Technical field [0001] 　The present invention relates to a laminate and its use. BACKGROUND [0002] 　The industrial hose formed from rubber, strength, flexibility, heat resistance, flex resistance, various properties such as solvent resistance is required, one kind of difficult to satisfy all properties required in rubber it is. Therefore, it is laminated rubber having different properties is generally performed. [0003] 　When laminating a heterologous rubber, in the case of rubber having a polar but also be directly adhered to other rubbers, a method of adhering via an adhesive layer in the case of non-polar rubber is generally used. [0004] 　The automobile engine around the rubber hose, heat aging resistance, fatigue resistance, such as oil resistance is required at a high level. Therefore, the hose obtained by laminating an expensive fluorine rubber and acrylic rubber have been used. Fluorine rubber, the adhesion between the non-polar rubber, the adhered via an adhesive layer were common (e.g., see Patent Document 1). As a method of bonding without interposing an adhesive layer, a layer containing a fluoro rubber and a vulcanizing agent and a layer containing a non-fluorine rubber and vulcanizing agent, it is proposed to adhere by vulcanization bonding ( For example, see Patent Document 2). [0005] 　Toward the fuel economy of automobiles, in recent years the engine down-sizing, is progressing turbo reduction. Turbocharged engine has a structure for feeding the engine to cool the air compressed by the compressor wheel charge air cooler, between the compressor wheel and charge air cooler are connected by a rubber hose. The turbocharger hose, high heat aging resistance because air passes through the high pressure and high temperature (about 180 ° C.) is obtained. Further, fatigue resistance to withstand the constant pressure vibration generated by the passage of air also required. In the current such applications, such as high an acrylic rubber and a silicone elastomer heat aging resistance is employed. [0006] 　Patent Document 3, a composition containing an ethylene-alkyl acrylate copolymer and have been described cured product, cured product is vulcanizates, impact fatigue resistance and improved over conventional vulcanizate It has been described to exhibit heat resistance. [0007] 　Patent Document 4, excellent heat resistance and have a fatigue resistance, as to prevent the occurrence of inner layer cracking, with an innermost rubber layer made of fluorinated rubber, silicone rubber, acrylic rubber, ethylene acrylic rubber and an outer skin layer due to the fastening structure of the piping has been proposed. [0008] 　The adhesive of the non-polar rubber such as ethylene-propylene-diene rubber (EPDM), and other materials was generally difficult. EPDM, because non-polar rubber, when stacking a method via an adhesive layer were common (e.g., see Patent Document 5). CITATION Patent Document [0009] Patent Document 1: JP-T 2005-523181 Patent Publication Patent Document 2: WO 2003/039858 Patent Document 3: JP-T 2009-500473 Patent Publication Patent Document 4: JP 2013-221580 Patent Publication Patent Document 5: JP 2014-162823 JP Summary of the Invention Problems that the Invention is to Solve [0010] 　The present invention aims adhesion and difficult rubber with non-polar or polar small other material laminated without lamination or intervention through an adhesive layer, to provide a laminate with a heterologous rubber . Means for Solving the Problems [0011] 　The present inventors have made intensive studies, as a result, they found the following stack in such a situation, and have completed the present invention. [0012] 　That is, the present invention relates to the following [1] to [11]. [0013] 　[1] 　following layer (1) and at least one layer selected from a layer (2), and the following layer (3) and the layer (4) a laminate comprising at least one layer selected from There, 　at least one layer of at least one layer selected from the layer (1) and layer (2) is a layer (3) and the layer (4) at least one layer selected from at least one of a layer, either in direct contact, or laminate in contact with an adhesive layer. [0014] 　Layer (1): ethylene-alpha-olefin-nonconjugated polyene copolymer layer produced by using a 　layer (2): a layer produced using the ethylene-carboxylic acid copolymer 　layer (3) Acrylic layer manufactured using the rubber 　layer (4) halogen layer is manufactured using the containing polymer 　[2] 　at least one layer selected from the layer (1) and layer (2) is 　an onium salt the containing more than 0.2 part by weight copolymer per 100 parts by weight of, and 　at least one element and the copolymer 100 parts by mass of an inorganic compound containing oxygen selected from the group 2 elements and group 13 elements containing parts per 7 parts by mass or more, the laminated body according to [1]. [0015] 　[3] 　at least one layer selected from the layer (1) and layer (2) is 　an onium salt copolymer 100 parts by weight per 0.2 part by mass or more, and containing 10 parts by mass or less, and, 　and at least one element selected from the group 2 elements and group 13 elements, oxygen and the inorganic compound containing copolymer 100 parts by weight per 7 parts by mass or more, containing 100 parts by mass or less, according to [1] laminate. [0016] 　[4] 　the layer (1), although the layer (4), directly adhered, the laminated body according to any one of [1] to [3]. [0017] 　[5] 　and at least one layer selected from the layer (1) and layer (2), said layer (3), characterized in that it is adhered through an adhesive layer [1] laminate according to any one of - [4]. [0018] 　[6] 　The ethylene-alpha-olefin-non-conjugated polyene copolymer satisfies the following requirements (I) ~ (III), the laminated body according to any one