Abstract: Provided are, as a lithographic printing plate precursor that enables good development with a developer having a pH from 2 to 10 and is excellent in runlength and stain resistance and a production process of a lithographic printing plate using the precursor, a lithographic printing plate precursor whose photosensitive layer contains the following components (A), (B), and (C): (A) a copolymer having a repeating unit of the formula (1) and at least one of a repeating unit of the formula (2) and a repeating unit of the formula (3): wherein each of A and B independently represents a hetero atom, each of R and R1 to R9 represents a monovalent substituent, L represents a divalent linking group, X represents a hydroxyl group, a monovalent group containing an acid group, an alkyleneoxy group, an amide group, or an ether group, an amino group, an ammonium group, or a salt obtained by neutralizing an acid group, and Lo represents a single bond or divalent hydrocarbon group, (B) a compound having an ethylenically unsaturated bond, and (c) a polymerization initiator, and a production process of a lithographic printing plate by using the precursor.
We claim:
1. A process for producing a lithographic printing plate, comprising subjecting a lithographic printing plate precursor to image-wise exposure and then removing the photosensitive layer from an unexposed portion in the presence of a developer having a pH from 2 to 10,
wherein the lithographic printing plate precursor comprising at least a photosensitive layer on a support and employing a system of removing a photosensitive layer from an unexposed portion in a presence of a developer having a pH from 2 to 10, wherein the photosensitive layer comprises the following components (A), (B), and (C):
(A) a copolymer having a repeating unit represented by the formula (1) and at least either one of a repeating unit represented by the formula (2) and a repeating unit represented by the formula (3):
in the formulae (1), (2), and (3), each of A and B independently represents a hetero atom, each of R and R1 to R9 represents a monovalent substituent, L represents a divalent linking group, X represents a hydroxyl group, a monovalent group containing an acid group, an alkyleneoxy group, an amide group, or an ether group, an amino group, an ammonium group, or a salt obtained by neutralizing an acid group, L0 represents a single bond or a divalent hydrocarbon group, with the proviso that R2 and R in the formula (1), R5 and L in the formula (2), and R8 and Lo in the formula (3) may be coupled to each other to form a ring;
(B) a compound having an ethylenically unsaturated bond; and
(C) a polymerization initiator.
2. The process for producing a lithographic printing plate according to claim 1, wherein X in the formula (2) or (3) in the component (A) is selected from an amino group, a sulfonic acid group, a carboxylic acid group, a phosphonic acid group, a group obtained by neutralizing a carboxylic acid, a group obtained by neutralizing a sulfonic acid, and a group obtained by neutralizing a phosphonic acid.
3. The process for producing a lithographic printing plate according to claim 1 or 2, wherein the photosensitive layer further comprises (D) a sensitizing dye.
4. The process for producing a lithographic printing plate according to any one of claims 1 to 3, wherein the copolymer (A) contains the repeating unit represented by the formula (2) or (3) in which X represents a carboxylic acid or a carboxylate and further contains a repeating unit represented by the following formula (I):
in the formula (I), each of two A's independently represents a hetero atom and each of R1 to R3 and R10 independently represents a monovalent substituent, with the proviso that any two of Rx to R3 may be the same or different.
5. The process for producing a lithographic printing plate according to claim 4, wherein the copolymer (A) contains 70 mol% or greater but not greater than 95 mol% of the repeating unit represented by the formula (I).
6. The process for producing a lithographic printing plate according to claim 4 or 5, wherein the copolymer (A) contains the repeating unit represented by the formula (2) or formula (3) in which X represents a carboxylic acid or a carboxylate; contains a repeating unit represented by the formula (II) which is a repeating units represented by the formula (3); and contains, in the copolymer, 30 mol% or greater but not greater than 80 mol% of the repeating unit represented by the formula (II):
7. The process for producing a lithographic printing plate according to any one of claims 4 to 6, wherein the copolymer (A) has a mass average molecular weight (Mw) of from 10,000 to 40,000.
8. The process for producing a lithographic printing plate according to any one of claims 4 to 7, wherein the copolymer (A) contains the repeating unit represented by the formula (2) or the formula (3) in which X represents a carboxylic acid or a carboxylate; and the number of the carboxylic acid or carboxylate contained in one repeating unit is one.
9. The process for producing a lithographic printing plate according to any one of claims 4 to 8, wherein the copolymer (A) contains the repeating unit represented by the formula (2) or the formula (3) in which X represents a carboxylic acid or a carboxylate and L or Lo represents an aliphatic linking group which may have a substituent.
10. The process for producing a lithographic printing plate according to any one of claims 4 to 9, wherein the copolymer (A) has at least one ethylenically unsaturated double bond group.
