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Lithium Secondary Battery Having Improved High Temperature Storage Characteristics

Abstract: The present invention relates to a lithium secondary battery comprising: a positive electrode; a negative electrode; a separator interposed between the positive electrode and the negative electrode; and a non-aqueous electrolyte, the positive electrode containing a positive electrode active material represented by chemical formula 1 below, the non-aqueous electrolyte containing a non-aqueous organic solvent, a first lithium salt, lithium bis(fluorosulfonyl)imide as a second lithium salt, and an additive, wherein the molar ratio of the first lithium salt : the second lithium salt is 1:0.01 to 1:1, and the additive is a mixed additive containing fluorobenzene, tetravinyl silane, and tertiary butyl benzene at a weight ratio of 1:0.05:0.1 to 1:1:1.5. [Chemical formula 1] Li(NiaCobMnc)O2 In chemical formula 1, 0.65

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Patent Information

Application #
Filing Date
05 June 2020
Publication Number
37/2020
Publication Type
INA
Invention Field
ELECTRICAL
Status
Email
mahua.ray@remfry.com
Parent Application
Patent Number
Legal Status
Grant Date
2023-12-21
Renewal Date

Applicants

LG CHEM, LTD.
128, Yeoui-daero, Yeongdeungpo-gu, Seoul 07336

Inventors

1. LIM, Young Min
LG Chem Research Park, 188, Munji-ro, Yuseong-gu, Daejeon 34122
2. LEE, Chul Haeng
LG Chem Research Park, 188, Munji-ro, Yuseong-gu, Daejeon 34122

Specification

Specification Title of Invention: Lithium secondary battery with improved high temperature storage characteristics Technical field [One] Cross-reference with related application(s) [2] This application claims the benefit of priority based on Korean Patent Application No. 2018-0011216 filed January 30, 2018 and Korean Patent Application No. 2019-0009128 filed January 24, 2019, and all disclosed in the documents of the relevant Korean patent application. The content is incorporated as part of this specification. [3] [4] Technical field [5] The present invention relates to a lithium secondary battery with improved high temperature storage characteristics. Background [6] Recently, interest in energy storage technology is increasing, and as its application fields are expanded to energy sources of mobile phones, camcorders and notebook PCs, and furthermore, electric vehicles, efforts for research and development of electrochemical devices are increasingly being concreted. [7] In particular, interest in rechargeable secondary batteries is emerging among electrochemical devices, and among them, lithium secondary batteries developed in the early 1990s are in the spotlight for their advantages of high operating voltage and remarkably large energy density. [8] Currently applied lithium secondary batteries are composed of a negative electrode capable of occluding and releasing lithium ions, a positive electrode made of a transition metal oxide containing lithium, and a non-aqueous electrolyte in which a lithium salt is dissolved in a carbonate-based organic solvent. [9] In the lithium secondary battery, lithium ions from the positive electrode are inserted into the negative electrode by charging, and during discharging, lithium ions are repeatedly desorbed while transferring energy to enable charge and discharge. [10] On the other hand, lithium secondary batteries form a film on the anode surface as some of the electrolyte additive components and organic solvents decompose in the 0.5V~3.5V range during initial charging, and lithium ions generated from the anode move to the cathode, In the reaction with the electrolyte to produce compounds such as Li 2 CO 3 , Li 2 O, LiOH. These compounds form a kind of passivation layer on the surface of the negative electrode, which is called a solid electrolyte interface (SEI) film. [11] The SEI film formed at the beginning of charging serves as a protective film to stabilize the battery by suppressing the decomposition of the carbonate-based electrolyte on the surface of the negative electrode. [12] However, the SEI film produced only by the organic solvent and the lithium salt is somewhat insufficient to perform the role as a continuous protective film, so that the charging and discharging of the battery continues to proceed, especially when stored at a high temperature in a fully charged state, increased electrochemical energy. And can be slowly decayed by thermal energy. Due to the collapse of the SEI film, side reactions in which the exposed surface of the negative electrode active material and the electrolyte solution react and decompose continuously occur, resulting in deterioration of battery characteristics, such as a decrease in capacity, a decrease in life, and an increase in resistance. In addition, such side reactions cause the generation of gases such as CO, CO 2 , CH 4 , and C 2 H 6 inside the battery, and such continuous gas generation increases the internal pressure of the lithium secondary battery at high temperatures to expand the battery thickness. Not only does it cause a problem, but it also causes problems in the safety of the secondary battery. [13] [14] (Prior technical literature) Japanese Laid-Open Patent Publication No. 2017-117684 Detailed description of the invention Technical challenge [15] In the present invention, by including a non-aqueous electrolyte capable of forming a solid film on the electrode surface, it is intended to provide a lithium secondary battery capable of securing capacity characteristics even at high temperature storage. Means of solving the task [16] In order to solve the above problem, in one embodiment of the present invention [17] A positive electrode, a negative electrode, a separator interposed between the positive electrode and the negative electrode, and a non-aqueous electrolyte, [18] The positive electrode includes a positive electrode active material represented by Formula 1 below, [19] The non-aqueous electrolyte contains a non-aqueous organic solvent, a first lithium salt, a second lithium salt, lithium bis (fluorosulfonyl) imide, and an additive, [20] At this time, the molar ratio of the first lithium salt: the second lithium salt is 1:0.01 to 1:1, [21] The additive provides a lithium secondary battery that is a mixed additive containing fluorobenzene, tetravinylsilane, and tertiary butylbenzene in a weight ratio of 1:0.05:0.1 to 1:1:1.5. [22] [Formula 1] [23] Li(Ni a Co b Mn c )O 2 [24] In Formula 1, [25] 0.65

