Sign In to Follow Application
View All Documents & Correspondence

N Type Semiconductor Element, Complementary Type Semiconductor Device And Method For Manufacturing Same, And Wireless Communication Device In Which Same Is Used

Abstract: In the present invention an exceptional complementary type semiconductor element is provided using a simple process. An n-type drive semiconductor element provided with a base material and a source electrode a drain electrode a gate electrode a gate insulating layer and a semiconductor layer on the base material wherein the n-type semiconductor element contains a second insulation layer containing an organic compound that includes bonds between carbon atoms and nitrogen atoms on the opposite side from the gate insulating layer across the semiconductor layer and the semiconductor layer contains a carbon nanotube composite in which a conjugated polymer is affixed to at least a portion of the surface.

Get Free WhatsApp Updates!
Notices, Deadlines & Correspondence

Patent Information

Application #
Filing Date
18 July 2018
Publication Number
30/2018
Publication Type
INA
Invention Field
ELECTRICAL
Status
Email
Parent Application

Applicants

TORAY INDUSTRIES, INC.
1-1, Nihonbashi-Muromachi 2-chome, Chuo-ku, Tokyo 103-8666, Japan.

Inventors

1. SHIMIZU, Hiroji
c/o Shiga Plant, Toray Industries, Inc., 1-1, Sonoyama 1-chome, Otsu-shi, Shiga 520-8558
2. MURASE, Seiichiro
c/o Shiga Plant, Toray Industries, Inc., 1-1, Sonoyama 1-chome, Otsu-shi, Shiga 520-8558
3. SAKII, Daisuke
c/o Shiga Plant, Toray Industries, Inc., 1-1, Sonoyama 1-chome, Otsu-shi, Shiga 520-8558

Specification

1. An n-type semiconductor device comprising:
a substrate;
a source electrode, a drain electrode, and a gate electrode;
a semiconductor layer in contact with the source electrode and the drain electrode;
a gate insulating layer insulating the semiconductor layer from the gate electrode; and
a second insulating layer in contact with the semiconductor layer on the . opposite side of the semiconductor layer from the gate insulating layer;
wherein the semiconductor layer contains a carbon nanotube composite having a conjugated polymer attached to at least a part of the surface thereof; and
wherein the second insulating layer contains an organic compound containing a bond between a carbon atom and a nitrogen atom.
2. The n-type semiconductor device according to claim 1, wherein the conjugated polymer comprises, in the repeating units thereof, a fused heteroaryl unit having a nitrogen-containing double bond in the ring thereof and a thiophene unit. •' '
3. The n-type semiconductor device according to claim 1 or 2, wherein the second insulating layer comprises one or more compounds selected from the following general formulae (1) and (2):

(wherein R1 to R4 independently represent a group constituted by one or more atoms selected from a hydrogen atom(s), a carbon atom(s), a nitrogen atom(s), an oxygen atom(s), a silicon atom(s), a phosphorus atom(s), and a sulfur atom(s); and
X1 and X2 independently represent a group represented by the following general
(wherein R5 to R13 independently represent a group constituted by one or more atoms selected from a hydrogen atom(s), a carbon atom(s), a nitrogen atom(s), an oxygen atom(s), a silicon atom(s), a phosphorus atom(s), and a sulfur atom(s)).
4. The n-type semiconductor device according to claim 3, wherein R1 to R13 in the general formulae (1) to (8) are hydrocarbon groups.
5. The n-type semiconductor device according to any one of claims 1 to 4, wherein the second insulating layer comprises an amine compound having a ring structure.

