Abstract: A hot-rolled steel sheet contains C, Si, Mn and sol. Al as chemical components, and has such a property that the sum total of the mean pole density in direction groups consisting of {211}<111> to {111}<112> and the pole density in a {110}<001> crystal direction in a surface region thereof is 0.5 to 6.0 inclusive and the tensile strength is 780 to 1370 MPa inclusive.
The present invention relates to a high-strength hot-rolled steel sheet having excellent bending workability.
The present application claims priority based on Japanese Patent Application No. 2018-222297 filed in Japan on November 28, 2018, the contents of which are incorporated herein by reference.
Background technology
[0002]
There is a demand for both improving fuel efficiency of automobiles and ensuring collision safety, and increasing the strength of steel sheets for automobiles is being promoted, and high-strength steel sheets are often used for automobile bodies. ..
[0003]
So-called hot-rolled steel sheets manufactured by hot rolling are widely used as relatively inexpensive structural materials and as materials for structural members of automobiles and industrial equipment. In particular, hot-rolled steel sheets used for undercarriage parts, bumper parts, shock absorbing members, etc. of automobiles are being strengthened from the viewpoints of weight reduction, durability, shock absorbing capacity, etc., and at the same time, they are complicated. It is also required to have excellent moldability that can withstand molding into a flexible shape.
[0004]
However, since the formability of the hot-rolled steel sheet tends to decrease as the strength of the material increases, it is a difficult problem to achieve both high strength and good formability.
[0005]
In particular, in recent years, there has been an increasing demand for weight reduction of undercarriage parts of automobiles, and it has become an important issue to realize high tensile strength of 780 MPa or more and excellent bending workability.
[0006]
For example, Non-Patent Document 1 reports that bending workability is improved by controlling a single structure such as ferrite, bainite, and martensite by controlling the structure.
[0007]
Patent Document 1 describes in terms of mass%, C: 0.010 to 0.055%, Si: 0.2% or less, Mn: 0.7% or less, P: 0.025% or less, S: 0.02. % Or less, N: 0.01% or less, Al: 0.1% or less, Ti: 0.06 to 0.095%, and the area ratio is controlled to be 95% or more composed of ferrite. By controlling the structure in which only the carbide particle size containing Ti in the grain and TiS having an average diameter of 0.5 μm or less as Ti-containing sulfide are dispersed and precipitated, the tensile strength of 590 MPa or more and 750 MPa or less and excellent bending workability are controlled. The method of realizing the above is disclosed.
[0008]
On the other hand, Patent Document 2 describes in terms of mass%, C: 0.05 to 0.15%, Si: 0.2 to 1.2%, Mn: 1.0 to 2.0%, P: 0.04. % Or less, S: 0.0030% or less, Al: 0.005 to 0.10%, N: 0.005% or less and Ti: 0.03 to 0.13%. The bainite single phase or bainite is controlled to a structure with a fraction of more than 95%, and the structure of the surface layer of the steel plate is a bainite phase with a fraction of less than 80% and a highly processable ferrite fraction of 10. % Or more, a method of improving the bending workability while maintaining the tensile strength of 780 MPa or more is disclosed.
[0009]
Further, Patent Document 3 describes in terms of mass%, C: 0.08 to 0.25%, Si: 0.01 to 1.0%, Mn: 0.8 to 1.5%, P: 0.025. % Or less, S: 0.005% or less, Al: 0.005 to 0.10%, Nb: 0.001 to 0.05%, Ti: 0.001 to 0.05%, Mo: 0.1 to Contains 1.0%, Cr: 0.1-1.0%, the tempered martensite phase is the main phase with a volume ratio of 90% or more, and the average particle size of the old austenite grains in the cross section parallel to the rolling direction. Is 20 μm or less and the average particle size of the old austenite grains in the cross section orthogonal to the rolling direction is 15 μm or less. A high-strength hot-rolled steel sheet having excellent bending workability and low-temperature toughness is disclosed.
[0010]
In Patent Document 4, the extreme density of each direction of a specific crystal orientation group in the central portion of the plate thickness, which is in the plate thickness range of 5/8 to 3/8 from the surface of the steel plate, is controlled, and the direction is perpendicular to the rolling direction. The rankford value of rC is 0.70 or more and 1.10 or less, and the rankford value of r30 in the direction forming 30 ° with respect to the rolling direction is 0.70 or more and 1.10 or less. A hot-rolled steel sheet having excellent local deformability and small bending workability anisotropy is disclosed.
Prior art literature
Patent documents
[0011]
Patent Document 1: Japanese Patent Application Laid-Open No. 2013-133499
Patent Document 2: Japanese Patent Application Laid-Open No. 2012-62558
Patent Document 3: Japanese Patent Application Laid-Open No. 2012-77336
Patent Document 4: International Publication No. 2012/121219
Non-patent literature
[0012]
Non-Patent Document 1: Journal of the Japan Society for Technology of Plasticity, vol. 36 (1995), No. 416, p. 973
Outline of the invention
Problems to be solved by the invention
[0013]
As described above, it is currently required to further improve the bending workability after increasing the strength of the steel sheet. However, in the above-mentioned techniques of Patent Documents 1 to 4, the strength and the bending workability are different. It cannot be said that both are sufficient. An object to be solved by the present invention is to provide a high-strength hot-rolled steel sheet having excellent bending workability.
[0014]
The above-mentioned bending workability is an index indicating that cracks are unlikely to occur in the processed portion during bending processing, or an index indicating that the cracks are unlikely to grow. However, in the present invention, which will be described in detail later, unlike the conventional case, a crack (internal bending crack) generated from the inside of the bending portion during bending is targeted.
Means to solve problems
[0015]
The gist of the present invention is as follows.
(1) The hot-rolled steel sheet according to one aspect of the present invention has C: 0.030% or more and 0.400% or less, Si: 0.050% or more and 2.5% or less, Mn in mass% as chemical components. : 1.00% or more and 4.00% or less, sol. Al: 0.001% or more and 2.0% or less, Ti: 0% or more and 0.20% or less, Nb: 0% or more and 0.20% or less, B: 0% or more and 0.010% or less, V: 0% More than 1.0% or less, Cr: 0% or more and 1.0% or less, Mo: 0% or more and 1.0% or less, Cu: 0% or more and 1.0% or less, Co: 0% or more and 1.0% or less , W: 0% or more and 1.0% or less, Ni: 0% or more and 1.0% or less, Ca: 0% or more and 0.01% or less, Mg: 0% or more and 0.01% or less, REM: 0% or more Includes 0.01% or less, Zr: 0% or more and 0.01% or less, P: 0.020% or less, S: 0.020% or less, N: 0.010% or less, and the balance is iron and The average polar density of the orientation group consisting of {211} <111> to {111} <112> and {110} <001 in the surface region consisting of impurities and ranging from the surface of the steel plate to the plate thickness of 1/10. > With the extreme density of the crystal orientation is 0.5 or more and 6.0 or less, and the tensile strength is 780 MPa or more and 1370 MPa or less.
(2) In the hot-rolled steel sheet according to (1) above, crystals of {332} <113> are formed in an internal region having a plate thickness of 1/8 to 3/8 based on the surface of the steel sheet. The sum of the polar density of the orientation and the polar density of the crystal orientation of {110} <001> may be 1.0 or more and 7.0 or less.
(3) In the hot-rolled steel sheet according to (1) or (2) above, as the chemical components, Ti: 0.001% or more and 0.20% or less, Nb: 0.001% or more and 0. 20% or less, B: 0.001% or more and 0.010% or less, V: 0.005% or more and 1.0% or less, Cr: 0.005% or more and 1.0% or less, Mo: 0.005% or more 1.0% or less, Cu: 0.005% or more and 1.0% or less, Co: 0.005% or more and 1.0% or less, W: 0.005% or more and 1.0% or less, Ni: 0.005 % Or more and 1.0% or less, Ca: 0.0003% or more and 0.01% or less, Mg: 0.0003% or more and 0.01% or less, REM: 0.0003% or more and 0.01% or less, Zr: 0 It may contain at least one of 0003% or more and 0.01% or less.
The invention's effect
[0016]
According to the above embodiment of the present invention, it is possible to obtain a hot-rolled steel sheet having a tensile strength (maximum tensile strength) of 780 MPa or more and excellent bending workability capable of suppressing the occurrence of internal bending cracks.
A brief description of the drawing
[0017]
FIG. 1 is a crystal orientation distribution function (ODF) with a cross section of φ2 = 45 °, showing an orientation group consisting of {211} <111> to {111} <112> and {110} <001> orientation. It is a figure.
FIG. 2 is a crystal orientation distribution function (ODF) with a cross section of φ2 = 45 °, showing {332} <113> orientation and {110} <001> orientation.
Mode for carrying out the invention
[0018]
Hereinafter, the hot-rolled steel sheet according to the embodiment of the present invention will be described in detail. However, the present invention is not limited to the configuration disclosed in the present embodiment, and various modifications can be made without departing from the spirit of the present invention. In addition, the lower limit value and the upper limit value are included in the numerical limitation range described below. Numerical values that indicate "greater than" or "less than" are not included in the numerical range. "%" Regarding the content of each element means "mass%".
