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High Gas Adsorption In A Metal Organic Framework

Abstract: In accordance with the present subject matter an organic compound of formula I is disclosed. The present subject matter also relates to a process for preparing the organic compound. The present subject matter further relates to the use of the synthesized organic compound as an organic linker, in combination with a metal, for synthesis of metal-organic frameworks of formula M-L, where M is a metal ion and L is an organic compound, and where M is at least one of a alkaline earth metal or a transitional metal. The invention further discloses the use of the synthesized metal-organic frameworks for storage of gases.

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Notices, Deadlines & Correspondence

Patent Information

Application #
Filing Date
01 July 2013
Publication Number
24/2015
Publication Type
INA
Invention Field
CHEMICAL
Status
Email
iprdel@lakshmisri.com
Parent Application
Patent Number
Legal Status
Grant Date
2023-02-10
Renewal Date

Applicants

HINDUSTAN PETROLEUM CORPORATION LTD.
HINDUSTAN PETROLEUM CORPORATION LTD, PETROLEUM HOUSE, 17 JAMSHEDJI TATA ROAD, CHURCHGATE, MUMBAI 400020
GITAM UNIVERSITY
NANOSCIENCE & NANOTECHNOLOGY LABORATORY, DEPARTMENT OF CHEMISTRY, GITAM UNIVERSITY VISAKHAPATNAM, ANDHRA PRADESH 530045
CENTRE FOR HIGH TECHNOLOGY (CHT)
CENTRE FOR HIGH TECHNOLOGY, OIDB BHAWAN, TOWER 'A', 9TH FLOOR, PLOT NO. 2, SECTOR- 73, NOIDA, UTTAR PRADESH 201301

Inventors

1. RAMAN, Ravishankar
HINDUSTAN PETROLEUM CORPORATION LTD., HPCL CORPORATE R&D CENTRE, 1ST FLOOR, ADARSH ECO PLACE, 176 EPIP KUNDENAHALLI HOBLI, WHITEFIELD, BANGALORE- 560 066
2. TOMPALA, Annaji Rajiv Kumar
HINDUSTAN PETROLEUM CORPORATION LTD., HPCL CORPORATE R&D CENTRE, 1ST FLOOR, ADARSH ECO PLACE, 176 EPIP KUNDENAHALLI HOBLI, WHITEFIELD, BANGALORE- 560 066
3. PEDDY, Venkata Chalapathi Rao
HINDUSTAN PETROLEUM CORPORATION LTD., HPCL CORPORATE R&D CENTRE, 1ST FLOOR, ADARSH ECO PLACE, 176 EPIP KUNDENAHALLI HOBLI, WHITEFIELD, BANGALORE- 560 066
4. NETTEM, Venkateswarlu Choudary
HINDUSTAN PETROLEUM CORPORATION LTD., HPCL CORPORATE R&D CENTRE, 1ST FLOOR, ADARSH ECO PLACE, 176 EPIP KUNDENAHALLI HOBLI, WHITEFIELD, BANGALORE- 560 066
5. GANDHAM, Sriganesh
HINDUSTAN PETROLEUM CORPORATION LTD., HPCL CORPORATE R&D CENTRE, 1ST FLOOR, ADARSH ECO PLACE, 176 EPIP KUNDENAHALLI HOBLI, WHITEFIELD, BANGALORE- 560 066
6. MUKKAMALA, Saratchandra Babu
NANOSCIENCE & NANOTECHNOLOGY LABORATORY, DEPARTMENT OF CHEMISTRY, GITAM UNIVERSITY VISAKHAPATNAM, ANDHRA PRADESH 530045
7. NARAYANAM, Nagaraju
NANOSCIENCE & NANOTECHNOLOGY LABORATORY, DEPARTMENT OF CHEMISTRY, GITAM UNIVERSITY VISAKHAPATNAM, ANDHRA PRADESH 530045
8. GANGU, Kranthi Kumar
NANOSCIENCE & NANOTECHNOLOGY LABORATORY, DEPARTMENT OF CHEMISTRY, GITAM UNIVERSITY VISAKHAPATNAM, ANDHRA PRADESH 530045

