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Hot Rolled Steel Sheet

Abstract: A hot-rolled steel sheet contains C, Si, Mn and sol.Al as chemical components, and has such properties that the mean pole density in a direction group consisting of {110}<110> to {110}<001> in a surface area is 0.5 to 3.0 inclusive, the standard deviation of the pole densities in this direction group is 0.2 to 2.0 inclusive and the tensile strength is 780 to 1370 MPa inclusive.

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Patent Information

Application #
Filing Date
12 May 2021
Publication Number
44/2021
Publication Type
INA
Invention Field
METALLURGY
Status
Email
mahua.ray@remfry.com
Parent Application
Patent Number
Legal Status
Grant Date
2024-06-20
Renewal Date

Applicants

NIPPON STEEL CORPORATION
6-1, Marunouchi 2-chome, Chiyoda-ku, Tokyo 1008071

Inventors

1. YABU Shohei
c/o NIPPON STEEL CORPORATION, 6-1, Marunouchi 2-chome, Chiyoda-ku, Tokyo 1008071
2. HAYASHI Kunio
c/o NIPPON STEEL CORPORATION, 6-1, Marunouchi 2-chome, Chiyoda-ku, Tokyo 1008071
3. YAMAGUCHI Yuji
c/o NIPPON STEEL CORPORATION, 6-1, Marunouchi 2-chome, Chiyoda-ku, Tokyo 1008071
4. MORI Marina
c/o NIPPON STEEL CORPORATION, 6-1, Marunouchi 2-chome, Chiyoda-ku, Tokyo 1008071
5. INOUE Naoki
c/o NIPPON STEEL CORPORATION, 6-1, Marunouchi 2-chome, Chiyoda-ku, Tokyo 1008071
6. ABUKAWA Genki
c/o NIPPON STEEL CORPORATION, 6-1, Marunouchi 2-chome, Chiyoda-ku, Tokyo 1008071

