Liquid For Absorbing And Collecting Carbon Dioxide In Gas And Method For Collecting Carbon Dioxide With Use Of Same
Abstract:
Disclosed is a liquid for absorbing and collecting carbon dioxide from a gas that contains the carbon dioxide which contains (A) a secondary amine compound represented by general formula (1) R NH (CH) OH (B) a polyamine compound represented by general formula (2) RRN (X) NRR and (C) water and wherein the content of the secondary amine compound (A) is 50% by weight or more. Also disclosed is a method for absorbing and collecting carbon dioxide with use of this liquid.
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Notices, Deadlines & Correspondence
c/o RESEARCH INSTITUTE OF INNOVATIVE TECHNOLOGY FOR THE EARTH 9 2 Kizugawadai Kizugawa shi Kyoto
6190292
2. CHOWDHURY Firoz Alam
c/o RESEARCH INSTITUTE OF INNOVATIVE TECHNOLOGY FOR THE EARTH 9 2 Kizugawadai Kizugawa shi Kyoto
6190292
3. GOTO Kazuya
c/o RESEARCH INSTITUTE OF INNOVATIVE TECHNOLOGY FOR THE EARTH 9 2 Kizugawadai Kizugawa shi Kyoto
6190292
4. MATSUZAKI Yoichi
c/o NIPPON STEEL & SUMITOMO METAL CORPORATION 6 1 Marunouchi 2 chome Chiyoda ku Tokyo
1008071
5. ONODA Masami
c/o NIPPON STEEL & SUMITOMO METAL CORPORATION 6 1 Marunouchi 2 chome Chiyoda ku Tokyo
1008071
Specification
[Document Name] Specification
[Title of Invention] LIQUID FOR ABSORBING AND COLLECTING CARBON
DIOXIDE IN GAS, AND METHOD FOR COLLECTING CARBON DIOXIDE WITH USE
OF SAME
[Technical Field]
[0001]
The present invention relates to a liquid for absorbing
and recovering carbon dioxide contained in a gas, and a method
10 for efficiently absorbing and recovering carbon dioxide in a gas,
the method using the liquid.
[Background Art]
[0002]
15 In recent years, climate change and natural disasters
presumably caused by global warming have had a serious influence
on agricultural production, living conditions, energy consumption,
etc. Global warming is believed to be due to an increase in
greenhouse gases, such as carbon dioxide, methane, nitrous oxide,
20 and chlorofluorocarbons (CFCs), in the atmosphere, in association
vii th an increase in human activity. The main gas among the
greenhouse gases is atmospheric carbon dioxide, and there is thus
a worldvlide need for a measure to reduce carbon dioxide emissions
into the atmosphere.
25 [0003]
Examples of sources of carbon dioxide include thermal
pOiver plants using coal·, heavy oil, natural gas, or the like as a
fuel; ironworks blast furnaces where iron oxide is reduced with
coke; ironworks converters where carbon in pig iron is combusted
30 to produce st.eel; factory boilers; cement plant kilns; and
transportation equipment using gasoline, heavy oil, light oil, or
the like as a fuel, such as automobiles, ships, and aircrafts.
Except for transportation equipment, these sources of carbon
dioxide are fixed facilities, which are easily adapted to
35 implement measures for reducing carbon dioxide emissions into the
atmosphere.
[0004]
-2-
Several methods for separating and recovering carbon
dioxide from gases exhausted from the above-mentioned sources are
5 hitherto known.
[0005]
For example, a method for absorbing carbon dioxide by
bringing an aqueous solution of an alkanolamine into contact with
a carbon dioxide-containing gas in an absorption tower is known.
10 Examples of known alkanolamines include monoethanolamine (MEA) ,
diethanolamine (DEA), triethanolamine (TEA), methyl
diethanolamine (MDEA), diisopropanolamine (DIPA), diglycolamine
(DGA), and the like. Typically, MEA is often used.
15
[ 0006]
In general, alkanolamines have high solubility in 1·mter,
and the alkanolamine concentration is preferably higher to more
efficiently separate and recover carbon dioxide. However, the
rate at which carbon dioxide is recovered decreases as the
a1kanolamine concentration increases. Thus, the development of a
20 liquid, for absorbing carbon dioxide, that achieves higher
reaction efficiency has not been attained.
[0007]
To recover carbon dioxide from a liquid in which the
carbon dioxide is absorbed, the liquid is heated to, for example,
25 120°C to separate the carbon dioxide from the liquid containing
the absorbed carbon dioxide. However, when the heat of reaction
between the carbon dioxide and the alkanolamine is high, a large
amount of energy is required to recover the carbon dioxide. For
example, when MEA is used, the heat of reaction with one mole of
30 carbon~dioxide is as high as 80 kJ (80 kJ/mol C02), and to
separate and recover carbon dioxide in an electric power plant by
using MEA, energy that corresponds to about 20% of the generated
electric power is required.
[0008]
35 From the viev~oint of carbon dioxide emissions into the
-3-
atmosphere, as well as energy-saving and resource-saving, this
additional energy consumption is a major problem in the practical
use for separation and recovery of carbon dioxide. There is thus
a need for a carbon dioxide-absorbing liquid for absorbing and
5 recovering carbon dioxide with lower energy consumption, i.e.,
with high energy efficiency, and a method therefor.
[0009]
Various studies have been conducted to address the
above problems. Patent Literature 1 discloses a method for
10 removing carbon dioxide from a combustion exhaust gas, the method
comprising bringing an aqueous solution of a so-called hindered
amine, which is an amine compound having a steric hindrance of
alkyl groups or the like around the amine group, into contact
with a combustion exhaust gas at atmospheric pressure to absorb
15 carbon dioxide into the aqueous solution. Patent Literature 1
discloses 2-methylaminoethanol (•lhich hereafter may be referred
to as MAE) and 2-ethylaminoethanol (which hereafter may be
referred to as EAE) as specific examples of hindered amines. In
the Examples of Patent Literature 1, an aqueous solution
20 containing 30 l·lt% of MAE or EAE ~