TECHNICAL FIELD [0001] The present invention relates to a non-aqueous electrolyte solution which includes a non-aqueous organi5 c solvent including propylene carbonate (PC) and an ester-based solvent; and lithium bis(fluorosulfonyl)imide (LiFSI), and a lithium secondary battery including the non-aqueous electrolyte solution. 10 BACKGROUND ART [0002] Demand for secondary batteries as an energy source has been significantly increased as technology development and demand with respect to mobile devices have increased. Among these secondary batteries, lithium secondary batteries 15 having high energy density and high voltage have been commercialized and widely used. [0003] A lithium metal oxide is used as a cathode active material of a lithium secondary battery, and lithium metal, a lithium alloy, crystalline or amorphous carbon, or a carbon 20 composite is used as an anode active material. A current collector may be coated with the active material of appropriate thickness and length or the active material itself may be coated in the form of a film, and the resultant product is then wound or stacked with an insulating separator 25 to prepare an electrode group. Thereafter, the electrode 3 group is put into a can or a container similar thereto, and a secondary battery is then prepared by injecting an electrolyte solution. [0004] Charge and discharge of the lithium secondary battery is performed while a process of intercalating an5 d deintercalating lithium ions from a lithium metal oxide cathode into and out of a graphite anode is repeated. In this case, since lithium is highly reactive, lithium reacts with the carbon electrode to form Li2CO3, LiO, or LiOH. Thus, 10 a film may be formed on the surface of the anode. The film is denoted as “solid electrolyte interface (SEI)”, wherein the SEI formed at an initial stage of charging may prevent a reaction of the lithium ions with the carbon anode or other materials during charge and discharge. Also, the SEI may 15 only pass the lithium ions by acting as an ion tunnel. The ion tunnel may prevent the destruction of a structure of the carbon anode due to the co-intercalation of the carbon anode and organic solvents of an electrolyte solution having a high molecular weight which solvates lithium ions and moves 20 therewith. [0005] Therefore, in order to improve high-temperature cycle characteristics and low-temperature output of the lithium secondary battery, a robust SEI must be formed on the anode of the lithium secondary battery. When the SEI is once 25 formed during the first charge, the SEI may prevent the 4 reaction of the lithium ions with the anode or other materials during repeated charge and discharge cycles caused by the subsequent use of the battery, and the SEI may act as an ion tunnel that only passes the lithium ions between the electrolyte solution and the anode5 . [0006] Typically, with respect to an electrolyte solution which does not include an electrolyte solution additive or includes a non-aqueous organic solvent or electrolyte solution additive having poor characteristics, the 10 improvement of low-temperature output characteristics may be difficult to expect due to the formation of a non-uniform SEI. In particular, in a case where a type or addition amount of a non-aqueous organic solvent, electrolyte solution additive or lithium salt that are included in the electrolyte solution is 15 not adjusted to the required amount, the surface of a cathode may be decomposed during a high-temperature reaction or the electrolyte solution may cause an oxidation reaction, and eventually, irreversible capacity of a secondary battery may increase and output characteristics may be reduced. 20 [0007] Thus, an ester-based solvent was used to improve the output characteristics of the secondary battery. However, in this case, although the output characteristics were improved, there was a limitation that high-temperature characteristics as much as those of a typical lithium secondary battery may 25 be difficult to be maintained due to material properties of 5 the ester-based solvent. [0008] [Prior Art Documents] [0009] [Patent Document] [0010] KR 2012-0090969 5 A DISCLOSURE OF THE INVENTION TECHNICAL PROBLEM [0011] The present invention provides a non-aqueous 10 electrolyte solution which may improve high-temperature cycle characteristics and capacity characteristics after hightemperature storage, as well as low-temperature, room temperature, and high-temperature output characteristics, and a lithium secondary battery including the same. 15 TECHNICAL SOLUTION [0012] According to an aspect of the present invention, there is provided a non-aqueous electrolyte solution including: i) a non-aqueous organic solvent including propylene carbonate (PC) and an ester-based solvent; and ii) 20 lithium bis(fluorosulfonyl)imide (LiFSI). [0013] According to another aspect of the present invention, there is provided a lithium secondary battery including: a cathode; an anode; a separator disposed between the cathode and the anode; and the non-aqueous electrolyte solution. 