FORM - 2
THE PATENTS ACT, 1970
(39 of 1970)
&
The Patents Rules, 2003
COMPLETE SPECIFICATION
(See Section 10 and Rule 13)
HAIR CARE METHOD
HINDUSTAN UNILEVER LIMITED, a company incorporated under
the Indian Companies Act, 1913 and having its registered office
at 165/166, Backbay Reclamation, Mumbai -400 020, Maharashtra, India
The following specification particularly describes the invention and the manner in which it is to be performed

Hair Care Method
The present invention relates to a composition for improving detangling of hair.
Shampoo and conditioner formulations have been marketed for many years. Despite the prior art there remains the need for compositions which are able to prevent the tangling which occurs during shampooing.
The present invention relates to a method of treating hair comprising the step of applying to dry towel dried hair a hair care product comprising a non-surfactant esterified sugar which is non-crystalline at 20°C.
Also disclosed is the use of a non-surfactant esterified sugar, preferably sucrose acetate isobutyrate to prevent hair from tangling.
The invention has the further advantage that one application of non-surfac;tant esterified sugar has an effect on cumulative washing. Indeed, cumulative washing can enhance the de-tangli.ng effect.
Preferably the hair is dry.
It is preferred if the method of treating hair comprises the following steps:
i) applying to the hair a composition comprising a non-surfactant esterified sugar;
ii) followed by washing the hair.

Compositions of the invention are preferably pre-treatment compositions in that they are applied to dry hair. Shortly after application of the product (within 1 hour, more preferably within 5 minutes) the hair is washed then rinsed.
In the context of this invention towel dried hair can be defined such that lg of hair has less than 0.8g of water, preferably less than 0.6g associated with it. It should be noted that a dry switch of hair has negligible water associated with it and wet hair greater than lg of water associated with it.
Hair is washed in the conventional manner using any commercially available shampoo.
A particularly preferred product for the pre-treatment product is a spray, mousse, gel, serum/oil, cream or lotion. Spray products and/or serums are particularly preferred.
It is preferred if the non-surfactant esterified sugar has a alkyl chain length from C2 to C6. Preferably non-surfactant esterified sugar is a sucrose, particularly preferred is sucrose acetate isobutyrate.
The level of esterified sugar in the tangle prevention composition is preferably from 0.001 to 10 wt% of the total composition, more preferably from 0.01 to 5 wt%.
It is further preferred if the level of non-surfactant esterified sugar in the composition is such that it delivers

from 0.3 to 12 mg of sugar per g of hair, preferably from 0.6 to 6 mg, more preferably from 1 to 1.5 mg.
The composition may comprise a solvent for the non-surfactant esterified sugar. Suitable solvents include ethanol, isopropyl alcohol, n-propyl alcohol, n-butyl alcohol isobutyl alcohol, caprylic / capric triglycerides or mixtures thereof. Water may also be present with these solvents. Particularly preferred is ethanol, of particular benefit is an ethanol and water mix.
It is preferred if the weight ratio of non-surfactant esterified sugar to solvent is from 0.01:100 to 1:100.
Compositions of the invention may further comprise a silicone, more preferably in the form of an emulsion.
In some instances, particularly when the product is a serum or oil the composition may comprise cyclopentasiloxane (D5). Also preferred for oils serums are triglycerides.
Amino-functional polydimethyl siloxanes which have the CTFA designation amodimethicone may be used with the present invention. Preferred silicones are emulsions and include silicones such as polydiorganosiloxanes, in particular polydimethylsiloxanes which have the CTFA designation dimethicone, polydimethyl siloxanes having hydroxyl end groups which have the CTFA designation dimethiconol.
Suitable silicone emulsions for use in compositions of the invention are available from suppliers of silicones such as

Dow Corning and Momentive. The use of such pre-formed silicone emulsions is preferred for ease of processing and control of silicone particle size. Such pre-formed silicone emulsions will typically additionally comprise a suitable emulsifier such as an anionic or nonionic emulsifier, or mixture thereof, and may be prepared by a chemical emulsifi.cation process such as emulsion polymerisation, or by mechanical emulsification using a high shear mixer. Examples of suitable pre-formed silicone emulsions include emulsions DC2-1766, DC2-1784, DC-1785, DC-1786, DC-1788 and microemulsions DC2-1865 and DC2-1870, all available from Dow Corning. These are all emulsions/microemulsions of dimethiconol.
Suitable amodimethicone emulsions are DC939, DC7134 (from Dow Corning) and SME253 (from Momentive).
Silicone will generally be present in a composition of the invention at levels of from 0.05 to 20%, preferably 1 to 15%, more preferably from 2 to 10% by total weight of silicone based on the total weight of the composition.
In instances where the product is a serum or oil the level of solvent is higher than that stated above, in these cases it is usually from 80 to 99 wt% of the total weight of the composition.
The Examples will now be illustrated with reference to the following non-limiting Examples. Inventions according to the invention are demonstrated by a number, comparative inventions are demonstrated by a letter.

