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Improved Process For The Regeneration Of An Alkaline Solution Utilized In A Process For The Extraction Of Sulphur Containing Compounds Comprising A Washing Step

Abstract: The present invention relates to the field of the extraction of sulphur-containing compounds such as the mercaptans, COS or H2S from a hydrocarbon-containing cut. This selective extraction is carried out by bringing the hydrocarbon-containing cut in liquid phase into contact with an alkaline solution, for example soda. The process according to the invention is an improved process for the regeneration of the alkaline solution, making it possible to reduce the quantity of alkaline solution required in the regeneration section Figure 2 to be published

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Notices, Deadlines & Correspondence

Patent Information

Application #
Filing Date
27 February 2018
Publication Number
42/2018
Publication Type
INA
Invention Field
CHEMICAL
Status
Email
patent@depenning.com
Parent Application
Patent Number
Legal Status
Grant Date
2022-02-25
Renewal Date

Applicants

AXENS
89 Bd Franklin Roosevelt, B.P. 50802, F-92508 Rueil Malmaison, Cedex, France

Inventors

1. BESNAULT, Jean-Michel
0008 Rue Du Marche, Le Vesinet, 78110 Le Vesinet, France
2. FERRERO, Sebastien
0011 Av Ste Marie, Chaville, 92370 Chaville, France
3. DO, Mai Phuong
BB-31-1, 10 Mont Kiara, Jalan Kiara 1, 50480 Kuala Lumpur, Malaysia

Specification

CLAIMS
1) Process for the regeneration of a used alkaline Solution utilized in a unit for the
extraction of the sulphur-containing Compounds from a hydrocarbon-containing cut,
comprising the following sequence of Steps:
a) Sending the used alkaline Solution (1a) into an oxidation reactor (4) in which it is brought into contact with an oxidizing agent (5) and a catalyst (3), said used alkaline Solution being heated beforehand to a temperature comprised between 40°C and 50°C.
b) Sending the effluents (7) of the oxidation reactor (4) into a Separator (8) from which a hydrocarbon phase rieh in disulphides (10), and a partially regenerated alkaline Solution (11) are extracted,
c) Cooling the partially regenerated alkaline Solution (11) originating from step b) to a temperature less than or equal to 45°C,
d) Dividing the partially regenerated alkaline Solution (15) cooled in step c) into two flows:

- a flow constituting the excess of recirculated alkaline Solution which is sent upstream (21a), or directly (22a), into the oxidation reactor (4), and which constitutes the cooling means used to control the rise in temperature of said reactor, and,
- a flow (21b) or (22b) which continues the regeneration process,

e) Mixing the flow (21b) or (22b), originating from step d) with a hydrocarbon-containing cut without sulphur-containing Compounds (16),
f) Sending the mixture originating from step e) into a Separator (18) from which a totally regenerated alkaline Solution (19), and a hydrocarbon-containing cut partially enriched with disulphides (6) are extracted.
2) Process for the regeneration of a used alkaline Solution aecording to claim 1, in
which the excess (21a) of recirculated alkaline Solution is sent to the oxidation
reactor (4), via the cireuit upstream of said oxidation reactor (4), in a mixture with
the used alkaline Solution (1a).

3) Process for the regeneration of a used alkaline Solution according to claim 1, in which the excess (22a) of recirculated alkaline Solution is sent to the oxidation reactor (4), directly to one or more points of said oxidation reactor (4).
4) Process for the regeneration of a used alkaline Solution according to Claim 3, in which the point or points of introduction of the excess of recirculated alkaline Solution into the oxidation reactor (4) are provided with a diffusion means or a mixing means.
5) Process for the regeneration of a used alkaline Solution according to claim 3, in which the point or points of introduction of the excess of recirculated alkaline Solution into the oxidation reactor (4) are positioned so as to allow control of the rise in temperature of the oxidation reactor (4).
6) Process for the regeneration of a used alkaline Solution according to claim 1, in which the catalyst employed in the oxidation reactor (4) is of cobalt or vanadium phthalocyanines type.
7) Process for the regeneration of a used alkaline Solution according to claim 1, in which the catalyst employed in the oxidation reactor (4) is added to the alkaline Solution at the inlet of the oxidation reactor (4), so as to achieve a concentration of catalyst in the alkaline Solution comprised between 10 and 1,000 ppm by weight, preferentially between 10 and 500 ppm by weight.
8) Process for the regeneration of a used alkaline Solution according to claim 1, in which the oxidation reactor (4) is equipped with an additional cooling means (23).
9) Process for the regeneration of a used alkaline Solution according to claim 1, in which the excess of recirculated alkaline Solution (21a) or (22a) is cooled to a temperature at least 5°C less than that of the partially regenerated alkaline Solution, before being sent to the oxidation reactor (4).
10) Process for the regeneration of a used alkaline Solution according to claim 1, in which the hydrocarbon-containing cut to be desulphurized can ränge from methane to kerosene.