25 ADVANTAGEOUS EFFECTS [0014] According to a non-aqueous electrolyte solution of 6 the present invention, since a robust solid electrolyte interface (SEI) may be formed on an anode during initial charge of a lithium secondary battery including the nonaqueous electrolyte solution, high-temperature cycle characteristics and capacity characteristics after high5 - temperature storage as well as low-temperature, room temperature, and high-temperature output characteristics may be simultaneously improved. BRIEF DESCRIPTION OF THE DRAWINGS 10 [0015] FIG. 1 is a graph illustrating the results of the measurement of low-temperature (-30°C) output characteristics of lithium secondary batteries of Examples 1 to 3 and Comparative Examples 1, 3, and 4 according to Experimental Example 1; 15 [0016] FIG. 2 is a graph illustrating the results of the measurement of high-temperature (45°C) cycle characteristics of lithium secondary batteries of Examples 1 to 3 and Comparative Examples 1, 3, and 4 according to Experimental Example 2; 20 [0017] FIG. 3 is a graph illustrating the results of the measurement of output characteristics after high-temperature storage (60°C) of lithium secondary batteries of Examples 1 to 3 and Comparative Examples 1, 3, and 4 according to Experimental Example 3; and 25 [0018] FIGS. 4A and 4B are graphs illustrating the results 7 of the measurement of initial discharge output characteristics (FIG. 4A) and initial charge output characteristics (FIG. 4B) of lithium secondary batteries of Example 1 and Comparative Examples 1 and 2 according to the state of charge (SOC), according to Experimental Example 45 . [0019] FIG. 5 is a graph illustrating the results of the measurement of capacity retention ratios (%) of lithium secondary batteries of Example 1 and Comparative Examples 1 and 2 according to storage time after high-temperature 10 storage, according to Experimental Example 5. MODE FOR CARRYING OUT THE INVENTION [0020] Hereinafter, the present invention will be described in more detail to allow for a clearer understanding of the present invention. It will be understood that words or terms 15 used in the specification and claims shall not be interpreted as the meaning defined in commonly used dictionaries. It will be further understood that the words or terms should be interpreted as having a meaning that is consistent with their meaning in the context of the relevant art and the technical 20 idea of the invention, based on the principle that an inventor may properly define the meaning of the words or terms to best explain the invention. [0021] A non-aqueous electrolyte solution according to an embodiment of the present invention may include a non-aqueous 25 organic solvent including propylene carbonate (PC) and an 8 ester-based solvent; and lithium bis(fluorosulfonyl)imide (LiFSI). [0022] According to an embodiment of the present invention, in a case where lithium bis(fluorosulfonyl)imide is used in combination with the non-aqueous organic solvent includin5 g propylene carbonate (PC) and an ester-based solvent, since a solid SEI layer is formed on an anode during initial charge, initial output characteristics, low-temperature output characteristics, and high-temperature output characteristics 10 may not only be improved, but also the decomposition of the surface of a cathode, which may occur during high-temperature cycles at 45°C or more, may be suppressed and an oxidation reaction of an electrolyte solution may be prevented. Thus, capacity characteristics of a secondary battery may be 15 simultaneously improved. [0023] In general, since an ester-based solvent may have a lower freezing point than other carbonate-based solvents and may have excellent viscosity and permittivity at low temperature, the ester-based solvent has advantages in that 20 it may reduce the resistance of a lithium secondary battery at low temperature and may improve output characteristics as well as initial room temperature output characteristics when the ester-based solvent is used in the battery. However, since the ester-based solvent has a low freezing point, high25 temperature battery characteristics as much as those of a 9 typical lithium secondary battery may be difficult to be maintained. [0024] Propylene carbonate has advantages in that it may exceptionally act as an electrolyte while having a wider temperature range than other carbonate-based solvents5 . [0025] Thus, in the