The present invention relates to esters formed from sugar alcohol, in particular sugar polyol, and their use as a lubricating base as well as their manufacturing process.

Currently, the lubricating base market is dominated by mineral oils of petroleum origin. In 2008, European production of lubricants amounted to 4.5 million tonnes per year. These lubricating bases are used in various industries such as motor oil, cutting oil for chainsaw chains, oil for offshore petroleum drilling, hydraulic oil for construction machinery and agricultural machinery, etc.

These mineral oils, once used, are not always recycled and cause environmental pollution due to discharge on the ground, in sewers, in lakes and rivers. In view of the potential impact of these lubricating oils on the environment, the development of ecological and biodegradable lubricating bases is essential, in particular for applications in which the lubricant is likely to escape into the environment.

Vegetable and animal oils, known for several years for their use as a lubricant, could meet this concern for environmental protection because they have the advantage of being ecological. However, these oils have a low thermal stability as well as a low resistance to oxidation compared to mineral oils and their † likely to hydrolyze in the presence of water.

Polyol esters, formed from fatty acids attached to an alcohol, exhibit good oxidative stability, good hydrolytic stability, relatively high biodegradability and good low temperature performance. Biodegradable lubricating compositions of polyol esters derived from palm oil comprising polyols such as neopentylglycol or trimethylolpropane and

Products derived from palm oil are described in patent application EPI 533360. However, such compositions are only suitable for temperatures ranging from 15 to 40 ° C.

In this context, it therefore remains necessary to develop alternative polyol esters whose structure can derive entirely from ingredients of renewable origins, possessing excellent lubricating properties, as well as being harmless to the chemical. man and the environment.

Summary of the invention

In the context of the present invention, it has been observed that esters of sugar alcohol, in particular of sugar polyol e † of linear C6-Cn fatty acid exhibit excellent properties for application in lubricants. .

The present invention results from the unexpected demonstration, by the inventors, that esters of sugar alcohol, in particular of sugar polyol, in particular of erythritol, e † of linear C6-Cn fatty acids have excellent properties for application in lubricants.

Thus, the present invention relates to esters of at least one sugar alcohol, in particular a sugar polyol, e † of at least one linear C6-Cn fatty acid in which the sugar alcohol, in particular the polyol of sugar, is erythritol.

The present invention also relates to the use of an ester of at least one sugar alcohol, in particular a sugar polyol, e † of at least one linear C6-Cn fatty acid as defined above as a base. lubricating.

The present invention also relates to a lubricating base composition comprising an ester of at least one sugar alcohol, in particular a sugar polyol, e † of at least one linear C6-Cn fatty acid as defined above.

The present invention also relates to a process for preparing an ester comprising the esterification reaction of at least one linear C 6 -Cn fatty acid with at least one sugar alcohol, in particular a sugar polyol, preferably the method comprises a step of removing excess acids, e † in the absence of at least one of the following steps:

• downstream treatment by adding an additive;

• addition of catalyst;

• addition of organic solvent.

The present invention also relates to esters of at least one sugar alcohol, in particular a sugar polyol, and of at least linear C6-Cn fatty acid obtained by the process defined above.

The lubricating base compositions according to the invention synthesized from esters of at least one polyol and of a fatty acid of renewable origin, such as for example erythritol and n-heptanoic acid (eg Oleris® C7 from Arkema) without adding a catalyst and without downstream treatment by adding an additive make it possible to achieve firm properties of thermal stability superior to the usual esters don † the alcohol is not biobased, such as for example trimethylolpropane, as this is detailed in the examples below.

Thus, the present invention provides a lubricating base composition of renewable origin, which exhibits good oxidation stability, good thermal stability and very good lubricating properties.

Furthermore, the composition exhibiting good flow at low temperature is particularly suitable for use at low temperatures, namely, typically equal to or less than 0 ° C.

The term “biodegradable” is used here to denote a compound formed from molecules which can be transformed into smaller molecules and less polluting, for example by microorganisms living in the natural environment, such as bacteria, fungi and algae. The end result of this degradation is usually water, carbon dioxide or methane.

