DESC:FIELD OF INVENTION:
The present invention relates to use of a pyrethroid insecticide and/or neonicotinoid insecticide for reducing phytotoxicity in crops treated with a herbicide. The present invention relates to the method of reducing phytotoxicity in crops treated with herbicide using an insecticide selected from group of neonicotinoid insecticide and/or pyrethroid insecticides.

BACKGROUND OF THE INVENTION:
Weeds are a nuisance in most landscapes and sometimes the herbicides used to control the weeds end up injuring some of ornamental plants. Herbicide injury is usually the result of the person making the application. It normally happens while not following the directions on the label as carefully as one should. Farmers tend to use more herbicide than the label instructs or can be careless and spray during windy conditions or wave the wand around so that the spray drifts onto non-target plants.
The term for plant damage is “phytotoxicity” and it can be caused by pesticides, nutrients, or physical and environmental damage (wind, sun, hail, etc.). Often the identity of the herbicide can be determined by the injury symptoms on the plants. Symptoms can be divided into 5 main categories: leaf and shoot malformations, root and shoot stunting, leaf spotting, leaf chlorosis (yellowing), and leaf necrosis (death).
The compound 2-[(2-chlorophenyl)methyl]-4,4-dimethyl-3-isoxazolidinone, also known as "clomazone", is a potent herbicide as evidenced by its ability to control, for full growing seasons and at low application rates. However, clomazone is phytotoxic to other crops when applied at rates effective to control undesired vegetation, such contact resulting from drift to adjacent fields planted with low tolerance crops or from carryover when soybean fields treated with clomazone are rotated to a crop sensitive to clomazone.
Pigment inhibitors prevent plants from forming photosynthetic pigments. As a result, the affected plant parts become white to translucent. Clomazone (Command), a soil-applied herbicide, is the only member of the isoxazolidinone family in use at this time. Command is taken up by plant roots and shoots and can move in the xylem to plant leaves. The newly developed foliage of many plant species is so sensitive to Command that very small amounts can whiten new plant growth. Norflurazon (Zorial), a soil-applied herbicide, is the only member of the pyridazinone family in use at this time. Zorial is taken up by plant roots and moves to the growing points of susceptible plants. Susceptible weeds will emerge as white plants before dying.
It has been known that certain insecticides act as a safener against injury inflicted by herbicide application. Article titled “Evaluation of Safening Effects to Herbicides Conferred via Insecticide Seed Treatments in Soybean (Glycine max) and Grain Sorghum (Sorghum bicolor)” by Nicholas Robert Steppig discloses that applications of some organophosphate insecticides at planting can reduce cotton injury following applications of the soil-applied herbicide clomazone.
WO 1989006492 A1 discloses a method of controlling undesirable vegetation at locus by applying to the locus clomazone and, as an antidote to clomazone, a safening amount of at least one organophosphorus compound.
Article titled “Cotton (Gossypium hirsutum) Response to Clomazone and Insecticide Combination” discloses that combination of aldicarb, and phorate protected cotton from clomazone injury. Phorate at 0.14 kg ha-1 partially protected cotton from clomazone injury.
Even though use of insecticide as safener to herbicide is known, the present invention provides an alternative method for safening crops to the phytotoxic effects of herbicides in agriculture which will act as useful agronomic tool to farmers.

SUMMARY OF THE INVENTION:
Therefore, in one aspect, the present invention may provide use of a pyrethroid insecticide for reducing phytotoxicity in crops treated with a herbicide.
In another aspect, the present invention may provide use of a combination comprising a pyrethroid insecticide and at least another insecticide for reducing phytotoxicity in crops treated with a herbicide.
In another aspect, the present invention may provide use of a combination comprising a pyrethroid insecticide and at least another insecticide selected from the group consisting of a neonicotinoid insecticide, a thiazole insecticide and a thiazolidine insecticide for reducing phytotoxicity in crops treated with a herbicide.
In another aspect, the present invention may provide a method of reducing the phytotoxic effect of a herbicide on crops which are treated with said herbicide, the method comprising treating the crop with the herbicide in combination with at least one pyrethroid insecticide.
In yet another aspect, the present invention may provide a method of reducing the phytotoxic effect of a herbicide on crops which are treated with said herbicide, the method comprising treating the crop with at least one herbicide in combination with a pyrethroid insecticide and at least another insecticide.
In yet another aspect, the present invention may provide a method of reducing the phytotoxic effect of a herbicide on crops which are treated with said herbicide, the method comprising treating the crop and/or seed with at least one herbicide in combination with a pyrethroid insecticide and at least another insecticide selected from the group consisting of a neonicotinoid insecticide, a thiazole insecticide and a thiazolidine insecticide.
In another aspect, the present invention provides a combination comprising at least one herbicide and at least one pyrethroid insecticide.
In another aspect, the present invention provides a combination comprising at least one herbicide, at least one pyrethroid insecticide and at least another insecticide.
In another aspect, the present invention provides a combination comprising at least one herbicide, at least one pyrethroid insecticide, and at least another insecticide selected from the group consisting of a neonicotinoid insecticide, a thiazole insecticide and a thiazolidine insecticide.

DETAILED DESCRIPTION OF THE INVENTION:
For the purposes of the present invention, the term ‘safener’ is defined as substances which reduce or prevent the phytotoxic effect of crop protectants specifically herbicide, on plants treated therewith and/or on plants whose seeds and/or growth substrate have been treated or are treated therewith. According to present invention safener means a pyrethroid insecticide or a combination of a pyrethroid insecticide with a neonicotinoid insecticide or a thiazole insecticide or a thiazolidine insecticide.
The term ‘herbicide’ is used herein to mean an active ingredient that kills, controls or otherwise adversely modifies the growth of unwanted plants. An herbicidally effective or vegetation controlling amount is an amount of active ingredient which causes an adversely modifying effect and includes deviations from natural development, killing, regulation, desiccation, retardation, and the like.
The term “seed” represents all types of plant propagation material. It comprises seeds in the actual sense, grains, fruits, tubers, the rhizome, spores, cuttings, slips, meristem tissue, individual plant cells and any form of plant tissue from which a complete plant can be grown. Preferably, it takes the form of seed in the actual sense.
The term “phytotoxicity” as used herein means unintended herbicidal effect on a plant of interest resulting in significant damage to the plant.
In an embodiment the present invention relates to use of a pyrethroid insecticide for reducing phytotoxicity in crops treated with a herbicide.
In another embodiment the pyrethroid insecticide is selected from the group consisting of acrinathrin, allethrin, bioallethrin, esdépalléthrine, barthrin, bifenthrin, kappa-bifenthrin, bioethanomethrin, brofenvalerate, brofluthrinate, bromethrin, butethrin, chlorempenthrin, cyclethrin, cycloprothrin, cyfluthrin, beta-cyfluthrin, cyhalothrin, gamma-cyhalothrin, lambda-cyhalothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, cyphenothrin, deltamethrin, dimefluthrin, dimethrin, empenthrin, d-fanshiluquebingjuzhi, chloroprallethrin, fenfluthrin, fenpirithrin, fenpropathrin, fenvalerate, esfenvalerate, flucythrinate, fluvalinate, tau-fluvalinate, furamethrin, furethrin, heptafluthrin, imiprothrin, japothrins, kadethrin, methothrin, metofluthrin, epsilon-metofluthrin, momfluorothrin, epsilon-momfluorothrin, pentmethrin, permethrin, biopermethrin, transpermethrin, phenothrin, prallethrin, profluthrin, proparthrin, pyresmethrin, renofluthrin, meperfluthrin, resmethrin, bioresmethrin, cismethrin, tefluthrin, kappa-tefluthrin, terallethrin, tetramethrin, tetramethylfluthrin, tralocythrin, tralomethrin, transfluthrin, valerate, etofenprox, flufenprox, halfenprox, protrifenbute, silafluofen, sulfoxime, thiofluoximate.
In an embodiment, the preferred pyrethroid insecticide is lambda-cyhalothrin.
In an embodiment, the preferred pyrethroid insecticide is bifenthrin.
In an embodiment, the preferred pyrethroid insecticide is cypermethrin.
In an embodiment, the preferred pyrethroid insecticide is permethrin.
In another embodiment, the present invention provides use of a pyrethroid insecticide in a combination with at least another insecticide for reducing phytotoxicity in crops treated with a herbicide.
In an embodiment, said another insecticide is selected from the group consisting of a neonicotinoid insecticide, a thiazole insecticide and a thiazolidine insecticide for reducing phytotoxicity in crops treated with a herbicide.
The neonicotinoid insecticide is selected from clothianidin, dinotefuran, imidacloprid, imidaclothiz, thiamethoxam, nitenpyram, nithiazine, acetamiprid, imidacloprid, nitenpyram, paichongding, and thiacloprid.
In an embodiment, the preferred neonicotinoid insecticide is thiamethoxam.
In an embodiment, the preferred neonicotinoid insecticide is imidacloprid.
In an embodiment, the preferred neonicotinoid insecticide is acetamiprid.
In an embodiment, the preferred neonicotinoid insecticide is thiacloprid.
In an embodiment, the preferred neonicotinoid insecticide is clothianidin.
In an embodiment, the thiazole insecticide is selected from clothianidin and imidaclothiz.
In an embodiment, the thiazolidine insecticide is selected from tazimcarb and thiacloprid.
The phytotoxically active herbicides are preferably selected from 2,4-D esters and amines, 2,4-MCPA, acetochlor, acifluorfen, clomazone, aclonifen, AE0172747, alachlor, amidosulfuron, aminopyralid, aminotriazole, ammonium thiocyanate, anilifos, azimsulfuron, benfuresate, bensulfuron-methyl, bentazone, benthiocarb, benzobicyclon, bifenox, bispyribac-sodium, butachlor, butafenacil, butralin, cafenstrole, carbetamide, carfentrazone-ethyl, chlorflurenol, chlorimuron, cinosulfuron, clethodim, clopyralid, cloransulam-methyl, cyclosulfamuron, cycloxydim, cyhalofop-butyl, dicamba, dichlobenil, dichlorprop-P, diclosulam, diflufenican, diflufenzopyr, dimethenamid, dimethenamid-p, diquat, dithiopyr, diuron, EK2612, EPTC, esprocarb, ET-751, ethoxysulfuron, ethbenzanid, F7967, fenoxaprop, fenoxaprop-ethyl, fenoxaprop-ethyl + isoxidifen-ethyl, fentrazamide, flazasulfuron, florasulam, fluazifop, fluazifop-P-butyl, flucetosulfuron, flufenacet, flufenpyr-ethyl, flumetsulam, flumiclorac-pentyl, flumioxazin, fluometuron, flupyrsulfuron, fluroxypyr, fluroxypyr esters and salts, fomesafen, foramsulfuron, fumiclorac, glufosinate, glufosinate-ammonium, glyphosate , halosulfuron, haloxyfop-methyl, haloxyfop-R, HOK-201, imazamethabenz, imazamox, imazapic, imazapyr, imazaquin, imazethapyr, imazosulfuron, indanofan, indaziflam, iodosulfuron, ioxynil, IR 5790, isoproturon, isoxaben, isoxaflutole, KUH-071, lactofen, linuron, MCPA, MCPA ester & amine, mecoprop-P, mefenacet, mesosulfuron, mesotrione, metamifop, metolachlor, metosulam, metribuzin, metsulfuron, molinate, MSMA, napropamide, NC-620, nicosulfuron, norflurazon, OK-9701, orthosulfamuron, oryzalin, oxadiargyl, oxadiazon, oxazichlomefone, oxyfluorfen, paraquat, pendimethalin, pentoxazone, pethoxamid, picloram, picolinafen, piperophos, pretilachlor, profoxydim, propachlor, propanil, propyzamide, prosulfocarb, prosulfuron, pyraclonil, pyrazogyl, pyrazosulfuron, pyribenzoxim, pyriftalid, pyrimisulfan (KUH-021), pyriminobac-methyl, primisulfuron, propyrisulfuron (TH-547), pyroxsulam, pyroxasulfone (KIH-485), quinclorac, quizalofop-ethyl-D, S-3252, saflufenacil, sethoxydim, SL-0401, SL-0402, s-metolachlor, sulcotrione, sulfentrazone, sulfosate, tebuthiuron, tefuryltrione (AVH-301), thiazopyr, thiobencarb, triclopyr, triclopyr esters and amine, and tritosulfuron.
Thus, in an embodiment, the present invention relates to use of a pyrethroid insecticide for reducing phytotoxicity in crops treated with a herbicide selected from the group consisting of 2,4-D esters and amines, 2,4-MCPA, acetochlor, acifluorfen, clomazone, aclonifen, AE0172747, alachlor, amidosulfuron, aminopyralid, aminotriazole, ammonium thiocyanate, anilifos, azimsulfuron, benfuresate, bensulfuron-methyl, bentazone, benthiocarb, benzobicyclon, bifenox, bispyribac-sodium, butachlor, butafenacil, butralin, cafenstrole, carbetamide, carfentrazone-ethyl, chlorflurenol, chlorimuron, cinosulfuron, clethodim, clopyralid, cloransulam-methyl, cyclosulfamuron, cycloxydim, cyhalofop-butyl, dicamba, dichlobenil, dichlorprop-P, diclosulam, diflufenican, diflufenzopyr, dimethenamid, dimethenamid-p, diquat, dithiopyr, diuron, EK2612, EPTC, esprocarb, ET-751, ethoxysulfuron, ethbenzanid, F7967, fenoxaprop, fenoxaprop-ethyl, fenoxaprop-ethyl + isoxidifen-ethyl, fentrazamide, flazasulfuron, florasulam, fluazifop, fluazifop-P-butyl, flucetosulfuron, flufenacet, flufenpyr-ethyl, flumetsulam, flumiclorac-pentyl, flumioxazin, fluometuron, flupyrsulfuron, fluroxypyr, fluroxypyr esters and salts, fomesafen, foramsulfuron, fumiclorac, glufosinate, glufosinate-ammonium, glyphosate , halosulfuron, haloxyfop-methyl, haloxyfop-R, HOK-201, imazamethabenz, imazamox, imazapic, imazapyr, imazaquin, imazethapyr, imazosulfuron, indanofan, indaziflam, iodosulfuron, ioxynil, IR 5790, isoproturon, isoxaben, isoxaflutole, KUH-071, lactofen, linuron, MCPA, MCPA ester & amine, mecoprop-P, mefenacet, mesosulfuron, mesotrione, metamifop, metolachlor, metosulam, metribuzin, metsulfuron, molinate, MSMA, napropamide, NC-620, nicosulfuron, norflurazon, OK-9701, orthosulfamuron, oryzalin, oxadiargyl, oxadiazon, oxazichlomefone, oxyfluorfen, paraquat, pendimethalin, pentoxazone, pethoxamid, picloram, picolinafen, piperophos, pretilachlor, profoxydim, propachlor, propanil, propyzamide, prosulfocarb, prosulfuron, pyraclonil, pyrazogyl, pyrazosulfuron, pyribenzoxim, pyriftalid, pyrimisulfan (KUH-021), pyriminobac-methyl, primisulfuron, propyrisulfuron (TH-547), pyroxsulam, pyroxasulfone (KIH-485), quinclorac, quizalofop-ethyl-D, S-3252, saflufenacil, sethoxydim, SL-0401, SL-0402, s-metolachlor, sulcotrione, sulfentrazone, sulfosate, tebuthiuron, tefuryltrione (AVH-301), thiazopyr, thiobencarb, triclopyr, triclopyr esters and amine, and tritosulfuron.
