP-2015-Written submissions and relevant documents [17-07-2023(online)].pdf 2023-07-17
12 Form 13 [17-12-2015(online)].pdf 2015-12-17
13 9886-DELNP-2015-PETITION UNDER RULE 138 [09-06-2023(online)].pdf 2023-06-09
13 Description(Complete) [17-12-2015(online)].pdf 2015-12-17
14 9886-DELNP-2015-Correspondence to notify the Controller [29-05-2023(online)].pdf 2023-05-29
14 9886-delnp-2015-Form-1-(18-12-2015).pdf 2015-12-18
15 9886-delnp-2015-Correspondence Others-(18-12-2015).pdf 2015-12-18
15 9886-DELNP-2015-US(14)-ExtendedHearingNotice-(HearingDate-02-06-2023).pdf 2023-05-03
16 9886-delnp-2015-PCT-(22-02-2016).pdf 2016-02-22
16 9886-delnp-2015-REQUEST FOR ADJOURNMENT OF HEARING UNDER RULE 129A [28-04-2023(online)].pdf 2023-04-28
17 9886-DELNP-2015-Response to office action [28-04-2023(online)].pdf 2023-04-28
17 9886-delnp-2015-Correspondence Other-(22-02-2016).pdf 2016-02-22
18 9886-delnp-2015-Form-3-(19-04-2016).pdf 2016-04-19
18 9886-DELNP-2015-US(14)-HearingNotice-(HearingDate-03-05-2023).pdf 2023-04-13
19 9886-delnp-2015-Correspondence Others-(19-04-2016).pdf 2016-04-19
19 9886-DELNP-2015-FER_SER_REPLY [31-01-2020(online)].pdf 2020-01-31
20 9886-delnp-2015-ABSTRACT [28-01-2020(online)].pdf 2020-01-28
20 9886-DELNP-2015-RELEVANT DOCUMENTS [06-06-2019(online)].pdf 2019-06-06
21 9886-delnp-2015-CLAIMS [28-01-2020(online)].pdf 2020-01-28
21 9886-DELNP-2015-FORM 13 [06-06-2019(online)].pdf 2019-06-06
22 9886-delnp-2015-COMPLETE SPECIFICATION [28-01-2020(online)].pdf 2020-01-28
22 9886-DELNP-2015-Power of Attorney-100619.pdf 2019-06-13
23 9886-delnp-2015-DRAWING [28-01-2020(online)].pdf 2020-01-28
23 9886-DELNP-2015-OTHERS-100619.pdf 2019-06-13
24 9886-delnp-2015-FER_SER_REPLY [28-01-2020(online)].pdf 2020-01-28
24 9886-DELNP-2015-Correspondence-100619.pdf 2019-06-13
25 9886-DELNP-2015-FER.pdf 2019-08-02
25 9886-delnp-2015-OTHERS [28-01-2020(online)].pdf 2020-01-28
26 9886-DELNP-2015-PETITION UNDER RULE 137 [28-01-2020(online)].pdf 2020-01-28
27 9886-DELNP-2015-FER.pdf 2019-08-02
27 9886-delnp-2015-OTHERS [28-01-2020(online)].pdf 2020-01-28
28 9886-DELNP-2015-Correspondence-100619.pdf 2019-06-13
28 9886-delnp-2015-FER_SER_REPLY [28-01-2020(online)].pdf 2020-01-28
29 9886-delnp-2015-DRAWING [28-01-2020(online)].pdf 2020-01-28
29 9886-DELNP-2015-OTHERS-100619.pdf 2019-06-13
30 9886-delnp-2015-COMPLETE SPECIFICATION [28-01-2020(online)].pdf 2020-01-28
30 9886-DELNP-2015-Power of Attorney-100619.pdf 2019-06-13
31 9886-delnp-2015-CLAIMS [28-01-2020(online)].pdf 2020-01-28
31 9886-DELNP-2015-FORM 13 [06-06-2019(online)].pdf 2019-06-06
32 9886-delnp-2015-ABSTRACT [28-01-2020(online)].pdf 2020-01-28
32 9886-DELNP-2015-RELEVANT DOCUMENTS [06-06-2019(online)].pdf 2019-06-06