By materials or compounds or ingredients “derived from renewable resources” or “biobased”, we mean renewable natural materials or compounds or ingredients whose stock can be reconstituted over a short period on a human scale. These are in particular raw materials of animal or plant origin. By raw materials of renewable origin or bio-resourced raw materials, is meant materials which include bio-resourced carbon or carbon of renewable origin. In fact, unlike materials made from fossil fuels, materials made from renewable raw materials contain carbon 14 ( , 4VS). The “carbon content of renewable origin” or “bio-resourced carbon content” is determined in application of the standards ASTM D 6866 (ASTM D 6866-06) and ASTM D 7026 (ASTM D 7026-04).

The viscosity of a fluid means the resistance it opposes to the internal sliding of its molecules during its flow. The viscosity is given for a reference temperature. The expressed kinematic viscosity is m / s 2 , is calculated using the following formula: o = h / r, where

h is the dynamic viscosity in Pa.s; and

p is the density of the fluid in kg / m 3

Kinematic viscosity is also expressed in Stockes (St) or in cenfistokes (cSt).

Kinematic viscosity is measured according to the ISO 3104 standard.

Oxidative stability can be determined via two measurements: oxygen induction time and oxygen induction temperature. The oxygen induction time and the oxygen induction temperature can be measured in a differential scanning calorimeter (DSC - Differential scanning calorimetry) according to ISO 1 1357-6: 2018.

The pour point of a product is the minimum temperature at which the product will still flow. The pour point is measured according to ISO 3016.

The viscosity index (VI) (unitless) indicates the rate of change in the viscosity of an oil over a given temperature range, usually between 40 ° C and 100 ° C. The viscosity index can be defined as the kinematic viscosity gradient of a material, between 40 and 100 ° C. When the viscosity index is low (less than 100) the fluid shows a relatively large variation in viscosity with temperature. When the viscosity index is high (greater than 150), the fluid exhibits relatively little change in viscosity with temperature. In a variety of applications, a high or very high viscosity index is preferable. The viscosity index is measured according to the test method described in standard ASTM D 2270.

Esters

Alcohol is understood to mean a molecule having at least one hydroxyl group (-OH). The term “polyol” is understood to mean a molecule having at least two hydroxyl groups (—OH).

Preferably, the polyol according to the invention is an organic compound containing several hydroxyl groups. Preferably, the polyols do not refer to compounds which contain functional groups other than hydroxyl. More

preferably, the polyol according to the invention is a compound corresponding to the general chemical formula C n H2n + 20n and having at least two hydroxyl groups.

The esters according to the present invention are formed from at least one sugar alcohol, in particular a sugar polyol, and at least one C6-Cn fatty acid.

According to one embodiment, the esters according to the present invention can be mono-, di-, tri-, and tetraesters.

The sugar alcohol, in particular the sugar polyol, according to the invention is preferably obtained from renewable resources. The sugar alcohol, in particular the sugar polyol, according to the invention is preferably biodegradable.

Preferably, the sugar alcohol, in particular the sugar polyol, according to the invention is selected from the group consisting of monosaccharides, disaccharides, trisaccharides, and mixtures thereof.

Preferably, the monosaccharide according to the invention is selected from the group consisting of erythritol, xylose, arabinose, ribose, sorbitol, sorbitan, glucose, sorbose, fructose, xylitol, and their mixtures. , more preferably from the group consisting of xylose, arabinose, ribose, glucose, sorbose, fructose, and mixtures thereof.

Preferably, the disaccharide according to the invention is selected from the group consisting of maltose, lactose, sucrose, and mixtures thereof.

The trisaccharide according to the invention is preferably selected from the group consisting of raffinose, maltotriose, hydrogenated starch hydrolysates, and mixtures thereof.

More preferably, the sugar alcohol, in particular the sugar polyol, according to the invention is erythritol.

According to one embodiment, the sugar polyol according to the invention is obtained by hydrogenation of a sugar.

The fatty acid according to the invention is preferably obtained from renewable resources. The fatty acid according to the invention is preferably of plant or animal origin, saturated or unsaturated, linear or branched.

The fatty acid according to the invention is preferably obtained by trituration of seeds, stones or fruits of plants, in particular oleaginous plants, such as linseed, rapeseed, sunflower, soybean, olive, palm, castor, wood, corn, squash, grape seeds, jojoba, sesame, walnut, hazelnut, almond, shea, macadamia, cotton, alfalfa, rye, of

safflower, peanut, copra, de † all e † of argan or from animal fats such as tallow fat.