wherein the pyrethroid insecticide is selected from the group consisting of acrinathrin, allethrin, bioallethrin, esdépalléthrine, barthrin, bifenthrin, kappa-bifenthrin, bioethanomethrin, brofenvalerate, brofluthrinate, bromethrin, butethrin, chlorempenthrin, cyclethrin, cycloprothrin, cyfluthrin, beta-cyfluthrin, cyhalothrin, gamma-cyhalothrin, lambda-cyhalothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, cyphenothrin, deltamethrin, dimefluthrin, dimethrin, empenthrin, d-fanshiluquebingjuzhi, chloroprallethrin, fenfluthrin, fenpirithrin, fenpropathrin, fenvalerate, esfenvalerate, flucythrinate, fluvalinate, tau-fluvalinate, furamethrin, furethrin, heptafluthrin, imiprothrin, japothrins, kadethrin, methothrin, metofluthrin, epsilon-metofluthrin, momfluorothrin, epsilon-momfluorothrin, pentmethrin, permethrin, biopermethrin, transpermethrin, phenothrin, prallethrin, profluthrin, proparthrin, pyresmethrin, renofluthrin, meperfluthrin, resmethrin, bioresmethrin, cismethrin, tefluthrin, kappa-tefluthrin, terallethrin, tetramethrin, tetramethylfluthrin, tralocythrin, tralomethrin, transfluthrin, valerate, etofenprox, flufenprox, halfenprox, protrifenbute, silafluofen, sulfoxime, and thiofluoximate.
In an embodiment, the preferred phytotoxic herbicide is clomazone.
In an embodiment, the preferred phytotoxic herbicide is acifluorfen.
In an embodiment, the preferred phytotoxic herbicide is bensulfuron-methyl.
In an embodiment, the preferred phytotoxic herbicide is carfentrazone-ethyl.
In an embodiment, the preferred phytotoxic herbicide is diflufenican.
In an embodiment, the preferred phytotoxic herbicide is fluroxypyr.
In an embodiment, the preferred phytotoxic herbicide is fomesafen.
In an embodiment, the preferred phytotoxic herbicide is glufosinate.
In an embodiment, the preferred phytotoxic herbicide is glyphosate.
In an embodiment, the preferred phytotoxic herbicide is halosulfuron.
In an embodiment, the preferred phytotoxic herbicide is imazamethabenz.
In an embodiment, the preferred phytotoxic herbicide is imazamox.
In an embodiment, the preferred phytotoxic herbicide is imazapic.
In an embodiment, the preferred phytotoxic herbicide is imazapyr.
In an embodiment, the preferred phytotoxic herbicide is imazaquin.
In an embodiment, the preferred phytotoxic herbicide is imazethapyr.
In an embodiment, the preferred phytotoxic herbicide is mefenacet.
In an embodiment, the preferred phytotoxic herbicide is mesotrione.
In an embodiment, the preferred phytotoxic herbicide is metolachlor.
In an embodiment, the preferred phytotoxic herbicide is metribuzin.
In an embodiment, the preferred phytotoxic herbicide is napropamide.
In an embodiment, the preferred phytotoxic herbicide is pendimethalin.
In an embodiment, the preferred phytotoxic herbicide is pretilachlor.
In an embodiment, the preferred phytotoxic herbicide is pyrazosulfuron.
In an embodiment, the preferred phytotoxic herbicide is quinclorac.
In an embodiment, the preferred phytotoxic herbicide is saflufenacil.
In an embodiment, the preferred phytotoxic herbicide is S-metolachlor.
In an embodiment, the preferred phytotoxic herbicide is sulfentrazone.
Thus, in this embodiment, the present invention provides the use of a pyrethroid insecticide for reducing phytotoxicity in crops treated with clomazone, wherein the pyrethroid insecticide is selected from the group consisting of acrinathrin, allethrin, bioallethrin, esdépalléthrine, barthrin, bifenthrin, kappa-bifenthrin, bioethanomethrin, brofenvalerate, brofluthrinate, bromethrin, butethrin, chlorempenthrin, cyclethrin, cycloprothrin, cyfluthrin, beta-cyfluthrin, cyhalothrin, gamma-cyhalothrin, lambda-cyhalothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, cyphenothrin, deltamethrin, dimefluthrin, dimethrin, empenthrin, d-fanshiluquebingjuzhi, chloroprallethrin, fenfluthrin, fenpirithrin, fenpropathrin, fenvalerate, esfenvalerate, flucythrinate, fluvalinate, tau-fluvalinate, furamethrin, furethrin, heptafluthrin, imiprothrin, japothrins, kadethrin, methothrin, metofluthrin, epsilon-metofluthrin, momfluorothrin, epsilon-momfluorothrin, pentmethrin, permethrin, biopermethrin, transpermethrin, phenothrin, prallethrin, profluthrin, proparthrin, pyresmethrin, renofluthrin, meperfluthrin, resmethrin, bioresmethrin, cismethrin, tefluthrin, kappa-tefluthrin, terallethrin, tetramethrin, tetramethylfluthrin, tralocythrin, tralomethrin, transfluthrin, valerate, etofenprox, flufenprox, halfenprox, protrifenbute, silafluofen, sulfoxime, and thiofluoximate.
In an embodiment, the preferred pyrethroid insecticide is lambda-cyhalothrin.
Thus, in this embodiment, the present invention provides the use of lambda-cyhalothrin for reducing phytotoxicity in crops treated with clomazone.
In another embodiment, the present invention provides use of a pyrethroid insecticide in a combination with at least another insecticide for reducing phytotoxicity in crops treated with clomazone.
Thus, in this embodiment, the present invention provides the use of a pyrethroid insecticide in combination with at least another insecticide for reducing phytotoxicity in crops treated with clomazone, wherein the pyrethroid insecticide is selected from the group consisting of acrinathrin, allethrin, bioallethrin, esdépalléthrine, barthrin, bifenthrin, kappa-bifenthrin, bioethanomethrin, brofenvalerate, brofluthrinate, bromethrin, butethrin, chlorempenthrin, cyclethrin, cycloprothrin, cyfluthrin, beta-cyfluthrin, cyhalothrin, gamma-cyhalothrin, lambda-cyhalothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, cyphenothrin, deltamethrin, dimefluthrin, dimethrin, empenthrin, d-fanshiluquebingjuzhi, chloroprallethrin, fenfluthrin, fenpirithrin, fenpropathrin, fenvalerate, esfenvalerate, flucythrinate, fluvalinate, tau-fluvalinate, furamethrin, furethrin, heptafluthrin, imiprothrin, japothrins, kadethrin, methothrin, metofluthrin, epsilon-metofluthrin, momfluorothrin, epsilon-momfluorothrin, pentmethrin, permethrin, biopermethrin, transpermethrin, phenothrin, prallethrin, profluthrin, proparthrin, pyresmethrin, renofluthrin, meperfluthrin, resmethrin, bioresmethrin, cismethrin, tefluthrin, kappa-tefluthrin, terallethrin, tetramethrin, tetramethylfluthrin, tralocythrin, tralomethrin, transfluthrin, valerate, etofenprox, flufenprox, halfenprox, protrifenbute, silafluofen, sulfoxime, and thiofluoximate.
In an embodiment, said another insecticide is selected from the group consisting of a neonicotinoid insecticide, a thiazole insecticide and a thiazolidine insecticide for reducing phytotoxicity in crops treated with clomazone.
Thus, in this embodiment, the present invention provides the use of a pyrethroid insecticide in combination with at least one neonicotinoid insecticide for reducing phytotoxicity in crops treated with clomazone, wherein the pyrethroid insecticide is selected from the group consisting of acrinathrin, allethrin, bioallethrin, esdépalléthrine, barthrin, bifenthrin, kappa-bifenthrin, bioethanomethrin, brofenvalerate, brofluthrinate, bromethrin, butethrin, chlorempenthrin, cyclethrin, cycloprothrin, cyfluthrin, beta-cyfluthrin, cyhalothrin, gamma-cyhalothrin, lambda-cyhalothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, cyphenothrin, deltamethrin, dimefluthrin, dimethrin, empenthrin, d-fanshiluquebingjuzhi, chloroprallethrin, fenfluthrin, fenpirithrin, fenpropathrin, fenvalerate, esfenvalerate, flucythrinate, fluvalinate, tau-fluvalinate, furamethrin, furethrin, heptafluthrin, imiprothrin, japothrins, kadethrin, methothrin, metofluthrin, epsilon-metofluthrin, momfluorothrin, epsilon-momfluorothrin, pentmethrin, permethrin, biopermethrin, transpermethrin, phenothrin, prallethrin, profluthrin, proparthrin, pyresmethrin, renofluthrin, meperfluthrin, resmethrin, bioresmethrin, cismethrin, tefluthrin, kappa-tefluthrin, terallethrin, tetramethrin, tetramethylfluthrin, tralocythrin, tralomethrin, transfluthrin, valerate, etofenprox, flufenprox, halfenprox, protrifenbute, silafluofen, sulfoxime, and thiofluoximate; and wherein the neonicotinoid insecticide is selected from the group consisting of clothianidin, dinotefuran, imidacloprid, imidaclothiz, thiamethoxam, nitenpyram, nithiazine, acetamiprid, nitenpyram, paichongding, and thiacloprid.
In an embodiment, the present invention provides the use of bifenthrin in combination with imidacloprid for reducing phytotoxicity in crops treated with clomazone.
In an embodiment, the present invention provides the use of bifenthrin in combination with thiamethoxam for reducing phytotoxicity in crops treated with clomazone.
In an embodiment, the present invention provides the use of bifenthrin in combination with acetamiprid for reducing phytotoxicity in crops treated with clomazone.
In an embodiment, the present invention provides the use of bifenthrin in combination with thiacloprid for reducing phytotoxicity in crops treated with clomazone.
In an embodiment, the present invention provides the use of cyhalothrin in combination with imidacloprid for reducing phytotoxicity in crops treated with clomazone.
In an embodiment, the present invention provides the use of cyhalothrin in combination with thiamethoxam for reducing phytotoxicity in crops treated with clomazone.
In an embodiment, the present invention provides the use of cyhalothrin in combination with acetamiprid for reducing phytotoxicity in crops treated with clomazone.
In an embodiment, the present invention provides the use of cyhalothrin in combination with thiacloprid for reducing phytotoxicity in crops treated with clomazone.
In an embodiment, the present invention provides the use of gamma-cyhalothrin in combination with imidacloprid for reducing phytotoxicity in crops treated with clomazone.
In an embodiment, the present invention provides the use of gamma-cyhalothrin in combination with thiamethoxam for reducing phytotoxicity in crops treated with clomazone.
In an embodiment, the present invention provides the use of gamma-cyhalothrin in combination with acetamiprid for reducing phytotoxicity in crops treated with clomazone.
In an embodiment, the present invention provides the use of gamma-cyhalothrin in combination with thiacloprid for reducing phytotoxicity in crops treated with clomazone.
In an embodiment, the present invention provides the use of lambda-cyhalothrin in combination with imidacloprid for reducing phytotoxicity in crops treated with clomazone.
In an embodiment, the present invention provides the use of lambda-cyhalothrin in combination with thiamethoxam for reducing phytotoxicity in crops treated with clomazone.
In an embodiment, the present invention provides the use of lambda-cyhalothrin in an amount of about 37.5 g/L in combination with thiamethoxam in an amount of about 210 g/L for reducing phytotoxicity in crops treated with clomazone.
In an embodiment, the present invention provides the use of lambda-cyhalothrin in combination with acetamiprid for reducing phytotoxicity in crops treated with clomazone.
In an embodiment, the present invention provides the use of lambda-cyhalothrin in combination with thiacloprid for reducing phytotoxicity in crops treated with clomazone.
In an embodiment, the present invention provides the use of cypermethrin in combination with imidacloprid for reducing phytotoxicity in crops treated with clomazone.
In an embodiment, the present invention provides the use of cypermethrin in combination with thiamethoxam for reducing phytotoxicity in crops treated with clomazone.
In an embodiment, the present invention provides the use of cypermethrin in combination with acetamiprid for reducing phytotoxicity in crops treated with clomazone.
In an embodiment, the present invention provides the use of cypermethrin in combination with thiacloprid for reducing phytotoxicity in crops treated with clomazone.
In an embodiment, the present invention provides the use of alpha-cypermethrin in combination with imidacloprid for reducing phytotoxicity in crops treated with clomazone.
In an embodiment, the present invention provides the use of alpha-cypermethrin in combination with thiamethoxam for reducing phytotoxicity in crops treated with clomazone.
In an embodiment, the present invention provides the use of alpha-cypermethrin in combination with acetamiprid for reducing phytotoxicity in crops treated with clomazone.
In an embodiment, the present invention provides the use of alpha-cypermethrin in combination with thiacloprid for reducing phytotoxicity in crops treated with clomazone.
In an embodiment, the present invention provides the use of beta-cypermethrin in combination with imidacloprid for reducing phytotoxicity in crops treated with clomazone.
In an embodiment, the present invention provides the use of beta-cypermethrin in combination with thiamethoxam for reducing phytotoxicity in crops treated with clomazone.
In an embodiment, the present invention provides the use of beta-cypermethrin in combination with acetamiprid for reducing phytotoxicity in crops treated with clomazone.
In an embodiment, the present invention provides the use of beta-cypermethrin in combination with thiacloprid for reducing phytotoxicity in crops treated with clomazone.
In an embodiment, the present invention provides the use of permethrin in combination with imidacloprid for reducing phytotoxicity in crops treated with clomazone.
In an embodiment, the present invention provides the use of permethrin in combination with thiamethoxam for reducing phytotoxicity in crops treated with clomazone.
