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Lithographic Printing Plate Precursor And Production Process Of Lithographic Printing Plate Using The Precursor

Abstract: Provided are, as a lithographic printing plate precursor that enables good development with a developer having a pH from 2 to 10 and is excellent in runlength and stain resistance and a production process of a lithographic printing plate using the precursor, a lithographic printing plate precursor whose photosensitive layer contains the following components (A), (B), and (C): (A) a copolymer having a repeating unit of the formula (1) and at least one of a repeating unit of the formula (2) and a repeating unit of the formula (3): wherein each of A and B independently represents a hetero atom, each of R and R1 to R9 represents a monovalent substituent, L represents a divalent linking group, X represents a hydroxyl group, a monovalent group containing an acid group, an alkyleneoxy group, an amide group, or an ether group, an amino group, an ammonium group, or a salt obtained by neutralizing an acid group, and Lo represents a single bond or divalent hydrocarbon group, (B) a compound having an ethylenically unsaturated bond, and (c) a polymerization initiator, and a production process of a lithographic printing plate by using the precursor.

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Notices, Deadlines & Correspondence

Patent Information

Application #
Filing Date
27 September 2010
Publication Number
28/2011
Publication Type
INA
Invention Field
PHYSICS
Status
Email
Parent Application
Patent Number
Legal Status
Grant Date
2018-01-08
Renewal Date

Applicants

FUJIFILM CORPORATION
26-30, NISHIAZABU 2-CHOME, MINATO-KU, TOKYO.

Inventors

1. TAGUCHI, YOSHINORI
C/O FUJIFILM CORPORATION, 4000, KAWASHIRI, YOSHIDA-CHO, HAIBARA-GUN, SHIZUOKA.
2. ARIMURA, KEISUKE
C/O FUJIFILM CORPORATION, 4000, KAWASHIRI, YOSHIDA-CHO, HAIBARA-GUN, SHIZUOKA.
3. OOHASHI, HIDEKAZU
C/O FUJIFILM CORPORATION, 4000, KAWASHIRI, YOSHIDA-CHO, HAIBARA-GUN, SHIZUOKA.
4. INNO, TOSHIFUMI
C/O FUJIFILM CORPORATION, 4000, KAWASHIRI, YOSHIDA-CHO, HAIBARA-GUN, SHIZUOKA.
5. MIKOSHIBA, HISASHI
C/O FUJIFILM CORPORATION, 4000, KAWASHIRI, YOSHIDA-CHO, HAIBARA-GUN, SHIZUOKA.

Specification

We claim:

1. A process for producing a lithographic printing plate, comprising subjecting a lithographic printing plate precursor to image-wise exposure and then removing the photosensitive layer from an unexposed portion in the presence of a developer having a pH from 2 to 10,

wherein the lithographic printing plate precursor comprising at least a photosensitive layer on a support and employing a system of removing a photosensitive layer from an unexposed portion in a presence of a developer having a pH from 2 to 10, wherein the photosensitive layer comprises the following components (A), (B), and (C):

(A) a copolymer having a repeating unit represented by the formula (1) and at least either one of a repeating unit represented by the formula (2) and a repeating unit represented by the formula (3):

in the formulae (1), (2), and (3), each of A and B independently represents a hetero atom, each of R and R1 to R9 represents a monovalent substituent, L represents a divalent linking group, X represents a hydroxyl group, a monovalent group containing an acid group, an alkyleneoxy group, an amide group, or an ether group, an amino group, an ammonium group, or a salt obtained by neutralizing an acid group, L0 represents a single bond or a divalent hydrocarbon group, with the proviso that R2 and R in the formula (1), R5 and L in the formula (2), and R8 and Lo in the formula (3) may be coupled to each other to form a ring;

(B) a compound having an ethylenically unsaturated bond; and

(C) a polymerization initiator.

2. The process for producing a lithographic printing plate according to claim 1, wherein X in the formula (2) or (3) in the component (A) is selected from an amino group, a sulfonic acid group, a carboxylic acid group, a phosphonic acid group, a group obtained by neutralizing a carboxylic acid, a group obtained by neutralizing a sulfonic acid, and a group obtained by neutralizing a phosphonic acid.

3. The process for producing a lithographic printing plate according to claim 1 or 2, wherein the photosensitive layer further comprises (D) a sensitizing dye.

4. The process for producing a lithographic printing plate according to any one of claims 1 to 3, wherein the copolymer (A) contains the repeating unit represented by the formula (2) or (3) in which X represents a carboxylic acid or a carboxylate and further contains a repeating unit represented by the following formula (I):

in the formula (I), each of two A's independently represents a hetero atom and each of R1 to R3 and R10 independently represents a monovalent substituent, with the proviso that any two of Rx to R3 may be the same or different.