The fatty acid according to the invention is preferably selected from the group consisting of fatty acids of castor oil, coconut oil, cottonseed oil, dehydrated castor oil, soybean oil, tall oil, rapeseed oil, sunflower oil, linseed oil, palm oil, tung oil, oiticica oil, safflower oil, oil olive, wood, corn, squash, grape seed oil, jojoba oil, sesame, walnut, hazelnut, almond, shea, macadamia, alfalfa, rye, peanut, copra, argan e †.

The fatty acid according to the invention comprises from 6 to 11 carbon atoms.

Preferably the fatty acid according to the invention is selected from the group consisting of caproic acid, heptanoic acid, caprylic acid, pelargonic acid, capric acid, furan dicarboxylic acid, l tetrahydrofuran 2,5 dicarboxylic acid, tetrahydrofuran 3,5 dicarboxylic acid, azelaic acid, decanedioic acid, 10-undecylenic acid, undecandioic acid, e † dodecanedioic acid.

Preferably, the fatty acid according to the invention is a linear fatty acid.

Preferably, linear fatty acids make it possible to increase the viscosity index of the lubricating bases synthesized, to improve their thermal stability and are more easily biodegradable than branched acids, mainly obtained from the petroleum industry.

Preferably, the fatty acid according to the invention is obtained from castor oil.

The term “fatty acid obtained from castor oil” is understood to mean the fatty acid present in the oil and / or the fatty acids which can be obtained at the end of a chemical transformation. For example, heptanoic acid and / or 10-undecylenic acid can be obtained from castor oil, typically, by the thermal cracking step of methyl ricinoleate which results from the transesterification of the methyl ricinoleate. Castor oil. The fatty acid according to the invention is preferably n-heptanoic acid. Preferably also the fatty acid according to the invention is the n-heptanoic acid Oleris® (Arkema).

Preferably, n-heptanoic acid is derived from castor oil.

Preferably, the ester according to the invention is formed of a sugar alcohol, in particular of a sugar polyol, according to the invention of which at least 3 alcohol groups, preferably 4 alcohol groups, are esterified by fatty acids according to the invention.

Also preferably, the mass ratio of the fatty acid according to the invention to the sugar alcohol, in particular the sugar polyol, according to the invention is in the range from 4: 1 to 10: 1. More preferably, the mass ratio of the fatty acid according to the invention to the sugar alcohol, in particular the sugar polyol, according to the invention is about 5: 1.

Preferably, a fraction of at least 50% by mass, preferably 75% by mass of the ester is obtained from renewable resources relative to the total mass of the ester.

Preferably, the ester according to the invention has an oxygen induction time measured in a differential scanning calorimeter at 150 ° C. greater than 2 hours.

Preferably, the ester according to the invention has an oxygen induction temperature measured in a differential scanning calorimeter of greater than 200 ° C.

The ester according to the invention preferably comprises a pour point below -30 ° C, preferably between -50 ° C and -30 ° C, more preferably about -42 ° C.

The ester according to the invention preferably comprises a kinematic viscosity of between 14 and 30 mm 2 / s at 40 ° C, and / or less than 4.5 mm 2 / s at 100 ° C, which are measured according to the ISO 3104 standard. .

Process

The process for preparing the esters according to the invention from sugar alcohol, in particular sugar polyol, and fatty acid according to the invention can be carried out according to the usual esterification techniques well known to man. of career.

Preferably, the esterification process according to the invention comprises a step of esterifying at least one sugar alcohol according to the invention, in particular a sugar polyol, in the presence of at least one linear C6 fatty acid. -Cn according to the invention in excess, with or without catalyst.

The esterification step according to the invention is preferably carried out at a temperature between 140 ° C and 250 ° C for a period of 0.5 to 12 hours, preferably 1 to 10 hours, more preferably from 2 to 9 hours.

The esterification step according to the invention is preferably carried out under an inert atmosphere.

Preferably, the process for preparing the esters according to the invention is carried out under controlled vacuum so as to remove the excess acid. The esterification process according to the invention can comprise a step of adding an absorbent such as alumina, silica gel, zeolites, activated carbon, and clay.

The process according to the invention can further comprise a step of adding water and base to simultaneously neutralize the residual organic and mineral acids and / or hydrolyze the catalyst. In this case, the method according to the invention can comprise a step of eliminating the water used by heating and placing under vacuum.

The process according to the invention can also comprise a step of filtering the solids of the mixture of esters containing the major part of the mixture of excess acid used in the esterification reaction.