33 9886-delnp-2015-Correspondence Others-(19-04-2016).pdf 2016-04-19
33 9886-DELNP-2015-FER_SER_REPLY [31-01-2020(online)].pdf 2020-01-31
34 9886-delnp-2015-Form-3-(19-04-2016).pdf 2016-04-19
34 9886-DELNP-2015-US(14)-HearingNotice-(HearingDate-03-05-2023).pdf 2023-04-13
35 9886-delnp-2015-Correspondence Other-(22-02-2016).pdf 2016-02-22
35 9886-DELNP-2015-Response to office action [28-04-2023(online)].pdf 2023-04-28
36 9886-delnp-2015-REQUEST FOR ADJOURNMENT OF HEARING UNDER RULE 129A [28-04-2023(online)].pdf 2023-04-28
36 9886-delnp-2015-PCT-(22-02-2016).pdf 2016-02-22
37 9886-DELNP-2015-US(14)-ExtendedHearingNotice-(HearingDate-02-06-2023).pdf 2023-05-03
37 9886-delnp-2015-Correspondence Others-(18-12-2015).pdf 2015-12-18
38 9886-DELNP-2015-Correspondence to notify the Controller [29-05-2023(online)].pdf 2023-05-29
38 9886-delnp-2015-Form-1-(18-12-2015).pdf 2015-12-18
39 9886-DELNP-2015-PETITION UNDER RULE 138 [09-06-2023(online)].pdf 2023-06-09
39 Description(Complete) [17-12-2015(online)].pdf 2015-12-17
40 9886-DELNP-2015-Written submissions and relevant documents [17-07-2023(online)].pdf 2023-07-17
40 Form 13 [17-12-2015(online)].pdf 2015-12-17
41 9886-DELNP-2015-US(14)-ExtendedHearingNotice-(HearingDate-17-10-2023).pdf 2023-09-19
41 Marked Copy [17-12-2015(online)].pdf 2015-12-17
42 9886-DELNP-2015-REQUEST FOR ADJOURNMENT OF HEARING UNDER RULE 129A [12-10-2023(online)].pdf 2023-10-12
42 Other Document [17-12-2015(online)].pdf 2015-12-17
43 9886-DELNP-2015-US(14)-ExtendedHearingNotice-(HearingDate-15-11-2023).pdf 2023-10-16
43 9886-DELNP-2015.pdf 2015-10-24
44 9886-delnp-2015-REQUEST FOR ADJOURNMENT OF HEARING UNDER RULE 129A [08-11-2023(online)].pdf 2023-11-08
44 Description(Complete) [21-10-2015(online)].pdf 2015-10-21
45 9886-DELNP-2015-US(14)-ExtendedHearingNotice-(HearingDate-14-12-2023).pdf 2023-11-15
45 Drawing [21-10-2015(online)].pdf 2015-10-21
46 Form 1 [21-10-2015(online)].pdf 2015-10-21
46 9886-DELNP-2015-Correspondence to notify the Controller [08-12-2023(online)].pdf 2023-12-08
47 Form 18 [21-10-2015(online)].pdf 2015-10-21
47 9886-DELNP-2015-FORM 3 [15-12-2023(online)].pdf 2023-12-15
48 Form 3 [21-10-2015(online)].pdf 2015-10-21
48 9886-DELNP-2015-PETITION UNDER RULE 138 [22-12-2023(online)].pdf 2023-12-22
49 Form 5 [21-10-2015(online)].pdf 2015-10-21
49 9886-DELNP-2015-Written submissions and relevant documents [29-01-2024(online)].pdf 2024-01-29
50 Power of Attorney [21-10-2015(online)].pdf 2015-10-21
50 9886-DELNP-2015-PatentCertificate25-04-2024.pdf 2024-04-25
51 9886-DELNP-2015-IntimationOfGrant25-04-2024.pdf 2024-04-25
51 Priority Document [21-10-2015(online)].pdf 2015-10-21

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