Method For Manufacturing Positive Electrode Active Material For Secondary Battery And Positive Electrode Active Material For Secondary Battery Manufactured According To Same
Method For Manufacturing Positive Electrode Active Material For Secondary Battery And Positive Electrode Active Material For Secondary Battery Manufactured According To Same
Abstract:
The present invention provides a method for manufacturing a positive electrode active material for a secondary battery comprising the steps of: mixing a metal precursor for a positive electrode active material having an average particle diameter ratio of 2000 to 5:1 with a raw material including a doping element by using acoustic resonance to prepare a precursor having been doped by the doping element; and mixing the doped precursor with a lithium raw material and then heat-treating the same so that the secondary battery is uniformly doped by various doping elements without a danger of damage to a surface of the active material and property deterioration thereof. Further the present invention provides a positive electrode active material which is manufactured by the method and thus has an improved structural stability and can enhance a property of a battery to which the method is applied for example can minimize reduction of the capacity of the battery and improve a cycle property thereof.
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Notices, Deadlines & Correspondence
LG Chem Research Park, 188, Munji-ro,
Yuseong-gu,
Daejeon 34122
2. CHO, Seung Beom
LG Chem Research Park, 188, Munji-ro,
Yuseong-gu,
Daejeon 34122
3. SON, San Su
LG Chem Research Park, 188, Munji-ro,
Yuseong-gu,
Daejeon 34122
4. JU, Jin Wook
LG Chem Research Park, 188, Munji-ro,
Yuseong-gu,
Daejeon 34122
5. CHOI, Sang Soon
LG Chem Research Park, 188, Munji-ro,
Yuseong-gu,
Daejeon 34122
6. KIM, Jong Pil
LG Chem Research Park, 188, Munji-ro,
Yuseong-gu,
Daejeon 34122
Specification
[1]Mutual citations and related applications
[2]This application claims the benefit of priority based on the date of July 04, Korea Patent Application No. 10-2016-0084359 and No. 03 dated July 2017 Korea Patent Application No. 10-2017-0084337, 2016, and of the Korea Patent Application everything described in the literature are included as part of the specification.
[3]
[4]
Art
[5]
The present invention relates to a production method and hence the positive electrode active material prepared in accordance with the active material without concern for damage or deterioration in characteristics of the surface, a positive electrode which doping elements are uniformly doped active material can exhibit excellent structural stability.
BACKGROUND
[6]
Lithium secondary batteries since appeared in 1991 as a small, lightweight, high-capacity batteries, widely used as a power source for mobile devices. In recent years, electronic, communication, with the rapid development of computer industry, a camcorder, has been continued to the appearance and remarkable development cell, such as a notebook PC, these portable electronic information day by day increasing demand for lithium secondary batteries as a power source for driving the communication device and.
[7]
The lithium secondary battery has a falling rapidly For this reason, the life as the repeated charge and discharge problems. In particular, this problem is more serious in a high temperature or a high voltage. The reason for this is that decomposition of the electrolyte in the battery due to moisture or other active material is affected or deteriorated, resulting also is the internal resistance of the battery increases phenomenon.
[8]
Accordingly, a lithium secondary battery positive electrode active material that is being used is active research and development is now the layer structure of LiCoO 2 is. LiCoO 2 has a limit doegie but the most widely used, the structural stability is excellent in life characteristics and the charge-and-discharge efficiency of the technology applied to a high capacity battery decreases.
[9]
As a positive electrode active material to replace them, LiNiO 2 , LiMnO 2 , LiMn 2 O 4 , LiFePO 4 , or Li (Ni x CoyMnz) O 2 a variety of lithium-transition metal oxide, such as has been developed. Double, LiNiO 2 for, but the advantage of showing the characteristics of the cell of the high discharge capacity, a simple solid-phase reaction is difficult to synthesize, it has a low thermal stability, and cycle characteristic problem. Further, LiMnO 2 , or LiMn 2 O 4 lithium-manganese-based oxide, such as, but is advantageous in that thermal stability is excellent, a low price, a small capacity, there is a problem of low temperature properties. In particular, LiMn 2 O 4 for a part in merchandising products, but low cost, Mn 3 +Because of the structure deformed (Jahn-Teller distortion) due to the not good life property. In addition, LiFePO 4 is excellent in low price and safety of current hybrid cars (hybrid electric vehicle, HEV), but many studies have been done for, due to the low conductivity applied to other fields is a difficult situation.
[10]
Because of such circumstances, LiCoO 2 materials which under the spotlight recently as a replacement cathode active material is Li (NixCoyMnz) O 2 (In this case, the x, y, z is an atomic fraction of each independent oxide composition element, 0
Documents
Application Documents
#
Name
Date
1
201817027947-STATEMENT OF UNDERTAKING (FORM 3) [25-07-2018(online)].pdf
2018-07-25
2
201817027947-POWER OF AUTHORITY [25-07-2018(online)].pdf
2018-07-25
3
201817027947-FORM 1 [25-07-2018(online)].pdf
2018-07-25
4
201817027947-DRAWINGS [25-07-2018(online)].pdf
2018-07-25
5
201817027947-DECLARATION OF INVENTORSHIP (FORM 5) [25-07-2018(online)].pdf