J3817/C
FORM-2
THE PATENTS ACT, 1970
(39 of 1970)
&
The Patents Rules, 2003
COMPLETE SPECIFICATION
(See Section 10 and Rule 13)


HAIR TREATMENT COMPOSITIONS
HINDUSTAN UNILEVER LIMITED, a company incorporated under the Indian Companies Act, 1913 and having its registered office at Hindustan Lever House, 165/166, Backbay Reclamation, Mumbai -400 020, Maharashtra, India

The following specification particularly describes the invention and the manner in which it is to be performed


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HAIR TREATMENT COMPOSITIONS
FIELD OF THE INVENTION
5 The invention relates to hair treatment compositions which comprise a combination of a sugar, an amino acid and a salt of an organic acid. The compositions are particularly suitable for the treatment of hair which is dry, damaged and/or prone to manageability problems.
0
BACKGROUND AND PRIOR ART
Hair can suffer damage from a number of sources. For example, environmental sources of hair damage include such
5 as exposure to UV and chlorine. Chemical sources of hair damage include treatments such as bleaching, perming and straightening, and overly frequent washing with harsh surfactant-based cleansing shampoo compositions. Mechanical sources of hair damage include excessive brushing and
0 combing and prolonged use of heated appliances for drying and styling the hair.
Damage to the hair typically manifests itself in cuticle and protein loss from the hair fibre, hair fibre dryness, hair 5 fibre brittleness and breakage and frayed or split ends. Dry, damaged hair is particularly prone to manageability problems, resulting in symptoms such as "flyaway" hair which is difficult to style or which does not retain a style, especially under conditions such as high humidity.

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Various organic molecules and combinations thereof have been suggested for use in the treatment of dry, damaged and/or unmanageable hair.
5 For example, WO 2004054526 describes hair treatment
compositions for the care and repair of damaged hair, and for improving hair manageability, comprising a disaccharide, (in particular trehalose), and a diacid (in particular adipic acid).
10
WO 2004054525 describes hair treatment compositions for the care and repair of damaged hair, and for improving hair manageability, comprising a disaccharide (in particular trehalose), and a diol (in particular 3-methyl-l,3-
15 butanediol).
WO 2004006874 describes hair treatment compositions for repairing and preventing the principal symptoms of damaged hair, comprising specific branched amine and/or hydroxy 20 compounds (in particular 3,3-dimethyl-l,2-butanediol).
The present inventors have found that hair treatment compositions comprising a combination of a sugar, an amino acid and a salt of an organic acid show improved efficacy in 25 the treatment of hair which is dry, damaged and/or prone to manageability problems.

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SUMMARY OF THE INVENTION
The present invention provides a hair treatment composition comprising a combination of a sugar, an amino acid and a 5 salt of an organic acid.
The invention also provides the use of the above composition in the treatment of dry, damaged and/or unmanageable hair.
10 The invention also provides a method of treating hair by applying the above composition to the hair.
DETAILED DESCRIPTION AND PREFERRED EMBODIMENTS
15 Sugar
The composition of the invention comprises at least one
sugar.
20 By 'sugar' is generally meant monosaccharides, disaccharides and lower oligosaccharides (typically containing between 3 and 6 monosaccharide units linked together by glycosidic bonds).
25 Monosaccharides are preferred for use in the invention. The term 'monosaccharide' (as opposed to oligosaccharide or polysaccharide) denotes a single unit, without glycosidic connection to other such units.
30 Monosaccharides have the molecular formula (CH20)n, where n
may be any integer from 3 to 8. Monosaccharides contain from

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2 to 7 hydroxy1 groups, depending on the number of carbon atoms, and either a ketone or an aldehyde group.
The monosaccharides containing an aldehyde group are 5 conventionally called "aldoses" and the monosaccharides containing a ketone group are conventionally called "ketoses". Aldoses are preferred.
Preferred monosaccharides for use in the invention contain 10 4, 5, 6 or 7 carbon atoms. These are tetroses, pentoses, hexoses and heptoses, respectively.
In view of the presence of asymmetric carbons - one for the trioses (monosaccharides containing 3 carbon atoms) and 15 several for the other monosaccharides — each monosaccharide takes the form of several stereoisomers, which can be enantiomers in the case of the trioses and enantiomers and diastereoisomers in the case of the other monosaccharides.
20 The pentoses and hexoses which can be used in the invention can cyclize to furanose and pyranose rings, respectively. In an aqueous medium, pentoses and hexoses will exist mainly in cyclic form.
25 Preferred aldoses which can be used in the invention are: erythrose and threose (which are tetroses), ribose, arabinose, xylose and lyxose, (which are pentoses), and allose, altrose, glucose, mannose, gulose, idose, galactose and talose (which are hexoses).
30