11) Installation forthe regeneration of a used alkaline Solution utilized in a unitforthe
extraction of the sulphur-containing Compounds from a hydrocarbon-containing
cut, according to the invention, comprising at least:
- an item of equipment (2) making it possible to heat the used alkaline Solution, before its introduction into the oxidation reactor to a temperature comprised between 40°C and 50°C,
- an oxidation reactor (4), in which the used alkaline Solution is brought into contact with an oxidizing agent (5) and a catalyst (3),
- a Separator (8) supplied with the effluent originating from the oxidation reactor (4), from which a hydrocarbon phase rieh in disulphides (10), and a partially regenerated alkaline Solution (11) are extracted,
- a cooling means (14) making it possible to cool the partially regenerated alkaline Solution (11) originating from the Separator (8) to a temperature less than or equal to 45°C,
- a means making it possible to divide the cooled partially regenerated alkaline Solution (15) into two flows:
- a first flow constituting the excess of recirculated alkaline Solution which is sent upstream (21a), or directly (22a), into the oxidation reactor (4), and,
- a second flow (21b) or (22b) which continues the regeneration process
- a cooling means constituted by the excess of recirculated alkaline Solution which is sent upstream (21a), or directly (22a), into the oxidation reactor (4),
- a means of mixing the flow (21b) or (22b), with a hydrocarbon-containing cut without sulphur-containing Compounds (16),
- a Separator (18) supplied with the mixture, from which a totally regenerated alkaline Solution (19), and a hydrocarbon-containing cut partially enriched with disulphides (6) are extracted.
12) Installation for the regeneration of used alkaline Solution according to Claim 11, in
which the oxidation reactor is equipped with an additional cooling means (23).

13) Installation for the regeneration of used alkaline Solution according to claim 11, in which an additional cooling means makes it possible to cool the excess of recirculated alkaline Solution (21a) or (22a) to a temperature at least 5°C less than that of the cooled partially regenerated alkaline Solution (15).

Documents

Application Documents

# Name Date
1 201844007288-TRANSLATIOIN OF PRIOIRTY DOCUMENTS ETC. [27-02-2018(online)].pdf 2018-02-27
2 201844007288-STATEMENT OF UNDERTAKING (FORM 3) [27-02-2018(online)].pdf 2018-02-27
3 201844007288-FORM 1 [27-02-2018(online)].pdf 2018-02-27
4 201844007288-FIGURE OF ABSTRACT [27-02-2018(online)].jpg 2018-02-27
5 201844007288-DRAWINGS [27-02-2018(online)].pdf 2018-02-27
6 201844007288-DECLARATION OF INVENTORSHIP (FORM 5) [27-02-2018(online)].pdf 2018-02-27
7 201844007288-COMPLETE SPECIFICATION [27-02-2018(online)].pdf 2018-02-27
8 201844007288-CLAIMS UNDER RULE 1 (PROVISIO) OF RULE 20 [27-02-2018(online)].pdf 2018-02-27
9 201844007288-Verified English translation (MANDATORY) [19-03-2018(online)].pdf 2018-03-19
10 201844007288-FORM-26 [19-03-2018(online)].pdf 2018-03-19
11 201844007288-Certified Copy of Priority Document (MANDATORY) [19-03-2018(online)].pdf 2018-03-19
12 Correspondence by Agent_Priority Document,PA_21-03-2018.pdf 2018-03-21
13 201844007288-Proof of Right (MANDATORY) [03-07-2018(online)].pdf 2018-07-03
14 Correspondence by Agent_Proof of Right(Form1)_04-07-2018.pdf 2018-07-04
15 201844007288-Proof of Right (MANDATORY) [04-07-2018(online)].pdf 2018-07-04
16 201844007288-FORM 3 [30-07-2018(online)].pdf 2018-07-30
17 201844007288-FORM 18 [02-02-2021(online)].pdf 2021-02-02
18 201844007288-FER.pdf 2021-10-17
19 201844007288-OTHERS [03-12-2021(online)].pdf 2021-12-03
20 201844007288-Information under section 8(2) [03-12-2021(online)].pdf 2021-12-03
21 201844007288-FORM 3 [03-12-2021(online)].pdf 2021-12-03
22 201844007288-FER_SER_REPLY [03-12-2021(online)].pdf 2021-12-03
23 201844007288-DRAWING [03-12-2021(online)].pdf 2021-12-03
24 201844007288-COMPLETE SPECIFICATION [03-12-2021(online)].pdf 2021-12-03
25 201844007288-CLAIMS [03-12-2021(online)].pdf 2021-12-03
26 201844007288-US(14)-HearingNotice-(HearingDate-11-01-2022).pdf 2021-12-15
27 201844007288-Correspondence to notify the Controller [07-01-2022(online)].pdf 2022-01-07
28 201844007288-Written submissions and relevant documents [24-01-2022(online)].pdf 2022-01-24
29 201844007288-Retyped Pages under Rule 14(1) [24-01-2022(online)].pdf 2022-01-24
30 201844007288-2. Marked Copy under Rule 14(2) [24-01-2022(online)].pdf 2022-01-24
31 201844007288-PatentCertificate25-02-2022.pdf 2022-02-25
32 201844007288-IntimationOfGrant25-02-2022.pdf 2022-02-25
33 201844007288-RELEVANT DOCUMENTS [12-08-2023(online)].pdf 2023-08-12

Search Strategy

1 SS201844007288E_14-06-2021.pdf

ERegister / Renewals

3rd: 02 May 2022

From 27/02/2020 - To 27/02/2021

4th: 02 May 2022

From 27/02/2021 - To 27/02/2022

5th: 02 May 2022

From 27/02/2022 - To 27/02/2023

6th: 24 Feb 2023

From 27/02/2023 - To 27/02/2024

7th: 19 Feb 2024

From 27/02/2024 - To 27/02/2025

8th: 17 Feb 2025

From 27/02/2025 - To 27/02/2026