The process according to the invention can comprise a step of removing the excess acids by steam extraction or by any other method of distillation and recycling of the acid in the reaction vessel.

According to one embodiment, the method of the invention comprises a step of removing excess acids, preferably carried out by vacuum distillation.

Preferably, the compound obtained by the process according to the invention is purified by distillation at reduced pressure of the unreacted acid. The distillation is preferably carried out under vacuum for 15 minutes to 2 hours. The distillation is further preferably carried out at a temperature between 140 ° C and 180 ° C. The amount of free acid remaining after the distillation step can be reduced by treatment with epoxy esters, by neutralization with any suitable alkali material such as lime, alkali metal hydroxides, alkali metal carbonates or basic alumina. When treatment with epoxy esters is carried out, a second distillation under reduced pressure can be carried out to remove excess epoxy ester.

The method according to the invention can comprise a step of removing any residual solid material from the ester extracted during a final filtration.

Preferably, the fatty acid according to the invention is present in the reaction to form the ester according to the invention in an excess of approximately 10 to 50% by moles, preferably 10 to 30% by moles, relative to the amount of sugar alcohol, in particular sugar polyol, used.

The process according to the invention can be carried out in the presence of a catalyst. The catalyst can be any catalyst well known to those skilled in the art for esterification reactions. Preferably, the catalyst is selected from the group consisting of tin chloride, sulfuric acid, p-toluenesulphonic acid, methanesulphonic acid, sulphosuccinic acid, hydrochloric acid, phosphoric acid. , catalysts based on zinc, copper, tin, titanium, zirconium or tungsten; alkali metal salts such as sodium or potassium hydroxide, sodium or potassium carbonate, sodium or potassium ethoxide, sodium or potassium methoxide, zeolites and acidic ion exchangers , or mixtures thereof.

Preferably, no downstream treatment step by adding an additive is carried out during the process for preparing the ester according to the invention.

The term “downstream treatment by addition of an additive” is understood to mean one or more of the steps typically carried out at the end of the esterification step, as (s) described above, at namely, the step of adding an absorbent, the step of adding water and base, the step of filtering solids from the ester mixture and / or the step of removing acids by excess.

Preferably, the process for preparing the ester is carried out without a catalyst.

Preferably, the process for preparing the ester is carried out without adding an organic solvent.

Preferably, the process for preparing the ester is carried out in the absence of at least one, preferably at least two, more preferably all of the following steps:

• downstream treatment by adding an additive;

• addition of catalyst;

• addition of organic solvent.

Preferably, the reaction is carried out for a sufficient time to obtain a false fetraesters greater than or equal to 80% by mass relative to the total amount of ester. More preferably the reaction is carried out for a sufficient time to obtain a false fetraesters greater than or equal to 93% by mass relative to the total amount of ester.

Use

The esters according to the invention are preferably used as such as lubricating base or lubricating base oil.

The esters according to the invention can also be used as a mixture with other base oils, such as mineral oils, highly refined mineral oils, polyalphaolefins (PAO), polyalkylene glycols (PAG), phosphate esters, silicone oils, diesfers, polyisobufylenes and polyol esters.

In particular, the esters according to the invention are useful for the preparation of a lubricating base composition. The lubricating base composition according to the invention can be used in all types of industries, in particular as automotive lubricants, as metalworking oils, as hydraulic oils, as turbine oils, or even as oils for airplanes.

Preferably, the composition according to the invention can comprise a level of tetraesters greater than or equal to 80% by mass relative to the total amount of ester. More preferably, the composition may contain a level of tetraesters greater than or equal to 93% by mass relative to the total amount of ester.

The composition according to the invention can comprise, in addition to the esters according to the invention, one or more additives. Preferably, the additives are selected from the group consisting of antioxidants, thermal stability improvers, corrosion inhibitors, metal deactivators, lubricant additives, viscosity index improvers, pour point depressants, detergents, dispersants, defoamers, antiwear agents, and additives resistant to extreme pressures.

Preferably, the amount of additives in the composition according to the invention does not exceed 10% by weight, preferably 8% by weight, more preferably 5% by weight relative to the total weight of the lubricating base composition.

Preferably, the amount of antioxidants used is between 0.01% and 5% relative to the total weight of the lubricating base composition.

Preferably, the amount of corrosion inhibitors is between 0.01% and 5% by weight relative to the total weight of the lubricating base composition.