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Preferred ketoses which can be used in the invention are: erythrulose (which is a tetrose), ribulose and xylulose (which are pentoses), and psicose, fructose, sorbose and tagatose (which are hexoses). 5
The ketoses can also have cyclic forms. For example, fructose can have the fructofuranose or fructopyranose form.
Mixtures of any of the above-described materials may also be 10 used in the composition of the invention.
Preferably, the sugar used in the composition of the invention is an aldohexose, most preferably galactose.
15 The total amount of sugar in hair treatment compositions of the invention generally ranges from 0.01 to 10%, preferably from 0.05 to 1%, and is more preferably about 0.1% (by total weight sugar based on the total weight of the composition).
20 Amino Acid
The composition of the invention comprises at least one amino acid.
25 The term "amino acid" denotes a molecule containing both an amino group and a carboxyl group. The amino acid may belong to the L-or D-series or may be racemic.
Examples of suitable amino acids for use in the invention 30 have the general formula:

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CH(COOH) (NHR1) (R2)
in which R is hydrogen or an alkyl group having an alkyl
2
chain length of from 1 to 20 carbon atoms, and R is 5 hydrogen or an alkyl group having from 1 to 4 carbon atoms.
In preferred amino acids for use in the invention, R is an
2 alkyl group having from 1 to 4 carbon atoms, and R is
selected from H, -CH3, -CH(CH3)2, -CH2CH(CH3)2 and -CH(CH3)-
10 CH2CH3.
Mixtures of any of the above-described materials may also be used in the composition of the invention.
15 A most preferred material is N-methyl glycine (also known as sarcosine).
The total amount of amino acid in hair treatment compositions of the invention generally ranges from 0.01 to 20 10%, preferably from 0.05 to 1%, and is more preferably about 0.1% (by total weight amino acid based on the total weight of the composition).
Organic Acid Salt 25
The composition of the invention comprises at least one salt of an organic acid (also referred to herein as an "organic acid salt").

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Suitable classes of organic acids whose salts can be used in the compositions of the invention are:
aromatic(poly)carboxylic acids such as benzenecarboxylic 5 acids: for example, benzenecarboxylic acid, 1,2-
benzenedicarboxylic acid, 1,3 benzenedicarboxylic acid, 1,4-benzenedicarboxylic acid and salicylic acid;
pyridine(poly)carboxylic acids: for example, 2-10 pyridinecarboxylic acid, 3-pyridinecarboxylic acid, 4-
pyridinecarboxylic acid, 2,3-pyridinecarboxylic acid, 2,4-pyridinedicarboxylic acid, 2,5-pyridinedicarboxylic acid and 2,6-pyridinedicarboxylic acid;
15 alkane(poly)carboxylic acids: for example, formic acid,
acetic acid, propionic acid, butyric acid, palmitic acid, oxalic acid, malonic acid, phthalic acid, succinic acid, 2,3,5-hexanetricarboxylic acid, 1,2,3-butanetricarboxylic acid and 2-(3-carboxypropyl- 1, 1,5,6-heptanetetracarboxylic
2 0 acid;
hydroxy acids: for example, citric acid, glycolic acid, lactic acid, malic acid and tartaric acid;
25 phosphonic acids: for example, acetophosphonic acid, hydroxyphosphonic acids and aminophosphonic acids, especially with several phosphonic acid groups, such as 1-hydroxyethane- 1,1-diphosphonic acid, aminotri(methylenephosphonic acid), alkylenediaminotetra-
30 (methylenephosphonic acid) and
dialkylenetriaminopenta(methylenephosphonic acid), where the

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alkylenes can be ethylene, 1,2-propylene and 1,3-propylene as well as 1,2-butylene and 1,4-butylene;
sulphonic acids, for example, methanesulphonic acid, 5 methanedisulphonic acid, 1,2- ethanedisulphonic acid, toluenesulphonic acid and aminosulphonic acids, such as sulphanilic acid.
A preferred class of organic acids whose salts can be used 10 in the compositions of the invention are aminopolycarboxylic acids.
Examples of aminopolycarboxylic acids whose salts can be used are: iminodiacetic acid, methyliminodiacetic acid,
15 N-hydroxyethyliminodiacetic acid,
monoethanolethylenediaminetriacetic acid, diethanolethylenediaminediacetic acid, 2,2,2"-nitrilotriacetic acid, tri(carboxymethyl)amine, propylene-1,2-diaminetetraacetic acid, p-alaninediacetic acid, serine
20 diacetic acid, isoserinediacetic acid, asparaginediacetic acid, polyasparagine acid, iminodisuccinic acid, hydroxyethylethylenediamine triacetic acid, and diethylenetriaminepentaacetic acid.
25 Particularly preferred examples of aminopolycarboxylic acids are polyaminopolycarboxylic acids, such as the alkylenepolyaminopolycarboxylic acids.
The alkylene polyaminopolycarboxylic acids can be 30 represented by the general formula:

