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Method For Manufacturing Thin Wall Cast Slab

Abstract: In this method for manufacturing a thin wall cast slab, a molten steel is supplied to a molten steel reservoir part formed by a pair of rotatable cooling drums and a pair of side weirs, and a solidified shell is formed and grown on the peripheral surfaces of the cooling drums to manufacture a thin-wall cast slab. The pressing force P of the pair of cooling drums is set so that the pressing force P (kgf/mm), the cast thickness D (mm), and the radius R (m) of the cooling drums satisfy 0.90=P×(D×R)0.5=1.30.

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Patent Information

Application #
Filing Date
20 November 2020
Publication Number
07/2021
Publication Type
INA
Invention Field
METALLURGY
Status
Email
mahua.ray@remfry.com
Parent Application
Patent Number
Legal Status
Grant Date
2023-12-14
Renewal Date

Applicants

NIPPON STEEL CORPORATION
6-1, Marunouchi 2-chome, Chiyoda-ku, Tokyo 1008071

Inventors

1. MIYAZAKI Masafumi
c/o NIPPON STEEL CORPORATION, 6-1, Marunouchi 2-chome, Chiyoda-ku, Tokyo 1008071
2. WAKISAKA Takeaki
c/o NIPPON STEEL CORPORATION, 6-1, Marunouchi 2-chome, Chiyoda-ku, Tokyo 1008071
3. ARAI Takashi
c/o NIPPON STEEL CORPORATION, 6-1, Marunouchi 2-chome, Chiyoda-ku, Tokyo 1008071
4. YOSHIDA Naotsugu
c/o NIPPON STEEL CORPORATION, 6-1, Marunouchi 2-chome, Chiyoda-ku, Tokyo 1008071