In an embodiment, the present invention provides the use of permethrin in combination with acetamiprid for reducing phytotoxicity in crops treated with clomazone.
In an embodiment, the present invention provides the use of permethrin in combination with thiacloprid for reducing phytotoxicity in crops treated with clomazone.
In an embodiment, the present invention provides the use of a pyrethroid insecticide in combination with a thiazole insecticide selected from clothianidin and imidaclothiz for reducing phytotoxicity in crops treated with clomazone, wherein the pyrethroid insecticide is selected from the group consisting of acrinathrin, allethrin, bioallethrin, esdépalléthrine, barthrin, bifenthrin, kappa-bifenthrin, bioethanomethrin, brofenvalerate, brofluthrinate, bromethrin, butethrin, chlorempenthrin, cyclethrin, cycloprothrin, cyfluthrin, beta-cyfluthrin, cyhalothrin, gamma-cyhalothrin, lambda-cyhalothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, cyphenothrin, deltamethrin, dimefluthrin, dimethrin, empenthrin, d-fanshiluquebingjuzhi, chloroprallethrin, fenfluthrin, fenpirithrin, fenpropathrin, fenvalerate, esfenvalerate, flucythrinate, fluvalinate, tau-fluvalinate, furamethrin, furethrin, heptafluthrin, imiprothrin, japothrins, kadethrin, methothrin, metofluthrin, epsilon-metofluthrin, momfluorothrin, epsilon-momfluorothrin, pentmethrin, permethrin, biopermethrin, transpermethrin, phenothrin, prallethrin, profluthrin, proparthrin, pyresmethrin, renofluthrin, meperfluthrin, resmethrin, bioresmethrin, cismethrin, tefluthrin, kappa-tefluthrin, terallethrin, tetramethrin, tetramethylfluthrin, tralocythrin, tralomethrin, transfluthrin, valerate, etofenprox, flufenprox, halfenprox, protrifenbute, silafluofen, sulfoxime, and thiofluoximate.
In an embodiment, the present invention provides the use of a pyrethroid insecticide in combination with a thiazolidine insecticide selected from tazimcarb and thiacloprid for reducing phytotoxicity in crops treated with clomazone, wherein the pyrethroid insecticide is selected from the group consisting of acrinathrin, allethrin, bioallethrin, esdépalléthrine, barthrin, bifenthrin, kappa-bifenthrin, bioethanomethrin, brofenvalerate, brofluthrinate, bromethrin, butethrin, chlorempenthrin, cyclethrin, cycloprothrin, cyfluthrin, beta-cyfluthrin, cyhalothrin, gamma-cyhalothrin, lambda-cyhalothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, cyphenothrin, deltamethrin, dimefluthrin, dimethrin, empenthrin, d-fanshiluquebingjuzhi, chloroprallethrin, fenfluthrin, fenpirithrin, fenpropathrin, fenvalerate, esfenvalerate, flucythrinate, fluvalinate, tau-fluvalinate, furamethrin, furethrin, heptafluthrin, imiprothrin, japothrins, kadethrin, methothrin, metofluthrin, epsilon-metofluthrin, momfluorothrin, epsilon-momfluorothrin, pentmethrin, permethrin, biopermethrin, transpermethrin, phenothrin, prallethrin, profluthrin, proparthrin, pyresmethrin, renofluthrin, meperfluthrin, resmethrin, bioresmethrin, cismethrin, tefluthrin, kappa-tefluthrin, terallethrin, tetramethrin, tetramethylfluthrin, tralocythrin, tralomethrin, transfluthrin, valerate, etofenprox, flufenprox, halfenprox, protrifenbute, silafluofen, sulfoxime, and thiofluoximate.
In an embodiment, the preferred herbicide is clomazone.
In preferred embodiment, the present invention provides use of a pyrethroid insecticide in combination with a neonicotinoid insecticide for reducing phytotoxicity in crops treated with clomazone.
In another preferred embodiment, the present invention provides use of a pyrethroid insecticide in combination with thiamethoxam for reducing phytotoxicity in crops treated with clomazone.
In most preferred embodiment, the present invention provides use of a lambda cyhalothrin in combination with thiamethoxam for reducing phytotoxicity in crops treated with clomazone.
In accordance with another aspect of this invention, certain pyrethroid insecticide are combined with clomazone either by admixture prior to application, or by separate application. The combined application not only safens the crops against phytotoxic effects of clomazone but also combats insects and other pests to which the crops may be subject.
In another aspect, the present invention may provide a method of reducing the phytotoxic effect of herbicide on crops which are treated with said herbicide, the method comprising treating the crop with at least one pyrethroid insecticide.
In another emboidment the pyrethroid insecticide is selected form acrinathrin, allethrin, bioallethrin, esdépalléthrine, barthrin, bifenthrin, kappa-bifenthrin, bioethanomethrin, brofenvalerate, brofluthrinate, bromethrin, butethrin, chlorempenthrin, cyclethrin, cycloprothrin, cyfluthrin, beta-cyfluthrin, cyhalothrin, gamma-cyhalothrin, lambda-cyhalothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, cyphenothrin, deltamethrin, dimefluthrin, dimethrin, empenthrin, d-fanshiluquebingjuzhi, chloroprallethrin, fenfluthrin, fenpirithrin, fenpropathrin, fenvalerate, esfenvalerate, flucythrinate, fluvalinate, tau-fluvalinate, furamethrin, furethrin, heptafluthrin, imiprothrin, japothrins, kadethrin, methothrin, metofluthrin, epsilon-metofluthrin, momfluorothrin, epsilon-momfluorothrin, pentmethrin, permethrin, biopermethrin, transpermethrin, phenothrin, prallethrin, profluthrin, proparthrin, pyresmethrin, renofluthrin, meperfluthrin, resmethrin, bioresmethrin, cismethrin, tefluthrin, kappa-tefluthrin, terallethrin, tetramethrin, tetramethylfluthrin, tralocythrin, tralomethrin, transfluthrin, valerate, etofenprox, flufenprox, halfenprox, protrifenbute, silafluofen, sulfoxime, thiofluoximate, preferably Lambda cyhalothrin.
In yet another aspect, the present invention may provide a method of reducing the phytotoxic effect of herbicide on crops which are treated with said herbicide, the method comprising treating the crop with a pyrethroid insecticide and at least another insecticide.
In yet another aspect, the present invention may provide a method of reducing the phytotoxic effect of herbicide on crops which are treated with said herbicide, said method comprising treating the crop and/or seed with at least one herbicide in combination with a pyrethroid insecticide and at least another insecticide selected from a neonicotinoid insecticide, a thiazole insecticide and a thiazolidine insecticide.
The neonicotinoid insecticide is selected from clothianidin, dinotefuran, imidacloprid, imidaclothiz, thiamethoxam, nitenpyram, nithiazine, acetamiprid, imidacloprid, nitenpyram, paichongding, thiacloprid preferbaly thiamethoxam.
The thiazole insecticide is selected from clothianidin and imidaclothiz,
The thiazolidine insecticide is selected from tazimcarb and thiacloprid.
The phytotoxically active herbicides are preferably selected from 2,4-D esters and amines, 2,4-MCPA, acetochlor, acifluorfen, clomazone, aclonifen, AE0172747, alachlor, amidosulfuron, aminopyralid, aminotriazole, ammonium thiocyanate, anilifos, azimsulfuron, benfuresate, bensulfuron-methyl, bentazone, benthiocarb, benzobicyclon, bifenox, bispyribac-sodium, butachlor, butafenacil, butralin, cafenstrole, carbetamide, carfentrazone-ethyl, chlorflurenol, chlorimuron, cinosulfuron, clethodim, clopyralid, cloransulam-methyl, cyclosulfamuron, cycloxydim, cyhalofop-butyl, dicamba, dichlobenil, dichlorprop-P, diclosulam, diflufenican, diflufenzopyr, dimethenamid, dimethenamid-p, diquat, dithiopyr, diuron, EK2612, EPTC, esprocarb, ET-751, ethoxysulfuron, ethbenzanid, F7967, fenoxaprop, fenoxaprop-ethyl, fenoxaprop-ethyl + isoxidifen-ethyl, fentrazamide, flazasulfuron, florasulam, fluazifop, fluazifop-P-butyl, flucetosulfuron, flufenacet, flufenpyr-ethyl, flumetsulam, flumiclorac-pentyl, flumioxazin, fluometuron, flupyrsulfuron, fluroxypyr, fluroxypyr esters and salts, fomesafen, foramsulfuron, fumiclorac, glufosinate, glufosinate-ammonium, glyphosate , halosulfuron, haloxyfop-methyl, haloxyfop-R, HOK-201, imazamethabenz, imazamox, imazapic, imazapyr, imazaquin, imazethapyr, imazosulfuron, indanofan, indaziflam, iodosulfuron, ioxynil, IR 5790, isoproturon, isoxaben, isoxaflutole, KUH-071, lactofen, linuron, MCPA, MCPA ester & amine, mecoprop-P, mefenacet, mesosulfuron, mesotrione, metamifop, metolachlor, metosulam, metribuzin, metsulfuron, molinate, MSMA, napropamide, NC-620, nicosulfuron, norflurazon, OK-9701, orthosulfamuron, oryzalin, oxadiargyl, oxadiazon, oxazichlomefone, oxyfluorfen, paraquat, pendimethalin, pentoxazone, pethoxamid, picloram, picolinafen, piperophos, pretilachlor, profoxydim, propachlor, propanil, propyzamide, prosulfocarb, prosulfuron, pyraclonil, pyrazogyl, pyrazosulfuron, pyribenzoxim, pyriftalid, pyrimisulfan (KUH-021), pyriminobac-methyl, primisulfuron, propyrisulfuron (TH-547), pyroxsulam, pyroxasulfone (KIH-485), quinclorac, quizalofop-ethyl-D, S-3252, saflufenacil, sethoxydim, SL-0401, SL-0402, s-metolachlor, sulcotrione, sulfentrazone, sulfosate, tebuthiuron, tefuryltrione (AVH-301), thiazopyr, thiobencarb, triclopyr, triclopyr esters and amine, and tritosulfuron preferably clomazone.
In preferred embodiment, the present invention provides use of a pyrethroid insecticide in combination with neonicotinoid insecticide for reducing phytotoxicity in crops treated with clomazone.
In another preferred embodiment, the present invention provides use of a pyrethroid insecticide in combination with thiamethoxam for reducing phytotoxicity in crops treated with clomazone.
In most preferred embodiment, the present invention provides use of a lambda cyhalothrin in combination with thiamethoxam for reducing phytotoxicity in crops treated with clomazone.
The preferred crop wherein the phytotoxicity of clomazone is reduce is selected from soybean, maize, wheat, triticale, rye, oats, barley, oilseed rape, millet/sorghum, rice, sunflower, cotton, sugar beet, stone fruit, pome fruit, citrus fruit, banana, strawberry, blueberry, almond, grape, mango, pawpaw, peanut, potato, tomato, capsicum, cucumber, pumpkin/squash, melon, watermelon, garlic, onion, carrot, cabbage, bean, vegetable pea and fodder pea, lentil, lucerne, clover, flax, elephant grass (Miscanthus), grass, lettuce, sugar cane, tea, tobacco and coffee. The plants can be non-transgenic or transgenic in nature.
In an embodiment herbicide and the safener insecticides of the present invention are formulated and applied in accordance with procedures standard in herbicidal treatments as modified by the labels established for each of the active ingredients. The herbicides and the safener are applied in dilute form with an agriculturally acceptable, relatively inert, solid or liquid carrier to the locus where herbicidal effect and safening are needed. The formulation and mode of application of an agricultural chemical may affect activity in a given application, the herbicide and safener may be formulated separately or in admixture as emulsifiable concentrates (EC's), as granules preferably of relatively large particle size, as wettable powders, as solutions or suspensions, or in other forms.
In a preferred embodiment the safener is applied prior to application of the clomazone, typically in a preemergent, post emergent or pre-plant incorporated manner, alone or as a tank mix with herbicide.
In another preferred embodiment, the safener according to the present invention may also be applied to seeds of crops prior to or simultaneously with planting.
In another aspect, the present invention provides a combination comprising at least one herbicide and at least one pyrethroid insecticide.
In another aspect, the present invention provides a combination comprising at least one herbicide, at least one pyrethroid insecticide and at least another insecticide.
In another aspect, the present invention provides a combination comprising at least one herbicide, at least one pyrethroid insecticide, and at least another insecticide selected from the group consisting of a neonicotinoid insecticide, a thiazole insecticide and a thiazolidine insecticide.
In another embodiment the pyrethroid insecticide is selected from the group consisting of acrinathrin, allethrin, bioallethrin, esdépalléthrine, barthrin, bifenthrin, kappa-bifenthrin, bioethanomethrin, brofenvalerate, brofluthrinate, bromethrin, butethrin, chlorempenthrin, cyclethrin, cycloprothrin, cyfluthrin, beta-cyfluthrin, cyhalothrin, gamma-cyhalothrin, lambda-cyhalothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, cyphenothrin, deltamethrin, dimefluthrin, dimethrin, empenthrin, d-fanshiluquebingjuzhi, chloroprallethrin, fenfluthrin, fenpirithrin, fenpropathrin, fenvalerate, esfenvalerate, flucythrinate, fluvalinate, tau-fluvalinate, furamethrin, furethrin, heptafluthrin, imiprothrin, japothrins, kadethrin, methothrin, metofluthrin, epsilon-metofluthrin, momfluorothrin, epsilon-momfluorothrin, pentmethrin, permethrin, biopermethrin, transpermethrin, phenothrin, prallethrin, profluthrin, proparthrin, pyresmethrin, renofluthrin, meperfluthrin, resmethrin, bioresmethrin, cismethrin, tefluthrin, kappa-tefluthrin, terallethrin, tetramethrin, tetramethylfluthrin, tralocythrin, tralomethrin, transfluthrin, valerate, etofenprox, flufenprox, halfenprox, protrifenbute, silafluofen, sulfoxime, thiofluoximate.
In an embodiment, the preferred pyrethroid insecticide is lambda-cyhalothrin.
In another embodiment, the present invention provides a combination comprising a pyrethroid insecticide, at least another insecticide and a herbicide.
In an embodiment, said another insecticide is selected from the group consisting of a neonicotinoid insecticide, a thiazole insecticide and a thiazolidine insecticide.
The neonicotinoid insecticide is selected from clothianidin, dinotefuran, imidacloprid, imidaclothiz, thiamethoxam, nitenpyram, nithiazine, acetamiprid, imidacloprid, nitenpyram, paichongding, and thiacloprid.
