FIELD OF THE INVENTION:

The present invention relates to synergistic agrochemical composition comprising herbicide(s) or mixture thereof; and Insecticide as a safener for reducing phytotoxicity in crops treated with herbicide. More particularly, the present invention relates to a herbicidal composition for weeds control in post emergence conditions comprising bioactive amounts of (A) a herbicide Florpyrauxifen benzyl; (B) a one or more herbicide(s) selected from the group of various class of compounds for control of broad- leaved weeds and grassy weeds and sedges in economical crops or mixture thereof; and (C) an insecticide selected from the class of diamide, metadiamide or isoxazoline or mixture thereof for reducing phytotoxicity in crops treated with a herbicide. The present invention further relates to process of preparing said composition along with at least one inactive excipients and formulation thereof.
BACKGROUND OF THE INVENTION:
Weeds are a nuisance in most agricultural crops, orchards, plantation crops, landscapes and sometimes the herbicides used to control the weeds end up injuring crops, useful plants, some of ornamental plants. Herbicides are pesticides useful for killing or controlling unwanted plants. Generally, there are two kinds of herbicides- selective and non-selective. Selective herbicides kill certain target weeds while leaving the desired crop relatively unharmed while non-selective herbicides kill both the weeds and crops. Profitable crop production depends on effective weed control. The weeds can reduce field crop yields by competing for water, sunlight and nutrients. In today's crop production systems, starting off with a good burn-down program is a must as it helps to achieve maximum initial crop growth and reduce weed interference during early stages of the crop cycle. Since the weed-crop competition is critical during the early stages of crop cycle, the weed interference at early stage has a direct impact on the yield of the crop.
Herbicide injury is observed after application of herbicide in terms of stunting, yellowing, scorching, epinasty, hyponasty, germination loss, poor plant population stand in field and even loss of crop or plant yield. It normally happens while not following the directions on the label as carefully as one should. Farmers tend to use more herbicide than the label

instructs or can be careless and spray during windy conditions or wave the wand around so that the spray drifts onto non-target plants.
The term for plant damage is "phytotoxicity" and it can be caused by pesticides, nutrients, or physical and environmental damage (wind, sun, hail, etc.). Often the identity of the herbicide can be determined by the injury symptoms on the plants.
Symptoms can be divided into 5 main categories: leaf and shoot malformations, root and shoot stunting, leaf spotting, leaf chlorosis (yellowing), and leaf necrosis (death).
An effective weed control can be achieved by usage of herbicides appropriately. The activity of herbicides can be enhanced in various ways to achieve the maximum benefit. One of the ways is to use combinations. However, identifying appropriate combinations, which will reduce the toxicity at the same time due to the application of herbicides on crop, their agrochemical application rates and ratio of the combinations is essential to achieve efficacious control, which is not straight forward. The selection of a particular formulation type is more cumbersome for an agrochemical combination.
The efficacy of these herbicides against harmful weeds in the crop plants depends on the application rate, the formulation ingredients, the harmful weeds to be controlled, the climatic conditions and the soil conditions.
Farmers are applying more than one active ingredient or applying high use rate to control different types of weeds at a time, to control multiple generations of weeds in fields, to control troublesome weeds and to get residual control. Such practices increase the chances of herbicidal injury or phytotoxicity to the target crops.
There are many herbicides which used in combination creates characteristic phytotoxic injuries in plants like malformed, distorted leaves and shoots, stunted shoots and roots, chlorotic, necrotic, or spotted leaves.
However, there remains a great need for improved broadleaf and grassy weed control compositions and a method of controlling such noxious vegetation in post emergence

without adversely affecting desirable plants and which reduces the amount of chemical herbicidal agent necessary to obtain the acceptable weed control along with reducing the undesirable post treatment toxic effect or injury of the herbicides on crops.
The compound 2-[(2-chlorophenyl)methyl]-4,4-dimethyl-3-isoxazolidinone, also known as "clomazone", is a potent herbicide as evidenced by its ability to control, for full growing seasons and at low application rates. However, clomazone is phytotoxic to other crops when applied at rates effective to control undesired vegetation, such contact resulting from drift to adjacent fields planted with low tolerance crops or from carryover when soybean fields treated with clomazone are rotated to a crop sensitive to clomazone.
It has been known that certain insecticides act as a safener against injury inflicted by herbicide application. Article titled "Evaluation of Safening Effects to Herbicides Conferred via Insecticide Seed Treatments in Soybean (Glycine max) and Grain Sorghum (Sorghum bicolor)" by Nicholas Robert Steppig discloses that applications of some organophosphate insecticides at planting can reduce cotton injury following applications of the soil-applied herbicide clomazone.
There are many combinations of herbicides known in the art for the control of weeds further comprising an insecticide used as a safener. For example, US20200095202A1 relates to a mixture of certain substituted pyrrolidinone compounds and salts thereof, with florpyrauxifen-benzyl, compositions containing them, and methods of their use for controlling undesirable vegetation.
WO2017014973 Al relates to a method for controlling aquatic weeds using halauxifen or florpyrauxifen or agriculturally acceptable esters or salts thereof in combination with one or more of diquat dibromide, copper salts, endothal, or fluridone, or agriculturally acceptable salts or esters thereof.
WO2020131628A1 relates to compositions comprising florpyrauxifen, an agriculturally acceptable salt or ester thereof, or combinations thereof, and a second herbicide, wherein the compositions are safened for use on white clover. The second herbicide may be selected

from 2,4-D, amidosulfuron, saflufenacil, an agriculturally acceptable salt or ester thereof, or combinations thereof.
There is however a need for improvement of these combinations. Further there is a need of a safener in the herbicidal composition which will reduce the unwanted phytotoxic effect on crops treated with the herbicides. An insecticide plays a significant role in development of crop and reduces the phytotoxic effect. Many insecticides has phytotonic (growth promoting action) effect. It accelerate the growth of plant by influencing many physiological processes, increases the tolerance capacity of plants to many biotic and abiotic factors.
Even though use of insecticide as safener to herbicide is known, the present invention provides an alternative composition for safening crops to the phytotoxic effects of herbicides in agriculture which will act as useful agronomic tool to farmers.
However still there is a need of herbicidal composition comprises of a herbicide Florpyrauxifen benzyl; a one or more herbicide(s) selected from the group of various class of compounds for control of broad-leaved weeds and grassy weeds and sedges in economical crops or mixture thereof; and an insecticide selected from the class of diamide, metadiamide or isoxazoline as safener for reducing phytotoxicity in crops treated with a herbicide or mixture thereof, which overcomes some of the existing problems and can be prepared easily without much complex manufacturing process.
In general use, the herbicidal actives are used in the form of a dilute aqueous composition because it can attain a good interaction with the target weed. However, most active herbicidal compounds that are used as pesticides are only sparingly or even insoluble in water. The low solubility of such compounds present the challenges and difficulties to formulator in formulating herbicidal compounds in stable formulations that can be easily stored for a long time and which still have a high stability and effective activity until end use. This problem especially occurs and may get worsen if more than one active compound is present in the composition.

Therefore, one object of the present invention is to provide improved herbicidal combination for weeds control in post emergence conditions along with an insecticide acting as a safener in the herbicidal composition which will reduce the unwanted phytotoxic effect on crops treated with the herbicides. Another object of the present invention is to provide a method and a composition for controlling weeds in post emergence conditions.
Yet another object of the present invention is to provide improved combinations of improved broadleaf and grassy weed control without adversely affecting desirable plants and reducing the unwanted effect by using an insecticide(s) as a safener.
Embodiment of the present invention can ameliorate one or more of the above mentioned problems.
Inventors of the present invention have surprisingly found that the novel synergistic herbicidal composition of (A) a herbicide Florpyrauxifen benzyl; (B) a one or more herbicide(s) selected from the group of various class of compounds for control of broad-leaved weeds and grassy weeds and sedges in economical crops or mixture thereof; and (C) an insecticide selected from the class of diamide, metadiamide or isoxazoline as safener for reducing phytotoxicity in crops treated with a herbicide or mixture thereof as described herein which can provide solution to the above mentioned problems.
SUMMARY OF THE INVENTION
Therefore an aspect of the present invention provides composition comprises with herbicidal compound or mixture thereof along with insecticide as safener for reducing phytotoxicity in crops treated with a herbicide.
Another aspect of the present invention provides a synergistic herbicidal composition comprising an insecticide(s) selected from the class of diamide, metadiamide or isoxazoline used as safener for reducing phytotoxicity in crops treated with a herbicide.

Therefore an aspect of the present invention provides a synergistic herbicidal composition comprising bioactive amounts of (A) a herbicide Florpyrauxifen benzyl; (B) a one or more herbicide(s) selected from the group of various class of compounds for control of broad-leaved weeds and grassy weeds and sedges in economical crops or mixture thereof; and (C) an insecticide selected from the class of diamide, metadiamide or isoxazoline as safener for reducing phytotoxicity in crops treated with a herbicide or mixture thereof.
Further aspect of the present invention provides a synergistic herbicidal composition comprising bioactive amounts of (A) a herbicide Florpyrauxifen benzyl; (B) a one or more herbicide(s) selected from the group of Acetyl CoA Carboxylase (ACCase) Inhibitor, Acetolactate Synthase (ALS) or Acetohydroxy Acid Synthase (AHAS) inhibitor, Inhibitor of microtubule assembly, Synthetic Auxin, Inhibitor of photosynthesis at photosystem II site B, Inhibitor of 1-deoxy-D-xyulose 5-phosphate sunthatase (DOXP synthase), Inhibitor of protoporphyrinogen oxidase (Protox, PPO), Mitosis Inhibitor, Inhibitor of Hydroxyphenyl Pyruvate Dioxygenase (4-HPPD), Tyrosine Aminotransferase, Inhibition of dihydroorotate dehydrogenase(DHODH), HTS (hornogentisate solanesyltransferase)-a downstream enzyme of HPPD, VLCAFE inhibitors, or Herbicide with unknown mode of action or mixture thereof; and (C) an insecticide selected from the class of diamide, metadiamide or isoxazoline as safener for reducing phytotoxicity in crops treated with a herbicide or mixture thereof.
In present aspect of the invention to provide a synergistic herbicidal composition comprising an insecticide selected from the class of diamide, metadiamide or isoxazoline as a safener in composition for reducing phytotoxicity in crops treated with a herbicide present in the present herbicidal composition.
In further aspect of the present invention provides a synergistic herbicidal composition comprising an insecticide(s) as a safener to promote speedy recovery of the crop or plant from herbicidal injury. Thus accordingly reduces the stress due to abiotic factors and thus promotes overall plant or crop health and there by plant or crop yield.
Accordingly, in a further aspect, the present invention to provide a combination and a method of controlling pre-emergence and post-emergence weeds and provide a herbicidal

combination for improved broadleaf and grassy weed control without adversely affecting desirable plants by reducing phytotoxicity in crops treated with a herbicide present in the present herbicidal composition.
Yet another aspect, the present invention provides to provide a herbicidal combination which reduces the amount of chemical herbicidal agent necessary to obtain the acceptable weed control.
Accordingly, the present invention relates to method which provides a broader spectrum of controlling weeds that helps in resistance management, thus preventing the weed from becoming resistant to either of the herbicides while providing a broader spectrum of control at lower use rates.
As per one embodiment formulation for the herbicidal composition is selected from Capsule suspension (CS), Dispersible concentrate (DC), Emulsifiable concentrate (EC), Emulsion, water in oil (EO), Emulsion, oil in water (EW), Jambo balls or bags (bags in water soluble pouch), Micro-emulsion (ME), Oil dispersion (OD), Oil miscible flowable concentrate (oil miscible suspension (OF), Oil miscible liquid (OL), Suspension concentrate (SC), Suspo-emulsion (SE), Soluble concentrate (SL), Water dispersible granule (WG or WDG), Water soluble granule (SG), Water soluble powder (SP), Wettable powder (WP), A mixed formulation of CS and SC (ZC), A mixed formulation of CS and SE (ZE), A mixed formulation of CS and EW (ZW), Granule (GR) / Soil Applied Granules (SAG), Controlled release granules (CR); and one or more customary formulation adjuvants such as a) dispersant, b) wetting agent, c) anti-foaming agent, d) biocides, e) anti-freezing agent, f) suspending agent, g) thickener, h) coating agent and i) buffering agent.
The remainder of the aqueous formulation is preferably wholly water but may comprise other materials, such as inorganic salts. The formulation is preferably, completely free from organic solvents.
Accordingly, in a first aspect, the present invention provides a synergistic herbicidal composition comprising bioactive amounts of (A) a herbicide Florpyrauxifen benzyl; (B) a one or more herbicide(s) selected from the group of Acetyl CoA Carboxylase (ACCase)

Inhibitor, Acetolactate Synthase (ALS) or Acetohydroxy Acid Synthase (AHAS) inhibitor, Inhibitor of microtubule assembly, Synthetic Auxin, Inhibitor of photosynthesis at photosystem II site B, Inhibitor of 1-deoxy-D-xyulose 5-phosphate synthatase (DOXP synthase), Inhibitor of protoporphyrinogen oxidase (Protox, PPO), Mitosis Inhibitor, Inhibitor of Hydroxyphenyl Pyruvate Dioxygenase (4-HPPD), Tyrosine Aminotransferase, Inhibition of dihydroorotate dehydrogenase(DHODH), HTS (homogentisate solanesyl transferase)-a downstream enzyme of HPPD, VLCAFE inhibitors, or Herbicide with unknown mode of action or mixture thereof; and (C) an insecticide selected from the class of diamide, metadiamide or isoxazoline as safener for reducing phytotoxicity in crops treated with a herbicide or mixture thereof and one or more customary formulation adjuvants; shows synergistic activity.
DETAILED DESCRIPTION OF THE INVENTION:
The term "synergistic", as used herein, refers the combined action of two or more active agents blended together and administered conjointly that is greater than the sum of their individual effects.
"Bioactive amounts" as mentioned herein means that amount which, when applied treatment of crops, is sufficient to effect such treatment.
For the purposes of the present invention, an insecticide(s) insecticide selected from the class of diamide, metadiamide or isoxazoline or mixture thereof is used as a 'safener' and the term 'safener' in present context is defined as substances which reduce or prevent the phytotoxic effect of crop protectants specifically herbicide, on plants treated therewith and/or on plants whose seeds and/or growth substrate have been treated or are treated therewith.
The term 'herbicide' is used herein to mean an active ingredient that kills, controls or otherwise adversely modifies the growth of unwanted plants. An herbicidally effective or vegetation controlling amount is an amount of active ingredient which causes an adversely modifying effect and includes deviations from natural development, killing, regulation, desiccation, retardation, and the like.