6. The n-type semiconductor device according to any one of claims 3 to 5, wherein the second insulating layer comprises an organic compound having a structure of the general formula (1) or (2) and containing a ring structure containing the nitrogen atom shown in the formula (1) or (2) as a heteroatom.
7. The n-type semiconductor device according to any one of claims 3 to 6, wherein the second insulating layer comprises one or more compounds selected .from an amidine compound and a guanidine compound.
8. The n-type semiconductor device according to any one of claims 1 to 7, wherein the gate insulating layer comprises an organic compound containing a bond between a silicon atom and a carbon atom. *
9. The n-type semiconductor device according to any one of claims 1 to 8, wherein the gate insulating layer further comprises a metal compound containing a bond between a metal atom and an oxygen atom.
10. The n-type semiconductor device according to claim 9, wherein the metal atom
i
is aluminum. ""
11. An n-type semiconductor device comprising:
a substrate;
a source electrode, a drain electrode, and a gate electrode;
a semiconductor layer in contact with the source electrode and the drain
electrode; • :.
a gate insulating layer insulating the semiconductor layer from the gate
electrode; and - "

a second insulating layer in contact with the semiconductor layer on the opposite side of the semiconductor layer from the gate insulating layer; wherein the semiconductor layer contains a carbon nanotube; and wherein the second insulating layer contains an organic compound having a
(wherein R4 represents a group constituted by one or more atoms selected from a hydrogen atom(s), a carbon atom(s), a nitrogen atom(s), an oxygen atom(s), a silicon atom(s), a phosphorus atom(s), and a sulfur atom(s); and
X1 and X2 independently represent a group represented by the following general

from a hydrogen atom(s), a carbon atom(s), a nitrogen atom(s), an oxygen atom(s), a silicon atom(s), a phosphorus atom(s), and a sulfur atom(s)).
12. The n-type semiconductor device according to claim 11, wherein the second insulating layer comprises an organic compound having a structure of the general formula (2) and containing a ring structure containing the nitrogen atom shown in the general formula (2) as a heteroatom.
13. The n-type semiconductor device according to any one of claims 1 or 12, wherein the total length of the carbon nanotube composite present per 1 um2 of the semiconductor layer is 1 um to 50 urn. • ...
14. A complementary semiconductor device comprising the n-type semiconductor device according to any one of claims 1 to 13 and ap-type semiconductor device,
wherein the p-type semiconductor device comprises:
a substrate; a source electrode, a drain electrode, and a gate electrode; *
a semiconductor layer in contact with the source electrode and the drain electrode; and
a gate insulating layer insulating the semiconductor layer from the gate insulating layer;
wherein the semiconductor layer of the p-type semiconductor device contains a carbon nanotube composite having a conjugated polymer attached to at least a part of the surface thereof.
15. The complementary semiconductor device according to claim 14, wherein the p-
type semiconductor device comprises a second insulating layer in contact with the

semiconductor layer of the p-type semiconductor device on the opposite side of the semiconductor layer of the p-type semiconductor device from the gate insulating layer of the p-type semiconductor device.
16. The complementary semiconductor device according to claim 14 or 15, wherein the source electrode and the drain electrode of the p-type semiconductor device and . the source electrode and the drain electrode of the n-type semiconductor device are all composed of the same material.
17. The complementary semiconductor device according to any one of claims 14 to
16, wherein the semiconductor layer of the p-type semiconductor device and the
semiconductor layer of the n-type semiconductor device are composed of the same
material.
18. The complementary semiconductor device according to any one of claims 14 to
17, wherein the gate insulating layer of the p-type semiconductor device and the gate
insulating layer of the n-type semiconductor device are composed of the same
material.
19. A method of producing the n-type semiconductor device according to any one of claims 1 to 13, the method comprising the step of forming the semiconductor layer of the n-type semiconductor device by applying and drying the layer.
20. A method of producing the n-type semiconductor device according to any one of claims 1 to 13, the method comprising the step of forming the second insulating layer by applying a composition containing an organic compound containing a bond between a carbon atom and a nitrogen atom and drying the composition.

21. A method of producing the complementary semiconductor device according to
any one of claims 14 to 18, the method comprising the steps of:
(1) forming the source electrode and the drain electrode of the p-type semiconductor device and the source electrode and the drain electrode of the n-type semiconductor device in the same step;
(2) forming the gate insulating layer of the p-type semiconductor device and the gate insulating layer of the n-type semiconductor device in the same step; and
(3) forming the semiconductor layer of the p-type semiconductor device and the semiconductor layer of the n-type semiconductor device in the same step.