present invention, excellent output characteristics at low temperature or room temperature, i.e., the advantages of the ester-based solvent, are maintained, and the limitations related to the high-temperature 10 characteristics of the ester-based solvent may be addressed by using the ester-based solvent in combination with the propylene carbonate. [0026] However, in a case where propylene carbonate is used with a lithium salt, such as LiPF6, as a solvent, an enormous 15 amount of irreversible reactions may occur during a process of forming the SEI in a lithium secondary battery using a carbon electrode and a process of intercalating lithium ions, which are solvated by the propylene carbonate, between carbon layers. This may cause the degradation of the battery 20 performance such as high-temperature cycle characteristics. [0027] Also, when the lithium ions solvated by the propylene carbonate are intercalated into the carbon layers constituting the anode, exfoliation of a carbon surface layer may proceed. The exfoliation may occur because gas, which is 25 generated when the solvent decomposes between the carbon 10 layers, causes a large distortion in the carbon layers. The exfoliation of the surface layer and the decomposition of the electrolyte solution may continuously proceed. As a result, since an effective SEI may not be formed when the electrolyte solution including propylene carbonate is used in combinatio5 n with a carbon-based anode material, lithium ions may not be intercalated. [0028] In the present invention, the above-described limitations, which occur when the propylene carbonate and the 10 lithium salt, such as LiPF6, are used together, may be addressed by using lithium bis(fluorosulfonyl)imide in combination therewith. [0029] Since the lithium bis(fluorosulfonyl)imide, as a lithium salt, is added to a non-aqueous electrolyte solution 15 to form a robust and stable SEI on an anode, the lithium bis(fluorosulfonyl)imide may improve low-temperature output characteristics. Also, the lithium bis(fluorosulfonyl)imide may suppress the decomposition of the surface of the cathode, which may occur during high-temperature cycles, and may 20 prevent the oxidation reaction of the electrolyte solution. [0030] According to an embodiment of the present invention, a mixing ratio of the propylene carbonate to the ester-based solvent, as the non-aqueous organic solvent, may significantly affect the improvement of initial room 25 temperature, low-temperature, and high-temperature output 11 characteristics as well as capacity characteristics after high-temperature storage. [0031] The mixing ratio of the propylene carbonate to the ester-based solvent is in a range of 1:0.5 to 1:4, preferably, in a range of 1:1 to 1:3.5, and more preferably, in a rang5 e of 1:1 to 1:2.5. In the case that the above range of the mixing ratio is satisfied, a synergistic effect due to the mixing of the two non-aqueous organic solvents may be obtained. 10 [0032] In the case that the amount of the propylene carbonate added is less than the above range, since gas may be continuously generated due to the decomposition of the surface of the cathode during the high-temperature cycles, a swelling phenomenon may occur in which a thickness of the 15 battery increases. In the case in which the amount of the propylene carbonate is greater than the above range, a robust SEI may be difficult to be formed on the anode during the initial charge. [0033] In the non-aqueous organic solvent according to an 20 embodiment of the present invention, the ester-based solvent may be included in an amount of 10 parts by weight to 70 parts by weight, for example, 20 parts by weight to 50 parts by weight based on 100 parts by weight of the non-aqueous organic solvent. 25 [0034] In the case that the amount of the added ester-based 12 solvent is greater than 70 parts by weight, high-temperature performance may degrade, and in the case in which the amount of the added ester-based solvent is less than 10 parts by weight, it is not desirable because effects, such as targeted initial room temperature output characteristics and low5 - temperature output characteristics, may not be sufficiently obtained. [0035] According to an embodiment of the present invention, within the above amount of the ester-based solvent included, 10 an optimum effect on capacity characteristics after hightemperature storage as well as room temperature, lowtemperature, and high-temperature output characteristics of the lithium secondary battery of the present invention may be achieved by appropriately adjusting the amount of the 15 propylene carbonate within the range of the mixing ratio. [0036] In the non-aqueous organic solvent according to the embodiment of the present invention, examples of the esterbased solvent may be any one selected from the group consisting of methyl formate, methyl acetate, ethyl acetate, 20 isopropyl acetate, isoamyl acetate, methyl propionate, ethyl propionate, methyl butylate, and ethyl butylate, or a mixture of two or more thereof. Among these materials, the esterbased solvent may include methyl propionate, ethyl propionate, or a mixed solvent thereof, and for example, may include 25 ethyl propionate. 