The invention relates to a multilayer composite which has a barrier layer comprising a thermoplastic polyester and a protective layer comprising a material which acts as a barrier to alcohols and is selected from among a fluoropolymer and a polyolefin.
In the development of multilayer composites which are used, for example, as pipes for conveying liquid or gaseous media in motor vehicles, the molding compositions used have to have a sufficient chemical resistance toward the media to be conveyed and the pipes have to meet all the relevant mechanical requirements even after long-term exposure to fuels, oils or heat. Apart from the requirement of a satisfactory fuel resistance, the automobile industry demands an improved barrier action of the fuel lines in order to reduce the emissions of hydrocarbons into the environment. This has led to the development of multilayer pipe systems in which, for example, a thermoplastic polyester is used as barrier layer material. Such systems are described, for example, in EP-A-0 509 211, EP-A-0 569 681 and EP-A-1 065 048. However, these known pipes have the disadvantage that polyester molding compositions are susceptible to alcoholysis and hydrolysis and can lose their good mechanical strength as time goes on when alcohol-containing fuel is used.
To solve this problem, EP-A-0 637 509 proposes incorporating a fluoropolymer layer as innermost layer to protect the polyester layer from water and alcohols. Fluoropolymer layer and polyester layer are joined to one another by means of a bonding agent. Bonding agents disclosed are mixtures comprising firstly a fluoropolymer, flexible fluoropolymer or fluororubber

and, secondly, a crystalline polyester or a polyester elastomer. In addition, a thermoplastic polyurethane, a polyamide elastomer, a modified polyolefin or a "miscibilizer" having, for example, epoxy, acid anhydride, oxazoline, isocyanate, carboxyl or amino groups can be present. However, it is not demonstrated whether this achieves any adhesion at all, apart from permanent adhesion. Due to the constituents disclosed, some of which are soluble in fuels, these bonding agents do not have a satisfactory fuel resistance. In addition, the teachings of EP 0 637 509 in this respect cannot readily be reproduced by a person skilled in the arts on the basis of the very general information.
Another technical solution is described in DE-A 43 36 289. There, the polyester layer and the internal fluoropolymer layer are joined to one another by means of two successive bonding layers. However, such complex systems are expensive to produce.
As a modification thereof, a polyolefinic inner layer is also able to protect a polyester layer against the action of water and alcohol. However, there is also the problem here that satisfactory adhesion has to be achieved.
It is accordingly an object of the invention to develop a bonding agent which makes good adhesion between the polyester layer and the protective layer possible. A further object was to make adhesion which is not impaired by contact with fuel possible. Furthermore, the adhesion should be retained to a sufficient extent during the operating life of the composite. Overall, a very simple technical solution is desirable.
These objects are achieved by a multilayer composite
comprising the following layers:
I. an inner layer I selected from among an unmodified

or adhesion-modified fluoropolymer molding composition and an unmodified or adhesion-modified polyolefin molding composition; II. a bonding layer II which has the following composition:
a) from 2 to 80 parts by weight, preferably from 4
to 60 parts by weight and particularly
preferably from 6 to 4 0 parts by weight, of a
graft copolymer prepared using the following
monomers:
from 0.5 to 25% by weight, based on the graft copolymer, of a polyamine having at least 4, preferably at least 8 and particularly preferably at least 11 nitrogen atoms and a number average molecular weight Mn of preferably at least 146 g/mol, particularly preferably at least 500 g/mol and very particularly preferably at least 800 g/mol, and
polyamide-forming monomers selected from among lactams, oo-aminocarboxylic acids and equimolar combinations of diamine and dicarboxylic acid;
b) from 0 to 85 parts by weight, preferably from 10 to 75 parts by weight and particularly preferably from 25 to 65 parts by weight, of a polyester,
c) from 0 to 85 parts by weight of a polymer selected from among polyamides, fluoropolymers and polyolefins,
where the sum of the parts by weight of a), b) and
c) is 100;
d) not more than 50 parts by weight, preferably not more than 3 0 parts by weight and particularly preferably not more than 2 0 parts by weight, of additives selected from among impact-modifying rubber and customary auxiliaries and additives;

