Abstract: A lithographic printing plate original plate and a method for producing a lithographic printing plate using the lithographic printing plate original plate the lithographic printing plate original plate having an image-recording layer on a hydrophilic support body the image-recording layer including a polymerization initiator an infrared ray absorber a polymerizable compound and an acid-generating color agent and the infrared ray absorber including the compound represented by formula 1. In formula 1 Ar1 and/or Ar2 has the group represented by formula 2. -X Formula 2 X represents a halogen atom -C(=O)-X2-R11 -C (=O)-NR12R13 -O-C (=O)-R 14 -CN -SO2NR15R16 or a perfluoroalkyl group; X2 represents a single bond or an oxygen atom; R11 and R14 each independently represents an alkyl group or an aryl group; and R12 R13 R15 and R16 each independently represents a hydrogen atom an alkyl group or an aryl group.
WE CLAIM:
1. A lithographic printing plate precursor comprising
an image recording layer on a hydrophilic support,
wherein the image recording layer comprises a polymerization initiator, an infrared absorbent, a polymerizable compound, and an acid color former, the infrared absorbent comprises a compound represented by the following Formula 1, and
the difference between the HOMO of the compound represented by Formula 1 and the HOMO of at least one compound of the polymerization initiator is 0.60 eV or less,
wherein Ri and R2 each independently represent a hydrogen atom or an alkyl group, Ri and R2 are optionally mutually linked to form a ring, R3 to R5 each independently represent a hydrogen atom or an alkyl group, R7 and Rg each independently represent an alkyl group or an aryl group, Yi and Y2 each independently represent an oxygen atom, a sulfur atom, -NRo-or a dialkylmethylene group, An and Ar2 each independently represent a group that forms a benzene ring or a naphthalene ring optionally having -X described below, Ai represents -NR9R10, -X1-L1, or -X described below, R9 and Rio each independently represent an alkyl group, an aryl group, an alkoxycarbonyl group, or an arylsulfonyl group, Xi represents an oxygen atom or a sulfur atom, Li represents a hydrocarbon group, a heteroaryl group, or a group where a bond with Xi is to be cleaved by heat or infrared exposure, Za represents a counter ion that neutralizes charge, and at least one of Ari or Ar2 has a group represented by the following Formula 2:
-X Formula 2
wherein X represents a halogen atom, -C(=0)-X2-Rn, -C(=0)-NRi2Ri3, -0-C(=0)-Ri4, -CN, -SO2NR15R16, or a perfluoroalkyl group, X2 represents a single bond or an oxygen atom, Rn and R14 each independently represent an alkyl group or an aryl group, and R12, R13, R15 and Ri6 each independently represent a hydrogen atom, an alkyl group, or an aryl group.
2. The lithographic printing plate precursor according to claim 1, wherein X in Formula 2 represents a fluorine atom, a chlorine atom, or -C(=0)ORi7, provided that R17 represents an
alkyl group or an aryl group.
3. The lithographic printing plate precursor according to claim 2, wherein Ai in Formula 1 represents -NRigRi9 or -S-R20, provided that Ri8 and R19 each independently represent an aryl group and R20 represents a hydrocarbon group or a heteroaryl group.
4. The lithographic printing plate precursor according to any one of claims 1 to 3, wherein the polymerization initiator is a borate compound.
5. The lithographic printing plate precursor according to claim 4, wherein the borate compound is a tetraarylborate compound or a monoalkyltriarylborate compound.
6. The lithographic printing plate precursor according to any one of claims 1 to 5, wherein the polymerization initiator comprises an electron-donating polymerization initiator and an electron-accepting polymerization initiator.
7. The lithographic printing plate precursor according to any one of claims 1 to 6, wherein the acid color former is at least one compound selected from the group consisting of a spiropyran compound, a spirooxazine compound, a spirolactone compound, and a spirolactam compound.
8. The lithographic printing plate precursor according to any one of claims 1 to 7, wherein Za represents a carbon atom-containing organic anion.
9. The lithographic printing plate precursor according to any one of claims 1 to 8, wherein Za represents a sulfonimide anion.
10. The lithographic printing plate precursor according to any one of claims 1 to 9, wherein the polymerizable compound includes a urethane-based addition-polymerizable compound.
11. The lithographic printing plate precursor according to any one of claims 1 to 10, wherein the polymerizable compound includes a compound selected from the group consisting of an ester compound of unsaturated carboxylic acid and a polyhydric alcohol compound, and an amide compound of unsaturated carboxylic acid and a polyvalent amine compound.