13 [0037] Also, a non-aqueous organic solvent, which may be further included in the non-aqueous electrolyte solution in addition to the ester-based solvent and propylene carbonate, is not limited as long as it may minimize the decomposition due to the oxidation reaction during charge and discharge o5 f the battery and may exhibit desired characteristics with additives. [0038] The non-aqueous organic solvent, which may be further included in the non-aqueous electrolyte solution according to 10 an embodiment of the present invention, for example, may further include any one selected from the group consisting of butylene carbonate (BC), dimethyl carbonate (DMC), diethyl carbonate (DEC), dipropyl carbonate (DPC), ethylmethyl carbonate (EMC), methylpropyl carbonate (MPC), and 15 ethylpropyl carbonate (EPC), or a mixture of two or more thereof. [0039] According to an embodiment of the present invention, a concentration of the lithium bis(fluorosulfonyl)imide in the non-aqueous electrolyte solution may be in a range of 0.1 20 mole/ℓ to 2 mole/ℓ, preferably, 0.5 mole/ℓ to 1.5 mole/ℓ. In the case that the concentration of the lithium bis(fluorosulfonyl)imide is less than 0.1 mole/ℓ, effects of improving the low-temperature output and high-temperature cycle characteristics of the battery may be insignificant. 25 In the case in which the concentration of the lithium 14 bis(fluorosulfonyl)imide is greater than 2 mole/ℓ, side reactions in the electrolyte solution may excessively occur during the charge and discharge of the battery, and thus, the swelling phenomenon may occur. [0040] In order to further prevent the side reactions, th5 e non-aqueous electrolyte solution of the present invention may further include a lithium salt. Any lithium salt typically used in the art may be used as the lithium salt. For example, the lithium salt may include any one selected from the group 10 consisting of LiPF6, LiBF4, LiSbF6, LiAsF6, LiClO4, LiN(C2F5SO2)2, LiN(CF3SO2)2, CF3SO3Li, LiC(CF3SO2)3, and LiC4BO8, or a mixture of two or more thereof. [0041] A mixing ratio of the lithium salt to the lithium bis(fluorosulfonyl)imide may be in a range of 1:1 to 1:9 as a 15 molar ratio. In the case that the mixing ratio of the lithium salt to the lithium bis(fluorosulfonyl)imide is outside the range of the molar ratio, the side reactions may excessively occur in the electrolyte solution during the charge and discharge of the battery, and thus, the swelling 20 phenomenon may occur. [0042] In particular, the mixing ratio of the lithium salt to the lithium bis(fluorosulfonyl)imide may be in a range of 1:6 to 1:9 as a molar ratio. Specifically, in the case in which the mixing ratio of the lithium salt to the lithium 25 bis(fluorosulfonyl)imide is less than 1:6 as a molar ratio, 15 the enormous amount of irreversible reactions may occur during the process of forming the SEI in the lithium-ion battery and the process of intercalating lithium ions, which are solvated by the propylene carbonate and ethylene carbonate, into the anode, and the effects of improving th5 e low-temperature output, cycle characteristics after hightemperature storage, and capacity characteristics after hightemperature storage of the secondary battery may be insignificant due to the exfoliation of an anode surface 10 layer (e.g., carbon surface layer) and the decomposition of the electrolyte solution. [0043] The non-aqueous electrolyte solution according to the embodiment of the present invention may further include at least one compound selected from the group consisting of 15 LiBF4, lithium oxalyldifluoroborate (LiODFB), and ethylene sulfate (ES), as an additive. Also, for example, the nonaqueous electrolyte solution may include two or more compounds selected from the group consisting of LiBF4, LiODFB, and ES. The additive may prevent a side reaction in the 20 electrolyte solution during the charge and discharge of the lithium secondary battery including an excessive amount of lithium bis(fluorosulfonyl)imide at room temperature. Accordingly, the additive may effectively improve cycle characteristics of the battery at room temperature. In this 25 case, an amount of each additive may be in a range of 0.01 16 wt% to 5 wt% based on the total weight of the electrolyte solution. [0044] A