Specification

The present invention relates to a high-strength hot-rolled steel sheet having excellent bending workability and low anisotropy of bending workability.
 The present application claims priority based on Japanese Patent Application No. 2018-222296 filed in Japan on November 28, 2018, the contents of which are incorporated herein by reference.
Background technology
[0002]
 There is a demand for both improving fuel efficiency of automobiles and ensuring collision safety, and increasing the strength of steel sheets for automobiles is being promoted, and high-strength steel sheets are often used for automobile bodies. ..
[0003]
 So-called hot-rolled steel sheets manufactured by hot rolling are widely used as relatively inexpensive structural materials and as materials for structural members of automobiles and industrial equipment. In particular, hot-rolled steel sheets used for automobile suspension parts, bumper parts, shock absorbing members, etc. are being strengthened from the viewpoints of weight reduction, durability, shock absorbing capacity, etc., and at the same time are complicated. There is also a need for excellent formability that can withstand molding into various shapes.
[0004]
 However, since the formability of the hot-rolled steel sheet tends to decrease as the strength of the material increases, it is a difficult problem to achieve both high strength and good formability.
[0005]
 In particular, in recent years, there has been an increasing demand for weight reduction of undercarriage parts of automobiles, and it has become an important issue to realize high tensile strength of 780 MPa or more and excellent bending workability.
[0006]
 For example, Non-Patent Document 1 reports that bending workability is improved by controlling a single structure such as ferrite, bainite, and martensite by controlling the structure.
[0007]
 Patent Document 1 describes in terms of mass%, C: 0.010 to 0.055%, Si: 0.2% or less, Mn: 0.7% or less, P: 0.025% or less, S: 0.02. % Or less, N: 0.01% or less, Al: 0.1% or less, Ti: 0.06 to 0.095%, and the area ratio is controlled to be 95% or more composed of ferrite. By controlling the structure in which only the carbide particle size containing Ti in the grain and TiS having an average diameter of 0.5 μm or less as Ti-containing sulfide are dispersed and precipitated, the tensile strength of 590 MPa or more and 750 MPa or less and excellent bending workability are controlled. The method of realizing the above is disclosed.
[0008]
 However, although the technique of Patent Document 1 can realize excellent bending workability, it is not possible to realize a high strength of 780 MPa or more because the structure needs to be controlled to a ferrite single-phase structure.
[0009]
 On the other hand, Patent Document 2 describes in terms of mass%, C: 0.05 to 0.15%, Si: 0.2 to 1.2%, Mn: 1.0 to 2.0%, P: 0.04. % Or less, S: 0.0030% or less, Al: 0.005 to 0.10%, N: 0.005% or less and Ti: 0.03 to 0.13%. The bainite single phase or bainite is controlled to a structure with a fraction of more than 95%, and the structure of the surface layer of the steel plate has a bainite phase fraction of less than 80% and a highly processable ferrite fraction of 10. % Or more, a method of improving the bending workability while maintaining the tensile strength of 780 MPa or more is disclosed.
[0010]
 Further, Patent Document 3 describes in terms of mass%, C: 0.08 to 0.25%, Si: 0.01 to 1.0%, Mn: 0.8 to 1.5%, P: 0.025. % Or less, S: 0.005% or less, Al: 0.005 to 0.10%, Nb: 0.001 to 0.05%, Ti: 0.001 to 0.05%, Mo: 0.1 to Contains 1.0%, Cr: 0.1-1.0%, the tempered martensite phase is the main phase with a volume ratio of 90% or more, and the average particle size of the old austenite grains in the cross section parallel to the rolling direction. Is 20 μm or less and the average particle size of the old austenite grains in the cross section orthogonal to the rolling direction is 15 μm or less. A high-strength hot-rolled steel sheet having excellent bending workability and low-temperature toughness is disclosed.
[0011]
 However, in recent years, elements such as Nb and Ti are often contained in order to increase the strength, and finish rolling is often performed at a low temperature. Therefore, the anisotropy of the bending workability of the hot-rolled steel sheet is large, and molding is performed. The problem of limiting the direction of the previous blank removal has become apparent.
[0012]
 In Patent Document 4, the extreme density of each direction of a specific crystal orientation group in the central portion of the plate thickness, which is in the plate thickness range of 5/8 to 3/8 from the surface of the steel plate, is controlled, and the direction is perpendicular to the rolling direction. The rankford value of rC is 0.70 or more and 1.10 or less, and the rankford value of r30 in the direction forming 30 ° with respect to the rolling direction is 0.70 or more and 1.10 or less. A hot-rolled steel sheet having excellent local deformability and small bending workability anisotropy is disclosed.
Prior art literature
Patent documents
[0013]
Patent Document 1: Japanese Patent Application Laid-Open No. 2013-133499
Patent Document 2: Japanese Patent Application Laid-Open No. 2012-62558
Patent Document 3: Japanese Patent Application Laid-Open No. 2012-77336
Patent Document 4: International Publication No. 2012/121219
Non-patent literature
[0014]
Non-Patent Document 1: Journal of the Japan Society for Technology of Plasticity, vol. 36 (1995), No. 416, p. 973
Outline of the invention
Problems to be solved by the invention
[0015]
 As described above, it is currently required to further improve the bending workability and its anisotropy after increasing the strength of the steel sheet. However, in the above-mentioned techniques of Patent Documents 1 to 4, the strength and the anisotropy are improved. It cannot be said that the bending workability and its anisotropy are sufficiently improved. An object to be solved by the present invention is to provide a high-strength hot-rolled steel sheet having excellent bending workability and low anisotropy of bending workability.
[0016]
 The above-mentioned bending workability is an index indicating that cracks are unlikely to occur from the outside of the bending even in a bending process having a small bending radius R, or an index indicating that the cracks are unlikely to grow.
Means to solve problems
[0017]
 The gist of the present invention is as follows.
 (1) The hot-rolled steel sheet according to one aspect of the present invention has C: 0.030% or more and 0.400% or less, Si: 0.050% or more and 2.5% or less, Mn in mass% as chemical components. : 1.00% or more and 4.00% or less, sol. Al: 0.001% or more and 2.0% or less, Ti: 0% or more and 0.20% or less, Nb: 0% or more and 0.20% or less, B: 0% or more and 0.010% or less, V: 0% More than 1.0% or less, Cr: 0% or more and 1.0% or less, Mo: 0% or more and 1.0% or less, Cu: 0% or more and 1.0% or less, Co: 0% or more and 1.0% or less , W: 0% or more and 1.0% or less, Ni: 0% or more and 1.0% or less, Ca: 0% or more and 0.01% or less, Mg: 0% or more and 0.01% or less, REM: 0% or more Includes 0.01% or less, Zr: 0% or more and 0.01% or less, P: 0.020% or less, S: 0.020% or less, N: 0.010% or less, and the balance is iron and 2. The average polar density of the orientation group consisting of {110} <110> to {110} <001> is 0.5 or more in the surface region consisting of impurities and ranging from the surface of the steel plate to the plate thickness of 1/10. It is 0 or less, the standard deviation of the extreme density of the orientation group is 0.2 or more and 2.0 or less, and the tensile strength is 780 MPa or more and 1370 MPa or less.
 (2) In the hot-rolled steel sheet according to (1) above, crystals of {334} <263> are formed in a central region having a plate thickness of 3/8 to 5/8 with respect to the surface of the steel plate. The polar density of the orientation may be 1.0 or more and 7.0 or less.
 (3) The hot-rolled steel sheet according to (1) or (2) above has Ti: 0.001% or more and 0.20% or less and Nb: 0.001% or more and 0. 20% or less, B: 0.001% or more and 0.010% or less, V: 0.005% or more and 1.0% or less, Cr: 0.005% or more and 1.0% or less, Mo: 0.005% or more 1.0% or less, Cu: 0.005% or more and 1.0% or less, Co: 0.005% or more and 1.0% or less, W: 0.005% or more and 1.0% or less, Ni: 0.005 % Or more and 1.0% or less, Ca: 0.0003% or more and 0.01% or less, Mg: 0.0003% or more and 0.01% or less, REM: 0.0003% or more and 0.01% or less, Zr: 0 It may contain at least one of 0003% or more and 0.01% or less.
The invention's effect
[0018]
 According to the above aspect of the present invention, it is possible to obtain a hot-rolled steel sheet having a tensile strength (maximum tensile strength) of 780 MPa or more, excellent bending workability, and small anisotropy of bending workability.
A brief description of the drawing
[0019]
[Fig. 1] Fig. 1 is a schematic view of a hot-rolled steel sheet, showing a sampling direction of a test piece for a bending test and a bending direction for a bending test.
FIG. 2 is a crystal orientation distribution function (ODF) having a cross section of φ2 = 45 ° and shows an orientation group consisting of {110} <110> to {110} <001>.
FIG. 3 is a crystal orientation distribution function (ODF) with a cross section of φ2 = 45 ° and shows the crystal orientation of {334} <263>.
Mode for carrying out the invention
[0020]
 Hereinafter, the hot-rolled steel sheet according to the embodiment of the present invention will be described in detail. However, the present invention is not limited to the configuration disclosed in the present embodiment, and various modifications can be made without departing from the spirit of the present invention. In addition, the lower limit value and the upper limit value are included in the numerical limitation range described below. Numerical values ​​that indicate "greater than" or "less than" are not included in the numerical range. "%" Regarding the content of each element means "mass%".
[0021]
 First, the background to the idea of ​​the hot-rolled steel sheet according to the present embodiment will be described.
[0022]
 The present inventors diligently investigated the factors for the development of anisotropy in bending workability, and the bending anisotropy was caused by the texture of the hot-rolled steel sheet, and as shown in FIG. 1, bending. Bending anisotropy between bending where the ridgeline is parallel to the rolling direction (L direction) (L-axis bending) and bending where the bending ridgeline is parallel to the direction perpendicular to the rolling direction (C direction) (C-axis bending) It was found that the sex was the largest.
[0023]
 Further, conventionally, it is generally recognized that the bending workability at the time of L-axis bending is inferior to the bending workability at the time of C-axis bending due to inclusions such as MnS stretched in the rolling direction. However, when the anisotropy of bending workability due to the texture of the steel sheet appears, contrary to the conventional recognition, the bending workability at the time of C-axis bending is changed to the bending work at the time of L-axis bending. It was found that it may be inferior to sex.
[0024]
 Furthermore, the anisotropy of bending workability is more strongly influenced by the texture of the steel sheet surface region where bending deformation is most severe than by the texture of the center region of the plate thickness. Without it, it became clear that the anisotropy between the L-axis bend and the C-axis bend was not sufficiently improved.
[0025]