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where x and y are integers independently from 1 to 4 and R
represents an alkylene group with one to three carbon atoms 5 and where up to x of the carboxyalkyl groups can be replaced by betahydroxyethyl groups.
Representative examples of such alkylenepolyaminopolycarboxylic acids are: 10
ethylenediaminetetraacetic acid (R is -CH2-; x is 2; y is
ethylenetriaminepentaacetic acid (R is -CH2-; x is 2; y is
2);
3 15 propylene-1,3-diaminetetraacetic acid (R is -CH2-; x is 3;
y is 2),
and the isomeric butylenediaminetetraacetic acids.
20 Ethylenediaminetetraacetic acid (also referred to herein as "EDTA") is most preferred.
The cation of the salt of the organic may be any cation, for example, a lithium, sodium, potassium or an ammonium, or 25 alkyl-substituted ammonium ions such as tetraalkyl-
substituted ammonium. Preferably, lithium, sodium and potassium salts are used.

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Most preferably, lithium salts are used, such as in particular dilithium ethylenediaminetetraacetate.
Mixtures of any of the above-described organic acid salts 5 may also be used in the composition of the invention.
The total amount of organic acid salt in hair treatment compositions of the invention generally ranges from 0.01 to 10%, preferably from 0.05 to 1%, and is more preferably 10 about 0.1% (by total weight organic acid salt based on the total weight of the composition).
Product Form
15 Hair treatment compositions according to the invention may suitably take the form of shampoos, conditioners, sprays, mousses, gels, waxes or lotions.
Particularly preferred product forms are shampoos, post-wash 20 conditioners (leave-in and rinse-off) and hair treatment products such as hair oils and lotions.
Shampoo Compositions
25 Shampoo compositions of the invention are generally aqueous, i.e. they have water or an aqueous solution or a lyotropic liquid crystalline phase as their major component.
Suitably, the shampoo composition will comprise from 50 to 30 98%, preferably from 60 to 90% water by weight based on the total weight of the composition.

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Anionic Cleansing Surfactant
Shampoo compositions according to the invention will generally comprise one or more anionic cleansing surfactants 5 which are cosmetically acceptable and suitable for topical application to the hair.
Examples of suitable anionic cleansing surfactants are the alkyl sulphates, alkyl ether sulphates, alkaryl sulphonates,
10 alkanoyl isethionates, alkyl succinates, alkyl
sulphosuccinates, alkyl ether sulphosuccinates, N-alkyl sarcosinates, alkyl phosphates, alkyl ether phosphates, and alkyl ether carboxylic acids and salts thereof, especially their sodium, magnesium, ammonium and mono-, di- and
15 triethanolamine salts. The alkyl and acyl groups generally contain from 8 to 18, preferably from 10 to 16 carbon atoms and may be unsaturated. The alkyl ether sulphates, alkyl ether sulphosuccinates, alkyl ether phosphates and alkyl ether carboxylic acids and salts thereof may contain from 1
20 to 20 ethylene oxide or propylene oxide units per molecule.
Typical anionic cleansing surfactants for use in shampoo compositions of the invention include sodium oleyl succinate, ammonium lauryl sulphosuccinate, sodium lauryl sulphate,
25 sodium lauryl ether sulphate, sodium lauryl ether
sulphosuccinate, ammonium lauryl sulphate, ammonium lauryl ether sulphate, sodium dodecylbenzene sulphonate, triethanolamine dodecylbenzene sulphonate, sodium cocoyl isethionate, sodium lauryl isethionate, lauryl ether
30 carboxylic acid and sodium N-lauryl sarcosinate.

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Preferred anionic cleansing surfactants are sodium lauryl sulphate, sodium lauryl ether sulphate (n)EO, (where n is from 1 to 3), sodium lauryl ether sulphosuccinate(n)EO, (where n is from 1 to 3), ammonium lauryl sulphate, ammonium 5 lauryl ether sulphate(n)EO, (where n is from 1 to 3), sodium cocoyl isethionate and lauryl ether carboxylic acid (n) EO (where n is from 10 to 20).
Mixtures of any of the foregoing anionic cleansing 10 surfactants may also be suitable.
The total amount of anionic cleansing surfactant in shampoo compositions of the invention generally ranges from 0.5 to 45%, preferably from 1.5 to 35%, more preferably from 5 to 15 20% by total weight anionic cleansing surfactant based on the total weight of the composition.
Further Ingredients
2 0 Optionally, a shampoo composition of the invention may
contain further ingredients as described below to enhance performance and/or consumer acceptability.
Co-surfactant 25
The composition can include co-surfactants, to help impart aesthetic, physical or cleansing properties to the composition.
*
30 An example of a co-surfactant is a nonionic surfactant, which can be included in an amount ranging from 0.5 to 8%,