Specification

Title of invention: Method for manufacturing thin-walled slabs
Technical field
[0001]
 The present invention relates to a method for producing a thin-walled slab by supplying molten steel to a molten steel reservoir formed by a pair of cooling drums and a pair of side weirs to produce a thin-walled slab.
 The present application claims priority based on Japanese Patent Application No. 2018-111919 filed in Japan on June 12, 2018, the contents of which are incorporated herein by reference.
Background technology
[0002]
 As a device for producing thin-walled metal slabs, a pair of cooling drums having a water-cooled structure inside and rotating in opposite directions are provided, and molten steel is placed in a molten steel reservoir formed by a pair of cooling drums and a pair of side dams. A solidified shell is formed and grown on the peripheral surface of the cooling drum, and the solidified shells formed on the outer peripheral surfaces of the pair of cooling drums are crimped at a drum kiss point to produce a thin-walled slab having a predetermined thickness. A twin drum type continuous casting apparatus is provided. Such a twin drum type continuous casting apparatus is applied to various metals.
[0003]
 In the above-mentioned twin drum type continuous casting apparatus, for example, as shown in Patent Document 1, molten steel is continuously supplied from a tundish arranged above the cooling drum to the molten steel pool via a dipping nozzle and rotates. The molten steel solidifies and grows on the peripheral surface of the cooling drum to form a solidified shell, and the solidified shell formed on the peripheral surface of each cooling drum is crimped at the drum kiss point to produce a thin-walled slab.
[0004]
 By the way, in the thin-walled slab produced by using the above-mentioned twin-drum type continuous casting apparatus, since the molten steel is rapidly cooled at the time of solidification, the solidified structure has columnar crystals extending from the surface layers on both sides to the 1/2 thick portion. Have. Depending on the steel type and casting conditions, equiaxed crystals may be formed in the 1/2 thick part.
 Conventionally, in general, as shown in Patent Document 1, for example, it has been aimed to positively generate equiaxed crystals in order to homogenize the metal structure.
[0005]
 Further, in Patent Document 2, in a method of casting an austenitic stainless steel thin strip-shaped slab by a continuous casting apparatus in which the mold wall moves in synchronization with the slab, Ni negative segregation is performed by controlling the pressing force of the mold wall. A manufacturing method has been proposed in which the occurrence of the above-mentioned is suppressed and the speckled and staggered marbling gloss unevenness observed in the steel sheet after cold rolling and cold working is prevented.
Prior art literature
Patent documents
[0006]
Patent Document 1: Japanese Patent Application Laid-Open No. 02-092438
Patent Document 2: Japanese Patent Application Laid-Open No. 2003-285141
Outline of the invention
Problems to be solved by the invention
[0007]
 By the way, when the solidified shells are crimped to each other with the equiaxed crystal sandwiched between them, the liquid phase trapped between the grains may solidify and shrink, and micropores may be generated. The micropore is a hole having a diameter of about 300 μm to 100 μm, and by serving as a starting point of fracture during processing, it adversely affects mechanical properties such as strength and toughness.
 On the other hand, when the solidified shells made of columnar crystals are crimped to each other, the liquid phase is discharged and the columnar crystals are brought into close contact with each other, so that micropores are not generated. Therefore, from the viewpoint of preventing deterioration of mechanical properties due to micropores, thin-walled slabs having a low equiaxed crystal ratio and a high columnar crystal ratio are desired.
[0008]
 In thin-walled slabs manufactured using a twin-drum continuous casting device, even if an attempt is made to increase the columnar crystal ratio as a whole, the equiaxed crystal formation status is not stable and the equiaxed crystal ratio is locally increased. In some cases, the ratio was 5% or more, and the columnar crystal ratio was less than 95%.
 In the thin-walled slabs that are continuously cast, if defects due to micropores occur, it is necessary to crimp the micropores by further hot rolling the thin-walled slabs as a countermeasure. The increase in the number of processes will significantly reduce the production efficiency. For this reason, a stable thin-walled slab having a high columnar crystal ratio over the entire area has been desired.
[0009]
 The present invention has been made in view of the above-mentioned situation, and provides a method for producing a thin-walled slab capable of stably producing a thin-walled slab having a high columnar crystal ratio over the entire area of ​​the slab. The purpose.
Means to solve problems
[0010]
 In one aspect of the present invention, molten steel is supplied to a molten steel reservoir formed by a pair of rotating cooling drums and a pair of side dams, and a solidified shell is formed and grown on the peripheral surface of the cooling drum to form a thin-walled slab. A method for producing a thin-walled slab to be produced, wherein the pressing force P (kgf / mm) of the pair of cooling drums, the casting thickness D (mm), and the radius R (m) of the cooling drums are 0.90 ≦. The pressing force P of the pair of cooling drums is set so as to satisfy P × (D × R) 0.5 ≦ 1.30.
[0011]
 In the method for producing a thin-walled slab having this configuration, P × (D × R) 0.5 defined by the pressing force P of the cooling drum, the casting thickness D (mm), and the radius R (m) of the cooling drum. Since the value is 1.30 or less, it is possible to suppress the excessively high pressing force P of the drum, and to suppress the generation and growth of equiaxed crystals. Therefore, it is possible to stably produce thin-walled slabs having few equiaxed crystals over the entire area.
 On the other hand, since P × (D × R) 0.5 is 0.90 or more, the solidified shells can be reliably crimped to each other, and thin-walled slabs can be stably produced.
 Further, since the pressing force P of the pair of cooling drums is set in consideration of the casting thickness D (mm) and the radius R (m) of the cooling drums, it is possible to stabilize the actual pressing state.
The invention's effect
[0012]
 As described above, according to the present invention, it is possible to provide a method for producing a thin-walled slab capable of stably producing a thin-walled slab having a high columnar crystal ratio over the entire area of ​​the slab.