 In the techniques described in Patent Documents 2 and 3 described above, excellent bending workability is obtained by structure control, but no texture control is performed, and bending process during L-axis bending is performed. Although the property is improved, there is a problem that it is difficult to stably secure excellent bending workability at the time of C-axis bending.
[0026]
 Further, in the technique shown in Patent Document 4, the texture in the central region of the plate thickness is controlled, but the texture in the surface region of the steel sheet is not controlled at all. Therefore, the length of the test piece is in the C direction. Excellent bending workability is obtained for C-direction bending (that is, L-axis bending) along and bending in the 45 ° direction, but there is a problem that excellent bending workability cannot be obtained for C-axis bending. there were.
[0027]
 As a result of diligent studies by the present inventors, it has been found that the texture of the steel sheet surface region where the bending deformation is the most severe affects the formation of cracks during the bending deformation. Furthermore, it was found that the texture of the central region of the plate thickness affects the propagation of cracks generated in the surface region.
[0028]
 Based on the above findings, the present inventors control the texture formed in the surface region of the steel sheet in the finish rolling of hot rolling and suppress the anisotropy between the L direction and the C direction. , It has been found that a high-strength hot-rolled steel sheet having excellent bending workability can be realized by both L-axis bending and C-axis bending. In addition, it has been found that bending workability and its anisotropy can be further preferably improved by controlling the texture of the steel sheet surface region and also controlling the texture of the plate thickness center region.
[0029]
 Specifically, the steel composition is controlled within an appropriate range, the plate thickness and temperature during hot rolling are controlled, and in addition, during finish rolling of hot rolling, which has not been positively controlled in the past, In the final two-stage rolling, the processed structure of the steel sheet surface region is controlled by controlling the plate thickness, roll shape ratio, rolling ratio, and temperature. As a result, it has been found that recrystallization is controlled and the texture of the surface region of the steel sheet is optimized, so that excellent bending workability is realized in both L-axis bending and C-axis bending.
[0030]
 Further, in addition to optimizing the texture of the steel sheet surface region as described above, the work structure of the plate thickness center region is controlled by preferably controlling the finish rolling conditions of hot rolling, and as a result, the plate thickness center region is aggregated. It has been found that if the structure is optimized, the bending workability of both L-axis bending and C-axis bending is more preferably improved.
[0031]
 The hot-rolled steel sheet according to the present embodiment has C: 0.030% or more and 0.400% or less, Si: 0.050% or more and 2.5% or less, Mn: 1.00% in mass% as chemical components. More than 4.00% or less, sol. Al: 0.001% or more and 2.0% or less, Ti: 0% or more and 0.20% or less, Nb: 0% or more and 0.20% or less, B: 0% or more and 0.010% or less, V: 0% More than 1.0% or less, Cr: 0% or more and 1.0% or less, Mo: 0% or more and 1.0% or less, Cu: 0% or more and 1.0% or less, Co: 0% or more and 1.0% or less , W: 0% or more and 1.0% or less, Ni: 0% or more and 1.0% or less, Ca: 0% or more and 0.01% or less, Mg: 0% or more and 0.01% or less, REM: 0% or more Includes 0.01% or less, Zr: 0% or more and 0.01% or less, P: 0.020% or less, S: 0.020% or less, N: 0.010% or less, and the balance is iron and Consists of impurities. Further, in the hot-rolled steel sheet according to the present embodiment, the average pole of the orientation group consisting of {110} <110> to {110} <001> in the surface region in the range from the steel plate surface to the plate thickness 1/10. The density is 0.5 or more and 3.0 or less, and the standard deviation of the extreme density of the azimuth group is 0.2 or more and 2.0 or less. Further, in the hot-rolled steel sheet according to the present embodiment, the tensile strength is 780 MPa or more and 1370 MPa or less.
[0032]
 Further, in the hot-rolled steel sheet according to the present embodiment, the extreme density of the crystal orientation of {334} <263> in the central region in the range of the plate thickness of 3/8 to the plate thickness of 5/8 with respect to the surface of the steel plate. Is preferably 1.0 or more and 7.0 or less.
[0033]
 Further, the hot-rolled steel sheet according to the present embodiment has Ti: 0.001% or more and 0.20% or less, Nb: 0.001% or more and 0.20% or less, B: 0. 001% or more and 0.010% or less, V: 0.005% or more and 1.0% or less, Cr: 0.005% or more and 1.0% or less, Mo: 0.005% or more and 1.0% or less, Cu: 0.005% or more and 1.0% or less, Co: 0.005% or more and 1.0% or less, W: 0.005% or more and 1.0% or less, Ni: 0.005% or more and 1.0% or less, Ca: 0.0003% or more and 0.01% or less, Mg: 0.0003% or more and 0.01% or less, REM: 0.0003% or more and 0.01% or less, Zr: 0.0003% or more and 0.01% It may contain at least one of the following.
[0034]
1. 1. Chemical composition
 First, the steel composition and the reasons for its limitation will be described. The hot-rolled steel sheet according to the present embodiment contains a basic element as a chemical component, and if necessary, a selective element, and the balance is composed of iron and impurities.
[0035]
 Among the chemical components of the hot-rolled steel sheet according to the present embodiment, C, Si, Mn, and Al are basic elements (main alloying elements).
[0036]
(C: 0.030% or more and 0.400% or less)
 C (carbon) is an important element for ensuring the strength of the steel sheet. If the C content is less than 0.030%, the tensile strength of 780 MPa or more cannot be secured. Therefore, the C content is 0.030% or more, preferably 0.05% or more. On the other hand, if the C content exceeds 0.400%, the weldability deteriorates, so the upper limit is set to 0.400%. The C content is preferably 0.30% or less, more preferably 0.20%.
[0037]
(Si: 0.050% or more and 2.5% or less)
 Si (silicon) is an important element that can increase the material strength by solid solution strengthening. If the Si content is less than 0.050%, the yield strength is lowered, so the Si content is set to 0.050% or more. The Si content is preferably 0.1% or more, more preferably 0.3% or more. On the other hand, if the Si content exceeds 2.5%, the surface texture deteriorates, so the Si content is set to 2.5% or less. The Si content is preferably 2.0% or less, more preferably 1.5% or less.
[0038]
(Mn: 1.00% or more and 4.00% or less)
 Mn (manganese) is an effective element for increasing the mechanical strength of a steel sheet. If the Mn content is less than 1.00%, it is not possible to secure a tensile strength of 780 MPa or more. Therefore, the Mn content is set to 1.00% or more. The Mn content is preferably 1.50% or more, more preferably 2.00% or more. On the other hand, when Mn is added excessively, the structure becomes non-uniform due to Mn segregation, and the bending workability is lowered. Therefore, the Mn content is set to 4.00% or less, preferably 3.00% or less, and more preferably 2.60% or less.
[0039]
(Sol.Al: 0.001% or more and 2.0% or less)
 sol. Al (acid-soluble aluminum) is an element that has the effect of deoxidizing steel and making the steel sheet sound. sol. If the Al content is less than 0.001%, it cannot be sufficiently deoxidized. The Al content is 0.001% or more. However, if sufficient deoxidation is required, sol. The Al content is more preferably 0.01% or more, and more preferably 0.02% or more. On the other hand, sol. When the Al content exceeds 2.0%, the weldability is remarkably lowered, oxide-based inclusions are increased, and the surface texture is remarkably deteriorated. Therefore, sol. The Al content is 2.0% or less, preferably 1.5% or less, more preferably 1.0% or less, and most preferably 0.08% or less. In addition, sol. Al means an acid-soluble Al that is not an oxide such as Al 2 O 3 and is soluble in an acid.
[0040]
 The hot-rolled steel sheet according to this embodiment contains impurities as a chemical component. The term "impurity" refers to substances mixed from ore or scrap as a raw material, or from the manufacturing environment, etc., when steel is industrially manufactured. For example, it means an element such as P, S, N. These impurities are preferably limited as follows in order to fully exert the effects of the present embodiment. Further, since the content of impurities is preferably small, it is not necessary to limit the lower limit value, and the lower limit value of impurities may be 0%.
[0041]
(P: 0.020% or less)
 P (phosphorus) is an impurity generally contained in steel. However, since it has an effect of increasing the tensile strength, P may be intentionally contained. However, when the P content exceeds 0.020%, the deterioration of weldability becomes remarkable. Therefore, the P content is limited to 0.020% or less. The P content is preferably limited to 0.010% or less. In order to obtain the effect of the above action more reliably, the P content may be 0.001% or more.
[0042]
(S: 0.020% or less)
 S (sulfur) is an impurity contained in steel, and the smaller the amount, the more preferable it is from the viewpoint of weldability. When the S content exceeds 0.020%, the weldability is significantly lowered, the MnS precipitation amount is increased, and the low temperature toughness is lowered. Therefore, the S content is limited to 0.020% or less. The S content is preferably limited to 0.010% or less, more preferably 0.005% or less. From the viewpoint of desulfurization cost, the S content may be 0.001% or more.
[0043]
(N: 0.010% or less)
 N (nitrogen) is an impurity contained in steel, and the smaller the amount, the more preferable it is from the viewpoint of weldability. If the N content exceeds 0.010%, the weldability is significantly reduced. Therefore, the N content is limited to 0.010% or less. The N content is preferably limited to 0.005% or less, more preferably 0.003% or less.
[0044]
 The hot-rolled steel sheet according to the present embodiment may contain a selective element in addition to the basic elements and impurities described above. For example, instead of a part of Fe which is the balance described above, at least one of Ti, Nb, B, V, Cr, Mo, Cu, Co, W, Ni, Ca, Mg, REM, and Zr is used as a selective element. It may contain one kind. These selective elements preferably improve the mechanical properties of the hot-rolled steel sheet. These selective elements may be contained according to the purpose. Therefore, it is not necessary to limit the lower limit values ​​of these selective elements, and the lower limit value may be 0%. Further, even if these selective elements are contained as impurities, the above effects are not impaired.
[0045]
(Ti: 0% or more and 0.20% or less)
 Ti (titanium) is an element as TiC that precipitates on ferrite or bainite of the steel sheet structure during cooling or winding of the steel sheet and contributes to the improvement of strength. .. Therefore, Ti may be contained. Excessive addition of Ti suppresses recrystallization during hot rolling and develops a texture with a specific crystal orientation. Therefore, at least one of L-axis bending and C-axis bending, Rm / t, which is the value obtained by dividing the minimum bending radius required for processing undercarriage parts having a complicated shape by the plate thickness, is 2.0 or less. It doesn't become. Therefore, the Ti content is set to 0.20% or less. The Ti content is preferably 0.18% or less, more preferably 0.15% or less. In order to obtain the above effect preferably, the Ti content may be 0.001% or more. The Ti content is preferably 0.02% or more.