11. The process for producing a lithographic printing plate according to any one of claims 4 to 10, wherein the copolymer (A) contains the repeating unit represented by the formula (2) or the formula (3) in which X represents a carboxylate having a metal salt as a counter cation.
12. The process for producing a lithographic printing plate according to any one of claims 4 to 11, wherein the photosensitive layer further contains an acrylic resin.
13. The process for producing a lithographic printing plate according to claim 1, wherein the developer contains a surfactant.
14. The process for producing a lithographic printing plate according to claim 13, wherein the surfactant is a surfactant selected from the group consisting of nonionic surfactants and amphoteric surfactants, and combinations thereof.
15. The process for producing a lithographic printing plate according to claim 1, wherein the developer contains an organic amine compound.
16. The process for producing a lithographic printing plate according to any one of claims 1 to 15, wherein removal of the protective layer, development, and gumming are carried out at the same time.
| # | Name | Date |
|---|---|---|
| 1 | 6074-chenp-2010 power of attorney 27-09-2010.pdf | 2010-09-27 |
| 1 | 6074-CHENP-2010-RELEVANT DOCUMENTS [09-08-2021(online)].pdf | 2021-08-09 |
| 2 | 6074-chenp-2010 pct 27-09-2010.pdf | 2010-09-27 |
| 2 | 6074-CHENP-2010-RELEVANT DOCUMENTS [09-03-2020(online)].pdf | 2020-03-09 |
| 3 | 6074-CHENP-2010-RELEVANT DOCUMENTS [07-03-2019(online)].pdf | 2019-03-07 |
| 3 | 6074-chenp-2010 form-5 27-09-2010.pdf | 2010-09-27 |
| 4 | 6074-CHENP-2010-IntimationOfGrant08-01-2018.pdf | 2018-01-08 |
| 4 | 6074-chenp-2010 form-3 27-09-2010.pdf | 2010-09-27 |
| 5 | 6074-CHENP-2010-PatentCertificate08-01-2018.pdf | 2018-01-08 |
| 5 | 6074-chenp-2010 form-1 27-09-2010.pdf | 2010-09-27 |
| 6 | Abstract_Granted 291490_08-01-2018.pdf | 2018-01-08 |
| 6 | 6074-chenp-2010 correspondence others 27-09-2010.pdf | 2010-09-27 |
| 7 | Claims_Granted 291490_08-01-2018.pdf | 2018-01-08 |
| 7 | 6074-chenp-2010 form-2 27-09-2010.pdf | 2010-09-27 |
| 8 | Description_Granted 291490_08-01-2018.pdf | 2018-01-08 |
| 8 | 6074-chenp-2010 drawings 27-09-2010.pdf | 2010-09-27 |
| 9 | 6074-chenp-2010 description(complete) 27-09-2010.pdf | 2010-09-27 |
| 9 | Drawing_Granted 291490_08-01-2018.pdf | 2018-01-08 |
| 10 | 6074-chenp-2010 claims 27-09-2010.pdf | 2010-09-27 |
| 10 | 6074-CHENP-2010-ABSTRACT [20-12-2017(online)].pdf | 2017-12-20 |
| 11 | 6074-chenp-2010 abstract 27-09-2010.pdf | 2010-09-27 |
| 11 | 6074-CHENP-2010-certified copy of translation (MANDATORY) [20-12-2017(online)].pdf | 2017-12-20 |
| 12 | 6074-CHENP-2010 CORRESPONDENCE OTHERS 24-02-2011.pdf | 2011-02-24 |
| 12 | 6074-CHENP-2010-CLAIMS [20-12-2017(online)].pdf | 2017-12-20 |
| 13 | 6074-chenp-2010 form-3 18-03-2011.pdf | 2011-03-18 |
| 13 | 6074-CHENP-2010-FER_SER_REPLY [20-12-2017(online)].pdf | 2017-12-20 |
| 14 | 6074-chenp-2010 correspondence others 18-03-2011.pdf | 2011-03-18 |
| 14 | 6074-CHENP-2010-FORM 3 [20-12-2017(online)].pdf | 2017-12-20 |
| 15 | 6074-CHENP-2010-FORM-26 [20-12-2017(online)].pdf | 2017-12-20 |
