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Method Of Regenerating Exhaust Gas Treatment Catalyst

Abstract: Provided is a method of regenerating an exhaust gas treatment catalyst 11 having ash adhered to a surface thereof. The method includes a crushing step SI in which the exhaust gas treatment catalyst 11 is crushed such that 70 to 95 wt% of the whole exhaust gas treatment catalyst 11 becomes coarse pieces 12 having a size exceeding a threshold size S (any value in a range of 0.105 to 1.0 mm); a separating step S2 in which the fragments obtained by crushing the exhaust gas treatment catalyst 11 are separated into the coarse pieces 12 having a size exceeding threshold size S and fine particles 13 having a size not larger than the threshold size S; a pulverizing step S3 in which the coarse pieces 12 thus separated are pulverized to a fine powder having an average particle diameter of not larger than 0.1 mm; a kneading step S4 and a molding step S5 in which the fine powder is kneaded with other raw materials and molded into an exhaust gas treatment catalyst; and a drying step S6 and a calcining step S7 in which the molded precursor is dried and calcined to thus obtain a regenerated exhaust gas treatment catalyst 14.

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Notices, Deadlines & Correspondence

Patent Information

Application #
Filing Date
25 May 2010
Publication Number
39/2010
Publication Type
INA
Invention Field
CHEMICAL
Status
Email
Parent Application
Patent Number
Legal Status
Grant Date
2013-10-23
Renewal Date

Applicants

MITSUBISHI HEAVY INDUSTRIES, LTD.
16-5, KONAN 2-CHOME, MINATO-KU, TOKYO 1088215, JAPAN

Inventors

1. OBAYASHI, YOSHIAKI
C/O HIROSHIMA RESEARCH & DEVELOPMENT CENTER, MITSUBISHI HEAVY INDUSTRIES, LTD. 6-22 KAN-ON-SHIN-MACHI 4-CHOME, NISHI-KU, HIROSHIMA-SHI, HIROSHIMA 7338553, JAPAN
2. KIYOSAWA, MASASHI
C/O NAGASAKI SHIPYARD & MACHINERY WORKS, MITSUBISHI HEAVY INDUSTRIES, LTD., 1-1, AKUNOURA-MACHI, NAGASAKI-SHI, NAGASAKI 8508610, JAPAN