[0046]
(Nb: 0% or more and 0.20% or less)
 Nb (niobium) is an element that precipitates as NbC, improves the strength, and remarkably suppresses the recrystallization of austenite, like Ti. Therefore, Nb may be contained. When Nb exceeds 0.20%, recrystallization of austenite is suppressed during hot rolling and texture develops, so that the minimum bending radius is set to the minimum bending radius at least one of L-axis bending and C-axis bending. Rm / t, which is the value divided by, does not become 2.0 or less. Therefore, the Nb content is set to 0.20% or less. The Nb content is preferably 0.15% or less, more preferably 0.10% or less. In order to obtain the above effect preferably, the Nb content may be 0.001% or more. The Nb content is preferably 0.005% or more.
[0047]
 In the hot-rolled steel sheet according to the present embodiment, at least of Ti: 0.001% or more and 0.20% or less and Nb: 0.001% or more and 0.20% or less in mass% as chemical components. It is preferable to contain one kind.
[0048]
(B: 0% or more and 0.010% or less)
 B (boron) segregates at the grain boundaries to improve the grain boundary strength, so that the roughness of the punched cross section at the time of punching can be suppressed. Therefore, B may be contained. Even if the B content exceeds 0.010%, the above effect is saturated and economically disadvantageous. Therefore, the upper limit of the B content is set to 0.010%. The B content is preferably 0.005% or less, more preferably 0.003% or less. In order to obtain the above effect preferably, the B content may be 0.001% or more.
[0049]
(V: 0% or more and 1.0% or less)
(Cr: 0% or more and 1.0% or less)
(Mo: 0% or more and 1.0% or less)
(Cu: 0% or more and 1.0% or less)
(Co : 0% or more and 1.0% or less)
(W: 0% or more and 1.0% or less)
(Ni: 0% or more and 1.0% or less)
 V (vanadium), Cr (chromium), Mo (molybdenum), Cu (Copper), Co (cobalt), W (tungsten), and Ni (nickel) are all effective elements for ensuring stable strength. Therefore, these elements may be contained. However, even if each of the elements is contained in an amount of more than 1.0%, the effect of the above action is likely to be saturated, which may be economically disadvantageous. Therefore, the content of each of these elements is set to 1.0% or less. The content of each of these elements is preferably 0.8% or less, more preferably 0.5% or less, respectively. In order to obtain the effect of the above action more reliably, each element may be 0.005% or more.
[0050]
 In the hot-rolled steel sheet according to the present embodiment, as chemical components, V: 0.005% or more and 1.0% or less, Cr: 0.005% or more and 1.0% or less, Mo: 0. 005% or more and 1.0% or less, Cu: 0.005% or more and 1.0% or less, Co: 0.005% or more and 1.0% or less, W: 0.005% or more and 1.0% or less, Ni: It is preferable to contain at least one of 0.005% or more and 1.0% or less.
[0051]
(Ca: 0% or more and 0.01% or less)
(Mg: 0% or more and 0.01% or less)
(REM: 0% or more and 0.01% or less)
(Zr: 0% or more and 0.01% or less)
 Ca ( Calcium), Mg (magnesium), REM (rare earth element), and Zr (zirconium) are all elements that contribute to inclusion control, particularly fine dispersion of inclusions, and enhance toughness. Therefore, these elements may be contained. However, if each of the elements is contained in an amount of more than 0.01%, deterioration of the surface texture may become apparent. Therefore, the content of each of these elements shall be 0.01% or less. The content of each of these elements is preferably 0.005% or less, more preferably 0.003% or less, respectively. In order to obtain the effect of the above action more reliably, each element may be 0.0003% or more.
[0052]
 Here, REM refers to a total of 17 elements of Sc, Y and lanthanoid, and is at least one of them. The content of REM means the total content of at least one of these elements. In the case of lanthanoids, they are industrially added in the form of misch metal.
[0053]
 In the hot-rolled steel sheet according to the present embodiment, Ca: 0.0003% or more and 0.01% or less, Mg: 0.0003% or more and 0.01% or less, REM: 0. It is preferable to contain at least one of 0003% or more and 0.01% or less and Zr: 0.0003% or more and 0.01% or less.
[0054]
 The above-mentioned steel composition may be measured by a general method for analyzing steel. For example, the steel component may be measured using ICP-AES (Inductively Coupled Plasma-Atomic Emission Spectrometry). In addition, sol. Al may be measured by ICP-AES using a filtrate obtained by heat-decomposing the sample with an acid. Further, C and S may be measured by using the combustion-infrared absorption method, N may be measured by using the inert gas melting-heat conductivity method, and O may be measured by using the inert gas melting-non-dispersion infrared absorption method.
[0055]
 2. Aggregation Structure
 Next, the assembly structure of the hot-rolled steel sheet according to the present embodiment will be described.
[0056]
 The hot-rolled steel plate according to the present embodiment has an average pole density of the orientation group consisting of {110} <110> to {110} <001> in the surface region in the range from the steel plate surface to the plate thickness 1/10. It has an texture of 0.5 or more and 3.0 or less, and the standard deviation of the extreme density of this orientation group is 0.2 or more and 2.0 or less.
[0057]
(Surface region in the range from the surface of the steel plate to 1/10 of the plate thickness) When the
 steel plate is bent and deformed, the strain increases toward the surface with the center of the plate thickness as the boundary, and the strain becomes maximum on the outermost surface. Therefore, bending cracks are generated on the surface of the steel sheet. Since it is the structure of the surface region in the range from the surface of the steel sheet to the plate thickness of 1/10 that contributes to the formation of such cracks, the texture of the surface region is controlled.
[0058]
(In the surface region, the average polar density of the azimuth group consisting of {110} <110> to {110} <001> is 0.5 or more and 3.0 or less, and the standard deviation of the polar density of this azimuth group is (0.2 or more and 2.0 or less)
 The average polar density of the orientation group consisting of {110} <110> to {110} <001> in the surface region in the range from the steel plate surface to the plate thickness 1/10 is 3. If it exceeds 0, the region where deformation localization occurs increases and causes bending cracks. Therefore, a value obtained by dividing the minimum bending radius by the plate thickness at least one of L-axis bending and C-axis bending. Rm / t, which is, cannot satisfy 2.0 or less. Therefore, the average polar density of the orientation group consisting of {110} <110> to {110} <001> is set to 3.0 or less. The average polar density of this orientation group is preferably 2.5 or less, more preferably 2.0 or less.
[0059]
 The smaller the average polar density of the orientation group consisting of the above {110} <110> to {110} <001>, the more preferable, but for a high-strength hot-rolled steel sheet having a tensile strength of 780 MPa or more, this value is set to less than 0.5. Since this is difficult, the practical lower limit is 0.5.
[0060]
 If the distribution of the orientation group consisting of {110} <110> to {110} <001> in the surface region ranging from the surface of the steel sheet to the thickness of 1/10 is non-uniform, the anisotropy of bending workability Becomes larger. When the standard deviation of the extreme density of each direction of the direction group consisting of {110} <110> to {110} <001> is more than 2.0, the anisotropy between L-axis bending and C-axis bending becomes large. , At least one of L-axis bending and C-axis bending, Rm / t, which is the value obtained by dividing the minimum bending radius by the plate thickness, cannot satisfy 2.0 or less. Therefore, the standard deviation of the extreme density of the orientation group consisting of {110} <110> to {110} <001> is set to 2.0 or less. The standard deviation of the extreme density of this azimuth group is preferably 1.5 or less, more preferably 1.0 or less.
[0061]
 The smaller the standard deviation of the extreme density of the orientation group consisting of the above {110} <110> to {110} <001>, the more preferable, but for a high-strength hot-rolled steel sheet having a tensile strength of 780 MPa or more, it should be less than 0.2. Is difficult, so the practical lower limit is 0.2.
[0062]
 In the hot-rolled steel sheet according to the present embodiment, the extreme density of the crystal orientation of {334} <263> is 1 in the central region in the range of the plate thickness of 3/8 to the plate thickness of 5/8 with respect to the surface of the steel plate. It is preferable to have a texture of 0.0 or more and 7.0 or less.
[0063]
(Central region in the range from 3/8 plate thickness to 5/8 plate thickness with respect to the surface of the steel plate) When the
 steel plate is bent and deformed to generate bending cracks in the surface region, these bending cracks occur in the central region of the plate thickness. It may propagate toward. Since the central region, which is in the range of 3/8 to 5/8 of the plate thickness, mainly contributes to the growth of such bending cracks with respect to the surface of the steel plate, it is possible to control the texture of this region. preferable.
[0064]
(In the central region, the extreme density of the crystal orientation of {334} <263> is 1.0 or more and 7.0 or less.) In
 the central region, which ranges from 3/8 plate thickness to 5/8 plate thickness, { By controlling the extreme density of the crystal orientation of 334} <263> to 7.0 or less, more excellent bending workability can be obtained in both the L direction and the C direction. For example, in the surface region, the average polar density of the orientation group consisting of {110} <110> to {110} <001> is 0.5 or more and 3.0 or less, and the standard deviation of the extreme density of this orientation group is If it is 0.2 or more and 2.0 or less and the extreme density of the crystal orientation of {334} <263> in the central region is 7.0 or less, the minimum bending radius in both the L direction and the C direction. Rm / t, which is the value obtained by dividing by the plate thickness, satisfies 1.5 or less. Therefore, it is preferable that the extreme density of the crystal orientation of {334} <263> is 7.0 or less. The extreme density of this crystal orientation is more preferably 6.0 or less, still more preferably 5.0 or less.
[0065]
 The smaller the extreme density of the crystal orientation of {334} <263> is, the more preferable it is. However, in a high-strength hot-rolled steel sheet having a tensile strength of 780 MPa or more, it is difficult to control it to less than 1.0. Is 1.0.
[0066]
 The extreme density can be measured by the EBSP (Electron Backscatter Diffraction Pattern) method. For the sample to be analyzed by the EBSP method, the cut surface parallel to the rolling direction and perpendicular to the plate surface is mechanically polished, and then the strain is removed by chemical polishing or electrolytic polishing. Using this sample, the measurement interval is 4 μm and the measurement area is 150,000 μm 2 in the range from the surface of the steel plate to the plate thickness 1/10, and if necessary, in the range from the plate thickness 3/8 to the plate thickness 5/8. The analysis is performed by the EBSP method so as described above.