[0019]
First, the background to the idea of the hot-rolled steel sheet according to the present embodiment will be described.
[0020]
Conventionally, cracks in the bending process of a steel sheet have generally occurred from the surface of the steel sheet on the outside of the bending or the vicinity of the end face. However, as a result of diligent research on the bending workability of high-strength steel sheets, the present inventors have clarified that the higher the steel sheet strength, the more likely it is that cracks will occur from the surface of the steel sheet inside the bending process (hereinafter,). , Called internal bending crack). Such bending internal cracks have not been investigated so far.
[0021]
The mechanism of internal bending cracking is presumed as follows. During bending, compressive stress is generated inside the bend. At first, the entire inside of the bend is deformed uniformly while processing proceeds, but when the amount of processing increases, the deformation cannot be carried out only by uniform deformation, and the deformation progresses due to the concentration of strain locally (generation of shear deformation zone). As the shear band grows further, cracks along the shear band grow from the inner surface of the bend.
[0022]
The reason why internal bending cracks are likely to occur as the strength of the steel sheet increases is that uniform deformation is less likely to proceed due to the decrease in work hardening ability due to the increase in strength of the steel sheet, and biased deformation is likely to occur. It is presumed that a shear band is generated early in the work (or under loose work conditions).
[0023]
According to the research by the present inventors, it has been found that in-bending cracks are more likely to occur in a steel sheet having a tensile strength of 780 MPa or more, become more prominent in a steel sheet having a tensile strength of 980 MPa or more, and become more prominent in a steel sheet having a tensile strength of 1180 MPa or more.
[0024]
Based on the above-mentioned estimation mechanism (generation and propagation of cracks along the shear deformation zone) in which in-bending cracks occur, the present inventors have searched for a method for suppressing in-bending cracks focusing on the texture.
[0025]
When the steel sheet is deformed, the easiness of the slip system to work against the deformation differs depending on each crystal orientation (Schmid factor). This means that the deformation resistance differs depending on the crystal orientation. If the texture is relatively random, the deformation resistance is also uniform, so deformation is likely to occur uniformly. However, when a specific texture develops, between crystals with a large deformation resistance and crystals with other directions. Since the deformation is biased, a shear deformation zone is likely to occur.
[0026]
On the contrary, if the abundance ratio of the azimuth grains having a large deformation resistance is reduced, the deformation occurs uniformly, so that the shear deformation zone is less likely to occur. That is, there is a possibility that internal bending cracking can be suppressed. Based on this idea, the present inventors diligently investigated the relationship between the texture of the hot-rolled steel sheet and the bending internal cracks, and controlled the specific texture that easily develops in the hot-rolled steel sheet, thereby suppressing the bending internal cracks. I found.
[0027]
In particular, as a result of diligent studies by the present inventors, it has been found that the texture in the surface region of the steel sheet affects the formation of cracks during bending deformation. It was also found that the texture of the internal region in the range of 1/8 to 3/8 of the thickness of the steel sheet affects the propagation of cracks generated in the surface region.
[0028]
Based on the above findings, the present inventors control the texture formed in the surface region of the steel sheet in the finish rolling of hot rolling and reduce the abundance ratio of the directional grains having a large deformation resistance, thereby causing internal bending cracking. We have found that it is possible to realize a hot-rolled steel sheet that can suppress the occurrence of. In addition, it has been found that if the texture of the steel sheet surface region is controlled and then the texture of the steel plate inner region is also controlled, the propagation of internal bending cracks can be more preferably suppressed.
[0029]
Specifically, the steel composition is controlled within an appropriate range, the plate thickness and temperature during hot rolling are controlled, and in addition, during finish rolling of hot rolling, which has not been positively controlled in the past, Machining of the steel sheet surface area by controlling the plate thickness, roll shape ratio, rolling ratio and temperature in the final two-stage rolling, and controlling the total rolling ratio in the final three-stage rolling during finish rolling. Control the organization. As a result, it was found that recrystallization is controlled and the texture of the surface region of the steel sheet is optimized, so that the occurrence of internal bending cracks can be suppressed.
[0030]
Further, in addition to optimizing the texture of the steel sheet surface region as described above, the work structure of the steel sheet internal region is controlled by preferably controlling the finish rolling conditions of hot rolling, and as a result, the texture of the steel sheet internal region is obtained. It has been found that if it is optimized, the propagation of internal bending cracks can be suppressed more preferably.
[0031]
The hot-rolled steel sheet according to the present embodiment has C: 0.030% or more and 0.400% or less, Si: 0.050% or more and 2.5% or less, Mn: 1.00% in mass% as chemical components. More than 4.00% or less, sol. Al: 0.001% or more and 2.0% or less, Ti: 0% or more and 0.20% or less, Nb: 0% or more and 0.20% or less, B: 0% or more and 0.010% or less, V: 0% More than 1.0% or less, Cr: 0% or more and 1.0% or less, Mo: 0% or more and 1.0% or less, Cu: 0% or more and 1.0% or less, Co: 0% or more and 1.0% or less , W: 0% or more and 1.0% or less, Ni: 0% or more and 1.0% or less, Ca: 0% or more and 0.01% or less, Mg: 0% or more and 0.01% or less, REM: 0% or more Includes 0.01% or less, Zr: 0% or more and 0.01% or less, P: 0.020% or less, S: 0.020% or less, N: 0.010% or less, and the balance is iron and Consists of impurities. Further, in the hot-rolled steel sheet according to the present embodiment, the average pole of the orientation group consisting of {211} <111> to {111} <112> in the surface region in the range from the steel sheet surface to the plate thickness 1/10. The sum of the density and the extreme density of the crystal orientation of {110} <001> is 0.5 or more and 6.0 or less. Further, in the hot-rolled steel sheet according to the present embodiment, the tensile strength is 780 MPa or more and 1370 MPa or less.
[0032]
Further, in the hot-rolled steel sheet according to the present embodiment, the extreme density of the crystal orientation of {332} <113> in the internal region in the range of 1/8 to 3/8 of the plate thickness with respect to the surface of the steel plate. The sum of {110} <001> and the extreme density of the crystal orientation is preferably 1.0 or more and 7.0 or less.
[0033]
Further, the hot-rolled steel sheet according to the present embodiment has Ti: 0.001% or more and 0.20% or less, Nb: 0.001% or more and 0.20% or less, B: 0. 001% or more and 0.010% or less, V: 0.005% or more and 1.0% or less, Cr: 0.005% or more and 1.0% or less, Mo: 0.005% or more and 1.0% or less, Cu: 0.005% or more and 1.0% or less, Co: 0.005% or more and 1.0% or less, W: 0.005% or more and 1.0% or less, Ni: 0.005% or more and 1.0% or less, Ca: 0.0003% or more and 0.01% or less, Mg: 0.0003% or more and 0.01% or less, REM: 0.0003% or more and 0.01% or less, Zr: 0.0003% or more and 0.01% It may contain at least one of the following.
[0034]
1. 1. Chemical composition
First, the steel composition and the reasons for its limitation will be described. The hot-rolled steel sheet according to the present embodiment contains a basic element as a chemical component, and if necessary, a selective element, and the balance is composed of iron and impurities.
[0035]
Among the chemical components of the hot-rolled steel sheet according to the present embodiment, C, Si, Mn, and Al are basic elements (main alloying elements).
[0036]
(C: 0.030% or more and 0.400% or less)
C (carbon) is an important element for ensuring the strength of the steel sheet. If the C content is less than 0.030%, the tensile strength of 780 MPa or more cannot be secured. Therefore, the C content is 0.030% or more, preferably 0.05% or more. On the other hand, if the C content exceeds 0.400%, the weldability deteriorates, so the upper limit is set to 0.400%. The C content is preferably 0.30% or less, more preferably 0.20%.
[0037]
(Si: 0.050% or more and 2.5% or less)
Si (silicon) is an important element that can increase the material strength by solid solution strengthening. If the Si content is less than 0.050%, the yield strength is lowered, so the Si content is set to 0.050% or more. The Si content is preferably 0.1% or more, more preferably 0.3% or more. On the other hand, if the Si content exceeds 2.5%, the surface texture deteriorates, so the Si content is set to 2.5% or less. The Si content is preferably 2.0% or less, more preferably 1.5% or less.
[0038]
(Mn: 1.00% or more and 4.00% or less)
Mn (manganese) is an effective element for increasing the mechanical strength of a steel sheet. If the Mn content is less than 1.00%, it is not possible to secure a tensile strength of 780 MPa or more. Therefore, the Mn content is set to 1.00% or more. The Mn content is preferably 1.50% or more, more preferably 2.00% or more. On the other hand, when Mn is added excessively, the structure becomes non-uniform due to Mn segregation, and the bending workability is lowered. Therefore, the Mn content is set to 4.00% or less, preferably 3.00% or less, and more preferably 2.60% or less.