12. A method of preparing a lithographic printing plate, comprising
a step of imagewise exposing the lithographic printing plate precursor according to any one of claims 1 to 11 thereby forming an exposed portion and an unexposed portion, and
a step of feeding at least one of printing ink or dampening water, thereby removing the unexposed portion.
| # | Name | Date |
|---|---|---|
| 1 | 201947041189-IntimationOfGrant04-08-2023.pdf | 2023-08-04 |
| 1 | 201947041189.pdf | 2019-10-11 |
| 2 | 201947041189-TRANSLATIOIN OF PRIOIRTY DOCUMENTS ETC. [11-10-2019(online)].pdf | 2019-10-11 |
| 2 | 201947041189-PatentCertificate04-08-2023.pdf | 2023-08-04 |
| 3 | 201947041189-STATEMENT OF UNDERTAKING (FORM 3) [11-10-2019(online)].pdf | 2019-10-11 |
| 3 | 201947041189-CLAIMS [22-12-2022(online)].pdf | 2022-12-22 |
| 4 | 201947041189-REQUEST FOR EXAMINATION (FORM-18) [11-10-2019(online)].pdf | 2019-10-11 |
| 4 | 201947041189-COMPLETE SPECIFICATION [22-12-2022(online)].pdf | 2022-12-22 |
| 5 | 201947041189-PROOF OF RIGHT [11-10-2019(online)].pdf | 2019-10-11 |
| 5 | 201947041189-FER_SER_REPLY [22-12-2022(online)].pdf | 2022-12-22 |
| 6 | 201947041189-PRIORITY DOCUMENTS [11-10-2019(online)].pdf | 2019-10-11 |
| 6 | 201947041189-Information under section 8(2) [22-12-2022(online)].pdf | 2022-12-22 |
| 7 | 201947041189-OTHERS [22-12-2022(online)].pdf | 2022-12-22 |
| 7 | 201947041189-FORM-26 [11-10-2019(online)].pdf | 2019-10-11 |
| 8 | 201947041189-FORM 18 [11-10-2019(online)].pdf | 2019-10-11 |
| 8 | 201947041189-FER.pdf | 2022-06-23 |
| 9 | 201947041189-FORM 3 [20-02-2020(online)].pdf | 2020-02-20 |
| 9 | 201947041189-FORM 1 [11-10-2019(online)].pdf | 2019-10-11 |
| 10 | 201947041189-DECLARATION OF INVENTORSHIP (FORM 5) [11-10-2019(online)].pdf | 2019-10-11 |
| 10 | Correspondence by Agent_Form1,Form26_14-10-2019.pdf | 2019-10-14 |
| 11 | 201947041189-CLAIMS UNDER RULE 1 (PROVISIO) OF RULE 20 [11-10-2019(online)].pdf | 2019-10-11 |
| 11 | 201947041189-COMPLETE SPECIFICATION [11-10-2019(online)].pdf | 2019-10-11 |
| 12 | 201947041189-CLAIMS UNDER RULE 1 (PROVISIO) OF RULE 20 [11-10-2019(online)].pdf | 2019-10-11 |
| 12 | 201947041189-COMPLETE SPECIFICATION [11-10-2019(online)].pdf | 2019-10-11 |
| 13 | 201947041189-DECLARATION OF INVENTORSHIP (FORM 5) [11-10-2019(online)].pdf | 2019-10-11 |
| 13 | Correspondence by Agent_Form1,Form26_14-10-2019.pdf | 2019-10-14 |
| 14 | 201947041189-FORM 1 [11-10-2019(online)].pdf | 2019-10-11 |
| 14 | 201947041189-FORM 3 [20-02-2020(online)].pdf | 2020-02-20 |
| 15 | 201947041189-FER.pdf | 2022-06-23 |
| 15 | 201947041189-FORM 18 [11-10-2019(online)].pdf | 2019-10-11 |
| 16 | 201947041189-FORM-26 [11-10-2019(online)].pdf | 2019-10-11 |
| 16 | 201947041189-OTHERS [22-12-2022(online)].pdf | 2022-12-22 |
| 17 | 201947041189-Information under section 8(2) [22-12-2022(online)].pdf | 2022-12-22 |
| 17 | 201947041189-PRIORITY DOCUMENTS [11-10-2019(online)].pdf | 2019-10-11 |
| 18 | 201947041189-FER_SER_REPLY [22-12-2022(online)].pdf | 2022-12-22 |
| 18 | 201947041189-PROOF OF RIGHT [11-10-2019(online)].pdf | 2019-10-11 |
| 19 | 201947041189-REQUEST FOR EXAMINATION (FORM-18) [11-10-2019(online)].pdf | 2019-10-11 |
| 19 | 201947041189-COMPLETE SPECIFICATION [22-12-2022(online)].pdf | 2022-12-22 |
| 20 | 201947041189-STATEMENT OF UNDERTAKING (FORM 3) [11-10-2019(online)].pdf | 2019-10-11 |
| 20 | 201947041189-CLAIMS [22-12-2022(online)].pdf | 2022-12-22 |
| 21 | 201947041189-TRANSLATIOIN OF PRIOIRTY DOCUMENTS ETC. [11-10-2019(online)].pdf | 2019-10-11 |
| 21 | 201947041189-PatentCertificate04-08-2023.pdf | 2023-08-04 |
| 22 | 201947041189.pdf | 2019-10-11 |
| 22 | 201947041189-IntimationOfGrant04-08-2023.pdf | 2023-08-04 |
| 1 | SearchHistory_26_E_08-12-2021.pdf |