[0067]
 FIG. 2 shows a crystal orientation distribution function (ODF) having a cross section of φ2 = 45 ° and an orientation group consisting of {110} <110> to {110} <001>. The orientation group consisting of {110} <110> to {110} <001> is a crystal orientation distribution function (ODF) of φ2 = 45 ° cross section, which displays the texture analysis in BUNGE, and is of {110} <110>. From the crystal orientation (φ1 = 0 °, Φ = 90.0 °, φ2 = 45.0 °), the crystal orientation of {110} <001> (φ1 = 90.0 °, Φ = 90.0 °, φ2 = It refers to the range of φ1 = 0 to 90 ° up to 45.0 °). However, since there is a measurement error due to the processing of the test piece and the setting of the sample, the hot-rolled steel sheet according to this embodiment has the average pole density of the orientation group consisting of {110} <110> to {110} <001>. The standard deviation is calculated at the hatched portion (within the range of Φ = 80 to 90 ° and φ1 = 0 to 90 °) shown in FIG.
[0068]
 In addition, in the direction group consisting of {110} <110> to {110} <001>, {110} <110>, {110} <111>, {110} <223>, {110} <112>, The crystal orientation of {110} <001> is included.
[0069]
 Here, as for the crystal orientation of the rolled plate, the lattice plane parallel to the plate surface is usually indicated by (hkl) or {hkl}, and the orientation parallel to the rolling direction is indicated by [uvw] or . Note that {hkl} and are generic terms for equivalent lattice planes and directions, and (uvw) and [hkl] refer to individual lattice planes and directions. That is, since the hot-rolled steel sheet according to the present embodiment targets the bcc structure, for example, (110), (-110), (1-10), (-1-10), (101), (-). 101), (10-1), (-10-1), (011), (0-11), (01-1), (0-1-1) are equivalent lattice planes and can be distinguished. Not stick. In such a case, these lattice planes are collectively referred to as {110}.
[0070]
 The direction group consisting of {110} <110> to {110} <001> is a direction in which the deformation resistance value changes greatly depending on the value of φ1, for example, when the angle of φ1 is 0 ° to 45 °, the L direction. The deformation resistance when deformed to is large, and when the angle of φ1 is 45 ° to 90 °, the deformation resistance when deformed in the C direction becomes large. Therefore, in the texture in which this orientation group is developed, when deformed in the L direction or the C direction, it is caused by the difference in the amount of deformation between the crystal in the orientation having a large deformation resistance and the crystal in the orientation having a small deformation resistance. Localization of the deformed deformation occurs and becomes the starting point of crack generation.
[0071]
 FIG. 3 shows the crystal orientation distribution function (ODF) having a cross section of φ2 = 45 ° and the crystal orientation of {334} <263>. The crystal orientation of {334} <263> is the crystal orientation distribution function (ODF) of φ2 = 45 ° cross section, which displays the texture analysis in BUNGE, and is (φ1 = 36.1 °, Φ = 46.7 °, φ2 = 45.0 °). However, since there is a measurement error due to the processing of the test piece and the setting of the sample, in the hot-rolled steel sheet according to the present embodiment, the hatched portion (hatched portion) shown in FIG. 3 is set as the extreme density of the crystal orientation of {334} <263>. Calculate the average strength in the range of Φ = 40 to 50 ° and φ1 = 30 to 40 °).
[0072]
 Since the crystal orientation of {334} <263> has a large deformation resistance in both the L direction and the C direction, the development of this crystal orientation causes the deformation resistance with other crystal orientations. Deformation localization due to the difference occurs, and these deformation concentration points promote the propagation of cracks, thereby deteriorating the bendability.
[0073]
3. 3. Steel sheet structure
 in the hot rolled steel sheet according to the present embodiment, texture only to be controlled as described above, the configuration phase of the steel structure is not particularly limited.
[0074]
 However, the hot-rolled steel sheet according to the present embodiment may contain a compound such as ferrite, bainite, fresh martensite, tempered martensite, pearlite, retained austenite, and carbonitride as a constituent phase of the steel structure. No.
[0075]
 For example, in% area, ferrite: 0% or more and 70% or less, total of bainite and tempered martensite: 0% or more and 100% or less (may be bainite and tempered martensite single structure), retained austenite: 25% or less. , Fresh martensite: 0% or more and 100% or less (may be a single martensite structure), and pearlite: 5% or less are preferable. It is preferable that the balance other than the above constituent phases is limited to 5% or less.
[0076]
4. Mechanical Properties
 Next, the mechanical properties of the hot-rolled steel sheet according to this embodiment will be described.
[0077]
(Tensile strength is 780 MPa or more and 1370 MPa or less)
 The hot-rolled steel sheet according to the present embodiment preferably has sufficient strength that contributes to weight reduction of automobiles. Therefore, the maximum tensile strength (TS) is set to 780 MPa or more. The maximum tensile strength is preferably 980 MPa or more. The upper limit of the maximum tensile strength does not need to be set in particular, but for example, this upper limit may be set to 1370 MPa. Further, the hot-rolled steel sheet according to the present embodiment preferably has a total elongation (EL) of 7% or more. The tensile test may be performed in accordance with JIS Z2241 (2011).
[0078]
 The hot-rolled steel sheet according to the present embodiment can be subjected to a bending test along the rolling direction (L direction) and the direction perpendicular to the rolling direction (C direction) by satisfying the above-mentioned steel composition, texture, and tensile strength. However, Rm / t, which is the value obtained by dividing the minimum bending radius by the plate thickness (minimum bending radius ÷ plate thickness), is 2.0 or less.
[0079]
 Rm is the minimum bending radius, and t is the thickness of the hot-rolled steel sheet. In the bending test, for example, a strip-shaped test piece is cut out from a position 1/2 in the width direction of a hot-rolled steel sheet, and bending (L-axis bending) in which the bending ridge line is parallel to the rolling direction (L direction) and bending ridge line are Both bending (C-axis bending) parallel to the direction perpendicular to the rolling direction (C direction) may be performed in accordance with JIS Z 2248 (2014) (V block 90 ° bending test). It is investigated whether or not a crack is generated on the outside of the bend, and the minimum bending radius Rm at which the crack does not occur is obtained.
[0080]
5. Manufacturing Method
 Next, a preferable manufacturing method of the hot-rolled steel sheet according to the present embodiment will be described.
[0081]
 The method for manufacturing the hot-rolled steel sheet according to the present embodiment is not limited to the following method. The following manufacturing method is an example for manufacturing the hot-rolled steel sheet according to the present embodiment.
[0082]
 In order to obtain excellent bending workability in both the L direction and the C direction, bending in either the L direction or the C direction is performed by controlling the texture of the surface region of the steel sheet that undergoes the most severe bending deformation. It is important to suppress the occurrence of bending cracks even during deformation. Further, it is desirable to reduce the extreme density in a predetermined direction in the central region of the plate thickness so that minute cracks generated in the surface region of the steel sheet do not propagate to the inside. The manufacturing conditions for satisfying these conditions are shown below.
[0083]
 The manufacturing process prior to hot rolling is not particularly limited. That is, after melting in a blast furnace, an electric furnace, or the like, various secondary smelting may be performed, and then casting may be performed by a method such as ordinary continuous casting, casting by the ingot method, or thin slab casting. In the case of continuous casting, the cast slab may be cooled to a low temperature and then heated again and then hot-rolled, or the cast slab may be hot-rolled as it is after casting without being cooled to a low temperature. .. Scrap may be used as the raw material.
[0084]
 The cast slab is heated. In this heating step, the slab is heated to a temperature of 1200 ° C. or higher and 1300 ° C. or lower, and then held for 30 minutes or longer. If the heating temperature is less than 1200 ° C., Ti and Nb-based precipitates are not sufficiently melted, so that sufficient precipitation strengthening cannot be obtained during hot rolling in the subsequent process, and the precipitates remain in the steel as coarse carbides, so that formability is formed. Deteriorate. Therefore, the heating temperature of the slab is set to 1200 ° C. or higher. On the other hand, if the heating temperature exceeds 1300 ° C., the amount of scale generated increases and the yield decreases, so the heating temperature is set to 1300 ° C. or lower. In order to sufficiently dissolve the Ti and Nb-based precipitates, it is preferable to keep the Ti and Nb-based precipitates in this temperature range for 30 minutes or more. Further, in order to suppress excessive scale loss, the holding time is preferably 10 hours or less, and more preferably 5 hours or less.
[0085]
 The heated slab is roughly rolled. In this rough rolling step, the thickness of the rough rolled plate after rough rolling is controlled to be more than 35 mm and 45 mm or less. The thickness of the rough-rolled plate affects the amount of temperature decrease from the tip to the tail of the rolled plate that occurs from the start of rolling to the completion of rolling in the finish rolling process. Further, when the thickness of the rough-rolled plate is 35 mm or less or more than 45 mm, the amount of strain introduced into the steel sheet during the finish rolling, which is the next process, changes, and the processed structure formed during the finish rolling changes. do. As a result, the recrystallization behavior changes, making it difficult to obtain a desired texture. In particular, it becomes difficult to obtain the above-mentioned texture in the surface region of the steel sheet.
[0086]
 The rough-rolled plate is subjected to finish rolling. In this finish rolling process, multi-step finish rolling is performed. The start temperature of finish rolling is 1000 ° C. or higher and 1150 ° C. or lower, and the thickness of the steel plate (thickness of the rough-rolled plate) before the start of finish rolling is more than 35 mm and 45 mm or less. Further, in the rolling one step before the final step of the multi-step finish rolling, the rolling temperature is 960 ° C. or higher and 1015 ° C. or lower, and the rolling reduction ratio is more than 11% and 23% or lower. Further, in the final stage of the multi-stage finish rolling, the rolling temperature is 930 ° C. or higher and 995 ° C. or lower, and the rolling reduction ratio is more than 11% and 21% or less. In addition, each condition at the time of reduction in the final two stages is controlled, and the texture formation parameter ω calculated by the following equation 1 satisfies 100 or less. Finish rolling is performed under the above conditions.
[0087]
[Number 1]