[0039]
(Sol.Al: 0.001% or more and 2.0% or less)
sol. Al (acid-soluble aluminum) is an element that has the effect of deoxidizing steel and making the steel sheet sound. sol. If the Al content is less than 0.001%, it cannot be sufficiently deoxidized. The Al content is 0.001% or more. However, if sufficient deoxidation is required, sol. The Al content is more preferably 0.01% or more, and more preferably 0.02% or more. On the other hand, sol. When the Al content exceeds 2.0%, the weldability is remarkably lowered, and the oxide-based inclusions are increased, so that the surface texture is remarkably deteriorated. Therefore, sol. The Al content is 2.0% or less, preferably 1.5% or less, more preferably 1.0% or less, and most preferably 0.08% or less. In addition, sol. Al means an acid-soluble Al that is not an oxide such as Al 2 O 3 and is soluble in an acid.
[0040]
The hot-rolled steel sheet according to this embodiment contains impurities as a chemical component. The term "impurity" refers to substances mixed from ore or scrap as a raw material, or from the manufacturing environment, etc., when steel is industrially manufactured. For example, it means an element such as P, S, N. These impurities are preferably limited as follows in order to fully exert the effects of the present embodiment. Further, since the content of impurities is preferably small, it is not necessary to limit the lower limit value, and the lower limit value of impurities may be 0%.
[0041]
(P: 0.020% or less)
P (phosphorus) is an impurity generally contained in steel. However, since it has an effect of increasing the tensile strength, P may be positively contained. However, when the P content exceeds 0.020%, the deterioration of weldability becomes remarkable. Therefore, the P content is limited to 0.020% or less. The P content is preferably limited to 0.010% or less. In order to obtain the effect of the above action more reliably, the P content may be 0.001% or more.
[0042]
(S: 0.020% or less)
S (sulfur) is an impurity contained in steel, and the smaller the amount, the more preferable it is from the viewpoint of weldability. When the S content exceeds 0.020%, the weldability is significantly lowered, the MnS precipitation amount is increased, and the low temperature toughness is lowered. Therefore, the S content is limited to 0.020% or less. The S content is preferably limited to 0.010% or less, more preferably 0.005% or less. From the viewpoint of desulfurization cost, the S content may be 0.001% or more.
[0043]
(N: 0.010% or less)
N (nitrogen) is an impurity contained in steel, and the smaller the amount, the more preferable it is from the viewpoint of weldability. If the N content exceeds 0.010%, the weldability is significantly reduced. Therefore, the N content is limited to 0.010% or less. The N content is preferably limited to 0.005% or less, more preferably 0.003% or less.
[0044]
The hot-rolled steel sheet according to the present embodiment may contain a selective element in addition to the basic elements and impurities described above. For example, instead of a part of Fe which is the balance described above, at least one of Ti, Nb, B, V, Cr, Mo, Cu, Co, W, Ni, Ca, Mg, REM, and Zr is used as a selective element. It may contain one kind. These selective elements preferably improve the mechanical properties of the hot-rolled steel sheet. These selective elements may be contained according to the purpose. Therefore, it is not necessary to limit the lower limit values of these selective elements, and the lower limit value may be 0%. Further, even if these selective elements are contained as impurities, the above effects are not impaired.
[0045]
(Ti: 0% or more and 0.20% or less)
Ti (titanium) is an element as TiC that precipitates on ferrite or bainite of the steel sheet structure during cooling or winding of the steel sheet and contributes to the improvement of strength. .. Therefore, Ti may be contained. Excessive addition of Ti suppresses recrystallization during hot rolling and develops a texture with a specific crystal orientation. Therefore, R / t, which is the average value of the minimum inward bending radii of L-axis bending and C-axis bending divided by the plate thickness, does not become 2.2 or less. Therefore, the Ti content is set to 0.20% or less. The Ti content is preferably 0.18% or less, more preferably 0.15% or less. In order to obtain the above effect preferably, the Ti content may be 0.001% or more. The Ti content is preferably 0.02% or more.
[0046]
(Nb: 0% or more and 0.20% or less)
Nb (niobium) is an element that precipitates as NbC, improves the strength, and remarkably suppresses the recrystallization of austenite, like Ti. Therefore, Nb may be contained. When Nb exceeds 0.20%, recrystallization of austenite is suppressed during hot rolling and texture develops, so that the average value of the minimum inward bending radii of L-axis bending and C-axis bending is calculated by plate thickness. The divided value, R / t, does not fall below 2.2. Therefore, the Nb content is set to 0.20% or less. The Nb content is preferably 0.15% or less, more preferably 0.10% or less. In order to obtain the above effect preferably, the Nb content may be 0.001% or more. The Nb content is preferably 0.005% or more.
[0047]
In the hot-rolled steel sheet according to the present embodiment, at least of Ti: 0.001% or more and 0.20% or less and Nb: 0.001% or more and 0.20% or less in mass% as chemical components. It is preferable to contain one kind.
[0048]
(B: 0% or more and 0.010% or less)
B (boron) segregates at the grain boundaries to improve the grain boundary strength, so that the roughness of the punched cross section at the time of punching can be suppressed. Therefore, B may be contained. Even if the B content exceeds 0.010%, the above effect is saturated and economically disadvantageous. Therefore, the upper limit of the B content is set to 0.010%. The B content is preferably 0.005% or less, more preferably 0.003% or less. In order to obtain the above effect preferably, the B content may be 0.001% or more.
[0049]
(V: 0% or more and 1.0% or less)
(Cr: 0% or more and 1.0% or less)
(Mo: 0% or more and 1.0% or less)
(Cu: 0% or more and 1.0% or less)
(Co : 0% or more and 1.0% or less)
(W: 0% or more and 1.0% or less)
(Ni: 0% or more and 1.0% or less)
V (vanadium), Cr (chromium), Mo (molybdenum), Cu (Copper), Co (cobalt), W (tungsten), and Ni (nickel) are all effective elements for ensuring stable strength. Therefore, these elements may be contained. However, even if each of the elements is contained in an amount of more than 1.0%, the effect of the above action is likely to be saturated, which may be economically disadvantageous. Therefore, the content of each of these elements is set to 1.0% or less. The content of each of these elements is preferably 0.8% or less, more preferably 0.5% or less, respectively. In order to obtain the effect of the above action more reliably, each element may be 0.005% or more.
[0050]
In the hot-rolled steel sheet according to the present embodiment, as chemical components, V: 0.005% or more and 1.0% or less, Cr: 0.005% or more and 1.0% or less, Mo: 0. 005% or more and 1.0% or less, Cu: 0.005% or more and 1.0% or less, Co: 0.005% or more and 1.0% or less, W: 0.005% or more and 1.0% or less, Ni: It is preferable to contain at least one of 0.005% or more and 1.0% or less.
[0051]
(Ca: 0% or more and 0.01% or less)
(Mg: 0% or more and 0.01% or less)
(REM: 0% or more and 0.01% or less)
(Zr: 0% or more and 0.01% or less)
Ca ( Calcium), Mg (magnesium), REM (rare earth element), and Zr (zirconium) are all elements that contribute to inclusion control, particularly fine dispersion of inclusions, and enhance toughness. Therefore, these elements may be contained. However, if each of the elements is contained in an amount of more than 0.01%, deterioration of the surface texture may become apparent. Therefore, the content of each of these elements shall be 0.01% or less. The content of each of these elements is preferably 0.005% or less, more preferably 0.003% or less, respectively. In order to obtain the effect of the above action more reliably, each element may be 0.0003% or more.
[0052]
Here, REM refers to a total of 17 elements of Sc, Y and lanthanoid, and is at least one of them. The content of REM means the total content of at least one of these elements. In the case of lanthanoids, they are industrially added in the form of misch metal.
[0053]
In the hot-rolled steel sheet according to the present embodiment, Ca: 0.0003% or more and 0.01% or less, Mg: 0.0003% or more and 0.01% or less, REM: 0. It is preferable to contain at least one of 0003% or more and 0.01% or less and Zr: 0.0003% or more and 0.01% or less.
[0054]
The above-mentioned steel composition may be measured by a general method for analyzing steel. For example, the steel component may be measured using ICP-AES (Inductively Coupled Plasma-Atomic Emission Spectrometry). In addition, sol. Al may be measured by ICP-AES using a filtrate obtained by heat-decomposing the sample with an acid. Further, C and S may be measured by using the combustion-infrared absorption method, N may be measured by using the inert gas melting-heat conductivity method, and O may be measured by using the inert gas melting-non-dispersion infrared absorption method.
[0055]
2. Aggregation Structure
Next, the assembly structure of the hot-rolled steel sheet according to the present embodiment will be described.
[0056]
The hot-rolled steel sheet according to the present embodiment has the average polar density of the orientation group consisting of {211} <111> to {111} <112> in the surface region in the range from the steel sheet surface to the plate thickness 1/10. , {110} <001> has a texture in which the sum with the extreme density of the crystal orientation is 0.5 or more and 6.0 or less.