Specification

FORM 2 THE PATENT ACT 197 0 (39 of 1970) The Patents Rules, 2003 COMPLETE SPECIFICATION {See Section 10, and rule 13) 1. TITLE OF INVENTION METHOD OF REGENERATING EXHAUST GAS TREATMENT CATALYST AND EXHAUST GAS TREATMENT CATALYST OBTAINED BY THE METHOD 2. APPLICANT(S) a) Name : MITSUBISHI HEAVY INDUSTRIES, LTD. b) Nationality : JAPANESE Company c) Address : 16-5, KONAN 2-CHOME, MINATO-KU, TOKYO 1088215, JAPAN 3. PREAMBLE TO THE DESCRIPTION The following specification particularly describes the invention and the manner in which it is to be performed: - TECHNICAL FIELD The present invention relates to a method of regenerating an exhaust gas treatment catalyst having ash adhered to a surface thereof, and an exhaust gas treatment catalyst obtained by the method. The present invention is extremely effective particularly when employed to regenerate a catalyst for treating exhaust gas from burned coal and removing nitrogen oxide in the exhaust gas. BACKGROUND ART A discharge line for exhaust gas from equipment, for example, a coal-fired boiler or the like, in which coal is burnt is provided with an exhaust gas treatment catalyst to treat nitrogen oxide (NOx) in the exhaust gas. Such an exhaust gas treatment catalyst is obtained by the following process: catalyst components made of metal oxides such as titanium oxide (TiCh), tungsten oxide (WO3), and vanadium oxide (V2O5) are kneaded together with a binder, molded into a honeycomb shape so as to have multiple holes, and calcined. A reducing agent such as ammonia (NH3) is flowed into the holes together with the exhaust gas to bring the nitrogen oxide in the exhaust gas and the reducing agent into contact with the wall surfaces of the holes. This enables the decomposition and removal of the nitrogen oxide. While such an exhaust gas treatment catalyst is being used, ash (fly ash) generated by burning coal is continuously flowed into the holes together with exhaust gas. Thus, components such as calcium (Ca) in the fly ash are gradually adhered (to a thickness of several tens um) on the inner wall surfaces of the holes. Such components inhibit the contact reaction between the nitrogen oxide and the reducing agent on the catalyst surface. Additionally, the fly ash itself is partially deposited inside the holes, and gradually makes it hard for exhaust gas to flow into the holes. Eventually, the fly ash completely blocks and clogs the holes, accordingly lowering the dcnitration performance. Against this background, the following proposals have been made for the exhaust gas treatment catalyst used for a predetermined period. For example, such a catalyst is pulverized, molded again, and calcined. Thereby/ the aforementioned components in the fly ash that are adhered (to a thickness of several tens um) on the inner wall surfaces of the holes and the fly ash that is deposited inside the holes are incorporated into the wall surfaces. Moreover, with such a process, fresh surfaces are exposed on the wall surfaces, enabling the reuse of the catalyst (see, for example, Patent Document 1 below and other documents). Meanwhile, after the pulverization, a portion (50 wt% or less) of the catalyst is mixed with a fresh material thereof, molded, and calcined. Thereby, the amounts of the components and the fly ash incorporated into the wall surfaces are reduced, enabling the reuse of the catalyst (see, for example, Patent Document 2 below and other documents). Patent Document 1: JP-A Sho 60-038037 Patent Document 2: JP-A 2001-340764 DISCLOSURE OF THE INVENTION PROBLEMS TO BE SOLVED BY THE INVENTION However, such regeneration methods proposed in Patent Documents 1 and 2 and other documents as described above have the following problems. (1) Since the fly ash and so forth are mixed in the regenerated exhaust gas treatment catalyst, the amounts of the catalyst components per unit volume are reduced. This lowers the denitration performance per unit volume. Particularly, when fly ash is deposited to such an extent that the fly ash blocks and clogs the holes of the catalyst, the catalyst cannot be regenerated to have a sufficient denitration performance by the regeneration method as described above. (2) Alkali metal components such as a sodium (Na) component and a potassium (K) component and alkaline earth metal components such as a magnesium (Mg) component and a calcium (Ca) component contained in the fly ash poison the catalyst components. Accordingly, the denization performance is lowered, (3) An iron (Fe) component contained in the fly ash oxidizes sulfur dioxide (S02) contained in exhaust gas, generating sulfur trioxide (SO3). When sulfur trioxide (SO3) comes into contact with water (H2O) in the exhaust gas, sulfuric acid (H2SO4) is generated. This makes it likely for the exhaust gas line to corrode. The present invention has been made in view of the above-described problems. An object of the present