Examples
Example 1 Wt%
Sucrose acetate isobutyrate 0.2
Ethanol 50
Minors and Water to 100
Detangling Experiment
Two sets of switches were tested to evaluate the ability of sucrose acetate isobutyrate (SAIB) deposits to reduce the amount of energy required to detangle hair. The first set was treated as described below using only Dove Intensive Care Shampoo (European formulation 2007). The second set was treated with Example formulation 1 as a pre treatment before applying Dove Intensive Care Shampoo.
In each case, dark brown European hair switches of mass 2.5g and length 6" were used without any deliberate mechanical or chemical modification. Each switch was subject to multiple treatment cycles defined as follows: if used, Example formulation 1 was applied to the dry hair switch. 1.5ml of this solution was syringed into the hair switch and evenly distributed. Dove Intensive Care shampoo was then applied; 0.5g per switch, 1" from the clamped end and worked into the switch using a controlled tangling instrument.
The switch was then rinsed to remove the shampoo and placed into the detangling apparatus. This comprised an Instron load frame with a 1kN load cell. A narrow, grey Dupont Starflite comb, no. 858 was used for each switch at a fixed

speed of 4cm/s. The comb was inserted 1" from the bottom of the switch and combed through. The comb was then repeatedly combed through starting from positions 1" further up the switch each time until a distance of 5" from the bottom was reached. If at any pass, the load cut off of 30N was reached, that pass would be repeated. The energy per pass was calculated by the software and all 5 values added together for each test. This value was recorded as the detangling energy.
Once the switch had been fully detangled the whole wash, tangling and detangling cycle was repeated. Ten cycles were performed for each switch. Three replicates were used for each formulation.
The process was repeated up to 8 times.
The results are as follows:

IX 2X 3x 4x 5x 6x 7x 8x
Dove Shampoo 0.38 0.26 0.39 0.40 0.33 0.40 0.35 0.49
Example A
Example 1 0.29 0.24 0.28 0.24 0.24 0.25 0.22 0.26
followed by Dove
Shampoo
These results show that application on hair of a pre-treatment product comprising sucrose acetate isobutyrate prevents the hair from tangling. Furthermore after initial application on repeat washing the effect remains, with the

Example of the invention, this is not the case for the comparative example.
The following Examples (a cream formulation) show the benefit of using a non-surfactant esterified sugar compared with a surfactant based sugar.

INCI Name 1 Supplier % active Compara- Invention
in raw material tive
example
B Example 2
dimethicone and Dow 70 2.69 2.69
amodimethicone Corning
glycerol BDH 100 1.60 1.60
behenyl alcohol Cognis 100 2.00 2.00
stearamidopropyl Inolex 100 0.80 0.80
dimethylamine
hydroxyethyl Aqualon 100 0.24 0.24
cellulose
lactic acid Purac 88 0.16 0.16
sucrose acetate Eastman 90 0.00 0.33
isobutyrate (SAIB)
and ethanol
mineral oil Silkolene 100 4.50 4.50
sucrose hexaerucate Mistubishi Kagaku 100 0.30 0.00
water and minors 100 To 100 To 100
Votes 39 60
Virgin Dark Brown European (7g, 10 inch) Hair switches treated with the examples (dry application followed by repeatedly washing 6 times with a basic, non-conditioning

shampoo) were assessed for ease of combing by a trained panel. Ease of comb data analysed by Bradley Terry test shows a highly significant win for the Example of the invention Example 2 comprising SAIB (easier) with p=0.005
Example of serum type formulation

Chemical Name % in raw material % w/w water serum Example 3 in oil
alpha,omega dihydroxylated polydimethylsiloxane / polydimethylsiloxane 12 23.10
hydroxyethyl cellulose 100 0.21
PEG-400 100 3.50
Propylene glycol 100 41.57
Sodium Chloride 100 1.40
Polyacrylamide and C13-14 isoparaffin and laureth-7 47 6.00
Sodium Benzoate 100 0.70
Sucrose acetate isotmtyrate and caprylic and capric triglycerides 80 0.90
water 100 22.62

CLAIMS
1. A method of treating hair comprising the step of
applying to dry towel dried hair a hair care product
comprising sucrose acetate isobutyrate and a silicone.
2. A method according to claim 1 in which the product is
applied to dry hair.
3. A method of treating hair according to claim 1
comprising the following steps:
i) applying to the hair a composition comprising
sucrose acetate isobutyrate and a silicone; ii) followed by washing the hair.
4. A method according to any preceding claim in which the level of esterified sugar is from 0.01 t 5 wt% of the total composition.
5. A method according to any preceding claim in which the composition is in the form of a spray.
6. A method according to any preceding claim in which the composition further comprises ethanol.
7. A method according to any of claims 1 to 4 where the product is in the form of a serum.
8. A method according to claim 7 in which the serum further comprises a triglyceride.

9. A method according to any preceding claim in which the silicone is in the form of an silicone emulsion.
10. Use of sucrose acetate isobutyrate to prevent hair from tangling.