[0057]
(Surface region in the range from the surface of the steel plate to 1/10 of the plate thickness) When the
steel plate is bent and deformed, the strain increases toward the surface with the center of the plate thickness as the boundary, and the strain becomes maximum on the outermost surface. Therefore, cracks of internal bending cracks are generated on the surface of the steel sheet. Since it is the structure of the surface region in the range from the surface of the steel sheet to the plate thickness of 1/10 that contributes to the formation of such cracks, the texture of the surface region is controlled.
[0058]
In the case of steel sheets having different developments of texture on the front and back surfaces, the above texture may be satisfied in the range from the surface of the steel plate on one side to the plate thickness of 1/10. The effect of this embodiment can be obtained by bending the surface that fills the texture to the inside.
[0059]
(In the surface region, the sum of the average polar density of the orientation group consisting of {211} <111> to {111} <112> and the extreme density of the crystal orientation of {110} <001> is 0.5 or more. (0 or less) The
orientation group consisting of {211} <111> to {111} <112> and the crystal orientation of {110} <001> are the orientations that easily develop in the surface region of the high-strength hot-rolled steel sheet produced by a conventional method. Is. Crystals having these orientations have a particularly large deformation resistance inside the bending during bending. Therefore, a shear deformation zone is likely to occur due to the difference in deformation resistance between the crystals having these orientations and the crystals having other orientations. Therefore, by reducing the extreme densities in these directions, it is possible to suppress internal bending cracks. However, even if only one of the average polar density of the orientation group consisting of {211} <111> to {111} <112> and the extreme density of the crystal orientation of {110} <001> is reduced, the present embodiment Since the effect of is not obtained, it is important to reduce the total.
[0060]
The average pole density of the orientation group consisting of {211} <111> to {111} <112> and the pole of the crystal orientation of {110} <001> in the surface region ranging from the surface of the steel plate to the thickness of 1/10. If the sum with the density is more than 6.0, a shear deformation zone is likely to occur remarkably, which causes internal bending cracks. Therefore, the average value of the minimum inward bending radii of L-axis bending and C-axis bending. R / t, which is the value obtained by dividing by the plate thickness, does not become 2.2 or less. Therefore, the sum of these is set to 6.0 or less. The sum of these is preferably 5.0 or less, more preferably 4.0 or less.
[0061]
The smaller the sum of the average pole density of the orientation group consisting of {211} <111> to {111} <112> and the pole density of the crystal orientation of {110} <001> is preferable, but the tensile strength is 780 MPa or more. In a high-strength hot-rolled steel sheet, it is difficult to make this value less than 0.5, so that the practical lower limit is 0.5.
[0062]
The hot-rolled steel sheet according to the present embodiment has the extreme density of the crystal orientation of {332} <113> in the internal region in the range of 1/8 to 3/8 of the plate thickness with respect to the surface of the steel plate. It is preferable to have a texture in which the sum of {110} <001> and the extreme density of the crystal orientation is 1.0 or more and 7.0 or less.
[0063]
(Internal region in the range from 1/8 of the plate thickness to 3/8 of the plate thickness with respect to the surface of the steel plate) When the
steel plate is bent and deformed and internal bending cracks occur in the surface region , the internal bending cracks occur inside the plate thickness. May propagate towards the region. Since the internal region in the range of 1/8 to 3/8 of the plate thickness mainly contributes to the propagation of such internal bending cracks with respect to the surface of the steel plate, it is necessary to control the texture of this region. Is preferable.
[0064]
(In the internal region, the sum of the extreme densities of the crystal orientations of {332} <113> and the extreme densities of the crystal orientations of {110} <001> is 1.0 or more and 7.0 or less.)
{332} <113> The crystal orientation and the crystal orientation of (110) <001> are orientations that easily develop in the internal region in the range of 1/8 to 3/8 of the thickness of the high-strength hot-rolled steel sheet produced by a conventional method. .. Crystals having these orientations tend to have a large deformation resistance inside the bending during bending. Therefore, due to the difference in deformation resistance between the crystals having these orientations and the crystals having other orientations, the bending internal cracks generated in the surface region are likely to propagate to the internal region. Therefore, it is possible to preferably suppress bending internal cracks by controlling the texture in the surface region and further reducing the extreme densities in these directions in the internal region. However, even if only one of the polar density of the crystal orientation of {332} <113> and the polar density of the crystal orientation of (110) <001> is reduced, the effect of the present embodiment cannot be obtained. It is preferable to reduce the total.
[0065]
The sum of the extreme density of the crystal orientation of {332} <113> and the extreme density of the crystal orientation of {110} <001> in the internal region in the range of 1/8 to 3/8 of the plate thickness. By controlling the value to 7.0 or less, internal bending cracking can be preferably suppressed. Therefore, by controlling the crystal orientation of the steel sheet surface region within a predetermined range and setting the sum of these extreme densities to 7.0 or less, the average value of the minimum inward bending radii of L-axis bending and C-axis bending can be obtained. R / t, which is the value divided by the plate thickness, satisfies 1.8 or less. The sum of the extreme densities is preferably 6.0 or less, more preferably 5.0 or less.
[0066]
The smaller the sum of the extreme density of the crystal orientation of {332} <113> and the extreme density of the crystal orientation of {110} <001> is preferable, but in a high-strength hot-rolled steel sheet having a tensile strength of 780 MPa or more, it is substantially. Since it is difficult to control the value to less than 1.0, the practical lower limit is 1.0.
[0067]
The extreme density can be measured by the EBSP (Electron Backscatter Diffraction Pattern) method. For the sample to be analyzed by the EBSP method, the cut surface parallel to the rolling direction and perpendicular to the plate surface is mechanically polished, and then the strain is removed by chemical polishing or electrolytic polishing. Using this sample, the measurement interval is 4 μm and the measurement area is 150,000 μm 2 in the range from the surface of the steel plate to the plate thickness 1/10 and, if necessary, the plate thickness 1/8 to the plate thickness 3/8. The analysis is performed by the EBSP method so as described above.
[0068]
FIG. 1 shows a crystal orientation distribution function (ODF) having a cross section of φ2 = 45 °, an orientation group consisting of {211} <111> to {111} <112>, and {110} <001> orientation. The orientation group consisting of {211} <111> to {111} <112> is the crystal orientation distribution function (ODF) of φ2 = 45 ° cross section, which displays the texture analysis in BUNGE, and has φ1 = 85 to 90 °. It refers to the range of Φ = 30 to 60 ° and φ2 = 45 °. The average polar density of this azimuth group is calculated in the above range shown in FIG. Strictly speaking, the {211} <111> to {111} <112> orientation group is in the range of φ1 = 90 °, Φ = 30 to 60 °, and φ2 = 45 ° on the ODF, but the test piece is processed. In the hot-rolled steel sheet according to this embodiment, the average polar density is calculated in the range of φ1 = 85 to 90 °, Φ = 30 to 60 °, and φ2 = 45 ° because there is a measurement error due to the setting of the sample and the sample. ..
[0069]
Similarly, the crystal orientation of {110} <001> is a crystal orientation distribution function (ODF) with a cross section of φ2 = 45 °, and ranges from φ1 = 85 to 90 °, Φ = 85 to 90 °, and φ2 = 45 °. Point to. The extreme density of this crystal orientation is calculated in the above range shown in FIG.
[0070]
Here, as for the crystal orientation of the rolled plate, the lattice plane parallel to the plate surface is usually indicated by (hkl) or {hkl}, and the orientation parallel to the rolling direction is indicated by [uvw] or . Note that {hkl} and are generic terms for equivalent lattice planes and directions, and (uvw) and [hkl] refer to individual lattice planes and directions. That is, since the hot-rolled steel sheet according to the present embodiment targets the bcc structure, for example, (110), (-110), (1-10), (-1-10), (101), (-). 101), (10-1), (-10-1), (011), (0-11), (01-1), (0-1-1) are equivalent lattice planes and can be distinguished. Not stick. In such a case, these lattice planes are collectively referred to as {110}.
[0071]
FIG. 2 shows a crystal orientation distribution function (ODF) having a cross section of φ2 = 45 °, {332} <113> orientation, and {110} <001> orientation. The crystal orientation of {332} <113> is the crystal orientation distribution function (ODF) of φ2 = 45 ° cross section, which displays the texture analysis in BUNGE, φ1 = 85 to 90 °, Φ = 60 to 70 °, φ2. = Refers to the range of 45 °. The extreme density of this crystal orientation is calculated in the above range shown in FIG.
[0072]
Similarly, the crystal orientation of {110} <001> is a crystal orientation distribution function (ODF) with a cross section of φ2 = 45 °, and ranges from φ1 = 85 to 90 °, Φ = 85 to 90 °, and φ2 = 45 °. Point to. The extreme density of this crystal orientation is calculated in the above range shown in FIG.
[0073]
3. 3. Steel sheet structure
in the hot rolled steel sheet according to the present embodiment, texture only to be controlled as described above, the configuration phase of the steel structure is not particularly limited.
[0074]
However, the hot-rolled steel sheet according to the present embodiment may have any phase such as ferrite, bainite, fresh martensite, tempered martensite, pearlite, retained austenite, etc. as a constituent phase of the steel structure, and has a structure. A compound such as martensite may be contained therein.