of [1] to [5]. [0019] 　Requirements (I): a structural unit derived from ethylene, the molar ratio of the constituent unit derived from an alpha-olefin (ethylene / alpha-olefin) is 40/60 to 99.9 / 0.1. [0020] 　Requirements (II): constitutional unit derived from non-conjugated polyene, the ethylene-alpha-olefin-nonconjugated polyene copolymer in 100% by mass, 0.07 to 10 mass%. [0021] 　Requirements (III): The intrinsic viscosity measured in a 135 ° C. decalin [eta] is 1.0 ~ 4.0dl / g. [0022] 　[7] 　The ethylene-alpha-olefin-non-conjugated polyene copolymer has a 5-vinyl-2-norbornene (VNB) a constitutional unit derived from [1] to laminate according to any one of [6] . [0023] 　[8] 　The ethylene-alpha-olefin-non-conjugated polyene copolymer satisfies the following requirements (IV), the laminated body according to any one of [1] to [7]. [0024] 　Requirements (IV): B value represented by the following formula (i) is 1.20 or more. [0025] 　B value = ([EX] +2 [Y ]) / [2 × [E] × ([ X] + [Y]) ] · · (i) [where [E], [X] and [Y] is , respectively, ethylene, alpha-olefin, and shows the mole fraction of the non-conjugated polyene, showing the [EX] ethylene -α- olefin diad chain fraction. ] 　[9] 　[1] to the laminate according to any one of [8], the hose having as at least a part. [0026] 　[10] 　for the automotive, motorcycle, industrial machinery, used in any of the applications for construction equipment or agricultural machinery, hose according to [9]. [0027] 　[11] 　used in the turbocharger hoses for automobiles, hoses according to [9]. Effect of the invention [0028] 　The present invention can provide adhesion and difficult rubber with non-polar or polar small other material laminated without lamination or intervention through an adhesive layer, a laminate of a heterologous rubber. DESCRIPTION OF THE INVENTION [0029] 　Present invention will be described in detail below. [0030] 　[Laminate] 　The laminate of the invention, at least one comprises at least one layer selected from the following layers (1) and layer (2), and which are selected from the following layer (3) and the layer (4) at least a laminate comprising a seed layer, at least one layer of at least one layer selected from the layer (1) and layer (2) is selected from the layer (3) and the layer (4) at least one layer of one layer, a laminate in contact via or in direct contact, or an adhesive layer. [0031] 　Layer (1): ethylene-alpha-olefin-nonconjugated polyene copolymer layer produced by using a 　layer (2): a layer produced using the ethylene-carboxylic acid copolymer 　layer (3) Acrylic layer manufactured using the rubber 　layer (4) a layer made using a halogen-containing polymer 　or less, after the description of each polymer used in making the layer (1) to layer (4), the the laminate of the invention will be described in detail. [0032] 　(Ethylene-alpha-olefin-nonconjugated polyene copolymer) 　Ethylene-alpha-olefin-non-conjugated polyene copolymer has an ethylene, alpha-olefin, the structural units derived from the nonconjugated polyene. [0033] 　The α- olefin, preferably α- olefin of 3 to 20 carbon atoms. The α- olefin, e.g., propylene, 1-butene, 1-pentene, 1-hexene, 4-methyl-1-pentene, 1-heptene, 1-octene, 1-decene, 1-dodecene, 1-tetradecene, 1-hexadecene, and 1-eicosene, and the like. Of these, propylene, 1-butene, 1-hexene, preferably α- olefin having 3 to 8 carbon atoms such as 1-octene, propylene is particularly preferred. Such alpha-olefins, the raw material cost is relatively inexpensive, shows the mechanical properties of ethylene-alpha-olefin-nonconjugated polyene copolymer obtained is excellent to obtain a laminate further having rubber elasticity the preferred because it can. Be used these α- olefins alone may be used or two or more kinds. [0034] 　That is, the ethylene-alpha-olefin-nonconjugated polyene copolymer contains constituent units derived from at least one alpha-olefin, also contain structural units derived from two or more alpha-olefins good. [0035] 　The non-conjugated polyene, 5-vinyl-2-norbornene (VNB), norbornadiene, 1,4-hexadiene, dicyclopentadiene, 5-ethylidene-2-norbornene (ENB), 5-methylene-2-norbornene, 5 (2-propenyl) -2-norbornene, 5- (3-butenyl) -2-norbornene, 5- (1-methyl-2-propenyl) -2-norbornene, 5- (4-pentenyl) -2-norbornene, 5- (1-methyl-3-butenyl) -2-norbornene, 5- (5-hexenyl) -2-norbornene, 5- (1-methyl-4-pentenyl) -2-norbornene, 5- (2,3 - dimethyl-3-butenyl) -2-norbornene, 5- (2-ethyl-3-butenyl) -2-norbornene, 5- (6-heptenyl) -2 Ruborunen, 5- (3-methyl-5-hexenyl) -2-norbornene, 5- (3,4-dimethyl-4-pentenyl) -2-norbornene, 5- (3-ethyl-4-pentenyl) -2 norbornene, 5- (7-octenyl) -2-norbornene, 5- (2-methyl-6-heptenyl) -2-norbornene, 5- (1,2-dimethyl-5-hexenyl) -2-norbornene, 5- (5-ethyl-5-hexenyl) -2-norbornene, 5- (1,2,3-trimethyl-4-pentenyl) -2-norbornene. [0036] 　Even non-conjugated polyene is used alone, may be used or two or more kinds. [0037] 　That is, the ethylene-alpha-olefin-nonconjugated polyene copolymer contains constituent units derived from at least one non-conjugated polyene, also contain structural units derived from two or more non-conjugated polyene good. [0038] 　As the non-conjugated polyene, high availability, good reactivity with the organic peroxide during the polymerization after the crosslinking reaction, the heat resistance of the laminate, preferably VNB from the viewpoint of excellent fatigue resistance. That is, the ethylene-alpha-olefin-nonconjugated polyene copolymer preferably has a constitutional unit derived from VNB. Ethylene-alpha-olefin-nonconjugated polyene copolymer, the structural units derived from VNB is ethylene-alpha-olefin-nonconjugated polyene copolymer in 100% by mass, it is 0.07 to 10 mass% preferably, more preferably 0.1 to 8.0 mass%, and most preferably 0.5 to 5.0 mass%. [0039] 　As the non-conjugated