III. a layer III of a polyester molding composition.
The component II.c) is preferably used in an amount of from 5 to 75 parts by weight, particularly preferably from 10 to 65 parts by weight and very particularly preferably from 20 to 55 parts by weight.
The multilayer composite is generally a pipe or a hollow body.
The fluoropolymer used for layer I can be, for example, a polyvinylidene fluoride (PVDF), an ethylene-tetrafluoroethylene copolymer (ETFE), an ETFE modified by means of a third component such as propene, hexafluoropropene, vinyl fluoride or vinylidene fluoride (for example EFEP), an ethylene-chlorotrifluoroethylene copolymer (E-CTFE), a poly-chlorotrifluoroethylene (PCTFE), a tetrafluoroethylene-hexafluoropropene-vinylidene fluoride copolymer (THV), a tetrafluoroethylene-hexafluoropropene copolymer (FEP) or a tetrafluoroethylene-perfluoroalkyl vinyl ether copolymer (PFA).
If the bonding agent of layer II itself does not contain a fluoropolymer in a sufficient amount, the fluoropolymer of layer I is preferably adhesion-modified, i.e. functional groups which can react with amino groups of the bonding agent and thus make bonding of the phases possible are present. Such adhesion modification can generally be achieved in two ways,
either the fluoropolymer contains built-in functional groups, for example acid anhydride groups or carbonate groups, as described in US 5 576 106, US-A-2003148125, US-A-2003035914, US-A-2002104575, JP-A-10311461, EP-A-0 726 293, EP-A-0 992 518 or WO 9728394;
or the fluoropolymer molding composition comprises a polymer which bears functional groups and is

miscible or at least compatible with the fluoropolymer. Such systems are disclosed, for example, in EP-A-0 63 7 511 or the equivalent US 5 510 160 and in EP-A-0 673 762 or the equivalent US 5 554 426, which are hereby expressly incorporated by reference. The modified fluoropolymer of EP-A-0 673 762 comprises
from 97.5 to 50% by weight, preferably from
97.5 to 80% by weight and particularly
preferably from 96 to 90% by weight, of PVDF
and
from 2.5 to 50% by weight, preferably from 2.5
to 2 0% by weight and particularly preferably
from 4 to 10% by weight, of an acrylate
copolymer, comprising at least the following
building blocks:
i) from 14 to 85% by weight of ester
building blocks, ii) from 0 to 75% by weight of imide building
blocks, iii) from 0 to 15% by weight of carboxylic
acid building blocks and iiii) from 7 to 20 parts by weight of carboxylic anhydride building blocks.
For further details, reference may be made to the documents incorporated by reference, whose contents are expressly incorporated into the disclosure of the present patent application.
The polyolefin which is used as an alternative in the layer I can first and foremost be a polyethylene, in particular a high density polyethylene (HDPE) or an isotactic polypropylene. The polypropylene can be a homopolymer or copolymer, for example a copolymer with ethylene or 1-butene as comonomer, with both random and block copolymers being able to be used. Furthermore, the polypropylene can also be impact-modified, for

example by means of ethylene-propylene rubber (EPM) or EPDM as described in the prior art.
When the bonding agent of the layer II itself does not contain a polyolefin in a sufficient amount, the polyolefin of the layer I is also preferably adhesion-modified in the sense that functional groups which can react with amino groups of the bonding agent are present. Suitable functional groups are first and foremost carboxyl groups, carboxylic anhydride groups, carbonate groups, acyllactam groups, oxazoline groups, oxazine groups, oxazinone groups, carbodiimide groups or epoxide groups.
The functional groups are, as described in the prior art, grafted onto the polyolefin chain by reaction with olefinically unsaturated functional compounds such as acrylic acid, maleic acid, fumaric acid, monobutyl maleate, maleic anhydride, aconitic anhydride, itaconic anhydride or vinyloxazoline, generally with the aid of a free-radical initiator and/or thermally, or they are incorporated into the main chain by free-radical copolymerization of the olefinically unsaturated functional compounds with the olefin.
In the graft copolymer of component II. a), the amino group concentration is preferably in the range from 100 to 2 500 mmol/kg.
As polyamine, it is possible to use, for example, the following classes of substances:
polyvinyl amines (Rompp Chemie Lexikon, 9th edition, volume 6, page 4 921, Georg Thieme Verlag Stuttgart 1992);
polyamines prepared from alternating polyketones (DE-A 196 54 058);