Documents

Application Documents

# Name Date
1 202017023639-IntimationOfGrant21-12-2023.pdf 2023-12-21
1 202017023639-TRANSLATIOIN OF PRIOIRTY DOCUMENTS ETC. [05-06-2020(online)].pdf 2020-06-05
2 202017023639-PatentCertificate21-12-2023.pdf 2023-12-21
2 202017023639-STATEMENT OF UNDERTAKING (FORM 3) [05-06-2020(online)].pdf 2020-06-05
3 202017023639-Response to office action [27-10-2023(online)].pdf 2023-10-27
3 202017023639-PRIORITY DOCUMENTS [05-06-2020(online)].pdf 2020-06-05
4 202017023639-Response to office action [04-05-2023(online)].pdf 2023-05-04
4 202017023639-FORM 1 [05-06-2020(online)].pdf 2020-06-05
5 202017023639-FORM 3 [23-02-2023(online)].pdf 2023-02-23
5 202017023639-DECLARATION OF INVENTORSHIP (FORM 5) [05-06-2020(online)].pdf 2020-06-05
6 202017023639-Response to office action [20-12-2022(online)].pdf 2022-12-20
6 202017023639-COMPLETE SPECIFICATION [05-06-2020(online)].pdf 2020-06-05
7 202017023639-Verified English translation [23-06-2020(online)].pdf 2020-06-23
7 202017023639-8(i)-Substitution-Change Of Applicant - Form 6 [25-11-2022(online)].pdf 2022-11-25
8 202017023639-Proof of Right [23-06-2020(online)].pdf 2020-06-23
8 202017023639-ASSIGNMENT DOCUMENTS [25-11-2022(online)].pdf 2022-11-25
9 202017023639-FORM-26 [20-08-2020(online)].pdf 2020-08-20
9 202017023639-PA [25-11-2022(online)].pdf 2022-11-25
10 202017023639-FORM 3 [11-11-2020(online)].pdf 2020-11-11
10 202017023639-Response to office action [03-11-2022(online)].pdf 2022-11-03
11 202017023639-ABSTRACT [25-02-2022(online)].pdf 2022-02-25
11 202017023639-FORM 18 [29-07-2021(online)].pdf 2021-07-29
12 202017023639-CLAIMS [25-02-2022(online)].pdf 2022-02-25
12 202017023639.pdf 2021-10-19
13 202017023639-COMPLETE SPECIFICATION [25-02-2022(online)].pdf 2022-02-25
13 202017023639-FER.pdf 2021-10-19
14 202017023639-FER_SER_REPLY [25-02-2022(online)].pdf 2022-02-25
14 202017023639-OTHERS [25-02-2022(online)].pdf 2022-02-25
15 202017023639-FER_SER_REPLY [25-02-2022(online)].pdf 2022-02-25
15 202017023639-OTHERS [25-02-2022(online)].pdf 2022-02-25
16 202017023639-COMPLETE SPECIFICATION [25-02-2022(online)].pdf 2022-02-25
16 202017023639-FER.pdf 2021-10-19
17 202017023639.pdf 2021-10-19
17 202017023639-CLAIMS [25-02-2022(online)].pdf 2022-02-25
18 202017023639-ABSTRACT [25-02-2022(online)].pdf 2022-02-25
18 202017023639-FORM 18 [29-07-2021(online)].pdf 2021-07-29
19 202017023639-FORM 3 [11-11-2020(online)].pdf 2020-11-11
19 202017023639-Response to office action [03-11-2022(online)].pdf 2022-11-03
20 202017023639-FORM-26 [20-08-2020(online)].pdf 2020-08-20
20 202017023639-PA [25-11-2022(online)].pdf 2022-11-25
21 202017023639-ASSIGNMENT DOCUMENTS [25-11-2022(online)].pdf 2022-11-25
21 202017023639-Proof of Right [23-06-2020(online)].pdf 2020-06-23
22 202017023639-8(i)-Substitution-Change Of Applicant - Form 6 [25-11-2022(online)].pdf 2022-11-25
22 202017023639-Verified English translation [23-06-2020(online)].pdf 2020-06-23
23 202017023639-COMPLETE SPECIFICATION [05-06-2020(online)].pdf 2020-06-05
23 202017023639-Response to office action [20-12-2022(online)].pdf 2022-12-20
24 202017023639-DECLARATION OF INVENTORSHIP (FORM 5) [05-06-2020(online)].pdf 2020-06-05
24 202017023639-FORM 3 [23-02-2023(online)].pdf 2023-02-23
25 202017023639-Response to office action [04-05-2023(online)].pdf 2023-05-04
25 202017023639-FORM 1 [05-06-2020(online)].pdf 2020-06-05
26 202017023639-Response to office action [27-10-2023(online)].pdf 2023-10-27
26 202017023639-PRIORITY DOCUMENTS [05-06-2020(online)].pdf 2020-06-05
27 202017023639-STATEMENT OF UNDERTAKING (FORM 3) [05-06-2020(online)].pdf 2020-06-05
27 202017023639-PatentCertificate21-12-2023.pdf 2023-12-21
28 202017023639-TRANSLATIOIN OF PRIOIRTY DOCUMENTS ETC. [05-06-2020(online)].pdf 2020-06-05
28 202017023639-IntimationOfGrant21-12-2023.pdf 2023-12-21

Search Strategy

1 Searchstrategy202017023639E_25-08-2021.pdf

ERegister / Renewals

3rd: 12 Mar 2024

From 25/01/2021 - To 25/01/2022

4th: 12 Mar 2024

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5th: 12 Mar 2024

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6th: 12 Mar 2024

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7th: 30 Dec 2024

From 25/01/2025 - To 25/01/2026