Preferably, the amount of metal deactivators is between 0.001% and 0.5% by weight relative to the total weight of the lubricating base composition.

Preferably, the amount of lubricating additives is between 0.5% and 5% by weight relative to the total weight of the lubricating base composition.

Preferably, the amount of agents improving the viscosity index is between 0.01% and 2% by weight relative to the total weight of the lubricating base composition.

Preferably, the amount of pour point depressants is between 0.01% and 2% by weight relative to the total weight of the lubricating base composition.

Preferably, the amount of detergents is between 0.1% and 5% by weight relative to the total weight of the lubricating base composition.

Preferably, the amount of dispersing agents is between 0.1% and 5% by weight relative to the total weight of the lubricating base composition.

Preferably, the amount of antifoaming agents is between 0.01% and 2% by weight relative to the total weight of the lubricating base composition.

Preferably, the amount of antiwear agents is between 0.01% and 2% by weight relative to the total weight of the lubricating base composition.

Preferably, the amount of additives resistant to extreme pressures is between 0.1% and 2% by weight relative to the total weight of the lubricating base composition.

Antioxidants and thermal stability improvers can be selected from any antioxidant and thermal stability improvers well known to those skilled in the art. By way of example, the antioxidant and the thermal stability improving agent can be selected from the group consisting of:

- diphenyl-amine, dinaphthyl-amine, phenylnaphthylamine, in which the phenyl group or the naphthyl group can be substituted, for example by the groups N, N'-diphenyl phenylenediamine, p-octyldiphenylamine, p, p- dioctyldiphenylamine, N-phenyll -naphthyl amine, N-phenyl-2-naphthyl amine, N- (p-dodecyl) phenyl-2-naphthyl amine, di-1-naphthyl amine, and di-2-naphthyl amine;

phenothazines, such as N-alkylphenothiazines;

imino (bisbenzyl); and

hindered phenols such as 6- (t-butyl) phenol, 2, ô-di- (t-butyl) phenol, 4-methyl-2, 6- di- (t-butyl) phenol, 4,4'- methylenebis (-2,6-di- (t-butyl) phenol).

The metal deactivators can be chosen from any metal deactivators well known to those skilled in the art. By way of example, the metal deactivators can be selected from the group consisting of imidazole, benzamidazole, 2-mercaptobenzthiazole, 2,5-di-mercaptothiadiazole, salicylidine-propylenediamine, pyrazole, benzotriazole, tolutriazole, 2-methylbenzamidazole, 3,5-dimethyl pyrazole, and methylene bis-benzotriazole. Other examples of metal deactivators or corrosion inhibitors include:

- organic acids and their esters, metal salts and anhydrides, such as N-oleyl-sarcosine, sorbitan monooleate, lead naphthenate, dodecenyl-succinic acid and its partial esters and amides, and 4-nonylphenoxyacetic acid;

primary, secondary and tertiary aline and cycloaliphatic amines and amine salts of organic and inorganic acids, such as oil-soluble alkylammonium carboxylates;

- heterocyclic compounds containing nitrogen, such as thiadiazoles, substituted imidazolines and oxazolines;

quinolines, quinones and anthraquinones;

- propyl gallate:

barium dinonylnaphthalenesulfonate;

ester and amide derivatives of anhydrides or alkenylsuccinic acids, dithiocarbamates, dithiophosphates; amine salts of alkyl acid phosphates and their derivatives.

The lubricant additives can be chosen from any lubricant additives well known to those skilled in the art. By way of example of lubricating additives, mention may be made of long-chain derivatives of fatty acids and of natural oils, such as esters, amines, amides, imidazolines and borates.

The viscosity index improvers can be chosen from any viscosity index improver well known to those skilled in the art. As examples of viscosity index improvers, mention may be made of polymethacrylates, vinylpyrrolidone and methacrylate copolymers, polybutenes and styrene-acrylate copolymers.

The pour point depressants can be selected from any pour point depressants well known to those skilled in the art. As

examples of pour point depressants that may be mentioned are polymethacrylates such as ethylene methacrylate-vinyl acetate terpolymers; alkylated naphthalene derivatives; and Friedel-Crafts condensation products catalyzed by urea with naphthalene or phenols.