dendrimers such as
{ (H2N-(CH2)3)2N-(CH2)3)2-N(CH2)2-N((CH2)2-N((CH2)3-NH2)2)2
(DE-A-196 54 179) or
tris(2-aminoethyl)amine, N,N-bis(2-aminoethyl)-N',N'-bis[2-[bis(2-aminoethyl)amino]ethyl]-1,2-ethanediamine,
3,15-bis(2-aminoethyl)-6,12-bis[2-[bis(2-amino¬ethyl) amio]ethyl]-9-[2-[bis[2-bis(2-amino¬ethyl) amino]ethyl]amino]ethyl]-3,6, 9,12,15-pentaazaheptadecane-1,17-diamine (J.M. Warakomski, Chem. Mat. 1992, 4, 1000-1004);
linear polyethylenimines which can be prepared by polymerization of 4,5-dihydro-l,3-oxazoles and subsequent hydrolysis (Houben-Weyl, Methoden der Organischen Chemie, volume E20, pages 1482-1487, Georg Thieme Verlag Stuttgart, 1987);
branched polyethylenimines which are obtainable by polymerization of aziridines (Houben-Weyl, Methoden der Organischen Chemie, volume E2 0, pages 1482-1487, Georg Thieme Verlag Stuttgart, 1987) and generally have the following amino group distribution:
from 25 to 46% of primary amino groups, from 3 0 to 45% of secondary amino groups and from 16 to 40% of tertiary amino groups.
In the preferred case, the polyamine has a number average molecular weight Mn of not more than 20 000 g/mol, particularly preferably not more than 10 000 g/mol and very particularly preferably not more than 5 000 g/mol.
Lactams or co-aminocarboxylic acids which can be used as polyamide-forming monomers contain from 4 to 19, in

particular from 6 to 12, carbon atoms. Particular preference is given to using e-caprolactam, e-aminocaproic acid, caprylolactam, co-aminocaprylic acid, laurolactam, 12-aminododecanoic acid and/or 11-aminoundecanoic acid.
Combinations of diamine and dicarboxylic acid are, for example, hexamethylene diamine/adipic acid, hexa-methylenediamine/dodecanedioic acid, octamethylene-diamine/sebacic acid, decamethylenediamine/sebacic acid, decamethylenediamine/dodecanedioic acid, dodeca-methylenediamine/dodecanedioic acid and dodeca-methylenediamine/2,6-naphthalenedicarboxylic acid. However, all other combinations such as decamethylenediamine/dodecanedioic acid/terephthalic acid, hexamethylenediamine/adipic acid/terephthalic acid, hexamethylenediamine/adipic acid/caprolactam, decamethylenediamine/dodecanedioic acid/ll-amino-undecanoic acid, decamethylenediamine/dodecanedioic acid/laurolactam, decamethylenediamine/terephthalic acid/laurolactam or dodecamethylenediamine/2,6-naphthalenedicarboxylic acid/laurolactam can also be used.
In a preferred embodiment, the graft copolymer is prepared with additional use of an oligocarboxylic acid selected from among 0.015-ca.3 mol% of dicarboxylic acid and 0.01-ca.l.2 mol% of tricarboxylic acid, in each case based on the sum of the other polyamide-forming monomers. In determining this ratio, each of the monomers in the case of an equivalent combination of diamine and dicarboxylic acid is considered individually. As a result, the polyamide-forming monomers have an overall slight excess of carboxyl groups. If a dicarboxylic acid is used, preference is given to using from 0.03 to 2.2 mol%, particularly preferably from 0.05 to 1.5 mol%, very particularly preferably from 0.1 to 1 mol% and in particular from