polyene, high availability, the time of the crosslinking reaction after polymerization to highly reactive with sulfur and vulcanization accelerator, easily control the rate of crosslinking, from the viewpoint of easily obtaining good mechanical properties the ENB is preferable. That is, the ethylene-alpha-olefin-nonconjugated polyene copolymer preferably has a constitutional unit derived from ENB. [0040] 　Ethylene-alpha-olefin-nonconjugated polyene copolymer, it is preferable to satisfy at least one of the following requirements requirements (I) ~ (III), satisfies at least two requirements following requirement (I) ~ (III) it is more preferable, and particularly preferably satisfies the following requirements (I) ~ (III). [0041] 　Requirements (I): a structural unit derived from ethylene, the molar ratio of the constituent unit derived from an alpha-olefin (ethylene / alpha-olefin) is 40/60 to 99.9 / 0.1. [0042] 　Requirements (II): constitutional unit derived from non-conjugated polyene, the ethylene-alpha-olefin-nonconjugated polyene copolymer in 100% by mass, 0.07 to 10 mass%. [0043] 　Requirements (III): The intrinsic viscosity measured in a 135 ° C. decalin [eta] is 1.0 ~ 4.0dl / g. [0044] 　(Requirement (I)) 　requirements (I), the molar ratio of a structural unit derived from ethylene, the constitutional unit derived from alpha-olefin (ethylene / alpha-olefin) is 40/60 to 99.9 / 0. it is to identify that it is a 1. [0045] 　The molar ratio of a structural unit derived from ethylene, the constitutional unit derived from alpha-olefin (ethylene / alpha-olefin) is more preferably 55 / 45-85 / 15, 55 / 45-78 / 22 it is particularly preferred is. [0046] 　Wherein the ethylene / alpha-olefin is within the above range, obtained by crosslinking the ethylene-alpha-olefin-nonconjugated polyene copolymer, it shows a rubber elasticity layer excellent comprising a crosslinked body, mechanical strength and it preferred to become excellent in softness. Also within this range, it shows a rubber elasticity ethylene-alpha-olefin-nonconjugated polyene copolymer is excellent, preferable because of its excellent mechanical strength and flexibility. [0047] 　The molar ratio of a structural unit derived from ethylene of ethylene-alpha-olefin-nonconjugated polyene copolymer, a constituent unit derived from an alpha-olefin, 13 can be determined by C-NMR. [0048] 　(Requirement (II)) 　requirement (II) is a structural unit derived from a nonconjugated polyene, an ethylene-alpha-olefin-nonconjugated polyene copolymer in 100% by mass, it is from 0.07 to 10 mass% it is intended to identify it. [0049] 　The amount of the constitutional unit derived from non-conjugated polyene, more preferably 0.1 to 8.0 mass%, and particularly preferably 0.5 to 5.0 mass%. Ethylene-alpha-olefin-non-conjugated polyene copolymer having a constituent unit derived from a nonconjugated polyene in the range has a sufficient hardness, preferably to become excellent in mechanical properties, a large crosslinking density it is possible to obtain a crosslinked body, preferably it is possible to increase the hardness of the layer composed of crosslinked product. [0050] 　The amount of the constitutional unit derived from the non-conjugated polyene, 13 can be determined by C-NMR. [0051] 　(Requirement (III)) 　requirement (III) is ethylene-alpha-olefin-nonconjugated polyene copolymer, the intrinsic viscosity measured in a 135 ° C. decalin [eta] in the 1.0 ~ 4.0 dl / g it is intended to identify that. [0052] 　The intrinsic viscosity [eta] is more preferably 1.5 ~ 4.0dl / g. Preferable intrinsic viscosity balanced processability and physical properties to be within the range is favorable. [0053] 　The intrinsic viscosity can be measured by the method described in Examples. [0054] 　The ethylene-alpha-olefin-nonconjugated polyene copolymer preferably satisfies the following requirements (IV). [0055] 　(Requirement (IV)) 　requirements (IV) are those of ethylene-alpha-olefin-nonconjugated polyene copolymer, B value represented by the following formula (i), to identify that this is 1.20 or more it is. [0056] 　B value = ([EX] +2 [Y ]) / [2 × [E] × ([ X] + [Y]) ] · · (i) [where [E], [X] and [Y] is , respectively, ethylene, alpha-olefin, and shows the mole fraction of the non-conjugated polyene, showing the [EX] ethylene -α- olefin diad chain fraction. ] 　B value is more preferably 1.20 to 1.40 and particularly preferably 1.20 to 1.25. [0057] 　Within B value above range, the ethylene-alpha-olefin-nonconjugated polyene copolymer shows a small compression set at low temperature is preferred because an excellent balance between tensile strength of rubber elasticity and cold at low temperatures . [0058] 　And the B value of the ethylene-alpha-olefin-nonconjugated polyene copolymer is 1.20 or more, and the non-conjugated polyene is in VNB, the laminate of the present invention tend to particularly excellent in fatigue resistance, preferred . [0059] 　Incidentally, B value is an index indicating the randomness of the copolymerized monomer sequence distribution in the copolymer, in the formula (i) [E], [ X], [Y], [EX] is 13 C-NMR spectrum was measured, J. C. Randall [Macromolecules, 15, 353 ( 1982)], J. Ray [Macromolecules, 10, 773 ( 1977)] can be determined based on these reports. [0060] 　Incidentally, alpha-olefin of the ethylene-alpha-olefin-non-conjugated polyene copolymer (content of constituent units derived from the alpha-olefin), the non-conjugated polyene content (content of structural units derived from nonconjugated polyene) is , 13 can be determined by C-NMR. [0061] 　Ethylene-alpha-olefin-nonconjugated polyene copolymer, the range has ethylene as described above, and alpha-olefin, the structural units derived from the nonconjugated polyene, which does not impair the effects of the present invention, other