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preferably from 2 to 5% by weight based on the total weight of the composition.
For example, representative nonionic surfactants that can be 5 included in shampoo compositions of the invention include
condensation products of aliphatic (C8 - C18) primary or
secondary linear or branched chain alcohols or phenols with alkylene oxides, usually ethylene oxide and generally having from 6 to 30 ethylene oxide groups. 10
Other representative nonionic surfactants include mono- or di-alkyl alkanolamides. Examples include coco mono- or di-ethanolamide and coco mono-isopropanolamide.
15 Further nonionic surfactants which can be included in shampoo compositions of the invention are the alkyl polyglycosides (APGs). Typically, the APG is one which comprises an alkyl group connected (optionally via a bridging group) to a block of one or more glycosyl groups. Preferred APGs are defined
20 by the following formula:
RO - (G)n
wherein R is a branched or straight chain alkyl group which 25 may be saturated or unsaturated and G is a saccharide group.
R may represent a mean alkyl chain length of from about C5 to about C20- Preferably R represents a mean alkyl chain length of from about C8 to about C12. Most preferably the value of R

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lies between about 9.5 and about 10.5. G may be selected
from C5 or C6 monosaccharide residues, and is preferably a
glucoside. G may be selected from the group comprising glucose, xylose, lactose, fructose, mannose and derivatives 5 thereof. Preferably G is glucose.
The degree of polymerisation, n, may have a value of from about 1 to about 10 or more. Preferably, the value of n lies from about 1.1 to about 2. Most preferably the value of n 10 lies from about 1.3 to about 1.5.
Suitable alkyl polyglycosides for use in the invention are commercially available and include for example those materials identified as: Oramix NS10 ex Seppic; Plantaren 15 1200 and Plantaren 2000 ex Henkel.
Other sugar-derived nonionic surfactants which can be included in compositions of the invention include the Cio-Cis
N-alkyl (C1-C6) polyhydroxy fatty acid amides, such as the
2 0 C12_C18 N-methyl glucamides, as described for example in
WO 92 06154 and US 5 194 639, and the N-alkoxy polyhydroxy fatty acid amides, such as C10-C18 N-(3-methoxypropyl) glucamide.
25 A preferred example of a co-surfactant is an amphoteric or zwitterionic surfactant, which can be included in an amount ranging from 0.5 to about 8%, preferably from 1 to 4% by weight based on the total weight of the composition.

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Examples of amphoteric or zwitterionic surfactants include alkyl amine oxides, alkyl betaines, alkyl amidopropyl betaines, alkyl sulphobetaines (sultaines), alkyl glycinates, alkyl carboxyglycinates, alkyl amphoacetates, alkyl 5 amphopropionates, alkylamphoglycinates, alkyl amidopropyl hydroxysultaines, acyl taurates and acyl glutamates, wherein the alkyl and acyl groups have from 8 to 19 carbon atoms. Typical amphoteric and zwitterionic surfactants for use in shampoos of the invention include lauryl amine oxide, L0 cocodimethyl sulphopropyl betaine, lauryl betaine, cocamidopropyl betaine and sodium cocoamphoacetate.
A particularly preferred amphoteric or zwitterionic surfactant is cocamidopropyl betaine.
L5
Mixtures of any of the foregoing amphoteric or zwitterionic surfactants may also be suitable. Preferred mixtures are those of cocamidopropyl betaine with further amphoteric or zwitterionic surfactants as described above. A preferred
>0 further amphoteric or zwitterionic surfactant is sodium cocoamphoacetate.
The total amount of surfactant (including any co-surfactant, and/or any emulsifier) in a shampoo composition of the !5 invention is generally from 1 to 50%, preferably from 2 to 40%, more preferably from 10 to 25% by total weight surfactant based on the total weight of the composition.

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Cationic Polymers
Cationic polymers are preferred ingredients in a shampoo composition of the invention for enhancing conditioning 5 performance.
Suitable cationic polymers may be homopolymers which are cationically substituted or may be formed from two or more
types of monomers- The weight average (Mw) molecular weight
10 of the polymers will generally be between 100 000 and 2
million daltons. The polymers will have cationic nitrogen containing groups such as quaternary ammonium or protonated amino groups, or a mixture thereof. If the molecular weight of the polymer is too low, then the conditioning effect is
15 poor. If too high, then there may be problems of high extensional viscosity leading to stringiness of the composition when it is poured.
The cationic nitrogen-containing group will generally be 2 0 present as a substituent on a fraction of the total monomer units of the cationic polymer. Thus when the polymer is not a homopolymer it can contain spacer non-cationic monomer units. Such polymers are described in the CTFA Cosmetic Ingredient Directory, 3rd edition. The ratio of the cationic 25 to non-cationic monomer units is selected to give polymers
having a cationic charge density in the required range, which is generally from 0.2 to 3.0 meq/gm. The cationic charge density of the polymer is suitably determined via the Kjeldahl method as described in the US Pharmacopoeia under 30 chemical tests for nitrogen determination.