The term "phytotoxicity" as used herein means unintended herbicidal effect on a plant of interest resulting in significant damage to the plant. In an embodiment the present invention relates to use of a pyrethroid insecticide for reducing phytotoxicity in crops treated with a herbicide.
Therefore an aspect of the present invention provides a synergistic herbicidal composition comprising bioactive amounts of (A) a herbicide Florpyrauxifen benzyl; (B) a one or more herbicide(s) selected from the group of various class of compounds for control of broad-leaved weeds and grassy weeds and sedges in economical crops or mixture thereof; and (C) an insecticide selected from the class of diamide, metadiamide or isoxazoline as safener for reducing phytotoxicity in crops treated with a herbicide or mixture thereof.
Further aspect of the present invention provides a synergistic herbicidal composition comprising bioactive amounts of (A) a herbicide Florpyrauxifen benzyl; (B) a one or more herbicide(s) selected from the group of Acetyl CoA Carboxylase (ACCase) Inhibitor, Acetolactate Synthase (ALS) or Acetohydroxy Acid Synthase (AHAS) inhibitor, Inhibitor of microtubule assembly, Synthetic Auxin, Inhibitor of photosynthesis at photosystem II site B, Inhibitor of 1-deoxy-D-xyulose 5-phosphate synthatase (DOXP synthase), Inhibitor of protoporphyrinogen oxidase (Protox, PPO), Mitosis Inhibitor, Inhibitor of Hydroxyphenyl Pyruvate Dioxygenase (4-HPPD), Tyrosine Aminotransferase, Inhibition of dihydroorotate dehydrogenase(DHODH), HTS (hornogentisate solanesyltransferase)-a downstream enzyme of HPPD, VLCAFE inhibitors, or Herbicide with unknown mode of action or mixture thereof; and (C) an insecticide selected from the class of diamide, metadiamide or isoxazoline as safener for reducing phytotoxicity in crops treated with a herbicide or mixture thereof.
In an embodiment of the present invention herbicide from Acetyl CoA Carboxylase (ACCase) is selected from clodinafop-propargyl, cyhalofop-butyl, fenoxaprop-P, fluazifop-P, haloxyfop, metamifop, propaquizafop, quizalofop-P-ethyl, pinoxaden
In an embodiment of the present invention herbicide of Acetolactate Synthase (ALS) or Acetohydroxy Acid Synthase (AHAS) inhibitor is selected from azimsulfuron, bensulfuron methyl, chlorimuron ethyl, ethoxysulfuron, flucetosulfuron, halosulfuron methyl,

imazosulfuron, iodosulfuron, mesosulfuron, metsulfuron mehtyl, propyrisulfuron, pyrazosulfuron ehtyl, sulfosulfuron, bispyribac-sodium, pyribenzoxim, penoxsulam, pyroxsulam, flucarbazone-sodium, thiencarbazone-methyl, imazamox, imazapic, imazapyr, imazaquin, imazethapyr, triafamone.
In an embodiment of the present invention herbicide from Inhibitor of microtubule assembly is selected from pendimethalin.
In an embodiment of the present invention herbicide from Synthetic Auxin is selected from 2,4-D, aminopyralid, clopyralid, fluroxypyr, picloram, triclopyr, quinclorac, halauxifen methyl.
In an embodiment of the present invention herbicide from Inhibitor of photosynthesis at photosystem II site B bentazone.
In an embodiment of the present invention herbicide from Inhibitor of 1-deoxy-D-xyulose 5-phosphate synthatase (DOXP synthase) of Isoxazolidinone group is clomazone.
In an embodiment of the present invention herbicide from Inhibitor of protoporphyrinogen oxidase (Protox, PPO) is selected from aclifluorfen, bifenox, fluoroglycofen, fomesafen, lactofen, carfentrazone-ethyl, sulfentrazone, saflufenacil, flumiclorac, oxadiargyl, oxadiazon, pyraclonil, tiafenacil, cyclopyranil.
In an embodiment of the present invention herbicide from Mitosis Inhibitor is selected from butachlor, pretilachlor, S-metolachlor, fentrazamide, flufenacet, mefenacet, anilofos, carbetamide.
In an embodiment of the present invention herbicide from Inhibitor of 7,8-dihydro-preroate synthetase (DHP) of Carbamate group is asulam.
In an embodiment of the present invention herbicide from Inhibitor of Hydroxyphenyl Pyruvate Dioxygenase (4-HPPD) is selected from benzofenap, pyrasulfotole, pyrazolynate, pyrazoxyfen, tolpyralate, benzobicyclon, mesotrione, tembotrione, sulcotrione, tefuryltrione, fenquinotrione, lancotrione sodium, isoxaflutole, bicyclopyrone, topramezone;

In an embodiment of the present invention herbicide from Tyrosine Aminotransferase is cinmethylin.
In an embodiment of the present invention herbicide from Inhibitors of dihydroorotate dehydrogenase (DHODH) is tetflupyrolimet.
In an embodiment of the present invention herbicide from HTS (hornogentisate solanesyltransferase)-a downstream enzyme of HPPD is cyclopyrimorate.
In an embodiment of the present invention herbicide from VLCAFE inhibitors is selected from pyroxasulfone, ipfencarbazone, dimesulfazet, fenoxasulfone.
In an embodiment of the present invention herbicide from Inhibitors of Solanesyl Diphosphate Synthase (SDS) is aclonifen.
In an embodiment of the present invention herbicide with unknown mode of action is selected from bromobutide, fenclorim, epyrifenacil, bixzolone.
In an embodiment of the present invention an insecticide for reducing phytotoxicity in crops treated with a herbicides, of diamides class is selectede from chlorantraniliprole, cyantraniliprole, cyclaniliprole, cyhalodi amide, cyproflanilide, flubendiamide, tetraniliprole, tetrachlorantraniliprole, tyclopyrazoflor; of class of metadiamides is broflanilide; of class of isoxazolines is selected from fluxametamide, isocycloseram.
Insecticides from the class of diamides:
Chlorantraniliprole is a carboxamide resulting from the formal condensation of the carboxylic acid group of 3-bromo-l-(3-chloropyridin-2-yl)-lH-pyrazole-5-carboxylic acid with the primary amino group of 2-amino-5-chloro-N,3-dimethylbenzamide. The first of the anthranilic diamide insecticides, it is a ryanodine receptor activator and is used to protect a wide variety of crops, including corn, cotton, grapes, rice and potatoes. It has a role as a ryanodine receptor agonist. It is an organobromine compound, a member of pyridines, a member of pyrazoles, a pyrazole insecticide, a member of

monochlorobenzenes and a secondary carboxamide. It has an IUPAC name as 5-bromo-N-[4-chloro-2-methyl-6-(methylcarbamoyl)phenyl]-2-(3-chloropyridin-2-yl)pyrazole-3-carb oxamide.
Cyantraniliprole is a carboxamide that is chlorantraniliprole in which the chlorine atom attached to the phenyl ring has been replaced by a cyano group. A ryanodine receptor agonist, it is used as insecticide for the control of whitefly, thrips, aphids, fruitflies, and fruit worms in crops such as onions, potatoes and tomatoes. It is highly toxic to honeybees. It has a role as a ryanodine receptor agonist. It is a pyrazole insecticide, a nitrile, an organochlorine compound, an organobromine compound, a member of pyridines and a secondary carboxamide. It has an IUPAC name as 5-bromo-2-(3-chloropyridin-2-yl)-N-[4-cyano-2-methyl-6-(methylcarbamoyl)phenyl]pyrazole-3-carboxamide.
Tetraniliprole is a carboxamide that is cyantraniliprole in which the bromine atom has been
replaced by a [5-(trifluoromethyl)-2H-tetrazol-2-yl]methyl group. It has a role as a
ryanodine receptor agonist. It is a nitrile, an organochlorine compound, a pyrazole
insecticide, a member of pyridines, a member of tetrazoles, an organofluorine compound
and a secondary carboxamide. It has 2-(3-chloropyridin-2-yl)-N-[4-cyano-2-methyl-6-
(methylcarbamoyl)phenyl]-5-[[5-(trifluoro methyl)tetrazol-2-yl]methyl]pyrazole-3-
carboxamide.
Insecticides from the class of metadiamides:
Broflanilide is a benzamide obtained by formal condensation of the carboxy group of 3-[benzoyl(methyl)amino]-2-fluorobenzoic acid with the amino group of 2-bromo-4-(l,l,l,2,3,3,3-heptafluoropropan-2-yl)-6-(trifluoromethyl)aniline. An insecticide that exhibits high larvicidal activity against Spodoptera litura and is effective against pests with resistance to cyclodienes and fipronil It has a role as an agrochemical and a GABA antagonist. It is a member of benzamides, a member of monofluorobenzenes, an organofluorine insecticide, a member of bromobenzenes and a member of (trifluoromethyl)benzenes. It has an IUPAC name as 3-[benzoyl(methyl)amino]-N-[2-

bromo-4-(l,l,l,2,3,3,3-heptafluoropropan-2-yl)-6-(trifluoromethyl)phenyl]-2-fluoro benz amide.
Insecticide from the class of Isoxazolme s:
Isocycloseram is a member of the isoxazoline class ofinsecticides.lt has an IUPAC name as 4-[(5RS)-5-(3,5-dichloro-4-fluorophenyl)-4,5-dihydro-5-(trifluoromethyl)isoxazol-3-yl]-N-[(4RS)-2-ethyl-3-oxoisoxazolidin-4-yl]-o-toluamide. Isocycloseram acts as a non-competitive GABA-gated chloride channel antagonist at a site different from known antagonists such as fiproles and cyclodienes.
The present inventors believe that the combination of the present invention surprisingly results in a synergistic action. The combination of the present invention allows for a broad spectrum of weed control and hence has surprisingly improved plant vigour and yield. The broad spectrum of the present combination of controlling weeds that also provides a solution for in resistance management, thus preventing the weed from becoming resistant to either of the herbicides while providing a broader spectrum of control at lower use rates.
The synergistic composition has very advantageous curative, preventive herbicidal properties for protecting cultivated plants. As has been mentioned, said active ingredient composition can be used to inhibit or destroy and effective management of the controlling pre-emergence and post-emergence weeds. The synergistic composition comprising herbicidal compounds for management and control of broad-leaved weeds and grasses in crops of useful plants.
The present synergistic herbicidal composition further comprises of an insecticide(s), play a very crucial role in protection of plant or crops of interest. An insecticide(s) in present composition reduces the phytotoxicity in crops treated with herbicides and promotes speedy recovery of the crop or plant from herbicidal injury. Thus accordingly reduces the stress due to abiotic factors and thus promotes overall plant or crop health and there by plant or crop yield.
Therefor the aspect of the present invention provides the herbicidal compositions comprising bioactive amounts of (A) a herbicide Florpyrauxifen benzyl; (B) a one or more

herbicide(s) selected from the group of various class of compounds for control of broad-leaved weeds and grassy weeds and sedges in economical crops or mixture thereof; and (C) an insecticide selected from the class of diamide, metadiamide or isoxazoline as safener for reducing phytotoxicity in crops treated with a herbicide or mixture thereof; are present in most preferred combinations as below:

Compound A Florpyrauxifen benzyl Compound B Herbicide(s) Compound C Insecticide as safener
Florpyrauxifen benzyl Metam ifop Chlorantraniliprole
Florpyrauxifen benzyl Metam ifop Cyantraniliprole
Florpyrauxifen benzyl Metam ifop Cyclaniliprole
Florpyrauxifen benzyl Metam ifop Cyhalodi amide
Florpyrauxifen benzyl Metam ifop Cyproflanilide
Florpyrauxifen benzyl Metam ifop Flub endi amide
Florpyrauxifen benzyl Metam ifop Tetraniliprole
Florpyrauxifen benzyl Metam ifop Tetrachlorantraniliprole
Florpyrauxifen benzyl Metam ifop Tyclopyrazoflor
Florpyrauxifen benzyl Metam ifop Broflanilide
Florpyrauxifen benzyl Metam ifop Fluxametamide
Florpyrauxifen benzyl Metam ifop Isocycloseram
Florpyrauxifen benzyl Cyhalofop butyl Chlorantraniliprole
Florpyrauxifen benzyl Cyhalofop butyl Cyclaniliprole
Florpyrauxifen benzyl Cyhalofop butyl Cyhalodi amide
Florpyrauxifen benzyl Cyhalofop butyl Cyproflanilide
Florpyrauxifen benzyl Cyhalofop butyl Tetraniliprole
Florpyrauxifen benzyl Cyhalofop butyl Broflanilide
Florpyrauxifen benzyl Cyhalofop butyl Isocycloseram
Florpyrauxifen benzyl Fenoxaprop-P-ethyl Chlorantraniliprole
Florpyrauxifen benzyl Fenoxaprop-P-ethyl Cyclaniliprole
Florpyrauxifen benzyl Fenoxaprop-P-ethyl Cyhalodi amide
Florpyrauxifen benzyl Fenoxaprop-P-ethyl Cyproflanilide
Florpyrauxifen benzyl Fenoxaprop-P-ethyl Tetraniliprole
Florpyrauxifen benzyl Fenoxaprop-P-ethyl Broflanilide
Florpyrauxifen benzyl Fenoxaprop-P-ethyl Isocycloseram
Florpyrauxifen benzyl Clodinafop Propargyl Chlorantraniliprole
Florpyrauxifen benzyl Pinoxaden Chlorantraniliprole