[0088]
[Number 2]

[0089]
[Number 3]

[0090]
[Number 4]

[0091]
[Number 5]

[0092]
[Number 6]

[0093]
[Number 7]

[0094]
[Number 8]

[0095]
 Here,
 PE: conversion value of the recrystallization suppressing effect by the precipitate-forming element (unit: mass%)
 Ti: concentration of Ti contained in steel (unit: mass%)
 Nb: concentration of Nb contained in steel (unit: mass%) Unit: Mass%)
 F 1 * : Converted rolling reduction rate one step before the final stage (Unit:%)
 F 2 * : Converted rolling reduction rate of the final stage (Unit:%)
 F 1 : One step before the final stage Reduction rate (unit:%)
 F 2 : Reduction rate of the final stage (unit:%)
 Sr 1 : Rolling shape ratio one step before the final stage (no unit)
 Sr 2 : Rolling shape ratio in the final stage (no unit)
 D 1 : Roll diameter one step before the final stage (unit: mm)
 D 2 : Roll diameter of the final stage (unit: mm)
 t 1: Plate thickness at the start of rolling one step before the final stage (unit: mm)
 t 2 : Plate thickness at the start of rolling at the final stage (unit: mm)
 t f : Plate thickness after finish rolling (unit: mm)
 FT 1 * : Converted rolling temperature one step before the final stage (unit: ° C)
 FT 2 * : Converted rolling temperature of the final stage (unit: ° C)
 FT 1 : Rolling temperature one step before the final stage (unit: ° C) )
 FT 2 : Rolling temperature of the final stage (unit: ° C)
[0096]
 However, in Equations 1 to 8, the numbers 1 and 2 added to the variables such as F 1 and F 2 are the rolling one step before the final step in the final two-step rolling in the multi-step finish rolling. 1 is added to the variable related to rolling, and 2 is added to the variable related to rolling in the final stage. For example, in multi-step finish rolling consisting of all seven steps of rolling, F 1 means the rolling reduction of the sixth step counting from the rolling inlet side, and F 2 means the rolling reduction of the seventh step.
[0097]
 Conversion value of recrystallization suppression effect by precipitate-forming element Regarding PE, the effect of pinning and solution drag becomes apparent when the value of Ti + 1.3Nb is 0.02 or more. Therefore, in Equation 2, Ti + 1.3Nb <0 When 0.02 is satisfied, PE = 0.01, and when Ti + 1.3Nb ≧ 0.02 is satisfied, PE = Ti + 1.3Nb-0.01.
[0098]
Regarding  the converted reduction rate F 1 * one step before the final stage , the effect of the reduction rate F 1 one step before the final stage on the texture becomes apparent when the value of F 1 is 12 or more. at, F 1 if they meet the <12, F 1 * and = 1.0, F 1 when satisfying ≧ 12, F 1 * = F 1 to -11.
[0099]
 Conversion rolling reduction rate F in the final stage 2 * About the reduction ratio F in the final stage 2 Effects of on texture, F 2 because the value of becomes apparent in 11.1 above, in Equation 4, F 2 to {110} <001> develops in the surface region, and the surface region is aggregated. The organization cannot be controlled within the above range. Alternatively, the distribution of the extreme densities of the crystal orientations included in the azimuth group becomes uneven in the surface region, and the standard deviation of the extreme densities of the azimuth group cannot be controlled within the above range. Therefore, in the finish rolling step, the texture formation parameter ω is controlled to 100 or less.
[0105]
 Further, when the texture formation parameter ω is set to 60 or less, the amount of shear strain introduced into the steel sheet surface region is reduced and the recrystallization behavior in the plate thickness center region is promoted. In addition, the extreme density of the crystal orientation of {334} <263> becomes 7.0 or less in the central region of the plate thickness, and the anisotropy of bending workability becomes small. Therefore, it is preferable that the texture formation parameter ω is 60 or less in the finish rolling step.
[0106]
(Rolling temperature FT 1 one step before the final step is 960 ° C or higher and 1015 ° C or lower) When
 the rolling temperature FT 1 one step before the final step is less than 960 ° C, recrystallization of the structure processed by rolling is sufficient. The texture of the surface region cannot be controlled within the above range. Therefore, the rolling temperature FT 1 is set to 960 ° C. or higher. On the other hand, when the rolling temperature FT 1 exceeds 1015 ° C., the formed state of the processed structure and the recrystallization behavior change due to the coarsening of the austenite grains and the like, so that the texture of the surface region cannot be controlled within the above range. .. Therefore, the rolling temperature FT 1 is set to 1015 ° C. or lower.
[0107]
(The reduction rate F 1 one step before the final stage is more than 11% and 23% or less) If
 the reduction ratio F 1 one step before the final stage is 11% or less, the amount of strain introduced into the steel sheet by rolling is not sufficient. It becomes sufficient and recrystallization does not occur sufficiently, and the texture of the surface region cannot be controlled within the above range. Therefore, the reduction rate F 1 is set to more than 11%. On the other hand, when the reduction factor F 1 is more than 23%, the lattice defects in the crystal become excessive and the recrystallization behavior changes, so that the texture of the surface region cannot be controlled within the above range. Therefore, the reduction rate F 1 is set to 23% or less.
 The reduction rate F 1 is calculated as follows.
  F 1 = (t 1- t 2 ) / t 1 x 100
[0108]
(The rolling temperature FT 2 of the final stage is 930 ° C. or higher and 995 ° C. or lower) When
 the rolling temperature FT 2 of the final stage is lower than 930 ° C., the recrystallization rate of austenite is significantly reduced, and {110} < The development of the orientation group consisting of 110> to {110} <001> cannot be suppressed, and the texture of the surface region cannot be controlled within the above range. Therefore, the rolling temperature FT 2 is set to 930 ° C. or higher. On the other hand, when the rolling temperature FT 2 exceeds 995 ° C., the formed state of the processed structure and the recrystallization behavior change, so that the texture of the surface region cannot be controlled within the above range. Therefore, the rolling temperature FT 2 is set to 995 ° C. or lower.
[0109]
(The reduction ratio F 2 of the final stage is more than 11% and 21% or less) When
 the reduction ratio F 2 of the final stage is 11% or less, the amount of strain introduced into the steel sheet by rolling is insufficient and recrystallization is sufficient. The texture of the surface region cannot be controlled within the above range. Therefore, the reduction rate F 2 is set to exceed 11%. On the other hand, if the reduction factor F 2 is more than 21%, the lattice defects in the crystal become excessive and the recrystallization behavior changes, so that the texture of the surface region cannot be controlled within the above range. Therefore, the reduction rate F 2 is set to 21% or less.
 The reduction rate F 2 is calculated as follows.
  F 2 = (t 2- t f ) / t 2 × 100
[0110]
 In the finish rolling process, each of the above conditions is controlled simultaneously and inseparably. It is not necessary for each of the above-mentioned conditions to satisfy only one of the above-mentioned conditions, and when all of the above-mentioned conditions are satisfied at the same time, the texture of the surface region can be controlled within the above-mentioned range.
[0111]
 The hot-rolled steel sheet after finish rolling is cooled and wound up. In the hot-rolled steel sheet according to the present embodiment, excellent bending workability is achieved in both L-axis bending and C-axis bending by controlling the texture rather than the base structure (constituent phase of the steel structure). doing. Therefore, the manufacturing conditions are not particularly limited in the cooling step and the winding step. Therefore, the cooling step and the winding step after the multi-step finish rolling may be performed by a conventional method.
[0112]
 The constituent phase of the steel sheet during finish rolling is mainly austenite, and the texture of austenite is controlled by the finish rolling described above. This high temperature stable phase such as austenite undergoes a phase transformation to a low temperature stable phase such as bainite during cooling and winding after finish rolling. Due to this phase transformation, the crystal orientation may change, and the texture of the steel sheet after cooling may change. However, with respect to the hot-rolled steel sheet according to the present embodiment, the above-mentioned crystal orientation controlled in the surface region is not significantly affected by cooling and winding after finish rolling. That is, if the texture is controlled as austenite during finish rolling, even if the phase is transformed into a low temperature stable phase such as bainite during subsequent cooling and winding, this low temperature stable phase will have the above-mentioned texture in the surface region. Meet the provisions of. The same applies to the texture of the central region of plate thickness.
[0113]
 Further, the hot-rolled steel sheet according to the present embodiment may be pickled if necessary after cooling. Even if this pickling treatment is performed, the texture of the surface region does not change. The pickling treatment may be carried out, for example, in hydrochloric acid having a concentration of 3 to 10% at a temperature of 85 ° C. to 98 ° C. for 20 seconds to 100 seconds.
[0114]
 Further, the hot-rolled steel sheet according to the present embodiment may be subjected to skin pass rolling if necessary after cooling. In this skin pass rolling, the rolling reduction may be set so that the texture of the surface region does not change. Skin pass rolling has the effects of preventing stretcher strains that occur during processing and shaping, and of shape correction.
Example 1
[0115]
 Next, the effect of one aspect of the present invention will be described in more detail by way of examples. Yes, the present invention is not limited to this one-condition example. The present invention may adopt various conditions as long as the gist of the present invention is not deviated and the object of the present invention is achieved.
[0116]
 Steel having a predetermined chemical composition is cast, and after casting, it is cooled as it is or once to room temperature, then reheated, heated to a temperature range of 1200 ° C to 1300 ° C, and then at a temperature of 1100 ° C or higher, the desired coarseness is obtained. A rough-rolled plate was produced by rough-rolling the slab to the thickness of the rolled plate. The rough-rolled plate was subjected to multi-step finish rolling consisting of 7 steps in all steps. The steel sheet after finish rolling was cooled and wound to prepare a hot-rolled steel sheet.
[0117]
 Tables 1 and 2 show the chemical composition of the hot-rolled steel sheet. Regarding the chemical composition, the values ​​marked with "<" in the table indicate that the values ​​were below the detection limit of the measuring device, and that these elements were not intentionally added to the steel.
[0118]
 Further, in the finish rolling step, the finish rolling is started from the temperatures shown in Tables 3 to 6, and the final two steps of rolling are excluded from the start of rolling. plate thickness t in the rolling start of one stage prior to stage 1 was rolled up. Then, the final two-stage rolling was performed under the conditions shown in Tables 3 to 10. After the finish rolling was completed, each cooling pattern shown below was used for cooling and winding to obtain a hot-rolled steel sheet having a plate thickness t f shown in Tables 3 to 6 . The final plate thickness of the steel sheet after the completion of hot rolling was defined as the plate thickness t f after finish rolling .
[0119]
(Cooling pattern B: Bainite pattern) In
 this pattern, after the finish rolling was completed, the film was cooled to a winding temperature of 450 ° C. to 550 ° C. at an average cooling rate of 20 ° C./sec or more, and then wound into a coil.
[0120]