| 15 | abstract6074-chenp-2010.jpg | 2011-09-04 |
| 16 | 6074-CHENP-2010 CORRESPONDENCE OTHERS 27-12-2011.pdf | 2011-12-27 |
| 16 | 6074-CHENP-2010-OTHERS [20-12-2017(online)].pdf | 2017-12-20 |
| 17 | 6074-CHENP-2010-PETITION UNDER RULE 137 [20-12-2017(online)].pdf | 2017-12-20 |
| 17 | 6074-CHENP-2010 FORM-18 27-12-2011.pdf | 2011-12-27 |
| 18 | 6074-CHENP-2010 CORRESPONDENCE OTHERS 07-04-2014.pdf | 2014-04-07 |
| 18 | 6074-CHENP-2010-FER.pdf | 2017-08-09 |
| 19 | 6074-CHENP-2010 FORM-3 07-04-2014.pdf | 2014-04-07 |
| 19 | 6074-CHENP-2010 FORM-1 08-07-2014.pdf | 2014-07-08 |
| 20 | 6074-CHENP-2010 FORM-3 07-04-2014.pdf | 2014-04-07 |
| 20 | 6074-CHENP-2010 FORM-1 08-07-2014.pdf | 2014-07-08 |
| 21 | 6074-CHENP-2010 CORRESPONDENCE OTHERS 07-04-2014.pdf | 2014-04-07 |
| 21 | 6074-CHENP-2010-FER.pdf | 2017-08-09 |
| 22 | 6074-CHENP-2010 FORM-18 27-12-2011.pdf | 2011-12-27 |
| 22 | 6074-CHENP-2010-PETITION UNDER RULE 137 [20-12-2017(online)].pdf | 2017-12-20 |
| 23 | 6074-CHENP-2010 CORRESPONDENCE OTHERS 27-12-2011.pdf | 2011-12-27 |
| 23 | 6074-CHENP-2010-OTHERS [20-12-2017(online)].pdf | 2017-12-20 |
| 24 | abstract6074-chenp-2010.jpg | 2011-09-04 |
| 24 | 6074-CHENP-2010-FORM-26 [20-12-2017(online)].pdf | 2017-12-20 |
| 25 | 6074-chenp-2010 correspondence others 18-03-2011.pdf | 2011-03-18 |
| 25 | 6074-CHENP-2010-FORM 3 [20-12-2017(online)].pdf | 2017-12-20 |
| 26 | 6074-chenp-2010 form-3 18-03-2011.pdf | 2011-03-18 |
| 26 | 6074-CHENP-2010-FER_SER_REPLY [20-12-2017(online)].pdf | 2017-12-20 |
| 27 | 6074-CHENP-2010 CORRESPONDENCE OTHERS 24-02-2011.pdf | 2011-02-24 |
| 27 | 6074-CHENP-2010-CLAIMS [20-12-2017(online)].pdf | 2017-12-20 |
| 28 | 6074-chenp-2010 abstract 27-09-2010.pdf | 2010-09-27 |
| 28 | 6074-CHENP-2010-certified copy of translation (MANDATORY) [20-12-2017(online)].pdf | 2017-12-20 |
| 29 | 6074-chenp-2010 claims 27-09-2010.pdf | 2010-09-27 |
| 29 | 6074-CHENP-2010-ABSTRACT [20-12-2017(online)].pdf | 2017-12-20 |
| 30 | 6074-chenp-2010 description(complete) 27-09-2010.pdf | 2010-09-27 |
| 30 | Drawing_Granted 291490_08-01-2018.pdf | 2018-01-08 |
| 31 | Description_Granted 291490_08-01-2018.pdf | 2018-01-08 |
| 31 | 6074-chenp-2010 drawings 27-09-2010.pdf | 2010-09-27 |
| 32 | Claims_Granted 291490_08-01-2018.pdf | 2018-01-08 |
| 32 | 6074-chenp-2010 form-2 27-09-2010.pdf | 2010-09-27 |
| 33 | Abstract_Granted 291490_08-01-2018.pdf | 2018-01-08 |
| 33 | 6074-chenp-2010 correspondence others 27-09-2010.pdf | 2010-09-27 |
| 34 | 6074-CHENP-2010-PatentCertificate08-01-2018.pdf | 2018-01-08 |
| 34 | 6074-chenp-2010 form-1 27-09-2010.pdf | 2010-09-27 |
| 35 | 6074-CHENP-2010-IntimationOfGrant08-01-2018.pdf | 2018-01-08 |
| 35 | 6074-chenp-2010 form-3 27-09-2010.pdf | 2010-09-27 |
| 36 | 6074-CHENP-2010-RELEVANT DOCUMENTS [07-03-2019(online)].pdf | 2019-03-07 |
| 36 | 6074-chenp-2010 form-5 27-09-2010.pdf | 2010-09-27 |
| 37 | 6074-chenp-2010 pct 27-09-2010.pdf | 2010-09-27 |
| 37 | 6074-CHENP-2010-RELEVANT DOCUMENTS [09-03-2020(online)].pdf | 2020-03-09 |
| 38 | 6074-chenp-2010 power of attorney 27-09-2010.pdf | 2010-09-27 |
| 38 | 6074-CHENP-2010-RELEVANT DOCUMENTS [09-08-2021(online)].pdf | 2021-08-09 |
| 1 | 6074_23-03-2017.pdf |