In an embodiment, the preferred neonicotinoid insecticide is thiamethoxam.
The thiazole insecticide is selected from clothianidin and imidaclothiz,.
The thiazolidine insecticide is selected from tazimcarb and thiacloprid.
The phytotoxically active herbicides are preferably selected from 2,4-D esters and amines, 2,4-MCPA, acetochlor, acifluorfen, clomazone, aclonifen, AE0172747, alachlor, amidosulfuron, aminopyralid, aminotriazole, ammonium thiocyanate, anilifos, azimsulfuron, benfuresate, bensulfuron-methyl, bentazone, benthiocarb, benzobicyclon, bifenox, bispyribac-sodium, butachlor, butafenacil, butralin, cafenstrole, carbetamide, carfentrazone-ethyl, chlorflurenol, chlorimuron, cinosulfuron, clethodim, clopyralid, cloransulam-methyl, cyclosulfamuron, cycloxydim, cyhalofop-butyl, dicamba, dichlobenil, dichlorprop-P, diclosulam, diflufenican, diflufenzopyr, dimethenamid, dimethenamid-p, diquat, dithiopyr, diuron, EK2612, EPTC, esprocarb, ET-751, ethoxysulfuron, ethbenzanid, F7967, fenoxaprop, fenoxaprop-ethyl, fenoxaprop-ethyl + isoxidifen-ethyl, fentrazamide, flazasulfuron, florasulam, fluazifop, fluazifop-P-butyl, flucetosulfuron, flufenacet, flufenpyr-ethyl, flumetsulam, flumiclorac-pentyl, flumioxazin, fluometuron, flupyrsulfuron, fluroxypyr, fluroxypyr esters and salts, fomesafen, foramsulfuron, fumiclorac, glufosinate, glufosinate-ammonium, glyphosate , halosulfuron, haloxyfop-methyl, haloxyfop-R, HOK-201, imazamethabenz, imazamox, imazapic, imazapyr, imazaquin, imazethapyr, imazosulfuron, indanofan, indaziflam, iodosulfuron, ioxynil, IR 5790, isoproturon, isoxaben, isoxaflutole, KUH-071, lactofen, linuron, MCPA, MCPA ester & amine, mecoprop-P, mefenacet, mesosulfuron, mesotrione, metamifop, metolachlor, metosulam, metribuzin, metsulfuron, molinate, MSMA, napropamide, NC-620, nicosulfuron, norflurazon, OK-9701, orthosulfamuron, oryzalin, oxadiargyl, oxadiazon, oxazichlomefone, oxyfluorfen, paraquat, pendimethalin, pentoxazone, pethoxamid, picloram, picolinafen, piperophos, pretilachlor, profoxydim, propachlor, propanil, propyzamide, prosulfocarb, prosulfuron, pyraclonil, pyrazogyl, pyrazosulfuron, pyribenzoxim, pyriftalid, pyrimisulfan (KUH-021), pyriminobac-methyl, primisulfuron, propyrisulfuron (TH-547), pyroxsulam, pyroxasulfone (KIH-485), quinclorac, quizalofop-ethyl-D, S-3252, saflufenacil, sethoxydim, SL-0401, SL-0402, s-metolachlor, sulcotrione, sulfentrazone, sulfosate, tebuthiuron, tefuryltrione (AVH-301), thiazopyr, thiobencarb, triclopyr, triclopyr esters and amine, and tritosulfuron.
Thus, in an embodiment, the present invention provides a combination comprising a pyrethroid insecticide and a herbicide selected from the group consisting of 2,4-D esters and amines, 2,4-MCPA, acetochlor, acifluorfen, clomazone, aclonifen, AE0172747, alachlor, amidosulfuron, aminopyralid, aminotriazole, ammonium thiocyanate, anilifos, azimsulfuron, benfuresate, bensulfuron-methyl, bentazone, benthiocarb, benzobicyclon, bifenox, bispyribac-sodium, butachlor, butafenacil, butralin, cafenstrole, carbetamide, carfentrazone-ethyl, chlorflurenol, chlorimuron, cinosulfuron, clethodim, clopyralid, cloransulam-methyl, cyclosulfamuron, cycloxydim, cyhalofop-butyl, dicamba, dichlobenil, dichlorprop-P, diclosulam, diflufenican, diflufenzopyr, dimethenamid, dimethenamid-p, diquat, dithiopyr, diuron, EK2612, EPTC, esprocarb, ET-751, ethoxysulfuron, ethbenzanid, F7967, fenoxaprop, fenoxaprop-ethyl, fenoxaprop-ethyl + isoxidifen-ethyl, fentrazamide, flazasulfuron, florasulam, fluazifop, fluazifop-P-butyl, flucetosulfuron, flufenacet, flufenpyr-ethyl, flumetsulam, flumiclorac-pentyl, flumioxazin, fluometuron, flupyrsulfuron, fluroxypyr, fluroxypyr esters and salts, fomesafen, foramsulfuron, fumiclorac, glufosinate, glufosinate-ammonium, glyphosate , halosulfuron, haloxyfop-methyl, haloxyfop-R, HOK-201, imazamethabenz, imazamox, imazapic, imazapyr, imazaquin, imazethapyr, imazosulfuron, indanofan, indaziflam, iodosulfuron, ioxynil, IR 5790, isoproturon, isoxaben, isoxaflutole, KUH-071, lactofen, linuron, MCPA, MCPA ester & amine, mecoprop-P, mefenacet, mesosulfuron, mesotrione, metamifop, metolachlor, metosulam, metribuzin, metsulfuron, molinate, MSMA, napropamide, NC-620, nicosulfuron, norflurazon, OK-9701, orthosulfamuron, oryzalin, oxadiargyl, oxadiazon, oxazichlomefone, oxyfluorfen, paraquat, pendimethalin, pentoxazone, pethoxamid, picloram, picolinafen, piperophos, pretilachlor, profoxydim, propachlor, propanil, propyzamide, prosulfocarb, prosulfuron, pyraclonil, pyrazogyl, pyrazosulfuron, pyribenzoxim, pyriftalid, pyrimisulfan (KUH-021), pyriminobac-methyl, primisulfuron, propyrisulfuron (TH-547), pyroxsulam, pyroxasulfone (KIH-485), quinclorac, quizalofop-ethyl-D, S-3252, saflufenacil, sethoxydim, SL-0401, SL-0402, s-metolachlor, sulcotrione, sulfentrazone, sulfosate, tebuthiuron, tefuryltrione (AVH-301), thiazopyr, thiobencarb, triclopyr, triclopyr esters and amine, and tritosulfuron;
wherein the pyrethroid insecticide is selected from the group consisting of acrinathrin, allethrin, bioallethrin, esdépalléthrine, barthrin, bifenthrin, kappa-bifenthrin, bioethanomethrin, brofenvalerate, brofluthrinate, bromethrin, butethrin, chlorempenthrin, cyclethrin, cycloprothrin, cyfluthrin, beta-cyfluthrin, cyhalothrin, gamma-cyhalothrin, lambda-cyhalothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, cyphenothrin, deltamethrin, dimefluthrin, dimethrin, empenthrin, d-fanshiluquebingjuzhi, chloroprallethrin, fenfluthrin, fenpirithrin, fenpropathrin, fenvalerate, esfenvalerate, flucythrinate, fluvalinate, tau-fluvalinate, furamethrin, furethrin, heptafluthrin, imiprothrin, japothrins, kadethrin, methothrin, metofluthrin, epsilon-metofluthrin, momfluorothrin, epsilon-momfluorothrin, pentmethrin, permethrin, biopermethrin, transpermethrin, phenothrin, prallethrin, profluthrin, proparthrin, pyresmethrin, renofluthrin, meperfluthrin, resmethrin, bioresmethrin, cismethrin, tefluthrin, kappa-tefluthrin, terallethrin, tetramethrin, tetramethylfluthrin, tralocythrin, tralomethrin, transfluthrin, valerate, etofenprox, flufenprox, halfenprox, protrifenbute, silafluofen, sulfoxime, and thiofluoximate.
In an embodiment, the preferred herbicide is clomazone.
Thus, in this embodiment, the present invention provides a combination comprising a pyrethroid insecticide and clomazone, wherein the pyrethroid insecticide is selected from the group consisting of acrinathrin, allethrin, bioallethrin, esdépalléthrine, barthrin, bifenthrin, kappa-bifenthrin, bioethanomethrin, brofenvalerate, brofluthrinate, bromethrin, butethrin, chlorempenthrin, cyclethrin, cycloprothrin, cyfluthrin, beta-cyfluthrin, cyhalothrin, gamma-cyhalothrin, lambda-cyhalothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, cyphenothrin, deltamethrin, dimefluthrin, dimethrin, empenthrin, d-fanshiluquebingjuzhi, chloroprallethrin, fenfluthrin, fenpirithrin, fenpropathrin, fenvalerate, esfenvalerate, flucythrinate, fluvalinate, tau-fluvalinate, furamethrin, furethrin, heptafluthrin, imiprothrin, japothrins, kadethrin, methothrin, metofluthrin, epsilon-metofluthrin, momfluorothrin, epsilon-momfluorothrin, pentmethrin, permethrin, biopermethrin, transpermethrin, phenothrin, prallethrin, profluthrin, proparthrin, pyresmethrin, renofluthrin, meperfluthrin, resmethrin, bioresmethrin, cismethrin, tefluthrin, kappa-tefluthrin, terallethrin, tetramethrin, tetramethylfluthrin, tralocythrin, tralomethrin, transfluthrin, valerate, etofenprox, flufenprox, halfenprox, protrifenbute, silafluofen, sulfoxime, and thiofluoximate.
In an embodiment, the preferred pyrethroid insecticide is lambda-cyhalothrin.
Thus, in this embodiment, the present invention provides a combination comprising lambda-cyhalothrin and clomazone.
In another embodiment, the present invention provides a combination comprising a pyrethroid insecticide, at least another insecticide and clomazone.
Thus, in this embodiment, the present invention provides a combination comprising a pyrethroid insecticide, at least another insecticide and clomazone, wherein the pyrethroid insecticide is selected from the group consisting of acrinathrin, allethrin, bioallethrin, esdépalléthrine, barthrin, bifenthrin, kappa-bifenthrin, bioethanomethrin, brofenvalerate, brofluthrinate, bromethrin, butethrin, chlorempenthrin, cyclethrin, cycloprothrin, cyfluthrin, beta-cyfluthrin, cyhalothrin, gamma-cyhalothrin, lambda-cyhalothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, cyphenothrin, deltamethrin, dimefluthrin, dimethrin, empenthrin, d-fanshiluquebingjuzhi, chloroprallethrin, fenfluthrin, fenpirithrin, fenpropathrin, fenvalerate, esfenvalerate, flucythrinate, fluvalinate, tau-fluvalinate, furamethrin, furethrin, heptafluthrin, imiprothrin, japothrins, kadethrin, methothrin, metofluthrin, epsilon-metofluthrin, momfluorothrin, epsilon-momfluorothrin, pentmethrin, permethrin, biopermethrin, transpermethrin, phenothrin, prallethrin, profluthrin, proparthrin, pyresmethrin, renofluthrin, meperfluthrin, resmethrin, bioresmethrin, cismethrin, tefluthrin, kappa-tefluthrin, terallethrin, tetramethrin, tetramethylfluthrin, tralocythrin, tralomethrin, transfluthrin, valerate, etofenprox, flufenprox, halfenprox, protrifenbute, silafluofen, sulfoxime, and thiofluoximate.
In an embodiment, said another insecticide is selected from the group consisting of a neonicotinoid insecticide, a thiazole insecticide and a thiazolidine insecticide.
Thus, in this embodiment, the present invention provides a combination comprising a pyrethroid insecticide, at least one neonicotinoid insecticide and clomazone,
wherein the pyrethroid insecticide is selected from the group consisting of acrinathrin, allethrin, bioallethrin, esdépalléthrine, barthrin, bifenthrin, kappa-bifenthrin, bioethanomethrin, brofenvalerate, brofluthrinate, bromethrin, butethrin, chlorempenthrin, cyclethrin, cycloprothrin, cyfluthrin, beta-cyfluthrin, cyhalothrin, gamma-cyhalothrin, lambda-cyhalothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, cyphenothrin, deltamethrin, dimefluthrin, dimethrin, empenthrin, d-fanshiluquebingjuzhi, chloroprallethrin, fenfluthrin, fenpirithrin, fenpropathrin, fenvalerate, esfenvalerate, flucythrinate, fluvalinate, tau-fluvalinate, furamethrin, furethrin, heptafluthrin, imiprothrin, japothrins, kadethrin, methothrin, metofluthrin, epsilon-metofluthrin, momfluorothrin, epsilon-momfluorothrin, pentmethrin, permethrin, biopermethrin, transpermethrin, phenothrin, prallethrin, profluthrin, proparthrin, pyresmethrin, renofluthrin, meperfluthrin, resmethrin, bioresmethrin, cismethrin, tefluthrin, kappa-tefluthrin, terallethrin, tetramethrin, tetramethylfluthrin, tralocythrin, tralomethrin, transfluthrin, valerate, etofenprox, flufenprox, halfenprox, protrifenbute, silafluofen, sulfoxime, and thiofluoximate; and
wherein the neonicotinoid insecticide is selected from the group consisting of clothianidin, dinotefuran, imidacloprid, imidaclothiz, thiamethoxam, nitenpyram, nithiazine, acetamiprid, nitenpyram, paichongding, and thiacloprid.
In an embodiment, the present invention provides a combination comprising bifenthrin, imidacloprid and clomazone.
In an embodiment, the present invention provides a combination comprising bifenthrin, thiamethoxam and clomazone.
In an embodiment, the present invention provides a combination comprising bifenthrin, acetamiprid and clomazone.
In an embodiment, the present invention provides a combination comprising bifenthrin, thiacloprid and clomazone.
In an embodiment, the present invention provides a combination comprising cyhalothrin, imidacloprid and clomazone.
In an embodiment, the present invention provides a combination comprising cyhalothrin, thiamethoxam and clomazone.
In an embodiment, the present invention provides a combination comprising cyhalothrin, acetamiprid and clomazone.
In an embodiment, the present invention provides a combination comprising cyhalothrin, thiacloprid and clomazone.
In an embodiment, the present invention provides a combination comprising gamma-cyhalothrin, imidacloprid and clomazone.
In an embodiment, the present invention provides a combination comprising gamma-cyhalothrin, thiamethoxam and clomazone.
In an embodiment, the present invention provides a combination comprising gamma-cyhalothrin, acetamiprid and clomazone.