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Suitable cationic polymers include, for example, copolymers of vinyl monomers having cationic amine or quaternary ammonium functionalities with water soluble spacer monomers such as (meth)acrylamide, alkyl and dialkyl 5 (meth)acrylamides, alkyl (meth)acrylate, vinyl caprolactone and vinyl pyrrolidine. The alkyl and dialkyl substituted monomers preferably have C1-C7 alkyl groups, more preferably Cl-3 alkyl groups. Other suitable spacers include vinyl esters, vinyl alcohol, maleic anhydride, propylene glycol 10 and ethylene glycol.
The cationic amines can be primary, secondary or tertiary amines, depending upon the particular species and the pH of the composition. In general secondary and tertiary amines, 15 especially tertiary, are preferred.
Amine substituted vinyl monomers and amines can be polymerised in the amine form and then converted to ammonium by quaternization. 20
The cationic polymers can comprise mixtures of monomer units derived from amine- and/or quaternary ammonium-substituted monomer and/or compatible spacer monomers.
25 Suitable cationic polymers include, for example:
-cationic diallyl quaternary ammonium-containing polymers including, for example, dimethyldiallylammonium chloride homopolymer and copolymers of acrylamide and 30 dimethyldiallylammonium chloride, referred to in the

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industry (CTFA) as Polyquaternium 6 and Polyquaternium 7, respectively;
-mineral acid salts of amino-alkyl esters of homo-and 5 co-polymers of unsaturated carboxylic acids having from 3 to 5 carbon atoms, (as described in U.S. Patent 4,009,256) ;
- cationic polyacrylamides(as described in W095/22311).
0
Other cationic polymers that can be used include cationic polysaccharide polymers, such as cationic cellulose derivatives, cationic starch derivatives, and cationic guar gum derivatives.
5
Cationic polysaccharide polymers suitable for use in compositions of the invention include monomers of the formula:
0 A-0-[R-N+(R1) (R2) (R3)X~],
wherein: A is an anhydroglucose residual group, such as a starch or cellulose anhydroglucose residual. R is an
alkylene, oxyalkylene, polyoxyalkylene, or hydroxyalkylene

5 group, or combination thereof. R1 , R2 and R3 independently
represent alkyl, aryl, alkylaryl, arylalkyl, alkoxyalkyl, or alkoxyaryl groups, each group containing up to about 18
carbon atoms. The total number of carbon atoms for each
l 2 cationic moiety (i.e., the sum of carbon atoms in R , R and

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3 R ) is preferably about 20 or less, and X is an anionic
counterion.
Another type of cationic cellulose includes the polymeric 5 quaternary ammonium salts of hydroxyethyl cellulose reacted with lauryl dimethyl ammonium-substituted epoxide, referred to in the industry (CTFA) as Polyquaternium 24. These materials are available from the Amerchol Corporation, for instance under the tradename Polymer LM-200.
10
Other suitable cationic polysaccharide polymers include quaternary nitrogen-containing cellulose ethers (e.g. as described in U.S. Patent 3,962,418), and copolymers of etherified cellulose and starch (e.g. as described in
15 U.S. Patent 3,958,581).
A particularly suitable type of cationic polysaccharide polymer that can be used is a cationic guar gum derivative, such as guar hydroxypropyltrimethylammonium chloride (commercially available from Rhodia in their JAGUAR trademark series). Examples of such materials are JAGUAR C13S, JAGUAR C14, JAGUAR C15 and JAGUAR C17.
Mixtures of any of the above cationic polymers may be used.
20 Cationic polymer will generally be present in a shampoo
composition of the invention at levels of from 0.01 to 5%, preferably from 0.05 to 1%, more preferably from 0.08 to 0.5% by total weight of cationic polymer based on the total weight of the composition.
25

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Suspending Agent
Preferably an aqueous shampoo composition of the invention further comprises a suspending agent. Suitable suspending
5 agents are selected from polyacrylic acids, cross-linked polymers of acrylic acid, copolymers of acrylic acid with a hydrophobic monomer, copolymers of carboxylic acid-containing monomers and acrylic esters, cross-linked copolymers of acrylic acid and acrylate esters,
0 heteropolysaccharide gums and crystalline long chain acyl derivatives. The long chain acyl derivative is desirably selected from ethylene glycol stearate, alkanolamides of fatty acids having from 16 to 22 carbon atoms and mixtures thereof. Ethylene glycol distearate and polyethylene glycol
5 3 distearate are preferred long chain acyl derivatives, since these impart pearlescence to the composition. Polyacrylic acid is available commercially as Carbopol 420, Carbopol 488 or Carbopol 493. Polymers of acrylic acid cross-linked with a polyfunctional agent may also be used;
0 they are available commercially as Carbopol 910, Carbopol 934, Carbopol 941 and Carbopol 980. An example of a suitable copolymer of a carboxylic acid containing monomer and acrylic acid esters is Carbopol 1342. All Carbopol (trademark) materials are available from Goodrich.
5
Suitable cross-linked polymers of acrylic acid and acrylate esters are Pemulen TR1 or Pemulen TR2. A suitable heteropolysaccharide gum is xanthan gum, for example that available as Kelzan mu.