0.15 to 0.65 mol%; if a tricarboxylic acid is used, preference is given to employing from 0.02 to 0.9 mol%, particularly preferably from 0.025 to 0.6 mol%, very particularly preferably from 0.03 to 0.4 mol% and in particular from 0.04 to 0.25 mol%. The concomitant use of the oligocarboxylic acid significantly improves the solvent and fuel resistance, in particular the resistance to hydrolysis and alcoholysis and the environmental stress cracking resistance, but also the swelling behavior and, associated therewith, the dimensional stability and also the barrier action against diffusion.
As oligocarboxylic acid, it is possible to use any dicarboxylic or tricarboxylic acid having from 6 to 24 carbon atoms, for example adipic acid, suberic acid, azelaic acid, sebacic acid, dodecanedioic acid, isophthalic acid, 2,6-naphthalenedicarboxylic acid, cyclohexane-1,4-dicarboxylic acid, trimesic acid and/or trimellitic acid.
In addition, aliphatic, alicyclic, aromatic, aralyphatic and/or alkylaryl-substituted monocarboxylic acids having from 3 to 50 carbon atoms, e.g. lauric acid, unsaturated fatty acids, acrylic acid or benzoic acid, can, if desired, be used as regulators. The concentration of amino groups can be reduced by means of these regulators without altering the geometry of the molecules. In addition, functional groups such as double or triple bonds, etc., can be introduced in this way. However, it is desirable for the graft copolymer to have a substantial proportion of amino groups. The amino group concentration of the graft copolymer is particularly preferably in the range from 15 0 to 1500 mmol/kg, in particular in the range from 250 to 13 00 mmol/kg and very particularly preferably in the range from 300 to 1100 mmol/kg. Here and in the following, the term amino groups encompasses not only

Possible aromatic dicarboxylic acids are, for example, terephthalic acid, isophthalic acid, 1,4-, 1,5-, 2,6-or 2,7-naphthalenedicarboxylic acid, diphenic acid and bis (4-carboxylphenyl) ether. Up to 30 mol% of these dicarboxylic acids can be replaced by aliphatic or cycloaliphatic dicarboxylic acids such as succinic acid, adipic acid, sebacic acid, dodecanedioic acid or cyclohexane-1,4-dicarboxylic acid.
Examples of suitable polyesters are polyethylene terephthalate, polypropylene terephthalate, poly-butyl ene terephthalate, polyethylene 2,6-naphthalate, polypropylene 2,6-naphthalate and polybutylene 2,6-naphthalate. In principle, the polyester of layer III and the polyester of component II b) can be of the same type. If this is not the case, preference is given to choosing polyesters which are compatible with one another.
The preparation of these polyesters is prior art (DE-A 24 07 155, 24 07 156; Ullmanns Encyclopadie der technischen Chemie, 4th edition, vol. 19, page 65 ff., Verlag Chemie, Weinheim, 1980).
The polyester molding composition can comprise either one of these polyesters or a plurality thereof as a mixture. Furthermore, up to 4 0% by weight of other thermoplastics can be present, as long as these do not interfere with the bonding capability, in particular impact-modifying rubbers. Furthermore, the polyester molding composition can further comprise the auxiliaries and additives customary for polyesters, e.g. flame retardants, stabilizers, processing aids, fillers, in particular the fillers to improve the electrical conductivity, reinforcing fibers, pigments or the like. The amount of these substances should be such that the desired properties are not seriously impaired.

Suitable polyamides for component II.c) are first and foremost aliphatic homopolyamides and copolyamides, for example PA 46, PA 66, PA 68, PA 612, PA 88, PA 810, PA 1010, PA 1012, PA 1212, PA 6, PA 7, PA 8, PA 9, PA 10, PA 11 and PA 12. (The designation of the polyamides corresponds to the international standard, with the first digit(s) indicating the number of carbon atoms in the starting diamine and the last digit (s) indicating the number of carbon atoms in the dicarboxylic acid, if only one number is given, this means that an a, co-aminocarboxylic acid or the lactam derived therefrom has been used as starting material; otherwise, reference may be made to H. Domininghaus, Die Kunststoffe und ihre Eigenschaften, pages 272 ff., VDI-Verlag, 1976.)
If copolyamides are used, these can comprise, for example, adipic acid, sebacic acid, suberic acid, isophthalic acid, terephthalic acid, naphthalene-2,6-dicarboxylic acid, etc., as coacid and bis(4-aminocyclohexyl)methane, trimethylhexamethylenediamine, hexamethylenediamine or the like as codiamine. Lactams such as caprolactam or laurolactam and aminocarboxylic acids such as 11-aminoundecanoic acid can likewise be incorporated as cocomponents.
The preparation of these polyamides is known (e.g. D.B. Jacobs, J. Zimmermann, Polymerization Processes, i pp. 424-467, Interscience Publishers, New York, 1977; DE-B-21 52 194).
Further suitable polyamides are mixed aliphatic/aromatic polycondensates as are described, for example, in the US patents 2 071 250, 2 071 251, 2 130 523, 2 130 348, 2 241 322, 2 312 966, 2 512 606 and 3 393 210 and in Kirk-Othmer, Encyclopedia of Chemical Technology, 3rd edition, vol. 18, pages 328