A brief description of the drawing
[0013]
FIG. 1 is a schematic explanatory view of a twin-drum type continuous casting apparatus used when carrying out a method for producing a thin-walled slab according to an embodiment of the present invention.
FIG. 2 is an enlarged explanatory view of the twin drum type continuous casting apparatus shown in FIG.
FIG. 3 is a diagram illustrating the relationship between the contact length between a rolling roll and a material to be rolled, the radius of the rolling roll, and the amount of reduction in the plate thickness of the material to be rolled due to rolling in rolling with a rolling roll.
[Fig. 4] Fig. 4 is a graph showing the results of evaluating the casting situation in the examples.
[Fig. 5] Fig. 5 is a graph showing the results of evaluating the columnar crystal ratio in Examples.
Mode for carrying out the invention
[0014]
 As a result of diligent studies by the present inventors in order to solve the above problems, it has been confirmed that there are the following two mechanisms for generating equiaxed crystals in the twin drum type continuous casting apparatus.
(1) The solidified nuclei generated at the contact portion (meniscus) between the molten steel and the drum surface are separated from the drum surface by the molten steel flow to become crystal nuclei, and move below the molten steel pool portion as the drum rotates. Here, when the pressing force of the pair of cooling drums exceeds a certain value, the crystal nuclei stay by crimping and squeezing the solidified shells by pressing the cooling drums, and the crystal nuclei coalesce and grow, which is between the solidified shells. It becomes an equiaxed crystal.
(2) When the solidified shell is crimped by pressing the cooling drum, if the pressing force is excessive, the tip of the solidified shell is broken by the reduction and crystal nuclei are generated. Then, the crystal nuclei stay by crimping and squeezing the solidified shell by pressing the cooling drum, and the crystal nuclei coalesce and grow, which are caught between the solidified shells and become equiaxed crystals.
[0015]
 As described above, in the equiaxed crystal generation mechanism, the factors that promote the formation and growth of equiaxed crystals are all excessive crimping of the solidified shell by pressing the cooling drum, and the pressing condition of the cooling drum is optimized. By doing so, it was found that the generation and growth of equiaxed crystals can be suppressed.
 Here, when the outer diameter (drum diameter) of the cooling drum is large, the crimping of the solidification shell becomes closer to flat plate compression, and the drawing and breaking due to the crimping become more excessive. Therefore, when the drum diameter is large, it is necessary to keep the pressing force of the drum low.
 Further, when the solidification shell thickness corresponding to the casting thickness is thick, the peripheral speed of the cooling drum becomes slower, and a large number of free crystal nuclei are generated. In addition, the temperature gradient at the interface between the solidified shell and the molten steel becomes smaller, and the fragile portion at the tip of the solidified shell becomes thicker, resulting in excessive breakage due to pressing. Therefore, when the solidification shell thickness (that is, the casting thickness) is thick, it is necessary to keep the pressing force of the drum low.
[0016]
 A method for producing a thin-walled slab according to an embodiment of the present invention based on the above findings will be described with reference to the attached drawings. The present invention is not limited to the following embodiments.
 The thin-walled slab 1 produced in the present embodiment may be used for an automobile steel plate, a corrosion / weathering steel plate, a welded pipe, a grain-oriented electrical steel sheet, a non-oriented electrical steel sheet, or the like.
 Further, in the present embodiment, the width of the thin-walled slab 1 to be manufactured is within the range of 300 mm or more and 2000 mm or less, and the thickness is within the range of 1 mm or more and 5 mm or less.
[0017]
 As shown in FIG. 1, the twin-drum type continuous casting apparatus 10 in the present embodiment has a pair of cooling drums 11 and 11, bender rolls 12 and 12 for bending the thin-walled slab 1, and a pinch for supporting the thin-walled slab 1. The molten steel reservoir 16 defined by the rolls 13 and 13, the side dams 15 arranged at the widthwise ends of the pair of cooling drums 11 and 11, and the pair of cooling drums 11 and 11 and the side dams 15. A tundish 17 for holding the molten steel 3 supplied to the machine and a dipping nozzle 18 for supplying the molten steel 3 from the tundish 17 to the molten steel reservoir 16 are provided.
[0018]
 FIG. 2 shows an enlarged explanatory view of the periphery of the molten steel reservoir 16 in FIG. In the twin drum type continuous casting apparatus 10 of the present embodiment, as shown in FIG. 2, a chamber 20 is arranged above the molten steel reservoir 16 and the cooling drums 11 and 11.
[0019]
 Next, a method for producing a thin-walled slab according to the present embodiment using the twin-drum type continuous casting apparatus 10 described above will be described.
[0020]
 The molten steel 3 is supplied from the tundish 17 to the molten steel reservoir 16 formed by the pair of cooling drums 11 and 11 and the side weir 15 via the immersion nozzle 18, and the pair of cooling drums 11 and 11 are moved in the rotation direction F. The cooling drums 11 and 11 are rotated so that the regions where the pair of cooling drums 11 and 11 are close to each other are directed toward the drawing direction (downward in FIG. 1) of the thin-walled slab 1.
[0021]
 Then, the solidification shell 5 is formed on the peripheral surface of the cooling drum 11. Then, the solidification shell 5 grows on the peripheral surface of the cooling drum 11, and the solidification shells 5 and 5 formed on the pair of cooling drums 11 and 11 are crimped to each other at the drum kiss point KP to obtain a predetermined thickness. The thin-walled slab 1 is cast.
[0022]
 Then, in the present embodiment, the pressing force P (kgf / mm) at the drum kiss point KP between the pair of cooling drums 11 and 11 is used with the casting thickness D (mm) and the radius R (m) of the cooling drum 11. Therefore, it is stipulated as shown below.
 0.90 ≤ P x (D x R) 0.5 ≤ 1.30
[0023]
 Here, as described above, the reason why the pressing force P between the pair of cooling drums 11 and 11 is defined will be described.
 Generally, in the rolling theory, in the case of rolling with a rolling roll, as shown in FIG. 3, the relationship between the contact length L between the roll and the rolled material, the rolling roll radius R, and the amount of decrease in plate thickness due to rolling Δh is ,