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10

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Mixtures of any of the above suspending agents may be used. Preferred is a mixture of cross-linked polymer of acrylic acid and crystalline long chain acyl derivative.
Suspending agent will generally be present in a shampoo composition of the invention at levels of from 0.1 to 10%, preferably from 0.5 to 6%, more preferably from 0.9 to 4% by total weight of suspending agent based on the total weight of the composition.
Conditioner Compositions

Conditioner compositions will typically comprise one or more cationic conditioning surfactants which are cosmetically 15 acceptable and suitable for topical application to the hair.
Preferably, the cationic conditioning surfactants have the
+ 1234 123 4
formula N (R ) (R ) (R ) (R ) , wherein R , R , R and R are
independently (C1 to C30) alkyl or benzyl
20
1 2 Preferably, one, two or three of R , R , R3 and R4 are
1 2 independently (C4 to C30) alkyl and the other R , R , R 3 and
4 R group or groups are (C1-C6) alkyl or benzyl.
1 2 3 4 25 More preferably, one or two of R , R , R and R are
1 2 3 independently (C6 to C30) alkyl and the other R , R , R and
4 ' ,■
R groups are (C1.-C6) alkyl or benzyl groups. Optionally, the alkyl groups may comprise one or more ester (-OCO- or -

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COO-) and/or ether (-0-) linkages within the alkyl chain. Alkyl groups may optionally be substituted with one or more hydroxyl groups. Alkyl groups may be straight chain or branched and, for alkyl groups having 3 or more carbon 5 atoms, cyclic. The alkyl groups may be saturated or may contain one or more carbon-carbon double bonds (e.g., oleyl). Alkyl groups are optionally ethoxylated on the alkyl chain with one or more ethyleneoxy groups.
10 Suitable cationic conditioning surfactants for use in
conditioner compositions according to the invention include cetyltrimethylammonium chloride, behenyltrimethylammonium chloride, cetylpyridinium chloride, tetramethylammonium chloride, tetraethylammonium chloride, octyltrimethylammonium
15 chloride, dodecyltrimethylammonium chloride, hexadecyltrimethylammonium chloride, octyldimethylbenzylammonium chloride, decyldimethylbenzylammonium chloride, stearyldimethylbenzylammonium chloride,
20 didodecyldimethylammonium chloride,
dioctadecyldimethylammonium chloride, tallowtrimethylammonium chloride, dihydrogenated tallow dimethyl ammonium chloride (e.g., Arquad 2HT/75 from Akzo Nobel), cocotrimethylammonium chloride, PEG-2-oleammonium chloride and the corresponding
25 hydroxides thereof. Further suitable cationic surfactants include those materials having the CTFA designations Quaternium-5, Quaternium-31 and Quaternium-18. Mixtures of any of the foregoing materials may also be suitable. A particularly useful cationic surfactant for use in
30 conditioners according to the invention is
cetyltrimethylammonium chloride, available commercially, for

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example as GENAMIN CTAC, ex Hoechst Celanese. Another particularly useful cationic surfactant for use in conditioners according to the invention is
behenyltrimethylammonium chloride, available commercially, 5 for example as GENAMIN KDMP, ex Clariant.
Another example of a class of suitable cationic conditioning surfactants for use in the invention, either alone or in admixture with one or more other cationic conditioning 10 surfactants, is a combination of (i) and (ii) below:
(i) an amidoamine corresponding to the general formula (I)

15 in which R is a hydrocarbyl chain having 10 or more
carbon atoms,
2 3 R and R are independently selected from hydrocarbyl
chains of from 1 to 10 carbon atoms, and m is an integer from 1 to about 10; and
20

25

(ii) an acid.
As used herein, the term hydrocarbyl chain means an alkyl or alkenyl chain.
Preferred amidoamine compounds are those corresponding to formula (I) in which