ff. and 435 ff., Wiley & Sons, 1982. Poly (ether ester amides) or poly(ether amides) are also suitable as polyamides; such products are described, for example, in DE-A 25 23 991, 27 12 987 and 30 06 961.
The polyamide end groups are not subject to any
restrictions. However, the best results are generally
obtained when more than 50% of the end groups are amino
end groups.
As fluoropolymer and as polyolefin, which can optionally be present as a constituent of the component II. c), it is possible to use the same compounds as for the layer I. When the layer I comprises a fluoropolymer molding composition, the component II.c) can likewise comprise a fluoropolymer, preferably of the same type, while the use of a polyolefin in the component II.c) does not improve adhesion of the layers in this case.
In an analogous way, when the layer I comprises a polyolefin molding composition, the component II.c) can likewise comprise a polyolefin, preferably of the same type, while the use of a fluoropolymer in the component II. c) does not improve adhesion of the layers in this case.
The fluoropolymer or the polyolefin which is optionally present in the component II.c) is preferably adhesion-modified as described above. In this case, adhesion-modification of the molding composition of layer I can be dispensed with.
As additives for the component II.d) it is possible to use the same ones as described for the polyester molding composition of layer III.
Apart from the layers I to III, further layers, for example a layer V which comprises a polyamide molding

composition or a polyolefin molding composition and is joined to the layer III via a suitable bonding agent (layer IV) , can additionally be present in the composite of the invention. Bonding agents suitable for this purpose are prior art. Furthermore, this polyamide or polyolefin layer can be adjoined by a sheath or envelope of a rubber or a thermoplastic elastomer. A further, innermost fluoropolymer or polyolefin layer can equally well adjoin the inner layer I.
In one embodiment, the multilayer composite further comprises a regrind layer. In the production of composites according to the invention, the scrap is obtained time and again, for example from the start-up of the extrusion plant or in the form of flash from extrusion blown molding or else in the manufacture of pipes. A regrind layer derived from this scrap is embedded between two other layers so that any brittleness of the regrind blend is compensated as far as possible.
The multilayer composite of the invention is, for example, a pipe, a filling port or a container, in particular for conveying or storing liquids or gases. Such a pipe can be smooth or corrugated or only corrugated in subsections. Corrugated pipes are prior art (e.g. US 5 460 771), for which reason further details here are superfluous. Important uses of such multilayer composites are the use as fuel line, as tank filling port, as vapor line (i.e. line in which fuel vapors are conveyed, e.g. breather lines), as filling station line, as cooling fluid line, as air conditioner line or as fuel container, for instance a canister or a tank.
When the multilayer composite of the invention is used for conveying or storing flammable liquids, gases or dusts, e.g. fuel or fuel vapors, it is advisable to

V7
make one of the layers of the composite or an additional inner layer electrically conductive. This can be achieved by compounding with an electrically conductive additive using all methods of the prior art. As conductive additive, it is possible to use, for example, conductive carbon black, metal flakes, metal powder, metallized glass spheres, metallized glass fibers, metal fibers (for example stainless steel fibers), metallized whiskers, carbon fibers (including metallized carbon fibers), intrinsically conductive polymers or graphite fibrils. It is also possible to use mixtures of various conductive additives.
In the preferred case, the electrically conductive layer is in direct contact with the medium to be conveyed or stored and has a surface resistance of not more than 109 D/square and preferably not more than 106 Q/square. The method of determining the resistance of multilayer pipes is described in SAE J 2260 (November 1996, Paragraph 7.9).
The multilayer composite can be produced in one or more stages, for example by means of single-stage multicomponent injection-molding processes, coextrusion, coextrusion blow molding (for example 3D blow molding, parison extrusion into an opened mold half, 3D parison manipulation, suction blow molding, 3D suction blow molding, sequential blow molding), or by means of multistage processes such as coating.
The invention is illustrated by way of example below.
In the examples, the following molding compositions were used:
Inner layer (layer I):
Fluoropolymer 1: Mixture as described in
EP-A-0 673 762 of 95% by weight of a