 L = (Δh × R) 0.5
.
[0024]
 Here, as (Δh × R) 0.5 increases, the contact length L increases and the rolling efficiency increases even when pressed with the same rolling force. Therefore, in order to keep the rolling state constant, (Δh × R) It is necessary to reduce the pressing force according to the increase of 0.5 .
 In the twin drum type continuous casting apparatus 10 of the present embodiment, the amount of decrease Δh in the plate thickness due to rolling is substantially proportional to the casting thickness D. Further, the radius R of the rolling roll corresponds to the radius R of the cooling drum 11. Therefore, in the twin-drum type continuous casting apparatus 10 of the present embodiment, the indexes indicating the degree of crimping of the solidified shell 5 and the degree of breakage of the solidified shell 5 leading to the formation of equiaxed crystals are the pressing force P and (D). × R) The product of 0.5 P × (D × R) is represented by 0.5 . Then, in order to stably suppress the generation and growth of equiaxed crystals over the entire area and to securely crimp the solidified shells 5 and 5 to each other, the above-mentioned appropriate range of P × (D × R) 0.5 is set. Stipulated.
[0025]
 Here, if P × (D × R) 0.5 exceeds 1.30, the cooling drums 11 and 11 are pressed excessively against each other, and the tip of the solidification shell 5 is broken. Further, the crystal nuclei floating in the molten steel pool 16 stay by crimping and squeezing the solidified shell 5 by pressing the cooling drum 11, and the crystal nuclei coalesce and grow, which is caught between the solidified shells 5 and 5. There is a risk that equiaxed crystals will be generated and grow.
 That is, by controlling the pressing force P using (D × R) 0.5 , which is the root of the product of the drum radius R (mm) and the casting thickness D (mm), as an index, the solidification shell 5 at the drum kiss point KP, The way the force is transmitted to 5 can be made appropriate, and the generation and growth of equiaxed crystals can be suppressed.
 On the other hand, if P × (D × R) 0.5 is less than 0.90, the solidified shells 5 and 5 may not be sufficiently crimped to each other.
 From the above, in the present embodiment, P × (D × R) 0.5 is set within the range of 0.90 or more and 1.30 or less.
 In order to further suppress the generation and growth of equiaxed crystals, it is preferable that the upper limit of P × (D × R) 0.5 is 1.1 or less.
[0026]
 In the thin-walled slab 1 manufactured by the method for producing a thin-walled slab according to the present embodiment having such a configuration, every 10 rotations of the cooling drum 11 (for example, the radius R of the cooling drum 11) covers the entire area of ​​the thin-walled slab 1. When the total width of the thin-walled slab 1 is sampled at 18.8 m pitch) and the metal structure of the entire cross section in the width direction excluding 20 mm at both ends, which is the trim allowance, is observed, the thin-walled slab is cast. The minimum value of the ratio of the columnar crystal thickness to the thickness of the piece 1 is said to exceed 95%.
[0027]
 In the method for producing a thin-walled slab according to the present embodiment having the above configuration, it is defined by the pressing force P of the cooling drum 11, the casting thickness D (mm), and the radius R (m) of the cooling drum 11. Since P × (D × R) 0.5 is 1.30 or less, it is suppressed that the pressing force P of the cooling drum 11 becomes excessively high, and the generation and growth of equiaxed crystals are suppressed. Can be done. On the other hand, since P × (D × R) 0.5 is 0.90 or more, the solidified shells 5 and 5 can be reliably crimped to each other.
 Further, since the pressing force P of the pair of cooling drums 11 and 11 is set in consideration of the casting thickness D (mm) and the radius R (m) of the cooling drum 11, the actual pressing condition can be stabilized. It will be possible.
 Therefore, the thin-walled slab 1 having few equiaxed crystals can be stably produced over the entire area of ​​the thin-walled slab 1.
[0028]
 Further, as described above, in the thin-walled slab 1 produced by the thin-walled slab manufacturing method of the present embodiment, the minimum value of the ratio of the columnar crystal thickness to the thickness of the thin-walled slab 1 is set to exceed 95%. Therefore, it is possible to prevent deterioration of mechanical properties due to micropores.
[0029]
 Although the method for producing the thin-walled slab 1 according to the embodiment of the present invention has been specifically described above, the present invention is not limited to this, and can be appropriately changed without departing from the technical idea of ​​the present invention. Is.
 For example, in the present embodiment, as shown in FIG. 1, a twin-drum type continuous casting apparatus in which a bender roll and a pinch roll are arranged has been described as an example, but the arrangement of these rolls and the like is not limited and is appropriate. The design may be changed.
[0030]
(Example) The
 results of experiments carried out in order to confirm the effects of the present invention will be described below.
[0031]
Using
 the twin drum type continuous casting apparatus described in the embodiment, C; 0.02 mass%, Si; 3.5 mass%, Al; 0.6 mass%, Mn; 0.2 mass% are contained. A thin-walled slab made of steel was cast under the conditions shown in Table 1. The drum width was 400 mm.
[0032]
 First, the casting situation was visually evaluated. The evaluation results are shown in Table 1 and FIG.
 Then, the columnar crystal ratio of the obtained thin-walled slab was measured. The entire width of the thin-walled slab is sampled every 10 rotations of the cooling drum (for example, when the radius R of the cooling drum is 0.3 m, the pitch is 18.8 m) over the entire area of ​​the thin-walled slab. The metallographic structure of the entire cross section in the width direction except 20 mm was observed, and the minimum value of the ratio of the columnar crystal thickness to the plate thickness was taken as the columnar crystal ratio in the casting. The evaluation results are shown in Table 1 and FIG.
[0033]
 In addition, Table 1 shows the average size and number density of micropores. A full-width sample was taken from the thin-walled slab with a length equivalent to one rotation of the cooling drum, and an X-ray transmission photograph was taken from the plate surface direction of the thin-walled slab. Then, two-dimensional image processing was performed on the micropores observed as white spots, and the average size (μm) and the number density (pieces / m 2 ) of the micropores were measured.
[0034]
[table 1]

