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"Method For Producing Norbornene Derivative"
Abstract: A method for producing a norbornene derivative, comprising: a first step of forming a Mannich base by reacting a carbonyl compound and an amine compound with each other in an acidic solvent, to thereby obtain a reaction liquid comprising the Mannich base in the acidic solvent, the acidic solvent comprising a formaldehyde derivative and 0.01 mol/L or more of an acid represented by the formula: HX (In the formula, X represents F or the like), the carbonyl compound being represented by any of the following general formulae (1) to (3) : [Chem. 1] [in formulae (1) to (3), R1, R2, R3, R4, R5, and R6 each independently represent a hydrogen atom or the like, and n represents an integer of any of 0 to 4], the amine compound being represented by the following general formula (4): [Chem. 2] [in the formula (4) , R7s each independently represent a linear chain saturated hydrocarbon group having 1 to 20 carbon atoms or the like, and X" represents F" or the like] , the Mannich base being represented by any of the following general formulae (5) to (7): [Chem. 3] [R1, R2, R3, R4, R5, R6, and n in the formulae (5) to (7) have the same meanings as those of R1, R2, R3, R4, R5, R6, and n in the formulae (1) to (3 ) , and R7 and X-in the formulae (5) to (7) have the same meanings as those of R7 and X- in the formula (4)] ; and a second step of reacting the Mannich base and a diene compound with each other by adding an organic solvent, a base in an amount of 1.0 to 20.0 equivalents to the acid, and the diene compound to the reaction liquid, and then heating the reaction liquid, to thereby form a norbornene derivative, the diene compound being represented by the following general formula (8): [Chem. 4] [in the formula (8) , R8 represents a hydrogen atom or the like], the norbornene derivative being represented by any of the following general formulae (9) to (11) : [Chem. 5] [R1, R2, R3, R4, R5, R6, and n in the formulae (9) to (11) have the same meanings as those of R1, R2, R3, R4, R5, R6 and n in the formulae (1) to (3) , and R8 in the formulae (9) to (11) has the same meaning as that of R8 in the formula (8)] .
Notices, Deadlines & Correspondence
Patent Information
Applicants
JX NIPPON OIL & ENERGY CORPORATION
Inventors
1. SHINICHI KOMATSU
2. HISASHI SONE
3. TAKESHI KOIKE
4. SAYAKO KAWAHAMA
Specification
NA
Documents
Application Documents
| # | Name | Date |
|---|---|---|
| 1 | 10102-delnp-2011-PCT-Documents-(21-12-2011).pdf | 2011-12-21 |
| 2 | 10102-delnp-2011-GPA.pdf | 2012-07-12 |
| 3 | 10102-delnp-2011-Form-5.pdf | 2012-07-12 |
| 4 | 10102-delnp-2011-Form-3.pdf | 2012-07-12 |
| 5 | 10102-delnp-2011-Form-2.pdf | 2012-07-12 |
| 6 | 10102-delnp-2011-Form-18.pdf | 2012-07-12 |
| 7 | 10102-delnp-2011-Form-1.pdf | 2012-07-12 |
| 8 | 10102-delnp-2011-Drawings.pdf | 2012-07-12 |
| 9 | 10102-delnp-2011-Description (Complete).pdf | 2012-07-12 |
| 10 | 10102-delnp-2011-Correspondence Others.pdf | 2012-07-12 |
| 11 | 10102-delnp-2011-Claims.pdf | 2012-07-12 |
| 12 | 10102-delnp-2011-Abstract.pdf | 2012-07-12 |
| 13 | 10102-delnp-2011-Form-3-(16-07-2012).pdf | 2012-07-16 |
| 14 | 10102-delnp-2011-Correspondence-Others-(16-07-2012).pdf | 2012-07-16 |
| 15 | 10102-delnp-2011-Form-5.pdf | 2012-07-12 |
| 15 | 10102-delnp-2011-Correspondence-Others-(08-08-2012).pdf | 2012-08-08 |
| 16 | 10102-delnp-2011-GPA.pdf | 2012-07-12 |
| 16 | 10102-delnp-2011-Correspondence Others-(23-09-2013).pdf | 2013-09-23 |
| 17 | 10102-delnp-2011-PCT-Documents-(21-12-2011).pdf | 2011-12-21 |
| 17 | 10102-DELNP-2011_EXAMREPORT.pdf | 2016-06-30 |