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R is a hydrocarbyl residue having from about 11 to about 24
carbon atoms,
2 3 R and R are each independently hydrocarbyl residues,
preferably alkyl groups, having from 1 to about 4 carbon 5 atoms, and
m is an integer from 1 to about 4.
2 3
Preferably, R and R are methyl or ethyl groups.
10 Preferably, m is 2 or 3, i.e. an ethylene or propylene group.
Preferred amidoamines useful herein include stearamido-
propyldimethylamine, stearamidopropyldiethylamine, 15 stearamidoethyldiethylamine, stearamidoethyldimethylamine,
palmitamidopropyldimethylamine,
palmitamidopropyldiethylamine, palmitamidoethyldiethylamine,
palmitamidoethyldimethylamine,
behenamidopropyldimethylamine, behenamidopropyldiethylmine, 2 0 behenamidoethyldiethylamine, behenamidoethyldimethylamine,
arachidamidopropyldimethylamine,
arachidamidopropyldiethylamine, arachid-
amidoethyldiethylamine, arachidamidoethyldimethylamine, and
mixtures thereof. 25
Particularly preferred amidoamines useful herein are
stearamidopropyldimethylamine, stearamidoethyldiethylamine,
and mixtures thereof.

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Commercially available amidoamines useful herein include: stearamidopropyldimethylamine with tradenames LEXAMINE S-13 available from Inolex (Philadelphia Pennsylvania, USA) and AMIDOAMINE MSP available from Nikko (Tokyo, Japan), 5 stearamidoethyldiethylaimine with a tradename AMIDOAMINE S available from Nikko, behenamidopropyldimethylamine with a tradename INCROMINE BB available from Croda (North Humberside, England), and various amidoamines with tradenames SCHERCODINE series available from Scher (Clifton 10 New Jersey, USA).
Acid (ii) may be any organic or mineral acid which is capable of protonating the amidoamine in the hair treatment composition. Suitable acids useful herein include
15 hydrochloric acid, acetic acid, tartaric acid, fumaric acid, lactic acid, malic acid, succinic acid, and mixtures thereof. Preferably, the acid is selected from the group consisting of acetic acid, tartaric acid, hydrochloric acid, fumaric acid, and mixtures thereof.
20
The primary role of the acid is to protonate the amidoamine in the hair treatment composition thus forming a tertiary amine salt (TAS) in situ in the hair treatment composition. The TAS in effect is a non-permanent quaternary ammonium or
25 pseudo-quaternary ammonium cationic surfactant.
Suitably, the acid is included in a sufficient amount to protonate all the amidoamine present, i.e. at a level which is at least equimolar to the amount of amidoamine present in 30 the composition.

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In conditioners of the invention, the level of cationic conditioning surfactant will generally range from 0.01 to 10%, more preferably 0.05 to 7.5%, most preferably 0.1 to 5% by total weight of cationic conditioning surfactant based on 5 the total weight of the composition.
Conditioners of the invention will typically also incorporate a fatty alcohol. The combined use of fatty alcohols and cationic surfactants in conditioning compositions is believed 10 to be especially advantageous, because this leads to the formation of a lamellar phase, in which the cationic surfactant is dispersed.
Representative fatty alcohols comprise from 8 to 22 carbon 15 atoms, more preferably 16 to 22. Fatty alcohols are
typically compounds containing straight chain alkyl groups. Examples of suitable fatty alcohols include cetyl alcohol, stearyl alcohol and mixtures thereof. The use of these materials is also advantageous in that they contribute to 20 the overall conditioning properties of compositions of the invention.
The level of fatty alcohol in conditioners of the invention will generally range from 0.01 to 10%, preferably from 0.1 to
25 8%, more preferably from 0.2 to 7%, most preferably from 0.3 to 6% by weight of the composition. The weight ratio of cationic surfactant to fatty alcohol is suitably from 1:1 to 1:10, preferably from 1:1.5 to 1:8, optimally from 1:2 to 1:5. If the weight ratio of cationic surfactant to fatty
30 alcohol is too high, this can lead to eye irritancy from the

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composition. If it is too low, it can make the hair feel squeaky for some consumers.
Hair Oils and Lotions
5
Compositions of the invention may suitably take the form of a hair oil, for pre-wash or post-wash use. Typically, hair oils will predominantly comprise water-insoluble oily conditioning materials, such as triglycerides, mineral oil
0 and mixtures thereof.
Compositions of the invention may also take the form of a hair lotion, typically for use in between washes. Lotions are aqueous emulsions comprising water-insoluble oily 5 conditioning materials. Suitable surfactants can also be included in lotions to improve their stability to phase separation.
Silicone Conditioning Agents
0
Hair treatment compositions according to the invention, particularly water-based shampoos and hair conditioners, will preferably also contain one or more silicone conditioning agents.
5
Particularly preferred silicone conditioning agents are silicone emulsions such as those formed from silicones such as polydiorganosiloxanes, in particular polydimethylsiloxanes which have the CTFA designation
0 dimethicone, polydimethyl siloxanes having hydroxyl end groups which have the CTFA designation dimethiconol, and