[0035]
 In Comparative Examples 1 to 4, the value of P × (D × R) 0.5 was smaller than 0.90, and the end of the slab was missing or bulging fracture occurred, resulting in a thin-walled slab. Could not be obtained. It is presumed that the solidified shell could not be sufficiently crimped.
 In Comparative Examples 5 to 9, the value of P × (D × R) 0.5 was larger than 1.30, the generation and growth of equiaxed crystals could not be sufficiently suppressed, and the columnar crystal ratio was low. became. In addition, a large number of micropores were generated.
[0036]
 On the other hand, in Examples 1 to 8 of the present invention in which P × (D × R) 0.5 is an appropriate range, stable casting is possible and the columnar crystal ratio is high over the entire area of ​​the slab. As a result, it was confirmed that micropores could be prevented.
[0037]
 From the above, it was confirmed that according to the example of the present invention, a thin-walled slab having a high columnar crystal ratio can be stably produced over the entire area of ​​the slab.
Industrial applicability
[0038]
 According to the present invention, it is possible to provide a method for producing a thin-walled slab capable of stably producing a thin-walled slab having a high columnar crystallinity over the entire area of ​​the slab.
Description of the sign
[0039]
1 Thin-walled slab
3 Molten steel
5 Solidification shell
11 Cooling drum
The scope of the claims
[Claim 1]
 Manufacture of thin-walled slabs by supplying molten steel to a molten steel reservoir formed by a pair of rotating cooling drums and a pair of side dams, and forming and growing a solidified shell on the peripheral surface of the cooling drum to produce thin-walled slabs. In the method,
 the pressing force P (kgf / mm) of the pair of the cooling drums, the casting thickness D (mm), and the radius R (m) of the cooling drums are
  0.90 ≦ P × (D × R). A
method for producing a thin-walled slab, which comprises setting a pressing force P of the pair of cooling drums so as to satisfy 0.5 ≤ 1.30 .

