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Method For Producing Nitrile

Abstract: The present invention is a method for producing a nitrile from a primary amide, which is characterized by subjecting the primary amide to a dehydration reaction in a supercritical fluid in the presence of an acid catalyst. The present invention solves the problem of suppressing corrosion of a reaction apparatus and thermal decomposition of starting materials, while achieving the effect of improving the reaction rate and nitrile selectivity.

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Notices, Deadlines & Correspondence

Patent Information

Application #
Filing Date
25 August 2020
Publication Number
36/2020
Publication Type
INA
Invention Field
CHEMICAL
Status
Email
patent@depenning.com
Parent Application

Applicants

TORAY INDUSTRIES, INC.
1-1, Nihonbashi-Muromachi 2-chome, Chuo-ku, Tokyo 1038666

Inventors

1. TSUKAMOTO, Daijiro
c/o Basic Research Center, Toray Industries, Inc., 10-1, Tebiro 6-chome, Kamakura-shi, Kanagawa 2488555
2. KAWAMURA, Kenji
c/o Basic Research Center, Toray Industries, Inc., 10-1, Tebiro 6-chome, Kamakura-shi, Kanagawa 2488555
3. YAMADA, Katsushige
c/o Basic Research Center, Toray Industries, Inc., 10-1, Tebiro 6-chome, Kamakura-shi, Kanagawa 2488555
4. AKAHIRA, Masato
c/o Nagoya Plant, Toray Industries, Inc., 9-1, Oe-cho, Minato-ku, Nagoya-shi, Aichi 4558502
5. YAMAMOTO, Daisuke
c/o Nagoya Plant, Toray Industries, Inc., 9-1, Oe-cho, Minato-ku, Nagoya-shi, Aichi 4558502

Specification

1. A method of producing a nitrile, the method comprising subjecting a primary
amide to a dehydration reaction in a supercritical fluid in the presence of an acid
5 catalyst.
2. The method according to claim 1, wherein said primary amide is a primary
amide comprising one or two primary amide groups.
10 3. The method according to claim 1 or 2, wherein said primary amide is a
saturated alkylamide, an unsaturated alkylamide, or an amide comprising an aromatic ring and/or a heterocyclic ring.
4. The method according to any one of claims 1 to 3, wherein said acid catalyst
15 is a solid acid catalyst.
5. The method according to any one of claims 1 to 4, wherein said supercritical
fluid is a supercritical fluid of one or more substances selected from the group
consisting of carbon dioxide, an alcohol compound, an ether compound and a
2 0 hydrocarbon compound.
6. The method according to any one of claims 1 to 5, wherein said supercritical
fluid is a supercritical fluid of one or more substances selected from the group
consisting of carbon dioxide, methanol, ethanol, 1-propanol, 2-propanol, 1-butanol,
2 5 2-butanol, isobutanol, tert-butanol, tert-amyl alcohol, diethyl ether, methyl-tert-butyl ether, diisopropyl ether, 1,2-dimethoxyethane, tetrahydrofuran, pentane, hexane and benzene.

Documents

Application Documents

# Name Date
1 202047036482-Correspondence Form-1 And POA_27-10-2021.pdf 2021-10-27
1 202047036482-STATEMENT OF UNDERTAKING (FORM 3) [25-08-2020(online)].pdf 2020-08-25
2 202047036482.pdf 2021-10-18
2 202047036482-PROOF OF RIGHT [25-08-2020(online)].pdf 2020-08-25
3 202047036482-PRIORITY DOCUMENTS [25-08-2020(online)].pdf 2020-08-25
3 202047036482-FORM 3 [13-10-2020(online)].pdf 2020-10-13
4 202047036482-FORM-26 [06-09-2020(online)].pdf 2020-09-06
4 202047036482-FORM 1 [25-08-2020(online)].pdf 2020-08-25
5 202047036482-DECLARATION OF INVENTORSHIP (FORM 5) [25-08-2020(online)].pdf 2020-08-25
5 202047036482-AMMENDED DOCUMENTS [02-09-2020(online)].pdf 2020-09-02
6 202047036482-COMPLETE SPECIFICATION [25-08-2020(online)].pdf 2020-08-25
6 202047036482-Annexure [02-09-2020(online)].pdf 2020-09-02
7 202047036482-RELEVANT DOCUMENTS [02-09-2020(online)].pdf 2020-09-02
7 202047036482-FORM 13 [02-09-2020(online)].pdf 2020-09-02
8 202047036482-MARKED COPIES OF AMENDEMENTS [02-09-2020(online)].pdf 2020-09-02
9 202047036482-RELEVANT DOCUMENTS [02-09-2020(online)].pdf 2020-09-02
9 202047036482-FORM 13 [02-09-2020(online)].pdf 2020-09-02
10 202047036482-Annexure [02-09-2020(online)].pdf 2020-09-02
10 202047036482-COMPLETE SPECIFICATION [25-08-2020(online)].pdf 2020-08-25
11 202047036482-DECLARATION OF INVENTORSHIP (FORM 5) [25-08-2020(online)].pdf 2020-08-25
11 202047036482-AMMENDED DOCUMENTS [02-09-2020(online)].pdf 2020-09-02
12 202047036482-FORM-26 [06-09-2020(online)].pdf 2020-09-06
12 202047036482-FORM 1 [25-08-2020(online)].pdf 2020-08-25
13 202047036482-PRIORITY DOCUMENTS [25-08-2020(online)].pdf 2020-08-25
13 202047036482-FORM 3 [13-10-2020(online)].pdf 2020-10-13
14 202047036482.pdf 2021-10-18
14 202047036482-PROOF OF RIGHT [25-08-2020(online)].pdf 2020-08-25
15 202047036482-STATEMENT OF UNDERTAKING (FORM 3) [25-08-2020(online)].pdf 2020-08-25
15 202047036482-Correspondence Form-1 And POA_27-10-2021.pdf 2021-10-27