Florpyrauxifen benzyl

Azimsulfuron

Chlorantraniliprole

Florpyrauxifen benzyl Bensulfuron methyl Chlorantraniliprole
Florpyrauxifen benzyl Chlorimuron ethyl Chlorantraniliprole
Florpyrauxifen benzyl Ethoxysulfuron Chlorantraniliprole
Florpyrauxifen benzyl Flucetosulfuron Chlorantraniliprole
Florpyrauxifen benzyl Halosulfuron methyl Chlorantraniliprole
Florpyrauxifen benzyl Imazosulfuron Chlorantraniliprole
Florpyrauxifen benzyl Mesosulfuron methyl Chlorantraniliprole
Florpyrauxifen benzyl Propyrisulfuron Chlorantraniliprole
Florpyrauxifen benzyl Pyrazosulfuron ethyl Chlorantraniliprole
Florpyrauxifen benzyl Bispyribac sodium Chlorantraniliprole
Florpyrauxifen benzyl Pyribenzoxim Chlorantraniliprole
Florpyrauxifen benzyl Penoxsulam Chlorantraniliprole
Florpyrauxifen benzyl Flucarbazon sodium Chlorantraniliprole
Florpyrauxifen benzyl Thiencarbazone methyl Chlorantraniliprole
Florpyrauxifen benzyl Triafamone Chlorantraniliprole
Florpyrauxifen benzyl Pendimethalin Chlorantraniliprole
Florpyrauxifen benzyl Pyrimisulfan Chlorantraniliprole
Florpyrauxifen benzyl Ipfencarbazone Chlorantraniliprole
Florpyrauxifen benzyl Fenoxasulfone Chlorantraniliprole
Florpyrauxifen benzyl Tefuryltrione Chlorantraniliprole
Florpyrauxifen benzyl Fenquinotrione Chlorantraniliprole
Florpyrauxifen benzyl Lancotrione sodium Chlorantraniliprole
Florpyrauxifen benzyl Florpyrauxifen benzyl Chlorantraniliprole
Florpyrauxifen benzyl Cyclopyrimorate Chlorantraniliprole
Florpyrauxifen benzyl Cinmethylin Chlorantraniliprole
Florpyrauxifen benzyl Dimesulfazet Chlorantraniliprole
Florpyrauxifen benzyl Metcamifen Chlorantraniliprole
Florpyrauxifen benzyl Tetflupyrolimet Chlorantraniliprole
Florpyrauxifen benzyl Clodinafop Propargyl Chlorantraniliprole
Florpyrauxifen benzyl Pinoxaden Chlorantraniliprole
Florpyrauxifen benzyl 2,4-D Chlorantraniliprole
Florpyrauxifen benzyl Halauxifen methyl Chlorantraniliprole
Florpyrauxifen benzyl Bentazon Chlorantraniliprole
Florpyrauxifen benzyl Clomazone Chlorantraniliprole
Florpyrauxifen benzyl Acifluorfen Chlorantraniliprole
Florpyrauxifen benzyl Fomesafen Chlorantraniliprole
Florpyrauxifen benzyl Lactofen Chlorantraniliprole
Florpyrauxifen benzyl Carfentrazone ethyl Chlorantraniliprole
Florpyrauxifen benzyl Oxadiargyl Chlorantraniliprole

Florpyrauxifen benzyl Oxadiazon Chlorantraniliprole
Florpyrauxifen benzyl Pyraclonil Chlorantraniliprole
Florpyrauxifen benzyl Pretilachlor Chlorantraniliprole
Florpyrauxifen benzyl S-metolachlor Chlorantraniliprole
Florpyrauxifen benzyl Flufenacet Chlorantraniliprole
Florpyrauxifen benzyl Benzobicyclon Chlorantraniliprole
Florpyrauxifen benzyl Bromobutide Chlorantraniliprole
Florpyrauxifen benzyl Fenclorim Chlorantraniliprole
Florpyrauxifen benzyl Epyrifencil Chlorantraniliprole
Florpyrauxifen benzyl Metamifop+Carfentrazon ethyl Chlorantraniliprole
Florpyrauxifen benzyl Metamifop+Bentazon Cyantraniliprole
Florpyrauxifen benzyl Cyahofop butyl+Carfentrazon ethyl Cyclaniliprole
Florpyrauxifen benzyl Cyahofop butyl+Bentazon Cyhalodi amide
Florpyrauxifen benzyl Pinoxsul am+Pretil achlor Cyproflanilide
Florpyrauxifen benzyl Pinoxsulam+Oxadiargyl Flub endi amide
Florpyrauxifen benzyl Pinoxsulam+Oxadiazon Tetraniliprole
Florpyrauxifen benzyl Triafamone+Carfentrazon ethyl Tetrachlorantraniliprole
Florpyrauxifen benzyl Triafamone+Bentazon Tyclopyrazoflor
Florpyrauxifen benzyl Pyrazosulfuron ethyl+Carfentrazon ethyl Broflanilide
Florpyrauxifen benzyl Pyrazosulfuron ethyl+Bentazon Fluxametamide
Florpyrauxifen benzyl Pyrazosulfuron ethyl+Triafamone Isocycloseram
Florpyrauxifen benzyl Ipfencarbazone+Pretilachlor Chlorantraniliprole
Florpyrauxifen benzyl Ipfencarb azone+Oxadi argyl Tetraniliprole
Florpyrauxifen benzyl Ipfencarb azone+Pyrazo sulfur on ethyl Chlorantraniliprole
Florpyrauxifen benzyl Ipfencarbazone+Pinoxsulam Tetraniliprole
The herbicidal combination of the present invention maybe used to control the target weeds among the crops such as GMO (Genetically Modified Organism) and Non GMO varieties of Cotton (Gossypium spp.), Paddy (Oryza sativa), Wheat (Triticum aestavum), Barley (Hordeum vulgare), Maize (Zea mays), Sorghum (Sorghum bicolor), Oat (Avena sativa), Pearl millet (Pennisetum glaucum), Sugarcane (Saccharum officinarum), Sugarbeet (Beta vulgaris), Soybean (Glycin max), Peanut (Arachis hypogaea), Sunflower (Helianthus annuus) , Mustard (Brassica juncea), Rape seed (Brassica napus), Linseed (Linum usitatissimum), Sesame (Sesamum indicum), Green gram (Vigna radiata), Black gram (Vigna mungo), Chickpea (Cicer aritinum), Cowpea (Vigna unguiculata), Redgram

(Cajanus cajan), Frenchbean (Phaseolus vulgaris), Indian bean (Lablab purpureus), Horse gram (Macrotyloma uniflorum), Field pea (Pisum sativum), Cluster bean (Cyamopsis tetragonoloba), Lentils (Lens culinaris), Brinjal (Solanum melongena), Cabbage (Brassica oleracea var. capitata), Cauliflower (Brassica oleracea var. botrytis), Okra (Abelmoschus esculentus) , Onion (Allium cepa L.), Tomato (Solanum lycopersicun) , Potato (Solanum tuberosum) , Sweet potato (Ipomoea batatas), Chilly (Capsicum annum), Garlic (Allium sativum), Cucumber (Cucumis sativus), Muskmelons (Cucumis melo), Watermelon (Citrullus lanatus), Bottle gourd (Lagenaria siceraria), Bitter gourd (Momordica charantia), Radish (Raphanus sativus), Carrot (Dacus carota subsp. sativus), Turnip (Brassica rapa subsp rapa), Apple (Melus domestica), Banana (Musa spp.), Citrus groups (Citrus spp.), Grape (Vitis vinifera), Guava (Psidium guajava), Litchi (Litchi chinensis), Mango (Mangifera indica), Papaya (Carica papaya), Pineapple (Ananas comosus), Pomegranate (Punica granatum), Sapota (Manilkara zapota), Tea (Camellia sinensis), Coffea (Coffea Arabica), Turmeric (Curcuma longa), Ginger (Zingiber officinale), Cumin (Cuminum cyminum), Fenugreek (Trigonella foenum-graecum), Fennel (Foeniculum vulgare), Coriander (Coriandrum sativum), Ajwain (Trachyspermum ammi), Psyllium (Plantago ovate), Black Pepper (Piper nigrum), Stevia (Stevia rebaudiana), Safed musli (Chlorophytum tuberosum), Drum stick (Moringa oleifera), Coconut (Coco nucifera), Mentha ( Mentha spp.), Rose (Rosa spp.), Jasmine (Jasminum spp.), Marigold (Tagetes spp.), Common daisy (Bellis perennis), Dahlia (Dahlia hortnesis), Gerbera (Gerbera jamesonii), Carnation (Dianthus caryophyllus).
The present invention of synergistic herbicidal combinations can be also used to control unwanted vegetation in plantation crops, orchards, fallow lands, water bodies, field bunds etc.
A herbicidal synergistic composition of present invention controls all kind of monocots, dicots and sedges weeds. The present synergistic herbicidal combinations also controls annual and perennial weeds. The most common weeds controlled by present inventions are Abutilon indicum, Acalypha indica, Acanthospermum hispidum, Achyranthes aspera, Aerva tomentosa, Ageratum conyzoides, Alhagi camelorum, Amaranthus hybridus, Amaranthus spinosus, Amaranthus viridis, Ammannia baccifera, Anagallis arvensis,

Argemone mexicana, Artemisia nilagiricia, Asphodelus tenuifolius, Avena fatua, Avena ludoviciana, Bidens pilosa, Boerhaavia diffusa, Boerhavia repanda, Brachiaria mutica, Brassica kaber, Bromus tectorum, Calotropis gigantea, Cannabis sativa, Carthamus axyacantha, Cassia tora, Celosia argentea, Centella asiatica, Chenopodium album, Chenopodium murale, Chloris barbata, Chrozophora rottlerii, Cichorium intybus, Cirsium arvense, Clitoria ternatea, Cnicus arvensis, Commelina benghalensis, Commelina communis, Convolvulus arvensis, Conyza canadensis, Corchorus acutangulus, Coronopus didymus, Crotalaria serice, Cucumis callosus, Cuscuta campestris, Cuscuta chinensis, Cynodon dactylon, Cyanotis axillaris, Cyperus esculenthus, Cyperus iria, Cyperus rotundus, Dactyloctenium aegyptium, Datura stramonium, Daucus carota, Digera arvensis, Digitaria sanguinalis, Dinebra retroflexa, Echinochola colonum, Echinochola crusgalli, Eclipta alba, Eichhorniacrassipes, Elephantopus scaber, Eleusine indica, Eragrostis major, Euphorbia geniculata, Euphorbia hirta, Fimbristylis miliacea, Fumaria indica, Gynandropsis gynandra, Heliotropium indicum, Indigofera glandulosa, Ipomea aquatica, Lantana camara, Lathyrus aphaca, Launaea asplenifolia, Launaea nudicaulis, Leucas aspera, Ludwigia parviflora, Marsilea quadrifoliata, Medicago denticulate, Mimosa pudica, Melilotus alba, Melilotus indica, Ocimum canum, Oenothera biennis, Opuntia dillenil, Orobanche ramosa, Oryza longistaminata, Oryza sativa, Oxalis corniculata, Oxalis latifolia, Parthenium hysterophorus, Paspalum sanguinale, Phalaris minor, Phyllanthus niruri, Physalis minima, Polypogon monspeliensis, Portulaca oleracea, Prosopis juliflora, Rumex dentatus, Saccharum spontaneum, Stearia glauca, Seteria viridis, Sida spinosa, Silene antirrhina, Sisymbrium irio, Solanum nigrum, Solanum surattense, Sonchus oleraceous, Sorghum halepense, Spergula arvensis, Sphenocleazeylanica Gaertn, Striga asiatica, Tagetes minuta, Trianthema monogyna, Trianthema portulacastrum, Tribulus terrestris, Trigonelia polycerata, Vernonia cinerea, Vicia sativa and Xanthium strumarium.
Formulation of the present invention can be in any of the formulations selected from Capsule suspension (CS), Dispersible concentrate (DC), Emulsifiable concentrate (EC), Emulsion, water in oil (EO), Emulsion, oil in water (EW), Jambo balls or bags (bags in water soluble pouch), Micro-emulsion (ME), Oil dispersion (OD), Oil miscible flowable concentrate (oil miscible suspension (OF), Oil miscible liquid (OL), Suspension concentrate (SC), Suspo-emulsion (SE), Soluble concentrate (SL), Water dispersible

granule (WG or WDG), Water soluble granule (SG), Water soluble powder (SP), Wettable powder (WP), A mixed formulation of CS and SC (ZC), A mixed formulation of CS and SE (ZE), A mixed formulation of CS and EW (ZW), Granule (GR) / Soil Applied Granules (SAG), Controlled release granules (CR).
Further formulation for the present synergistic agrochemical composition comprises 'crop safener' for use especially in monocotyledonous crops (wheat, paddy/rice, corn/maize, sugarcane, sorghum, pearlmillet).
In an embodiment of the present invention any one of the crop safener for the monocotyledonous crops is selected from the cyprosulfamide, dietholate, isoxadifen / isoxadifen ethyl, dicyclonon, benoxacor, mefenpyr ethyl, fenchlorazole ethyl, cloquintocet / cloquintocet mexyl, oxabetrinil, naphthalic anhydride, mephenate, mefenpyr, furilazole, fluxofenim, flurazole, fenclorim, fenchlorazole, dichlormid, cyometrinil.
One or more of the active ingredients is encapsulated for various purposes, such as to increase the residual biological activity, or to reduce the acute toxicity, or to obtain a physical or chemically stable water-based formulation. The purpose determines whether the "free" active ingredient and the "release rate" are relevant properties of a specific product.
Further herbicidal composition comprising (A) a herbicide Florpyrauxifen benzyl; (B) a one or more herbicide(s) selected from the group of various class of compounds for control of broad-leaved weeds and grassy weeds and sedges in economical crops or mixture thereof; and (C) an insecticide selected from the class of diamide, metadiamide or isoxazoline as safener for reducing phytotoxicity in crops treated with a herbicide or mixture thereof; are present in the said composition in specific fixed ratio.
In further aspect the present invention relates to the synergistic herbicidal composition comprising bioactive amounts of (A) is 0.1 to 80% w/w of the composition; (B) is 0.01 to 80% w/w of the composition; and (C) is 0.01 to 30 % w/w of the composition.