Specification

DESC:HIGH GAS ADSORPTION IN A METAL ORGANIC FRAMEWORK ,CLAIMS:1. An organic linker represented by formula I:

Formula I
2. A process for preparing the organic linker of formula I as claimed in claim 1, the process comprising:
a) adding 4-amino benzoic acid to 1,4,5,8-napthalene tetracarboxylic acid dianhydride in a weight ratio in the range of 1:5 to 5:1 in an organic solvent to obtain a mixture; and
b) heating the mixture at a temperature range of 160?C - 190 ?C for a period of 1 - 2 hours to obtain an organic linker of formula I.
3. The process as claimed in claim 2, wherein the organic solvent is selected from the group comprising of polar solvents, non polar solvents, and mixtures thereof.
4. The process as claimed in claim 2, wherein the organic solvent is selected from the group comprising of acetone, acetonitrile, DMF, DMA, DMSO, ethyl acetate, and mixtures thereof, preferably DMF.
5. A process for preparing the organic linker of formula I as claimed in claim 2, the process comprising:
c) adding 4-amino benzoic acid to 1,4,5,8-napthalene tetracarboxylic acid dianhydride in a weight ratio of 1:1 in DMF to obtain a mixture; and
d) heating the mixture at a temperature of 180 ?C for 1.5 hours, to obtain an organic linker of formula I.
6. A metal-organic framework of the formula M-L, wherein,
M comprises a metal ion and L is an organic linker of formula I as claimed in claim 1

Formula I
7. The metal-organic framework as claimed in claim 6, wherein the metal ion is selected from the group consisting of alkaline earth metals, transition metals, and mixtures thereof.
8. The metal-organic framework as claimed in claim 6, wherein the metal ion is Mg.
9. The metal-organic framework as claimed in claim 6, wherein the metal ion is Co.
10. A process for preparing a metal organic framework as claimed in claim 6, the process comprising:
dissolving at least one metal salt and an organic linker of formula I as claimed in claim 1 in a solvent in a weight ratio in the range of 2:1 to 30:1 to obtain a solution;
heating the solution at a temperature range of 90?C - 150 ?C for a period of about 50-100 hours; and
cooling slowly to a temperature in the range of 10-30°C to obtain crystals of metal organic framework.
11. The process as claimed in claim 10, wherein the metal salt is selected from the group comprising of alkaline earth metal salts, transitional metal salts, and mixtures thereof, preferably selected from the group comprising of alkaline earth metal halides, and transitional metal nitrates, most preferably selected from the group comprising of MgCl2. 6H2O and Co(NO3)2. 6H2O.
12. The process as claimed in claim 10, wherein the solvent is selected from the group comprising of polar solvents, and mixtures thereof, preferably selected from the group comprising of DMF, DMA, ethanol, methanol, water, acetonitrile, acetone, ethyl acetate, acetyl acetonate, DMSO, and mixtures thereof, most preferably selected from the group comprising of DMF, ethanol, water, and mixtures thereof.
13. A process for preparing a metal organic framework as claimed in claim 6, the process comprising:
dissolving MgCl2. 6H2O and an organic linker of formula I as claimed in claim 1, in the ratio of 16:1 by weight in a solvent to obtain a solution, wherein the solvent is DMF:ethanol:water in the ratio of 15:1:1 v/v;
heating the solution at a temperature of 125 ?C for 72 hours; and
cooling slowly to a temperature in the range of 10-30°C to obtain crystals of metal organic framework.
14. The process as claimed in claim 13, wherein the metal organic framework material has a distorted octahedral structure
15. A process for preparing a metal organic framework as claimed in claim 6, the process comprising:
dissolving Co(NO3)2. 6H2O and an organic compound of formula I in a ratio of 6:1 by weight in a solvent to obtain a solution, wherein the solvent is DMF: ethanol: water in the ratio of 3:2:2 v/v;
heating the solution at a temperature of 100 ?C for 96 hours; and
cooling slowly to a temperature in the range of 20-30°C to obtain crystals of metal organic framework.
16. The process as claimed in claim 15, wherein the metal organic framework material has a cubic structure
17. The metal-organic framework as claimed in claim 6, wherein the metal-organic framework is used for storage of gas selected from the group consisting of ammonia, argon, helium, hydrogen sulfide, carbon dioxide, carbon monoxide, hydrogen, nitrogen, methane and combinations thereof, preferably hydrogen.