monomer may have a structure unit derived from (ethylene, alpha-olefin, and monomers other than non-conjugated polyene). Constituent units derived from other monomers, ethylene-alpha-olefin-nonconjugated polyene copolymer in 100% by mass, preferably at most 30 mass%, more preferably at most 25 mass%, 20 mass % by particularly preferably less. Other monomers styrene, vinyl acetate, and the like. [0062] 　The ethylene-alpha-olefin-non-conjugated polyene copolymer has a weight average molecular weight (Mw) of preferably 10,000 to 600,000, more preferably 30,000 to 500,000, more preferably 50,000 ~ it is 400,000. Ethylene-alpha-olefin-nonconjugated polyene copolymer, the molecular weight distribution (Mw / Mn), preferably from 1.8 to 30, more preferably from 1.8 to 25.0, more preferably from 2.0 to 20 it is a .0. Incidentally, Mw and Mw / Mn can be determined as a numerical value in terms of polystyrene measured by gel permeation chromatography (GPC). [0063] 　For example, the laminate of the present invention, the heat-resistant hose applications such as turbocharger hoses for automobiles, can be preferably used a relatively high molecular weight ethylene-alpha-olefin-nonconjugated polyene copolymer, specifically specifically, the weight-average molecular weight (Mw) can be preferably used ethylene-alpha-olefin-nonconjugated polyene copolymer 100,000 to 600,000. [0064] 　 　ethylene-alpha-olefin-nonconjugated polyene copolymer, copolymerized with ethylene, and alpha-olefin, the monomer comprising a non-conjugated polyene comprising Te is a copolymer. [0065] 　Ethylene-alpha-olefin-nonconjugated polyene copolymer of the present invention, any may be prepared by manufacturing methods, it is obtained by copolymerization of monomers in the presence of a metallocene compound preferably, it is more preferably obtained by copolymerization of monomers in the presence of a catalyst system comprising a metallocene compound. [0066] 　(Metallocene compound) 　Ethylene-alpha-olefin-nonconjugated polyene copolymer, preferably in the presence of at least one metallocene compound selected from the compounds represented by the following general formula [A1], copolymerizing a monomer it is desirable to those obtained. The copolymerization of the monomers, if performed with a catalyst system comprising the metallocene compounds, long chain branching can be suppressed copolymer obtained contains, ethylene-alpha-olefin-nonconjugated polyene copolymer it can be readily prepared. [0067] Formula 1] 　In the formula [A1], R 1 , R 2 , R 3 , R 4 , R 5 , R 8 , R 9 and R 12 each independently represent a hydrogen atom, a hydrocarbon group, a silicon-containing group or a silicon shows the hetero atom-containing groups other than containing group, R 1 ~ R 4 two groups adjacent to each other out of may be bonded to each other to form a ring. [0068] 　The hydrocarbon group is preferably a hydrocarbon group having 1 to 20 carbon atoms, specifically, an alkyl group having 1 to 20 carbon atoms, an arylalkyl group having 7 to 20 carbon atoms, 6 to 20 carbon atoms and aryl (aryl) groups, or substituted aryl (aryl) groups. For example, a methyl group, an ethyl group, n- propyl group, an isopropyl group, allyl (allyl) group, n- butyl group, isobutyl group, sec- butyl group, t- butyl group, amyl group, n- pentyl group, a neopentyl group , n- hexyl, n- heptyl, n- octyl, n- nonyl, n- decanyl group, 3-methylpentyl group, 1,1-diethyl propyl group, 1,1-dimethylbutyl group, 1- methyl-1-propyl butyl group, 1,1-propyl butyl group, 1,1-dimethyl-2-methylpropyl group, 1-methyl-1-isopropyl-2-methylpropyl group, a cyclopentyl group, a cyclohexyl group, a cycloheptyl group, cyclooctyl group, norbornyl group, adamantyl group, a phenyl group, o- tolyl group, m- tolyl group, p- tolyl group, xylyl group, isoproterenol Butylphenyl group, t- butyl phenyl group, a naphthyl group, a biphenyl group, terphenyl group, phenanthryl group, anthracenyl group, a benzyl group, and a cumyl group. [0069] 　The hydrocarbon group may have a hydrogen atom substituted with a halogen atom, for example, can be mentioned a trifluoromethyl group, trifluoromethylphenyl group, pentafluorophenyl group, etc. chlorophenyl group. [0070] 　Examples of the silicon-containing group, a silyl group, siloxy group, hydrocarbon-substituted silyl group, etc. can be mentioned hydrocarbon-substituted siloxy group. For example, methylsilyl group, dimethylsilyl group, trimethylsilyl group, ethylsilyl group, diethylsilyl group, triethylsilyl group, diphenylmethyl silyl group, a triphenylsilyl group, dimethylphenylsilyl group, dimethyl -t- butylsilyl group, dimethyl (pentafluorophenyl ), such as a silyl group can be mentioned. [0071] 　The hetero atom-containing groups other than silicon-containing group, a methoxy group, an ethoxy group, an oxygen-containing group such as a phenoxy group, a nitro group, a cyano group, N- methylamino group, N, N- dimethylamino group, N- phenylamino can be exemplified nitrogen-containing groups such as groups, Borantoriiru group, a boron-containing group such as Jiboraniru group, a sulfonyl group, and sulfur-containing groups such as a phenyl group. [0072] 　R 6 and R 11 is a hydrogen atom, a hydrocarbon group, are the same atoms or the same group selected from heteroatom-containing groups other than silicon-containing group and a silicon-containing group, R 7 and R 10 are a hydrogen atom, a hydrocarbon group, are the same atoms or the same group selected from heteroatom-containing groups other than silicon-containing group and a silicon-containing group, R 6 and R 7 may bond to each other to form a ring, R 10 and R 11 may be bonded to each other to form a ring. However, R 6 , R 7 , R 10 and R 11 are not are all hydrogen atoms. [0073] 　R 13 and R 14 each independently represent an aryl group. [0074] 　M 1 represents