[0075]
For example, in% area, ferrite: 0% or more and 70% or less, total of bainite and tempered martensite: 0% or more and 100% or less (may be bainite and tempered martensite single structure), retained austenite: 25% or less. , Fresh martensite: 0% or more and 100% or less (may be a single martensite structure), and pearlite: 5% or less are preferable. It is preferable that the balance other than the above constituent phases is limited to 5% or less.
[0076]
4. Mechanical Properties
Next, the mechanical properties of the hot-rolled steel sheet according to this embodiment will be described.
[0077]
(Tensile strength is 780 MPa or more and 1370 MPa or less)
The hot-rolled steel sheet according to the present embodiment preferably has sufficient strength that contributes to weight reduction of automobiles. Therefore, the maximum tensile strength (TS) is set to 780 MPa or more. The maximum tensile strength is preferably 980 MPa or more. The upper limit of the maximum tensile strength does not need to be set in particular, but for example, this upper limit may be set to 1370 MPa. Further, the hot-rolled steel sheet according to the present embodiment preferably has a total elongation (EL) of 7% or more. The tensile test may be performed in accordance with JIS Z2241 (2011).
[0078]
The hot-rolled steel sheet according to the present embodiment is a value obtained by dividing the average value of the minimum inward bending radii of L-axis bending and C-axis bending by the plate thickness by satisfying the above-mentioned steel composition, texture, and tensile strength. A certain R / t becomes 2.2 or less.
[0079]
R is the minimum bending radius of the internal bending crack, and t is the thickness of the hot-rolled steel sheet. In the bending test, for example, a strip-shaped test piece is cut out from a position 1/2 in the width direction of a hot-rolled steel sheet, and bending (L-axis bending) in which the bending ridge line is parallel to the rolling direction (L direction) and bending ridge line are Both bending (C-axis bending) parallel to the direction perpendicular to the rolling direction (C direction) may be performed in accordance with JIS Z2248 (2014) (V block 90 ° bending test). It is investigated whether or not a crack is generated inside the bend, and the minimum inward bending radius R where the crack does not occur is obtained.
[0080]
5. Manufacturing Method
Next, a preferable manufacturing method of the hot-rolled steel sheet according to the present embodiment will be described.
[0081]
The method for manufacturing the hot-rolled steel sheet according to the present embodiment is not limited to the following method. The following manufacturing method is an example for manufacturing the hot-rolled steel sheet according to the present embodiment.
[0082]
In order to obtain excellent bending workability, it is important to suppress the occurrence of cracks by controlling the texture of the surface region of the steel sheet inside the bending, which is subjected to the most severe bending deformation. Further, it is desirable to reduce the extreme density of the inner region of the steel sheet in a predetermined direction so that minute cracks generated in the surface region of the steel sheet do not propagate to the inside. The manufacturing conditions for satisfying these conditions are shown below.
[0083]
The manufacturing process prior to hot rolling is not particularly limited. That is, after melting in a blast furnace, an electric furnace, or the like, various secondary smelting may be performed, and then casting may be performed by a method such as ordinary continuous casting, casting by the ingot method, or thin slab casting. In the case of continuous casting, the cast slab may be cooled to a low temperature and then heated again and then hot-rolled, or the cast slab may be hot-rolled as it is after casting without being cooled to a low temperature. .. Scrap may be used as the raw material.
[0084]
The cast slab is heated. In this heating step, the slab is heated to a temperature of 1200 ° C. or higher and 1300 ° C. or lower, and then held for 30 minutes or longer. If the heating temperature is less than 1200 ° C., Ti and Nb-based precipitates are not sufficiently melted, so that sufficient precipitation strengthening cannot be obtained during hot rolling in the subsequent process, and the precipitates remain in the steel as coarse carbides, so that formability is formed. Deteriorate. Therefore, the heating temperature of the slab is set to 1200 ° C. or higher. On the other hand, if the heating temperature exceeds 1300 ° C., the amount of scale generated increases and the yield decreases, so the heating temperature is set to 1300 ° C. or lower. In order to sufficiently dissolve the Ti and Nb-based precipitates, it is preferable to keep the Ti and Nb-based precipitates in this temperature range for 30 minutes or more. Further, in order to suppress excessive scale loss, the holding time is preferably 10 hours or less, and more preferably 5 hours or less.
[0085]
The heated slab is roughly rolled. In this rough rolling step, the thickness of the rough rolled plate after rough rolling is controlled to be more than 35 mm and 45 mm or less. The thickness of the rough-rolled plate affects the amount of temperature decrease from the tip to the tail of the rolled plate that occurs from the start of rolling to the completion of rolling in the finish rolling process. Further, when the thickness of the rough-rolled plate is 35 mm or less or more than 45 mm, the amount of strain introduced into the steel sheet during the finish rolling, which is the next process, changes, and the processed structure formed during the finish rolling changes. do. As a result, the recrystallization behavior changes, making it difficult to obtain a desired texture. In particular, it becomes difficult to obtain the above-mentioned texture in the surface region of the steel sheet.
[0086]
The rough-rolled plate is subjected to finish rolling. In this finish rolling process, multi-step finish rolling is performed. The start temperature of finish rolling is 1000 ° C. or higher and 1150 ° C. or lower, and the thickness of the steel plate (thickness of the rough-rolled plate) before the start of finish rolling is more than 35 mm and 45 mm or less. Further, in the rolling one step before the final step of the multi-step finish rolling, the rolling temperature is 960 ° C. or higher and 1020 ° C. or lower, and the rolling reduction ratio is more than 11% and 23% or lower. Further, in the final stage of the multi-stage finish rolling, the rolling temperature is 930 ° C. or higher and 995 ° C. or lower, and the rolling reduction ratio is more than 11% and 22% or less. Further, each condition at the time of reduction in the final two stages is controlled, and the texture formation parameter ω calculated by the following equation 1 satisfies 110 or less. Further, the total rolling reduction of the final three stages of the multi-stage finish rolling is 35% or more. Finish rolling is performed under the above conditions.
[0087]
[Number 1]
[0088]
[Number 2]
[0089]
[Number 3]
[0090]
[Number 4]
[0091]
[Number 5]
[0092]
[Number 6]
[0093]
[Number 7]
[0094]
[Number 8]
[0095]
Here,
PE: conversion value of the recrystallization suppressing effect by the precipitate-forming element (unit: mass%)
Ti: concentration of Ti contained in steel (unit: mass%)
Nb: concentration of Nb contained in steel (unit: mass%) Unit: Mass%)
F 1 * : Converted rolling reduction rate one step before the final stage (Unit:%)
F 2 * : Converted rolling reduction rate of the final stage (Unit:%)
F 1 : One step before the final stage Reduction rate (unit:%)
F 2 : Reduction rate of the final stage (unit:%)
Sr 1 : Rolling shape ratio one step before the final stage (no unit)
Sr 2 : Rolling shape ratio in the final stage (no unit)
D 1 : Roll diameter one step before the final stage (unit: mm)
D 2 : Roll diameter of the final stage (unit: mm)
t 1: Plate thickness at the start of rolling one step before the final stage (unit: mm)
t 2 : Plate thickness at the start of rolling at the final stage (unit: mm)
t f : Plate thickness after finish rolling (unit: mm)
FT 1 * : Converted rolling temperature one step before the final stage (unit: ° C)
FT 2 * : Converted rolling temperature of the final stage (unit: ° C)
FT 1 : Rolling temperature one step before the final stage (unit: ° C) )
FT 2 : Rolling temperature of the final stage (unit: ° C)
[0096]
However, in Equations 1 to 8, the numbers 1 and 2 added to the variables such as F 1 and F 2 are the rolling one step before the final step in the final two-step rolling in the multi-step finish rolling. 1 is added to the variable related to rolling, and 2 is added to the variable related to rolling in the final stage. For example, in multi-step finish rolling consisting of all seven steps of rolling, F 1 means the rolling reduction of the sixth step counting from the rolling inlet side, and F 2 means the rolling reduction of the seventh step.
[0097]
Conversion value of recrystallization suppression effect by precipitate-forming element Regarding PE, the effect of pinning and solution drag becomes apparent when the value of Ti + 1.3Nb is 0.02 or more. Therefore, in Equation 2, Ti + 1.3Nb <0 When 0.02 is satisfied, PE = 0.01, and when Ti + 1.3Nb ≧ 0.02 is satisfied, PE = Ti + 1.3Nb-0.01.
[0098]
Regarding the converted reduction rate F 1 * one step before the final stage , the effect of the reduction rate F 1 one step before the final stage on the texture becomes apparent when the value of F 1 is 12 or more. at, F 1 if they meet the <12, F 1 * and = 1.0, F 1 when satisfying ≧ 12, F 1 * = F 1 to -11.
[0099]
Conversion rolling reduction rate F in the final stage 2 * About the reduction ratio F in the final stage 2 Effects of on texture, F 2 because the value of becomes apparent in 11.1 above, in Equation 4, F 2 to {111} <112> and {110} in the surface region. The extreme density of the crystal orientation of <001> develops, and the texture of the surface region cannot be controlled within the above range. Therefore, in the finish rolling process, the texture formation parameter ω is controlled to 110 or less.
