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Nicrfe Alloy

Abstract: Provided is an NiCrFe alloy which has excellent creep strength and stress relaxation cracking resistance. This NiCrFe alloy contains in mass% C in the amount of 0.03-0.15% Si in the amount of 1.00% or less Mn in the amount of 2.00% or less P in the amount of 0.040% or less S in the amount of 0.0050% or less Cr in the amount of 18.0-25.0% Ni in the amount of 25.0-40.0% Ti in the amount of 0.10-1.60% Al in the amount of 0.05-1.00% N in the amount of 0.020% or less O in the amount of 0.008% or less and rare earth elements (REM) in the amount of 0.001-0.100% with Fe and impurities constituting the remainder. In addition the alloy satisfies formulas (1)-(3). (1): 0.50=Ti+48Al/27=2.20 (2): 0.40=Ti/(Ti+48Al/27)=0.80 (3): S[REM/(A(REM))]-S/32-2/3·O/16=0 The symbols for the elements in the formulas are substituted with the content (mass%) of the corresponding element and A(REM) in formula (3) is substituted with the atomic weight of the rare earth elements.

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Patent Information

Application #
Filing Date
08 April 2019
Publication Number
27/2019
Publication Type
INA
Invention Field
METALLURGY
Status
Email
dev.robinson@AMSShardul.com
Parent Application

Applicants

NIPPON STEEL & SUMITOMO METAL CORPORATION
6-1, Marunouchi 2-chome, Chiyoda-ku, Tokyo 1008071

Inventors

1. OKADA, Hirokazu
c/o NIPPON STEEL & SUMITOMO METAL CORPORATION, 6-1, Marunouchi 2-chome, Chiyoda-ku, Tokyo 1008071
2. HAMAGUCHI, Tomoaki
c/o NIPPON STEEL & SUMITOMO METAL CORPORATION, 6-1, Marunouchi 2-chome, Chiyoda-ku, Tokyo 1008071
3. KURIHARA, Shinnosuke
c/o NIPPON STEEL & SUMITOMO METAL CORPORATION, 6-1, Marunouchi 2-chome, Chiyoda-ku, Tokyo 1008071

Specification

0001]The present invention relates to an austenitic heat resistant alloy, more particularly NiCrFe alloy. BACKGROUND [0002]Conventionally, equipment such thermal power boilers, chemical plants, operating in a high temperature environment (e.g., 400 ~ 800 ° C.), further contact with the process fluid containing the sulfides and / or chlorides. Therefore, the materials used in these facilities, it is required creep strength and corrosion resistance at high temperatures. [0003]  Material used in such equipment, for example, SUS304H, SUS316H, SUS321H, and 18-8 stainless steel such as SUS347H, there is NiCrFe alloys typified by Alloy800H defined as NCF800H in JIS standard. [0004]  NiCrFe alloy is excellent in comparison to corrosion resistance and high temperature strength 18-8 stainless steel. NiCrFe alloy addition is excellent in economy as compared to the Ni-base alloy represented by Alloy617. Therefore, NiCrFe alloys are widely used in the site of harsh environments. [0005]  Such NiCrFe alloys used in harsh environments, JP 2013-227644 (Patent Document 1), JP-A-6-264169 (Patent Document 2), JP 2002-256398 (Patent Document 3), and it has been proposed in JP-a 8-13104 (Patent Document 4). [0006]  Patent Document 1 austenitic heat resistant alloys disclosed in, in mass%, C: less than 0.02%, Si: 2% or less, Mn: 2% or less, Cr: 20% or more and less than 28%, Ni: 35% 50% or less beyond, W: 2.0 ~ 7.0%, Mo: less than 2.5% (including 0%), Nb: less than 2.5% (including 0%), Ti: 3. below 0% (including 0%), Al: 0.3% or less, P: 0.04% or less, S: 0.01% or less and N: 0.05% or less, the balance being Fe and impurities consists, furthermore, f1 = (1/2) W + Mo is 1.0 ~ 5.0, f2 = (1/2) W + Mo + Nb + 2Ti 2.0 to 8.0 and f3 = Nb + 2Ti is 0.5-5.0 it is. [0007]  It disclosed in Patent Document 2 heat and corrosion resistant alloy, in weight%, nickel 55 to 65%, chromium 19 to 25%, aluminum 1 to 4.5%, yttrium from 0.045 to 0.3%, titanium 0.15 to 1%, carbon from 0.005 to 0.5%, silicon 0.1 to 1.5%, 1% manganese less, magnesium, at least one element selected from the group consisting of calcium and cerium total 0.005%, magnesium and total less than 0.5% calcium, cerium less than 1%, boron from 0.0001 to 0.1%, 0.5% zirconium less, nitrogen 0.0001 to 0.2 percent, cobalt 10% or less and the balance being iron and incidental impurities. [0008]  Disclosed austenitic alloy in Patent Document 3, by mass%, C: 0.01 ~ 0.1%, Mn: 0.05 ~ 2%, Cr: 19 ~ 26%, Ni: 10-35% contained, the content of Si satisfies the equation 0.01

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