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Hydrodesulfurization Catalyst For Hydrocarbon Oil Process Of Producing Same And Method For Hydrorefining

Abstract: The present invention provides a hydrodesulfurization catalyst that exhibits a high desulfurization activity when used in hydrotreatment of hydrocarbon oil  in particular straight-run gas oil. The catalyst comprising at least one type of metal component selected from Groups VIA and VIII in the periodic table  supported on a silica-titania-alumina support where the total of the diffraction peak area indicating the crystal structure of anatase titania (101) planes and the diffraction peak area indicating the crystal structure of rutile titania (110) planes is 1/4 or less of the diffraction peak area indicating the aluminum crystal structure ascribed to ?-alumina (400) planes  as measured by X-ray diffraction analysis  the catalyst having (a) a specific surface area (SA) of 150 m2/g or greater  (b) a total pore volume (PVo) of 0.30 ml/g or greater  (c) an average pore diameter (PD)

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Notices, Deadlines & Correspondence

Patent Information

Application #
Filing Date
29 March 2012
Publication Number
25/2013
Publication Type
INA
Invention Field
CHEMICAL
Status
Email
Parent Application
Patent Number
Legal Status
Grant Date
2019-01-17
Renewal Date

Applicants

JX NIPPON OIL & ENERGY CORPORATION
6-3  Otemachi 2-chome  Chiyoda-ku  Tokyo 100-8162  Japan
JGC CATALYSTS AND CHEMICALS LTD
16th Floor  Solid Square East Tower  580  Horikawa-cho  Saiwai-ku  Kawasaki-shi  Kanagawa-212-0013  Japan

Inventors

1. SEKI  Hiroyuki
c/o JX NIPPON OIL & ENERGY CORPORATION  6-3  Otemachi 2-chome  Chiyoda-ku  Tokyo 100-8162  Japan
2. FUKUI  Yoshiaki
c/o JX NIPPON OIL & ENERGY CORPORATION  6-3  Otemachi 2-chome  Chiyoda-ku  Tokyo 100-8162  Japan
3. YOSHIDA  Masanori
c/o JX NIPPON OIL & ENERGY CORPORATION  6-3  Otemachi 2-chome  Chiyoda-ku  Tokyo 100-8162  Japan
4. TAGAWA  Shogo
c/o JGC CATALYSTS AND CHEMICALS LTD.  13-2  Kitaminato-machi  Wakamatsu-ku  Kitakyushu-shi  Fukuoka 808-0027  Japan
5. KAGAWA  Tomoyasu
c/o JGC CATALYSTS AND CHEMICALS LTD.  13-2  Kitaminato-machi  Wakamatsu-ku  Kitakyushu-shi  Fukuoka 808-0027  Japan

Specification

We Claim:
1. A hydrodesulfurization catalyst for a hydrocarbon oil comprising at least
one type of metal component selected from Groups VIA and VIII in the periodic table,
supported on a silica-titania-alumina support where the total of the diffraction peak
area indicating the crystal structure of anatase titania (101) planes and the diffraction
peak area indicating the crystal structure of rutile titania (110) planes is 1/4 or less of
the diffraction peak area indicating the aluminum crystal structure ascribed to γ-
alumina (400) planes, as measured by X-ray diffraction analysis, the catalyst having
(a) a specific surface area (SA) of 150 m2/g or greater, (b) a total pore volume (PVo)
of 0.30 ml/g or greater, (c) an average pore diameter (PD) of 6 to 15 nm (60 to 150 Å),
and (d) the ratio of the pore volume (PVp) of pores having diameters within ±30
percent of the average pore diameter (PD) being 70 percent or greater of the total pore
volume (PVo),
wherein said silica-titania-alumina support contains silica in the form of SiO2 in an amount of 1 to 10 percent by mass, titania in the form of TiO2 in an amount of 15 to 35 percent by mass, and alumina in the form of A12O3 in an amount of 55 to 84 percent by mass, all on the support basis.
2. The hydrodesulfurization catalyst for a hydrocarbon oil as claimed in claim 1, wherein said metal component selected from Groups VIA and VIII in the periodic table is selected from the group consisting of molybdenum, tungsten, cobalt, and nickel.
3. The hydrodesulfurization catalyst for a hydrocarbon oil as claimed in claim 1 or 2, wherein said metal component selected from Groups VIA and VIII in the periodic table is supported in an amount of l to 35 percent by mass in the form of oxide on the catalyst basis.
4. A method for hydrorefining a hydrocarbon oil wherein a hydrocarbon oil is hydrotreated under a hydrogen atmosphere using the hydrodesulfurization catalyst as claimed in any one of claims 1 to 3.

5. The method for hydrorefining a hydrocarbon oil as claimed in claim 4, wherein said hydrotreatment is carried out at a reaction temperature of 300 to 420ºC., a hydrogen partial pressure of 3.0 to 15.0 MPa, a liquid hourly space velocity of 0.5 to 4.0 h-1, and a hydrogen/oil ratio of 120 to 420 NL/L.
6. The method for hydrorefining a hydrocarbon oil as claimed in claim 4 or 5, wherein said hydrocarbon oil is selected from the group consisting of straight-run gas oil, vacuum gas oil, light cycle oil, hydrocracked gas oil, and thermal cracked gas oil.
7. The method for hydrorefining a hydrocarbon as claimed in any one of claims 4 to 6, wherein said hydrocarbon oil contains 70 percent by volume or more of a fraction having a boiling point of 260 to 360ºC.
8. The method for hydrorefining a hydrocarbon oil as claimed in any one of claims 4 to 7, wherein an oil produced by hydrotreatment of said hydrocarbon oil contains sulfur in an amount of 10 ppm by mass or less and nitrogen in an amount of 3 ppm by mass or less.