22. A wireless communication device comprising at least the n-type semiconductor device according to any one of claims 1 to 13 and an antenna.
23. A wireless communication device comprising at least the complementary semiconductor device according to any one of claims 14 to 18 and an antenna.

Documents

Application Documents

# Name Date
1 201847026811-FER.pdf 2021-10-17
1 201847026811-TRANSLATIOIN OF PRIOIRTY DOCUMENTS ETC. [18-07-2018(online)].pdf 2018-07-18
2 201847026811-STATEMENT OF UNDERTAKING (FORM 3) [18-07-2018(online)].pdf 2018-07-18
2 201847026811-FORM 3 [31-12-2019(online)].pdf 2019-12-31
3 201847026811-PROOF OF RIGHT [18-07-2018(online)].pdf 2018-07-18
3 201847026811-FORM 18 [27-12-2019(online)].pdf 2019-12-27
4 201847026811-PRIORITY DOCUMENTS [18-07-2018(online)].pdf 2018-07-18
4 201847026811-FORM 3 [04-12-2018(online)].pdf 2018-12-04
5 Correspondence by Agent_Form1_24-07-2018.pdf 2018-07-24
5 201847026811-POWER OF AUTHORITY [18-07-2018(online)].pdf 2018-07-18
6 Abstract_201847026811.jpg 2018-07-19
6 201847026811-FORM 1 [18-07-2018(online)].pdf 2018-07-18
7 201847026811-DRAWINGS [18-07-2018(online)].pdf 2018-07-18
7 201847026811-CLAIMS UNDER RULE 1 (PROVISIO) OF RULE 20 [18-07-2018(online)].pdf 2018-07-18
8 201847026811-DECLARATION OF INVENTORSHIP (FORM 5) [18-07-2018(online)].pdf 2018-07-18
8 201847026811-COMPLETE SPECIFICATION [18-07-2018(online)].pdf 2018-07-18
9 201847026811-DECLARATION OF INVENTORSHIP (FORM 5) [18-07-2018(online)].pdf 2018-07-18
9 201847026811-COMPLETE SPECIFICATION [18-07-2018(online)].pdf 2018-07-18
10 201847026811-CLAIMS UNDER RULE 1 (PROVISIO) OF RULE 20 [18-07-2018(online)].pdf 2018-07-18
10 201847026811-DRAWINGS [18-07-2018(online)].pdf 2018-07-18
11 Abstract_201847026811.jpg 2018-07-19
11 201847026811-FORM 1 [18-07-2018(online)].pdf 2018-07-18
12 Correspondence by Agent_Form1_24-07-2018.pdf 2018-07-24
12 201847026811-POWER OF AUTHORITY [18-07-2018(online)].pdf 2018-07-18
13 201847026811-PRIORITY DOCUMENTS [18-07-2018(online)].pdf 2018-07-18
13 201847026811-FORM 3 [04-12-2018(online)].pdf 2018-12-04
14 201847026811-PROOF OF RIGHT [18-07-2018(online)].pdf 2018-07-18
14 201847026811-FORM 18 [27-12-2019(online)].pdf 2019-12-27
15 201847026811-STATEMENT OF UNDERTAKING (FORM 3) [18-07-2018(online)].pdf 2018-07-18
15 201847026811-FORM 3 [31-12-2019(online)].pdf 2019-12-31
16 201847026811-TRANSLATIOIN OF PRIOIRTY DOCUMENTS ETC. [18-07-2018(online)].pdf 2018-07-18
16 201847026811-FER.pdf 2021-10-17

Search Strategy

1 2021-04-0711-54-10E_07-04-2021.pdf
1 klinke2005E_07-04-2021.pdf
2 2021-04-0711-54-10E_07-04-2021.pdf
2 klinke2005E_07-04-2021.pdf