The detergent and dispersing agents can be chosen from any detergent and dispersing agents well known to those skilled in the art. By way of example of detergents and dispersants, mention may be made of polybutenylsuccinic acid amides; polybutenylphosphonic acid derivatives; long chain alkyl substituted aromatic sulfonic acids and their salts; and metal salts of alkylsulfides, alkylphenols and condensation products of alkylphenols and aldehydes.

The anti-foaming agents can be selected from any anti-foaming agents well known to those skilled in the art. By way of example of anti-foaming agents, mention may be made of silicone polymers and certain acrylates.

The antiwear agents and additives resistant to extreme pressure can be selected from any antiwear agents and additives resistant to extreme pressures. As an example of anti-wear agents and additives resistant to extreme pressures, we can cite:

- sulfurized fatty acids and fatty acid esters, such as sulfurized octyl fallate;

- sulfurized terpenes;

sulfurized olefins;

- organopolysulphides;

organophosphorus derivatives including amine phosphates, alkyl acid phosphates, dialkyl phosphates, aminedithiophosphates, frialkyl and triaryl phosphorothionates, frialkyl and triaryl phosphines, and dialkyl phosphines such as phosphoric acid monohexyl ester amine salts, dinonylnaphfalenesulfonate amine salts, triphenyl phosphate, frinaphfyl phosphate, diphenylcresyl and phenylphenyl phosphates, naphfyldiphenyl phosphate, friphenylphosphorothionate;

dithiocarbamates, such as antimony dialkyldithiocarbamate; chlorinated and / or fluorinated hydrocarbons and xanfhates.

The invention will be further explained with the aid of the nonlimiting Examples which follow.

Examples

The inventors have studied the properties of an ester according to the present invention for application in lubricants.

1. Preparation of the ester

2 samples are prepared:

- ester of erythritol and of n-heptanoic acid (ester according to the invention); and

- ester of trimethylolpropane and of n-heptanoic acid (comparative example 1).

Synthesis of an
'invention):

Erythritol (14.7g; 0.12 mol) and n-heptanoic acid (81.7g; 0.62 mol) are loaded into a 250ml three-necked flask equipped with a stirrer, a thermometer, 'a refrigerant and an inlet for nitrogen. The reaction mixture was heated at 210 ° C. under a nitrogen atmosphere for a period of 7:30, until the theoretical quantity of water was collected. The crude product is then distilled at a temperature of 180 ° C and under maximum vacuum for 1 hour 30 minutes to remove excess n-heptanoic acid in order to obtain 66.5 g of product with an acid number of

0.1 mgKOH / g.

The kinematic viscosities, the viscosity index (VI.) And the pour point of the product are evaluated and reported in Table 2.

The chemical composition of the product was established by chromatography

gaseous as follows: 94.1% tetraester of erythritol and n-heptanoic acid,

2.2% erythritol n-heptanoic acid triester and 2.9% erythritol n-heptanoic acid anhydroester.

Synthesis of an ester of trimethylolpropane and n-heptanoic acid (example

Trimethylolpropane (53.8g, 0.4 mol) and n-heptanoic acid (1 81.5g, 1.38mol) are loaded into a 500ml three-necked flask equipped with a stirrer, a thermometer, a condenser and an inlet for nitrogen. The reaction mixture was heated at 185 ° C under a nitrogen atmosphere for a period of 3 h, until the

theoretical amount of water is collected. Zirconium tetrabutanolate (1.5 g, 80% in butanol, 0.5% by weight / total weight of the reactants) is then added in batch to the reactor. The assembly is gradually placed under maximum vacuum at 150 ° C. for 3 hours 30 minutes to distill off the excess unreacted acid and leads to 187.4 g of product. A downstream treatment with activated basic alumina is carried out on the reaction crude and results in an oil with an acid number of

0.1 mgKOH / g.

The kinematic viscosities, the viscosity index (VI.) And the pour point of the product are evaluated and reported in Table 2.

The chemical composition of the product was established by chromatography

gaseous as follows: 98.8% of trimethylol propane triheptanoate and 0.03% of trimethylol propane diheptanoate.

2. Measurement of the resistance to oxidation

Oxidative stability is determined via two measurements: oxygen induction time and oxygen induction temperature. Oxygen induction time and oxygen induction temperature are † measured in a Differential Scanning Calorimeter (DSC).

For the measurement of the oxygen induction time, the sample is heated to 150 ° C. and then maintained at constant temperature. It is then exposed to an oxidizing atmosphere. The time between contact with oxygen and the onset of oxidation is the oxygen induction time.