lithium secondary battery according to an embodiment of the present invention may include a cathode including a cathode active material; an anode including a5 n anode active material; a separator disposed between the cathode and the anode; and the non-aqueous electrolyte solution. [0045] Herein, the cathode active material may include a 10 manganese spinel-based active material, lithium metal oxide, or a mixture thereof. Furthermore, the lithium metal oxide may be selected from the group consisting of lithium-nickelmanganese- cobalt-based oxide, lithium-manganese-based oxide, lithium-nickel-manganese-based oxide, and lithium-manganese15 cobalt-based oxide, and for example, may include LiCoO2, LiNiO2, LiMnO2, LiMn2O4, Li(NiaCobMnc)O2 (where 0 [0081] Low-temperature outputs were calculated from voltage 15 differences which were obtained by discharging the lithium secondary batteries of Examples 1 to 3 and Comparative Examples 1, 3, and 4 at 0.5 C for 10 seconds for the state of charge (SOC) at -30°C. The results thereof are presented in FIG. 1. 20 [0082] Referring to FIG. 1, in a case where a molar ratio of LiPF6 to lithium bis(fluorosulfonyl)imide (LiFSI) is 1:5 to 1:9 when the SOC was 100%, it may be understood that lowtemperature output characteristics were significantly improved in comparison to Comparative Example 4 having the 25 molar ratio of 1:0.5 and Comparative Example 3 in which LIFSI 25 was not used but LiPF6 was used alone. In particular, it may be understood that that the low-temperature output characteristics were improved as the amount of LiFSI increased. [0083] Specifically, with respect to Example 1 in which th5 e molar ratio of LiPF6 to LiFSI is 1:9, it may be understood that the low-temperature output characteristics were improved by about 40% or more in comparison to those of Comparative Example 4 having the molar ratio of 1:0.5 and were improved 10 by 60% or more in comparison to those of Comparative Example 3 in the case that the SOC was 100%. Similarly, in a case where the SOC was 20%, 40%, 60%, and 80%, excellent results may be obtained similar to the case in which the SOC was 100%. [0084] When comparing Example 2, in which the molar ratio of 15 LiPF6 to LiFSI is 1:6, with Example 3 having the molar ratio of 1:5, it may be understood that despite the fact that the difference in the molar ratios was only 1, low-temperature output characteristics of Example 2 were significantly different from those of Example 3 in consideration of an 20 increase in the amount of LIFSI in Example 3. [0085] Therefore, it may be confirmed that the lowtemperature output characteristics of the lithium secondary battery may be improved by adjusting the molar ratio of LiPF6 to LiFSI. 25 26 [0086] Experimental Example 2 [0087] [0088] The lithium secondary batteries of Examples 1 to 3 and Comparative Examples 1, 3, and 4 were charged at 1 C t5 o 4.2 V/38 mA at 45°C under a constant current/constant voltage (CC/CV) condition and then discharged at a constant current (CC) of 3 C to a voltage of 3.03 V to measure discharge capacities. The charge and discharge were repeated 1 to 10 1,000 cycles and the measured discharge capacities are presented in FIG. 2. [0089] Referring to FIG. 2, with respect to high-temperature cycle characteristics, the lithium secondary batteries of Examples 1 to 3 initially exhibited capacity retention ratios 15 similar to those of Comparative Examples 1, 3, and 4 to a 250th cycle. The capacity retention ratios of Examples 1 to 3 were significantly different from those of Comparative Examples 1, 3, and 4 as the number of cycles increased, in particular, after a 700th cycle. 20 [0090] Also, in a 1,000th cycle, it may be understood that the capacity retention ratios of Example 1 and 2 were improved by about 40% or more in comparison to that of Comparative Examples 1, were improved by about 35% or more in comparison to that of Comparative Example 4, and were 25 improved by about 100% or more in comparison to that of 27 Comparative Example 3. [0091] When comparing Example 2, in which the molar ratio of LiPF6 to LiFSI is 1:6, with Example 3 having the molar ratio of 1:5, it may be understood that despite the fact that the difference in the molar ratios was only 1, high-temperatur5 e cycle characteristics of Example 2 were significantly different from those of Example 3 in consideration of the increase in the amount of LIFSI in Example 3. [0092] Therefore, it may be confirmed that the high10 temperature cycle characteristics of the lithium secondary battery may be improved by adjusting the molar ratio of LiPF6 to LiFSI. [0093] Experimental Example 3 15 [0094]