a zirconium atom. [0075] 　Y 1 represents a carbon atom or a silicon atom. [0076] 　Q is a halogen atom, a hydrocarbon group, halogenated hydrocarbon group, conjugated or nonconjugated diene neutral having 4 to 20 carbon atoms, a neutral ligand capable of coordination by an anionic ligand or a lone pair shown, j is an integer of 1-4, a plurality of Q if j is an integer of 2 or more may be the same as or different from each other. [0077] 　Examples of the halogen atom include a fluorine atom, a chlorine atom, a bromine atom, an iodine atom, preferably a chlorine atom. [0078] 　The hydrocarbon group is preferably a hydrocarbon group having 1 to 10 carbon atoms, specifically, methyl group, ethyl group, n- propyl group, an isopropyl group, a 2-methylpropyl group, 1,1-dimethylpropyl group , 2,2-dimethylpropyl group, 1,1-diethyl propyl group, 1-ethyl-1-methylpropyl group, 1,1,2,2-methylpropyl group, sec- butyl group, t- butyl group, 1,1-dimethylbutyl group, 1,1,3-trimethyl butyl group, a neopentyl group, a cyclohexylmethyl group, a cyclohexyl group, 1-methyl-1-cyclohexyl group, a benzyl group and the like, preferably methyl group, ethyl group, a benzyl group. [0079] 　Examples of the halogenated hydrocarbon group, preferably a halogenated hydrocarbon group of 1 to 10 carbon atoms, specifically, a trifluoromethyl group, trifluoromethylphenyl group, pentafluorophenyl group, chlorophenyl group and the like. [0080] 　The conjugated or non-conjugated diene neutral having 4 to 20 carbon atoms, conjugated or nonconjugated diene neutral having 4 to 10 carbon atoms are preferred. Specific examples of the conjugated or nonconjugated diene neutral, s- cis - or s- trans eta 4 -1,3-butadiene, s- cis - or s- trans eta 4 -1,4-diphenyl - 1,3-butadiene, s- cis - or s- trans eta 4 -3-methyl-1,3-pentadiene, s- cis - or s- trans eta 4 -1,4-dibenzyl-1,3 butadiene, s- cis - or s- trans eta 4 -2,4-hexadiene, s- cis - or s- trans eta 4 -1,3-pentadiene, s- cis - or s- trans eta 4 - 1,4-ditolyl-1,3-butadiene, s- cis - or s- trans eta 4 -1,4-bis (trimethylsilyl) -1,3-butadiene and the like. [0081] 　Examples of the anionic ligands, methoxy, t-butoxy, alkoxy group, phenoxy, acetate, carboxylate groups benzoate etc., mesylate, etc. sulfonate groups tosylate, and the like. [0082] 　Specific examples of the neutral ligands capable of coordination by lone pair, trimethylphosphine, triethylphosphine, triphenylphosphine, organic phosphorus compounds such as diphenyl methyl phosphine or tetrahydrofuran, diethyl ether, dioxane, 1,2 ethers such as dimethoxyethane. [0083] 　Substituents R in the formula [A1] 1 R from 4 The cyclopentadienyl group having, R 1 from R 4 unsubstituted cyclopentadienyl group is a hydrogen atom, 3-t-butylcyclopentadienyl group, 3-methylcyclopentadienyl group, 3-trimethylsilyl cyclopentadienyl group, 3-phenyl-cyclopentadienyl group, 3-adamantyl-cyclopentadienyl group, 3-amyl cyclopentadienyl group, 3-cyclohexyl 3 of 1-substituted cyclopentadienyl groups such as cyclopentadienyl group, 3-t-butyl-5-methylcyclopentadienyl group, 3-t-butyl-5-ethyl-cyclopentadienyl group, 3-phenyl 5-methylcyclopentadienyl group, 3,5-di -t- butyl cyclopentadienyl group, 3,5-dimethyl-cyclopentadienyl Group, 3-phenyl-5-methylcyclopentadienyl group, 3-trimethylsilyl-5-methylcyclopentadienyl such 3,5-position 2 substituted cyclopentadienyl groups such as cyclopentadienyl group can be exemplified, but this shall is not. Ease of synthesis of the metallocene compounds, from the viewpoint of copolymerization capability of manufacturing cost and a non-conjugated polyene, unsubstituted (R 1 ~ R 4 cyclopentadienyl group is preferably a hydrogen atom) is. [0084] 　Substituents R in the formula [A1] 5 R from 12 The fluorenyl group having the 2-methyl-fluorenyl group, 2-t-butyl-fluorenyl group, 2-position 2 monosubstituted such as phenyl fluorenyl group fluorenyl group, 4-methyl fluorenyl group, 4-t-butyl-fluorenyl group, 4-position mono-substituted fluorenyl group such as 4-phenyl fluorenyl group or 2,7-di -t- butyl-fluorenyl, group, 3,6-di -t- butyl-fluorenyl 2,7-position or 3,6-position disubstituted fluorenyl group such group, 2,7-dimethyl-3,6-di -t- butyl-fluorenyl group , 2,3,6,7-position 4-substituted fluorenyl group such as 2,7-diphenyl-3,6-di -t- butyl-fluorenyl group or the following general formula, [V-I], [ V-II] R, as represented in 6 and R 7 bound to form a ring with each other, 10 and R 11 is and bonded 2,3,6,7-position 4-substituted fluorenyl group which forms a ring are exemplified together, not limited. [0085] [Formula 2] [0086] [Formula 3] 　formula [V-I], in [V-II], R 5 , R 8 , R 9 , R 12 are the same as defined in the general formula [A1], 　R a , R b , R c , R d , R e , R f , R g and R h are each independently a hydrogen atom or an alkyl group having 1 to 5 carbon atoms, to form a ring together with adjacent substituents it may be. Examples of the alkyl group include exemplified a methyl group, an ethyl group, n- propyl group, an isopropyl group, n- butyl group, t- butyl group, amyl group, a n- pentyl group. In the formula [V-I], R x and R y are each independently a hydrocarbon group which may have an unsaturated bond having 1 to 3 carbon atoms, R x is R a or R c bond the may form a double bond in cooperation with the carbon, R y is R e or R g may form a double bond in cooperation with the carbon to which is bonded, R x and R y are together it is preferably a hydrocarbon group having a saturated or unsaturated having 1 or 2 carbon atoms. [0087] 　As the above-mentioned general formula [V-I] or compound represented by [V-II], specifically, the formula [V-III] represented by octamethyloctahydrodibenzofluorenyl group, the formula [V- tetramethyl dodeca hydro-dibenzo fluorenyl group represented by IV], octamethyl-tetrahydrodicyclopentadiene fluorenyl group represented by