invention is to provide a method of regenerating an exhaust gas treatment catalyst, the method being capable of suppressing the lowering of the exhaust-gas treating performance and the oxidation of sulfur dioxide; and an exhaust gas treatment catalyst obtained, by the method. MEANS FOR SOLVING THE PROBLEMS To solve the above-described problems, a method of regenerating an exhaust gas treatment catalyst according to a first invention provides a method of regenerating an exhaust gas treatment catalyst having ash adhered to a surface thereof, the method characterized by comprising; a crushing step of crushing the exhaust gas treatment catalyst that has been used; a separating step of separating the crushed exhaust gas treatment catalyst into coarse pieces having a size exceeding a threshold size S and fine particles having a size not larger than the threshold size S; a pulverizing step of pulverizing the separated coarse pieces into a fine powder; a molding step of molding the pulverized fine powder as a raw material into an exhaust gas treatment catalyst; and a calcining step of calcining a molded precursor of the exhaust gas treatment catalyst, the method characterized in that the threshold size S has a value not smaller than 0.105 mm. A method of regenerating an exhaust gas treatment catalyst according to a second invention provides the method of regenerating an exhaust gas treatment catalyst according to the first invention, characterized in that the crushing step is a step in which the exhaust gas treatment catalyst that has been used is crushed such that 70 to 95 wt% of the whole exhaust gas treatment catalyst that has been used becomes the coarse pieces having a size exceeding the threshold size $. A method of regenerating an exhaust gas treatment catalyst according to a third invention provides the method of regenerating an exhaust gas treatment catalyst according to the second invention, characterized in that the threshold size S has a value not larger than 1.0 mm. A method of regenerating an exhaust gas treatment catalyst according to a fourth invention provides the method of regenerating an exhaust gas treatment catalyst according to any one of the first to third inventions, characterized in that the pulverizing step is a step in which the coarse pieces is pulverized such that the fine powder has an average particle diameter not larger than 0.1 mm. A method of regenerating an exhaust gas treatment catalyst according to a fifth invention provides the method of regenerating an exhaust gas treatment catalyst according to any one of the first to fourth inventions, characterized in that the exhaust gas treatment catalyst is used to treat exhaust gas from a burned coal. A method of regenerating an exhaust gas treatment catalyst according to a sixth invention provides the method of regenerating an exhaust gas treatment catalyst according to the fifth invention, characterized in that the exhaust gas treatment catalyst is used to treat nitrogen oxide in the exhaust gas. An exhaust gas treatment catalyst according to a seventh invention provides an exhaust gas treatment catalyst characterized by being regenerated by the method of regenerating an exhaust gas treatment catalyst according to any one of the first to sixth inventions. EFFECTS OF THE INVENTION In the crushing step of the method of regenerating an exhaust gas treatment catalyst according to the present invention, a large portion of the exhaust gas treatment catalyst itself becomes coarse pieces having a size exceeding the threshold size S. Meanwhile, most of ash adhered to and deposited on the surface of the catalyst becomes fine particles having a size not larger than the threshold size S by impact in the crushing. Accordingly, when the coarse pieces having a size exceeding the threshold size S are separated from the fine particles having a size not larger than the threshold size S in the separating step, most of the ash can be easily removed from the exhaust gas treatment catalyst itself. For this reason, ash is hardly included in the exhaust gas treatment catalyst according to the present invention which is regenerated by molding and calcining by use of a fine powder obtained in the pulverizing step in which the coarse pieces are pulverized. Accordingly, the amounts of catalyst components per unit volume can be made approximately the same as those in a newly-made exhaust gas treatment catalyst, and the denitration performance per unit volume can be made approximately equivalent to that of the newly-made exhaust gas treatment catalyst. In addition, the catalyst components can be substantially prevented from being poisoned by the poisonous components, and the lowering of the exhaust-gas treating performance can be greatly suppressed. Simultaneously, the oxidation of sulfur dioxide by the iron component can be substantially eliminated. Therefore, the method of regenerating