[0105]
Further, when the texture formation parameter ω is set to 98 or less, the amount of shear strain introduced into the surface region of the steel sheet decreases, and recrystallization occurs in the internal region in the range of 1/8 to 3/8 of the plate thickness. Since the behavior is promoted, the sum of the extreme densities of the crystal orientations of {332} <113> and the crystal orientations of {110} <001> is 7. It becomes 0 or less, and internal bending cracking is less likely to occur. Therefore, it is preferable that the texture formation parameter ω is 98 or less in the finish rolling step.
[0106]
(Rolling temperature FT 1 one step before the final step is 960 ° C or higher and 1020 ° C or lower) When
the rolling temperature FT 1 one step before the final step is less than 960 ° C, recrystallization of the structure processed by rolling is sufficient. The texture of the surface region cannot be controlled within the above range. Therefore, the rolling temperature FT 1 is set to 960 ° C. or higher. On the other hand, when the rolling temperature FT 1 exceeds 1020 ° C., the formed state of the processed structure and the recrystallization behavior change due to the coarsening of the austenite grains and the like, so that the texture of the surface region cannot be controlled within the above range. .. Therefore, the rolling temperature FT 1 is set to 1020 ° C. or lower.
[0107]
(The reduction rate F 1 one step before the final stage is more than 11% and 23% or less) If
the reduction ratio F 1 one step before the final stage is 11% or less, the amount of strain introduced into the steel sheet by rolling is not sufficient. It becomes sufficient and recrystallization does not occur sufficiently, and the texture of the surface region cannot be controlled within the above range. Therefore, the reduction rate F 1 is set to more than 11%. On the other hand, when the reduction factor F 1 is more than 23%, the lattice defects in the crystal become excessive and the recrystallization behavior changes, so that the texture of the surface region cannot be controlled within the above range. Therefore, the reduction rate F 1 is set to 23% or less.
The reduction rate F 1 is calculated as follows.
F 1 = (t 1- t 2 ) / t 1 x 100
[0108]
(The rolling temperature FT 2 of the final stage is 930 ° C. or higher and 995 ° C. or lower) When
the rolling temperature FT 2 of the final stage is set to less than 930 ° C., the recrystallization rate of austenite is significantly reduced, and {211} <111 in the surface region. The sum of the average polar density of the orientation group consisting of> to {111} <112> and the extreme density of the crystal orientation of {110} <001> cannot be 6.0 or less. Therefore, the rolling temperature FT 2 is set to 930 ° C. or higher. On the other hand, when the rolling temperature FT 2 exceeds 995 ° C., the formed state of the processed structure and the recrystallization behavior change, so that the texture of the surface region cannot be controlled within the above range. Therefore, the rolling temperature FT 2 is set to 995 ° C. or lower.
[0109]
(The reduction ratio F 2 of the final stage is more than 11% and 22% or less) When
the reduction ratio F 2 of the final stage is 11% or less, the amount of strain introduced into the steel sheet by rolling is insufficient and recrystallization is sufficient. The texture of the surface region cannot be controlled within the above range. Therefore, the reduction rate F 2 is set to exceed 11%. On the other hand, when the reduction factor F 2 is more than 22%, the lattice defects in the crystal become excessive and the recrystallization behavior changes, so that the texture of the surface region cannot be controlled within the above range. Therefore, the reduction rate F 2 is set to 22% or less.
The reduction rate F 2 is calculated as follows.
F 2 = (t 2- t f ) / t 2 × 100
[0110]
(The total reduction rate Ft of the final three stages is 35% or more.)
The total reduction rate Ft of the final three stages should be large in order to promote the recrystallization of austenite. When the total reduction rate Ft of the final three stages is less than 35%, the recrystallization rate of austenite is significantly reduced, and the average of the orientation groups consisting of {211} <111> to {111} <112> in the surface region. The sum of the extreme density and the extreme density of the crystal orientation of {110} <001> cannot be 6.0 or less. On the other hand, the upper limit of the total reduction rate Ft is not particularly limited, but is preferably 43% or less in order to preferably control the recrystallization behavior.
The total reduction rate Ft in the final three stages is calculated as follows. NS.
Ft = (t 0 −t f ) / t 0 × 100
Here, t 0 is the plate thickness (unit: mm) at the start of rolling two steps before the final step.
[0111]
In the finish rolling process, each of the above conditions is controlled simultaneously and inseparably. Each of the above-mentioned conditions does not have to satisfy only one of the above-mentioned conditions, and when all of the above-mentioned conditions are satisfied at the same time, the texture of the surface region can be controlled within the above-mentioned range.
[0112]
The hot-rolled steel sheet after finish rolling is cooled and wound up. In the hot-rolled steel sheet according to the present embodiment, excellent bending workability is achieved by controlling the texture rather than the base structure (constituent phase of the steel structure). Therefore, the manufacturing conditions are not particularly limited in the cooling step and the winding step. Therefore, the cooling step and the winding step after the multi-step finish rolling may be performed by a conventional method.
[0113]
The constituent phase of the steel sheet during finish rolling is mainly austenite, and the texture of austenite is controlled by the finish rolling described above. This high temperature stable phase such as austenite undergoes a phase transformation to a low temperature stable phase such as bainite during cooling and winding after finish rolling. This phase transformation may change the crystal orientation and change the texture of the steel sheet after cooling. However, with respect to the hot-rolled steel sheet according to the present embodiment, the above-mentioned crystal orientation controlled in the surface region is not significantly affected by cooling and winding after finish rolling. That is, if the texture is controlled as austenite during finish rolling, even if the phase is transformed into a low temperature stable phase such as bainite during subsequent cooling and winding, this low temperature stable phase will have the above-mentioned texture in the surface region. Meet the provisions of. The same applies to the texture of the central region of plate thickness.
[0114]
Further, the hot-rolled steel sheet according to the present embodiment may be pickled if necessary after cooling. Even if this pickling treatment is performed, the texture of the surface region does not change. The pickling treatment may be carried out, for example, in hydrochloric acid having a concentration of 3 to 10% at a temperature of 85 ° C. to 98 ° C. for 20 seconds to 100 seconds.
[0115]
Further, the hot-rolled steel sheet according to the present embodiment may be subjected to skin pass rolling if necessary after cooling. In this skin pass rolling, the rolling reduction may be set so that the texture of the surface region does not change. Skin pass rolling has the effects of preventing stretcher strains that occur during processing and shaping, and of shape correction.
Example 1
[0116]
Next, the effect of one aspect of the present invention will be described in more detail by way of examples. Yes, the present invention is not limited to this one-condition example. The present invention may adopt various conditions as long as the gist of the present invention is not deviated and the object of the present invention is achieved.
[0117]
Steel having a predetermined chemical composition is cast, and after casting, it is cooled as it is or once to room temperature, then reheated, heated to a temperature range of 1200 ° C to 1300 ° C, and then at a temperature of 1100 ° C or higher, the desired coarseness is obtained. A rough-rolled plate was produced by rough-rolling the slab to the thickness of the rolled plate. The rough-rolled plate was subjected to multi-step finish rolling consisting of 7 steps in all steps. The steel sheet after finish rolling was cooled and wound to prepare a hot-rolled steel sheet. The steel sheet after finish rolling was cooled and wound to prepare a hot-rolled steel sheet.
[0118]
Tables 1 and 2 show the chemical composition of the hot-rolled steel sheet. Regarding the chemical composition, the values marked with "<" in the table indicate that the values were below the detection limit of the measuring device, and that these elements were not intentionally added to the steel.
[0119]
Further, in the finish rolling step, the finish rolling is started from the temperatures shown in Tables 3 to 6, and the final three steps of rolling are excluded from the start of rolling. Rolled to a plate thickness of t 0 at the start of rolling two steps before the step . Then, the final three-stage rolling was performed at the total rolling reduction Ft shown in Tables 7 to 10. In addition, the final two-stage rolling was performed under the conditions shown in Tables 3 to 10. After the finish rolling was completed, each cooling pattern shown below was used for cooling and winding to obtain a hot-rolled steel sheet having a plate thickness t f shown in Tables 3 to 6 . The final plate thickness of the steel sheet after the completion of hot rolling was defined as the plate thickness t f after finish rolling .
[0120]
(Cooling pattern B: Bainite pattern) In
this pattern, after the finish rolling was completed, the film was cooled to a winding temperature of 450 ° C. to 550 ° C. at an average cooling rate of 20 ° C./sec or more, and then wound into a coil.
[0121]
(Cooling pattern F + B: Ferrite-bainite pattern) In
this pattern, after finishing rolling is completed, the product is cooled to a cooling stop temperature range of 600 to 750 ° C at an average cooling rate of 20 ° C./sec or more, and within the cooling stop temperature range. After the cooling was stopped and held for 2 to 4 seconds, the mixture was further wound into a coil at an average cooling rate of 20 ° C./sec or more and a winding temperature of 550 ° C. or less. The cooling shutdown temperature and holding time were set with reference to the following Ar3 temperature.