Active Ingredients Compound A Compound B Compound C
Examples Florpyrauxifen benzyl One or more herbicide(s) An insecticide from class
of diamides,
metadiamides,
isoxazolines as 'safener'
% of Active Ingredient (w/w, w/v) 0.1 to 80% 0.01 to 80% 0.01 to 30%
The process for preparing the present synergistic agrochemical composition can be modified accordingly by any person skilled in the art based on the knowledge of manufacturing the formulation. However all such variations and modifications are covered by the scope of the present invention.
The composition of the present invention in addition to bioactive amounts of active ingredients further comprises inactive excipients including but not limited to dispersant or dispersing agent, anti-freezing agent, anti-foam agent, wetting agent, suspension aid, disintegrating agent, thickener, slow (controlled) releasing agents and buffering agent.
A wetting agent is a substance that when added to a liquid increases the spreading or penetration power of the liquid by reducing the interfacial tension between the liquid and the surface on which it is spreading. Wetting agents are used for two main functions in agrochemical formulations: during processing and manufacture to increase the rate of wetting of powders in water to make concentrates for soluble liquids or suspension concentrates; and during mixing of a product with water in a spray tank or other vessel to reduce the wetting time of wettable powders and to improve the penetration of water into water-dispersible granules.
Examples of wetting agent used herein for Granule (GR) and Controlled Release Granule (CR-GR) formulation include but not limited to Mono C2-6 alkyl ether of a poly C2-4alkylene oxide block copolymer, condensation product of castor oil and polyC2-4alkylene oxide, alkoxylated castor oil is available under the trade name Agnique CSO-36,

a mono- or di-ester of a C12-24fatty acid and polyC2-4alkylene oxide, carboxylates, sulphates, sulphonates, alcohol ethoxylates, alkyl phenol ethoxylates, fatty acid ethoxylates, sorbitan esters, ethoxylated fats or oils, amine ethoxylates, phosphate esters, ethylene oxide - propylene oxide copolymers, fluorocarbons, alkyd-polyethylene glycol resin, polyalkylene glycol ether, apolyalkoxylated nonyl phenyl, alkoxylated primary alcohol, ethoxylated distyryl phenol, ethoxylated distyrylphenol sulphate, ethoxylated tristyrylphenol phosphate, tristyrylphenol phosphate ester, hydroxylated stearic acid polyalkylene glycol polymer, and their corresponding salts,alkyd-polyethylene glycol resin, polyalkylene glycol ether, ethoxylated distyrylphenol, ethoxylated distyrylphenol sulphate, ethoxylated tristyrylphenol phosphate, tristyrylphenol phosphate ester, tristyrylphenol phosphate potassium salt, dodecysulfate sodium salt.
Examples of wetting agent used herein for SE (Suspo Emulsion) formulation includes but not limited to Ethylene oxide/propylene oxide block copolymer, Polyarylphenyl ether phosphate, Ethoxylated Fatty Alcohol, Sodium dioctyl sulfosuccinate, sodium lauryl sulphate and sodium dodecyl benzene sulfonate, alkyl diphenyl sulfonates, sodium isopropyl naphthalene sulfonate, Alkyl naphthalene sulfonate, Octyl phenol ethoxylate, alkyl phenol ethoxylate and aliphatic alcohol ethoxylate or mixture thereof.
Examples of Wetting-spreading-penetrating agent used herein for Suspo-emulsion (SE) formulation include but not limited to Organo silicone surfactants includes trisiloxane ethoxylate, polydimethylsiloxane, polyoxyethylene methyl polysiloxane, polyoxyalkylene methyl polysiloxane, polyether polymethyl siloxane copolymer, modified heptamethyl trisiloxane, polyether modified polysiloxane, 10 mole ethylene oxide adduct of octylphenol, may or may not be in modified form, may be liquid or powder form or mixture thereof etc.
A dispersant or a dispersing agent is a substance which adsorbs onto the surface of particles and helps to preserve the state of dispersion of the particles and prevents them from re-aggregating. Dispersants are added to agrochemical formulations to facilitate dispersion and suspension during manufacture, and to ensure the particles re-disperse into water in a spray tank. They are widely used in wettable powders, suspension concentrates and water-

dispersible granules. Surfactants that are used as dispersants have the ability to adsorb strongly onto a particle surface and provide a charged or steric barrier to re-aggregation of particles. The most commonly used surfactants are anionic, non-ionic, or mixtures of the two types. For wettable powder formulations, the most common dispersants are sodium lingo sulphonates. In recent years, new types of very high molecular weight polymeric surfactants have been developed as dispersants. These have very long hydrophobic 'backbones' and a large number of ethylene oxide chains forming the 'teeth' of a 'comb' surfactant. These high molecular weight polymers can give very good long-term stability to suspension concentrates because the hydrophobic backbones have many anchoring points onto the particle surfaces.
Examples of Dispersing agent used herein for Granule (GR) and Controlled Release Granule (CR-GR) formulation include but not limited to Copolymer of propylene oxide (PO) and ethylene oxide (EO) and/or an ethoxylated tristyrene phenol, copolymer of PO and EO is alpha-butyl-omega-hydroxypoly (oxypropylene) block polymer with poly(oxyethylene), ethoxylated tristyrene phenol is alpha-[2,4,6-tris[l-(phenyl)ethyl] phenyl]-omega-hydroxy poly(oxyethylene, poly(oxy-l,2-ethanediyl)-alpha-C10-15alkyl-omega-hydroxy phosphate or sulphate and/or a C10-13alkylbenzenesulfonic acid, tristyrylphenols, nonylphenols, dinonylphenol and octyl phenols, styryl phenol poly ethoxyester phosphate, alkoxylated C14-20fatty amines.
Examples of dispersants or dispersing agent used herein for SE (Suspo Emulsion) formulation includes but not limited to a conventionally available for example polyesters, polyamides, poly- carbonates, polyurea and polyurethanes, acrylic polymers and copolymers, styrene copolymers, butadiene copolymers, polysaccharides such as starch and cellulose derivatives, vinylalcohol, vinylacetate and vinylpyrrolidone polymers and copolymers, polyethers, epoxy, phenolic and melamine resins, polyolefins and define copolymers and mixtures thereof. Examples of preferred polymers are acrylate polymers such as poly(methacrylate), poly(ethyl methacrylate), poly(methylmethacrylate), acrylate copoylmers and styrene-acrylic copolymers as defined herein below, poly(styrene-co maleic anhydride), cellulosic polymers such as ethyl cellulose, cellulose acetate, cellulose acetatebutyrate, acetylated mono, di, and triglycerides, poly(vinylpyrrolidone), vinyl

acetate polymers and copolymers, poly(alkylene glycol), styrene butadiene copolymers, poly(orthoesters), alkyd resins, and mixtures of two or more of these. Polymers that are biodegradable are also useful in the present invention. As used herein, a polymer is biodegradable if is not water soluble, but is degraded over a period of several weeks when placed in an application environment. Examples of biodegradable polymers that are useful in the present invention include biodegradable polyesters, starch, polylactic acid starch blends, polylactic acid, poly(lactic acid-glycolic acid) copolymers, polydioxanone, cellulose esters, ethyl cellulose, cellulose acetate butyrate, starch esters, starch esteraliphatic polyester blends, modified corn starch, polycaprolactone, poly(namylmethacrylate), wood rosin, polyanhydrides, polyvinylalcohol, polyhydroxybutyratevalerate, biodegradable aliphatic polyesters, and polyhydroxybutyrate or mixtures thereof. The examples of dispersing agents are alkylated naphthalene sulfonate, sodium salt, sodium salt of naphthalene sulfonate condensate, sodium salt of alkyl naphthalene sulfonate, sodium ligno sulfonate, sodium ploycarboxylate, EO/PO block copolymer, phenol sulfonate, sodium methyl oleoyl taurate, styrene acrylic acid copolymer, propyleneoxide-ethyleneoxide-copolymer, polyethylene glycol 2,4,6-tristyrylphenyl ether, tristyrylphenol-polyglycol ether-phosphate, tristyrylphenole with 16 moles EO, tristyrylphenol-polyglycolether-phosphate, oleyl-polyglycolether with ethylene oxide, tallow fatty amine polyethylene oxide, nonylphenol polyglycolether with 9-10 moles ethylene oxide.
Antifoaming agent for the present formulation is selected from various compounds and selectively used according to the formulation. Generally, there are two types of antifoam agents, namely silicones and non-silicones. Silicones are usually aqueous emulsions of dimethyl poly siloxane while the non-silicone anti-foam agents are water- insoluble oils, such as octanol and nonanol, or silica. In both cases, the function of the anti-foam agent is to displace the surfactant from the air-water interface.
Examples of Antifoaming agent used herein for SE (Suspo Emulsion) formulation include but not limited to silicone oil, silicone compound, C10~C20 saturated fat acid compounds or C8~C10 aliphatic alcohols compound, silicone antifoam emulsion, dimethyl siloxane,

poly dimethyl siloxane, vegetable oil based antifoam, tallow based fatty acids, polyalkylene oxide modified polydimethylsiloxane.
Anti-freezing agent for the present formulation is selected from various compounds and selectively used according to the formulation.
Examples of Anti-freezing agent used herein for SE (Suspo Emulsion) formulation include but not limited to ethylene glycol, propane diols, glycerine or the urea, glycol (monoethylene glycol, diethylene glycol, polypropylene glycol, polyethylene glycol), glycerine, urea, magnesium sulfate heptahydrate, sodium chloride.
Preservative used herein for the SE (Suspo Emulsion) formulation include but not limited to propionic acid and its sodium salt, sorbic acid and its sodium or potassium salt, benzoic acid and its sodium salt, p-hydroxy benzoic acid sodium salt; methyl p-hydroxy benzoate; and biocide such as sodium benzoate, l,2-benzisothiazoline-3-one, 2-methyl-4-isothiazolin-3-one, 5-chloro-2- methyl-4-isothiazolin-3-one, potassium sorbate, para hydroxy benzoates or mixtures thereof.
Thickeners or gelling agents are used mainly in the formulation of suspension concentrates, emulsions and suspo-emulsions to modify the rheology or flow properties of the liquid and to prevent separation and settling of the dispersed particles or droplets. Thickening, gelling, and anti-settling agents generally fall into two categories, namely water-insoluble particulates and water-soluble polymers.
Examples of thickeners used herein for SE (Suspo Emulsion) formulation include various compound depending upon the nature of the composition. Thickening, gelling, and anti-settling agents generally fall into two categories, namely water-insoluble particulates and water-soluble polymers. It is possible to produce suspension concentrate formulations using clays and silicas. Examples of these types of materials, include, but are limited to, montmorillonite, e.g. bentonite; magnesium aluminum silicate; and attapulgite. Water-soluble polysaccharides have been used as thickening-gelling agents for many years. The types of polysaccharides most commonly used are natural extracts of seeds and 15 seaweeds are synthetic derivatives of cellulose or mixtures thereof. Examples of these types of materials include, but are not limited to, guar gum; locust bean gum; carrageenam;

xanthan gum; alginates; methyl cellulose; sodium carboxymethyl cellulose (SCMC); hydroxy ethyl cellulose (HEC) or mixtures thereof. Other types of anti -settling agents are based on modified starches, polyacrylates, polyvinyl 20 alcohol and polyethylene oxide or mixtures.
Suspension aid or the suspending agent in the present description denotes a natural or synthetic, organic or inorganic material with which the active substance is combined in order to facilitate its application to the plant, to the seeds or to the soil. This carrier is hence generally inert, and it must be agriculturally acceptable, in particular to the plant being treated. The carrier may be solid (clays, natural or synthetic silicates, silica, resins, waxes, solid fertilizers, and the like or mixtures thereof) or liquid (water, alcohols, ketones, petroleum fractions, aromatic or paraffinic hydrocarbons, chlorinated hydrocarbons, liquefied gases, and the like or mixtures thereof).
Examples of suspending agent used herein for SE (Suspo Emulsion) formulation include but not limited to Aluminum Magnesium Silicate, Bentonite clay, Silica, Attapulgite clay.
Controlled release agent used herein for Granule (GR) and Controlled Release Granule (CR-GR) formulation includes but not limited to xanthan gum, PVK, carboxy methyl celluloses, polyvinyl alcohols, gelatin, sodium carboxy methyl cellulose, hydroxyethyl cellulose, Sodium Polyacrylate, modified starch, parafin wax, polyvinyl acetate, montan wax and vinyl acetate, polyethylene glycol 6000, cationic hydro soluble polymer, C4 alkylated polyvinyl pyrrolidone.
Carrier for the present formulation is selected from selected from various compounds and selectively used according to the formulation.
Examples of Carries used herein for Granule (GR) and Controlled Release Granule (CR-GR) formulation include but not limited to Diatomaceous earth, attapulgite or zeolites, dolomite, limestone, silica, fly ash, hydrated lime, wheat flour, wood flour, ground wheat straw, cellulose and soy flour, bentonite, kaolin, attapulgite, diatomaceous earth, calcium carbonate, talc, muscovite mica, fused sodium potassium, aluminum silicate , perlite, talc and muscovite mica, urea, sulfur-coated urea, isobutylidene diurea, ammonium nitrate, ammonium sulfate, ammonium phosphate, triple super phosphate, phosphoric acid,