an exhaust gas treatment catalyst according to the present invention is capable of regenerating an exhaust gas treatment catalyst in which the lowering of the exhaust-gas treating performance and the oxidation of sulfur dioxide are suppressed. Thus, the exhaust gas treatment catalyst according to the present invention is capable of demonstrating performances that are approximately equivalent to those of a newly-made exhaust gas treatment catalyst. BRIEF DESCRIPTION OF THE DRAWINGS [Fig. 1] Fig. 1 shows a schematic configuration diagram of an exhaust gas treatment catalyst used in a main embodiment of a method of regenerating an exhaust gas treatment catalyst according to the present invention. [Fig. 2] Fig. 2 shows a flowchart showing the procedure of the main embodiment of the method of regenerating an exhaust gas treatment catalyst according to the present invention. BEST MODES FOR CARRYING OUT THE INVENTION A method of regenerating an exhaust gas treatment catalyst according to the present invention and an exhaust gas treatment catalyst obtained by the method will be described on the basis of the drawings. However, the present invention is not limited only to embodiments described below.
A Ti02-W03-V20s-based exhaust gas treatment catalyst for denitration having a honeycomb shape (height: 150 mm, breadth: 150 mm, length: 800 mm, wall thickness: 1.15 mm, pitch (distance between the centers of adjacent walls): 7.4 mm, number of meshes (n): 20><20) was used in an exhaust gas line of a coal-fired boiler for approximately 70000 hours (percentage of clogged holes: approximately 3%). The catalyst was crushed with a crusher. The fragments obtained by crushing were screened with sieves respectively having mesh sizes of 0.074 mm, 0.105 mm, 0.150 mm, 0.212 mm, 0.297 mm, 0.5 mm, and 1.0 mm (the nominal dimensions are specified according to Japanese Industrial Standards (JIS)). Then, the weight percentages and composition percentages of the fine particles passed through the sieves and of the coarse pieces left on the sieves were obtained respectively. Tables 1 and 2 below show the result. Note that, for comparison, the composition percentages of a newly-made exhaust gas treatment catalyst are also shown in Tables 1 and 2 below. As seen from Tables 1 and 2 above, it was confirmed that the mesh sizes (threshold size S) set in a range of 0.105 to 1.0 mm were able to make the weight percentage of the coarse pieces in a range of 70 to 95%. Catalysts for treating exhaust gas were regenerated by using the coarse pieces screened with the sieves having mesh sizes of 0.5 mm and 0.074 mm, respectively, in Example 1 above. Specifically, each of the coarse pieces was pulverized (to have an average particle diameter of 20 urn) with a hammermill. The fine powder thus obtained (13 kg), an organic binder (0.9 kg), and water (adequate amount) were kneaded with a kneader and uniformly mixed. The obtained kneaded product was supplied into an extruder to prepare a precursor of an exhaust gas treatment catalyst the catalyst having a honeycomb shape (height: 69 mm, breadth: 69 mm, length: 800 mm, mesh pitch: 7.4 mm, mesh opening: 6.25 mm, number of meshes (n): 9x9). The precursor was sufficiently naturally dried and subsequently dried with hot air (100°C * 5 hours). Thereafter, the dried precursor was subjected to a calcining treatment (500°C * 3 hours) in a calcining furnace, and then cut into pieces (number of meshes: 6x7). In this manner, obtained were test samples 1 (screened product with the 0.5-mm mesh) and test samples 2 (screened product with the 0.074-mm mesh) of the regenerated exhaust gas treatment catalyst (two in each test sample). Subsequently, under conditions described below, the denitration rates and SO2 oxidation rates of the respective test samples 1 and 2 were obtained, and the AS2O3 contents thereof were also obtained. Moreover, for comparison, prepared were: an exhaust gas treatment catalyst (test sample 3) regenerated under the same conditions as those of the test samples 1 and 2 after mixing coarse pieces obtained under the conditions of the Example 1, except the omission of the screening (separation step), i.e., without removing fly ash; an exhaust gas treatment catalyst (test sample 4) before the regeneration treatment; and a newly-made exhaust gas treatment catalyst (test sample 5). The denization rates and SO2 oxidation rates thereof were obtained, and the AS2O3 contents thereof were also obtained. Table 3 below shows the result. Note that, the denitration rate and the SO2 oxidation rate were calculated according to equations described below. • Test conditions • Compositions of exhaust gas- NOx. 150 ppm NH3: 150 ppm SO2 : 800 ppm O2 : 4% CO2: approximately 12.5% H2O: approximately 11.5% N2: balance • Temperature of exhaust gas: 380°C • Amount of exhaust gas: 19.97 Nm3/hr • Ugs: 2.3 Nm/sec • AV: 11.63 N3/m2-hr • Denitration rate (%)= {l-(NOx concentration at catalyst outlet / NOx concentration at catalyst inlet)} *100 • SO2 oxidation rate (%)= {(SO3 concentration at catalyst outlet -SO3 concentration at catalyst inlet) / SO2 concentration at catalyst inlet} * 100 As seen from Table 3 above, the test sample 2 (screened product with the 0.074-mm mesh) and the test sample 3 (product without screening) had improved denization rates compared with that of the test sample 4 (used product having fly ash adhered thereto), but had greatly increased SOz oxidation rates more than those of the test sample 4 (used product having fly ash adhered thereto) and the test sample 5(newly-made product). In contrast, the test sample 1 (screened product with the 0.5-mm mesh) had an improved denitration rate compared with that of the test sample 4 (used product having fly ash adhered thereto), and also had a SO2 oxidation rate suppressed to a level approximately equivalent to that of the test sample 5 (newly-made product). The SO2 oxidation rate of the test sample 1 was satisfactorily reduced compared with those of the test sample 2 (screened product with the 0.074-mm mesh) and the test sample 3 (product without screening). Moreover, the test sample 1 (screened product with the 0.5-mm mesh) can be recognized as a regenerated product made of recycled raw material because the test sample 1 contains approximately the same amount of AS2O3, which was originated from the fly ash and so forth, as those of the other test samples 2 to 4. However, the test sample 1 demonstrated comparative performances to those of the test sample 5 that was a newly-made product containing no AS2O3. From the results described above, it was confirmed that the method of regenerating an exhaust gas treatment catalyst according to the present invention is capable of regenerating an exhaust gas treatment catalyst in which the lowering of the exhaust-gas treating performance and the oxidation of sulfur dioxide are suppress. It was also confirmed that the exhaust gas treatment catalyst according to the present invention is capable of demonstrating performances that are approximately equivalent to those of a newly-made exhaust gas treatment catalyst. INDUSTRIAL APPLICABILITY A method of regenerating an exhaust gas treatment catalyst according to the present invention and an exhaust gas treatment catalyst obtained by the method are extremely useful and beneficial in various industries, since such a method and an exhaust gas treatment catalyst are capable of suppressing the lowering of the exhaust-gas treating performance and the oxidation of sulfur dioxide, and demonstrating performances approximately equivalent to those of a newly-made product. WE CLAIM: 1. A method of regenerating an exhaust gas treatment catalyst having ash adhered to a surface thereof, the method characterized by comprising: a crushing step of crushing the exhaust gas treatment catalyst that has been used; a separating step of separating the crushed exhaust gas treatment catalyst into coarse pieces having a size exceeding a threshold size S and fine particles having a size not larger than the threshold size S; a pulverizing step of pulverizing the separated coarse pieces into a fine powder; a molding step of molding the pulverized fine powder as a raw material into an exhaust gas treatment catalyst; and a calcining step of calcining a molded precursor of the exhaust gas treatment catalyst, the method characterized in that the threshold size S has a value not smaller than 0.105 mm. 2. The method of regenerating an exhaust gas treatment catalyst according to claim 1, characterized in that the crushing step is a step in which the exhaust gas treatment catalyst that has been used is crushed such that 70 to 95 wt% of the whole exhaust gas treatment catalyst that has been used becomes the coarse pieces having a size exceeding the threshold size S. 3. The method of regenerating an exhaust gas treatment catalyst according to claim 2, characterized in that the threshold size S has a value not larger than 1.0 mm. 4. The method of regenerating an exhaust gas treatment catalyst according to any one of claims 1 to 3, characterized in that the pulverizing step is a step in which the coarse pieces is pulverized such that the fine powder has an average particle diameter not larger than 0.1 mm. 5. The method of regenerating an exhaust gas treatment catalyst according to any one of claims 1 to 4, characterized in that the exhaust gas treatment catalyst is used to treat exhaust gas from a burned coal. 6. The method of regenerating an exhaust gas treatment catalyst according to claim 5, characterized in that the exhaust gas treatment catalyst is used to treat nitrogen oxide in the exhaust gas. 7. An exhaust gas treatment catalyst characterized by being regenerated by the method of regenerating an exhaust gas treatment catalyst according to any one of claims 1 to 6.