[0095] The lithium secondary batteries of Examples 1 to 3 and Comparative Examples 1, 3, and 4 were stored at 60°C and then charged at 1 C to 4.2 V/38 mA under a CC/CV condition. 20 Then, the lithium secondary batteries were discharged at a CC of 1 C to a voltage of 3.0 V to measure discharge capacities. The results thereof are presented in FIG. 3. [0096] Referring to FIG. 3, it may be understood that capacity retention ratios of the lithium secondary batteries 25 of Examples 1 to 3 were significantly better than those of 28 the lithium secondary batteries of Comparative Examples 1, 3, and 4 up to a storage time of 16 weeks. [0097] In contrast, with respect to Comparative Example 4 having the molar ratio of 1:0.5 and Comparative Example 3 in which LiFSI was not used but LiPF6 was used alone, capacit5 y retention ratios at a storage time of 16 weeks were significantly decreased by 10% to 30% in comparison to those of Examples 1 and 2 of the present application. [0098] Thus, the high-temperature storage characteristics of 10 the lithium secondary battery may be improved by adjusting the molar ratio of LiPF6 to LiFSI. In particular, it may be confirmed that the high-temperature storage characteristics of the lithium secondary batteries, in which the molar ratio of LiPF6 to LiFSI was in a range of 1:6 to 1:9, were 15 significantly better than those of the lithium secondary batteries in which the molar ratio was outside the above range. [0099] Therefore, it may be confirmed that the output characteristics after high-temperature storage of the lithium 20 secondary battery may be improved by adjusting the molar ratio of LiPF6 to LiFSI. [00100] Experimental Example 4 [00101] 29 [00102] In order to evaluate output characteristics according to the type of an organic solvent, room temperature outputs were calculated from voltage differences which were obtained by discharging the lithium secondary batteries of Example 1 and Comparative Examples 1 and 2 at 0.5 C for 10 seconds fo5 r the state of charge (SOC) at 23°C. The results thereof are presented in FIGS. 4A and 4B. FIG. 4A illustrates results of discharge output (W) at 23°C according to SOC (%), and FIG. 4B illustrates results of charge output (W) at 23°C according 10 to SOC (%). [00103] Referring to FIG. 4A, the lithium secondary battery of Example 1 had better output characteristics than the lithium secondary batteries of Comparative Examples 1 and 2 from 30% SOC, and from 50% SOC, the output characteristics of 15 the lithium battery of Example 1 began to exhibit a more significant difference from those of the lithium batteries of Comparative Examples 1 and 2. Also, in a case where the SOC was 90%, it may be understood that the lithium battery of Example 1 had room temperature discharge output 20 characteristics that were improved about 1.2 to 1.4 times or more in comparison to those of the lithium secondary batteries of Comparative Examples 1 and 2. Similarly, when the results of charge output (W) at 23°C according to SOC (%) of FIG. 4B were examined, a difference in output 25 characteristics between Example 1 and Comparative Examples 1 30 and 2 was about 1.2 times or more at 30% SOC. [00104] In particular, in a case where propylene carbonate and ester-based solvent (ethyl propionate) were not used as a non-aqueous organic solvent as in Comparative Example 2, it may be understood that the room temperature outpu5 t characteristics were significantly decreased. In a case where propylene carbonate was used but an ester-based solvent (ethyl propionate) was not used as in Comparative Example 1, it may be understood that its output characteristics were 10 increased in comparison to Comparative Example 2, but were significantly decreased in comparison to Example 1 in which propylene carbonate and ester-based solvent(ethyl propionate) were used in combination. [00105] Therefore, it may be confirmed that the room 15 temperature output characteristics were significantly improved by using lithium bis(fluorosulfonyl)imide in combination with a non-aqueous organic solvent including propylene carbonate and ethyl propionate as an ester-based solvent. 20 [00106] Experimental Example 5 [00107] [00108] The lithium secondary batteries of Example 1 and 25 Comparative Examples 1 and 2 were charged at 1 C to 4.2 V/38 31 mA under a CC/CV condition, and then discharged at a CC of 1 C to a voltage of 3.0 V to measure discharge capacities. The results thereof are presented in FIG 5. [00109] Referring to FIG. 5, there was no difference between capacity retention ratio (%) of Example 1 and capacit5 y retention ratios of Comparative Examples 1 and 2 up to the storage time of 8 weeks. However, with respect to the lithium secondary batteries of Comparative Examples 1 and 2 after the storage time of 3 weeks, the capacity retention 10 ratios were rapidly decreased as the storage time increased. After the storage time of 5 weeks, it may be understood that the difference between the capacity retention ratio of Example 1 and the capacity retention ratios of Comparative Examples 1 and 2 was gradually increased. 