Abstract: The present invention provides a hydrodesulfurization catalyst that exhibits a high desulfurization activity when used in hydrotreatment of hydrocarbon oil in particular straight-run gas oil. The catalyst comprising at least one type of metal component selected from Groups VIA and VIII in the periodic table supported on a silica-titania-alumina support where the total of the diffraction peak area indicating the crystal structure of anatase titania (101) planes and the diffraction peak area indicating the crystal structure of rutile titania (110) planes is 1/4 or less of the diffraction peak area indicating the aluminum crystal structure ascribed to ?-alumina (400) planes as measured by X-ray diffraction analysis the catalyst having (a) a specific surface area (SA) of 150 m2/g or greater (b) a total pore volume (PVo) of 0.30 ml/g or greater (c) an average pore diameter (PD)
We Claim:
1. A hydrodesulfurization catalyst for a hydrocarbon oil comprising at least
one type of metal component selected from Groups VIA and VIII in the periodic table,
supported on a silica-titania-alumina support where the total of the diffraction peak
area indicating the crystal structure of anatase titania (101) planes and the diffraction
peak area indicating the crystal structure of rutile titania (110) planes is 1/4 or less of
the diffraction peak area indicating the aluminum crystal structure ascribed to γ-
alumina (400) planes, as measured by X-ray diffraction analysis, the catalyst having
(a) a specific surface area (SA) of 150 m2/g or greater, (b) a total pore volume (PVo)
of 0.30 ml/g or greater, (c) an average pore diameter (PD) of 6 to 15 nm (60 to 150 Å),
and (d) the ratio of the pore volume (PVp) of pores having diameters within ±30
percent of the average pore diameter (PD) being 70 percent or greater of the total pore
volume (PVo),
wherein said silica-titania-alumina support contains silica in the form of SiO2 in an amount of 1 to 10 percent by mass, titania in the form of TiO2 in an amount of 15 to 35 percent by mass, and alumina in the form of A12O3 in an amount of 55 to 84 percent by mass, all on the support basis.
2. The hydrodesulfurization catalyst for a hydrocarbon oil as claimed in claim 1, wherein said metal component selected from Groups VIA and VIII in the periodic table is selected from the group consisting of molybdenum, tungsten, cobalt, and nickel.
3. The hydrodesulfurization catalyst for a hydrocarbon oil as claimed in claim 1 or 2, wherein said metal component selected from Groups VIA and VIII in the periodic table is supported in an amount of l to 35 percent by mass in the form of oxide on the catalyst basis.
4. A method for hydrorefining a hydrocarbon oil wherein a hydrocarbon oil is hydrotreated under a hydrogen atmosphere using the hydrodesulfurization catalyst as claimed in any one of claims 1 to 3.
5. The method for hydrorefining a hydrocarbon oil as claimed in claim 4, wherein said hydrotreatment is carried out at a reaction temperature of 300 to 420ºC., a hydrogen partial pressure of 3.0 to 15.0 MPa, a liquid hourly space velocity of 0.5 to 4.0 h-1, and a hydrogen/oil ratio of 120 to 420 NL/L.
6. The method for hydrorefining a hydrocarbon oil as claimed in claim 4 or 5, wherein said hydrocarbon oil is selected from the group consisting of straight-run gas oil, vacuum gas oil, light cycle oil, hydrocracked gas oil, and thermal cracked gas oil.
7. The method for hydrorefining a hydrocarbon as claimed in any one of claims 4 to 6, wherein said hydrocarbon oil contains 70 percent by volume or more of a fraction having a boiling point of 260 to 360ºC.
8. The method for hydrorefining a hydrocarbon oil as claimed in any one of claims 4 to 7, wherein an oil produced by hydrotreatment of said hydrocarbon oil contains sulfur in an amount of 10 ppm by mass or less and nitrogen in an amount of 3 ppm by mass or less.