Documents

Application Documents

# Name Date
1 1105-MUMNP-2010-CORRESPONDENCE(13-10-2010).pdf 2010-10-13
1 1105-MUMNP-2010-RELEVANT DOCUMENTS [16-09-2023(online)].pdf 2023-09-16
2 1105-MUMNP-2010-RELEVANT DOCUMENTS [16-09-2022(online)].pdf 2022-09-16
2 1105-MUMNP-2010-FORM 3(16-11-2010).pdf 2010-11-16
3 1105-MUMNP-2010-RELEVANT DOCUMENTS [09-08-2021(online)].pdf 2021-08-09
3 1105-MUMNP-2010-CORRESPONDENCE(16-11-2010).pdf 2010-11-16
4 1105-MUMNP-2010-PROOF OF ALTERATION [12-02-2021(online)].pdf 2021-02-12
4 1105-MUMNP-2010-FORM 2(TITLE PAGE)-(GRANTED)-(23-10-2013).pdf 2013-10-23
5 1105-MUMNP-2010-RELEVANT DOCUMENTS [07-03-2020(online)].pdf 2020-03-07
5 1105-MUMNP-2010-FORM 2(GRANTED)-(23-10-2013).pdf 2013-10-23
6 1105-MUMNP-2010-RELEVANT DOCUMENTS [01-03-2019(online)].pdf 2019-03-01
6 1105-MUMNP-2010-DRAWING(GRANTED)-(23-10-2013).pdf 2013-10-23
7 1105-MUMNP-2010-DESCRIPTION(GRANTED)-(23-10-2013).pdf 2013-10-23
8 1105-MUMNP-2010-CORRESPONDENCE(IPO)-(23-10-2013).pdf 2013-10-23
8 1105-MUMNP-2010-ABSTRACT(17-8-2012).pdf 2018-08-10
9 1105-MUMNP-2010-CLAIMS(GRANTED)-(23-10-2013).pdf 2013-10-23
10 1105-MUMNP-2010-ABSTRACT(GRANTED)-(23-10-2013).pdf 2013-10-23
10 1105-mumnp-2010-abstract.pdf 2018-08-10
11 1105-MUMNP-2010-CANCELLED PAGES(17-8-2012).pdf 2018-08-10
11 1105-MUMNP-2010-CORRESPONDENCE-(17-12-2013).pdf 2013-12-17
12 1105-mumnp-2010-certificate.pdf 2018-08-10
12 1105-MUMNP-2010-CORRESPONDENCE(IPO)-(17-12-2013).pdf 2013-12-17
13 1105-MUMNP-2010-CLAIMS(AMENDED)-(12-9-2013).pdf 2018-08-10
13 Power of Attorney [10-11-2015(online)].pdf 2015-11-10
14 1105-MUMNP-2010-CLAIMS(AMENDED)-(17-8-2012).pdf 2018-08-10
14 Form 16 [10-11-2015(online)].pdf 2015-11-10
15 1105-MUMNP-2010-CLAIMS(MARKED COPY)-(12-9-2013).pdf 2018-08-10
15 Assignment [10-11-2015(online)].pdf 2015-11-10
16 1105-mumnp-2010-claims.pdf 2018-08-10
16 1105-MUMNP-2010-POWER OF AUTHORITY (16-11-2015).pdf 2015-11-16
17 1105-MUMNP-2010-CORRESPONDENCE(1-7-2013).pdf 2018-08-10
17 1105-MUMNP-2010-CORRESPONDENCE(16-11-2015).pdf 2015-11-16
18 1105-MUMNP-2010-ASSIGNMENT(16-11-2015).pdf 2015-11-16
18 1105-MUMNP-2010-CORRESPONDENCE(10-1-2011).pdf 2018-08-10
19 Form 27 [28-03-2017(online)].pdf 2017-03-28
19 1105-MUMNP-2010-CORRESPONDENCE(10-8-2010).pdf 2018-08-10
20 1105-MUMNP-2010-CORRESPONDENCE(20-8-2010).pdf 2018-08-10
20 1105-MUMNP-2010-RELEVANT DOCUMENTS [27-02-2018(online)].pdf 2018-02-27
21 1105-mumnp-2010-correspondence.pdf 2018-08-10
21 Form16-Online.pdf 2018-08-10
22 1105-mumnp-2010-description(complete).pdf 2018-08-10
22 abstract1.jpg 2018-08-10
23 1105-mumnp-2010-drawing.pdf 2018-08-10
23 1105-MUMNP-2010_EXAMREPORT.pdf 2018-08-10
24 1105-mumnp-2010-wo international publication report a1.pdf 2018-08-10
25 1105-mumnp-2010-verification.pdf 2018-08-10
25 1105-MUMNP-2010-FORM 1(10-8-2010).pdf 2018-08-10
26 1105-mumnp-2010-form 1.pdf 2018-08-10
26 1105-MUMNP-2010-REPLY TO HEARING(12-9-2013).pdf 2018-08-10
27 1105-MUMNP-2010-FORM 18.pdf 2018-08-10
27 1105-MUMNP-2010-REPLY TO EXAMINATION REPORT(17-8-2012).pdf 2018-08-10
28 1105-mumnp-2010-form 2(title page).pdf 2018-08-10
28 1105-MUMNP-2010-POWER OF ATTORNEY(20-8-2010).pdf 2018-08-10
29 1105-mumnp-2010-form 2.pdf 2018-08-10
29 1105-MUMNP-2010-OTHER DOCUMENT(12-9-2013).pdf 2018-08-10
30 1105-MUMNP-2010-FORM 26(12-9-2013).pdf 2018-08-10
30 1105-MUMNP-2010-FORM PCT-ISA-237(12-9-2013).pdf 2018-08-10
31 1105-MUMNP-2010-FORM 3(17-8-2012).pdf 2018-08-10
31 1105-MUMNP-2010-FORM PCT-ISA-237(10-1-2011).pdf 2018-08-10
32 1105-mumnp-2010-form 3.pdf 2018-08-10
32 1105-mumnp-2010-form pct-isa-210.pdf 2018-08-10
33 1105-mumnp-2010-form 5.pdf 2018-08-10
33 1105-MUMNP-2010-FORM PCT-IB-373(12-9-2013).pdf 2018-08-10
34 1105-mumnp-2010-form pct-ib-304.pdf 2018-08-10
34 1105-MUMNP-2010-FORM PCT-IB-338(10-1-2011).pdf 2018-08-10