potassium sulfate, potassium nitrate, potassium metaphosphate, potassium chloride, dipotassium carbonate, potassium oxide and a combination of these. Calcium, magnesium, sulfur, iron, manganese, copper, zinc; oxides, humic acid, Wood floor, Calcium silicate, Cellulose granules, Magnesium stearate.
Examples of Solvents used herein for Granule (GR) and Controlled Release Granule (CR-GR) formulation include but not limited to Fatty acid methyl ester, cyclohexane, xylene, mineral oil or kerosene, mixtures or substituted naphthalenes, mixtures of mono- and polyalkylated aromatics, dibutyl phthalate or dioctyl phthalate, ethylene glycol monomethyl or monoethyl ether, butyrolactone, octanol, castor oil, soybean oil, cottonseed oil , epoxidised coconut oil or soybean oil, aromatic hydrocarbons, dipropyleneglycol monomethylether, polypropylene glycol [M.W. 2000-4000], polyoxyethylene polyoxypropylene glycols, polyoxypropylene polyoxyethylene glycols, diethyleneglycol, polyethylene glycol [M.W. 200-4000 amu], methoxy polyethylene glycols 350, 550, 750, 2000, 5000; glycerol, methyl oleate, n-octanol, alkyl phosphates such as tri-n-butyl phosphate, propylene carbonate and isoparaffinic, tetrahydrofurfuryl alcohol, gamma-butyrolactone, N-methyl-2-pyrrolidone, tetramethylurea, dimethylsulfoxide, N,N-dimethylacetamide , Diacetone alcohol, Polybutene, Propylene carbonate, Dipropylene glycol isomer mixture. All the said oils used as a solvents are procured from the vendor based in Gujarat State.
Example of solvents used herein for the SE (Suspo Emulsion) formulation includes but not limited to water, water soluble alcohols and dihydroxy alcohol ethers. Water soluble alcohol or lower alcohol (1-4 carbon atoms) includes-methanol, ethanol, n-propanol, isopropanol, n-butanol, tert-butanol. Macromolecular alcohol includes polyethylene glycol, sorbitol, glucitol etc., dihydroxy alcohol ethers includes dihydroxy alcohol alkyl ether or dihydroxy alcohol aryl ethers. The examples of dihydroxy alcohol alkyl ether include ethylene glycol methyl ether, diethylene glycol methyl ether, propylene glycol methyl ether, di-propylene glycol methyl ether, ethylene glycol ethyl ether, diethylene glycol ethyl ether, propylene glycol ethyl ether, di-propylene glycol ethyl ether, etc. The examples of dihydroxy alcohol aryl ethers include ethylene glycol phenyl ether, 5 diethylene glycol phenyl ether, propylene glycol phenyl ether, di-propylene glycol phenyl

ether, and the like. Any of the mentioned solvent can be used either alone or in combinations thereof. Paraffinic hydrocarbons, cyclohexanone, isophorone and ester solvents such as methyloleate, dimethylamide and morpholineamide derivatives of C6-C16 fatty acids, and mono-alkylene carbonates such as ethylene carbonate, propylene carbonate and butylene carbonates, dimethylsulfoxide (DMSO), 2-ethylhexanol and n-butanol, n-alkylpyrrolidones, fatty acid dimethyl esters, fatty acid esters, dibasic esters, aromatic hydrocarbons and/or aliphatic hydrocarbons, one or more dimethylamides, such as C8-dimethylamide, ClO-dimethylamide, C12-dimethylamide, ethylene glycol, propylene glycol, polyalkylene glycols, aromatic hydrocarbons, methylpyrrolidinone (NMP); dimethylformamide (DMF); dimethylisosorbide (DMI); isophorone; acetophenone; 1,3-dimethyl-2-imidazolidonone; lactate esters; dimethyl and diethylcarbonates; alcohols including methanol; ethanol; iso-propanol; n-propanol; n-butanol; iso-butanol; and tert-butanol; Methyl L-lactate, 2-Ethylhexyl L-lactate, Ethyl L-lactate, n-Butyl L-lactate, Octyl phenyl ethoxylates; N,N decanamide.
Examples of Colouring agents for Granule (GR) and Controlled Release Granule (CR-GR) formulation include but not limited to Crystal violet, Thalocyano dye chlorinated, Aerosol green FFB dye, Rodamine, Azo compound.
Example of emulsifier used herein for the Suspo-emulsion (SE) formulation includes but not limited to salts of dodecylbenzene sulphonate, e.g. Ca-salts or amine salts, and sulphonates of other C11-C16 alkylbenzenes, alkyl ether sulphates, alkylphenoletherphosphates and ester phosphates; non-ionic surfactants such as alkoxylated alcohols and alkylphenols, ethoxylated fatty acids, ethoxylated vegetable oils, e.g. ethoxylated castor oil, fatty acid esters, e.g. of sorbitol, and their ethoxylated derivatives, ethoxylated amines, and condensates of glycerol; and catanionic emulsifiers such as a cationic amine, optionally in combination with an alkyl sulphonate or ether sulphonate or ether phosphate, alkoxylated alcohols; alkoxylated alkylphenols; ethoxylated fatty acids; ethoxylated vegetable oils; ethoxylated tristyrylphenol; fatty acid esters of sorbitol and ethoxylated derivatives thereof; ethoxylated amines and condensates of glycerol; sulfonated alkylbenzenes in the range C11-C16 and salts thereof; alkyl ether sulphates; alkyletherphosphates; alkylphenoletherphosphates; or combinations thereof;

salts of phosphate esters of ethoxylated tristyryl phenol; salts of sulphated ethers of ethoxylated tristyryl phenol; or a catanionic system, wherein a cationic amine is present in combination with an alkylsulphonate, an alkylethersulphonate, an ether sulphate, or an ether phosphate such as an alkyletherphosphate, nonylphenol polyethoxy ethanols, castor oil polyglycol ethers, polyadducts of ethylene oxide and polypropylene, tributyl phenoxy polyethoxy ethanol, octyl phenoxy polyethoxy ethanol.
Examples of Stabilizers or stabilizing agent used herein for the Suspo-emulsion (SE) formulation includes but not limited to butylated hydroxytoluene (BHT) and epoxidized soybean oil (ESBO), Epichlorhydrin.
Buffering agent used herein for the SE (Suspo Emulsion) formulation includes but not limited to calcium hydroxyapatite, Potassium Dihydrogen Phosphate, Sodium Hydroxide, carbonated apatite, calcium carbonate, sodium bicarbonate, tricalcium phosphate, calcium phosphates, carbonated calcium phosphates, amine monomers, lactate dehydrogenase and magnesium hydroxide.
While the foregoing written description of the invention enables one of ordinary skill to make and use what is considered presently to be the best mode thereof, those of ordinary skill will understand and appreciate the existence of variations, combinations, and equivalents of the specific embodiment, method, and examples herein. The invention should therefore not be limited by the above described embodiment, method, and examples, but by all embodiments and methods within the scope and spirit of the invention. The invention shall now be described with reference to the following specific examples. It should be noted that the example(s) appended below illustrate rather than limit the invention, and that those skilled in the art will be able to design many alternative embodiments without departing from the scope of the present invention.
These and other aspects of the invention may become more apparent from the examples set forth herein below. These examples are provided merely as illustrations of the invention and are not intended to be construed as a limitation thereof.
EXAMPLE 1:

Granule (GR) (Granule / Soil Applied Granule) formulation of Florpyrauxifen benzyl 0.3% + Pretilachlor 6% + Chlorantraniliprole 0.4%

Chemical composition % (w/w)
Florpyrauxifen benzyl a.i. 0.30
Pretilachlor a.i. 6.00
Chlorantraniliprole a.i. 0.40
Wetting agent 3.00
Dispersing agent 1.00
Colourant 0.50
Solvent 4.00
Carrier 84.80
Total 100.00
Storage stability -
Florpyrauxifen benzyl 0.3% + Pretilachlor 6% + Chlorantraniliprole 0.4% GR (Granule / Soil Applied Granule):
Storage stability study in laboratory and at room temperature shows that Florpyrauxifen benzyl 0.3%+ Pretilachlor 6%+Chlorantraniliprole 0.4% GR formulation complies all the in-house parameters like active ingredients content, pH range, dustiness, dry sieve, attrition resistance, bulk density and moisture content.
Procedure: Manufacturing process of Granules (GR) / Soil Applied Granules (SAG):

Preparation of Granules (GR) / Soil Applied Granules (SAG):
Step 1 Charged required quantity of carrier into the booth mixture with help of bucket elevator, then add other raw material (as technical, solvent, Surfactant, stabilizer, and binder) into the booth mixture and at this point add filler and allow mixing for another 20 minutes for homogenization.
Step 2 After completion of raw material addition and proper mixing, stop booth mixture for sampling.
Step 3- Sample is sent for QC approval and approved material is unloaded into the approved packing materials as per the requirement.

EXAMPLE 2:
SE (Suspo Emulsion) formulation of Florpyrauxifen benzyl 5%+Bispyribac sodium 2%+Chlorantraniliprole 3%

Chemical composition % (w/w)
Florpyrauxifen benzyl a.i. 5.00
Bispyribac sodium a.i. 2.00
Chlorantramliprole a.i. 3.00
N,N decanamide 10.00
Octyl phenol Ethoxylate 10.00
Trisiloxane ethoxylate 5.00
Tristyrylphenol-polyglycolether-phosphate 4.50
Polyarylphenyl ether sulphate ammonium salt 1.00
Bentonite clay 2.00
Polydi emthyl si 1 oxane 0.30
2-bromo-2-nitropropane-l,3-diol 0.20
Polypropylene glycol 5.00
Xanthan gum 0.15
Water 51.85
Total 100.00
Storage stability-
SE (Suspo Emulsion) formulation of Florpyrauxifen benzyl 5%+Bispyribac sodium 2%+Chlorantraniliprole 3%
Storage stability study in laboratory (at 54±2 C & At 0±2 C temp, for 14 days) and at room temperature (for 12 months) shows that Florpyrauxifen benzyl 5%+Bispyribac sodium 2%+ Chlorantramliprole 3% SE (Suspo Emulsion) formulation complies all the in-house parameters like active ingredients content, suspensibility, pH range, pourability, specific gravity, viscosity, particle size and anti-foaming.
Procedure: Manufacturing process of Suspo Emulsion (SE) formulation:
Preparation of Suspo Emulsion (SE) formulation:


2% Gel Preparation: Charge the required quantity of water to a vessel, equipped with a high shear stirrer and start the agitation. Add the required amount of preservative. Mix until homogenous. Add the required amount of thickener and mix vigorously until it is fully wetted.

Step 2- Oil Phase: Charge solvent into the vessel and then add active technical slowly and if required, heat it for 50°C so that technical can be dissolved in solvent and then add emulsifier.
Step 3- Charge the required quantity of water to a vessel, equipped with bulk agitator and a high shear homogenizer and start agitation. Add the required amount of ant freezing agent and mix until uniform. Add the antifoaming agent and ensure that it is well dispersed. Add the wetting and dispersing agent and mix until uniform. Ensure that the dispersing agent is fully dispersed.
Step 4- Now add the active ingredient and continue agitating the vessel contents until all components get dissolved. Mill this pre-mix through a Colloid mill and subsequently through a Dyno mill to meet the specified particle size.
Step 5- Now add remaining antifoaming agent to this mill base to a vessel, equipped with bulk agitator. Mix until uniform.
Step 6- Now add oil phase in aqueous phase and stir for 30 minutes using homogenizer.
Step 7- Add the required amount of 2% aqueous pre-gel and also suspending agent and continue agitation until the formulation is homogeneous and has the target viscosity. Mix well.
Step 8- Final product is sent for QC approval.
Step 9- After approval, material is packed in required pack sizes.
EXAMPLE 3:
Most preferred formulations:

Compound A Compound B Compound C Active ingi (%) 'edients Formula
tion Strength
(%) Formul ation Type

A B C

Florpyrauxifen benzyl Pyrazosulfuron Chlorantranili prole 0.3 0.2 0.4 0.90 GR
Florpyrauxifen benzyl Penoxsulam Chlorantranili prole 0.3 0.2 0.4 0.90 GR
Florpyrauxifen benzyl Pyribenzoxim Chlorantranili prole 0.3 0.3 0.4 1.00 GR
Florpyrauxifen benzyl Bensulfuron methyl Chlorantranili prole 0.3 0.6 0.4 1.30 GR
Florpyrauxifen benzyl Cinmethylin Chlorantranili prole 0.3 1 0.4 1.70 GR

Florpyrauxifen benzyl Pyriftalid Chlorantranili prole 0.3 1.5 0.4 2.20 GR
Florpyrauxifen benzyl Pretilachlor Chlorantranili prole 0.3 6 0.4 6.70 GR
Florpyrauxifen benzyl Butachlor Chlorantranili prole 0.3 6 0.4 6.70 GR
Florpyrauxifen benzyl Pendimethalin Chlorantranili prole 0.3 7.5 0.4 8.20 GR
Florpyrauxifen benzyl Metamifop Chlorantranili prole 5 6 3 14.00 SE
Florpyrauxifen benzyl Cyhalofop butyl Chlorantranili prole 5 6 3 14.00 SE
Florpyrauxifen benzyl Fenoxaprop-P-ethyl Chlorantranili prole 5 6 3 14.00 SE
Florpyrauxifen benzyl Bispyribac sodium Cyantranilipro le 5 2 3 10.00 SE
Florpyrauxifen benzyl Triafamone Cyantranilipro le 5 5 5 15.00 OD
Florpyrauxifen benzyl Tefuryltrione Cyantranilipro le 5 8 5 18.00 OD
Florpyrauxifen benzyl Penoxsulam Tetraniliprole 5 2 4 11.00 OD
Florpyrauxifen benzyl Bentazon Tetraniliprole 2 30 1.6 33.60 SC
Florpyrauxifen benzyl Benzofenap Tetraniliprole 2 20 1.6 23.60 SC
BIOLOGICAL EXAMPLES:
Biological Examples:
The field experiments were carried out to judge the impact on crop safety. The ready mix samples has been developed and evaluated under field condition.
Example 1: Crop safety and weed control in rice, Oryza sativa
Crops: Rice/Paddy
No. of Treatments: As per treatment details
Plot size: 25 sq. mt.
Application Time: 5 DATP (Days after transplanting)
Application Method: The required quantity of ready mix granules has been bulked out by
mixing with sand and broadcasted manually.