Documents

Application Documents

# Name Date
1 2223-MUM-2013-FORM 26(26-12-2013).pdf 2013-12-26
1 2223-MUM-2013-IntimationOfGrant10-02-2023.pdf 2023-02-10
1 2223-MUM-2013-PROOF OF ALTERATION [18-04-2025(online)].pdf 2025-04-18
2 2223-MUM-2013-FORM 1(26-12-2013).pdf 2013-12-26
2 2223-MUM-2013-IntimationOfGrant10-02-2023.pdf 2023-02-10
2 2223-MUM-2013-PatentCertificate10-02-2023.pdf 2023-02-10
3 2223-MUM-2013-CORRESPONDENCE(26-12-2013).pdf 2013-12-26
3 2223-MUM-2013-PatentCertificate10-02-2023.pdf 2023-02-10
3 2223-MUM-2013-Written submissions and relevant documents (MANDATORY) [18-10-2019(online)].pdf 2019-10-18
4 2223-MUM-2013-Written submissions and relevant documents (MANDATORY) [18-10-2019(online)].pdf 2019-10-18
4 2223-MUM-2013-PETITION UNDER RULE 137 [04-04-2018(online)].pdf 2018-04-04
4 2223-MUM-2013-HearingNoticeLetter04-10-2019.pdf 2019-10-04
5 2223-MUM-2013-OTHERS [04-04-2018(online)].pdf 2018-04-04
5 2223-MUM-2013-HearingNoticeLetter04-10-2019.pdf 2019-10-04
5 2223-MUM-2013-Correspondence to notify the Controller (Mandatory) [30-09-2019(online)].pdf 2019-09-30
6 2223-MUM-2013-FER_SER_REPLY [04-04-2018(online)].pdf 2018-04-04
6 2223-MUM-2013-CORRESPONDENCE(24-7-2014).pdf 2018-08-11
6 2223-MUM-2013-Correspondence to notify the Controller (Mandatory) [30-09-2019(online)].pdf 2019-09-30
7 2223-MUM-2013-CORRESPONDENCE(25-6-2014).pdf 2018-08-11
7 2223-MUM-2013-CORRESPONDENCE(24-7-2014).pdf 2018-08-11
7 2223-MUM-2013-COMPLETE SPECIFICATION [04-04-2018(online)].pdf 2018-04-04
8 2223-MUM-2013-CORRESPONDENCE(25-6-2014).pdf 2018-08-11
8 2223-MUM-2013-FER.pdf 2018-08-11
8 RRS-26072013-Complete specification_PD010181IN-SC.pdf 2018-08-11
9 2223-MUM-2013-FER.pdf 2018-08-11
9 2223-MUM-2013-FORM 26(24-7-2014).pdf 2018-08-11
9 PD010181IN-SC-HIGH GAS ADSORPTION IN A METAL ORGANIC FRAMEWORK.pdf 2018-08-11
10 2223-MUM-2013-FORM 26(24-7-2014).pdf 2018-08-11
10 2223-MUM-2013-FORM 5(25-6-2014).pdf 2018-08-11
10 Form-2(Online).pdf 2018-08-11
11 2223-MUM-2013-FORM 5(25-6-2014).pdf 2018-08-11
11 2223-MUM-2013-ORIGINAL UR 6( 1A) FORM 26-090418.pdf 2018-08-11
11 Form-18(Online).pdf 2018-08-11
12 2223-MUM-2013-ORIGINAL UR 6( 1A) FORM 26-090418.pdf 2018-08-11
12 ABSTRACT.jpg 2018-08-11
12 FORM 3.pdf 2018-08-11
13 Figures.pdf 2018-08-11
13 ABSTRACT.jpg 2018-08-11