35 1105-mumnp-2010-form pct-ib-311.pdf 2018-08-10
36 1105-mumnp-2010-form pct-ib-304.pdf 2018-08-10
36 1105-MUMNP-2010-FORM PCT-IB-338(10-1-2011).pdf 2018-08-10
37 1105-mumnp-2010-form 5.pdf 2018-08-10
37 1105-MUMNP-2010-FORM PCT-IB-373(12-9-2013).pdf 2018-08-10
38 1105-mumnp-2010-form 3.pdf 2018-08-10
38 1105-mumnp-2010-form pct-isa-210.pdf 2018-08-10
39 1105-MUMNP-2010-FORM 3(17-8-2012).pdf 2018-08-10
39 1105-MUMNP-2010-FORM PCT-ISA-237(10-1-2011).pdf 2018-08-10
40 1105-MUMNP-2010-FORM 26(12-9-2013).pdf 2018-08-10
40 1105-MUMNP-2010-FORM PCT-ISA-237(12-9-2013).pdf 2018-08-10
41 1105-mumnp-2010-form 2.pdf 2018-08-10
41 1105-MUMNP-2010-OTHER DOCUMENT(12-9-2013).pdf 2018-08-10
42 1105-mumnp-2010-form 2(title page).pdf 2018-08-10
42 1105-MUMNP-2010-POWER OF ATTORNEY(20-8-2010).pdf 2018-08-10
43 1105-MUMNP-2010-FORM 18.pdf 2018-08-10
43 1105-MUMNP-2010-REPLY TO EXAMINATION REPORT(17-8-2012).pdf 2018-08-10
44 1105-mumnp-2010-form 1.pdf 2018-08-10
44 1105-MUMNP-2010-REPLY TO HEARING(12-9-2013).pdf 2018-08-10
45 1105-MUMNP-2010-FORM 1(10-8-2010).pdf 2018-08-10
45 1105-mumnp-2010-verification.pdf 2018-08-10
46 1105-mumnp-2010-wo international publication report a1.pdf 2018-08-10
47 1105-MUMNP-2010_EXAMREPORT.pdf 2018-08-10
47 1105-mumnp-2010-drawing.pdf 2018-08-10
48 1105-mumnp-2010-description(complete).pdf 2018-08-10
48 abstract1.jpg 2018-08-10
49 1105-mumnp-2010-correspondence.pdf 2018-08-10
49 Form16-Online.pdf 2018-08-10
50 1105-MUMNP-2010-CORRESPONDENCE(20-8-2010).pdf 2018-08-10
50 1105-MUMNP-2010-RELEVANT DOCUMENTS [27-02-2018(online)].pdf 2018-02-27
51 1105-MUMNP-2010-CORRESPONDENCE(10-8-2010).pdf 2018-08-10
51 Form 27 [28-03-2017(online)].pdf 2017-03-28
52 1105-MUMNP-2010-ASSIGNMENT(16-11-2015).pdf 2015-11-16
52 1105-MUMNP-2010-CORRESPONDENCE(10-1-2011).pdf 2018-08-10
53 1105-MUMNP-2010-CORRESPONDENCE(1-7-2013).pdf 2018-08-10
53 1105-MUMNP-2010-CORRESPONDENCE(16-11-2015).pdf 2015-11-16
54 1105-mumnp-2010-claims.pdf 2018-08-10
54 1105-MUMNP-2010-POWER OF AUTHORITY (16-11-2015).pdf 2015-11-16
55 1105-MUMNP-2010-CLAIMS(MARKED COPY)-(12-9-2013).pdf 2018-08-10
55 Assignment [10-11-2015(online)].pdf 2015-11-10
56 1105-MUMNP-2010-CLAIMS(AMENDED)-(17-8-2012).pdf 2018-08-10
56 Form 16 [10-11-2015(online)].pdf 2015-11-10
57 1105-MUMNP-2010-CLAIMS(AMENDED)-(12-9-2013).pdf 2018-08-10
57 Power of Attorney [10-11-2015(online)].pdf 2015-11-10
58 1105-mumnp-2010-certificate.pdf 2018-08-10
58 1105-MUMNP-2010-CORRESPONDENCE(IPO)-(17-12-2013).pdf 2013-12-17
59 1105-MUMNP-2010-CORRESPONDENCE-(17-12-2013).pdf 2013-12-17
59 1105-MUMNP-2010-CANCELLED PAGES(17-8-2012).pdf 2018-08-10
60 1105-MUMNP-2010-ABSTRACT(GRANTED)-(23-10-2013).pdf 2013-10-23
60 1105-mumnp-2010-abstract.pdf 2018-08-10
61 1105-MUMNP-2010-CLAIMS(GRANTED)-(23-10-2013).pdf 2013-10-23
62 1105-MUMNP-2010-CORRESPONDENCE(IPO)-(23-10-2013).pdf 2013-10-23
62 1105-MUMNP-2010-ABSTRACT(17-8-2012).pdf 2018-08-10
63 1105-MUMNP-2010-DESCRIPTION(GRANTED)-(23-10-2013).pdf 2013-10-23
64 1105-MUMNP-2010-DRAWING(GRANTED)-(23-10-2013).pdf 2013-10-23
64 1105-MUMNP-2010-RELEVANT DOCUMENTS [01-03-2019(online)].pdf 2019-03-01
65 1105-MUMNP-2010-FORM 2(GRANTED)-(23-10-2013).pdf 2013-10-23
65 1105-MUMNP-2010-RELEVANT DOCUMENTS [07-03-2020(online)].pdf 2020-03-07
66 1105-MUMNP-2010-FORM 2(TITLE PAGE)-(GRANTED)-(23-10-2013).pdf 2013-10-23
66 1105-MUMNP-2010-PROOF OF ALTERATION [12-02-2021(online)].pdf 2021-02-12
67 1105-MUMNP-2010-CORRESPONDENCE(16-11-2010).pdf 2010-11-16
67 1105-MUMNP-2010-RELEVANT DOCUMENTS [09-08-2021(online)].pdf 2021-08-09
68 1105-MUMNP-2010-FORM 3(16-11-2010).pdf 2010-11-16
68 1105-MUMNP-2010-RELEVANT DOCUMENTS [16-09-2022(online)].pdf 2022-09-16
69 1105-MUMNP-2010-CORRESPONDENCE(13-10-2010).pdf 2010-10-13
69 1105-MUMNP-2010-RELEVANT DOCUMENTS [16-09-2023(online)].pdf 2023-09-16