Agronomic practices: All the required agronomic practices followed except herbicidal
application.
Observations:
Phytotoxicity: The observations on crop safety i.e. phytotoxicity or adverse effect of
treatments were recorded on 7th, 14th, 21st and 30th DAA (days after application). All the
visual phytotoxicity symptoms like plant yellowing, leaf scorching, bleaching, necrosis,
stunting, crinkling, epinasty, hyponasty recorded on the basis of entire plot in comparison
with untreated control (UTC) plot. Each individual visual symptoms were recorded on the
basis severity of injury i.e. from 0 to 100%. Plant height (cm) has been recorded at 30 DAA
and tiller count (number of tillers per sq.m.) has been recorded on 45 DAA.
Weed control: Weed count were recorded at 20 DAA (Days after Application by using
(100 cm x 100 cm=lm2) quadrant treatment wise in minimum 4 places randomly selected
in the plot. The weed control (%) calculated by using given formula.
Average number of weeds in treatment
Weed control (%)= 100 x 100
Average number of weeds in untreated control (UTC)
The weed control (%) data used in Colby's formula to calculate the synergism. A synergistic effect exists wherever the action of a combination of active ingredient is greater than the sum of the action of each of the components alone. Therefore, a synergistically effective amount or an effective amount of a synergistic composition or combination is an amount that exhibits greater pesticidal activity than the sum of the pesticidal activities of the individual components.

Colby's formula for calculating synergism between two active ingredient
XY
E = X + Y
100 Where,
E=Expected percent (°o) control by mixtiue or combination of Compound A and Compound B
in a defined dose X=Observed percent (%) control by Compound A Y=Observed percent (%) control by Compomid B
Observed percent (%) control
Ratio =
Expected percent (%) control
Ratio of O/E > 1, means synergism observed, 0/E>l, means antagonism. O/E =1, means additive effect. Higher the ratio means stronger the synergism
Colby's formula for calculating synergism between three active ingredients
E = (X+Y+ Z )-(XY + XZ+YZ) + (X Y Z)
100 10000
Wliere. E=Expected percent (%) control by mixture or combination of Compound A, Compound B and CompoundC in a defined dose X=Observed percent (%) control by Compound A Y=Observed percent (%) control by CompoundB Z=Observed percent (%) control by Compomid C
Observed percent (%) control
Colby's Ratio =
Expected percent (%) control
If ratio of O/E >1, means synergism observed, O/E < 1, means antagonism, O/E = 1, means additive reaction. Higher the ratio means stronger the synergism
Table 1: Treatment details

Treatment number Treatment details Use Rate
(gai/h)
Tl Florpyrauxifen benzyl 0.3%+Pyrazosulfuron ethyl 0.2%+Chlorantraniliprole 0.4% GR 30+20+40
T2 Florpyrauxifen benzyl 0.3%+Penoxsulam 0.2%+Chlorantraniliprole 0.4% GR 30+20+40
T3 Florpyrauxifen benzyl 0.3%+Pyribenzoxim 0.3%+Chlorantraniliprole 0.4% GR 30+30+40
T4 Florpyrauxifen benzyl 0.3%+Bensulfuron methyl 0.6%+Chlorantraniliprole 0.4% GR 30+60+40
T5 Florpyrauxifen benzyl 0.3%+Pretilachlor 6%+Chlorantraniliprole 0.4% GR 30+600+40
T6 Florpyrauxifen benzyl 0.3%+Pendimethalin 7.5%+Chlorantraniliprole 0.4% GR 30+750+40

T7 Florpyrauxifen benzyl 2.7% EC+Pyrazosulfuron ethyl 10% WP 30+20
T8 Florpyrauxifen benzyl 2.7% EC+Penoxsulam 21.7% SC 30+20
T9 Florpyrauxifen benzyl 2.7% EC+Pyribenzoxim 5% EC 30+30
T10 Florpyrauxifen benzyl 2.7% EC+Bensulfuron methyl 10% SC 30+60
Til Florpyrauxifen benzyl 2.7% EC+Pretilachlor 30% EC 30+600
T12 Florpyrauxifen benzyl 2.7% EC+Pendimethalin 30% EC 30+750
T13 Pyrazosulfuron ethyl 10% WP+Chlorantraniliprole 18.5% SC 20+40
T14 Penoxsulam 21.7% SC+Chlorantraniliprole 18.5% SC 20+40
T15 Pyribenzoxim 5% EC+Chlorantraniliprole 18.5% SC 30+40
T16 Bensulfuron methyl 10% SC+Chlorantraniliprole 18.5% SC 60+40
T17 Pretilachlor 30% EC+Chlorantraniliprole 18.5% SC 600+40
T18 Pendimethalin 30% EC+Chlorantraniliprole 18.5% SC 750+40
T19 Florpyrauxifen benzyl 2.7% EC+Chlorantraniliprole 18.5% SC 30+40
T20 Florpyrauxifen benzyl 2.7% EC 30
T21 Pyrazosulfuron ethyl 10% WP 20
T22 Penoxsulam 21.7% SC 20
T23 Pyribenzoxim 5% EC 30
T24 Bensulfuron methyl 10% SC 60
T25 Pretilachlor 30% EC 600
T26 Pendimethalin 30% EC 750
T27 Chlorantraniliprole 18.5% SC 40
T28 Untreated control (UTC) -
T7 to T27- mixed with sand and broadcasted, GR Granule, EC Emulsifiable concentrate, WP Wettable powder, SC Suspension concentrate
Table 2: Synergistic weed control in rice

Treatment number Weed control (%) on 20 DAA

Observed Value Calculated Value Colby's ratio Synergism
(Y/N)
Tl 95.6 85.14 1.12 Y

T2 96.2 87.53 1.10 Y
T3 97.8 88.29 1.11 Y
T4 96.4 87.97 1.10 Y
T5 98.2 89.11 1.10 Y
T6 98.4 89.67 1.10 Y
T7 95.2 84.99 1.12 Y
T8 95.8 87.41 1.10 Y
T9 97.2 88.17 1.10 Y
T10 95.6 87.85 1.09 Y
Til 97.8 89.00 1.10 Y
T12 98.0 89.57 1.09 Y
T13 52.2 53.27 0.98 N
T14 60.0 60.80 0.99 N
T15 62.2 63.17 0.98 N
T16 61.4 62.18 0.99 N
T17 65.0 65.75 0.99 N
T18 66.8 67.53 0.99 N
T19 67.8 68.52 0.99 N
T20 68.2
T21 52.8
T22 60.4
T23 62.8
T24 61.8
T25 65.4
T26 67.2
T27 1.0
T28 0.0
Weed flora of trial plot: Grassy weeds (Echinochloa colonum, Leptochloa chinensis), Broad leaf weeds (Eclipta alba, Ammania baccifera), Sedges (Cyperus irria, Fibristylis spp.). DAA Days after application.
All the ready mix granules (Tl to T6) provides synergistic control of weeds.
Table 3: Phytotoxicity and yield parameters in maize crop

Treatment number Yellowing (%) Plant height (cm) at
45 DAA Increase(%)
in plant height over Number
of tillers/1 sq.m. at 45 DAA Increase(%)
in tillers
over

7 DAA 14 DAA 21 DAA 30 DAA

Tl 5.0 0.0 0.0 0.0 53.6 8.94 (over T7) 258 14.80 (over T7)
T2 5.0 0.0 0.0 0.0 54.2 8.84 (over T8) 251 16.38 (over T8)
T3 5.0 0.0 0.0 0.0 53.2 9.02 260 14.80

(over T9) (over T9)
T4 5.0 0.0 0.0 0.0 54.0 10.20 (overT10) 255 16.38 (overT10)
T5 5.0 0.0 0.0 0.0 53.4 8.54 (over Til) 258 16.38 (over Til)
T6 5.0 0.0 0.0 0.0 54.4 10.12 (over T12) 253 16.38 (overT12)
T7 10.0 10.0 5.0 0.0 49.2 232
T8 10.0 10.0 5.0 0.0 49.8 228
T9 10.0 10.0 5.0 0.0 48.8 230
T10 10.0 10.0 5.0 0.0 49.0 229
Til 10.0 10.0 5.0 0.0 49.2 227
T12 10.0 10.0 5.0 0.0 49.4 228
T13 0.0 0.0 0.0 0.0 51.6 242
T14 0.0 0.0 0.0 0.0 52.2 241
T15 0.0 0.0 0.0 0.0 51.6 240
T16 0.0 0.0 0.0 0.0 50.8 244
T17 0.0 0.0 0.0 0.0 50.2 241
T18 0.0 0.0 0.0 0.0 51.0 243
T19 0.0 0.0 0.0 0.0 50.6 242
T20 0.0 0.0 0.0 0.0 41.4 220
T21 0.0 0.0 0.0 0.0 40.6 221
T22 0.0 0.0 0.0 0.0 41.0 219
T23 0.0 0.0 0.0 0.0 39.8 223
T24 0.0 0.0 0.0 0.0 40.6 220
T25 0.0 0.0 0.0 0.0 40.2 217
T26 0.0 0.0 0.0 0.0 39.8 218
T27 0.0 0.0 0.0 0.0 40.0 222
T28 0.0 0.0 0.0 0.0 38.8 216
All the innovative treatments (Tl to T6) shows excellent crop safety and produces higher
number of productive tillers in comparison to conventional treatments (T7 to T12)
respectively.
Example 2: Crop safety and weed control in rice, Oryza sativa
Crops: Rice/Paddy
No. of Treatments: As per treatment details
Plot size: 20 sq. mt.
Application Time: 22 DATP (Days after transplanting)
Application Method: Foliar spray with backpack sprayer fitted with flatfan nozzle

Agronomic practices: All the required agronomic practices followed except herbicidal
application.
Observations:
Phytotoxicity: As given in Experiment 1
Weed control: As given in Experiment 1
Table 4: Treatment details

Treatment number Treatment details Rate
(gai/h)
Tl Florpyrauxifen benzyl 5%+Metamifop 6%+Chlorantraniliprole 3% SE 50+60+30
T2 Florpyrauxifen benzyl 5%+Cyhalofop butyl 10%+Chlorantraniliprole 3% SE 50+60+30
T3 Florpyrauxifen benzyl 5%+Fenoxaprop-P-ethyl 6%+Chlorantraniliprole 3% SE 50+60+30
T4 Florpyrauxifen benzyl 5%+Bispyribac sodium 2%+Chlorantraniliprole 3% SE 50+20+30
T5 Florpyrauxifen benzyl 2.7% EC+Metamifop 10% EC 50+60
T6 Florpyrauxifen benzyl 2.7% EC+Cyhalofop butyl 10% EC 50+60
T7 Florpyrauxifen benzyl 2.7% EC+Fenoxaprop-P-ethyl 10% EC 50+60
T8 Florpyrauxifen benzyl 2.7% EC+Bispyribac sodium 10% SC 50+20
T9 Metamifop 10%EC+Chlorantraniliprole 18.5% SC 60+30
T10 Cyhalofop butyl 10% EC+Chlorantraniliprole 18.5% SC 60+30
Til Fenoxaprop-P-ethyl 10% EC+Chlorantraniliprole 18.5% SC 60+30
T12 Bispyribac sodium 10% SC+Chlorantraniliprole 18.5% SC 20+30
T13 Florpyrauxifen benzyl 2.7% EC+Chlorantraniliprole 18.5% SC 50+30
T14 Florpyrauxifen benzyl 2.7% EC 50
T15 Metamifop 10% EC 60
T16 Cyhalofop butyl 10% EC 60
T17 Fenoxaprop-P-ethyl 10% EC 60
T18 Bispyribac sodium 10% SC 20
T19 Chlorantraniliprole 18.5% SC 30
T20 Untreated control (UTC) -

Weed flora of trial plot: Grassy weeds (Echinochloa crusgalli, Panicum spp., Leptochloa chinensis), Broad leaf weeds (Marsilea minuta, Cyanotis spp.), Sedges (Cyperus difformis), DAA Days after application.
All the ready mix granules (Tl to T4) provides synergistic control of weeds.
Table 5: Weed control

Treatment number Yellowing (%) Plant height (cm) at
20 DAA Increase(%) in
plant height
over Number
of tillers/1 sq.m. at 20 DAA Increase(%) in tillers over

7 DAA 14 DAA 20 DAA

Tl 0.0 0.0 0.0 50.2 6.36 (over T5) 246 4.24 (over T5)
T2 0.0 0.0 0.0 51.4 6.64 (over T6) 247 4.22 (over T6)
T3 0.0 0.0 0.0 50.4 6.33 (over T7) 245 4.26 (over T7)
T4 0.0 0.0 0.0 51.0 6.25 (over T8) 246 3.80 (over T8)
T5 10.0 5.0 0.0 47.2 236
T6 10.0 5.0 0.0 48.2 237
T7 10.0 5.0 0.0 47.4 235
T8 10.0 5.0 0.0 48.0 237
T9 0.0 0.0 0.0 48.8 241
T10 0.0 0.0 0.0 49.2 242
Til 0.0 0.0 0.0 48.4 240
T12 0.0 0.0 0.0 49.0 241
T13 0.0 0.0 0.0 48.6 242
T14 5.0 0.0 0.0 48.2 232
T15 5.0 0.0 0.0 47.2 230
T16 5.0 0.0 0.0 47.6 231
T17 5.0 0.0 0.0 47.0 232
T18 5.0 0.0 0.0 46.8 230
T19 0.0 0.0 0.0 47.4 231
T20 0.0 0.0 0.0 46.8 230
All the innovative treatments (Tl to T4) shows excellent crop safety and produces higher number of productive tillers in comparison to conventional treatments (T5 to T8) respectively.