In an embodiment, the present invention provides a combination comprising gamma-cyhalothrin, thiacloprid and clomazone.
In an embodiment, the present invention provides a combination comprising lambda-cyhalothrin, imidacloprid and clomazone.
In an embodiment, the present invention provides a combination comprising lambda-cyhalothrin, thiamethoxam and clomazone.
In an embodiment, the present invention provides a combination comprising lambda-cyhalothrin, acetamiprid and clomazone.
In an embodiment, the present invention provides a combination comprising lambda-cyhalothrin, thiacloprid and clomazone.
In an embodiment, the present invention provides a combination comprising cypermethrin, imidacloprid and clomazone.
In an embodiment, the present invention provides a combination comprising cypermethrin, thiamethoxam and clomazone.
In an embodiment, the present invention provides a combination comprising cypermethrin, acetamiprid and clomazone.
In an embodiment, the present invention provides a combination comprising cypermethrin, thiacloprid and clomazone.
In an embodiment, the present invention provides a combination comprising alpha-cypermethrin, imidacloprid and clomazone.
In an embodiment, the present invention provides a combination comprising alpha-cypermethrin, thiamethoxam and clomazone.
In an embodiment, the present invention provides a combination comprising alpha-cypermethrin, acetamiprid and clomazone.
In an embodiment, the present invention provides a combination comprising alpha-cypermethrin, thiacloprid and clomazone.
In an embodiment, the present invention provides a combination comprising beta-cypermethrin, imidacloprid and clomazone.
In an embodiment, the present invention provides a combination comprising beta-cypermethrin, thiamethoxam and clomazone.
In an embodiment, the present invention provides a combination comprising beta-cypermethrin, acetamiprid and clomazone.
In an embodiment, the present invention provides a combination comprising beta-cypermethrin, thiacloprid and clomazone.
In an embodiment, the present invention provides a combination comprising permethrin, imidacloprid and clomazone.
In an embodiment, the present invention provides a combination comprising permethrin, thiamethoxam and clomazone.
In an embodiment, the present invention provides a combination comprising permethrin, acetamiprid and clomazone.
In an embodiment, the present invention provides a combination comprising permethrin, thiacloprid and clomazone.
In an embodiment, the present invention provides a combination comprising a thiazole insecticide selected from clothianidin and imidaclothiz; clomazone; and a pyrethroid insecticide selected from the group consisting of acrinathrin, allethrin, bioallethrin, esdépalléthrine, barthrin, bifenthrin, kappa-bifenthrin, bioethanomethrin, brofenvalerate, brofluthrinate, bromethrin, butethrin, chlorempenthrin, cyclethrin, cycloprothrin, cyfluthrin, beta-cyfluthrin, cyhalothrin, gamma-cyhalothrin, lambda-cyhalothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, cyphenothrin, deltamethrin, dimefluthrin, dimethrin, empenthrin, d-fanshiluquebingjuzhi, chloroprallethrin, fenfluthrin, fenpirithrin, fenpropathrin, fenvalerate, esfenvalerate, flucythrinate, fluvalinate, tau-fluvalinate, furamethrin, furethrin, heptafluthrin, imiprothrin, japothrins, kadethrin, methothrin, metofluthrin, epsilon-metofluthrin, momfluorothrin, epsilon-momfluorothrin, pentmethrin, permethrin, biopermethrin, transpermethrin, phenothrin, prallethrin, profluthrin, proparthrin, pyresmethrin, renofluthrin, meperfluthrin, resmethrin, bioresmethrin, cismethrin, tefluthrin, kappa-tefluthrin, terallethrin, tetramethrin, tetramethylfluthrin, tralocythrin, tralomethrin, transfluthrin, valerate, etofenprox, flufenprox, halfenprox, protrifenbute, silafluofen, sulfoxime, and thiofluoximate.
In an embodiment, the present invention provides a combination comprising a thiazolidine insecticide selected from tazimcarb and thiacloprid; clomazone; and a pyrethroid insecticide selected from the group consisting of acrinathrin, allethrin, bioallethrin, esdépalléthrine, barthrin, bifenthrin, kappa-bifenthrin, bioethanomethrin, brofenvalerate, brofluthrinate, bromethrin, butethrin, chlorempenthrin, cyclethrin, cycloprothrin, cyfluthrin, beta-cyfluthrin, cyhalothrin, gamma-cyhalothrin, lambda-cyhalothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, cyphenothrin, deltamethrin, dimefluthrin, dimethrin, empenthrin, d-fanshiluquebingjuzhi, chloroprallethrin, fenfluthrin, fenpirithrin, fenpropathrin, fenvalerate, esfenvalerate, flucythrinate, fluvalinate, tau-fluvalinate, furamethrin, furethrin, heptafluthrin, imiprothrin, japothrins, kadethrin, methothrin, metofluthrin, epsilon-metofluthrin, momfluorothrin, epsilon-momfluorothrin, pentmethrin, permethrin, biopermethrin, transpermethrin, phenothrin, prallethrin, profluthrin, proparthrin, pyresmethrin, renofluthrin, meperfluthrin, resmethrin, bioresmethrin, cismethrin, tefluthrin, kappa-tefluthrin, terallethrin, tetramethrin, tetramethylfluthrin, tralocythrin, tralomethrin, transfluthrin, valerate, etofenprox, flufenprox, halfenprox, protrifenbute, silafluofen, sulfoxime, and thiofluoximate.
In an embodiment, the preferred herbicide is clomazone.
In preferred embodiment, the present invention provides a combination comprising at least one pyrethroid insecticide, at least one neonicotinoid insecticide and clomazone.
In another preferred embodiment, the present invention provides a combination comprising at least one pyrethroid insecticide; thiamethoxam and clomazone.
In most preferred embodiment, the present invention provides a combination comprising lambda cyhalothrin, thiamethoxam and clomazone.
Each of the aspects described hereinabove may have one or more embodiments.
For example, one or more aspects may include:
(i) the of a pyrethroid insecticide for reducing phytotoxicity in crops treated with a herbicide, or
(ii) the use of a combination comprising a pyrethroid insecticide and at least another insecticide for reducing phytotoxicity in crops treated with a herbicide, or
(iii) the use of a combination comprising a pyrethroid insecticide and at least another insecticide selected from the group consisting of a neonicotinoid insecticide, a thiazole insecticide and a thiazolidine insecticide for reducing phytotoxicity in crops treated with a herbicide, or
(iv) a method of reducing the phytotoxic effect of a herbicide on crops which are treated with said herbicide by treating the crop with the herbicide in combination with at least one pyrethroid insecticide, or
(v) a method of reducing the phytotoxic effect of a herbicide on crops which are treated with said herbicide by treating the crop with at least one herbicide in combination with a pyrethroid insecticide and at least another insecticide, or
(vi) a method of reducing the phytotoxic effect of a herbicide on crops which are treated with said herbicide by treating the crop and/or seed with at least one herbicide in combination with a pyrethroid insecticide and at least another insecticide selected from the group consisting of a neonicotinoid insecticide, a thiazole insecticide and a thiazolidine insecticide, or
(vii) a combination comprising at least one herbicide and at least one pyrethroid insecticide, or
(viii) a combination comprising at least one herbicide, at least one pyrethroid insecticide and at least another insecticide, or
(ix) a combination comprising at least one herbicide, at least one pyrethroid insecticide, and at least another insecticide selected from the group consisting of a neonicotinoid insecticide, a thiazole insecticide and a thiazolidine insecticide.
Each of these aspects may have embodiments in which the phytotoxic herbicide of the present invention may be used in the presence of, or combined with, at least another insecticide, or with at least two other insecticides. The insecticide(s), when combined with the phytotoxic herbicides, safen the crop against the phytotoxic effect of these herbicides. Some of these preferred embodiments are described as the selection of the phytotoxic herbicides, and their combination with the safening insecticide(s), in the table appearing below. In other embodiments, these preferred combinations may themselves be novel, and/or may be used in one or more methods of the present invention.
Each combination appearing in the table below may represent one of these embodiments.
S No. Phytotoxic herbicide Insecticide I Insecticide II
1 Clomazone Bifenthrin -
2 Clomazone Lambda-cyhalothrin -
3 Clomazone Cypermethrin -
4 Clomazone Permethrin -
5 Clomazone Bifenthrin Thiamethoxam
6 Clomazone Lambda-cyhalothrin Thiamethoxam
7 Clomazone Cypermethrin Thiamethoxam
8 Clomazone Permethrin Thiamethoxam
9 Clomazone Bifenthrin Imidacloprid
10 Clomazone Lambda-cyhalothrin Imidacloprid
11 Clomazone Cypermethrin Imidacloprid
12 Clomazone Permethrin Imidacloprid
13 Clomazone Bifenthrin Acetamiprid
14 Clomazone Lambda-cyhalothrin Acetamiprid
15 Clomazone Cypermethrin Acetamiprid
16 Clomazone Permethrin Acetamiprid
17 Clomazone Bifenthrin Thiacloprid
18 Clomazone Lambda-cyhalothrin Thiacloprid
19 Clomazone Cypermethrin Thiacloprid
20 Clomazone Permethrin Thiacloprid
21 Clomazone Bifenthrin Clothianidin
22 Clomazone Lambda-cyhalothrin Clothianidin
23 Clomazone Cypermethrin Clothianidin
24 Clomazone Permethrin Clothianidin
25 Acifluorfen Bifenthrin -
26 Acifluorfen Lambda-cyhalothrin -
27 Acifluorfen Cypermethrin -
28 Acifluorfen Permethrin -
29 Acifluorfen Bifenthrin Thiamethoxam
30 Acifluorfen Lambda-cyhalothrin Thiamethoxam
31 Acifluorfen Cypermethrin Thiamethoxam
32 Acifluorfen Permethrin Thiamethoxam
33 Acifluorfen Bifenthrin Imidacloprid
34 Acifluorfen Lambda-cyhalothrin Imidacloprid
35 Acifluorfen Cypermethrin Imidacloprid
36 Acifluorfen Permethrin Imidacloprid
37 Acifluorfen Bifenthrin Acetamiprid
38 Acifluorfen Lambda-cyhalothrin Acetamiprid
39 Acifluorfen Cypermethrin Acetamiprid
40 Acifluorfen Permethrin Acetamiprid
41 Acifluorfen Bifenthrin Thiacloprid
42 Acifluorfen Lambda-cyhalothrin Thiacloprid
43 Acifluorfen Cypermethrin Thiacloprid
44 Acifluorfen Permethrin Thiacloprid
45 Acifluorfen Bifenthrin Clothianidin
46 Acifluorfen Lambda-cyhalothrin Clothianidin
47 Acifluorfen Cypermethrin Clothianidin
48 Acifluorfen Permethrin Clothianidin
49 Bensulfuron Bifenthrin -
50 Bensulfuron Lambda-cyhalothrin -
51 Bensulfuron Cypermethrin -
52 Bensulfuron Permethrin -
53 Bensulfuron Bifenthrin Thiamethoxam
54 Bensulfuron Lambda-cyhalothrin Thiamethoxam
55 Bensulfuron Cypermethrin Thiamethoxam
56 Bensulfuron Permethrin Thiamethoxam
57 Bensulfuron Bifenthrin Imidacloprid
58 Bensulfuron Lambda-cyhalothrin Imidacloprid
59 Bensulfuron Cypermethrin Imidacloprid
60 Bensulfuron Permethrin Imidacloprid
61 Bensulfuron Bifenthrin Acetamiprid
62 Bensulfuron Lambda-cyhalothrin Acetamiprid
63 Bensulfuron Cypermethrin Acetamiprid
64 Bensulfuron Permethrin Acetamiprid
65 Bensulfuron Bifenthrin Thiacloprid
66 Bensulfuron Lambda-cyhalothrin Thiacloprid
67 Bensulfuron Cypermethrin Thiacloprid
68 Bensulfuron Permethrin Thiacloprid
69 Bensulfuron Bifenthrin Clothianidin
70 Bensulfuron Lambda-cyhalothrin Clothianidin
71 Bensulfuron Cypermethrin Clothianidin
72 Bensulfuron Permethrin Clothianidin
73 Cerfentrazone Bifenthrin -