commercial PVDF and 5% by weight of a
polyglutarimide made up of the
following building blocks:
57% by weight derived from methyl
methacrylate,
3 0% by weight of N-methylglutarimide
type,
3% by weight derived from methacrylic
acid and
10% by weight of the glutaric
anhydride type
(prepared by reaction of methyl
methacrylate with an aqueous solution
of methylamine in the melt).
Fluoropolymer 2: NEOFLON® RP 5000 from Daikin
Industries Ltd., Japan, a modified EFEP

Fluoropolymer 3

NEOFLON' RP 5000 AS from Daikin Industries Ltd., Japan, a modified EFEP which has been made electrically conductive

Polyolefin 1

STAMYLAN P 83 MF 10, a PP copolymer from DSM Deutschland GmbH

Polyolefin 2

VESTOLEN A 6013, an HDPE from DSM Deutschland GmbH

Bonding agent (layer II and IV): Preparation of the graft copolymer:
9.5 kg of laurolactam were melted at 180°C-210°C in a heating vessel and transferred to a pressure-rated polycondensation vessel; 475 g of water and 0.54 g of hypophosphorous acid was subsequently added. The cleavage of the lactam was carried out at 280°C under the autogenous pressure; the vessel was then

i^depressurized to a residual vapor pressure of 5 bar over a period of three hours and 500 g of polyethylenimine (LUPASOL G 100 from BASF AG, Ludwigshafen) and 15 g of dodecanedioic acid were added. Both components were incorporated under the autogenous pressure; the vessel was subsequently depressurized to atmospheric pressure and nitrogen was then passed over the melt at 280°C for two hours. The clear melt was discharged as a strand by means of a melt pump, cooled in a water bath and subsequently palletized.
BA 1: 12.6 kg of a PA12 (r|rei = 2.1), 22.82 kg of VESTODUR® 3000 (homopolybutylene terephthalate from Degussa AG having a solution viscosity J of 165 cm3/g) and 5.0 kg of the graft copolymer were melt-mixed on a twin-screw kneader ZE 25 33D from Berstorff at 270°C and 150 rpm and a throughput of 10 kg/h, extruded and pelletized.
BA 2: As BA 1, except that PA12 was replaced by
polypropylene grafted with maleic anhydride
(ADMER® QB 520 E from Mitsui Chemicals Inc.,
Japan)
BA 3: As BA 1, except that the PA12 was replaced by polyethylene grafted with maleic anhydride (ADMER® NF 408 E of Mitsui Chemicals Inc., Japan)
Polyester layer (layer III):
PEL: An impact-modified homopolybutylene
terephthalate from Degussa AG
Outer layer (layer V):
PA12: An impact-modified, plasticized polyamide from Degussa AG (VESTAMID® X 72 93)

Polyolefin 2: as above
Examples 1 to 5:
Pipes having the dimensions 8 x 1 mm were produced at an extrusion velocity of about 12 m/min on a 5-layer unit equipped with two 45 mm extruders and three 3 0 mm extruders.