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amino-functional polydimethyl siloxanes which have the CTFA designation amodimethicone.
The emulsion droplets may typically have a Sauter mean
5 droplet diameter (D3,2) in the composition of the invention
ranging from 0.01 to 20 micrometer, more preferably from 0.2 to 10 micrometer.
A suitable method for measuring the Sauter mean droplet 10 diameter (D 3,2) is by laser light scattering using an instrument such as a Malvern Mastersizer.
Suitable silicone emulsions for use in compositions of the invention are available from suppliers of silicones such as
15 Dow Corning and GE Silicones. The use of such pre-formed silicone emulsions is preferred for ease of processing and control of silicone particle size. Such pre-formed silicone emulsions will typically additionally comprise a suitable emulsifier such as an anionic or nonionic emulsifier, or
2 0 mixture thereof,,and may be prepared by a chemical
emulsification process such as emulsion polymerisation, or by mechanical emulsification using a high shear mixer. Pre¬formed silicone emulsions having a Sauter mean droplet
diameter (D 3,2) of less than 0.15 micrometers are generally
25 termed microemulsions.
Examples of suitable pre-formed silicone emulsions include emulsions DC2-1766, DC2-1784, DC-1785, DC-1786, DC-1788 and microemulsions DC2-1865 and DC2-1870, all available from Dow 30 Corning. These are all emulsions/microemulsions of

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dimethiconol. Also suitable are amodimethicone emulsions such as DC2-8177 and DC939 (from Dow Corning) and SME253 (from GE Silicones).
5 Also suitable are silicone emulsions in which certain types of surface active block copolymers of a high molecular weight have been blended with the silicone emulsion droplets, as described for example in WO03/094874. In such materials, the silicone emulsion droplets are preferably 10 formed from polydiorganosiloxanes such as those described above. One preferred form of the surface active block copolymer is according to the following formula:


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The above described silicone emulsions will generally be present in a composition of the invention at levels of from 0.05 to 10%, preferably 0.05 to 5%, more preferably from 0.5 to 2% by total weight of silicone based on the total 5 weight of the composition.
Other Optional Ingredients
A composition of the invention may contain other ingredients 10 for enhancing performance and/or consumer acceptability. Such ingredients include fragrance, dyes and pigments, pH adjusting agents, pearlescers or opacifiers, viscosity modifiers, and preservatives or antimicrobials. Each of these ingredients will be present in an amount effective to 15 accomplish its purpose. Generally these optional
ingredients are included individually at a level of up to 5% by weight of the total composition.
Mode of Use
20.
Hair treatment compositions of the invention are primarily intended for topical application to the hair and/or scalp of a human subject, either in rinse-off or leave-on compositions, for the treatment of dry, damaged and/or
25 unmanageable hair.
The invention will be further illustrated by the following, non-limiting Example, in which all percentages quoted are by weight based on total weight unless otherwise stated.

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EXAMPLE
Formulations were prepared having ingredients as shown in the following Table 1: 5
Table 1

Formulation ingredients Weight%

Example 1 Control
Sodium laurylether sulphate (2EO) 12 12
Cocoyl amidopropyldimethyl glycine 2 2
Silicone emulsion 2 2
Guar hydroxypropyl trimethylammonium chloride 0.30 0.30
Preservative 0.35 0.35
Perfume 0.42 0.42
Citric acid 0.17 0.17
Galactose 0.1 -
Sarcosine 0.1 -
Dilithium EDTA 0.1 -
Water and Minors To 100 Weight%
The formulation of Example 1 was compared against the 0 control formulation across a number of performance attributes, using a rank sensory methodology.
Bleached and coloured Chinese hair switches were treated with the formulation of Example 1 and the control 5 formulation respectively.
12 panellists were asked to assess the treated hair switches. Switches treated with the formulation of Example 1 were ranked by the panellists against switches treated 0 with the control formulation, across the following four

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sensory attributes: tip alignment, smoothness, ease of comb and dry ends.
Sensory data was analysed using a Friedman's two-way ANOVA 5 for ranks.
The results (rank mean for each formulation tested) are shown in the following Table 2:
10 Table 2

Sensory Attribute Rank mean for Control Rank mean for Example 1
Tip alignment 2.79 3.08
Smoothness 2.21 3.13
Ease of comb 2.04 3.08
Dry ends 2.71 1.92
The sensory attribute rank direction is as follows:
15
Tip alignment: higher rank is better
Smoothness: higher rank is better
Ease of comb: higher rank is better
Dry ends: lower rank is better.
20
The results show that, compared to the control, the formulation of Example 1 gives better tip alignment, significantly (>95%) better smoothness, significantly (>95%) better ease of comb and significantly (>95%) reduced dry
25 ends.

Printed: 16/10/2007 CLMSPAMD EP2006011B13
J3817(C) WO

AMENDED SHEET IBHH

HINDUSTAN UNILEVER LIWUTE©
(S.Venkatramani)-Senior Patents Manager

m

AMENDED SHEET

04/10/2007