Documents

Application Documents

# Name Date
1 Form-5.pdf 2012-04-09
2 Form-3.pdf 2012-04-09
3 Form-1.pdf 2012-04-09
4 3020-CHENP-2012 POWER OF ATTORNEY 27-09-2012.pdf 2012-09-27
5 3020-CHENP-2012 FORM-3 27-09-2012.pdf 2012-09-27
6 3020-CHENP-2012 CORRESPONDENCE OTHERS 27-09-2012.pdf 2012-09-27
7 3020-CHENP-2012 FORM-3 23-11-2012.pdf 2012-11-23
8 3020-CHENP-2012 CORRESPONDENCE OTHERS 23-11-2012.pdf 2012-11-23
9 3020-CHENP-2012-FER.pdf 2018-01-15
10 3020-CHENP-2012-certified copy of translation (MANDATORY) [12-03-2018(online)].pdf 2018-03-12
11 3020-CHENP-2012-Proof of Right (MANDATORY) [05-07-2018(online)].pdf 2018-07-05
12 3020-CHENP-2012-PETITION UNDER RULE 137 [05-07-2018(online)].pdf 2018-07-05
13 3020-CHENP-2012-PETITION UNDER RULE 137 [05-07-2018(online)]-1.pdf 2018-07-05
14 3020-CHENP-2012-OTHERS [05-07-2018(online)].pdf 2018-07-05
15 3020-CHENP-2012-Information under section 8(2) (MANDATORY) [05-07-2018(online)].pdf 2018-07-05
16 3020-CHENP-2012-FORM 3 [05-07-2018(online)].pdf 2018-07-05
17 3020-CHENP-2012-FER_SER_REPLY [05-07-2018(online)].pdf 2018-07-05
18 3020-CHENP-2012-DRAWING [05-07-2018(online)].pdf 2018-07-05
19 3020-CHENP-2012-CLAIMS [05-07-2018(online)].pdf 2018-07-05
20 3020-CHENP-2012-certified copy of translation (MANDATORY) [05-07-2018(online)].pdf 2018-07-05
21 3020-CHENP-2012-ABSTRACT [05-07-2018(online)].pdf 2018-07-05
22 Correspondence by Agent_Assignment_11-07-2018.pdf 2018-07-11
23 3020-CHENP-2012-RELEVANT DOCUMENTS [26-09-2018(online)].pdf 2018-09-26
24 3020-CHENP-2012-RELEVANT DOCUMENTS [26-09-2018(online)]-1.pdf 2018-09-26
25 3020-CHENP-2012-MARKED COPIES OF AMENDEMENTS [26-09-2018(online)].pdf 2018-09-26
26 3020-CHENP-2012-MARKED COPIES OF AMENDEMENTS [26-09-2018(online)]-1.pdf 2018-09-26
27 3020-CHENP-2012-FORM-26 [26-09-2018(online)].pdf 2018-09-26
28 3020-CHENP-2012-FORM-26 [26-09-2018(online)]-1.pdf 2018-09-26
29 3020-CHENP-2012-Changing Name-Nationality-Address For Service [26-09-2018(online)].pdf 2018-09-26
30 3020-CHENP-2012-Changing Name-Nationality-Address For Service [26-09-2018(online)]-1.pdf 2018-09-26
31 3020-CHENP-2012-AMENDED DOCUMENTS [26-09-2018(online)].pdf 2018-09-26
32 3020-CHENP-2012-AMENDED DOCUMENTS [26-09-2018(online)]-1.pdf 2018-09-26
33 Correspondence by Agent_Power of Attorney and Translate Certificate_27-09-2018.pdf 2018-09-27
34 3020-CHENP-2012-HearingNoticeLetter.pdf 2018-11-12
35 3020-CHENP-2012-REQUEST FOR ADJOURNMENT OF HEARING UNDER RULE 129A [29-11-2018(online)].pdf 2018-11-29
36 3020-chenp-2012-ExtendedHearingNoticeLetter_03Jan2019.pdf 2018-12-05
37 3020-CHENP-2012-Correspondence to notify the Controller (Mandatory) [20-12-2018(online)].pdf 2018-12-20
38 3020-CHENP-2012-Written submissions and relevant documents (MANDATORY) [11-01-2019(online)].pdf 2019-01-11
39 3020-CHENP-2012-Retyped Pages under Rule 14(1) (MANDATORY) [11-01-2019(online)].pdf 2019-01-11
40 3020-CHENP-2012-2. Marked Copy under Rule 14(2) (MANDATORY) [11-01-2019(online)].pdf 2019-01-11
41 Marked up Claims_Granted 305820_17-01-2019.pdf 2019-01-17
42 Drawings_Granted 305820_17-01-2019.pdf 2019-01-17
43 Description_Granted 305820_17-01-2019.pdf 2019-01-17
44 Claims_Granted 305820_17-01-2019.pdf 2019-01-17
45 Abstract_Granted 305820_17-01-2019.pdf 2019-01-17
46 3020-CHENP-2012-PatentCertificate17-01-2019.pdf 2019-01-17
47 3020-CHENP-2012-IntimationOfGrant17-01-2019.pdf 2019-01-17
48 3020-CHENP-2012-RELEVANT DOCUMENTS [21-03-2020(online)].pdf 2020-03-21
49 3020-CHENP-2012-RELEVANT DOCUMENTS [18-06-2021(online)].pdf 2021-06-18
50 3020-CHENP-2012-RELEVANT DOCUMENTS [04-08-2022(online)].pdf 2022-08-04
51 3020-CHENP-2012-RELEVANT DOCUMENTS [16-09-2023(online)].pdf 2023-09-16

Search Strategy

1 SearchStrategy_12-01-2018.pdf

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