For the measurement of the oxygen induction temperature, the sample is heated with a constant heating rate under an oxidizing atmosphere until the reaction begins. The oxygen induction temperature is the temperature at which the oxidation reaction begins.

The results are presented in Table 1 below:

[Tables 1]

Table 1: measurement of the resistance to oxidation

The measurements show that the oxygen induction times at 150 ° C of the two samples are similar. The ester according to the invention has a higher oxygen induction temperature than that of the comparative example. Consequently, the ester according to the invention has better properties of resistance to oxidation than a usual ester synthesized from a non-biobased alcohol.

4. Measurement of kinematic viscosity

The kinematic viscosity was measured at 40 ° C. e † at 100 ° C. according to the ISO 3104 standard. The results, expressed in mm 2 / s, are presented in Table 2 below.

5. Measurement of viscosity index

The viscosity index (unitless) is measured according to the test method described in standard ASTM D 2270. The results are presented in Table 2 below.

6. Pour point measurement

The pour point, expressed in ° C, is measured according to the ISO 3016 standard. The results are presented in Table 2 below.

[Tables 2]

Table 2: Measurement of kinematic viscosity, viscosity index and pour point.

These results show that the ester according to the invention synthesized only from substances of renewable origin without addition of catalyst and without downstream treatment by addition of additive, unlike the comparative example, exhibits kinemafic viscosities at 40 ° C. e † 100 ° C close to those of the comparative example. The ester according to the invention displays a higher viscosity index, which means that the lubricating base according to the invention has a more stable viscosity as a function of the temperature. The lubricating base of the invention exhibits a higher pour point, correlated with the higher melting point of erythritol (120 ° C) than that of trimefhylolpropane (60 ° C) of the comparative example but this value. remains relatively low and attractive for application in lubricants.

CLAIMS

[Claim 1] Esters of at least one sugar polyol e † of at least one linear C6-Cn fatty acid in which the sugar polyol is erythritol.

[Claim 2] Esters according to claim 1, wherein the linear C6-Cn fatty acid is n-heptanoic acid.

[Claim 3] Esters according to claim 1 or 2, wherein the mass ratio of linear C6-Cn fatty acid to sugar polyol is at least 5: 1.

[Claim 4] Esters according to any one of claims 1 to 3, wherein the linear C6-Cn fatty acid is derived from renewable resources.

[Claim 5] Esters according to one of claims 1 to 4, in which the linear C6-Cn fatty acid is derived from castor oil.

[Claim 6] Use of an ester of at least one sugar polyol and of at least one linear C6-Cn fatty acid as defined in one of claims 1 to 5 as a lubricating base.

[Claim 7] Composition of a lubricating base comprising an ester of at least one sugar polyol e † of at least one linear C6-Cn fatty acid as defined in one of claims 1 to 5.

[Claim 8] A process for preparing an ester comprising a step of esterifying at least one sugar polyol in the presence of at least one excess linear C6-Cn fatty acid.

[Claim 9] A method according to claim 8, wherein the method comprises a step of removing excess acids, preferably carried out by vacuum distillation.

[Claim 10] The method according to one of claims 8 to 9, wherein the method is carried out in the absence of at least one of the following steps:

- downstream treatment by adding an additive;

- addition of catalyst;

- addition of organic solvent.

[Claim 1 1] Method according to one of claims 8 to 10, in which the reaction is carried out for a sufficient time to obtain a tetraesters level greater than or equal to 80%, preferably greater than or equal to 93% by mass relative to the total amount of ester.

[Claim 12] A method according to any one of claims 8-1 1, wherein the sugar polyol is erythritol.

[Claim 13] A method according to any one of claims 8 to 12, wherein the linear C6-Cn fatty acid is n-heptanoic acid.

[Claim 14] A method according to any one of claims 8 to 13, wherein the linear C6-Cn fatty acid is derived from renewable resources.

[Claim 15] The method of claim 13, wherein the linear C6-Cn fatty acid is derived from castor oil.

[Claim 16] A method according to any one of claims 8 to 15 wherein the mass ratio of linear C6-Cn fatty acid to sugar polyol is at least 5: 1.

[Claim 17] Esters of at least one sugar polyol and of at least one linear C6-Cn fatty acid obtained by the process according to one of claims 8 to 1 6.