5. The process for producing a lithographic printing plate according to claim 4, wherein the copolymer (A) contains 70 mol% or greater but not greater than 95 mol% of the repeating unit represented by the formula (I).

6. The process for producing a lithographic printing plate according to claim 4 or 5, wherein the copolymer (A) contains the repeating unit represented by the formula (2) or formula (3) in which X represents a carboxylic acid or a carboxylate; contains a repeating unit represented by the formula (II) which is a repeating units represented by the formula (3); and contains, in the copolymer, 30 mol% or greater but not greater than 80 mol% of the repeating unit represented by the formula (II):

7. The process for producing a lithographic printing plate according to any one of claims 4 to 6, wherein the copolymer (A) has a mass average molecular weight (Mw) of from 10,000 to 40,000.

8. The process for producing a lithographic printing plate according to any one of claims 4 to 7, wherein the copolymer (A) contains the repeating unit represented by the formula (2) or the formula (3) in which X represents a carboxylic acid or a carboxylate; and the number of the carboxylic acid or carboxylate contained in one repeating unit is one.

9. The process for producing a lithographic printing plate according to any one of claims 4 to 8, wherein the copolymer (A) contains the repeating unit represented by the formula (2) or the formula (3) in which X represents a carboxylic acid or a carboxylate and L or Lo represents an aliphatic linking group which may have a substituent.

10. The process for producing a lithographic printing plate according to any one of claims 4 to 9, wherein the copolymer (A) has at least one ethylenically unsaturated double bond group.

11. The process for producing a lithographic printing plate according to any one of claims 4 to 10, wherein the copolymer (A) contains the repeating unit represented by the formula (2) or the formula (3) in which X represents a carboxylate having a metal salt as a counter cation.

12. The process for producing a lithographic printing plate according to any one of claims 4 to 11, wherein the photosensitive layer further contains an acrylic resin.

13. The process for producing a lithographic printing plate according to claim 1, wherein the developer contains a surfactant.

14. The process for producing a lithographic printing plate according to claim 13, wherein the surfactant is a surfactant selected from the group consisting of nonionic surfactants and amphoteric surfactants, and combinations thereof.

15. The process for producing a lithographic printing plate according to claim 1, wherein the developer contains an organic amine compound.

16. The process for producing a lithographic printing plate according to any one of claims 1 to 15, wherein removal of the protective layer, development, and gumming are carried out at the same time.