ERegister / Renewals

3rd: 17 Dec 2013

From 27/10/2010 - To 27/10/2011

4th: 17 Dec 2013

From 27/10/2011 - To 27/10/2012

5th: 17 Dec 2013

From 27/10/2012 - To 27/10/2013

6th: 17 Dec 2013

From 27/10/2013 - To 27/10/2014

7th: 28 Aug 2014

From 27/10/2014 - To 27/10/2015

8th: 04 Sep 2015

From 27/10/2015 - To 27/10/2016

9th: 08 Sep 2016

From 27/10/2016 - To 27/10/2017

10th: 07 Sep 2017

From 27/10/2017 - To 27/10/2018

11th: 11 Sep 2018

From 27/10/2018 - To 27/10/2019

12th: 09 Oct 2019

From 27/10/2019 - To 27/10/2020

13th: 17 Sep 2020

From 27/10/2020 - To 27/10/2021

14th: 08 Sep 2021

From 27/10/2021 - To 27/10/2022

15th: 14 Sep 2022

From 27/10/2022 - To 27/10/2023

16th: 13 Sep 2023

From 27/10/2023 - To 27/10/2024

17th: 10 Sep 2024

From 27/10/2024 - To 27/10/2025

18th: 09 Sep 2025

From 27/10/2025 - To 27/10/2026