Ar3 (° C.) = 870-390C + 24Si-70Mn-50Ni-5Cr-20Cu + 80Mo
[0122]
(Cooling pattern Ms: Martensite pattern) In
this pattern, after the finish rolling was completed, the film was cooled to a winding temperature of 100 ° C. or lower at an average cooling rate of 20 ° C./sec or more, and then wound into a coil.
[0123]
In addition, the sample material No. 1 to No. In 128, rough rolling with a total reduction rate of 40% or more is performed in the range of 1200 ° C. to 1100 ° C., and finish rolling is performed so that the total reduction rate of the five stages other than the final two stages of multi-stage finish rolling is 50% or more. went. However, the total rolling reduction is calculated based on the plate thickness at the start of rough rolling and finish rolling and the plate thickness at the completion of rough rolling and the completion of the fifth finishing stage, and is expressed as a percentage. It is a numerical value.
[0124]
Tables 1 and 2 show the chemical components, Tables 3 to 10 show the manufacturing conditions, and Tables 11 to 14 show the manufacturing results of the produced hot-rolled steel sheet. In the "cooling / winding pattern" in Tables 7 to 10, "B" indicates a bainite pattern, "F + B" indicates a ferrite-bainite pattern, and "Ms" indicates a martensite pattern. Further, in the "aggregate structure" in Tables 11 to 14, the "sum of extreme densities A" is the average polar density of the orientation group consisting of {211} <111> to {111} <112> and {110} <001. > Shows the sum with the extreme density of the crystal orientation, and "sum of extreme densities B" is the sum of the extreme density of the crystal orientation of {332} <113> and the extreme density of the crystal orientation of {110} <001>. show. In addition, each symbol used in the table corresponds to the symbol described above.
[0125]
The tensile strength of the JIS Z 2241 (2011) was determined by using a JIS No. 5 test piece collected from a position 1/4 of the width direction of the hot-rolled steel sheet so that the direction perpendicular to the rolling direction (C direction) is the longitudinal direction. A tensile test was carried out in accordance with the regulations, and the maximum tensile strength TS and butt elongation (total elongation) EL were determined.
[0126]
The bending test is performed in accordance with JIS Z 2248 (2014) (V block 90 ° bending test) using a test piece cut out from the width direction 1/2 position of the hot-rolled steel plate into a strip shape of 100 mm × 30 mm. Bending test of both bending where the bending ridge is parallel to the rolling direction (L direction) (L-axis bending) and bending where the bending ridge is parallel to the direction perpendicular to the rolling direction (C direction) (C-axis bending) Was carried out, and the minimum bending radius at which cracks did not occur was determined. However, the presence or absence of cracks is determined by mirror polishing the cross section of the test piece after the V block 90 ° bending test on a surface parallel to the bending direction and perpendicular to the plate surface, and then using an optical microscope to detect cracks inside the bending of the test piece. After observing, it was judged that there was a crack when the observed crack length exceeded 30 μm. The value obtained by dividing the average value of the minimum inward bending radius of the L-axis bending and the minimum inward bending radius of the C-axis bending by the plate thickness was defined as the limit bending R / t as an index value of bendability.
[0127]
The underlined values in Tables 1 to 14 indicate that they are outside the scope of the present invention.
[0128]
In Tables 1 to 14, the sample material No. described as "Example of the present invention". Is a steel sheet that satisfies all the conditions of the present invention.
[0129]
In the example of the present invention, the average polar density of the orientation group consisting of {211} <111> to {111} <112> and the extreme density of the crystal orientation of {110} <001> in the surface region, satisfying the steel composition. The sum of the above is 0.5 or more and 6.0 or less, and the tensile strength is 780 MPa or more. Therefore, a hot-rolled steel sheet having a limit bending R / t of 2.2 or less and excellent bending workability in which the occurrence of internal bending cracks is suppressed has been obtained.
[0130]
On the other hand, in Tables 1 to 14, the sample material No. described as "comparative example". Is a steel sheet that does not satisfy at least one of the steel composition, the texture of the surface region, or the tensile strength.
[0131]
Sample No. In No. 5, the tensile strength was not sufficient because the Mn content was out of the control range.
Sample No. In No. 8, since the Mn content was out of the control range, the suppression of internal bending cracking was not sufficient.
Sample No. No. 9 had insufficient tensile strength because the C content was out of the control range.
Sample No. In No. 15, since the Ti content and the texture formation parameter ω were out of the control range, the texture was not satisfied and the suppression of internal bending cracking was not sufficient.
Sample No. In No. 19, since the Nb content and the texture formation parameter ω were out of the control range, the texture was not satisfied and the suppression of internal bending cracking was not sufficient.
Sample No. In No. 30, since the finish rolling conditions FT 1 and FT 2 were out of the control range, the texture was not satisfied and the suppression of internal bending cracks was not sufficient.
Sample No. In No. 32, since the finish rolling conditions FT 1 and FT 2 were out of the control range, the texture was not satisfied and the suppression of internal bending cracks was not sufficient.
Sample No. In No. 34, since the texture formation parameter ω was out of the control range, the texture was not satisfied, and the suppression of internal bending cracking was not sufficient.
Sample No. In No. 48, since the Ti content and the texture formation parameter ω were out of the control range, the texture was not satisfied and the suppression of internal bending cracking was not sufficient.
Sample No. In No. 51, since the Nb content and the texture formation parameter ω were out of the control range, the texture was not satisfied and the suppression of internal bending cracking was not sufficient.
Sample No. In 55, the finish rolling condition FT 1 and the texture formation parameter ω were out of the control range, so that the texture was not satisfied and the suppression of internal bending cracks was not sufficient.
Sample No. In No. 58, since the finish rolling condition FT 1 and the texture formation parameter ω were out of the control range, the texture was not satisfied and the suppression of internal bending cracks was not sufficient.
Sample No. 63, the finish rolling conditions F 1 and for texture formation parameter ω is outside the control range, not satisfy the texture, bending the crack inhibition it was not sufficient.
Sample No. In No. 66, since the texture formation parameter ω was out of the control range, the texture was not satisfied, and the suppression of internal bending cracking was not sufficient.
Sample No. In No. 71, since the texture formation parameter ω was out of the control range, the texture was not satisfied, and the suppression of internal bending cracking was not sufficient.
Sample No. 74, the finish rolling conditions F 1 and for texture formation parameter ω is outside the control range, not satisfy the texture, bending the crack inhibition it was not sufficient.
Sample No. In 79, since the texture formation parameter ω was out of the control range, the texture was not satisfied, and the suppression of internal bending cracking was not sufficient.
Sample No. In No. 82, since the texture formation parameter ω was out of the control range, the texture was not satisfied, and the suppression of internal bending cracking was not sufficient.
Sample No. In 87, since the texture formation parameter ω was out of the control range, the texture was not satisfied, and the suppression of internal bending cracking was not sufficient.
Sample No. 95, the finish rolling conditions F 1 and for texture formation parameter ω is outside the control range, not satisfy the texture, bending the crack inhibition it was not sufficient.
Sample No. In 98, since the finish rolling condition F 2 and the texture formation parameter ω were out of the control range, the texture was not satisfied and the suppression of internal bending cracks was not sufficient.
Sample No. 103, the starting temperature and the finish rolling condition F of the finish rolling 1 because it was out of the control range, not satisfy the texture, bending the crack inhibition was not sufficient.
Sample No. In 111, since the finish rolling condition Ft was out of the control range, the texture was not satisfied, and the suppression of internal bending cracks was not sufficient.
Sample No. In 113, since the thickness of the rough-rolled plate was out of the control range, the texture was not satisfied, and the suppression of internal bending cracks was not sufficient.
Sample No. In 116, since the thickness of the rough-rolled plate was out of the control range, the texture was not satisfied, and the suppression of internal bending cracks was not sufficient.
Sample No. 117 is the finish rolling condition FT 1Was out of the control range, so it did not satisfy the texture and the suppression of internal bending cracking was not sufficient.
Sample No. In 118, since the finish rolling condition FT 2 was out of the control range, the texture was not satisfied, and the suppression of internal bending cracks was not sufficient.
Sample No. In 119, since the finish rolling condition FT 2 was out of the control range, the texture was not satisfied and the suppression of internal bending cracks was not sufficient.
Sample No. In No. 120, since the finish rolling condition F1 was out of the control range, the texture was not satisfied, and the suppression of internal bending cracks was not sufficient.
Sample No. In 121, the finish rolling condition F 2 and the texture formation parameter ω were out of the control range, so that the texture was not satisfied and cracking in bending was not sufficiently suppressed.
Sample No. In 122, since the finish rolling condition F 2 was out of the control range, the texture was not satisfied, and the suppression of internal bending cracks was not sufficient.
Sample No. Since the start temperature of finish rolling of 123 was out of the control range, it did not satisfy the texture and did not sufficiently suppress internal bending cracks.
Sample No. 124, Si content, the thickness of the roughly rolled plate, the starting temperature of the finish rolling, and finish rolling conditions F 1 because it was out of the control range, not satisfy the texture, bending the crack inhibition was not sufficient.