74 Cerfentrazone Lambda-cyhalothrin -
75 Cerfentrazone Cypermethrin -
76 Cerfentrazone Permethrin -
77 Cerfentrazone Bifenthrin Thiamethoxam
78 Cerfentrazone Lambda-cyhalothrin Thiamethoxam
79 Cerfentrazone Cypermethrin Thiamethoxam
80 Cerfentrazone Permethrin Thiamethoxam
81 Cerfentrazone Bifenthrin Imidacloprid
82 Cerfentrazone Lambda-cyhalothrin Imidacloprid
83 Cerfentrazone Cypermethrin Imidacloprid
84 Cerfentrazone Permethrin Imidacloprid
85 Cerfentrazone Bifenthrin Acetamiprid
86 Cerfentrazone Lambda-cyhalothrin Acetamiprid
87 Cerfentrazone Cypermethrin Acetamiprid
88 Cerfentrazone Permethrin Acetamiprid
89 Cerfentrazone Bifenthrin Thiacloprid
90 Cerfentrazone Lambda-cyhalothrin Thiacloprid
91 Cerfentrazone Cypermethrin Thiacloprid
92 Cerfentrazone Permethrin Thiacloprid
93 Cerfentrazone Bifenthrin Clothianidin
94 Cerfentrazone Lambda-cyhalothrin Clothianidin
95 Cerfentrazone Cypermethrin Clothianidin
96 Cerfentrazone Permethrin Clothianidin
97 Diflufenican Bifenthrin -
98 Diflufenican Lambda-cyhalothrin -
99 Diflufenican Cypermethrin -
100 Diflufenican Permethrin -
101 Diflufenican Bifenthrin Thiamethoxam
102 Diflufenican Lambda-cyhalothrin Thiamethoxam
103 Diflufenican Cypermethrin Thiamethoxam
104 Diflufenican Permethrin Thiamethoxam
105 Diflufenican Bifenthrin Imidacloprid
106 Diflufenican Lambda-cyhalothrin Imidacloprid
107 Diflufenican Cypermethrin Imidacloprid
108 Diflufenican Permethrin Imidacloprid
109 Diflufenican Bifenthrin Acetamiprid
110 Bensulfuron Lambda-cyhalothrin Acetamiprid
111 Diflufenican Cypermethrin Acetamiprid
112 Diflufenican Permethrin Acetamiprid
113 Diflufenican Bifenthrin Thiacloprid
114 Diflufenican Lambda-cyhalothrin Thiacloprid
115 Diflufenican Cypermethrin Thiacloprid
116 Diflufenican Permethrin Thiacloprid
117 Diflufenican Bifenthrin Clothianidin
118 Diflufenican Lambda-cyhalothrin Clothianidin
119 Diflufenican Cypermethrin Clothianidin
120 Diflufenican Permethrin Clothianidin
121 Fluroxypyr Bifenthrin -
122 Fluroxypyr Lambda-cyhalothrin -
123 Fluroxypyr Cypermethrin -
124 Fluroxypyr Permethrin -
125 Fluroxypyr Bifenthrin Thiamethoxam
126 Fluroxypyr Lambda-cyhalothrin Thiamethoxam
127 Fluroxypyr Cypermethrin Thiamethoxam
128 Fluroxypyr Permethrin Thiamethoxam
129 Fluroxypyr Bifenthrin Imidacloprid
130 Fluroxypyr Lambda-cyhalothrin Imidacloprid
131 Fluroxypyr Cypermethrin Imidacloprid
132 Fluroxypyr Permethrin Imidacloprid
133 Fluroxypyr Bifenthrin Acetamiprid
134 Fluroxypyr Lambda-cyhalothrin Acetamiprid
135 Fluroxypyr Cypermethrin Acetamiprid
136 Fluroxypyr Permethrin Acetamiprid
137 Fluroxypyr Bifenthrin Thiacloprid
138 Fluroxypyr Lambda-cyhalothrin Thiacloprid
139 Fluroxypyr Cypermethrin Thiacloprid
140 Fluroxypyr Permethrin Thiacloprid
141 Fluroxypyr Bifenthrin Clothianidin
142 Fluroxypyr Lambda-cyhalothrin Clothianidin
143 Fluroxypyr Cypermethrin Clothianidin
144 Fluroxypyr Permethrin Clothianidin
145 Fluroxypyr Bifenthrin -
146 Fluroxypyr Lambda-cyhalothrin -
147 Fluroxypyr Cypermethrin -
148 Fluroxypyr Permethrin -
149 Fluroxypyr Bifenthrin Thiamethoxam
150 Fluroxypyr Lambda-cyhalothrin Thiamethoxam
151 Fluroxypyr Cypermethrin Thiamethoxam
152 Fluroxypyr Permethrin Thiamethoxam
153 Fluroxypyr Bifenthrin Imidacloprid
154 Fluroxypyr Lambda-cyhalothrin Imidacloprid
155 Fluroxypyr Cypermethrin Imidacloprid
156 Fluroxypyr Permethrin Imidacloprid
157 Fluroxypyr Bifenthrin Acetamiprid
158 Fluroxypyr Lambda-cyhalothrin Acetamiprid
159 Fluroxypyr Cypermethrin Acetamiprid
160 Fluroxypyr Permethrin Acetamiprid
161 Fluroxypyr Bifenthrin Thiacloprid
162 Fluroxypyr Lambda-cyhalothrin Thiacloprid
163 Fluroxypyr Cypermethrin Thiacloprid
164 Fluroxypyr Permethrin Thiacloprid
165 Fluroxypyr Bifenthrin Clothianidin
166 Fluroxypyr Lambda-cyhalothrin Clothianidin
167 Fluroxypyr Cypermethrin Clothianidin
168 Fluroxypyr Permethrin Clothianidin
169 Fomesafen Bifenthrin -
170 Fomesafen Lambda-cyhalothrin -
171 Fomesafen Cypermethrin -
172 Fomesafen Permethrin -
173 Fomesafen Bifenthrin Thiamethoxam
174 Fomesafen Lambda-cyhalothrin Thiamethoxam
175 Fomesafen Cypermethrin Thiamethoxam
176 Fomesafen Permethrin Thiamethoxam
177 Fomesafen Bifenthrin Imidacloprid
178 Fomesafen Lambda-cyhalothrin Imidacloprid
179 Fomesafen Cypermethrin Imidacloprid
180 Fomesafen Permethrin Imidacloprid
181 Fomesafen Bifenthrin Acetamiprid
182 Fomesafen Lambda-cyhalothrin Acetamiprid
183 Fomesafen Cypermethrin Acetamiprid
184 Fomesafen Permethrin Acetamiprid
185 Fomesafen Bifenthrin Thiacloprid
186 Fomesafen Lambda-cyhalothrin Thiacloprid
187 Fomesafen Cypermethrin Thiacloprid
188 Fomesafen Permethrin Thiacloprid
189 Fomesafen Bifenthrin Clothianidin
190 Fomesafen Lambda-cyhalothrin Clothianidin
191 Fomesafen Cypermethrin Clothianidin
192 Fomesafen Permethrin Clothianidin
193 Glufosinate Bifenthrin -
194 Glufosinate Lambda-cyhalothrin -
195 Glufosinate Cypermethrin -
196 Glufosinate Permethrin -
197 Glufosinate Bifenthrin Thiamethoxam
198 Glufosinate Lambda-cyhalothrin Thiamethoxam
199 Glufosinate Cypermethrin Thiamethoxam
200 Glufosinate Permethrin Thiamethoxam
201 Glufosinate Bifenthrin Imidacloprid
202 Glufosinate Lambda-cyhalothrin Imidacloprid
203 Glufosinate Cypermethrin Imidacloprid
204 Glufosinate Permethrin Imidacloprid
205 Glufosinate Bifenthrin Acetamiprid
206 Glufosinate Lambda-cyhalothrin Acetamiprid
207 Glufosinate Cypermethrin Acetamiprid
208 Glufosinate Permethrin Acetamiprid
209 Glufosinate Bifenthrin Thiacloprid
210 Glufosinate Lambda-cyhalothrin Thiacloprid
211 Glufosinate Cypermethrin Thiacloprid
212 Glufosinate Permethrin Thiacloprid
213 Glufosinate Bifenthrin Clothianidin
214 Glufosinate Lambda-cyhalothrin Clothianidin
215 Glufosinate Cypermethrin Clothianidin
216 Glufosinate Permethrin Clothianidin
217 Glyphosate Bifenthrin -
218 Glyphosate Lambda-cyhalothrin -
219 Glyphosate Cypermethrin -
220 Glyphosate Permethrin -
221 Glyphosate Bifenthrin Thiamethoxam
222 Glyphosate Lambda-cyhalothrin Thiamethoxam
223 Glyphosate Cypermethrin Thiamethoxam
224 Glyphosate Permethrin Thiamethoxam
225 Glyphosate Bifenthrin Imidacloprid
226 Glyphosate Lambda-cyhalothrin Imidacloprid
227 Glyphosate Cypermethrin Imidacloprid
228 Glyphosate Permethrin Imidacloprid
229 Glyphosate Bifenthrin Acetamiprid
230 Glyphosate Lambda-cyhalothrin Acetamiprid
231 Glyphosate Cypermethrin Acetamiprid
232 Glyphosate Permethrin Acetamiprid
233 Glyphosate Bifenthrin Thiacloprid
234 Glyphosate Lambda-cyhalothrin Thiacloprid
235 Glyphosate Cypermethrin Thiacloprid
236 Glyphosate Permethrin Thiacloprid
237 Glyphosate Bifenthrin Clothianidin
238 Glyphosate Lambda-cyhalothrin Clothianidin
239 Glyphosate Cypermethrin Clothianidin
240 Glyphosate Permethrin Clothianidin
241 Halosulfuron Bifenthrin -
242 Halosulfuron Lambda-cyhalothrin -
243 Halosulfuron Cypermethrin -
244 Halosulfuron Permethrin -
245 Halosulfuron Bifenthrin Thiamethoxam
246 Halosulfuron Lambda-cyhalothrin Thiamethoxam
247 Halosulfuron Cypermethrin Thiamethoxam
248 Halosulfuron Permethrin Thiamethoxam
249 Halosulfuron Bifenthrin Imidacloprid
250 Halosulfuron Lambda-cyhalothrin Imidacloprid
251 Halosulfuron Cypermethrin Imidacloprid
252 Halosulfuron Permethrin Imidacloprid
253 Halosulfuron Bifenthrin Acetamiprid
254 Halosulfuron Lambda-cyhalothrin Acetamiprid
255 Halosulfuron Cypermethrin Acetamiprid
256 Halosulfuron Permethrin Acetamiprid
257 Halosulfuron Bifenthrin Thiacloprid
258 Halosulfuron Lambda-cyhalothrin Thiacloprid
259 Halosulfuron Cypermethrin Thiacloprid
260 Halosulfuron Permethrin Thiacloprid
261 Halosulfuron Bifenthrin Clothianidin
262 Halosulfuron Lambda-cyhalothrin Clothianidin
263 Halosulfuron Cypermethrin Clothianidin
264 Halosulfuron Permethrin Clothianidin
265 Imazamox Bifenthrin -
266 Imazamox Lambda-cyhalothrin -
267 Imazamox Cypermethrin -
268 Imazamox Permethrin -
269 Imazamox Bifenthrin Thiamethoxam
270 Imazamox Lambda-cyhalothrin Thiamethoxam
271 Imazamox Cypermethrin Thiamethoxam
272 Imazamox Permethrin Thiamethoxam
273 Imazamox Bifenthrin Imidacloprid
274 Imazamox Lambda-cyhalothrin Imidacloprid
275 Imazamox Cypermethrin Imidacloprid
276 Imazamox Permethrin Imidacloprid
277 Imazamox Bifenthrin Acetamiprid
278 Imazamox Lambda-cyhalothrin Acetamiprid
279 Imazamox Cypermethrin Acetamiprid
280 Imazamox Permethrin Acetamiprid
281 Imazamox Bifenthrin Thiacloprid
282 Imazamox Lambda-cyhalothrin Thiacloprid
283 Imazamox Cypermethrin Thiacloprid
284 Imazamox Permethrin Thiacloprid
285 Imazamox Bifenthrin Clothianidin
286 Imazamox Lambda-cyhalothrin Clothianidin
287 Imazamox Cypermethrin Clothianidin
288 Imazamox Permethrin Clothianidin
289 Imazapic Bifenthrin -
290 Imazapic Lambda-cyhalothrin -
291 Imazapic Cypermethrin -
292 Imazapic Permethrin -
293 Imazapic Bifenthrin Thiamethoxam
294 Imazapic Lambda-cyhalothrin Thiamethoxam
295 Imazapic Cypermethrin Thiamethoxam
296 Imazapic Permethrin Thiamethoxam
297 Imazapic Bifenthrin Imidacloprid
298 Imazapic Lambda-cyhalothrin Imidacloprid
299 Imazapic Cypermethrin Imidacloprid
300 Imazapic Permethrin Imidacloprid
301 Imazapic Bifenthrin Acetamiprid
302 Imazapic Lambda-cyhalothrin Acetamiprid
303 Imazapic Cypermethrin Acetamiprid
304 Imazapic Permethrin Acetamiprid
305 Imazapic Bifenthrin Thiacloprid
306 Imazapic Lambda-cyhalothrin Thiacloprid
307 Imazapic Cypermethrin Thiacloprid
308 Imazapic Permethrin Thiacloprid
309 Imazapic Bifenthrin Clothianidin
310 Imazapic Lambda-cyhalothrin Clothianidin
311 Imazapic Cypermethrin Clothianidin
312 Imazapic Permethrin Clothianidin
313 Imazapyr Bifenthrin -
314 Imazapyr Lambda-cyhalothrin -
315 Imazapyr Cypermethrin -
316 Imazapyr Permethrin -
317 Imazapyr Bifenthrin Thiamethoxam
318 Imazapyr Lambda-cyhalothrin Thiamethoxam
319 Imazapyr Cypermethrin Thiamethoxam
320 Imazapyr Permethrin Thiamethoxam
321 Imazapyr Bifenthrin Imidacloprid
322 Imazapyr Lambda-cyhalothrin Imidacloprid
323 Imazapyr Cypermethrin Imidacloprid
324 Imazapyr Permethrin Imidacloprid
325 Imazapyr Bifenthrin Acetamiprid
326 Imazapyr Lambda-cyhalothrin Acetamiprid
327 Imazapyr Cypermethrin Acetamiprid
328 Imazapyr Permethrin Acetamiprid
329 Imazapyr Bifenthrin Thiacloprid
330 Imazapyr Lambda-cyhalothrin Thiacloprid
331 Imazapyr Cypermethrin Thiacloprid
332 Imazapyr Permethrin Thiacloprid
333 Imazapyr Bifenthrin Clothianidin
334 Imazapyr Lambda-cyhalothrin Clothianidin
335 Imazapyr Cypermethrin Clothianidin
336 Imazapyr Permethrin Clothianidin
337 Imazethapyr Bifenthrin -
338 Imazethapyr Lambda-cyhalothrin -
339 Imazethapyr Cypermethrin -
340 Imazethapyr Permethrin -
341 Imazethapyr Bifenthrin Thiamethoxam
342 Imazethapyr Lambda-cyhalothrin Thiamethoxam
343 Imazethapyr Cypermethrin Thiamethoxam
344 Imazethapyr Permethrin Thiamethoxam
345 Imazethapyr Bifenthrin Imidacloprid
346 Imazethapyr Lambda-cyhalothrin Imidacloprid
347 Imazethapyr Cypermethrin Imidacloprid
348 Imazethapyr Permethrin Imidacloprid
349 Imazethapyr Bifenthrin Acetamiprid
350 Imazethapyr Lambda-cyhalothrin Acetamiprid
351 Imazethapyr Cypermethrin Acetamiprid
352 Imazethapyr Permethrin Acetamiprid
353 Imazethapyr Bifenthrin Thiacloprid
354 Imazethapyr Lambda-cyhalothrin Thiacloprid
355 Imazethapyr Cypermethrin Thiacloprid
356 Imazethapyr Permethrin Thiacloprid
357 Imazethapyr Bifenthrin Clothianidin
358 Imazethapyr Lambda-cyhalothrin Clothianidin
359 Imazethapyr Cypermethrin Clothianidin
360 Imazethapyr Permethrin Clothianidin