the formula [V-V], hexamethyl-dihydro represented by the formula [V-VI] dicyclopentanyl fluorenyl group, b of the formula [V-VII], h- dibenzo fluorenyl group. [0088] [Chemical Formula 4] [0089] [Formula 5] [0090] [Formula 6] [0091] [Chemical Formula 7] [0092] [Formula 8] 　is excellent in copolymerization ability of these above any formula metallocene compound represented by [A1] of the non-conjugated polyene containing fluorenyl groups, Y 1 when it is a silicon atom, 2,7-position 2 substituted fluorenyl group, 3,6-position disubstituted fluorenyl group, 2,3,6,7-position 4-substituted fluorenyl group, 2,3,6,7-position 4-substituted fluorenyl group represented by the general formula [V-I] transition metal compound having a particularly excellent. When Y is a carbon atom, R 5 a R 12 unsubstituted fluorenyl group is a hydrogen atom, 3,6-position disubstituted fluorenyl group, 2,3,6,7-position 4-substituted fluorenyl group, the general formula [V metallocene compounds having a 2,3,6,7-position 4-substituted fluorenyl group represented -I] it is particularly excellent. [0093] 　In the present invention, in the metallocene compound represented by the general formula [A1], Y 1 in the silicon atom, R 5 a R 12 when until it is all a hydrogen atom, R 13 and R 14 is methyl group, butyl group, a phenyl group, silicon-substituted phenyl group, a cyclohexyl group, selected from the group other than a benzyl group; 　Y 1 in the silicon atom, R 6 and R 11 are are both t- butyl group, R 5 , R 7 , R 8 , R 9 , R 10 , R 12 if is not t- butyl group, R 13 and R 14 is a benzyl group, selected from groups other than silicon-substituted phenyl 　group; Y 1 is a carbon atom, R 5 from R 12 when it is all hydrogen atoms, R 13 , R 14 is a methyl group, an isopropyl group, t- butyl group, an isobutyl group, a phenyl group, p-t-butylphenyl group, p-n-butyl phenyl group, silicon-substituted phenyl group, a 4-biphenyl group, p- Tolyl group, a naphthyl group, a benzyl group, a cyclopentyl group, a cyclohexyl group, selected from groups other than xylyl; 　Y 1 is a carbon atom, R 6 and R 11 is t- butyl group, and a methyl group or a phenyl group a common group, R 5 , R 7 , R 8 , R 9 , R 10 and R 12 when the are different groups or atoms, R 13 , R 14 is a methyl group, a phenyl group, p-t-butyl phenyl group, p-n-butylphenyl group, silicon-substituted phenyl group, selected from the group other than a benzyl group; 　Y 1 is a carbon atom, R 6 is dimethylamino group, a methoxy group or a methyl group, R 5 , R 7 , R 8 , R 9 , R 10 , R 11 and R 12 are, R 6 when it is different groups or atoms and is, R 13 , R 14 is selected from methyl, group other than a phenyl 　group; Y 1 is a carbon atom, a fluorenyl group and R 5 ~ 12 sites consisting of the, b, h- dibenzo fluorenyl or a, if it is i- dibenzo fluorenyl may, R 13 , R 14 is a methyl group, is preferably selected from groups other than a phenyl group . [0094] 　Hereinafter, specific examples of the metallocene compounds represented by the general formula [A1] in the present invention, nor is it particularly limited in the scope of the invention thereby. [0095] 　Specific examples of the metallocene compounds represented by the general formula [A1] in the present invention, 　in the case Y is a silicon atom, diphenylsilylene (cyclopentadienyl) (2,7-di -t- butyl-fluorenyl ) zirconium dichloride, diphenylsilylene (cyclopentadienyl) (3,6-di -t- butyl-fluorenyl) zirconium dichloride, diphenylsilylene (cyclopentadienyl) (2,7-dimethyl-3,6-di - t- butyl fluorenyl) zirconium dichloride, diphenylsilylene (cyclopentadienyl) (2,7-diphenyl-3,6-di -t- butyl-fluorenyl) zirconium dichloride, diphenylsilylene (cyclopentadienyl) ( octamethyloctahydrodibenzofluorenyl) zirconium dichloride De, diphenylsilylene (cyclopentadienyl) (tetramethyl-dodeca hydro-dibenzo fluorenyl) zirconium dichloride, diphenylsilylene (cyclopentadienyl) (octamethyl-tetrahydrodicyclopentadiene fluorenyl) zirconium dichloride, diphenylsilylene (cyclopenta dienyl) (hexamethyl dihydrodicyclopentadiene fluorenyl) zirconium dichloride, diphenylsilylene (cyclopentadienyl) (b, h- dibenzo fluorenyl) zirconium dichloride, di (p- tolyl) silylene (cyclopentadienyl ) (fluorenyl) zirconium dichloride, di (p- tolyl) silylene (cyclopentadienyl) (2,7-di -t- butyl-fluorenyl) zirconium dichloride, di (p- tolyl) Perylene (cyclopentadienyl) (3,6-di -t- butyl-fluorenyl) zirconium dichloride, di (p- tolyl) silylene (cyclopentadienyl) (2,7-dimethyl-3,6-di - t- butyl fluorenyl) zirconium dichloride, di (p- tolyl) silylene (cyclopentadienyl) (2,7-diphenyl-3,6-di -t- butyl-fluorenyl) zirconium dichloride, di (p- tolyl) silylene (cyclopentadienyl) (octamethyloctahydrodibenzofluorenyl) zirconium dichloride, di (p- tolyl) silylene (cyclopentadienyl) (tetramethyl-dodeca hydro-dibenzo fluorenyl) zirconium dichloride, di ( p- tolyl) silylene (cyclopentadienyl) (octamethyl-tetrahydronaphthalene Cyclopentadienyl fluorenyl) zirconium dichloride, di (p- tolyl) silylene (cyclopentadienyl) (hexamethyl dihydrodicyclopentadiene fluorenyl) zirconium dichloride, di (p- tolyl) silylene (cyclopentadienyl) ( b, h- dibenzo fluorenyl) zirconium dichloride, di (m-tolyl) silylene (cyclopentadienyl) (fluorenyl) zirconium dichloride, di (m-tolyl) silylene (cyclopentadienyl) (2,7-di -t- butyl fluorenyl) zirconium dichloride, di (m-tolyl) silylene (cyclopentadienyl) (3,6-di -t- butyl-fluorenyl) zirconium dichloride, di (m-tolyl) silylene (cyclo pentadienyl) (2,7-dimethyl-3,6-di -t - butyl fluorenyl) zirconium dichloride, di (m-tolyl) silylene (cyclopentadienyl) (2,7-diphenyl-3,6-di -t- butyl-fluorenyl) zirconium dichloride, di (m-tolyl ) silylene (cyclopentadienyl) (octamethyloctahydrodibenzofluorenyl) zirconium dichloride, di (m-tolyl) silylene (cyclopentadienyl) (tetramethyl-dodeca hydro-dibenzo fluorenyl) zirconium