15 [00110] Thus, it may be confirmed that the capacity characteristics after high-temperature storage of the lithium secondary battery of Example 1 was improved in comparison to those of the lithium secondary batteries of Comparative Examples 1 and 2. 20 [00111] Therefore, it may be confirmed that the capacity characteristics after high-temperature storage of the lithium secondary battery of Example 1, in which lithium bis(fluorosulfonyl)imide was used in combination with the non-aqueous organic solvent including propylene carbonate and 25 ethyl propionate as an ester-based solvent, was improved in 32 comparison to those of the lithium secondary batteries of Comparative Examples 1 and 2 having compositions different from that of Example 1. INDUSTRIAL APPLICABILITY [00112] According to a non-aqueous electrolyte solution o5 f the present invention, since a robust SEI may be formed on an anode during initial charge of a lithium secondary battery including the non-aqueous electrolyte solution, hightemperature cycle characteristics and capacity 10 characteristics after high-temperature storage as well as low-temperature, room temperature, and high-temperature output characteristics may be simultaneously improved. Therefore, the non-aqueous electrolyte solution may be suitable for secondary batteries. WE CLAIMS:- 1. A non-aqueous electrolyte solution comprising: i) a non-aqueous organic solvent including propylene carbonate (PC) and an ester-based solvent; an5 d ii) lithium bis(fluorosulfonyl)imide (LiFSI). 2. The non-aqueous electrolyte solution of claim 1, wherein a mixing ratio of the propylene carbonate to the 10 ester-based solvent is in a range of 1:0.5 to 1:4 as a weight ratio. 3. The non-aqueous electrolyte solution of claim 1, the ester-based solvent comprises any one selected from the group 15 consisting of methyl formate, methyl acetate, ethyl acetate, isopropyl acetate, isoamyl acetate, methyl propionate, ethyl propionate, methyl butylate, and ethyl butylate, or a mixture of two or more thereof. 20 4. The non-aqueous electrolyte solution of claim 3, wherein the ester-based solvent comprises methyl propionate, ethyl propionate, or a mixed solvent thereof. 5. The non-aqueous electrolyte solution of claim 1, 25 further comprising a lithium salt. 34 6. The non-aqueous electrolyte solution of claim 5, wherein a mixing ratio of the lithium salt to the lithium bis(fluorosulfonyl)imide is in a range of 1:1 to 1:9 as a molar ratio5 . 7. The non-aqueous electrolyte solution of claim 6, wherein the mixing ratio of the lithium salt to the lithium bis(fluorosulfonyl)imide is in a range of 1:6 to 1:9 as a 10 molar ratio. 8. The non-aqueous electrolyte solution of claim 1, wherein a concentration of the lithium bis(fluorosulfonyl)imide in the non-aqueous electrolyte 15 solution is in a range of 0.1 mole/ℓ to 2 mole/ℓ. 9. The non-aqueous electrolyte solution of claim 1, wherein an amount of the ester-based solvent is in a range of 10 parts by weight to 70 parts by weight based on 100 parts 20 by weight of the non-aqueous organic solvent. 10. The non-aqueous electrolyte solution of claim 9, wherein the amount of the ester-based solvent is in a range of 20 parts by weight to 50 parts by weight based on 100 25 parts by weight of the non-aqueous organic solvent. 35 11. The non-aqueous electrolyte solution of claim 1, wherein the non-aqueous organic solvent further comprises any one selected from the group consisting of butylene carbonate (BC), dimethyl carbonate (DMC), diethyl carbonate (DEC)5 , dipropyl carbonate (DPC), ethylmethyl carbonate (EMC), methylpropyl carbonate (MPC), and ethylpropyl carbonate (EPC), or a mixture of two or more thereof. 10 12. The non-aqueous electrolyte solution of claim 5, wherein the lithium salt comprises any one selected from the group consisting of LiPF6, LiBF4, LiSbF6, LiAsF6, LiClO4, LiN(C2F5SO2)2, LiN(CF3SO2)2, CF3SO3Li, LiC(CF3SO2)3, and LiC4BO8, or a mixture of two or more thereof. 15 13. The non-aqueous electrolyte solution of claim 1, further comprising at least one compound selected from the group consisting of LiBF4, lithium oxalyldifluoroborate (LiODFB), and ethylene sulfate (ES). 20 14. The non-aqueous electrolyte solution of claim 1, further comprising two or more compounds selected from the group consisting of LiBF4, LiODFB, and ES. 25 15. A lithium secondary battery comprising: 36 a cathode; an anode; a separator disposed between the cathode and the anode; and the non-aqueous electrolyte solution of claim 15 .