Documents

Application Documents

# Name Date
1 6074-chenp-2010 power of attorney 27-09-2010.pdf 2010-09-27
1 6074-CHENP-2010-RELEVANT DOCUMENTS [09-08-2021(online)].pdf 2021-08-09
2 6074-chenp-2010 pct 27-09-2010.pdf 2010-09-27
2 6074-CHENP-2010-RELEVANT DOCUMENTS [09-03-2020(online)].pdf 2020-03-09
3 6074-CHENP-2010-RELEVANT DOCUMENTS [07-03-2019(online)].pdf 2019-03-07
3 6074-chenp-2010 form-5 27-09-2010.pdf 2010-09-27
4 6074-CHENP-2010-IntimationOfGrant08-01-2018.pdf 2018-01-08
4 6074-chenp-2010 form-3 27-09-2010.pdf 2010-09-27
5 6074-CHENP-2010-PatentCertificate08-01-2018.pdf 2018-01-08
5 6074-chenp-2010 form-1 27-09-2010.pdf 2010-09-27
6 Abstract_Granted 291490_08-01-2018.pdf 2018-01-08
6 6074-chenp-2010 correspondence others 27-09-2010.pdf 2010-09-27
7 Claims_Granted 291490_08-01-2018.pdf 2018-01-08
7 6074-chenp-2010 form-2 27-09-2010.pdf 2010-09-27
8 Description_Granted 291490_08-01-2018.pdf 2018-01-08
8 6074-chenp-2010 drawings 27-09-2010.pdf 2010-09-27
9 6074-chenp-2010 description(complete) 27-09-2010.pdf 2010-09-27
9 Drawing_Granted 291490_08-01-2018.pdf 2018-01-08
10 6074-chenp-2010 claims 27-09-2010.pdf 2010-09-27
10 6074-CHENP-2010-ABSTRACT [20-12-2017(online)].pdf 2017-12-20
11 6074-chenp-2010 abstract 27-09-2010.pdf 2010-09-27
11 6074-CHENP-2010-certified copy of translation (MANDATORY) [20-12-2017(online)].pdf 2017-12-20
12 6074-CHENP-2010 CORRESPONDENCE OTHERS 24-02-2011.pdf 2011-02-24
12 6074-CHENP-2010-CLAIMS [20-12-2017(online)].pdf 2017-12-20
13 6074-chenp-2010 form-3 18-03-2011.pdf 2011-03-18
13 6074-CHENP-2010-FER_SER_REPLY [20-12-2017(online)].pdf 2017-12-20
14 6074-chenp-2010 correspondence others 18-03-2011.pdf 2011-03-18
14 6074-CHENP-2010-FORM 3 [20-12-2017(online)].pdf 2017-12-20
15 6074-CHENP-2010-FORM-26 [20-12-2017(online)].pdf 2017-12-20
15 abstract6074-chenp-2010.jpg 2011-09-04
16 6074-CHENP-2010 CORRESPONDENCE OTHERS 27-12-2011.pdf 2011-12-27
16 6074-CHENP-2010-OTHERS [20-12-2017(online)].pdf 2017-12-20
17 6074-CHENP-2010-PETITION UNDER RULE 137 [20-12-2017(online)].pdf 2017-12-20
17 6074-CHENP-2010 FORM-18 27-12-2011.pdf 2011-12-27
18 6074-CHENP-2010 CORRESPONDENCE OTHERS 07-04-2014.pdf 2014-04-07
18 6074-CHENP-2010-FER.pdf 2017-08-09
19 6074-CHENP-2010 FORM-3 07-04-2014.pdf 2014-04-07
19 6074-CHENP-2010 FORM-1 08-07-2014.pdf 2014-07-08
20 6074-CHENP-2010 FORM-3 07-04-2014.pdf 2014-04-07
20 6074-CHENP-2010 FORM-1 08-07-2014.pdf 2014-07-08
21 6074-CHENP-2010 CORRESPONDENCE OTHERS 07-04-2014.pdf 2014-04-07
21 6074-CHENP-2010-FER.pdf 2017-08-09
22 6074-CHENP-2010 FORM-18 27-12-2011.pdf 2011-12-27
22 6074-CHENP-2010-PETITION UNDER RULE 137 [20-12-2017(online)].pdf 2017-12-20
23 6074-CHENP-2010 CORRESPONDENCE OTHERS 27-12-2011.pdf 2011-12-27
23 6074-CHENP-2010-OTHERS [20-12-2017(online)].pdf 2017-12-20
24 abstract6074-chenp-2010.jpg 2011-09-04
24 6074-CHENP-2010-FORM-26 [20-12-2017(online)].pdf 2017-12-20
25 6074-chenp-2010 correspondence others 18-03-2011.pdf 2011-03-18
25 6074-CHENP-2010-FORM 3 [20-12-2017(online)].pdf 2017-12-20
26 6074-chenp-2010 form-3 18-03-2011.pdf 2011-03-18
26 6074-CHENP-2010-FER_SER_REPLY [20-12-2017(online)].pdf 2017-12-20
27 6074-CHENP-2010 CORRESPONDENCE OTHERS 24-02-2011.pdf 2011-02-24
27 6074-CHENP-2010-CLAIMS [20-12-2017(online)].pdf 2017-12-20
28 6074-chenp-2010 abstract 27-09-2010.pdf 2010-09-27
28 6074-CHENP-2010-certified copy of translation (MANDATORY) [20-12-2017(online)].pdf 2017-12-20
29 6074-chenp-2010 claims 27-09-2010.pdf 2010-09-27
29 6074-CHENP-2010-ABSTRACT [20-12-2017(online)].pdf 2017-12-20
30 6074-chenp-2010 description(complete) 27-09-2010.pdf 2010-09-27
30 Drawing_Granted 291490_08-01-2018.pdf 2018-01-08
31 Description_Granted 291490_08-01-2018.pdf 2018-01-08
31 6074-chenp-2010 drawings 27-09-2010.pdf 2010-09-27
32 Claims_Granted 291490_08-01-2018.pdf 2018-01-08
32 6074-chenp-2010 form-2 27-09-2010.pdf 2010-09-27
33 Abstract_Granted 291490_08-01-2018.pdf 2018-01-08
33 6074-chenp-2010 correspondence others 27-09-2010.pdf 2010-09-27
34 6074-CHENP-2010-PatentCertificate08-01-2018.pdf 2018-01-08
34 6074-chenp-2010 form-1 27-09-2010.pdf 2010-09-27
35 6074-CHENP-2010-IntimationOfGrant08-01-2018.pdf 2018-01-08
35 6074-chenp-2010 form-3 27-09-2010.pdf 2010-09-27
36 6074-CHENP-2010-RELEVANT DOCUMENTS [07-03-2019(online)].pdf 2019-03-07
36 6074-chenp-2010 form-5 27-09-2010.pdf 2010-09-27
37 6074-chenp-2010 pct 27-09-2010.pdf 2010-09-27
37 6074-CHENP-2010-RELEVANT DOCUMENTS [09-03-2020(online)].pdf 2020-03-09
38 6074-chenp-2010 power of attorney 27-09-2010.pdf 2010-09-27
38 6074-CHENP-2010-RELEVANT DOCUMENTS [09-08-2021(online)].pdf 2021-08-09

Search Strategy

1 6074_23-03-2017.pdf

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