14 ABSTRACT.jpg 2018-08-11
14 Figures.pdf 2018-08-11
14 FORM 3.pdf 2018-08-11
15 2223-MUM-2013-ORIGINAL UR 6( 1A) FORM 26-090418.pdf 2018-08-11
15 FORM 3.pdf 2018-08-11
15 Form-18(Online).pdf 2018-08-11
16 2223-MUM-2013-FORM 5(25-6-2014).pdf 2018-08-11
16 Form-18(Online).pdf 2018-08-11
16 Form-2(Online).pdf 2018-08-11
17 Form-2(Online).pdf 2018-08-11
17 PD010181IN-SC-HIGH GAS ADSORPTION IN A METAL ORGANIC FRAMEWORK.pdf 2018-08-11
17 2223-MUM-2013-FORM 26(24-7-2014).pdf 2018-08-11
18 PD010181IN-SC-HIGH GAS ADSORPTION IN A METAL ORGANIC FRAMEWORK.pdf 2018-08-11
18 RRS-26072013-Complete specification_PD010181IN-SC.pdf 2018-08-11
18 2223-MUM-2013-FER.pdf 2018-08-11
19 2223-MUM-2013-COMPLETE SPECIFICATION [04-04-2018(online)].pdf 2018-04-04
19 2223-MUM-2013-CORRESPONDENCE(25-6-2014).pdf 2018-08-11
19 RRS-26072013-Complete specification_PD010181IN-SC.pdf 2018-08-11
20 2223-MUM-2013-COMPLETE SPECIFICATION [04-04-2018(online)].pdf 2018-04-04
20 2223-MUM-2013-CORRESPONDENCE(24-7-2014).pdf 2018-08-11
20 2223-MUM-2013-FER_SER_REPLY [04-04-2018(online)].pdf 2018-04-04
21 2223-MUM-2013-Correspondence to notify the Controller (Mandatory) [30-09-2019(online)].pdf 2019-09-30
21 2223-MUM-2013-FER_SER_REPLY [04-04-2018(online)].pdf 2018-04-04
21 2223-MUM-2013-OTHERS [04-04-2018(online)].pdf 2018-04-04
22 2223-MUM-2013-HearingNoticeLetter04-10-2019.pdf 2019-10-04
22 2223-MUM-2013-OTHERS [04-04-2018(online)].pdf 2018-04-04
22 2223-MUM-2013-PETITION UNDER RULE 137 [04-04-2018(online)].pdf 2018-04-04
23 2223-MUM-2013-CORRESPONDENCE(26-12-2013).pdf 2013-12-26
23 2223-MUM-2013-PETITION UNDER RULE 137 [04-04-2018(online)].pdf 2018-04-04
23 2223-MUM-2013-Written submissions and relevant documents (MANDATORY) [18-10-2019(online)].pdf 2019-10-18
24 2223-MUM-2013-CORRESPONDENCE(26-12-2013).pdf 2013-12-26
24 2223-MUM-2013-FORM 1(26-12-2013).pdf 2013-12-26
24 2223-MUM-2013-PatentCertificate10-02-2023.pdf 2023-02-10
25 2223-MUM-2013-IntimationOfGrant10-02-2023.pdf 2023-02-10
25 2223-MUM-2013-FORM 26(26-12-2013).pdf 2013-12-26
25 2223-MUM-2013-FORM 1(26-12-2013).pdf 2013-12-26
26 2223-MUM-2013-PROOF OF ALTERATION [18-04-2025(online)].pdf 2025-04-18
26 2223-MUM-2013-FORM 26(26-12-2013).pdf 2013-12-26

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