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Section Controller Decision Date

Application Documents

# Name Date
1 202017050515-IntimationOfGrant14-12-2023.pdf 2023-12-14
1 202017050515-TRANSLATIOIN OF PRIOIRTY DOCUMENTS ETC. [20-11-2020(online)].pdf 2020-11-20
2 202017050515-PatentCertificate14-12-2023.pdf 2023-12-14
2 202017050515-STATEMENT OF UNDERTAKING (FORM 3) [20-11-2020(online)].pdf 2020-11-20
3 202017050515-Written submissions and relevant documents [07-12-2023(online)].pdf 2023-12-07
3 202017050515-REQUEST FOR EXAMINATION (FORM-18) [20-11-2020(online)].pdf 2020-11-20
4 202017050515-PROOF OF RIGHT [20-11-2020(online)].pdf 2020-11-20
4 202017050515-Correspondence to notify the Controller [21-11-2023(online)].pdf 2023-11-21
5 202017050515-PRIORITY DOCUMENTS [20-11-2020(online)].pdf 2020-11-20
5 202017050515-FORM-26 [21-11-2023(online)].pdf 2023-11-21
6 202017050515-US(14)-HearingNotice-(HearingDate-24-11-2023).pdf 2023-11-13
6 202017050515-POWER OF AUTHORITY [20-11-2020(online)].pdf 2020-11-20
7 202017050515-FORM 18 [20-11-2020(online)].pdf 2020-11-20
7 202017050515-ABSTRACT [09-06-2022(online)].pdf 2022-06-09
8 202017050515-FORM 1 [20-11-2020(online)].pdf 2020-11-20
8 202017050515-CLAIMS [09-06-2022(online)].pdf 2022-06-09
9 202017050515-CORRESPONDENCE [09-06-2022(online)].pdf 2022-06-09
9 202017050515-DRAWINGS [20-11-2020(online)].pdf 2020-11-20
10 202017050515-DECLARATION OF INVENTORSHIP (FORM 5) [20-11-2020(online)].pdf 2020-11-20
10 202017050515-FER_SER_REPLY [09-06-2022(online)].pdf 2022-06-09
11 202017050515-COMPLETE SPECIFICATION [20-11-2020(online)].pdf 2020-11-20
11 202017050515-OTHERS [09-06-2022(online)].pdf 2022-06-09
12 202017050515-FER.pdf 2021-12-21
12 202017050515-Verified English translation [17-02-2021(online)].pdf 2021-02-17
13 202017050515-FORM 3 [18-03-2021(online)].pdf 2021-03-18
13 202017050515.pdf 2021-10-19
14 202017050515-FORM 3 [18-03-2021(online)].pdf 2021-03-18
14 202017050515.pdf 2021-10-19
15 202017050515-FER.pdf 2021-12-21
15 202017050515-Verified English translation [17-02-2021(online)].pdf 2021-02-17
16 202017050515-COMPLETE SPECIFICATION [20-11-2020(online)].pdf 2020-11-20
16 202017050515-OTHERS [09-06-2022(online)].pdf 2022-06-09
17 202017050515-FER_SER_REPLY [09-06-2022(online)].pdf 2022-06-09
17 202017050515-DECLARATION OF INVENTORSHIP (FORM 5) [20-11-2020(online)].pdf 2020-11-20
18 202017050515-CORRESPONDENCE [09-06-2022(online)].pdf 2022-06-09
18 202017050515-DRAWINGS [20-11-2020(online)].pdf 2020-11-20
19 202017050515-CLAIMS [09-06-2022(online)].pdf 2022-06-09
19 202017050515-FORM 1 [20-11-2020(online)].pdf 2020-11-20
20 202017050515-ABSTRACT [09-06-2022(online)].pdf 2022-06-09
20 202017050515-FORM 18 [20-11-2020(online)].pdf 2020-11-20
21 202017050515-POWER OF AUTHORITY [20-11-2020(online)].pdf 2020-11-20
21 202017050515-US(14)-HearingNotice-(HearingDate-24-11-2023).pdf 2023-11-13
22 202017050515-FORM-26 [21-11-2023(online)].pdf 2023-11-21
22 202017050515-PRIORITY DOCUMENTS [20-11-2020(online)].pdf 2020-11-20
23 202017050515-Correspondence to notify the Controller [21-11-2023(online)].pdf 2023-11-21
23 202017050515-PROOF OF RIGHT [20-11-2020(online)].pdf 2020-11-20
24 202017050515-REQUEST FOR EXAMINATION (FORM-18) [20-11-2020(online)].pdf 2020-11-20
24 202017050515-Written submissions and relevant documents [07-12-2023(online)].pdf 2023-12-07
25 202017050515-STATEMENT OF UNDERTAKING (FORM 3) [20-11-2020(online)].pdf 2020-11-20
25 202017050515-PatentCertificate14-12-2023.pdf 2023-12-14
26 202017050515-TRANSLATIOIN OF PRIOIRTY DOCUMENTS ETC. [20-11-2020(online)].pdf 2020-11-20
26 202017050515-IntimationOfGrant14-12-2023.pdf 2023-12-14

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