dichloride, di (m - tolyl) silylene (cyclopentadienyl) (octamethyl-tetrahydrodicyclopentadiene fluorenyl) zirconium dichloride, di (m-tolyl) silylene (cyclopentadienyl) (hexamethyl dihydrodicyclopentadiene fluorenyl) zirconium dichloride , di m- tolyl) silylene (cyclopentadienyl) (b, h- dibenzo fluorenyl) zirconium dichloride, and the like. [0096] 　In the case Y is a carbon atom, diphenylmethylene (cyclopentadienyl) (3,6-di -t- butyl-fluorenyl) zirconium dichloride, diphenylmethylene (cyclopentadienyl) (2,7-dimethyl-3, 6-di -t- butyl-fluorenyl) zirconium dichloride, diphenylmethylene (cyclopentadienyl) (2,7-diphenyl-3,6-di -t- butyl-fluorenyl) zirconium dichloride, diphenylmethylene (cyclopenta dienyl) (octamethyloctahydrodibenzofluorenyl) zirconium dichloride, diphenylmethylene (cyclopentadienyl) (tetramethyl-dodeca hydro-dibenzo fluorenyl) zirconium dichloride, diphenylmethylene (cyclopentadienyl) (octamethyltetrasiloxane arsenide Logistics cyclopentadienyl fluorenyl) zirconium dichloride, diphenylmethylene (cyclopentadienyl) (hexamethyl dihydrodicyclopentadiene fluorenyl) zirconium dichloride, diphenylmethylene (cyclopentadienyl) (b, h- dibenzo fluorenyl) zirconium dichloride, di (p- tolyl) methylene (cyclopentadienyl) (2,7-di -t- butyl-fluorenyl) zirconium dichloride, di (p- tolyl) methylene (cyclopentadienyl) (3,6 - di -t- butyl fluorenyl) zirconium dichloride, di (p- tolyl) methylene (cyclopentadienyl) (2,7-dimethyl-3,6-di -t- butyl-fluorenyl) zirconium dichloride, di (p- tolyl) methylene (cyclopentadienyl) 2,7-diphenyl-3,6-di -t- butyl-fluorenyl) zirconium dichloride, di (p- tolyl) methylene (cyclopentadienyl) (octamethyloctahydrodibenzofluorenyl) zirconium dichloride, di ( p- tolyl) methylene (cyclopentadienyl) (tetramethyl-dodeca hydro-dibenzo fluorenyl) zirconium dichloride, di (p- tolyl) methylene (cyclopentadienyl) (octamethyl-tetrahydrodicyclopentadiene fluorenyl) zirconium dichloride , di (p- tolyl) methylene (cyclopentadienyl) (hexamethyl dihydrodicyclopentadiene fluorenyl) zirconium dichloride, di (p- tolyl) methylene (cyclopentadienyl) (b, h- dibenzo fluorenyl ) zirconium dichloride Chloride, di (m-tolyl) methylene (cyclopentadienyl) (fluorenyl) zirconium dichloride, di (m-tolyl) methylene (cyclopentadienyl) (2,7-di -t- butyl-fluorenyl) zirconium dichloride , di (m-tolyl) methylene (cyclopentadienyl) (3,6-di -t- butyl-fluorenyl) zirconium dichloride, di (m-tolyl) methylene (cyclopentadienyl) (2,7-dimethyl 3,6-di -t- butyl-fluorenyl) zirconium dichloride, di (m-tolyl) methylene (cyclopentadienyl) (2,7-diphenyl-3,6-di -t- butyl-fluorenyl) zirconium dichloride, di (m-tolyl) methylene (cyclopentadienyl) (octamethyloctahydrodibenzofluorenyl Zirconium dichloride, di (m-tolyl) methylene (cyclopentadienyl) (tetramethyl-dodeca hydro-dibenzo fluorenyl) zirconium dichloride, di (m-tolyl) methylene (cyclopentadienyl) (octamethyl-tetrahydrodicyclopentadiene full Oreniru) zirconium dichloride, di (m-tolyl) methylene (cyclopentadienyl) (hexamethyl dihydrodicyclopentadiene fluorenyl) zirconium dichloride, di (m-tolyl) methylene (cyclopentadienyl) (b, h - dibenzo fluorenyl) zirconium dichloride, di (p-t-butylphenyl) methylene (cyclopentadienyl) (3,6-di -t- butyl-fluorenyl) zirconium dichloride, di (p-t-butylphenyl ) methylene (cyclopentyl Tajieniru) (2,7-dimethyl-3,6-di -t- butyl-fluorenyl) zirconium dichloride, di (p-t-butylphenyl) methylene (cyclopentadienyl) (2,7-diphenyl -3, 6-di -t- butyl-fluorenyl) zirconium dichloride, di (p-t-butylphenyl) methylene (cyclopentadienyl) (octamethyloctahydrodibenzofluorenyl) zirconium dichloride, di (p-t-butyl phenyl) methylene (cyclopentadienyl) (tetramethyl-dodeca hydro-dibenzo fluorenyl) zirconium dichloride, di (p-t-butylphenyl) methylene (cyclopentadienyl) (octamethyl-tetrahydrodicyclopentadiene fluorenyl) zirconium dichloride, di (p-t-butylphenyl) method Styrene (cyclopentadienyl) (hexamethyl dihydrodicyclopentadiene fluorenyl) zirconium dichloride, di (p-t-butylphenyl) methylene (cyclopentadienyl) (b, h- dibenzo fluorenyl) zirconium dichloride, di (4-biphenyl) methylene (cyclopentadienyl) (2,7-di -t- butyl-fluorenyl) zirconium dichloride, di (4-biphenyl) methylene (cyclopentadienyl) (3,6-di - t- butyl fluorenyl) zirconium dichloride, di (4-biphenyl) methylene (cyclopentadienyl) (2,7-dimethyl-3,6-di -t- butyl-fluorenyl) zirconium dichloride, di (4- biphenyl) methylene (cyclopentadienyl) (2,7-diphenyl-3,6-di - - butyl fluorenyl) zirconium dichloride, di (4-biphenyl) methylene (cyclopentadienyl) (octamethyloctahydrodibenzofluorenyl) zirconium dichloride, di (4-biphenyl) methylene (cyclopentadienyl) (tetra methyl dodeca hydro-dibenzo fluorenyl) zirconium dichloride, di (4-biphenyl) methylene (cyclopentadienyl) (octamethyl-tetrahydrodicyclopentadiene fluorenyl) zirconium dichloride, di (4-biphenyl) methylene (cyclopentadienyl ) (hexamethyl dihydrodicyclopentadiene fluorenyl) zirconium dichloride, di (4-biphenyl) methylene (cyclopentadienyl) (b, h- dibenzo fluorenyl) zirconium dichloride, di (p Chlorophenyl) methylene (cyclopentadienyl) (fluorenyl) zirconium dichloride, di (p- chlorophenyl) methylene (cyclopentadienyl) (2,7-di -t- butyl-fluorenyl) zirconium dichloride, di (p- chlorophenyl ) methylene (cyclopentadienyl) (3,6-di -t- butyl-fluorenyl) zirconium dichloride, di (p- chlorophenyl) methylene (cyclopentadienyl) (2,7-dimethyl-3,6-di -t- butyl fluorenyl) zirconium dichloride, di (p- chlorophenyl) methylene (cyclopentadienyl) (2,7-diphenyl-3,6-di -t- butyl-fluorenyl) zirconium dichloride, di (p - chlorophenyl) methylene (cyclopentadienyl) (Okutamechi Le octahydro dibenzo fluorenyl) zirconium dichloride, di (p- chlorophenyl) methylene (cyclopentadienyl) (tetramethyl-dodeca hydro-dibenzo fluorenyl) zirconium dichloride, di (p- chlorophenyl) methylene (cyclopentadienyl) (octamethyl-tetrahydrodicyclopentadiene