(Cooling pattern F + B: Ferrite-bainite pattern) In
 this pattern, after finishing rolling is completed, the product is cooled to a cooling stop temperature range of 600 to 750 ° C at an average cooling rate of 20 ° C./sec or more, and within the cooling stop temperature range. After the cooling was stopped and held for 2 to 4 seconds, the mixture was further wound into a coil at an average cooling rate of 20 ° C./sec or more and a winding temperature of 550 ° C. or less. The cooling shutdown temperature and holding time were set with reference to the following Ar3 temperature.
 Ar3 (° C.) = 870-390C + 24Si-70Mn-50Ni-5Cr-20Cu + 80Mo
[0121]
(Cooling pattern Ms: Martensite pattern) In
 this pattern, after the finish rolling was completed, the film was cooled to a winding temperature of 100 ° C. or lower at an average cooling rate of 20 ° C./sec or more, and then wound into a coil.
[0122]
 In addition, the sample material No. 1 to No. In 142, rough rolling with a total reduction rate of 40% or more is performed in the range of 1200 ° C. to 1100 ° C., and finish rolling is performed so that the total reduction rate of the five stages other than the final two stages of multi-stage finish rolling is 50% or more. went. However, the total rolling reduction is calculated based on the plate thickness at the start of rough rolling and finish rolling and the plate thickness at the completion of rough rolling and the completion of the fifth finishing stage, and is expressed as a percentage. It is a numerical value.
[0123]
 Tables 1 and 2 show the chemical components, Tables 3 to 10 show the manufacturing conditions, and Tables 11 to 14 show the manufacturing results of the produced hot-rolled steel sheet. In the "cooling / winding pattern" in Tables 7 to 10, "B" indicates a bainite pattern, "F + B" indicates a ferrite-bainite pattern, and "Ms" indicates a martensite pattern. Further, in the "aggregate structure" in Tables 11 to 14, "A orientation group" indicates an orientation group consisting of {110} <110> to {110} <001>, and "B orientation" is {334} <. 263> Indicates the crystal orientation. In addition, each symbol used in the table corresponds to the symbol described above.
[0124]
 The tensile strength of the JIS Z 2241 (2011) was determined by using a JIS No. 5 test piece collected from a position 1/4 of the width direction of the hot-rolled steel sheet so that the direction perpendicular to the rolling direction (C direction) is the longitudinal direction. A tensile test was carried out in accordance with the regulations, and the maximum tensile strength TS and butt elongation (total elongation) EL were determined.
[0125]
 The bending test is performed in accordance with JIS Z 2248 (2014) (V block 90 ° bending test) using a test piece cut out from the width direction 1/2 position of the hot-rolled steel plate into a strip shape of 100 mm × 30 mm. Bending test of both bending where the bending ridge is parallel to the rolling direction (L direction) (L-axis bending) and bending where the bending ridge is parallel to the direction perpendicular to the rolling direction (C direction) (C-axis bending) Was carried out, and the minimum bending radius at which cracks did not occur was determined. However, the presence or absence of cracks is determined by mirror polishing the cross section of the test piece after the V block 90 ° bending test on a surface parallel to the bending direction and perpendicular to the plate surface, and then using an optical microscope to detect cracks on the outside of the bending of the test piece. After observing, it was judged that there was a crack when the observed crack length exceeded 50 μm.
[0126]
 The underlined values ​​in Tables 1 to 14 indicate that they are outside the scope of the present invention.
[0127]
 In Tables 1 to 14, the sample material No. described as "Example of the present invention". Is a steel sheet that satisfies all the conditions of the present invention.
[0128]
 In the example of the present invention, the steel composition is satisfied, and the average pole density of the orientation group consisting of {110} <110> to {110} <001> in the surface region is 0.5 or more and 3.0 or less, and this The standard deviation of the extreme density of the azimuth group is 0.2 or more and 2.0 or less, and the tensile strength is 780 MPa or more. Therefore, in both L-axis bending and C-axis bending, Rm / t, which is the value obtained by dividing the minimum bending radius by the plate thickness, is 2.0 or less, and has excellent bendability and different bending workability. A hot-rolled steel sheet with small anisotropy has been obtained.
[0129]
 On the other hand, in Tables 1 to 14, the sample material No. described as "comparative example". Is a steel sheet that does not satisfy at least one of the steel composition, the texture of the surface region, or the tensile strength.
[0130]
 Sample No. In No. 5, the tensile strength was not sufficient because the Mn content was out of the control range.
 Sample No. In No. 8, since the Mn content was out of the control range, the anisotropy of bendability and bendability was not sufficient.
 Sample No. In No. 9, the C content was out of the control range, so the tensile strength was not sufficient.
 Sample No. In No. 15, since the Ti content and the texture formation parameter ω were out of the control range, the texture was not satisfied, and the anisotropy of bendability and bendability was not sufficient.
 Sample No. In No. 19, since the Nb content and the texture formation parameter ω were out of the control range, the texture was not satisfied, and the anisotropy of bendability and bendability was not sufficient.
 Sample No. In No. 31, since the finish rolling conditions FT 1 and FT 2 were out of the control range, the texture was not satisfied, and the anisotropy of bendability and bendability was not sufficient.
 Sample No. In No. 33, since the finish rolling conditions FT 1 and FT 2 were out of the control range, the texture was not satisfied, and the anisotropy of bendability and bendability was not sufficient.
 Sample No. In No. 35, since the texture formation parameter ω was out of the control range, the texture was not satisfied, and the anisotropy of bendability and bendability was not sufficient.
 Sample No. In No. 48, since the Ti content and the texture formation parameter ω were out of the control range, the texture was not satisfied, and the anisotropy of bendability and bendability was not sufficient.
 Sample No. In No. 51, since the Nb content and the texture formation parameter ω were out of the control range, the texture was not satisfied, and the anisotropy of bendability and bendability was not sufficient.
 Sample No. In No. 55, since the finish rolling condition FT 1 and the texture formation parameter ω were out of the control range, the texture was not satisfied, and the anisotropy of bendability and bendability was not sufficient.
 Sample No. In No. 58, since the finish rolling condition FT 1 and the texture formation parameter ω were out of the control range, the texture was not satisfied, and the anisotropy of bendability and bendability was not sufficient.
 Sample No. In No. 63, since the texture formation parameter ω was out of the control range, the texture was not satisfied, and the anisotropy of bendability and bendability was not sufficient.
 Sample No. In No. 66, since the texture formation parameter ω was out of the control range, the texture was not satisfied, and the anisotropy of bendability and bendability was not sufficient.
 Sample No. In No. 71, since the texture formation parameter ω was out of the control range, the texture was not satisfied, and the anisotropy of bendability and bendability was not sufficient.
 Sample No. 74, the finish rolling conditions F 1 and for texture formation parameter ω is outside the control range, not satisfy the texture, bendability and bending workability anisotropy was not sufficient.
 Sample No. In 79, since the texture formation parameter ω was out of the control range, the texture was not satisfied, and the anisotropy of bendability and bendability was not sufficient.
 Sample No. In No. 82, since the texture formation parameter ω was out of the control range, the texture was not satisfied, and the anisotropy of bendability and bendability was not sufficient.
 Sample No. In 87, since the texture formation parameter ω was out of the control range, the texture was not satisfied, and the anisotropy of bendability and bendability was not sufficient.
 Sample No. In No. 90, since the texture formation parameter ω was out of the control range, the texture was not satisfied, and the anisotropy of bendability and bendability was not sufficient.
 Sample No. In No. 95, since the texture formation parameter ω was out of the control range, the texture was not satisfied, and the anisotropy of bendability and bendability was not sufficient.
 Sample No. In 98, since the texture formation parameter ω was out of the control range, the texture was not satisfied, and the anisotropy of bendability and bendability was not sufficient.
 Sample No. 103, the starting temperature and the finish rolling condition F of the finish rolling 1 because it was out of the control range, not satisfy the texture, bendability and bending workability anisotropy was not sufficient.
 Sample No. In No. 110, since the thickness of the rough-rolled plate was out of the control range, the texture was not satisfied, and the anisotropy of bendability and bendability was not sufficient.
 Sample No. In 113, since the thickness of the rough-rolled plate was out of the control range, the texture was not satisfied, and the anisotropy of bendability and bendability was not sufficient.
 Sample No. 114 is the finish rolling condition FT. Since 1 was out of the control range, the texture was not satisfied, and the anisotropy of bendability and bendability was not sufficient.
 Sample No. In 115, since the finish rolling condition FT 2 was out of the control range, the texture was not satisfied, and the anisotropy of bendability and bendability was not sufficient.
 Sample No. In 116, since the finish rolling condition FT 2 was out of the control range, the texture was not satisfied, and the anisotropy of bendability and bendability was not sufficient.
 Sample No. 117, finish rolling conditions F 1 because it was out of the control range, not satisfy the texture, bendability and bending workability anisotropy was not sufficient.
 Sample No. In 118, since the finish rolling condition F 2 was out of the control range, the texture was not satisfied, and the anisotropy of bendability and bendability was not sufficient.
 Sample No. 119, finish rolling condition F 2 because it was out of the control range, not satisfy the texture, bendability and bending workability anisotropy was not sufficient.
 Sample No. In No. 120, since the start temperature of finish rolling was out of the control range, the texture was not satisfied, and the anisotropy of bendability and bendability was not sufficient.
 Sample No. 121, Si content, the thickness of the roughly rolled plate, the starting temperature, and finish rolling conditions of the finishing rolling F 1Was out of the control range, so it did not satisfy the texture and the anisotropy of bendability and bendability was not sufficient.
 Sample No. In 122, since the finish rolling conditions F 1 and F 2 were out of the control range, the texture was not satisfied, and the anisotropy of bendability and bendability was not sufficient.
 Sample No. In 123, since the finish rolling conditions FT 1 and FT 2 were out of the control range, the texture was not satisfied, and the anisotropy of bendability and bendability was not sufficient.
 Sample No. In 124, since the thickness of the rough-rolled plate, the start temperature of finish rolling, the finish rolling conditions F 1 and F 2 were out of the control range, the texture was not satisfied, and the anisotropy of bendability and bendability was observed. It wasn't enough.
[0131]
 In the example in which the rolling temperature FT 2 in the final stage was less than 930 ° C., the value of the texture formation parameter ω does not make sense, so ω and the like are left blank in the table.
[0132]
[table 1]