Example Inner layer layer I Layer II Layer III Layer IV Layer V
1 0.1 mm of
fluoropolymer 1 0.1 mm of BA 1 0 .3 mm of PEL 0.1 mm of BA 1 0 .4 mm of PA12
2 0.1 mm of fluoropolymer 2 0.1 mm of BA 1 0.3 mm of PEL 0.1 mm of BA 1 0.4 mm of PA12
3 0.1 mm of fluoropolymer 3 0.1 mm of BA 1 0 .3 mm of PEL 0.1 mm of BA 1 0.4 mm of PA12
4 0.1 mm of polyolefin 1 0 .1 mm of BA 2 0 .3 mm of PEL 0.1 mm of BA 1 0 .4 mm of PA12
5 0.1 mm of polyolefin 2 0 .1 mm of BA 3 0.3 mm of PEL 0 .1 mm of BA 3 0.4 mm of polyolefin 2
Characterization of the pipes:
In the pipes of examples 1 to 5, the adhesion between the fluoropolymer or polyolefin inner layer and the polyester layer was so high that the composite could not be separated at this point, both when freshly extruded and after storage in fuel (internal contact storage using CM 15, a test fuel comprising 42.5% by volume of isooctane, 42.5% by volume of toluene and 15% by volume of methanol, at 80°C with a weekly change of fuel, 1000 h).
The rupture rate in the low-temperature impact toughness test at -40°C in accordance with SAE J 2260 was 0/10 for all pipes, both when freshly extruded and after storage in fuel (internal contact storage using CM 15 at 80°C with a weekly change of fuel, 1000 h).

We Claim:
1. Multilayer composite comprising the following layers:
I. an inner layer I selected from among a fluoropolymer molding composition and a polyolefin molding composition;
II. a bonding layer II;
III. a layer III of a polyester molding composition; characterized in that the bonding layer II has the following composition:
a) from 2 to 80 parts by weight of a graft copolymer
prepared using the following monomers:
from 0.5 to 25% by weight, based on the graft copolymer, of a polyamine having at least 4 nitrogen atoms, and - polyamide-forming monomers selected from among lactams, oo-aminocarboxylic acids and equimolar combinations of diamine and dicarboxylic acid;
b) from 0 to 85 parts by weight of a polyester;
c) from 0 to 85 parts by weight of a polymer selected from among polyamides, fluoropolymers and polyolefins,
where the sum of the parts by weight of a), b) and c) is 100;
d) not more than 50 parts by weight of additives selected
from among impact-modifying rubber and customary
auxiliaries and additives.
2. The multilayer composite as claimed in claim 1, wherein
the component II.a) is present in an amount of
from 4 to 60 parts by weight and/or
the component II.b) is present in an amount of
from 10 to 75 parts by weight.

3. The multilayer composite as claimed in claim 1,
wherein
the component II. a) is present in an amount of from 6 to 4 0 parts by weight and/or the component II. b) is present in an amount of from 25 to 65 parts by weight.
4. The multilayer composite as claimed in any of the preceding claims, wherein from 5 to 75 parts by weight of the component II.c) are present.
5. The multilayer composite as claimed in claim 4, wherein from 10 to 65 parts by weight of the component II. c) are present.'
6. The multilayer composite as claimed in claim 4, wherein from 20 to 55 parts by weight of the component II.c) are present.
7. The multilayer composite as claimed in any of claims 1 to 6, wherein the fluoropolymer is selected from the group consisting of PVDF, ETFE, ETFE modified by means of a third component, E-CTFE, PCTFE, THV, FEP and PFA.
8. The multilayer composite as claimed in any of claims 1 to 6, wherein the polyolefin is polyethylene or isotactic polypropylene,
9. The multilayer composite as claimed in any of the preceding claims, wherein the fluoropolymer or the polyolefin is adhesion-modified.
10. The multilayer composite as claimed in any of the preceding claims, wherein the polyester is selected from among polyethylene terephthalate, polypropylene terephthalate, polybutylene terephthalate, polyethylene 2,6-naphthalate, polypropylene 2,6-naphthalate and

polybutylene 2,6-naphthalate.
11. The multilayer composite as claimed in any of the preceding claims which additionally has a layer of a polyamide molding composition or a polyolefin molding composition which is joined via a suitable bonding agent to the layer III.
12. The multilayer composite as claimed in any of the preceding claims which is a pipe or a hollow body.
13. The multilayer composite as claimed in any of the preceding claims which is a pipe corrugated in
its entirety or in subregions.
14. A fuel line, a brake fluid line, a cooling fluid line, a hydraulic fluid line a filling station line, an air conditioner line, a vapor line, a container or a filling port made of the multilayer composite as claimed in claims 1-13.
15. The multilayer composite as claimed in any of the preceding claims, wherein one of the layers of the composite or an additional inner layer has been made electrically conductive.
16. The multilayer composite as claimed in any of the_ preceding claims produced by coextrusion, coating, multicomponent injection molding or coextrusion blow molding.