CLAIMS

We claim;

[CLAIM 1]. A synergistic agrochemical composition comprising:
a. a herbicide Florpyrauxifen benzyl present in amount of 0.1 to 80%
by weight;
b. a herbicide compound selected from the group of various class of
compounds or mixture thereof present in amount of 0.001% - 80%
by weight;
c. an insecticide selected the class of diamide, metadiamide or
isoxazoline or mixture thereof present in amount of 0.1% - 30% by
weight;
d. inactive formulation excipients.
[CLAIM 2]. The synergistic agrochemical composition as claimed in claim 1, wherein a herbicide compound
from Acetyl CoA Carboxylase (ACCase) is selected from clodinafop-propargyl, cyhalofop-butyl, fenoxaprop-P, fluazifop-P, haloxyfop, metamifop, propaquizafop, quizalofop-P-ethyl, pinoxaden; from Acetolactate Synthase (ALS) or Acetohydroxy Acid Synthase (AHAS) inhibitor is selected from azimsulfuron, bensulfuron methyl, chlorimuron ethyl, ethoxysulfuron, flucetosulfuron, halosulfuron methyl, imazosulfuron, iodosulfuron, mesosulfuron, metsulfuron mehtyl, propyrisulfuron, pyrazosulfuron ehtyl, sulfosulfuron, bispyribac-sodium, pyribenzoxim, penoxsulam, pyroxsulam, flucarbazone-sodium, thiencarbazone-methyl, imazamox, imazapic, imazapyr, imazaquin, imazethapyr, triafamone;
from Inhibitor of microtubule assembly is selected from pendimethalin; from Synthetic Auxin is selected from 2,4-D, aminopyralid, clopyralid, fluroxypyr, picloram, triclopyr, quinclorac, halauxifen methyl; from Inhibitor of photosynthesis at photosystem II site B bentazone;

from Inhibitor of 1-deoxy-D-xyulose 5-phosphate synthatase (DOXP
synthase) of Isoxazolidinone group is clomazone;
from Inhibitor of protoporphyrinogen oxidase (Protox, PPO) is selected
from aclifluorfen, bifenox, fluoroglycofen, fomesafen, lactofen,
carfentrazone-ethyl, sulfentrazone, saflufenacil, flumiclorac, oxadiargyl,
oxadiazon, pyraclonil, tiafenacil, cyclopyranil;
from Mitosis Inhibitor is selected from butachlor, pretilachlor, S-
metolachlor, fentrazamide, flufenacet, mefenacet, anilofos, carbetamide;
from Inhibitor of 7,8-dihydro-preroate synthetase (DHP) of Carbamate
group is asulam;
from Inhibitor of Hydroxyphenyl Pyruvate Dioxygenase (4-HPPD) is
selected from benzofenap, pyrasulfotole, pyrazolynate, pyrazoxyfen,
tolpyralate, benzobicyclon, mesotrione, tembotrione, sulcotrione,
tefuryltrione, fenquinotrione, lancotrione sodium, isoxaflutole,
bicyclopyrone, topramezone;
from Tyrosine Aminotransferase is cinmethylin;
from Inhibitors of dihydroorotate dehydrogenase (DHODH) is
tetflupyrolimet;
from HTS (homogentisate solanesyltransferase)-a downstream enzyme of
HPPD is cyclopyrimorate;
from VLCAFE inhibitors is selected from pyroxasulfone, ipfencarbazone,
dimesulfazet, fenoxasulfone;
from Inhibitors of Solanesyl Diphosphate Synthase (SDS) is aclonifen;
with unknown mode of action is selected from bromobutide, fenclorim,
epyrifenacil, bixzolone;
[CLAIM 3]. The synergistic agrochemical composition as claimed in claim 1, wherein an insecticide of diamides class is selected from chlorantraniliprole, cyantraniliprole, cyclaniliprole, cyhalodiamide, cyproflanilide, flubendiamide, tetraniliprole, tetrachlorantramliprole, tyclopyrazoflor; of

class of metadiamides is broflanilide; of class of isoxazolines is selected from fluxametamide, isocycloseram.
[CLAIM 4]. The synergistic agrochemical composition as claimed in claim 1, wherein, the formulation for the said composition is selected from Capsule suspension (CS), Dispersible concentrate (DC), Emulsifiable concentrate (EC), Emulsion, water in oil (EO), Emulsion, oil in water (EW), Jambo balls or bags (bags in water soluble pouch), Micro-emulsion (ME), Oil dispersion (OD), Oil miscible flowable concentrate (oil miscible suspension (OF), Oil miscible liquid (OL), Suspension concentrate (SC), Suspo-emulsion (SE), Soluble concentrate (SL), Water dispersible granule (WG or WDG), Water soluble granule (SG), Water soluble powder (SP), Wettable powder (WP), A mixed formulation of CS and SC (ZC), A mixed formulation of CS and SE (ZE), A mixed formulation of CS and EW (ZW), Granule (GR) / Soil Applied Granules (SAG), Controlled release granules (CR).
[CLAIM 5]. The synergistic agrochemical composition as claimed in claim 1-claim 4, wherein the preferred combinations of active ingredients in the composition of Granule (GR) (Granule / Soil Applied Granule) formulation comprises:
i. Florpyrauxifen benzyl 0.3 % + Pyrazo sulfur on 0.2 % +
Chlorantraniliprole 0.4 %; ii. Florpyrauxifen benzyl 0.3 % + Penoxsulam 0.2 % +
Chlorantraniliprole 0.4 %; iii. Florpyrauxifen benzyl 0.3 % + Pyribenzoxim 0.3 % +
Chlorantraniliprole 0.4 %; iv. Florpyrauxifen benzyl 0.3 % + Bensulfuron methyl 0.6 % +
Chlorantraniliprole 0.4 %; v. Florpyrauxifen benzyl 0.3 % + Cinmethylin 1 % +
Chlorantraniliprole 0.4 %; vi. Florpyrauxifen benzyl 0.3 % + Pyriftalid 1.5 % +
Chlorantraniliprole 0.4 %; vii. Florpyrauxifen benzyl 0.3 % + Pretilachlor 6 % +
Chlorantraniliprole 0.4 %;

Vlll.
IX.

Florpyrauxifen benzyl 0.3 % + Butachlor 6 % + Chlorantraniliprole 0.4 %;
Florpyrauxifen benzyl 0.3 % + Pendimethalin 7.5% + Chlorantraniliprole 0.4 %.

[CLAIM 6]. The synergistic agrochemical composition as claimed in claim 1 and claim 5, wherein the Granule (GR) (Granule / Soil Applied Granule) formulation comprises:
i. a herbicide Florpyrauxifen benzyl present in amount of 0.1 to 80%
by weight; ii. a herbicide compound selected from Pyrazosulfuron, Penoxsulam, Pyribenzoxim, Bensulfuron methyl, Cinmethylin, Pyriftalid, Pretilachlor, Butachlor, Pendimethalin for control of broad-leaved weeds and grassy weeds and sedges in economical crops or mixture thereof present in amount of 0.001% - 80% by weight; iii. an insecticide is Chlorantraniliprole as safener for reducing phytotoxicity in crops treated with a herbicide or mixture thereof present in amount of 0.1% - 30% by weight; iv. Wetting agent in an amount of 2 to 6 % by weight; v. Dispersing agent in an amount of lto 3 % by weight; vi. Colourant in an amount of 0.2 to 1.0 % by weight; vii. Solvent in an amount of 2 to 8 % by weight; viii. Carrier in an amount of 50 to 80% by weight
[CLAIM 7]. The synergistic agrochemical composition as claimed in 6, wherein wetting agent is selected from Mono C2-6 alkyl ether of a poly C2-4alkylene oxide block copolymer, condensation product of castor oil and polyC2-4alkylene oxide, alkoxylated castor oil is available under the trade name Agnique CSO-36, a mono- or di-ester of a C12-24fatty acid and polyC2-4alkylene oxide, carboxylates, sulphates, sulphonates, alcohol ethoxylates, alkyl phenol ethoxylates, fatty acid ethoxylates, sorbitan esters, ethoxylated fats or oils, amine ethoxylates, phosphate esters,

ethylene oxide - propylene oxide copolymers, fluorocarbons, alkyd-polyethylene glycol resin, polyalkylene glycol ether, apolyalkoxylated nonyl phenyl, alkoxylated primary alcohol, ethoxylated distyrylphenol, ethoxylated distyrylphenol sulphate, ethoxylated tristyrylphenol phosphate, tristyrylphenol phosphate ester, hydroxylated stearic acid polyalkylene glycol polymer, and their corresponding salts,alkyd-polyethylene glycol resin, polyalkylene glycol ether, ethoxylated distyrylphenol, ethoxylated distyrylphenol sulphate, ethoxylated tristyrylphenol phosphate, tristyrylphenol phosphate ester, tristyrylphenol phosphate potassium salt, dodecysulfate sodium salt.
[CLAIM 8]. The synergistic agrochemical composition as claimed in 6, wherein Dispersing agent is selected from copolymer of propylene oxide (PO) and ethylene oxide (EO) and/or an ethoxylated tristyrene phenol, copolymer of PO and EO is alpha-butyl-omega-hydroxypoly (oxypropylene) block polymer with poly(oxyethylene), ethoxylated tristyrene phenol is alpha-[2,4,6-tris[l-(phenyl)ethyl] phenyl]-omega-hydroxy poly(oxyethylene, poly(oxy-l,2-ethanediyl)-alpha-C10-15alkyl-omega-hydroxy phosphate or sulphate and/or a C10-13 alkylbenzene sulfonic acid, tristyrylphenols, nonylphenols, dinonylphenol and octyl phenols, styryl phenol polyethoxyester phosphate, alkoxylated CI4-20 fatty amines.
[CLAIM 9]. The synergistic agrochemical composition as claimed in 6, wherein solvent is selected from Fatty acid methyl ester, cyclohexane, xylene, mineral oil or kerosene, mixtures or substituted naphthalenes, mixtures of mono- and polyalkylated aromatics, dibutyl phthalate or dioctyl phthalate, ethylene glycol monomethyl or monoethyl ether, butyrolactone, octanol, castor oil, soybean oil, cottonseed oil , epoxidised coconut oil or soybean oil, aromatic hydrocarbons, dipropyleneglycol monomethylether, polypropylene glycol [M.W. 2000-4000], polyoxyethylene polyoxypropylene glycols, polyoxypropylene polyoxyethylene glycols,

diethyleneglycol, polyethylene glycol [M.W. 200-4000 amu], methoxy
polyethylene glycols 350, 550, 750, 2000, 5000; glycerol, methyl oleate,
n-octanol, alkyl phosphates such as tri-n-butyl phosphate, propylene
carbonate and isoparaffmic, tetrahydrofurfuryl alcohol, gamrna-
butyrolactone, N-methyl-2-pyrrolidone, tetramethylurea,
dimethylsulfoxide, N,N-dimethylacetamide , Diacetone alcohol, Polybutene, Propylene carbonate, Dipropylene glycol isomer mixture.
[CLAIM 10]. The synergistic agrochemical composition as claimed in 6, wherein Carrier is selected from Diatomaceous earth, attapulgite or zeolites, dolomite, limestone, silica, fly ash, hydrated lime, wheat flour, wood flour, ground wheat straw, cellulose and soy flour, bentonite, kaolin, attapulgite, diatomaceous earth, calcium carbonate, talc, muscovite mica, fused sodium potassium, aluminum silicate , perlite, talc and muscovite mica, urea, sulfur-coated urea, isobutylidene diurea, ammonium nitrate, ammonium sulfate, ammonium phosphate, triple super phosphate, phosphoric acid, potassium sulfate, potassium nitrate, potassium metaphosphate, potassium chloride, dipotassium carbonate, potassium oxide and a combination of these, calcium, magnesium, sulfur, iron, manganese, copper, zinc; oxides, humic acid, Wood floor, Calcium silicate, Cellulose granules, Magnesium stearate.
[CLAIM 11]. The synergistic agrochemical composition as claimed in 6, wherein colouring agent is selected from Crystal violet, Thalocyano dye chlorinated, Aerosol green FFB dye, Rodamine, Azo compound.
[CLAIM 12]. The synergistic agrochemical composition as claimed in 6, wherein Controlled release agent is selected from Xanthan gum, PVK, carboxymethyl celluloses, polyvinyl alcohols, gelatin, sodium carboxymethylcellulose, hydroxyethylcellulose, Sodium Polyacrylate,