361 Mefenacet Bifenthrin -
362 Mefenacet Lambda-cyhalothrin -
363 Mefenacet Cypermethrin -
364 Mefenacet Permethrin -
365 Mefenacet Bifenthrin Thiamethoxam
366 Mefenacet Lambda-cyhalothrin Thiamethoxam
367 Mefenacet Cypermethrin Thiamethoxam
368 Mefenacet Permethrin Thiamethoxam
369 Mefenacet Bifenthrin Imidacloprid
370 Mefenacet Lambda-cyhalothrin Imidacloprid
371 Mefenacet Cypermethrin Imidacloprid
372 Mefenacet Permethrin Imidacloprid
373 Mefenacet Bifenthrin Acetamiprid
374 Mefenacet Lambda-cyhalothrin Acetamiprid
375 Mefenacet Cypermethrin Acetamiprid
376 Mefenacet Permethrin Acetamiprid
377 Mefenacet Bifenthrin Thiacloprid
378 Mefenacet Lambda-cyhalothrin Thiacloprid
379 Mefenacet Cypermethrin Thiacloprid
380 Mefenacet Permethrin Thiacloprid
381 Mefenacet Bifenthrin Clothianidin
382 Mefenacet Lambda-cyhalothrin Clothianidin
383 Mefenacet Cypermethrin Clothianidin
384 Mefenacet Permethrin Clothianidin
385 Mesotrione Bifenthrin -
386 Mesotrione Lambda-cyhalothrin -
387 Mesotrione Cypermethrin -
388 Mesotrione Permethrin -
389 Mesotrione Bifenthrin Thiamethoxam
390 Mesotrione Lambda-cyhalothrin Thiamethoxam
391 Mesotrione Cypermethrin Thiamethoxam
392 Mesotrione Permethrin Thiamethoxam
393 Mesotrione Bifenthrin Imidacloprid
394 Mesotrione Lambda-cyhalothrin Imidacloprid
395 Mesotrione Cypermethrin Imidacloprid
396 Mesotrione Permethrin Imidacloprid
397 Mesotrione Bifenthrin Acetamiprid
398 Mesotrione Lambda-cyhalothrin Acetamiprid
399 Mesotrione Cypermethrin Acetamiprid
400 Mesotrione Permethrin Acetamiprid
401 Mesotrione Bifenthrin Thiacloprid
402 Mesotrione Lambda-cyhalothrin Thiacloprid
403 Mesotrione Cypermethrin Thiacloprid
404 Mesotrione Permethrin Thiacloprid
405 Mesotrione Bifenthrin Clothianidin
406 Mesotrione Lambda-cyhalothrin Clothianidin
407 Mesotrione Cypermethrin Clothianidin
408 Mesotrione Permethrin Clothianidin
409 Metribuzin Bifenthrin -
410 Metribuzin Lambda-cyhalothrin -
411 Metribuzin Cypermethrin -
412 Metribuzin Permethrin -
413 Metribuzin Bifenthrin Thiamethoxam
414 Metribuzin Lambda-cyhalothrin Thiamethoxam
415 Metribuzin Cypermethrin Thiamethoxam
416 Metribuzin Permethrin Thiamethoxam
417 Metribuzin Bifenthrin Imidacloprid
418 Metribuzin Lambda-cyhalothrin Imidacloprid
419 Metribuzin Cypermethrin Imidacloprid
420 Metribuzin Permethrin Imidacloprid
421 Metribuzin Bifenthrin Acetamiprid
422 Metribuzin Lambda-cyhalothrin Acetamiprid
423 Metribuzin Cypermethrin Acetamiprid
424 Metribuzin Permethrin Acetamiprid
425 Metribuzin Bifenthrin Thiacloprid
426 Metribuzin Lambda-cyhalothrin Thiacloprid
427 Metribuzin Cypermethrin Thiacloprid
428 Metribuzin Permethrin Thiacloprid
429 Metribuzin Bifenthrin Clothianidin
430 Metribuzin Lambda-cyhalothrin Clothianidin
431 Metribuzin Cypermethrin Clothianidin
432 Metribuzin Permethrin Clothianidin
433 Napropamide-M Bifenthrin -
434 Napropamide-M Lambda-cyhalothrin -
435 Napropamide-M Cypermethrin -
436 Napropamide-M Permethrin -
437 Napropamide-M Bifenthrin Thiamethoxam
438 Napropamide-M Lambda-cyhalothrin Thiamethoxam
439 Napropamide-M Cypermethrin Thiamethoxam
440 Napropamide-M Permethrin Thiamethoxam
441 Napropamide-M Bifenthrin Imidacloprid
442 Napropamide-M Lambda-cyhalothrin Imidacloprid
443 Napropamide-M Cypermethrin Imidacloprid
444 Napropamide-M Permethrin Imidacloprid
445 Napropamide-M Bifenthrin Acetamiprid
446 Napropamide-M Lambda-cyhalothrin Acetamiprid
447 Napropamide-M Cypermethrin Acetamiprid
448 Napropamide-M Permethrin Acetamiprid
449 Napropamide-M Bifenthrin Thiacloprid
450 Napropamide-M Lambda-cyhalothrin Thiacloprid
451 Napropamide-M Cypermethrin Thiacloprid
452 Napropamide-M Permethrin Thiacloprid
453 Napropamide-M Bifenthrin Clothianidin
454 Napropamide-M Lambda-cyhalothrin Clothianidin
455 Napropamide-M Cypermethrin Clothianidin
456 Napropamide-M Permethrin Clothianidin
457 Pendimethalin Bifenthrin -
458 Pendimethalin Lambda-cyhalothrin -
459 Pendimethalin Cypermethrin -
460 Pendimethalin Permethrin -
461 Pendimethalin Bifenthrin Thiamethoxam
462 Pendimethalin Lambda-cyhalothrin Thiamethoxam
463 Pendimethalin Cypermethrin Thiamethoxam
464 Pendimethalin Permethrin Thiamethoxam
465 Pendimethalin Bifenthrin Imidacloprid
466 Pendimethalin Lambda-cyhalothrin Imidacloprid
467 Pendimethalin Cypermethrin Imidacloprid
468 Pendimethalin Permethrin Imidacloprid
469 Pendimethalin Bifenthrin Acetamiprid
470 Pendimethalin Lambda-cyhalothrin Acetamiprid
471 Pendimethalin Cypermethrin Acetamiprid
472 Pendimethalin Permethrin Acetamiprid
473 Pendimethalin Bifenthrin Thiacloprid
474 Pendimethalin Lambda-cyhalothrin Thiacloprid
475 Pendimethalin Cypermethrin Thiacloprid
476 Pendimethalin Permethrin Thiacloprid
477 Pendimethalin Bifenthrin Clothianidin
478 Pendimethalin Lambda-cyhalothrin Clothianidin
479 Pendimethalin Cypermethrin Clothianidin
480 Pendimethalin Permethrin Clothianidin
481 Pretilachlor Bifenthrin -
482 Pretilachlor Lambda-cyhalothrin -
483 Pretilachlor Cypermethrin -
484 Pretilachlor Permethrin -
485 Pretilachlor Bifenthrin Thiamethoxam
486 Pretilachlor Lambda-cyhalothrin Thiamethoxam
487 Pretilachlor Cypermethrin Thiamethoxam
488 Pretilachlor Permethrin Thiamethoxam
489 Pretilachlor Bifenthrin Imidacloprid
490 Pretilachlor Lambda-cyhalothrin Imidacloprid
491 Pretilachlor Cypermethrin Imidacloprid
492 Pretilachlor Permethrin Imidacloprid
493 Pretilachlor Bifenthrin Acetamiprid
494 Pretilachlor Lambda-cyhalothrin Acetamiprid
495 Pretilachlor Cypermethrin Acetamiprid
496 Pretilachlor Permethrin Acetamiprid
497 Pretilachlor Bifenthrin Thiacloprid
498 Pretilachlor Lambda-cyhalothrin Thiacloprid
499 Pretilachlor Cypermethrin Thiacloprid
500 Pretilachlor Permethrin Thiacloprid
501 Pretilachlor Bifenthrin Clothianidin
502 Pretilachlor Lambda-cyhalothrin Clothianidin
503 Pretilachlor Cypermethrin Clothianidin
504 Pretilachlor Permethrin Clothianidin
505 Pyrazosulfuron Bifenthrin -
506 Pyrazosulfuron Lambda-cyhalothrin -
507 Pyrazosulfuron Cypermethrin -
508 Pyrazosulfuron Permethrin -
509 Pyrazosulfuron Bifenthrin Thiamethoxam
510 Pyrazosulfuron Lambda-cyhalothrin Thiamethoxam
511 Pyrazosulfuron Cypermethrin Thiamethoxam
512 Pyrazosulfuron Permethrin Thiamethoxam
513 Pyrazosulfuron Bifenthrin Imidacloprid
514 Pyrazosulfuron Lambda-cyhalothrin Imidacloprid
515 Pyrazosulfuron Cypermethrin Imidacloprid
516 Pyrazosulfuron Permethrin Imidacloprid
517 Pyrazosulfuron Bifenthrin Acetamiprid
518 Pyrazosulfuron Lambda-cyhalothrin Acetamiprid
519 Pyrazosulfuron Cypermethrin Acetamiprid
520 Pyrazosulfuron Permethrin Acetamiprid
521 Pyrazosulfuron Bifenthrin Thiacloprid
522 Pyrazosulfuron Lambda-cyhalothrin Thiacloprid
523 Pyrazosulfuron Cypermethrin Thiacloprid
524 Pyrazosulfuron Permethrin Thiacloprid
525 Pyrazosulfuron Bifenthrin Clothianidin
526 Pyrazosulfuron Lambda-cyhalothrin Clothianidin
527 Pyrazosulfuron Cypermethrin Clothianidin
528 Pyrazosulfuron Permethrin Clothianidin
529 Quinclorac Bifenthrin -
530 Quinclorac Lambda-cyhalothrin -
531 Quinclorac Cypermethrin -
532 Quinclorac Permethrin -
533 Quinclorac Bifenthrin Thiamethoxam
534 Quinclorac Lambda-cyhalothrin Thiamethoxam
535 Quinclorac Cypermethrin Thiamethoxam
536 Quinclorac Permethrin Thiamethoxam
537 Quinclorac Bifenthrin Imidacloprid
538 Quinclorac Lambda-cyhalothrin Imidacloprid
539 Quinclorac Cypermethrin Imidacloprid
540 Quinclorac Permethrin Imidacloprid
541 Quinclorac Bifenthrin Acetamiprid
542 Quinclorac Lambda-cyhalothrin Acetamiprid
543 Quinclorac Cypermethrin Acetamiprid
544 Quinclorac Permethrin Acetamiprid
545 Quinclorac Bifenthrin Thiacloprid
546 Quinclorac Lambda-cyhalothrin Thiacloprid
547 Quinclorac Cypermethrin Thiacloprid
548 Quinclorac Permethrin Thiacloprid
549 Quinclorac Bifenthrin Clothianidin
550 Quinclorac Lambda-cyhalothrin Clothianidin
551 Quinclorac Cypermethrin Clothianidin
552 Quinclorac Permethrin Clothianidin
553 Saflufenacil Bifenthrin -
554 Saflufenacil Lambda-cyhalothrin -
555 Saflufenacil Cypermethrin -
556 Saflufenacil Permethrin -
557 Saflufenacil Bifenthrin Thiamethoxam
558 Saflufenacil Lambda-cyhalothrin Thiamethoxam
559 Saflufenacil Cypermethrin Thiamethoxam
560 Saflufenacil Permethrin Thiamethoxam
561 Saflufenacil Bifenthrin Imidacloprid
562 Saflufenacil Lambda-cyhalothrin Imidacloprid
563 Saflufenacil Cypermethrin Imidacloprid
564 Saflufenacil Permethrin Imidacloprid
565 Saflufenacil Bifenthrin Acetamiprid
566 Saflufenacil Lambda-cyhalothrin Acetamiprid
567 Saflufenacil Cypermethrin Acetamiprid
568 Saflufenacil Permethrin Acetamiprid
569 Saflufenacil Bifenthrin Thiacloprid
570 Saflufenacil Lambda-cyhalothrin Thiacloprid
571 Saflufenacil Cypermethrin Thiacloprid
572 Saflufenacil Permethrin Thiacloprid
573 Saflufenacil Bifenthrin Clothianidin
574 Saflufenacil Lambda-cyhalothrin Clothianidin
575 Saflufenacil Cypermethrin Clothianidin
576 Saflufenacil Permethrin Clothianidin
577 S-Metolachlor Bifenthrin -
578 S-Metolachlor Lambda-cyhalothrin -
579 S-Metolachlor Cypermethrin -
580 S-Metolachlor Permethrin -
581 S-Metolachlor Bifenthrin Thiamethoxam
582 S-Metolachlor Lambda-cyhalothrin Thiamethoxam
583 S-Metolachlor Cypermethrin Thiamethoxam
584 S-Metolachlor Permethrin Thiamethoxam
585 S-Metolachlor Bifenthrin Imidacloprid
586 S-Metolachlor Lambda-cyhalothrin Imidacloprid
587 S-Metolachlor Cypermethrin Imidacloprid
588 S-Metolachlor Permethrin Imidacloprid
589 S-Metolachlor Bifenthrin Acetamiprid
590 S-Metolachlor Lambda-cyhalothrin Acetamiprid
591 S-Metolachlor Cypermethrin Acetamiprid
592 S-Metolachlor Permethrin Acetamiprid
593 S-Metolachlor Bifenthrin Thiacloprid
594 S-Metolachlor Lambda-cyhalothrin Thiacloprid
595 S-Metolachlor Cypermethrin Thiacloprid
596 S-Metolachlor Permethrin Thiacloprid
597 S-Metolachlor Bifenthrin Clothianidin
598 S-Metolachlor Lambda-cyhalothrin Clothianidin
599 S-Metolachlor Cypermethrin Clothianidin
600 S-Metolachlor Permethrin Clothianidin
601 Sulfentrazone Bifenthrin -
602 Sulfentrazone Lambda-cyhalothrin -
603 Sulfentrazone Cypermethrin -
604 Sulfentrazone Permethrin -
605 Sulfentrazone Bifenthrin Thiamethoxam
606 Sulfentrazone Lambda-cyhalothrin Thiamethoxam
607 Sulfentrazone Cypermethrin Thiamethoxam
608 Sulfentrazone Permethrin Thiamethoxam
609 Sulfentrazone Bifenthrin Imidacloprid
610 Sulfentrazone Lambda-cyhalothrin Imidacloprid
611 Sulfentrazone Cypermethrin Imidacloprid
612 Sulfentrazone Permethrin Imidacloprid
613 Sulfentrazone Bifenthrin Acetamiprid
614 Sulfentrazone Lambda-cyhalothrin Acetamiprid
615 Sulfentrazone Cypermethrin Acetamiprid
616 Sulfentrazone Permethrin Acetamiprid
617 Sulfentrazone Bifenthrin Thiacloprid
618 Sulfentrazone Lambda-cyhalothrin Thiacloprid
619 Sulfentrazone Cypermethrin Thiacloprid
620 Sulfentrazone Permethrin Thiacloprid
621 Sulfentrazone Bifenthrin Clothianidin
622 Sulfentrazone Lambda-cyhalothrin Clothianidin
623 Sulfentrazone Cypermethrin Clothianidin
624 Sulfentrazone Permethrin Clothianidin

EXAMPLE:
EXAMPLE 1:
Evaluate the phytotoxicity of clomazone in rice after seed treatment with thiametoxam and lambda-cyalothrin alone or in combination tank mix. Rice was planted in humid soil and clomazone was applied pre-emergence, and the tank mixture of the two insecticides was evaluated as safener for clomazone in rice. The evaluation was performed by measuring the selectivity of clomazone in rice after its seed treatment with thiomethoxam and lambda-cyhalothrin individually and in tank mixture.