fluorenyl) zirconium dichloride, di (p- chlorophenyl) methylene (cyclopentadienyl) (hexamethyl dihydrodicyclopentadiene fluorenyl) zirconium dichloride, di (p- chlorophenyl) methylene (cyclo pentadienyl) (b, h- dibenzo fluorenyl) zirconium dichloride, di (m-chlorophenyl) methylene (cyclopentadienyl) (fluorenyl) zirconium dichloride, di (m Chlorophenyl) methylene (cyclopentadienyl) (2,7-di -t- butyl-fluorenyl) zirconium dichloride, di (m-chlorophenyl) methylene (cyclopentadienyl) (3,6-di -t- Buchirufuru Oreniru) zirconium dichloride, di (m-chlorophenyl) methylene (cyclopentadienyl) (2,7-dimethyl-3,6-di -t- butyl-fluorenyl) zirconium dichloride, di (m-chlorophenyl) methylene ( cyclopentadienyl) (2,7-diphenyl-3,6-di -t- butyl-fluorenyl) zirconium dichloride, di (m-chlorophenyl) methylene (cyclopentadienyl) (octamethyloctahydrodibenzofluorenyl ) zirconium dichloride, di (m-chlorophenyl) methylene ( Cyclopentadienyl) (tetramethyl-dodeca hydro-dibenzo fluorenyl) zirconium dichloride, di (m-chlorophenyl) methylene (cyclopentadienyl) (octamethyl-tetrahydrodicyclopentadiene fluorenyl) zirconium dichloride, di (m-chlorophenyl ) methylene (cyclopentadienyl) (hexamethyl dihydrodicyclopentadiene fluorenyl) zirconium dichloride, di (m-chlorophenyl) methylene (cyclopentadienyl) (b, h- dibenzo fluorenyl) zirconium dichloride, di ( m- trifluoromethylphenyl) methylene (cyclopentadienyl) (fluorenyl) zirconium dichloride, di (m- trifluoromethylphenyl) methylene (cyclopentadienyl) (2,7-di -t- butyl Rufuruoreniru) zirconium dichloride, di (m-trifluoromethylphenyl) methylene (cyclopentadienyl) (3,6-di -t- butyl-fluorenyl) zirconium dichloride, di (m-trifluoromethylphenyl) methylene (cyclo pentadienyl) (2,7-dimethyl-3,6-di -t- butyl-fluorenyl) zirconium dichloride, di (m-trifluoromethylphenyl) methylene (cyclopentadienyl) (2,7-diphenyl - 3,6-di -t- butyl-fluorenyl) zirconium dichloride, di (m-trifluoromethylphenyl) methylene (cyclopentadienyl) (octamethyloctahydrodibenzofluorenyl) zirconium dichloride, di (m-tri- trifluoromethylphenyl) methylene (cyclopenta Enyl) (tetramethyl-dodeca hydro-dibenzo fluorenyl) zirconium dichloride, di (m-trifluoromethylphenyl) methylene (cyclopentadienyl) (octamethyl-tetrahydrodicyclopentadiene fluorenyl) zirconium dichloride, di (m-tri- trifluoromethylphenyl) methylene (cyclopentadienyl) (hexamethyl dihydrodicyclopentadiene fluorenyl) zirconium dichloride, di (m-trifluoromethylphenyl) methylene (cyclopentadienyl) (b, h- dibenzo fluorenyl ) zirconium dichloride, di (2-naphthyl) methylene (cyclopentadienyl) (2,7-di -t- butyl-fluorenyl) zirconium dichloride, di (2-naphthyl) methylene (cyclopentadienyl) (3, 6 -T- butyl fluorenyl) zirconium dichloride, di (2-naphthyl) methylene (cyclopentadienyl) (2,7-dimethyl-3,6-di -t- butyl-fluorenyl) zirconium dichloride, di (2 - naphthyl) methylene (cyclopentadienyl) (2,7-diphenyl-3,6-di -t- butyl-fluorenyl) zirconium dichloride, di (2-naphthyl) methylene (cyclopentadienyl) (octamethyl octa hydro dibenzo fluorenyl) zirconium dichloride, di (2-naphthyl) methylene (cyclopentadienyl) (tetramethyl-dodeca hydro-dibenzo fluorenyl) zirconium dichloride, di (2-naphthyl) methylene (cyclopentadienyl) (oct methyl-tetrahydrodicyclopentadiene fluorenyl) zirconium Niumujikurorido, di (2-naphthyl) methylene (cyclopentadienyl) (hexamethyl dihydrodicyclopentadiene fluorenyl) zirconium dichloride, di (2-naphthyl) methylene (cyclopentadienyl) (b, h- dibenzofluorenyl Oreniru) zirconium dichloride and the like. [0097] 　As an example of the structure of these metallocene compounds, di (p- tolyl) methylene (cyclopentadienyl) (octamethyloctahydrodibenzofluorenyl) zirconium dichloride (below (A1-1)), and di (p - the structural formula of chlorophenyl) methylene (cyclopentadienyl) (octamethyloctahydrodibenzofluorenyl) zirconium dichloride (below (A1-2)) below. [0098] [Formula 9] 　The above compounds may be used alone or in combination of two or more. [0099] 　Can be suitably used in the preparation of the ethylene-alpha-olefin-nonconjugated polyene copolymer of the present invention, the metallocene compound represented by the formula [A1] is prepared by any method without particular limitation be able to. Specifically, for example, J. Organomet. Chem. , 63,509 (1996), the applicant WO2005 / one hundred thousand four hundred and ten publication is a publication relating to applications by, WO2006 / 123,759, JP WO01 / 27124, JP 2004-168744 and JP Patent Application 2004-175759 , it can be produced according to the method described JP 2000-212194 and the like. [0100] 　(Catalyst comprising a metallocene compound) 　As the polymerization catalyst which can suitably used in the production of the ethylene-alpha-olefin-nonconjugated polyene copolymer of the present invention comprises a metallocene compound represented by the formula [A1] mentioned above , those copolymerizable monomers. [0101] 　Preferably, (a) and the metallocene compound represented by the general formula [A1], (b) (b-1) organometallic compound, (b-2) an organoaluminum oxy-compound, and (b-3) wherein the metallocene It reacts with compound (a) to form an ion pair compound, and at least one compound selected from, if necessary, include a catalyst composed of (c) and particulate carrier. [0102] 　It will be specifically described respective components. ((B-1) organometallic compound) 　as (b-1) organometallic compound used in the present invention, the following formula is specifically [VII] ~ periodic table first and second group, such as [IX] and organometallic compounds of 12, 13 group is used. [0103] 　(B-1a) formula R a m Al (OR b ) n H p X q ‥ [VII] (In the formula [VII], R a and R b may be the same or different from each other, the number of carbon atoms There 1-15, preferably a hydrocarbon group of 1 ~ 4, X is a halogen atom, m is 0