[0133]
[Table 2]

[0134]
[Table 3]

[0135]
[Table 4]

[0136]
[Table 5]

[0137]
[Table 6]

[0138]
[Table 7]

[0139]
[Table 8]

[0140]
[Table 9]

[0141]
[Table 10]

[0142]
[Table 11]

[0143]
[Table 12]

[0144]
[Table 13]

[0145]
[Table 14]

Industrial applicability
[0146]
 According to the above aspect of the present invention, it is possible to obtain a hot-rolled steel sheet having a tensile strength (maximum tensile strength) of 780 MPa or more, excellent bending workability, and small anisotropy of bending workability. Therefore, it has high industrial applicability.
The scope of the claims
[Claim 1]
 As chemical components, in mass%,
  C: 0.030% or more and 0.400% or less,
  Si: 0.050% or more and 2.5% or less,
  Mn: 1.00% or more and 4.00% or less,
  sol. Al: 0.001% or more and 2.0% or less,
  Ti: 0% or more and 0.20% or less,
  Nb: 0% or more and 0.20% or less,
  B: 0% or more and 0.010% or less,
  V: 0% More than 1.0% or less,
  Cr: 0% or more and 1.0% or less,
  Mo: 0% or more and 1.0% or less,
  Cu: 0% or more and 1.0% or less,
  Co: 0% or more and 1.0% or less ,
  W: 0% or more and 1.0% or less,
  Ni: 0% or more and 1.0% or less,
  Ca: 0% or more and 0.01% or less,
  Mg: 0% or more and 0.01% or less,
  REM: 0% or more  Includes
  0.01% or less, Zr: 0% or more and 0.01% or less
,
  P: 0.020% or less,
  S: 0.020% or less,
  N: 0.010% or less,

 The average pole of the orientation group consisting of {110} <110> to {110} <001> in the surface region  where the balance is composed of iron and impurities and is in the range from the surface of the steel sheet to the thickness of 1/10. The heat is characterized in that the density is 0.5 or more and 3.0 or less, the standard deviation of the extreme density of the orientation group is 0.2 or more and 2.0 or less, and the
 tensile strength is 780 MPa or more and 1370 MPa or less.
Rolled steel plate.
[Claim 2]
 The extreme density of the crystal orientation of {334} <263> is 1.0 or more and 7.0 or less in the central region in the range of the plate thickness of 3/8 to the plate thickness of 5/8 with respect to the surface of the steel plate.
The hot-rolled steel sheet according to claim 1.
[Claim 3]
 As the chemical components,
  Ti: 0.001% or more and 0.20% or less,
  Nb: 0.001% or more and 0.20% or less,
  B: 0.001% or more and 0.010% or less,
  V: 0.005% or more and 1.0% or less,
  Cr: 0.005% or more and 1.0% or less,
  Mo: 0.005% or more and 1.0% or less,
  Cu: 0.005% or more and 1.0% or less,
  Co: 0.005% or more and 1.0% or less,
  W: 0.005% or more and 1.0% or less,
  Ni: 0.005% or more and 1.0% or less,
  Ca: 0.0003% or more and 0.01% Hereinafter,  it contains at least one of
  Mg: 0.0003% or more and 0.01% or less,
  REM: 0.0003% or more and 0.01% or less, and
  Zr: 0.0003% or more and 0.01% or less. The hot-rolled steel plate according to claim 1 or 2, wherein the hot-rolled steel plate is characterized by the above.

Documents

Application Documents

# Name Date
1 202117021474-IntimationOfGrant20-06-2024.pdf 2024-06-20
1 202117021474-TRANSLATIOIN OF PRIOIRTY DOCUMENTS ETC. [12-05-2021(online)].pdf 2021-05-12
2 202117021474-PatentCertificate20-06-2024.pdf 2024-06-20
2 202117021474-STATEMENT OF UNDERTAKING (FORM 3) [12-05-2021(online)].pdf 2021-05-12
3 202117021474-REPLY FROM DAE-180624.pdf 2024-06-19
3 202117021474-PROOF OF RIGHT [12-05-2021(online)].pdf 2021-05-12
4 202117021474-Response to office action [30-05-2024(online)].pdf 2024-05-30
4 202117021474-PRIORITY DOCUMENTS [12-05-2021(online)].pdf 2021-05-12
5 202117021474-POWER OF AUTHORITY [12-05-2021(online)].pdf 2021-05-12
5 202117021474-AtomicEnergy-09-04-2024.pdf 2024-04-09
6 202117021474-FORM 1 [12-05-2021(online)].pdf 2021-05-12
6 202117021474-ABSTRACT [14-03-2023(online)].pdf 2023-03-14
7 202117021474-DRAWINGS [12-05-2021(online)].pdf 2021-05-12
7 202117021474-CLAIMS [14-03-2023(online)].pdf 2023-03-14
8 202117021474-DECLARATION OF INVENTORSHIP (FORM 5) [12-05-2021(online)].pdf 2021-05-12
8 202117021474-COMPLETE SPECIFICATION [14-03-2023(online)].pdf 2023-03-14
9 202117021474-COMPLETE SPECIFICATION [12-05-2021(online)].pdf 2021-05-12
9 202117021474-DRAWING [14-03-2023(online)].pdf 2023-03-14
10 202117021474-FER_SER_REPLY [14-03-2023(online)].pdf 2023-03-14
10 202117021474-Verified English translation [24-05-2021(online)].pdf 2021-05-24
11 202117021474-OTHERS [14-03-2023(online)].pdf 2023-03-14
11 202117021474-Proof of Right [24-05-2021(online)].pdf 2021-05-24
12 202117021474-Response to office action [13-12-2022(online)].pdf 2022-12-13
12 202117021474-Verified English translation [21-09-2021(online)].pdf 2021-09-21
13 202117021474-AtomicEnergy-14-11-2022.pdf 2022-11-14
13 202117021474-FORM 3 [04-10-2021(online)].pdf 2021-10-04
14 202117021474-FER.pdf 2022-11-10
14 202117021474.pdf 2021-10-19
15 202117021474-FORM 18 [18-10-2022(online)].pdf 2022-10-18
16 202117021474-FER.pdf 2022-11-10
16 202117021474.pdf 2021-10-19
17 202117021474-FORM 3 [04-10-2021(online)].pdf 2021-10-04
17 202117021474-AtomicEnergy-14-11-2022.pdf 2022-11-14
18 202117021474-Verified English translation [21-09-2021(online)].pdf 2021-09-21
18 202117021474-Response to office action [13-12-2022(online)].pdf 2022-12-13
19 202117021474-OTHERS [14-03-2023(online)].pdf 2023-03-14
19 202117021474-Proof of Right [24-05-2021(online)].pdf 2021-05-24
20 202117021474-FER_SER_REPLY [14-03-2023(online)].pdf 2023-03-14
20 202117021474-Verified English translation [24-05-2021(online)].pdf 2021-05-24
21 202117021474-COMPLETE SPECIFICATION [12-05-2021(online)].pdf 2021-05-12
21 202117021474-DRAWING [14-03-2023(online)].pdf 2023-03-14
22 202117021474-COMPLETE SPECIFICATION [14-03-2023(online)].pdf 2023-03-14
22 202117021474-DECLARATION OF INVENTORSHIP (FORM 5) [12-05-2021(online)].pdf 2021-05-12
23 202117021474-CLAIMS [14-03-2023(online)].pdf 2023-03-14
23 202117021474-DRAWINGS [12-05-2021(online)].pdf 2021-05-12
24 202117021474-ABSTRACT [14-03-2023(online)].pdf 2023-03-14
24 202117021474-FORM 1 [12-05-2021(online)].pdf 2021-05-12
25 202117021474-POWER OF AUTHORITY [12-05-2021(online)].pdf 2021-05-12
25 202117021474-AtomicEnergy-09-04-2024.pdf 2024-04-09
26 202117021474-Response to office action [30-05-2024(online)].pdf 2024-05-30
26 202117021474-PRIORITY DOCUMENTS [12-05-2021(online)].pdf 2021-05-12
27 202117021474-REPLY FROM DAE-180624.pdf 2024-06-19
27 202117021474-PROOF OF RIGHT [12-05-2021(online)].pdf 2021-05-12
28 202117021474-STATEMENT OF UNDERTAKING (FORM 3) [12-05-2021(online)].pdf 2021-05-12
28 202117021474-PatentCertificate20-06-2024.pdf 2024-06-20
29 202117021474-TRANSLATIOIN OF PRIOIRTY DOCUMENTS ETC. [12-05-2021(online)].pdf 2021-05-12
29 202117021474-IntimationOfGrant20-06-2024.pdf 2024-06-20

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1 ptser45AE_15-03-2023.pdf
2 ptser452E_10-11-2022.pdf
2 ptser45AE_15-03-2023.pdf

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