Thiamethoxam formulation Cruiser 350 FS was applied at 480mL/per 100 kg of seeds, while lambda-cyhalothrin formulation was applied at 600mL/per 100 kg of seeds. Their combination was also applied for seed treatment at the same dosage rates. Clomazone was applied to the resulting rice crop at 1.4 L/Ha. The percentage phytotoxicity was measured and tabulated as hereunder:
Percentage Phytotoxicity Clomazone 1.4L/ha
7DAA 10DAA
Check (unsafened) 80 75
Thiamethoxam 43.75 60
lambda-cyhalothrin 78 68.75
thiamethoxam + lambda cyhalothrin 37.5 55

The percentage phytotoxicity observed for each treatment was substracted from the untreated phytotoxicity values to arrive at the percentage phytotoxicity reduction for each treatment. The expected phytotoxicity percentage reduction was calculated using the Colby’s formula using the equation E = (X*Y)/100, where X and Y are the effects of the insecticides applied alone. The actual observed value for the mixture was then compared to the expected value, and interpreted using the rule: If greater = synergism, If less then = antagonism, and If equal = additive.
Percentage Phytotoxicity reduction (Control – Treatment) Clomazone 1.4L/ha
7DAA 10DAA
Check (unsafened) 0.0 0.0
Thiamethoxam 36.25 15
lambda-cyhalothrin 2.0 6.25
Expected percentage phytotoxicity reduction (Colby’s Formula) 37.5 20.3
thiamethoxam + lambda cyhalothrin (actual) 42.5 20
Difference (Expected – Actual) 5.0 - 0.30
Synergistic Additive

Conclusion: From the above results it is evident that the single seed treatment of thiamethoxam or lambda cyhalothrin showed signifcant phytotoxicity on rice crop caused by application of clomazone. However, seed treatment with combination of thiamethoxam and lambdacyhalothrin showed significant decrease in the phytoxicity caused by clomazone. Even mathematically, it was seen that the combination of thiamethoxam and lambda-cyhalothrin ‘safened’ clomazone synergistically in rice.
The instant invention is more specifically explained by examples given above. However, it should be understood that the scope of the present invention is not limited by the examples in any manner. It will be appreciated by any person skilled in this art that the present invention includes the given examples and further can be modified and altered without departing from the novel teachings and advantages of the invention which are intended to be included within the scope of the invention.
,CLAIMS:1. Use of a pyrethroid insecticide for reducing phytotoxicity in crops treated with a herbicide.
2. Use as claimed in claim 1, wherein pyrethroid insecticide is selected from the group consisting of acrinathrin, allethrin, bioallethrin, esdépalléthrine, barthrin, bifenthrin, kappa-bifenthrin, bioethanomethrin, brofenvalerate, brofluthrinate, bromethrin, butethrin, chlorempenthrin, cyclethrin, cycloprothrin, cyfluthrin, beta-cyfluthrin, cyhalothrin, gamma-cyhalothrin, lambda-cyhalothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, cyphenothrin, deltamethrin, dimefluthrin, dimethrin, empenthrin, d-fanshiluquebingjuzhi, chloroprallethrin, fenfluthrin, fenpirithrin, fenpropathrin, fenvalerate, esfenvalerate, flucythrinate, fluvalinate, tau-fluvalinate, furamethrin, furethrin, heptafluthrin, imiprothrin, japothrins, kadethrin, methothrin, metofluthrin, epsilon-metofluthrin, momfluorothrin, epsilon-momfluorothrin, pentmethrin, permethrin, biopermethrin, transpermethrin, phenothrin, prallethrin, profluthrin, proparthrin, pyresmethrin, renofluthrin, meperfluthrin, resmethrin, bioresmethrin, cismethrin, tefluthrin, kappa-tefluthrin, terallethrin, tetramethrin, tetramethylfluthrin, tralocythrin, tralomethrin, transfluthrin, valerate, etofenprox, flufenprox, halfenprox, protrifenbute, silafluofen, sulfoxime, thiofluoximate.
3. Use as claimed in claim 1 and 2 wherein pyrethroid insecticide is lambda-cyhalothrin.
4. Use of a pyrethroid insecticide in a combination with at least another insecticide for reducing phytotoxicity in crops treated with a herbicide.
5. Use as claimed in claim 1, wherein another insecticide is selected from the group consisting of a neonicotinoid insecticide, a thiazole insecticide and a thiazolidine insecticide.
6. Use as claimed in claim 5, wherein neonicotinoid insecticide is selected from clothianidin, dinotefuran, imidacloprid, imidaclothiz, thiamethoxam, nitenpyram, nithiazine, acetamiprid, imidacloprid, nitenpyram, paichongding, and thiacloprid
7. Use as claimed in claim 5, wherein thiazole insecticide is selected from clothianidin and imidaclothiz
8. Use as claimed in claim 5, wherein thiazolidine insecticide is selected from tazimcarb and thiacloprid
9. Use as claimed in any of the preceding claim, wherein the phytotoxic herbicide is selected from 2,4-D esters and amines, 2,4-MCPA, acetochlor, acifluorfen, clomazone, aclonifen, AE0172747, alachlor, amidosulfuron, aminopyralid, aminotriazole, ammonium thiocyanate, anilifos, azimsulfuron, benfuresate, bensulfuron-methyl, bentazone, benthiocarb, benzobicyclon, bifenox, bispyribac-sodium, butachlor, butafenacil, butralin, cafenstrole, carbetamide, carfentrazone-ethyl, chlorflurenol, chlorimuron, cinosulfuron, clethodim, clopyralid, cloransulam-methyl, cyclosulfamuron, cycloxydim, cyhalofop-butyl, dicamba, dichlobenil, dichlorprop-P, diclosulam, diflufenican, diflufenzopyr, dimethenamid, dimethenamid-p, diquat, dithiopyr, diuron, EK2612, EPTC, esprocarb, ET-751, ethoxysulfuron, ethbenzanid, F7967, fenoxaprop, fenoxaprop-ethyl, fenoxaprop-ethyl + isoxidifen-ethyl, fentrazamide, flazasulfuron, florasulam, fluazifop, fluazifop-P-butyl, flucetosulfuron, flufenacet, flufenpyr-ethyl, flumetsulam, flumiclorac-pentyl, flumioxazin, fluometuron, flupyrsulfuron, fluroxypyr, fluroxypyr esters and salts, fomesafen, foramsulfuron, fumiclorac, glufosinate, glufosinate-ammonium, glyphosate , halosulfuron, haloxyfop-methyl, haloxyfop-R, HOK-201, imazamethabenz, imazamox, imazapic, imazapyr, imazaquin, imazethapyr, imazosulfuron, indanofan, indaziflam, iodosulfuron, ioxynil, IR 5790, isoproturon, isoxaben, isoxaflutole, KUH-071, lactofen, linuron, MCPA, MCPA ester & amine, mecoprop-P, mefenacet, mesosulfuron, mesotrione, metamifop, metolachlor, metosulam, metribuzin, metsulfuron, molinate, MSMA, napropamide, NC-620, nicosulfuron, norflurazon, OK-9701, orthosulfamuron, oryzalin, oxadiargyl, oxadiazon, oxazichlomefone, oxyfluorfen, paraquat, pendimethalin, pentoxazone, pethoxamid, picloram, picolinafen, piperophos, pretilachlor, profoxydim, propachlor, propanil, propyzamide, prosulfocarb, prosulfuron, pyraclonil, pyrazogyl, pyrazosulfuron, pyribenzoxim, pyriftalid, pyrimisulfan (KUH-021), pyriminobac-methyl, primisulfuron, propyrisulfuron (TH-547), pyroxsulam, pyroxasulfone (KIH-485), quinclorac, quizalofop-ethyl-D, S-3252, saflufenacil, sethoxydim, SL-0401, SL-0402, s-metolachlor, sulcotrione, sulfentrazone, sulfosate, tebuthiuron, tefuryltrione (AVH-301), thiazopyr, thiobencarb, triclopyr, triclopyr esters and amine, and tritosulfuron.
10. Use of lambda-cyhalothrin for reducing phytotoxicity in crops treated with clomazone.
11. Use of lambda-cyhalothrin and thiamethoxam for reducing phytotoxicity in crops treated with clomazone.
12. A combination comprising a pyrethroid insecticide and a herbicide.
13. The combination as claimed in claim 12, wherein pyrethroid insecticide is selected from the group consisting of acrinathrin, allethrin, bioallethrin, esdépalléthrine, barthrin, bifenthrin, kappa-bifenthrin, bioethanomethrin, brofenvalerate, brofluthrinate, bromethrin, butethrin, chlorempenthrin, cyclethrin, cycloprothrin, cyfluthrin, beta-cyfluthrin, cyhalothrin, gamma-cyhalothrin, lambda-cyhalothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, cyphenothrin, deltamethrin, dimefluthrin, dimethrin, empenthrin, d-fanshiluquebingjuzhi, chloroprallethrin, fenfluthrin, fenpirithrin, fenpropathrin, fenvalerate, esfenvalerate, flucythrinate, fluvalinate, tau-fluvalinate, furamethrin, furethrin, heptafluthrin, imiprothrin, japothrins, kadethrin, methothrin, metofluthrin, epsilon-metofluthrin, momfluorothrin, epsilon-momfluorothrin, pentmethrin, permethrin, biopermethrin, transpermethrin, phenothrin, prallethrin, profluthrin, proparthrin, pyresmethrin, renofluthrin, meperfluthrin, resmethrin, bioresmethrin, cismethrin, tefluthrin, kappa-tefluthrin, terallethrin, tetramethrin, tetramethylfluthrin, tralocythrin, tralomethrin, transfluthrin, valerate, etofenprox, flufenprox, halfenprox, protrifenbute, silafluofen, sulfoxime, thiofluoximate.
14. The combination as claimed in claim 12 or 13, wherein pyrethroid insecticide is lambda-cyhalothrin.
15. A combination comprising a pyrethroid insecticide, at least another insecticide, and a herbicide.
16. The combination as claimed in claim 15, wherein another insecticide is selected from the group consisting of a neonicotinoid insecticide, a thiazole insecticide and a thiazolidine insecticide.
17. The combination as claimed in claim 16, wherein neonicotinoid insecticide is selected from clothianidin, dinotefuran, imidacloprid, imidaclothiz, thiamethoxam, nitenpyram, nithiazine, acetamiprid, imidacloprid, nitenpyram, paichongding, and thiacloprid.
18. The combination as claimed in claim 16, wherein thiazole insecticide is selected from clothianidin and imidaclothiz.
19. The combination as claimed in claim 19, wherein thiazolidine insecticide is selected from tazimcarb and thiacloprid.
20. The combination as claimed in any of the preceding claims 12 - 19, wherein the phytotoxic herbicide is selected from 2,4-D esters and amines, 2,4-MCPA, acetochlor, acifluorfen, clomazone, aclonifen, AE0172747, alachlor, amidosulfuron, aminopyralid, aminotriazole, ammonium thiocyanate, anilifos, azimsulfuron, benfuresate, bensulfuron-methyl, bentazone, benthiocarb, benzobicyclon, bifenox, bispyribac-sodium, butachlor, butafenacil, butralin, cafenstrole, carbetamide, carfentrazone-ethyl, chlorflurenol, chlorimuron, cinosulfuron, clethodim, clopyralid, cloransulam-methyl, cyclosulfamuron, cycloxydim, cyhalofop-butyl, dicamba, dichlobenil, dichlorprop-P, diclosulam, diflufenican, diflufenzopyr, dimethenamid, dimethenamid-p, diquat, dithiopyr, diuron, EK2612, EPTC, esprocarb, ET-751, ethoxysulfuron, ethbenzanid, F7967, fenoxaprop, fenoxaprop-ethyl, fenoxaprop-ethyl + isoxidifen-ethyl, fentrazamide, flazasulfuron, florasulam, fluazifop, fluazifop-P-butyl, flucetosulfuron, flufenacet, flufenpyr-ethyl, flumetsulam, flumiclorac-pentyl, flumioxazin, fluometuron, flupyrsulfuron, fluroxypyr, fluroxypyr esters and salts, fomesafen, foramsulfuron, fumiclorac, glufosinate, glufosinate-ammonium, glyphosate , halosulfuron, haloxyfop-methyl, haloxyfop-R, HOK-201, imazamethabenz, imazamox, imazapic, imazapyr, imazaquin, imazethapyr, imazosulfuron, indanofan, indaziflam, iodosulfuron, ioxynil, IR 5790, isoproturon, isoxaben, isoxaflutole, KUH-071, lactofen, linuron, MCPA, MCPA ester & amine, mecoprop-P, mefenacet, mesosulfuron, mesotrione, metamifop, metolachlor, metosulam, metribuzin, metsulfuron, molinate, MSMA, napropamide, NC-620, nicosulfuron, norflurazon, OK-9701, orthosulfamuron, oryzalin, oxadiargyl, oxadiazon, oxazichlomefone, oxyfluorfen, paraquat, pendimethalin, pentoxazone, pethoxamid, picloram, picolinafen, piperophos, pretilachlor, profoxydim, propachlor, propanil, propyzamide, prosulfocarb, prosulfuron, pyraclonil, pyrazogyl, pyrazosulfuron, pyribenzoxim, pyriftalid, pyrimisulfan (KUH-021), pyriminobac-methyl, primisulfuron, propyrisulfuron (TH-547), pyroxsulam, pyroxasulfone (KIH-485), quinclorac, quizalofop-ethyl-D, S-3252, saflufenacil, sethoxydim, SL-0401, SL-0402, s-metolachlor, sulcotrione, sulfentrazone, sulfosate, tebuthiuron, tefuryltrione (AVH-301), thiazopyr, thiobencarb, triclopyr, triclopyr esters and amine, and tritosulfuron.
21. A combination comprising lambda-cyhalothrin and clomazone.
22. A combination comprising lambda-cyhalothrin, thiamethoxam and clomazone.