Sample No. In 125, since the finish rolling conditions F 1 and F 2 were out of the control range, the texture was not satisfied and the suppression of internal bending cracking was not sufficient.
Sample No. In 126, since the finish rolling conditions FT 1 and FT 2 were out of the control range, the texture was not satisfied and the suppression of internal bending cracking was not sufficient.
Sample No. In 127, the thickness of the rough-rolled plate, the start temperature of finish rolling, the finish rolling conditions F 1 and F 2 were out of the control range, so that the texture was not satisfied and the suppression of internal bending cracks was not sufficient.
[0132]
In the example in which the rolling temperature FT 2 in the final stage was less than 930 ° C., the value of the texture formation parameter ω does not make sense, so ω and the like are left blank in the table.
[0133]
[table 1]
[0134]
[Table 2]
[0135]
[Table 3]
[0136]
[Table 4]
[0137]
[Table 5]
[0138]
[Table 6]
[0139]
[Table 7]
[0140]
[Table 8]
[0141]
[Table 9]
[0142]
[Table 10]
[0143]
[Table 11]
[0144]
[Table 12]
[0145]
[Table 13]
[0146]
[Table 14]
Industrial applicability
[0147]
According to the above aspect of the present invention, it is possible to obtain a hot-rolled steel sheet having a tensile strength (maximum tensile strength) of 780 MPa or more and excellent bending workability capable of suppressing the occurrence of internal bending cracks. Therefore, it has high industrial applicability.
The scope of the claims
[Claim 1]
As chemical components, in mass%,
C: 0.030% or more and 0.400% or less,
Si: 0.050% or more and 2.5% or less,
Mn: 1.00% or more and 4.00% or less,
sol. Al: 0.001% or more and 2.0% or less,
Ti: 0% or more and 0.20% or less,
Nb: 0% or more and 0.20% or less,
B: 0% or more and 0.010% or less,
V: 0% More than 1.0% or less,
Cr: 0% or more and 1.0% or less,
Mo: 0% or more and 1.0% or less,
Cu: 0% or more and 1.0% or less,
Co: 0% or more and 1.0% or less ,
W: 0% or more and 1.0% or less,
Ni: 0% or more and 1.0% or less,
Ca: 0% or more and 0.01% or less,
Mg: 0% or more and 0.01% or less,
REM: 0% or more Includes
0.01% or less, Zr: 0% or more and 0.01% or less
,
P: 0.020% or less,
S: 0.020% or less,
N: 0.010% or less,
The average pole of the orientation group consisting of {211} <111> to {111} <112> in the surface region in which the balance is composed of iron and impurities and is in the range from the steel plate surface to the plate thickness 1/10. A hot-rolled steel sheet characterized in that the sum of the density and the extreme density of the crystal orientation of {110} <001> is 0.5 or more and 6.0 or less, and the
tensile strength is 780 MPa or more and 1370 MPa or less
.
[Claim 2]
The extreme density of the crystal orientation of {332} <113> and the crystal orientation of {110} <001> in the internal region in the range of 1/8 to 3/8 of the plate thickness with respect to the surface of the steel plate. The
hot-rolled steel sheet according to claim 1, wherein the sum with the extreme density of is 1.0 or more and 7.0 or less .
[Claim 3]
As the chemical components,
Ti: 0.001% or more and 0.20% or less,
Nb: 0.001% or more and 0.20% or less,
B: 0.001% or more and 0.010% or less,
V: 0.005% or more and 1.0% or less,
Cr: 0.005% or more and 1.0% or less,
Mo: 0.005% or more and 1.0% or less,
Cu: 0.005% or more and 1.0% or less,
Co: 0.005% or more and 1.0% or less,
W: 0.005% or more and 1.0% or less,
Ni: 0.005% or more and 1.0% or less,
Ca: 0.0003% or more and 0.01% Hereinafter, it contains at least one of
Mg: 0.0003% or more and 0.01% or less,
REM: 0.0003% or more and 0.01% or less, and
Zr: 0.0003% or more and 0.01% or less. The hot-rolled steel plate according to claim 1 or 2, wherein the hot-rolled steel plate is characterized by the above.
| # | Name | Date |
|---|---|---|
| 1 | 202117021640-IntimationOfGrant10-02-2024.pdf | 2024-02-10 |
| 1 | 202117021640-TRANSLATIOIN OF PRIOIRTY DOCUMENTS ETC. [13-05-2021(online)].pdf | 2021-05-13 |
| 2 | 202117021640-STATEMENT OF UNDERTAKING (FORM 3) [13-05-2021(online)].pdf | 2021-05-13 |
| 2 | 202117021640-PatentCertificate10-02-2024.pdf | 2024-02-10 |
| 3 | 202117021640-PROOF OF RIGHT [13-05-2021(online)].pdf | 2021-05-13 |
| 3 | 202117021640-ABSTRACT [10-03-2023(online)].pdf | 2023-03-10 |
| 4 | 202117021640-PRIORITY DOCUMENTS [13-05-2021(online)].pdf | 2021-05-13 |
| 4 | 202117021640-CLAIMS [10-03-2023(online)].pdf | 2023-03-10 |
| 5 | 202117021640-POWER OF AUTHORITY [13-05-2021(online)].pdf | 2021-05-13 |
| 5 | 202117021640-COMPLETE SPECIFICATION [10-03-2023(online)].pdf | 2023-03-10 |
| 6 | 202117021640-FORM 1 [13-05-2021(online)].pdf | 2021-05-13 |
| 6 | 202117021640-DRAWING [10-03-2023(online)].pdf | 2023-03-10 |
| 7 | 202117021640-FER_SER_REPLY [10-03-2023(online)].pdf | 2023-03-10 |
| 7 | 202117021640-DRAWINGS [13-05-2021(online)].pdf | 2021-05-13 |
| 8 | 202117021640-OTHERS [10-03-2023(online)].pdf | 2023-03-10 |
| 8 | 202117021640-DECLARATION OF INVENTORSHIP (FORM 5) [13-05-2021(online)].pdf | 2021-05-13 |
| 9 | 202117021640-FER.pdf | 2022-11-17 |
| 9 | 202117021640-COMPLETE SPECIFICATION [13-05-2021(online)].pdf | 2021-05-13 |
| 10 | 202117021640-FORM 18 [04-11-2022(online)].pdf | 2022-11-04 |
| 10 | 202117021640-Verified English translation [21-09-2021(online)].pdf | 2021-09-21 |
| 11 | 202117021640-FORM 3 [04-10-2021(online)].pdf | 2021-10-04 |
| 11 | 202117021640.pdf | 2021-10-19 |
| 12 | 202117021640-FORM 3 [04-10-2021(online)].pdf | 2021-10-04 |
| 12 | 202117021640.pdf | 2021-10-19 |
| 13 | 202117021640-FORM 18 [04-11-2022(online)].pdf | 2022-11-04 |
| 13 | 202117021640-Verified English translation [21-09-2021(online)].pdf | 2021-09-21 |
| 14 | 202117021640-COMPLETE SPECIFICATION [13-05-2021(online)].pdf | 2021-05-13 |
| 14 | 202117021640-FER.pdf | 2022-11-17 |
| 15 | 202117021640-DECLARATION OF INVENTORSHIP (FORM 5) [13-05-2021(online)].pdf | 2021-05-13 |
| 15 | 202117021640-OTHERS [10-03-2023(online)].pdf | 2023-03-10 |
| 16 | 202117021640-DRAWINGS [13-05-2021(online)].pdf | 2021-05-13 |
| 16 | 202117021640-FER_SER_REPLY [10-03-2023(online)].pdf | 2023-03-10 |
| 17 | 202117021640-DRAWING [10-03-2023(online)].pdf | 2023-03-10 |
| 17 | 202117021640-FORM 1 [13-05-2021(online)].pdf | 2021-05-13 |
| 18 | 202117021640-COMPLETE SPECIFICATION [10-03-2023(online)].pdf | 2023-03-10 |
| 18 | 202117021640-POWER OF AUTHORITY [13-05-2021(online)].pdf | 2021-05-13 |
| 19 | 202117021640-PRIORITY DOCUMENTS [13-05-2021(online)].pdf | 2021-05-13 |
| 19 | 202117021640-CLAIMS [10-03-2023(online)].pdf | 2023-03-10 |
| 20 | 202117021640-PROOF OF RIGHT [13-05-2021(online)].pdf | 2021-05-13 |
| 20 | 202117021640-ABSTRACT [10-03-2023(online)].pdf | 2023-03-10 |
| 21 | 202117021640-STATEMENT OF UNDERTAKING (FORM 3) [13-05-2021(online)].pdf | 2021-05-13 |
| 21 | 202117021640-PatentCertificate10-02-2024.pdf | 2024-02-10 |
| 22 | 202117021640-TRANSLATIOIN OF PRIOIRTY DOCUMENTS ETC. [13-05-2021(online)].pdf | 2021-05-13 |
| 22 | 202117021640-IntimationOfGrant10-02-2024.pdf | 2024-02-10 |
| 1 | SteelSheetE_10-11-2022.pdf |