| # | Name | Date |
|---|---|---|
| 1 | Form-5.pdf | 2012-04-09 |
| 2 | Form-3.pdf | 2012-04-09 |
| 3 | Form-1.pdf | 2012-04-09 |
| 4 | 3020-CHENP-2012 POWER OF ATTORNEY 27-09-2012.pdf | 2012-09-27 |
| 5 | 3020-CHENP-2012 FORM-3 27-09-2012.pdf | 2012-09-27 |
| 6 | 3020-CHENP-2012 CORRESPONDENCE OTHERS 27-09-2012.pdf | 2012-09-27 |
| 7 | 3020-CHENP-2012 FORM-3 23-11-2012.pdf | 2012-11-23 |
| 8 | 3020-CHENP-2012 CORRESPONDENCE OTHERS 23-11-2012.pdf | 2012-11-23 |
| 9 | 3020-CHENP-2012-FER.pdf | 2018-01-15 |
| 10 | 3020-CHENP-2012-certified copy of translation (MANDATORY) [12-03-2018(online)].pdf | 2018-03-12 |
| 11 | 3020-CHENP-2012-Proof of Right (MANDATORY) [05-07-2018(online)].pdf | 2018-07-05 |
| 12 | 3020-CHENP-2012-PETITION UNDER RULE 137 [05-07-2018(online)].pdf | 2018-07-05 |
| 13 | 3020-CHENP-2012-PETITION UNDER RULE 137 [05-07-2018(online)]-1.pdf | 2018-07-05 |
| 14 | 3020-CHENP-2012-OTHERS [05-07-2018(online)].pdf | 2018-07-05 |
| 15 | 3020-CHENP-2012-Information under section 8(2) (MANDATORY) [05-07-2018(online)].pdf | 2018-07-05 |
| 16 | 3020-CHENP-2012-FORM 3 [05-07-2018(online)].pdf | 2018-07-05 |
| 17 | 3020-CHENP-2012-FER_SER_REPLY [05-07-2018(online)].pdf | 2018-07-05 |
| 18 | 3020-CHENP-2012-DRAWING [05-07-2018(online)].pdf | 2018-07-05 |
| 19 | 3020-CHENP-2012-CLAIMS [05-07-2018(online)].pdf | 2018-07-05 |
| 20 | 3020-CHENP-2012-certified copy of translation (MANDATORY) [05-07-2018(online)].pdf | 2018-07-05 |
| 21 | 3020-CHENP-2012-ABSTRACT [05-07-2018(online)].pdf | 2018-07-05 |
| 22 | Correspondence by Agent_Assignment_11-07-2018.pdf | 2018-07-11 |
| 23 | 3020-CHENP-2012-RELEVANT DOCUMENTS [26-09-2018(online)].pdf | 2018-09-26 |
| 24 | 3020-CHENP-2012-RELEVANT DOCUMENTS [26-09-2018(online)]-1.pdf | 2018-09-26 |
| 25 | 3020-CHENP-2012-MARKED COPIES OF AMENDEMENTS [26-09-2018(online)].pdf | 2018-09-26 |
| 26 | 3020-CHENP-2012-MARKED COPIES OF AMENDEMENTS [26-09-2018(online)]-1.pdf | 2018-09-26 |
| 27 | 3020-CHENP-2012-FORM-26 [26-09-2018(online)].pdf | 2018-09-26 |
| 28 | 3020-CHENP-2012-FORM-26 [26-09-2018(online)]-1.pdf | 2018-09-26 |
| 29 | 3020-CHENP-2012-Changing Name-Nationality-Address For Service [26-09-2018(online)].pdf | 2018-09-26 |
| 30 | 3020-CHENP-2012-Changing Name-Nationality-Address For Service [26-09-2018(online)]-1.pdf | 2018-09-26 |
| 31 | 3020-CHENP-2012-AMENDED DOCUMENTS [26-09-2018(online)].pdf | 2018-09-26 |
| 32 | 3020-CHENP-2012-AMENDED DOCUMENTS [26-09-2018(online)]-1.pdf | 2018-09-26 |
| 33 | Correspondence by Agent_Power of Attorney and Translate Certificate_27-09-2018.pdf | 2018-09-27 |
| 34 | 3020-CHENP-2012-HearingNoticeLetter.pdf | 2018-11-12 |
| 35 | 3020-CHENP-2012-REQUEST FOR ADJOURNMENT OF HEARING UNDER RULE 129A [29-11-2018(online)].pdf | 2018-11-29 |
| 36 | 3020-chenp-2012-ExtendedHearingNoticeLetter_03Jan2019.pdf | 2018-12-05 |
| 37 | 3020-CHENP-2012-Correspondence to notify the Controller (Mandatory) [20-12-2018(online)].pdf | 2018-12-20 |
| 38 | 3020-CHENP-2012-Written submissions and relevant documents (MANDATORY) [11-01-2019(online)].pdf | 2019-01-11 |
| 39 | 3020-CHENP-2012-Retyped Pages under Rule 14(1) (MANDATORY) [11-01-2019(online)].pdf | 2019-01-11 |
| 40 | 3020-CHENP-2012-2. Marked Copy under Rule 14(2) (MANDATORY) [11-01-2019(online)].pdf | 2019-01-11 |
| 41 | Marked up Claims_Granted 305820_17-01-2019.pdf | 2019-01-17 |
| 42 | Drawings_Granted 305820_17-01-2019.pdf | 2019-01-17 |
| 43 | Description_Granted 305820_17-01-2019.pdf | 2019-01-17 |
| 44 | Claims_Granted 305820_17-01-2019.pdf | 2019-01-17 |
| 45 | Abstract_Granted 305820_17-01-2019.pdf | 2019-01-17 |
| 46 | 3020-CHENP-2012-PatentCertificate17-01-2019.pdf | 2019-01-17 |
| 47 | 3020-CHENP-2012-IntimationOfGrant17-01-2019.pdf | 2019-01-17 |
| 48 | 3020-CHENP-2012-RELEVANT DOCUMENTS [21-03-2020(online)].pdf | 2020-03-21 |
| 49 | 3020-CHENP-2012-RELEVANT DOCUMENTS [18-06-2021(online)].pdf | 2021-06-18 |
| 50 | 3020-CHENP-2012-RELEVANT DOCUMENTS [04-08-2022(online)].pdf | 2022-08-04 |
| 51 | 3020-CHENP-2012-RELEVANT DOCUMENTS [16-09-2023(online)].pdf | 2023-09-16 |
| 1 | SearchStrategy_12-01-2018.pdf |