modified starch, Parafin wax, Polyvinyl acetate, Montan wax and vinyl acetate, Polyethylene Glycol 6000, Cationic hydrosoluble polymer, C4 alkylated Polyvinyl pyrrolidone.
[CLAIM 13]. The synergistic agrochemical composition as claimed in claim 1-claim 4,
wherein the preferred combinations of active ingredients in the
composition of Suspo-emulsion (SE) formulation comprises:
i. Florpyrauxifen benzyl 5% + Metamifop 6% + Chlorantraniliprole
3%; ii. Florpyrauxifen benzyl 5% + Cyhalofop butyl 6% +
Chlorantraniliprole 3%; iii. Florpyrauxifen benzyl 5% + Fenoxaprop-P-ethyl 6% +
Chlorantraniliprole 3%; iv. Florpyrauxifen benzyl 5% + Bispyribac sodium 2% + Cyantraniliprole 3%.
[CLAIM 14]. The synergistic agrochemical composition as claimed in claim 1-claim 4, wherein the Suspo-emulsion (SE) formulation comprises:
i. a herbicide Florpyrauxifen benzyl present in amount of 0.1 to 80%
by weight; ii. a herbicide compound selected from Metamifop, Cyhalofop butyl, Fenoxaprop-P-ethyl, Bispyribac sodium for control of broad-leaved weeds and grassy weeds and sedges in economical crops or mixture thereof present in amount of 0.001% - 80% by weight; iii. an insecticide is selected from Chlorantraniliprole and Cyantraniliprole as safener for reducing phytotoxicity in crops treated with a herbicide or mixture thereof present in amount of 0.1%-30% by weight; iv. Solvent in an amount of 8 to 12 % by weight; v. Wetting-spreading-penetrating agent in an amount of 2 to 6 % %
by weight; vi. Dispersing agent 1 in an amount of 2 to 8 % by weight; vii. Dispersing agent 2 in an amount of lto 3 % by weight;

viii. Suspending agent in an amount of 0.2 to 4.0 % by weight;
ix. Antifoaming agent in an amount of 0.1 to 1.5 % by weight;
x. Preservative in an amount of 0.1 to 0.5 % by weight;
xi. Anti-freezing agent in an amount of 2 to 6 % by weight;
xii. Thickener in an amount of 0.1 to 1.0 % by weight;
xiii. Diluent Water in an amount of 40 to 70 % by weight.
[CLAIM 15]. The synergistic agrochemical composition as claimed in 6, wherein solvent is selected from water, water soluble alcohols and dihydroxy alcohol ethers. Water soluble alcohol or lower alcohol (1-4 carbon atoms) includes-methanol, ethanol, n-propanol, isopropanol, n-butanol, tert-butanol. Macromolecular alcohol includes polyethylene glycol, sorbitol, glucitol etc., dihydroxy alcohol ethers includes dihydroxy alcohol alkyl ether or dihydroxy alcohol aryl ethers; the examples of dihydroxy alcohol alkyl ether include ethylene glycol methyl ether, diethylene glycol methyl ether, propylene glycol methyl ether, di-propylene glycol methyl ether, ethylene glycol ethyl ether, diethylene glycol ethyl ether, propylene glycol ethyl ether, di-propylene glycol ethyl ether; the examples of dihydroxy alcohol aryl ethers include ethylene glycol phenyl ether, 5 diethylene glycol phenyl ether, propylene glycol phenyl ether, di-propylene glycol phenyl ether, and the like, Paraffinic hydrocarbons, cyclohexanone, isophorone and ester solvents such as methyloleate, dimethylamide and morpholineamide derivatives of C6-C16 fatty acids, and mono-alkylene carbonates such as ethylene carbonate, propylene carbonate and butylene carbonates, dimethylsulfoxide (DMSO), 2-ethylhexanol and n-butanol, n-alkylpyrrolidones, fatty acid dimethyl esters, fatty acid esters, dibasic esters, aromatic hydrocarbons and/or aliphatic hydrocarbons, one or more dimethylamides, such as C8-dimethylamide, ClO-dimethylamide, C12-dimethylamide, ethylene glycol, propylene glycol, polyalkylene glycols, aromatic hydrocarbons, methylpyrrolidinone (NMP); dimethylformamide (DMF); dimethylisosorbide (DMI); isophorone; acetophenone; 1,3-

dimethyl-2-imidazolidonone; lactate esters; dimethyl and diethylcarbonates; alcohols including methanol; ethanol; iso-propanol; n-propanol; n-butanol; iso-butanol; and tert-butanol; Methyl L-lactate, 2-Ethylhexyl L-lactate, Ethyl L-lactate, n-Butyl L-lactate, Octyl phenyl ethoxylates, N,N decanamide.
[CLAIM 16]. The synergistic agrochemical composition as claimed in 6, wherein emulsifier or emulsifying agent is selected from salts of dodecylbenzene sulphonate, e.g. Ca-salts or amine salts, and sulphonates of other CI 1-C16 alkylbenzenes, alkylether sulphates, alkylphenoletherphosphates and ester phosphates; non-ionic surfactants such as alkoxylated alcohols and alkylphenols, ethoxylated fatty acids, ethoxylated vegetable oils, e.g. ethoxylated castor oil, fatty acid esters, e.g. of sorbitol, and their ethoxylated derivatives, ethoxylated amines, and condensates of glycerol; and catanionic emulsifiers such as a cationic amine, optionally in combination with an alkylsulphonate or ether sulphonate or ether phosphate, alkoxylated alcohols; alkoxylated alkylphenols; ethoxylated fatty acids; ethoxylated vegetable oils; ethoxylated tristyrylphenol; fatty acid esters of sorbitol and ethoxylated derivatives thereof; ethoxylated amines and condensates of glycerol; sulfonated alkylbenzenes in the range Cll-C16and salts thereof; alkylether sulphates; alkyletherphosphates; alkylphenoletherphosphates; or combinations thereof; salts of phosphate esters of ethoxylated tristyrylphenol; salts of sulphated ethers of ethoxylated tristyrylphenol; or a catanionic system, wherein a cationic amine is present in combination with an alkylsulphonate, an alkylethersulphonate, an ether sulphate, or an ether phosphate such as an alkyletherphosphate, nonylphenol polyethoxy ethanols, castor oil polyglycol ethers, polyadducts of ethylene oxide and polypropylene, tributyl phenoxy polyethoxy ethanol, octyl phenoxy polyethoxy ethanol.

[CLAIM 17]. The synergistic agrochemical composition as claimed in 6, wherein stabilizer is selected from butylated hydroxytoluene (BHT) and epoxidized soybean oil (ESBO), Epichlorhydrin.
[CLAIM 18]. The synergistic agrochemical composition as claimed in 6, wherein wetting agent is selected from Ethylene oxide/propylene oxide block copolymer, Polyarylphenyl ether phosphate, Ethoxylated Fatty Alcohol, Sodium dioctyl sulfosuccinate, sodium lauryl sulphate and sodium dodecyl benzene sulfonate, alkyl diphenyl sulfonates, sodium isopropyl naphthalene sulfonate, Alkyl naphthalene sulfonate, Octyl phenol ethoxylate, alkyl phenol ethoxylate.
[CLAIM 19]. The synergistic agrochemical composition as claimed in 6, wherein Wetting-spreading-penetrating agent is selected from Organosilicone surfactants includes trisiloxane ethoxylate, polydimethylsiloxane, polyoxyethylene methyl polysiloxane, polyoxyalkylene methyl polysiloxane, polyether polymethyl siloxane copolymer, heptamethyl trisiloxane, Polyalkyleneoxide modified heptamethyl trisiloxane, heptamethyl trisiloxane ethoxylate, polyether modified polysiloxane, 10 mole ethylene oxide adduct of octylphenol, may or may not be in modified form, may be liquid or powder form or mixture thereof.
[CLAIM 20]. The synergistic agrochemical composition as claimed in 6, wherein thickener is selected from montmorillonite, e.g. bentonite; magnesium aluminum silicate; and attapulgite. Water-soluble polysaccharides have been used as thickening-gelling agents for many years. The types of polysaccharides most commonly used are natural extracts of seeds and 15 seaweeds are synthetic derivatives of cellulose or mixtures thereof. Examples of these types of materials include, but are not limited to, guar gum; locust bean gum; carrageenam; xanthan gum; alginates; methyl cellulose; sodium carboxymethyl cellulose (SCMC); hydroxyethyl

cellulose (HEC) or mixtures thereof. Other types of anti-settling agents are based on modified starches, polyacrylates, polyvinyl 20 alcohol and polyethylene oxide or mixtures.
[CLAIM 21]. The synergistic agrochemical composition as claimed in 6, wherein dispersing agent is selected from polyesters, polyamides, poly- carbonates, polyurea and polyurethanes, acrylic polymers and copolymers, styrene copolymers, butadiene copolymers, polysaccharides such as starch and cellulose derivatives, vinylalcohol, vinylacetate and vinylpyrrolidone polymers and copolymers, polyethers, epoxy, phenolic and melamine resins, polyolefins and define copolymers and mixtures thereof. Examples of preferred polymers are acrylate polymers such as poly(methacrylate), poly(ethyl methacrylate), poly(methylmethacrylate), acrylate copoylmers and styrene-acrylic copolymers as defined herein below, poly(styrene-co maleic anhydride), cellulosic polymers such as ethyl cellulose, cellulose acetate, cellulose acetatebutyrate, acetylated mono, di, and triglycerides, poly(vinylpyrrolidone), vinyl acetate polymers and copolymers, poly(alkylene glycol), styrene butadiene copolymers, poly(orthoesters), alkyd resins, and mixtures of two or more of these. Polymers that are biodegradable are also useful in the present invention. As used herein, a polymer is biodegradable if is not water soluble, but is degraded over a period of several weeks when placed in an application environment. Examples of biodegradable polymers that are useful in the present invention include biodegradable polyesters, starch, polylactic acid starch blends, polylactic acid, poly(lactic acid-glycolic acid) copolymers, polydioxanone, cellulose esters, ethyl cellulose, cellulose acetate butyrate, starch esters, starch ester aliphatic polyester blends, modified corn starch, polycaprolactone, poly(namylmethacrylate), wood rosin, polyanhydrides, polyvinylalcohol, polyhydroxybutyratevalerate, biodegradable aliphatic polyesters, and polyhydroxybutyrate or mixtures thereof. The examples of dispersing agents are alkylated naphthalene sulfonate, sodium salt, sodium

salt of naphthalene sulfonate condensate, sodium salt of alkyl naphthalene sulfonate, sodium ligno sulfonate, sodium ploycarboxylate, EO/PO block copolymer, phenol sulfonate, sodium methyl oleoyl taurate, styrene acrylic acid copolymer, propyleneoxide-ethyleneoxide-copolymer, polyethylene glycol 2,4,6-tristyrylphenyl ether, tristyrylphenol-polyglycolether-phosphate, tristyrylphenole with 16 moles EO, tristyrylphenol-polyglycolether-phosphate, oleyl-polyglycolether with ethylene oxide, tallow fattyamine polyethylene oxide, nonylphenol polyglycolether with 9-10 moles ethylene oxide.
[CLAIM 22]. The synergistic agrochemical composition as claimed in 6, wherein buffering agent is selected from calcium hydroxyapatite, Potassium Dihydrogen Phosphate, Sodium Hydroxide, carbonated apatite, calcium carbonate, sodium bicarbonate, tricalcium phosphate, calcium phosphates, carbonated calcium phosphates, amine monomers, lactate dehydrogenase and magnesium hydroxide.
[CLAIM 23]. The synergistic agrochemical composition as claimed in 6, wherein Preservative is selected from calcium hydroxyapatite, Potassium Dihydrogen Phosphate, Sodium Hydroxide, carbonated apatite, calcium carbonate, sodium bicarbonate, tricalcium phosphate, calcium phosphates, carbonated calcium phosphates, amine monomers, lactate dehydrogenase and magnesium hydroxide.
[CLAIM 24]. The synergistic agrochemical composition as claimed in claim 1-claim 4,
wherein the preferred combinations of active ingredients in the
composition of Oil-Dispersion (OD) formulation comprises:
i. Florpyrauxifen benzyl 5%+Triafamone 5%+ Cyantraniliprole 5%; ii. Florpyrauxifen benzyl 5% + Tefuryltrione 8%+ Cyantraniliprole
5%; iii. Florpyrauxifen benzyl 5% + Penoxsulam 4% + Tetraniliprole 4%.

[CLAIM 25]. The synergistic agrochemical composition as claimed in claim 1-claim 4,
wherein the preferred combinations of active ingredients in the
composition of Suspension Concentrate (SC) formulation comprises:
i. Florpyrauxifen benzyl 2% + Bentazon 30% + Tetraniliprole 2%; ii. Florpyrauxifen benzyl 2% + Benzofenap 20% + Tetraniliprole
1.6%.
[CLAIM 26]. The synergistic agrochemical composition as claimed in claim 1, wherein crop safener for the monocotyledonous crops is selected from the cyprosulfamide, dietholate, isoxadifen / isoxadifen ethyl, dicyclonon, benoxacor, mefenpyr ethyl, fenchlorazole ethyl, cloquintocet / cloquintocet mexyl, oxabetrinil, naphthalic anhydride, mephenate, mefenpyr, furilazole, fluxofenim, flurazole, fenclorim, fenchlorazole, dichlormid, cyometrinil.